CARBON NANOTUBE

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OVERVIEWCarbon nanotubes

(CNTs) are allotropes of carbon with a cylindrical nanostructure. Nanotubes have been constructed with length-to-diameter ratio of up to 132,000,000:1.These cylindrical carbon molecules have novel properties, making them potentially useful in many applications.

STRUCTURE

Carbon Nanotubes are considered to be a curved graphene sheet. Graphene sheets are seamless cylinders derived from a honeycomb lattice, representing a single atomic layer of crystalline graphite.

TYPES OF CARBON NANOTUBE

Multi-walled Single-walled

Cup stacked carbon nanotubesNanobud Torus

PROPERTIES OF CARBON NANOTUBE

• Strength Carbon nanotubes are the strongest and stiffest materials yet discovered in terms of tensile strength and elastic modulus respectively. This strength results from the covalent sp2 bonds formed between the individual carbon atoms.

• Hardness Standard single walled carbon nanotubes can withstand a pressure up to 24GPa without deformation. Maximum pressures measured using current experimental techniques are around 55GPa.

Electrical : Because of the symmetry and unique electronic structure of graphene,the structure of a nanotube strongly affects its electrical properties. The metallic nanotubes can carry an electric current density that are limited by electromigration.

Thermal : All nanotubes are expected to be very good thermal conductors along the tube, exhibiting a property known as "ballistic conduction", but good insulators laterally to the tube axis.

Defects : the existence of a crystallographic defect affects the material properties.Defects can occur in the form of atomic vacancies.High levels of Such defects can lower the tensile strength by up to 85%.Another form of Carbon nanotube defect is the Stone Wales defect,which creates a pentagon and heptagon pair by rearrangement of the bonds.

Toxicity : Results of rodent studies collectively show that CNTs were capable of producing inflammation, epithelioid granulomas (microscopic nodules), fibrosis, and biochemical/toxicological changes in the lungs.Comparative toxicity studies in which mice were given equal weights of test materials showed that SWCNTs were more toxic than quartz, which is considered a serious occupational health hazard when chronically inhaled.

Arc discharge : Nanotubes were observed in 1991 in the carbon soot of graphite electrodes during an arc discharge, by using a current of 100 amps, that was intended to produce fullerenes.

Applications

Powder of carbon nanotube

Laser ablation : In this process, a pulsed laser vaporizesa graphite target in a high-temperature reactor while an inert gas is bled intothe chamber.Nanotubes develop on the cooler surfaces of the reactor as theVaporized carbon condenses.A water-cooled surface may be included in theSystem to collect the nanotubes.

Super-growth CVD (water-assisted chemical vapour deposition) this process was developed by Kenji Hata, Sumio Iijima and co-workers at AIST, Japan.In this process, the activity and lifetime of the catalyst are enhanced by addition of water into the CVD reactor.

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