Ardex Grout Booster - Artisan Stone · BRMA-TWA: 0.25 mg/m3 as cyclohexane solubles [BRMA Code of...

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Ardex Grout Booster Hazard Alert Code: MODERATE Chemwatch Material Safety Data Sheet Issue Date: 3-May-2013 CHEMWATCH 7516-96 A317LP Version No:4.1.1.1 Page 1 of 13 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Ardex Grout Booster SYNONYMS "grout additive" PRODUCT USE Additive for grout mixes. SUPPLIER Company: Ardex Australia Pty Ltd Address: 20 Powers Road Seven Hills NSW, 2147 Australia Telephone: 1800 224 070 Emergency Tel:1800 224 070 (Mon- Fri, 9am- 5pm) Fax: +61 2 9838 7817 Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code. CHEMWATCH HAZARD RATINGS Flammability Toxicity Body Contact Reactivity Chronic SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4 RISK SAFETY Harmful to aquatic organisms. • Do not breathe gas/fumes/vapour/spray. Cumulative effects may result • Avoid contact with skin. following exposure*. May produce discomfort of the • Avoid contact with eyes. eyes*. Limited evidence of a • Wear eye/face protection. carcinogenic effect*. * (limited evidence). • In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre. continued...

Transcript of Ardex Grout Booster - Artisan Stone · BRMA-TWA: 0.25 mg/m3 as cyclohexane solubles [BRMA Code of...

Page 1: Ardex Grout Booster - Artisan Stone · BRMA-TWA: 0.25 mg/m3 as cyclohexane solubles [BRMA Code of Practice] Rubber fume isa complex and indeterminate mixture of substances and isdefined

Ardex Grout Booster

Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 3-May-2013 CHEMWATCH 7516-96A317LP Version No:4.1.1.1

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Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMEArdex Grout Booster

SYNONYMS"grout additive"

PRODUCT USEAdditive for grout mixes.

SUPPLIERCompany: Ardex Australia Pty LtdAddress:20 Powers RoadSeven HillsNSW, 2147AustraliaTelephone: 1800 224 070Emergency Tel:1800 224 070 (Mon- Fri, 9am- 5pm)Fax: +61 2 9838 7817

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURENON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

CHEMWATCH HAZARD RATINGS

Flammability Toxicity

Body Contact Reactivity

Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

RISK SAFETY■ Harmful to aquatic organisms. • Do not breathe gas/fumes/vapour/spray.■ Cumulative effects may result • Avoid contact with skin.following exposure*.■ May produce discomfort of the • Avoid contact with eyes.eyes*.■ Limited evidence of a • Wear eye/face protection.carcinogenic effect*.* (limited evidence). • In case of contact with eyes, rinse with plenty of water

and contact Doctor or Poisons Information Centre.

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Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 3-May-2013 CHEMWATCH 7516-96A317LP Version No:4.1.1.1

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Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %styrene/ butadiene copolymer 9003-55-8 10-30ammonium hydroxide 1336-21-6 <0.5biocide <0.2additives, unregulated <0.2water 7732-18-5 balanceNOTE: Manufacturer has supplied full ingredientinformation to allow CHEMWATCH assessment

Section 4 - FIRST AID MEASURES

SWALLOWED■ Rinse mouth out with plenty of water.• For advice, contact a Poisons Information Centre or a doctor.• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.• Observe the patient carefully.• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious• Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.• Seek medical advice.

EYE■ If this product comes in contact with the eyes:• Wash out immediately with fresh running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.• Seek medical attention without delay; if pain persists or recurs seek medical attention.• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN■ If skin contact occurs:• Immediately remove all contaminated clothing, including footwear.• Flush skin and hair with running water (and soap if available).• Seek medical attention in event of irritation.

INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Lay patient down. Keep warm and rested.• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.• Transport to hospital, or doctor.

NOTES TO PHYSICIANTreat symptomatically.

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Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 3-May-2013 CHEMWATCH 7516-96A317LP Version No:4.1.1.1

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Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA• Water spray or fog.• Foam.• Dry chemical powder.• BCF (where regulations permit).• Carbon dioxide.

FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves in the event of a fire.• Prevent, by any means available, spillage from entering drains or water courses.• Use fire fighting procedures suitable for surrounding area.• DO NOT approach containers suspected to be hot.• Cool fire exposed containers with water spray from a protected location.• If safe to do so, remove containers from path of fire.• Equipment should be thoroughly decontaminated after use.

