According to Regulation (EC) No 1907/2006, Annex II, as ... · Supplier AF INTERNATIONAL. A...

Revision date: 24/05/2016 Revision: 1

SAFETY DATA SHEETAF Hot Desk Kit - 50ml Multi Screen Clean Pump SprayAccording to Regulation (EC) No 1907/2006, Annex II, as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name AF Hot Desk Kit - 50ml Multi Screen Clean Pump Spray

Product number AHDK000_2, ZA

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Cleaning agent.

Uses advised against No specific uses advised against are identified.

1.3. Details of the supplier of the safety data sheet

Supplier AF INTERNATIONAL. A division of HK WENTWORTH LTDASHBY PARKCOALFIELD WAYASHBY de la ZOUCHLEICESTERSHIRE. LE65 1JRUNITED KINGDOM+44 (0) 1530 419600+44 (0) 1530 [email protected]

1.4. Emergency telephone number

Emergency telephone IN CASE OF EMERGENCY CALL:+44 1865 407333 (24hr, Provided by Carechem 24)+353 (0)1 809 2166 (Beaumont Hospital, Republic of Ireland only, 8am-10pm, 7 days a week)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified

Health hazards Not Classified

Environmental hazards Not Classified

2.2. Label elements

Hazard statements EUH208 Contains 1,2-Benzisothiazol-3(2H)-one, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-6](3:1). May produce an allergic reaction.

Precautionary statements P102 Keep out of reach of children.

Detergent labelling Contains BENZISOTHIAZOLINONE, METHYLISOTHIAZOLINONE,METHYLCHLOROISOTHIAZOLINONE AND METHYLISOTHIAZOLINONE

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

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AF Hot Desk Kit - 50ml Multi Screen Clean Pump Spray

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Composition comments None of the ingredients are required to be listed.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information If in doubt, get medical attention promptly. Show this Safety Data Sheet to the medicalpersonnel.

Inhalation No specific recommendations. If throat irritation or coughing persists, proceed as follows.Move affected person to fresh air and keep warm and at rest in a position comfortable forbreathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if anydiscomfort continues.

Ingestion No specific recommendations. If throat irritation or coughing persists, proceed as follows.Rinse mouth. Get medical attention if any discomfort continues.

Skin contact No specific recommendations. Rinse with water. Get medical attention if any discomfortcontinues.

Eye contact Rinse with water. Get medical attention if any discomfort continues.

Protection of first aiders Use protective equipment appropriate for surrounding materials.

4.2. Most important symptoms and effects, both acute and delayed

General information The severity of the symptoms described will vary dependent on the concentration and thelength of exposure.

Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.

Ingestion No specific symptoms known. May cause discomfort if swallowed.

Skin contact No specific symptoms known. May cause discomfort.

Eye contact No specific symptoms known. May be slightly irritating to eyes.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor Treat symptomatically.

Specific treatments No special treatment required.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, drypowder or water fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.

Hazardous combustionproducts

Thermal decomposition or combustion products may include the following substances:Harmful gases or vapours.

5.3. Advice for firefighters

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Protective actions duringfirefighting

Avoid breathing fire gases or vapours. Evacuate area. Cool containers exposed to heat withwater spray and remove them from the fire area if it can be done without risk. Cool containersexposed to flames with water until well after the fire is out. If a leak or spill has not ignited, usewater spray to disperse vapours and protect men stopping the leak.

Special protective equipmentfor firefighters

Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protectiveclothing. Firefighter's clothing conforming to European standard EN469 (including helmets,protective boots and gloves) will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions No specific recommendations. For personal protection, see Section 8.

6.2. Environmental precautions

Environmental precautions Avoid discharge to the aquatic environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Reuse or recycle products wherever possible. Absorb spillage to prevent material damage.Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage.Dispose of contents/container in accordance with national regulations.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Keep out of the reach of children. Read and follow manufacturer's recommendations. Wearprotective clothing as described in Section 8 of this safety data sheet. Keep away from food,drink and animal feeding stuffs. Handle all packages and containers carefully to minimisespills. Keep container tightly sealed when not in use. Avoid the formation of mists. Avoiddischarge to the aquatic environment.

