A Late Roman ceramic production from Pompeii (in Journal of Archaeological Science 40, 2013, pp....

17
Research paper A Late Roman ceramic production from Pompeii Celestino Grifa a, * , Alberto De Bonis b , Alessio Langella a , Mariano Mercurio a , Gianluca Soricelli c , Vincenzo Morra b a Dipartimento di Scienze per la Biologia, la Geologia e lAmbiente, Università del Sannio, Via dei Mulini 59/A, 82100 Benevento, Italy b Dipartimento di Scienze della Terra, Università Federico II, Via Mezzocannone 8, 80134 Napoli, Italy c Dipartimento di Scienze Umane, Storiche e Sociali, Università del Molise, Via Mazzini 8, 86170 Isernia, Italy article info Article history: Received 12 September 2011 Received in revised form 27 August 2012 Accepted 28 August 2012 Keywords: Pompeii Pottery Clayey deposits Volcanic temper abstract The Via Lepanto site is one of the best examples showing how the Vesuvian region was partially reconstructed and earlier re-occupied after Vesuviuss eruption in the year 79 AD. The large amount of ceramic nds illustrates the typology in use in this area during the IV and V century AD. Analyses were focused on table and cooking ware productions. Archaeometric data were obtained using chemical and minero-petrographical methods (OM, XRD, XRF and SEM). Grain size measurements using Image Anal- yses on thin sections and a geochemical comparison with clayey deposits outcropping in the Campania region permitted the identication of the raw materials used for these pottery productions. XRD and SEM completed the data set, establishing the protocols used for pottery production in the Pompeii area during Late Roman period. The Via Lepanto site was part of an exchange network of markets with a periodic frequency, where locally produced and imported pottery was sold, indicating a ourishing network of exchanges spanning short, medium and long distances. Ó 2012 Elsevier Ltd. All rights reserved. 1. Introduction The so-called Agro Nocerino-Sarnese, in the southern part of the Campanian Plain, had been an optimum for human settlements since pre-historic times, due to its fertile soils and propitious climate (Soricelli, 2001; Marturano et al., 2009). However, the scenario commonly proposed for this land immediately after the 79 AD eruption, which destroyed Pompeii, Ercolano and Stabia, is that of a bare and abandoned land. In fact, several authors hypothesise an abrupt interruption of all human activities immediatelyafter the eruption and only a late and sporadic reoccupation of the area, up until III century AD (Soricelli, 2002). However, such reconstructions suffer a lack of interest on the part of archaeologists for the post-79 ADlevelswhichconsequently,wereonlysummarilyinvestigatedor simply removed, in order to reach the pre-eruption layers. According to ancient sources (Suet. Tit. 8,4; Cass. Dio LXVI.24, 3e 4 in Gazzetti, 1976), the reconstruction process immediately after the disaster, which focused on agricultural infrastructures, public buildings and road networks, was managed by two imperial of- cers, the curatores restituendae Campaniae, and was funded by the imperial treasury (Soricelli, 2001 , 2002). Several sites and settlements, in particular along the NuceriaePompei road (Fig. 1) (De Carolis and Soricelli, 2005), conrm a reoccupation of the area, such as the Porta-Vesuvio necropolis and the Moregine complex. The Via Lepanto site is one of the best examples of a reoccupa- tion of the Vesuvius area after the 79 AD eruption (Fig. 1). It dates back to the rst half of II century AD (as shown by the African Red Slip Ware, forms Hayes 7A, 8A). The site is located on the Nuceriae Pompei road,atapproximately1kmfromtheSEwallsoftheancient city of Pompeii. It was abandoned after the 472 AD eruption, as shown by the Pollenapyroclastic deposits that covered the whole settlement (De Carolis and Soricelli, 2005). Some ceramic dumps, dating back to the late IVeearly V century AD by the African Red Slip Ware forms Hayes 59, 60, 61, 73 and 91, brought to light a large amount of pottery, among which samples of table and cooking ware. These were collected and analysed from a mineralogical and petrographical point of view. Thisresearchstudyaimsatdeningthetechnologicalfeaturesof some selected ceramic productions that were widespread in the Via Lepanto site, by means of an exhaustive mineralogical, petrograph- ical and chemical characterisation, focussing on the identication of the clays and tempers used, as well as the ring technologies. Moreover, the whole data set aims at providing a useful archaeo- metric database on the ceramic productions from this area. An attempt of hypothesis on the provenance of the shards was also carried out in order to conrm the presence of active ceramic workshops in Pompeii and the surrounding area during the Late * Corresponding author. Tel.: þ39 (0)824 363649; fax: þ39 (0)824 323623. E-mail address: [email protected] (C. Grifa). Contents lists available at SciVerse ScienceDirect Journal of Archaeological Science journal homepage: http://www.elsevier.com/locate/jas 0305-4403/$ e see front matter Ó 2012 Elsevier Ltd. All rights reserved. http://dx.doi.org/10.1016/j.jas.2012.08.043 Journal of Archaeological Science 40 (2013) 810e826