FIRE/EXPLOSION HAZARD• The material is not readily combustible under normal conditions.• However, it will break down under fire conditions and the organic component may burn.• Not considered to be a significant fire risk.• Heat may cause expansion or decomposition with violent rupture of containers.• Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).• May emit acrid smoke.

FIRE INCOMPATIBILITY• Avoid reaction with oxidising agents.

HAZCHEMNone

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact with the substance, by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.• Wipe up.• Place in a suitable, labelled container for waste disposal.

MAJOR SPILLSMinor hazard.• Clear area of personnel.• Alert Fire Brigade and tell them location and nature of hazard.• Control personal contact with the substance, by using protective equipment as required.• Prevent spillage from entering drains or water ways.• Contain spill with sand, earth or vermiculite.• Collect recoverable product into labelled containers for recycling.

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Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 3-May-2013 CHEMWATCH 7516-96A317LP Version No:4.1.1.1

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• Absorb remaining product with sand, earth or vermiculite and place in appropriate containers for disposal.• Wash area and prevent runoff into drains or waterways.• If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING• Limit all unnecessary personal contact.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Avoid contact with incompatible materials.• When handling, DO NOT eat, drink or smoke.• Keep containers securely sealed when not in use.• Avoid physical damage to containers.• Always wash hands with soap and water after handling.• Work clothes should be laundered separately.• Use good occupational work practice.• Observe manufacturer's storage and handling recommendations contained within this MSDS.• Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.

SUITABLE CONTAINER• Lined metal can, lined metal pail/ can.• Plastic pail.• Polyliner drum.• Packing as recommended by manufacturer.• Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITYAvoid storage with oxidisers.

STORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.• Store in a cool, dry, well-ventilated area.• Store away from incompatible materials and foodstuff containers.• Protect containers against physical damage and check regularly for leaks.• Observe manufacturer's storage and handling recommendations contained within this MSDS._____________________________________________________

SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS

+ + + + X +_____________________________________________________+: May be stored togetherO: May be stored together with specific preventionsX: Must not be stored together

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Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 3-May-2013 CHEMWATCH 7516-96A317LP Version No:4.1.1.1

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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLSSource Material TWA TWA STEL STEL Peak Peak TWA Notes

ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC__________ __________ ______ ______ ______ ______ ______ ______ ______ ______Australia ammonium 25 17 35 24 AmericanExposure hydroxide Conference ofStandards (Ammonia) Governmental

IndustrialHygienists(ACGIH)4, 5 isthedocumentationsource

The following materials had no OELs on our records• styrene/ butadiene copolymer: CAS:9003- 55- 8• water: CAS:7732- 18- 5

EMERGENCY EXPOSURE LIMITSMaterial Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)ammonium hydroxide 430 300

MATERIAL DATAARDEX GROUT BOOSTER:

None assigned. Refer to individual constituents.

STYRENE/ BUTADIENE COPOLYMER:It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all

substances for which there is evidence of health effects at airborne concentrations encountered in theworkplace.

At this time no TLV has been established, even though this material may produce adverse health effects (asevidenced in animal experiments or clinical experience). Airborne concentrations must be maintained as low asis practically possible and occupational exposure must be kept to a minimum.

NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOTapply.

Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose orthroat. Historically occupational exposure standards for these irritants have been based on observation ofworkers' responses to various airborne concentrations. Present day expectations require that nearly everyindividual should be protected against even minor sensory irritation and exposure standards are establishedusing uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach,typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals,has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposurelimits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combineto warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system based onintensive odour, local irritation, and elimination half-life. However this system is being replaced to beconsistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); thisis more closely allied to that of the USA.

OSHA (USA) concluded that exposure to sensory irritants can:

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• cause inflammation• cause increased susceptibility to other irritants and infectious agents• lead to permanent injury or dysfunction• permit greater absorption of hazardous substances and• acclimate the worker to the irritant warning properties of these substances thus increasing the risk of

overexposure.TLV TWA: 0.001 mg/m3 (as total proteins) Inhalable fraction skin sensitiser

as rubber processing fume:MEL-TWA: 0.6 mg/m3 as cyclohexane solubles [HSE, UK]

BRMA-TWA: 0.25 mg/m3 as cyclohexane solubles [BRMA Code of Practice]Rubber fume is a complex and indeterminate mixture of substances and is defined as "fume evolved in the

mixing, milling and blending of natural rubber and synthetic polymers combined with chemicals, and in theprocesses which convert the resultant blend into finished products or parts thereof, and including anyinspection procedures where fume continues to be evolved".

"Fume" generally describes solid particles generated by chemical reactions, or by condensation from thegaseous state, usually after volatilisation from melted substances, and often accompanied by a chemicalreaction such as oxidation or thermal breakdown.