Advice on generaloccupational hygiene

Wash promptly if skin becomes contaminated. Take off contaminated clothing. Washcontaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions No specific recommendations.

Storage class Unspecified storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parametersOccupational exposure limitsEthanol

Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m³WEL = Workplace Exposure Limit

8.2. Exposure controls

Appropriate engineeringcontrols

No specific ventilation requirements.

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Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complyingwith an approved standard should be worn if a risk assessment indicates eye contact ispossible.

Hand protection No specific hand protection recommended.

Other skin and bodyprotection

Appropriate footwear and additional protective clothing complying with an approved standardshould be worn if a risk assessment indicates skin contamination is possible.

Hygiene measures Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product.Wash contaminated clothing before reuse.

Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation isinadequate, suitable respiratory protection must be worn.

Environmental exposurecontrols

Not regarded as dangerous for the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Colourless.

Odour No characteristic odour.

Odour threshold Not available.

pH Not available.

Melting point Not available.

Initial boiling point and range Not available.

Flash point Not available.

Evaporation rate Not available.

Evaporation factor Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability orexplosive limits

Not available.

Other flammability Not available.

Vapour pressure Not available.

Vapour density Not available.

Relative density 0.997

Bulk density Not available.

Solubility(ies) Not available.

Partition coefficient Not available.

Auto-ignition temperature Not available.

Decomposition Temperature Not available.

Viscosity Not available.

Explosive properties Not considered to be explosive.

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Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. Stable under theprescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardousreactions

No potentially hazardous reactions known.

10.4. Conditions to avoid

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials

Materials to avoid No specific material or group of materials is likely to react with the product to produce ahazardous situation.

10.6. Hazardous decomposition products

Hazardous decompositionproducts

Does not decompose when used and stored as recommended. Thermal decomposition orcombustion products may include the following substances: Harmful gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects Not regarded as a health hazard under current legislation.

Acute toxicity - oralNotes (oral LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - dermalNotes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalationNotes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritationAnimal data Based on available data the classification criteria are not met.

Serious eye damage/irritationSerious eye damage/irritation Based on available data the classification criteria are not met.

Respiratory sensitisationRespiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisationSkin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicityGenotoxicity - in vitro Based on available data the classification criteria are not met.

Carcinogenicity

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Carcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity Contains a substance/a group of substances which may cause cancer. IARC Group 1Carcinogenic to humans.

Reproductive toxicityReproductive toxicity - fertility Based on available data the classification criteria are not met.

Reproductive toxicity -development

Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposureSTOT - single exposure Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposureSTOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazardAspiration hazard Based on available data the classification criteria are not met.

General information No specific health hazards known. The severity of the symptoms described will varydependent on the concentration and the length of exposure.

Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.

Ingestion No specific symptoms known. May cause discomfort if swallowed.

Skin contact No specific symptoms known. May cause discomfort.

Eye contact No specific symptoms known. May be slightly irritating to eyes.

Route of exposure Ingestion Inhalation Skin and/or eye contact

Target organs No specific target organs known.

Toxicological information on ingredients.

Ethanol


Acute toxicity - oral

Notes (oral LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritation

Animal data Based on available data the classification criteria are not met.

Serious eye damage/irritation

Serious eyedamage/irritation


Respiratory sensitisation

Respiratory sensitisation Based on available data the classification criteria are not met.

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Skin sensitisation

Skin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicity

Genotoxicity - in vitro Based on available data the classification criteria are not met.

Genotoxicity - in vivo Chromosome aberration: Negative. REACH dossier information. Based on availabledata the classification criteria are not met.

Carcinogenicity


IARC carcinogenicity None of the ingredients are listed or exempt.

Reproductive toxicity

Reproductive toxicity -fertility




Specific target organ toxicity - single exposure

STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard

Aspiration hazard Based on available data the classification criteria are not met.

