ANNEX 5 Resolution MEPC 27(23) CATEGORIZATION OF ......ANNEX 5 Resolution MEPC 27(23) CATEGORIZATION...
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ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
)
ANNEX 5
Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
THE MARINE ENVIRONMENT PROTECTION COMMITTEE,
MEPC 23/22
RECALLING resolutions MEPC 16(22) and 17(22) by which the Committee
adopted amendments to Annex II of HARPOL 73/78 and decided that the Parties to
MARPOL 73/78 shall be bound by the provisions of Anne'x II of MARPOL ' 73/78 as
amended as from 6 April 1987,
NOTING regulations 3 and 4 of Annex II and its appendices II and III by
which liquid substances are categorized according to the environmental hazards
they pose upon release into the sea and that under regulation 13 chemical
tankers carrying noxious liquid substances of category A, B or C must comply
with the requirements of the International Code for the Construction and
Equipment of Ships Carrying Dangerous Chemicals in Bulk (IBe Code) or the Code
for the Construction and Equipment of Ships Carrying Dangerous Chemicals in
Bulk (BeH Code),
NOTING ALSO regulation 3(4) which specifies the procedure for
provisionally assessing Bnd categorizing the liquid substances not listed ~n
appendix II or III of Annex II and regulation 5(6) which prohibits the
discharge into the se,a of ballast water, tank washings or other residues or
mixtures containing substances not cBtegorized or provisionally assessed, and
which may have the consequence of requiring additional needs for reception
facilities for the time period before the substance is provisionally assessed,
NOTING FURTHER that under regulation VII/10 of the International
Convention for the Safety of Life at Sea, 1974, as amended (the 1974 SOLAS
Convention), chemical tankers must also comply with the requirements of the
IBC Code,
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ME PC 23/22 ANNEX 5 Page 2
NOTING that the Sub-Committee on Bulk Chemicals in the interest of the
smooth implementation of Annex II has provided provisional assessments and
specified carriage requirements under the Bulk Chemical Codes for a large
number of substances presently not listed in appendices II and III of
Annex II, as set out at Annex I to this resolution,
BEING AWARE that there still remaln many liquid chemicals presently known
to be carried in bulk, such as those listed in Annex 2 to this resolution,
which have neither been included in appendices II and III of Annex II nor
provisionally assessed,
RECOGNIZING the urgent need for assessing the substances listed in
Annex 2 to this resolution. in order to assist Member States in their efforts
to implement the provisions of Annex II and also to avoid a transitionAl need
for shore reception facilities,
HAVING CONSIDERED the recommendations of the Sub-Committee on Bulk
Chemicals made at its sixteenth session,
1. APPROVES, the provisional assessments and the provisional minimum
carriage requirements in the IHe and BCH Codes for liquid substances as set
out in Annex 1 to this resolution, pending the final assessments for these
substances and the formal amendments to appendices II and III to Annex II of
KARPOL 73/78 and to chapter 17 or 18 of the IBC Code and chapte~ VI or VII of
the BCH Code;
2. URGES flag and port States to accept these provisional assessments and
provisional m~n1mum carriage requirements and to apply the requirements of
Annex II of MARPOL 73/78 and the lBC and BCH Codes in accordance with these
provisional assessments and carriage requirements;
3. REQUESTS flag States and port States to provide the Organization with
data on liquid substances listed in Annexes 1 and 2 so that final assessments
and minimum carriage requirements can be developed;
"
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
)
MEPC 23/22 ANNEX 5 Page 3
4. REQUESTS ALSO flag and port States to inform the Organization of any
liquid substances known to be carried in bulk and not listed in Annex 1 or 2,
or in appendices II and III of Annex II of MARPOL 73/78 together with data
necessary for preparing final assessments;
S. INVITES the Sub-Committee on Bulk Chemicals to continue to develop, with
high priority, provisional assessment and provisional minimum carriage
requirements, as necessary. for those substances listed in Annex 2 and
referred to in paragraph 4 above l for the purpose of implementation of
regulation 3(4) of Annex II of MARPOL 73/78;
6. INVITES ALSO the Maritime Safety Committee to approve the provisional
minimum Bulk Chemical Code carriage requirements for the purpose of the 1974
SOLAS Convention.