Several chemical agents may occur in rubber fume which are experimental or animal carcinogens, however,given the number of chemicals used or formed during rubber making, difficulties arise in attributing aparticular effect to a given exposure.

Stomach cancer has been associated with work in jobs early in the production line; lung and loweroesophagus cancer with all work processes; and lymphomas with jobs where co-exposure to solvents occurs.Other cancers have also been reported with liver tumours appearing as a secondary phenomenon. No no-effectlevels have been determined.

Two studies showed no excess of bladder cancer in workers entering the industry after 1950: the excessrisk before that date is thought to result from exposure to residual beta-naphthylamines previously used asanti-oxidants.

as rubber process dust:MEL-TWA: 6 mg/m3 [HSE, UK]Rubber process dust is a complex, variable mixture of particulates defined as "dust arising in the stages

of rubber manufacture where ingredients are handled, weighed, added to or mixed with natural or syntheticelastomers. It does not include dusts arising from the abrasion of cured rubber but occurs during thepreparation of compounds of either synthetic or natural rubber.

There is some evidence that occupational exposure to rubber dusts produces an excess incidence of stomachcancer. HSE data concluded that there was a small but significant excess of stomach cancer associated withthe initial processes in rubber manufacture. Stomach cancer shows a marked social class gradient, which maylead to an over-estimation of the risk.

One report from the USA stated that exposure in rubber processing areas produces pulmonary disease butthis has not been supported by UK epidemiology nor reports from the industry.

No no-effect level has been determined. The MEL was considered appropriate because it was felt reasonablypractical for industry to comply with this value.

AMMONIUM HYDROXIDE:for exposure to ammonia gas/ vapours:Odour Threshold Value: Variously reported as 0.019 ppm and 55 ppm; AIHA Value 16.7 ppm (detection)NOTE: Detector tubes for ammonia, measuring in excess of 1 ppm, are commercially available.The TLV-TWA is thought to be protective against irritation of the eyes and respiratory tract and minimise

discomfort among workers that are not inured to its effects and systemic damage. Acclimatised persons areable to tolerate prolonged exposures of up to 100 ppm without symptoms. Marked irritation has been seen inpersons exposed to ammonia concentrations between 50 and 100 ppm only when the exposures involved suddenconcentration peaks which do not permit short-term acclimatisation. The detoxification capacity of the liveris significant since the amount of ammonia formed endogenously in the intestines markedly exceeds that fromexternal sources.

Human exposure effects, at vapour concentrations of about:

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Concentration Possible Effects(ppm)5 minimal irritation9- 50 nasal dryness, olfactory fatigue and moderate irritation125- 137 definite nose, throat and chest irritation140 slight eye irritation150 laryngeal spasm500 30 minute exposures may produce cyclic hypernea, increased blood pressure and

pulse rate, and upper respiratory tract irritation which may persist for 24 hours700 immediate eye irritation1, 500- 10, dyspnea, convulsive coughing, chest pain, respiratory spasm, pink frothy sputum,000 rapid asphyxia and delayed pulmonary oedema which may be fatal. Other effects

include runny nose, swelling of the lips, restlessness, headache, salivation,nausea, vomiting, glottal oedema, pharyngitis, tracheitis, and speechdifficulties. Bronchopneumonia, asphyxiation due to spasms, inflammation, andoedema of the larynx, may be fatal. Residual effects include hoarseness,productive cough, and decreased respiratory function

>2, 500 severe eye irritation, with swelling of the eyelids, lachrymation, blepharospasm,palpebral oedema, increased intraocular pressure, oval semi- dilated, fixedpupils, corneal ulceration (often severe) and temporary blindness. Depending onduration of exposure, there may be destruction of the epithelium, corneal andlenticular opacification, and iritis accompanied by hypopyon or haemorrhage andpossible loss of pigment from the posterior layer of the iris. Less severe damageis often resolved. In the case of severe damage, symptoms may be delayed; latecomplications including persistent oedema, vascularisation and corneal scarring,permanent opacity, acute angle glaucoma, staphyloma, cataract, and atrophy of theretina, iris, and symblepharon. Long- term exposure to sub- acute concentrationsor single exposures to high concentrations may produce chronic airwaydysfunction, alveolar disease, bronchiolitis, bronchiectasis, emphysema andanxiety neuroses

Odour Safety Factor(OSF)OSF=3.8 (AMMONIA).

WATER:No exposure limits set by NOHSC or ACGIH.