General information The severity of the symptoms described will vary dependent on the concentrationand the length of exposure.

Inhalation No specific symptoms known.

Ingestion No specific symptoms known.

Skin contact No specific symptoms known.

Eye contact No specific symptoms known.



SECTION 12: Ecological information

Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may havehazardous effects on the environment.

Ecological information on ingredients.

Ethanol

Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spillsmay have hazardous effects on the environment.

12.1. Toxicity

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Toxicity Based on available data the classification criteria are not met.


Ethanol


Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 14200 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquaticinvertebrates

LC₅₀, 48 hours: 5012 mg/l, Ceriodaphnia dubia

Acute toxicity - aquaticplants

EC₅₀, 72 hours: 11.5 mg/l, Chlorella vulgaris

Chronic aquatic toxicity

Chronic toxicity - aquaticinvertebrates

NOEC, 9 days: 9.6 mg/l, Daphnia magna

12.2. Persistence and degradability

Persistence and degradability The degradability of the product is not known.


Ethanol

Persistence anddegradability

The degradability of the product is not known.

Biodegradation Water - Degradation 74%: 10 days

Chemical oxygen demand 1.99 g O₂/g substance

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.



Ethanol


Partition coefficient log Pow: -0.35

12.4. Mobility in soil

Mobility No data available.


Ethanol


Surface tension 24.5 mN/m @ 20°C/68°F

12.5. Results of PBT and vPvB assessmentEcological information on ingredients.

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Ethanol

Results of PBT and vPvBassessment

This substance is not classified as PBT or vPvB according to current EU criteria.

12.6. Other adverse effects

Other adverse effects None known.


Ethanol


SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycleproducts wherever possible. This material and its container must be disposed of in a safeway.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of thelocal Waste Disposal Authority.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods(IMDG, IATA, ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutantNo.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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National regulations Health and Safety at Work etc. Act 1974 (as amended).The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009No. 716).The Carriage of Dangerous Goods and Use of Transportable Pressure EquipmentRegulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].EH40/2005 Workplace exposure limits.

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).Commission Regulation (EU) No 453/2010 of 20 May 2010.Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16December 2008 on classification, labelling and packaging of substances and mixtures (asamended).Dangerous Preparations Directive 1999/45/EC.Dangerous Substances Directive 67/548/EEC.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Training advice Read and follow manufacturer's recommendations.

Issued by Bethan Massey

Revision date 24/05/2016

Revision 1

SDS number 386

Hazard statements in full EUH208 Contains 1,2-Benzisothiazol-3(2H)-one, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-6](3:1). May produce an allergic reaction.

This information relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurateand reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability orcompleteness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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SAFETY DATA SHEETAF Hot Desk Kit - Phone-Clene Sachets

According to Regulation (EC) No 1907/2006, Annex II, as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name AF Hot Desk Kit - Phone-Clene Sachets

Product number AHDK000_1, ZA

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Cleaning agent.

Uses advised against No specific uses advised against are identified.

1.3. Details of the supplier of the safety data sheet

Supplier AF INTERNATIONAL. A division of HK WENTWORTH LTDASHBY PARKCOALFIELD WAYASHBY de la ZOUCHLEICESTERSHIRE. LE65 1JRUNITED KINGDOM+44 (0) 1530 419600+44 (0) 1530 [email protected]

1.4. Emergency telephone number

Emergency telephone IN CASE OF EMERGENCY CALL:+44 1865 407333 (24hr, Provided by Carechem 24)+353 (0)1 809 2166 (Beaumont Hospital, Republic of Ireland only, 8am-10pm, 7 days a week)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified

Health hazards Eye Irrit. 2 - H319

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Warning

Hazard statements EUH208 Contains 1,2-Benzisothiazol-3(2H)-one, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-6](3:1). May produce an allergic reaction.H319 Causes serious eye irritation.

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AF Hot Desk Kit - Phone-Clene Sachets

Precautionary statements P102 Keep out of reach of children.P264 Wash contaminated skin thoroughly after handling.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P337+P313 If eye irritation persists: Get medical advice/ attention.

