B nano tech

24
QinetiQ Nanomaterials Presentation to Rolls Royce QNL Business Overview QNL Business Overview 1 March 2007 Dr Paul Reip Founder and CTO / QNL - making a material difference

Transcript of B nano tech

Page 1: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 1/24

QinetiQ Nanomaterials

Presentation to Rolls Royce

QNL Business OverviewQNL Business Overview

1 March 2007

Dr Paul ReipFounder and CTO / QNL

- making a material difference

Page 2: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 2/24

QinetiQ Nanomaterials

QinetiQ PLC

Europe’s largest independent team of scientists and engineers

- 10,000 staff - $1.5bn revenue

QinetiQ Inc established with five

subsidiary companiesMain business streams:

- Technology-based solutions- Consultancy- Technology exploitation- Integrated managed services

IPO Feb 15th 2006

A commercial science and technology powerhouse formed from the UK Government’s military andaerospace research & development organization with an unrivalled track record in applied science andtechnology

Page 3: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 3/24

QinetiQ Nanomaterials

What is QNL?

UK based company and wholly ownedsubsidiary of QinetiQ plc.

Patented process for developing andmanufacturing novel nanomaterials

A leading nanotechnology company with a

broad set of international customers andpartners

Focussed on serving the unmet material needsfor renewable energy, clean technologysystems and performance materials

Working with a number of select industrial andleading academic partners to developsolutions to the markets needs

Page 4: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 4/24

QinetiQ Nanomaterials

Driving the need for nanomaterials

Renewable energy sources now demanded & operationalRenewable energy sources now demanded & operational

Clean technologies needed to meet regulatory and social pressureClean technologies needed to meet regulatory and social pressure ss

Process improvements demand performance materials to driveProcess improvements demand performance materials to drivedown costs and increase efficiencydown costs and increase efficiency

$1BN R&D in$1BN R&D inAutomotiveAutomotive

$250BN$250BNGlobalGlobal

$2BN$2BN15%15%

80% Global80% GlobalGDPGDP

$250BN$250BNGlobalGlobal

$1BN R&D$1BN R&DAutomotiveAutomotive

$2BN$2BN15% CAGR15% CAGR

80%80%Global GDPGlobal GDP

Page 5: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 5/24

QinetiQ Nanomaterials

Areas of FocusSustainable Economy

• Clean Technology• Anti viral• Anti bacterial• Anti fungal• Water purification• Functional Fibres

• Energy Management• Hydrogen storage materials• Photovoltaic silicon film production• Efficient coolants & refrigerants

• Performance Materials• Tooling• CMP• Catalysis• Super Capacitors

Page 6: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 6/24

QinetiQ Nanomaterials

Market Environment & Sector Needs

Need for multimodal solutions for antiviral &antimicrobial materials

- MRSA costs the NHS £1BN in the UK.- An Avian flu pandemic among humans could cost

the global economy about ca. US$1.25 trillion.

AVNP

Page 7: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 7/24

QinetiQ Nanomaterials

Market Environment & Sector Needs

Low pressure and temperature materialsneeded to carry H 2 gas

- Lack of material hampering wider and more rapid adoption.- >50 million new vehicle sales globally each year

Inefficient manufacturing processes for solar grade silicon keeps cost per Watt too high for mass adoption

- 26,000 tons of Si required in 2004, 90% supply achieved- $6BN market ca.12% growth

- Si pricing upward pressure

Page 8: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 8/24

QinetiQ Nanomaterials

Nanomaterial fabrication processes

high volumeproduction

but limited quality /yield of material

typically used for oxides for

sunscreens, etc

medium volumeproduction

but long processingcycles, quality issues

typically used for oxides - silica,

alumina

low volumeproduction

used for multilayer structured

applications

typically used for photovoltaics, highvalue applicationssuch as nano bar

codes

medium / highvolume production

with high quality of material

typically used for premium applications,

metals, oxides,carbides, nitrides

Page 9: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 9/24

QinetiQ Nanomaterials

Feedstock

Vaporised

Cooled &Modification

Nanoproduct

Feed

system

Advantages of using plasma

- material uniformity- chemical composition- no contamination- better control- scalability- flexibility