description

The Via Lepanto site is one of the best examples showing how the Vesuvian region was partiallyreconstructed and earlier re-occupied after Vesuvius’s eruption in the year 79 AD. The large amount ofceramic finds illustrates the typology in use in this area during the IV and V century AD. Analyses werefocused on table and cooking ware productions. Archaeometric data were obtained using chemical andminero-petrographical methods (OM, XRD, XRF and SEM). Grain size measurements using Image Anal-yses on thin sections and a geochemical comparison with clayey deposits outcropping in the Campaniaregion permitted the identification of the raw materials used for these pottery productions. XRD and SEMcompleted the data set, establishing the protocols used for pottery production in the Pompeii area duringLate Roman period. The Via Lepanto site was part of an exchange network of markets with a periodicfrequency, where locally produced and imported pottery was sold, indicating a flourishing network ofexchanges spanning short, medium and long distances.

Transcript of A Late Roman ceramic production from Pompeii (in Journal of Archaeological Science 40, 2013, pp....

  • Research paper

    A Late Roman ceramic production from Pompeii

    Celestino Grifa a,*, Alberto De Bonis b, Alessio Langella a, Mariano Mercurio a, Gianluca Soricelli c,Vincenzo Morra b

    aDipartimento di Scienze per la Biologia, la Geologia e lAmbiente, Universit del Sannio, Via dei Mulini 59/A, 82100 Benevento, ItalybDipartimento di Scienze della Terra, Universit Federico II, Via Mezzocannone 8, 80134 Napoli, ItalycDipartimento di Scienze Umane, Storiche e Sociali, Universit del Molise, Via Mazzini 8, 86170 Isernia, Italy

    a r t i c l e i n f o

    Article history:

    Received 12 September 2011

    Received in revised form

    27 August 2012

    Accepted 28 August 2012

    Keywords:

    Pompeii

    Pottery

    Clayey deposits

    Volcanic temper

    a b s t r a c t

    The Via Lepanto site is one of the best examples showing how the Vesuvian region was partially

    reconstructed and earlier re-occupied after Vesuviuss eruption in the year 79 AD. The large amount of

    ceramic nds illustrates the typology in use in this area during the IV and V century AD. Analyses were

    focused on table and cooking ware productions. Archaeometric data were obtained using chemical and

    minero-petrographical methods (OM, XRD, XRF and SEM). Grain size measurements using Image Anal-

    yses on thin sections and a geochemical comparison with clayey deposits outcropping in the Campania

    region permitted the identication of the rawmaterials used for these pottery productions. XRD and SEM

    completed the data set, establishing the protocols used for pottery production in the Pompeii area during

    Late Roman period. The Via Lepanto site was part of an exchange network of markets with a periodic

    frequency, where locally produced and imported pottery was sold, indicating a ourishing network of

    exchanges spanning short, medium and long distances.

    2012 Elsevier Ltd. All rights reserved.

    1. Introduction

    The so-called Agro Nocerino-Sarnese, in the southern part of the

    Campanian Plain, had been an optimum for human settlements

    since pre-historic times, due to its fertile soils and propitious

    climate (Soricelli, 2001; Marturano et al., 2009). However, the

    scenario commonly proposed for this land immediately after the 79

    AD eruption, which destroyed Pompeii, Ercolano and Stabia, is that

    of a bare and abandoned land. In fact, several authors hypothesise

    an abrupt interruption of all human activities immediately after the

    eruption and only a late and sporadic reoccupation of the area, up

    until III century AD (Soricelli, 2002). However, such reconstructions

    suffer a lack of interest on the part of archaeologists for the post-79

    AD levels which consequently, were only summarily investigated or

    simply removed, in order to reach the pre-eruption layers.