Detergent labelling < 5% perfumes, Contains D-LIMONENE, BENZISOTHIAZOLINONE,METHYLISOTHIAZOLINONE, METHYLCHLOROISOTHIAZOLINONE ANDMETHYLISOTHIAZOLINONE

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Propan-2-ol 10-30%

CAS number: 67-63-0 EC number: 200-661-7 REACH registration number: 01-2119457558-25-XXXX

ClassificationFlam. Liq. 2 - H225Eye Irrit. 2 - H319STOT SE 3 - H336

Benzyl-C12-14-alkyldimethylammonium chlorides <1%

CAS number: 68424-85-1 EC number: 939-350-2 REACH registration number: 01-2119970550-39-0000

M factor (Acute) = 10 M factor (Chronic) = 1

ClassificationAcute Tox. 4 - H302Skin Corr. 1B - H314Eye Dam. 1 - H318Aquatic Acute 1 - H400Aquatic Chronic 1 - H410

1,2-Benzisothiazol-3(2H)-one <1%

CAS number: 2634-33-5 EC number: 220-120-9

M factor (Acute) = 1

ClassificationAcute Tox. 4 - H302Skin Irrit. 2 - H315Eye Dam. 1 - H318Skin Sens. 1 - H317Aquatic Acute 1 - H400

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Ethanol <1%

CAS number: 64-17-5 EC number: 200-578-6 REACH registration number: 01-2119457610-43-XXXX

ClassificationFlam. Liq. 2 - H225

Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [ECno. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no.220-239-6] (3:1)

<1%

CAS number: 55965-84-9


ClassificationAcute Tox. 3 - H301Acute Tox. 3 - H311Acute Tox. 3 - H331Skin Corr. 1B - H314Eye Dam. 1 - H318Skin Sens. 1 - H317Aquatic Acute 1 - H400Aquatic Chronic 1 - H410

2,6-Di-tert-butyl-p-cresol <1%

CAS number: 128-37-0 EC number: 204-881-4


ClassificationAquatic Acute 1 - H400Aquatic Chronic 1 - H410

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medicalpersonnel.

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable forbreathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if symptomsare severe or persist.

Ingestion Rinse mouth thoroughly with water. Get medical advice/attention if you feel unwell. Do notinduce vomiting unless under the direction of medical personnel.

Skin contact Rinse with water.

Eye contact Rinse with water. Do not rub eye. Remove any contact lenses and open eyelids wide apart.Get medical attention if any discomfort continues.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue.

4.2. Most important symptoms and effects, both acute and delayed

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Eye contact Irritating to eyes.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, drypowder or water fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.

Hazardous combustionproducts

Thermal decomposition or combustion products may include the following substances:Harmful gases or vapours.

5.3. Advice for firefighters

Protective actions duringfirefighting

Avoid breathing fire gases or vapours. Evacuate area. Cool containers exposed to heat withwater spray and remove them from the fire area if it can be done without risk. Cool containersexposed to flames with water until well after the fire is out. If a leak or spill has not ignited, usewater spray to disperse vapours and protect men stopping the leak. Control run-off water bycontaining and keeping it out of sewers and watercourses. If risk of water pollution occurs,notify appropriate authorities.

Special protective equipmentfor firefighters

Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protectiveclothing. Firefighter's clothing conforming to European standard EN469 (including helmets,protective boots and gloves) will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall betaken without appropriate training or involving any personal risk.

6.2. Environmental precautions

Environmental precautions Avoid discharge to the aquatic environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spillsimmediately and dispose of waste safely. If the product is soluble in water, dilute the spillagewith water and mop it up. Alternatively, or if it is not water-soluble, absorb the spillage with aninert, dry material and place it in a suitable waste disposal container. The contaminatedabsorbent may pose the same hazard as the spilled material. Label the containers containingwaste and contaminated materials and remove from the area as soon as possible. Flushcontaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Forwaste disposal, see Section 13.