PERSONAL PROTECTION

EYE• Safety glasses with side shields; or as required,• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A

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Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 3-May-2013 CHEMWATCH 7516-96A317LP Version No:4.1.1.1

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written policy document, describing the wearing of lens or restrictions on use, should be created for eachworkplace or task. This should include a review of lens absorption and adsorption for the class ofchemicals in use and an account of injury experience. Medical and first-aid personnel should be trained intheir removal and suitable equipment should be readily available. In the event of chemical exposure, begineye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at thefirst signs of eye redness or irritation - lens should be removed in a clean environment only after workershave washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or nationalequivalent].

HANDS/FEET■ Wear chemical protective gloves, e.g. PVC.Wear safety footwear.

OTHER• Overalls.• Eyewash unit.

RESPIRATOR•Type K Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or nationalequivalent)

The local concentration of material, quantity and conditions of use determine the type of personal protectiveequipment required. For further information consult site specific CHEMWATCH data (if available), or yourOccupational Health and Safety Advisor.

ENGINEERING CONTROLS■ General exhaust is adequate under normal operating conditions.If inhalation risk of overexposure exists, wear SAA approved organic-vapour respirator.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCEMilky white liquid with a slight odour; disperses in water.

PHYSICAL PROPERTIESLiquid.Does not mix with water.

State Liquid Molecular Weight Not applicableMelting Range (°C) Not available Viscosity Not availableBoiling Range (°C) 100 Solubility in water (g/L) ImmiscibleFlash Point (°C) Not applicable pH (1% solution) 9- 11 dispersionDecomposition Temp (°C) Not available pH (as supplied) Not applicableAutoignition Temp (°C) Not applicable Vapour Pressure (kPa) Not availableUpper Explosive Limit (%) Not applicable Specific Gravity (water=1) Not availableLower Explosive Limit (%) Not applicable Relative Vapour Density Not available

(air=1)Volatile Component (%vol) 73- 77 approx Evaporation Rate Not available

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Section 10 - STABILITY AND REACTIVITY

CONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED■ Considered an unlikely route of entry in commercial/industrial environments.The liquid is discomforting to the gastro-intestinal tract.Ingestion may result in nausea, abdominal irritation, pain and vomiting.Ingestion of large quantities may coagulate and block the gastrointestinaltract. [ABA]

EYE■ The liquid may produce eye discomfort causing smarting, pain and redness.The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolongedexposure to irritants may produce conjunctivitis.

SKIN■ The liquid is discomforting to the skin and is capable of causing skin reactions which may lead todermatitis.

INHALED■ The vapour/mist is discomforting to the upper respiratory tract.Inhalation hazard is increased at higher temperatures.

CHRONIC HEALTH EFFECTS■ Principal routes of exposure are by accidental skin and eye contact and by inhalation of vapours especiallyat higher temperatures.Prolonged or repeated skin contact may cause drying with cracking, irritation and possible dermatitisfollowing.As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in workplace atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice.

TOXICITY AND IRRITATION■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.

ARDEX GROUT BOOSTER:■ Not available. Refer to individual constituents.

STYRENE/ BUTADIENE COPOLYMER:

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TOXICITY IRRITATIONEye (rabbit) 500:mg/24h -Eye :Mild

■ The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated orprolonged exposure to irritants may produce conjunctivitis.The substance is classified by IARC as Group 3:NOT classifiable as to its carcinogenicity to humans.Evidence of carcinogenicity may be inadequate or limited in animal testing.

AMMONIUM HYDROXIDE:TOXICITY IRRITATIONOral (rat) LD50:350 mg/kg Eye (rabbit):0.25 mg SEVEREOral (human) LDLo:43 mg/kg Eye (rabbit):1 mg/30s SEVEREInhalation (human) LCLo:5000 ppm/5mInhalation (human) TCLo:20 ppmInhalation (rat) LC50:2000 ppm/4hUnreported (man) LDLo:132 mg/kg■ The material may produce severe irritation to the eye causing pronounced inflammation. Repeated orprolonged exposure to irritants may produce conjunctivitis.Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may bedue to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occurfollowing exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADSinclude the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset ofpersistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. Areversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivityon methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia,have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritatinginhalation is an infrequent disorder with rates related to the concentration of and duration of exposure tothe irritating substance. Industrial bronchitis, on the other hand, is a disorder that occurs as result ofexposure due to high concentrations of irritating substance (often particulate in nature) and is completelyreversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus production.

WATER:■ No significant acute toxicological data identified in literature search.