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
PROVISIONAL POLLUTIO~ CAfEGORY AND HlNlMUM CARRIAGE ItEQU I REME NTS r.STABLISH£:D BY THE SUIl-COHMITI;':E ON BULK CHEMICALS"
1. F.otnes in Cha~tet' 17 of [he IBC Code
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Anthracene oil (coal [Aj P 2 2G Open No Yes 0 No A No No tar fraction)
Butyl benzene~ 270Y lC) P ] 2G Cout o No No R F A No No
Butyl neptyl ketone leI P 3 2G Opeon No Yes 0 No A No No
Calcium bromide/Zinc (AI p 2 2G Open No NF 0 No A No No bromide mixtut'es solution
4-Cnloco-2 Qethyl- LA] P 3 2G Opt:!u No NF 0 No No No No pnenoxyacetin ac~d, dirnetlly lanllne sa 1 c soiutlon
p-nicn.lorohen7.en~ l592 [B] sIp 2 2G Cont. No Yes R T B,D N5 No (molten)
OiphenyloL propane- (11) p 3 2G Open No Yes () N() Il No No
epich Ie rohydr in resins
;)odec.y i a"ll ne fTe [!" a- icj SIP ) 2G Cont.. ~o Yes R T A,D N2 N<.> dec'j iamloe mixture
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Speci.al Requi .emenLs (see Chaprer is)
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ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
-a h c d e f g h i' i H i" I j k 1 III " 0
E(hyl hexyl phthalate [el p 3 2G Open No Yes 0 No A No No
Isobutyl isobutyrate 2528 [8) p 3 2G Cone. No No R F A ho No 15.19.6
Magnesium sulphonate [el p 3 2G Open No Yes 0 No A No No
3 -Met hy lpyrid inc 2313 (B] sip 2 lG Cone. No No C F A.C N4 No 1).2.3, 15.19
Cetyl nitrates (all IS] SIP 3 2G Open No Yes 0 No B No No 15.XX,* 16.6 isomers)
Pine oil 1272 [AI P 3 2G Open No Yes 0 No A No No
Tetradecylben~ene [e] p 3 2G Open No Yes 0 No A No No
Undecy lbenzene Ie) p 3 2G Open No YeS 0 No A No No
* Proposed IDe Code Special Requirement
lS.XX Octyl nitrates, all isomers
lS.XX.l
The carriage temperature of the cargo should be maintained below lOo'e to prevent the occurrence of a self-sustaining exo(h~rrr,ic decomposition reaction.
lS.XX.2
The cargo may not be carried in independent pressure vessels permanently affixed to the vessels deck unless:
.1 the tanka are sufricie~tly insulated from fire; ~nd
.2 ehe vessel has a wa(er deluge syse~ for th~ tanks s~ch that the cargo lemperatllre is maintalned below lOO'C and the temperature rise in the tanks does not eXceed l.S·C/hour for a fire of &50·C (1200'F).
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ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
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Anthracene oiL (coal lAJ P 2 2G Open No St 0 No A 4.14.1 tar fraction)
Butyl benzenes [el p 3 2G Con!:. No SF R F A 4.14.1
Butyl hepeyl ke.tone Ie] p :1 2G Open No SI: 0 No fA
Calcium bromide/Zinc [Aj P 2 2G Open No !it 0 No A 4.14.1 bromide mixtures so lutiol1
4-chlaro-2-mcthyl- tAl P .3 2(; Open No Sc No No No
phenoxyacetic acid t dimethy lamia/!! salt so lilt ion
p-Oichlorobenzene 1592 (11) SiP 2 2(; Cont. No Sc R r B,D 4.12.> (ma lten)
[£11 p 3 3G Ope.n No 51:. 0 No B
resins
Dorlecy l.'l1nille/Tect'&- [C] sjp 3 2G ConI:. No SI: R T A,D 4.12.2
decyla~ine mixture
Et:hyl l1<!xyl pl1t.l1alace [el p l 2G Open No 51: 0 No A
Isobutyl isobutyrate 2528 lsI P 3 2(; Cont. No SP R F A 4.14. t .