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6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on healthhazards. See Section 12 for additional information on ecological hazards. For waste disposal,see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Keep out of the reach of children. Read and follow manufacturer's recommendations. Wearprotective clothing as described in Section 8 of this safety data sheet. Keep away from food,drink and animal feeding stuffs. Handle all packages and containers carefully to minimisespills. Keep container tightly sealed when not in use. Avoid the formation of mists. Avoiddischarge to the aquatic environment.

Advice on generaloccupational hygiene

Wash promptly if skin becomes contaminated. Take off contaminated clothing. Washcontaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep out of the reach of children. Keep away from food, drink and animal feeding stuffs. Keeponly in the original container. Keep container tightly closed, in a cool, well ventilated place.Keep containers upright. Protect containers from damage.

Storage class Chemical storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parametersOccupational exposure limitsPropan-2-ol

Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³

Ethanol

Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m³

2,6-Di-tert-butyl-p-cresol

Long-term exposure limit (8-hour TWA): WEL 10 mg/m³WEL = Workplace Exposure Limit

8.2. Exposure controls

Protective equipment

Appropriate engineeringcontrols

Provide adequate ventilation.

Eye/face protection Avoid contact with eyes. Large Spillages: Eyewear complying with an approved standardshould be worn if a risk assessment indicates eye contact is possible.

Hand protection No specific hand protection recommended.

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Other skin and bodyprotection

Appropriate footwear and additional protective clothing complying with an approved standardshould be worn if a risk assessment indicates skin contamination is possible.

Hygiene measures Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product.Wash contaminated clothing before reuse.

Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation isinadequate, suitable respiratory protection must be worn.

Environmental exposurecontrols

Keep container tightly sealed when not in use. Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid-impregnated wipe.

Colour Colourless.

Odour Characteristic.

Odour threshold Not available.

pH pH (concentrated solution): 5-6

Melting point Not available.

Initial boiling point and range Not available.

Flash point Not available.

Evaporation rate Not available.

Evaporation factor Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability orexplosive limits

Not available.

Other flammability Not available.

Vapour pressure Not available.

Vapour density Not available.

Relative density Not available.

Bulk density Not available.

Solubility(ies) Not available.


Auto-ignition temperature Not available.

Decomposition Temperature Not available.

Viscosity Not available.

Explosive properties Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

SECTION 10: Stability and reactivity

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10.1. Reactivity

Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. Stable under theprescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardousreactions

No potentially hazardous reactions known.

10.4. Conditions to avoid

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials

Materials to avoid No specific material or group of materials is likely to react with the product to produce ahazardous situation.

10.6. Hazardous decomposition products

Hazardous decompositionproducts

Does not decompose when used and stored as recommended. Thermal decomposition orcombustion products may include the following substances: Harmful gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effectsAcute toxicity - oralNotes (oral LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - dermalNotes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalationNotes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritationAnimal data Based on available data the classification criteria are not met.

Serious eye damage/irritationSerious eye damage/irritation Causes serious eye irritation.

Respiratory sensitisationRespiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisationSkin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicityGenotoxicity - in vitro Based on available data the classification criteria are not met.

CarcinogenicityCarcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity Contains a substance/a group of substances which may cause cancer. IARC Group 1Carcinogenic to humans.

Reproductive toxicityReproductive toxicity - fertility Based on available data the classification criteria are not met.

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Specific target organ toxicity - single exposureSTOT - single exposure Not classified as a specific target organ toxicant after a single exposure.

Target organs Central nervous system

Specific target organ toxicity - repeated exposureSTOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazardAspiration hazard Based on available data the classification criteria are not met.








Toxicological information on ingredients.

Propan-2-ol











Causes serious eye irritation.



Skin sensitisation




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Carcinogenicity









STOT - single exposure STOT SE 3 - H336 May cause drowsiness or dizziness.




Aspiration hazard



Inhalation A single exposure may cause the following adverse effects: Headache. Nausea,vomiting. Central nervous system depression. Drowsiness, dizziness,disorientation, vertigo. Narcotic effect.