- controllability- safety

The QNL Tesima® plasma process

Twin torch plasma – side view

Twin torch plasma – bottom view

Page 10: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 10/24

QinetiQ Nanomaterials

QNL Tesima® Process

Page 11: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 11/24

QinetiQ Nanomaterials

Tesima ® materials

MetalsAluminium

Copper

Silver

Nickel

Cobalt

TitaniumTungsten

Tantalum *

Boron *

* planned

OxidesZinc Oxide

Copper Oxide

Cerium Oxide

Tin Oxide

Cuprous Oxide

Titanium DioxideNickel Oxide

Zirconium Oxide

Carbides and NitridesTungsten Carbide

Aluminium Nitride

Boron Nitride

Silicon Carbide*

Silicon Nitride*

Boron Carbide*

Tesimet ® Tesimox ® Tesimide ®

Page 12: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 12/24

QinetiQ Nanomaterials

Tesima ® materials

Types

Doped materials

Alloys

Structured Blends

Layered

Non Stoichiometric

Tesimorph ®

Materials

ZnO / CuO

ZnO / TiO 2

Non stoi ZnO

Mixed Oxides

Stainless Steel

+ others under NDA

Applications

Electronics

Fuel Cells

Opto - electronics

Pyrotechnics

Rocket MotorsExplosives

Cermets

O&G

Defence

LayeredStructuredAlloysDoped Stoichiometry

Page 13: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 13/24

QinetiQ Nanomaterials

QNL Tesima ® Plant

QNL Facility commissioned 2002

New Tesima system (Al capable) 200524/7 capable

Metals, oxides, nitrides, carbidesTesimorph mixed materials

COMINA Rapid Particle Prototyping SystemScheduled for spring 2007

COMINA RPPS

TESIMA®

Page 14: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 14/24

QinetiQ Nanomaterials

COMINA Materials

Rapid Particle PrototypingCapability

- Metals, Oxides, Carbides, Nitrides,Sulphides

- Alloys- Mixed Oxides- Doped materials- Magnetic Materials- Catalysts- Phosphors

Cost Effective

Scaling Potential to kg’s and beyond

Page 15: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 15/24

QinetiQ Nanomaterials

QNL Nanomaterial Characterisation Services

Standard Tests – all materials:

Laser Particle Size Analysis (Mastersizer) QSEM QXRD QBET X

Specialised Tests – on request:

Raman Spectroscopy QSurface Characterisation (XPS) QTEM QDifferential Scanning Calorimetry (DSC) QDynamic Mechanical Thermal Analysis (DMTA)QExplosivity ( minimum ignition energy, layer ignition

energy, minimum ignition temperature, explosionseverity and LOC analysis)XOxygen Measurement XChemical Analysis XTEM EELS X

Q = in-houseX = external

Particle Size Distribution

0.01 0.1 1 10 100 1000 3000Particle Size (µm)

0

5

10

15

20

M i x e d R e s u

l t T y p e

( % )

Nano W QNA 1485, 21 February 2006 09:09:58 Nano W QNA 1485, 21 February 2006 09:09:58

Page 16: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 16/24

QinetiQ Nanomaterials

Material

Production

Formulation

& Dispersion

Application

DevelopmentCharacterisation HS&E

Associate

Provider

(Non-funded)

Core

Technology

Provider

(Funded)

Technology

Provider

(Non-funded)

Flame PyrolysisJohnson Matthey

High Energy MixingUniversity of Liverpool

Nano characterisationICI MSG

EU Nanomanufacturing Group

Nanoscale EngineeringLeeds Nanofactory

Coatings & CeramicsLongbridge

Trade / ResearchOrganisations

Liq. Phase ProcessingCPI / Uniqema

NanoSafeIOM

Colloid ScienceBCC

ColloidCharacterisation

BCC

MNT MetrologyCEMMNT

Multilayer CoatingHarman

High Shear PrecipitationHarman Dispersants

Noveon

Mixing / DispersingReed Bordal

Plastic Film CoatingAutotype

Ink Jet PrintingPTL / Xennia?