CARCINOGENstyrene/ butadiene International Group 3 Not classifiablecopolymer Agency for as to its

Research on Cancer carcinogenicity(IARC) - Agents to humansReviewed by theIARC Monographs

SKINstyrene/ butadiene GESAMP/EHS Composite D1: skin 0copolymer List - GESAMP Hazard irritation/corrosion

Profilesammonium hydroxide GESAMP/EHS Composite D1: skin 3

List - GESAMP Hazard irritation/corrosionProfiles

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Section 12 - ECOLOGICAL INFORMATION

AMMONIUM HYDROXIDE:STYRENE/ BUTADIENE COPOLYMER:DO NOT discharge into sewer or waterways.

AMMONIUM HYDROXIDE:Marine Pollutant YesFish LC50 (96hr.) (mg/l): 8.2Very toxic to aquatic organisms.Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high watermark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.For Ammonia:Atmospheric Fate: Ammonia reacts rapidly with available acids (mainly sulfuric, nitric, and sometimeshydrochloric acid) to form the corresponding salts. Ammonia is persistent in the air.Aquatic Fate: Biodegrades rapidly to nitrate, producing a high oxygen demand. Non-persistent in water (half-life 2 days).Ecotoxicity: Moderately toxic to fish under normal temperature and pH conditions and harmful to aquatic lifeat low concentrations. Does not concentrate in food chain.Prevent, by any means available, spillage from entering drains or water courses.

EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation Mobility

Water/Soilstyrene/ butadiene copolymer No Data No Data No Data No Data

Available Available Available Availableammonium hydroxide LOW No Data LOW HIGH

Available

Section 13 - DISPOSAL CONSIDERATIONS

• Consult manufacturer for recycling options and recycle where possible .• Consult State Land Waste Management Authority for disposal.• Incinerate residue at an approved site.• Recycle containers if possible, or dispose of in an authorised landfill.

Section 14 - TRANSPORTATION INFORMATION

HAZCHEM: None (ADG7)

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, IATA, IMDG

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Section 15 - REGULATORY INFORMATION

POISONS SCHEDULENone

REGULATIONS

Regulations for ingredients

styrene/ butadiene copolymer (CAS: 9003-55-8) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)", "FisherTransport Information", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "International Air Transport Association (IATA) Dangerous Goods Regulations", "International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo Aircraft", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – United Kingdom", "Sigma-AldrichTransport Information"

ammonium hydroxide (CAS: 1336-21-6) is found on the following regulatory lists;"Acros Transport Information", "Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (AQUA/1 to 6 - inorganic chemicals)", "Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - inorganic chemicals)", "Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm - Domestic water supply quality", "Australia -Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm (Aquatic habitat)", "Australia - Queensland Work Health and Safety Regulation - Hazardous chemicals at major hazard facilities (and their threshold quantity)", "Australia - Tasmania - Work Health and Safety Regulations 2012 - Hazardous Chemicals at Major Hazard Facilities (and their Threshold Quantity) - Table 15.1", "Australia - Victoria Drugs, Poisons and Controlled Substances (Precursor Chemicals) Regs 2007 - Schedule 1 - Precursor Chemicals and Quantities", "Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2", "Australia Council of Australian Governments (COAG) Chemicals of Security Concern", "Australia Drinking Water Guideline Values For Physical and Chemical Characteristics", "Australia Exposure Standards", "Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6", "Australia Work Health and Safety Regulations 2011 - Hazardous chemicals at major hazard facilities and their threshold quantity", "CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk", "International Council of Chemical Associations (ICCA) - High Production Volume List", "International Fragrance Association (IFRA) Survey: Transparency List", "International Numbering System for Food Additives", "IOFI Global Reference List of Chemically Defined Substances", "OECD List of High Production Volume (HPV) Chemicals", "Sigma-AldrichTransport Information", "WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not been established"

water (CAS: 7732-18-5) is found on the following regulatory lists;"Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)",

continued...

Page 13: Ardex Grout Booster - Artisan Stone · BRMA-TWA: 0.25 mg/m3 as cyclohexane solubles [BRMA Code of Practice] Rubber fume isa complex and indeterminate mixture of substances and isdefined

Ardex Grout Booster

Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 3-May-2013 CHEMWATCH 7516-96A317LP Version No:4.1.1.1

Page 13 of 13Section 15 - REGULATORY INFORMATION

"IMO IBC Code Chapter 18: List of products to which the Code does not apply", "International Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – Norway", "Sigma-AldrichTransport Information"

No data for Ardex Grout Booster (CW: 7516-96)

Section 16 - OTHER INFORMATION

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 3-May-2013Print Date: 9-Jul-2013

This is the end of the MSDS.