Benzyl-C12-14-alkyldimethylammonium chlorides


Acute toxicity oral (LD₅₀mg/kg)

795.0

Species Rat

Notes (oral LD₅₀) Acute Tox. 4 - H302 Harmful if swallowed.

ATE oral (mg/kg) 795.0




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Animal data Skin Corr. 1B - H314 Causes severe burns.



Eye Dam. 1 - H318 Corrosive to skin. Corrosivity to eyes is assumed.



Skin sensitisation




Carcinogenicity












Aspiration hazard

Aspiration hazard Not relevant. Solid.


Inhalation Corrosive to the respiratory tract. Symptoms following overexposure may includethe following: Severe irritation of nose and throat.

Ingestion May cause chemical burns in mouth, oesophagus and stomach. Symptomsfollowing overexposure may include the following: Severe stomach pain. Nausea,vomiting.

Skin contact Causes severe burns. Symptoms following overexposure may include the following:Pain or irritation. Redness. Blistering may occur.

Eye contact Causes serious eye damage. Symptoms following overexposure may include thefollowing: Pain. Profuse watering of the eyes. Redness.


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d-Limonene








Animal data Irritating.






Skin sensitisation

Skin sensitisation May cause skin sensitisation or allergic reactions in sensitive individuals.



Genotoxicity - in vivo DNA damage and/or repair: Negative. REACH dossier information. Based onavailable data the classification criteria are not met.

Carcinogenicity












Aspiration hazard



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Ingestion May cause sensitisation or allergic reactions in sensitive individuals. May causeirritation.

Skin contact May cause skin sensitisation or allergic reactions in sensitive individuals. Redness.Irritating to skin.




Medical considerations Skin disorders and allergies.

1,2-Benzisothiazol-3(2H)-one


Notes (oral LD₅₀) Acute Tox. 4 - H302 Harmful if swallowed.







Skin corrosion/irritation Irritating to skin.




Eye Dam. 1 - H318 Causes serious eye damage.



Skin sensitisation




Carcinogenicity








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Aspiration hazard




Ingestion May cause sensitisation or allergic reactions in sensitive individuals. May causediscomfort if swallowed. Stomach pain. Nausea, vomiting.






Pin-2(3)-ene









Human skin model test Cell Viability 39.6% 15 minutes REACH dossier information. Irritating.






Skin sensitisation




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Carcinogenicity












Aspiration hazard

Aspiration hazard Asp. Tox. 1 - H304 May be fatal if swallowed and enters airways. Pneumonia maybe the result if vomited material containing solvents reaches the lungs.



Ingestion May cause sensitisation or allergic reactions in sensitive individuals. May causeirritation. Aspiration hazard if swallowed. Entry into the lungs following ingestion orvomiting may cause chemical pneumonitis.






Citral








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Skin sensitisation





Carcinogenicity












Aspiration hazard




Ingestion May cause sensitisation or allergic reactions in sensitive individuals. May causeirritation.






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Ethanol















Skin sensitisation





Carcinogenicity












Aspiration hazard



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Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one[EC no. 220-239-6] (3:1)


Notes (oral LD₅₀) Acute Tox. 3 - H301 Toxic if swallowed.



Notes (dermal LD₅₀) Acute Tox. 3 - H311 Toxic in contact with skin.

ATE dermal (mg/kg) 300.0


Acute toxicity inhalation(LC₅₀ dust/mist mg/l)

0.33

Notes (inhalation LC₅₀) Acute Tox. 3 - H331 Toxic if inhaled.

ATE inhalation(dusts/mists mg/l)

0.33


Skin corrosion/irritation Corrosive to skin. Causes burns.

Animal data Skin Corr. 1B - H314 Causes severe burns.



Eye Dam. 1 - H318 Corrosive to skin. Corrosivity to eyes is assumed.



Skin sensitisation




Genotoxicity - in vivo This substance has no evidence of mutagenic properties.

Carcinogenicity




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Aspiration hazard



Inhalation Corrosive to the respiratory tract. Symptoms following overexposure may includethe following: Severe irritation of nose and throat.