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
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~agnesi~ 9ulphonace [el l' 3 2G Open No Sf: 0 No A
3-Methylpyridine 2313 (8] sip 2 2G Coot. No SP C F A,C 4.9.3, 4.12.4, 4.14
Oe tyl nitrates (all [ Bl SIP ) 2G Open No ~t 0 No B 4.XX"" iSOIIIers)
Pine oil 1272 [AI P 3 2G Open No St 0 No A
Tetradecylbeu~ene [el p 3 2G Open No Sc 0 No A
Undecylben~eoe leI P :3 2G Open No St 0 No A
Proposed Bulk Chemical Code Special Requirement
4.XX Oetyl nitrates, all isomers
4.XX.l
The carriage temperature of the cargo should be maintained below lOO·C to prevent the occurrence of a self-sustaining exothermic decomposition reactioo.
4.XX.2
n,e cargo lIIay not be carried in independent pre6sure vessel's permanently affiKed to the vessels deck uoless:
.1 tke tanks are sufficiently insulated from tire; and
.2 the vessel has 8 water deluge system for the tanks such that the cargo tem~er"ture iH maintained below lOO·C and th" temperature rise in the tanks does not exceed 1.S'C/hour for 8 fir~ o{ 650 C (1200·F).
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ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
MEPC 23/22 ~NEX5 Page 8
3. Entries 1n IBC Code Chapter l81/HCH Code Chapter VIr
Product Name Pollution Category
Ammonium hydrogen phosphate
Benzenetricarboxylic acid, trioctyl ester
Calcium carbonate slurry
Coconut oil fatty acid
Oi-n-Hexyl adipate
Dimethyl succinate
Edible oils including;
Babassu
Beechnut
Cocoa butter
Coconut oil, esterefied
Hazelnut
Nutmeg butter
Poppy
Peel oil (oranges and lemons)
Raisin seed
Salad
Soybean
Walnut
Ethylene glycol dibutyl ether
Ethylene, propylene copolymer (in liquid mixtures)
Glyco l triacetate
iso-Heptane
l,6-Hexanediol
Kaolin clay slurry
Kaolin slurry
Methyl acetoacetate
Miscellaneous oils, including;
Lanolin
Neatsfoot
Oiticica
Perilla
Pilchard
Whale
[III]*
[0 ]
[III ]
[0]
[III]
[0 ]
[0]
[0 )
. [III]
(IIIJ
[IIIl
[ III]
[III]
[III]
[0 J
(01
* Substances identified to be included 1n Appendix III of Annex II.
"
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
"
)
Product Name
Nonyl methacrylate monomer
Pslmnut oil fatty acid
Petrolatum
Polyisobutylene
Polypropylene
Potassium chloride
Silica slurry
Tridecane
Waxes
MEPC 23/22 ANNEX 5 Page 9
Pollution Category
[n]
[D)
[D]
[III]
[III]
[III ]
[rn]
[D)
[D 1
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
MEPC 23/22 ~~X5
Page 10
ANNEX 2
SUBSTANCES KNOWN TO BE MOVED IN BULK BUT EVALUATION OF SAFETY OR ENVIRONMENTAL HAZARDS NOT YET COMPLETED
Product Name
Acetyl tributyl citrate
Acrylic copolymer in ethyl acetate aqueous solution
Alkenyl succinate, potassium salt solution
Alkenylsuccinic acid
Alkenylsuccinic anhydride
Alkyl paint resins
Alkyl phosphorous acid ester
Amyl tallate
Aromasol H
Butyl octyl phthalate
C-Streams containing 15% or more Isoprene
Calcium alkyl phenate
Calcium amino nonyl phenolate
Calcium carboxylate
Calcium nitrate/
Magnesium nitrate/
Ammonium nitrate/
Potassium chloride
Mixture solution
Calcium Sulphonate, Calcium carbonate, Hydrocarbon solvents mixture (low oil saci feed)
Clairsol 250
Cumarone
CyclohexBne oxidation product acid water, 50% aqueous solution
Cyclohexanol acetate
1,3 Cyclopentadiene, molten
Pollution Category
"
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