Nano characterisationMalvern Instruments

DispersionsSunChemical

Other Dispersant &DispersionSuppliers?

DTF?Lucite?Invista?

Toll Manufacturers

Colloidal PrecipitationAMR

CNTT. Swan

Grinding/Mixing/Coating

Imerys

Plasma ProcessingQNL

NanoCentral

Page 17: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 17/24

QinetiQ Nanomaterials

Energetics – Aluminium – Special Products

Aluminium (passivated) 80nm

200nm

Aluminium (passivated) 200nm

Tesima enable arange of Particle sizes tobe produced

1 μm

Tesima enables some variation

in particle morphologyto be produced

Highly sensitivenano Al with 200nm+ “tails”

Page 18: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 18/24

QinetiQ Nanomaterials

Aluminium Boron Nanomaterials

Sponsored by UK MOD

Development of ultra high performance Al/Bmaterials for energetic applications- Pyrotechnics- Explosives- Igniters- Rocket motors

• Solid • Hybrid

QNL Tesima® Aluminium process chosen

System modified to enable high performancematerials to be manufactured

Successfully manufactured – a world first

10nm

200nm

1mm

QNL nano Aluminium

QNL nano Aluminium / Boron

Page 19: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 19/24

QinetiQ Nanomaterials

Aluminium Boron Nanomaterials for Energetics

Tesimorph® EAB-80

80nm aluminium boron particles

Passivated with oxide layer

Produced under UK MOD contract

World first

Page 20: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 20/24

QinetiQ Nanomaterials

Stainless Steel

Tests with standard 316 stainless steelfeedstock

Results show good quality result with 25nmaverage particle size, slightly Cr poor

0 2 4 6 8 10Energy (keV)

0

5

10

15

ps

COCr Fe

Ni

Ni

Al

Cr

Cr

Fe

FeNi

Ni

10

90

81

8686

%Oxide

12

1.2

31.954.9

Atomic%

3.3Si

23.4C

48.7O

0.4Ni

8.9Cr 15.3Fe

Atomic%Element(Surface)

XPS Quantification QNA1030

Page 21: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 21/24

QinetiQ Nanomaterials

Value Proposition

Openly InnovativePartnered development leads to shared IP

Exquisite control of process gives unique materials

Rapid prototype facility

Support of 10,000 QinetiQ scientists and engineers

QNL assists companies generate greater valueQNL assists companies generate greater valueby enhancing their competitive advantage throughby enhancing their competitive advantage through

the application of unique nanomaterials, whichthe application of unique nanomaterials, whichenhance performance and reduces costs.enhance performance and reduces costs.

Page 22: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 22/24

QinetiQ Nanomaterials

IP Assets

OpticalCompone

nts

Energetics

CMP

Hard &Tough

Performance Materials

EnhancedCooling

Renewable Energy

Water Treatment

FIBRES

AVNP

Sustainable Economy

Puresiliconfilms

H StorageMultifunctionalparticles

Polymer Composite

Fibres

NEMSExplosiveDevices

Fuel CellInk JetShapeMemoryAlloys

KnowHowMat’l

Design

IP

Area

Page 23: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 23/24

QinetiQ Nanomaterials

Summary

Leading Nanotechnology CompanyFocussed on solving importantproblems

Substantial IP portfolio

Locked in partners

Own production facility

Ability to supply volume

Rapid prototyping capabilityGrowing revenue

Page 24: B nano tech

8/8/2019 B nano tech

http://slidepdf.com/reader/full/b-nano-tech 24/24

QinetiQ Nanomaterials

Contact Details

- Founder and CTO

Dr Paul [email protected]+44 [0] 1252 39 7412

- Sales Director Dr Ian [email protected]

+44 [0] 1252 39 2348 QinetiQ Nanomaterials LtdY25 BuildingCody Technology ParkFarnboroughHampshireUKGU14 0LX

Web

www.nano.qinetiq.comwww.avnp.co.uk