Ingestion May cause sensitisation or allergic reactions in sensitive individuals. May causechemical burns in mouth, oesophagus and stomach. Symptoms followingoverexposure may include the following: Severe stomach pain. Nausea, vomiting.

Skin contact May cause skin sensitisation or allergic reactions in sensitive individuals. Causessevere burns. Symptoms following overexposure may include the following: Pain orirritation. Redness. Blistering may occur.





Pin-2(10)-ene









Human skin model test Cell Viability 38.5% 15 minutes REACH dossier information. Irritating.




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Skin sensitisation





Carcinogenicity












Aspiration hazard

Aspiration hazard Asp. Tox. 1 - H304 May be fatal if swallowed and enters airways. Pneumonia maybe the result if vomited material containing solvents reaches the lungs.



Ingestion May cause sensitisation or allergic reactions in sensitive individuals. May causeirritation. Aspiration hazard if swallowed. Entry into the lungs following ingestion orvomiting may cause chemical pneumonitis.








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Skin sensitisation





Carcinogenicity












Aspiration hazard

Aspiration hazard Not relevant. Solid.




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Skin contact Prolonged contact may cause dryness of the skin.




SECTION 12: Ecological information

Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may havehazardous effects on the environment.


Propan-2-ol


Pin-2(3)-ene


Citral


Ethanol


12.1. Toxicity



Propan-2-ol





LC₅₀, 24 hours: >10000 mg/l, Daphnia magna


EC₅₀, 7 days: 1800 mg/l, Scenedesmus quadricauda


Toxicity Aquatic Acute 1 - H400 Very toxic to aquatic life. Aquatic Chronic 1 - H410 Verytoxic to aquatic life with long lasting effects.


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LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1

M factor (Acute) 10

Acute toxicity - fish LC₅₀, 96 hours: 0.85 mg/l, Oncorhynchus mykiss (Rainbow trout)


LC₅₀, 48 hours: 0.32 mg/l, Acartia tonsa


EC₅₀, 96 hours: 0.03 mg/l, Selenastrum capricornutum


M factor (Chronic) 1

Short term toxicity -embryo and sac fry stages

NOEC, 28 days: 0.032 mg/l, Pimephales promelas (Fat-head Minnow)



d-Limonene



LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1

Acute toxicity - fish LC₅₀, 96 hours: 0.72 mg/l, Pimephales promelas (Fat-head Minnow)


EC₅₀, 48 hours: 0.36 mg/l, Daphnia magna


EC₅₀, 72 hours: 150 mg/l, Desmodesmus subspicatus

Acute toxicity -microorganisms

EC₅₀, 3 hours: 209 mg/l, Activated sludge




Toxicity Aquatic Acute 1 - H400 Very toxic to aquatic life.


LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1



LC₅₀, 96 hours: 1.9 mg/l, Mysidopsis bahiaEC₅₀, 48 hours: 2.94 mg/l, Daphnia magna

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EC₅₀, 96 hours: 0.38 mg/l, Pseudokirchneriella subcapitata

Pin-2(3)-ene



LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1



Citral



Acute toxicity - fish LC₅₀, 96 hours: 6.78 mg/l, Leuciscus idus (Golden orfe)




EC₅₀, 72 hours: 103.8 mg/l, Scenedesmus subspicatus

Ethanol





LC₅₀, 48 hours: 5012 mg/l, Ceriodaphnia dubia


EC₅₀, 72 hours: 11.5 mg/l, Chlorella vulgaris







LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1


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EC₅₀, 72 hours: 0.027 mg/l, Selenastrum capricornutum



Pin-2(10)-ene



LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1

Acute toxicity - fish LC₅₀, 96 hours: 0.557 mg/l, Cyprinus carpio (Common carp)




EC₅₀, 48 hours: 0.826 mg/l, Pseudokirchneriella subcapitata






LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1





12.2. Persistence and degradability

Persistence and degradability The degradability of the product is not known.