Product Name
DA feed - mixture of benzene and toluene
Dehexanister
Detergent Alkylate
Di-Coctylphenyl)amine
Dibutyl maleate
Diethylene maleate
Dimethyl adipate
N,N Dimethylaniline styrenic solution
Dimethyl glutarate
Dimethyl polysiloxane
Dimethylcyclicsiloxaoe hydrolyzate (70% or less)
2,2-Dimethyloctaooic acid
Dipropylene glycol dibenzoate
Dodecyl mercaptan
Drilling mud
Dutrex 729 HP
Escaids
Ether chloro-cyclopentadiene
Ethyl chlorothioformate
Ethyl hexyl tall ate
2-Ethyl-6 Methyl-N(1-Methyl-2-Methoxyethyl) Aniline (Herbicide)
Ethyleneimine
Eucalyptus oil
Exsol
Exsol heptane
Fatty acid amides
Halpasol
Heartcut alxylate
Heartcut distillates
Heavy alkylate
Herbicide (ClS-H22-N02-Cl)
Hexamethyleoe tetramine solution
Cs Hydrocarbons fraction (Residue from naphtha cracking)
MEPC 23/22 ANNEX 5 Page 11
Pollution Category
B
III
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
MEPC 23/22 ANNEX 5 Page 12
Product Name
2-Hydroxy-4-(Methylithio) Butanol acid
Isodecyldiphenyl phosphate
Isopar GIL
lsoparsffin hydrocarbon oils (IP solvents)
KA-Oil (mix of cyclohexanol and cyclohexanone)
Ketrol
Kononyl Neu
Linevol phthalate
Linevol. synthetic primary fatty alcohol
Liquid isocyanates having boiling points lower than 300°C and flashpoints higher than 61°C, and their solutions
Lube oil additives
Magnesium nonyl phenol sulphide
Methyl b"J.'omide
Methyl butenol
Methyl butynol
Methyl carbonate
Methyl cyclopentadiene dimer
Methyl formal (Dimethyl formal)
MIBK, MEK and Ethyl acetate mixture (ENJ 1013 Exxon)
n-Octyl chloride
Naphthalene sulphonic acid-formaldehyde co-polymer. sodium salt solution
Neodene
Neodol
Niax Polyols
Norpar 12
Octadecenoamide (Oleamide)
Oetyl decyl adipate
Octyl epoxytallate
Oetyl nitrates (mixed)
Pollution Category
B
, ,
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
.,
Product Name
oils:
Croton
Mustard Seed
Tucum
Resin
Resinous petroleum
Soapstock
Spray
Tanner's
Wood
Organic amine 70 (mixture of high molecular weight alcohol amines)
Palatinol Z
Paradynes
Pegasol
Phenethyl cumene
PhosphoBulphized bicyclic terpene
Poly-isopropyl-amino-alanate ~n ethanic solution
Polyalkenyl succinic anhydride amlne
Polyamine, amide mixture
Polystyrene dialkyl maleate
) Polyvinylbenzyl trimethyl ammonium chloride
Prestol l40E
Pyrolocondensate
Pyrolosis gasoline (stream cracked naphtha)
Raffinate
Shellsols - Aliphatic solvent naphtha
Sodium acetate, glycol solutions
Sodium dimethyl naphthalene sulphonate solution
Sodium naphthalene sulphonate solution 40% or less
Sodium sulphonate
MEPC 23/22 ANNEX 5 Page 13
Pollution Category
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
MEPC 23/22 ANNEX 5 Page 14
Sodium-N-Methy1dithiocarbonate solution 33% or less
Softanols (Detergent alcohols)
Solvesso
Somil SH - High boiling point aromatic oils
Sulphur chloride
Synthetic resin, unsaturated hydrocarbons C-20 to C-60 (eTLA polymer-Exxon)
Tallow nitrile
Tergitols
Tetramer D
Texanol
Triethy1ene glycol diethyl butyrate
Triisooctyl trimellitate
Trimethyl benzene. Xylene, para-Ethyl toluene mixture
Trimethyl phosphite
Varano1
Varsol
Vinyl acetate, fumarate copolymer
Vinylcyclohexene
***
"
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986
ANNEX 5 Resolution MEPC 27(23)
CATEGORIZATION OF LIQUID SUBSTANCES adopted on 8 July 1986