Propan-2-ol




Biological oxygen demand 1.19-1.72 g O₂/g substance

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Phototransformation Water - DT₅₀ : 0.26 days

Stability (hydrolysis) pH4 - Recovery 94.6%: 30 days @ 25°CpH7 - Recovery 94.4%: 30 days @ 25°CpH9 - Recovery 99.5%: 30 days @ 25°C

Biodegradation Water - Degradation 95.5%: 28 days

d-Limonene



Phototransformation Water - Half-life : 0.365 hoursEstimated value.





Pin-2(3)-ene



Phototransformation Water - DT₅₀ : 0.44-1.41 hours

Citral



Phototransformation Water - DT₅₀ : 37.35 minutes

Biodegradation Water - Degradation 85-95%: 28 days

Ethanol






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Biodegradation Water - DT₅₀ : 0.2 - 1.3 days

Pin-2(10)-ene







Phototransformation Water - DT₅₀ : 7 hoursEstimated value.

Biodegradation Water - Degradation 4.5%: 28 days

12.3. Bioaccumulative potential




Propan-2-ol




Partition coefficient log Pow: 2.75

d-Limonene






Pin-2(3)-ene



Citral

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Ethanol


Partition coefficient log Pow: -0.35




Pin-2(10)-ene






12.4. Mobility in soil



Propan-2-ol




Henry's law constant 0.00000104 Pa m³/mol @ 25°C Estimated value.

Surface tension 28.27 mN/m @ 19.7°C

d-Limonene


Adsorption/desorptioncoefficient

Water - Koc: 1984 @ 25°C



Pin-2(3)-ene

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Water - Koc: 2184 @ 25°C Estimated value.

Citral



Water - Log Koc: 2.169 @ 25°C Estimated value.

Henry's law constant 0.000376 atm m³/mol @ 25°C

Ethanol


Surface tension 24.5 mN/m @ 20°C/68°F



Pin-2(10)-ene



Water - Koc: 2080 @ 25°C Estimated value.



Henry's law constant 0.342 Pa m³/mol @ 25°C

12.5. Results of PBT and vPvB assessmentEcological information on ingredients.

Propan-2-ol






d-Limonene


This substance is not classified as PBT or vPvB according to current EU criteria.Estimated value.


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Pin-2(3)-ene



Citral



Ethanol






Pin-2(10)-ene






12.6. Other adverse effects



Propan-2-ol




d-Limonene




Pin-2(3)-ene

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Citral


Ethanol




Pin-2(10)-ene




SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycleproducts wherever possible. This material and its container must be disposed of in a safeway. When handling waste, the safety precautions applying to handling of the product shouldbe considered. Care should be taken when handling emptied containers that have not beenthoroughly cleaned or rinsed out. Empty containers or liners may retain some productresidues and hence be potentially hazardous.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of thelocal Waste Disposal Authority.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods(IMDG, IATA, ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutantNo.

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14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations Health and Safety at Work etc. Act 1974 (as amended).The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009No. 716).The Carriage of Dangerous Goods and Use of Transportable Pressure EquipmentRegulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].EH40/2005 Workplace exposure limits.

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).Commission Regulation (EU) No 453/2010 of 20 May 2010.Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16December 2008 on classification, labelling and packaging of substances and mixtures (asamended).Dangerous Preparations Directive 1999/45/EC.Dangerous Substances Directive 67/548/EEC.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Classification proceduresaccording to Regulation (EC)1272/2008

Eye Irrit. 2 - H319: : Calculation method.

Training advice Read and follow manufacturer's recommendations.

Issued by Toni Ashford

Revision date 24/05/2016

Revision 1

SDS number 2841

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Hazard statements in full H225 Highly flammable liquid and vapour.H301 Toxic if swallowed.H302 Harmful if swallowed.H311 Toxic in contact with skin.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H319 Causes serious eye irritation.H330 Fatal if inhaled.H336 May cause drowsiness or dizziness.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.EUH208 Contains 1,2-Benzisothiazol-3(2H)-one, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-6](3:1). May produce an allergic reaction.

This information relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurateand reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability orcompleteness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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