    According to ancient sources (Suet. Tit. 8,4; Cass. Dio LXVI.24, 3e

    4 in Gazzetti, 1976), the reconstruction process immediately after

    the disaster, which focused on agricultural infrastructures, public

    buildings and road networks, was managed by two imperial of-

    cers, the curatores restituendae Campaniae, and was funded by

    the imperial treasury (Soricelli, 2001, 2002). Several sites and

    settlements, in particular along the NuceriaePompei road (Fig. 1)

    (De Carolis and Soricelli, 2005), conrm a reoccupation of the area,

    such as the Porta-Vesuvio necropolis and the Moregine complex.

    The Via Lepanto site is one of the best examples of a reoccupa-

    tion of the Vesuvius area after the 79 AD eruption (Fig. 1). It dates

    back to the rst half of II century AD (as shown by the African Red

    Slip Ware, forms Hayes 7A, 8A). The site is located on the Nuceriae

    Pompei road, at approximately 1 km from the SEwalls of the ancient

    city of Pompeii. It was abandoned after the 472 AD eruption, as

    shown by the Pollena pyroclastic deposits that covered the whole

    settlement (De Carolis and Soricelli, 2005). Some ceramic dumps,

    dating back to the late IVeearly V century AD by the African Red Slip

    Ware forms Hayes 59, 60, 61, 73 and 91, brought to light a large

    amount of pottery, among which samples of table and cooking

    ware. These were collected and analysed from a mineralogical and

    petrographical point of view.

    This research study aims at dening the technological features of

    some selected ceramic productions that werewidespread in the Via

    Lepanto site, by means of an exhaustive mineralogical, petrograph-

    ical and chemical characterisation, focussing on the identication of

    the clays and tempers used, as well as the ring technologies.

    Moreover, the whole data set aims at providing a useful archaeo-

    metric database on the ceramic productions from this area. An

    attempt of hypothesis on the provenance of the shards was also

    carried out in order to conrm the presence of active ceramic

    workshops in Pompeii and the surrounding area during the Late* Corresponding author. Tel.: 39 (0)824 363649; fax: 39 (0)824 323623.

    E-mail address: [email protected] (C. Grifa).

    Contents lists available at SciVerse ScienceDirect

    Journal of Archaeological Science

    journal homepage: http: / /www.elsevier .com/locate/ jas

    0305-4403/$ e see front matter 2012 Elsevier Ltd. All rights reserved.

    http://dx.doi.org/10.1016/j.jas.2012.08.043

    Journal of Archaeological Science 40 (2013) 810e826

  • Roman period. This would provide a useful indicator of a retrieved

    socialeeconomic activity. Mineralogical, petrographical and

    geochemical analyses may also provide information on the prove-

    nance of the pottery. This is particularly true for coarse-grained

    common ware and amphorae productions in which inclusions can

    be easily correlated to the rocks cropping out in the surrounding

    area.

    The relationship between the minero-petrographical composi-

    tionof thecoarse-temper isparticularlyeffective involcanic contexts,

    as reported for some ceramic productions of the Circum-Mediterra-

    nean volcanic area, such as those from Sicily (Barone et al., 2010), the

    Aeolian islands (Williams et al., 2008) and Pantelleria (Grifa et al.,

    2005a). With regards to ceramic productions from the Bay of

    Naples, the occurrence of well sorted, rounded volcanic temper,

    mainlycomposedof sanidine, Ca-richpyroxene, plagioclase, pumices

    and scoriae, is largely attested in both fabrics of commonwares and

    amphorae (Grifa et al., 2005b, 2006, 2009a). To complete the char-

    acterization of the potsherds, clayey raw materials located close to

    the Pompeii area and along the Late Roman period main roads (e.g.

    Appia and Traiana roads) were also sampled and compared with the

    investigated ceramic products, from a mineralogical and geochem-

    ical point of view (De Bonis, 2011; De Bonis et al., 2012).

    2. Volcanological remarks

    Located not far from the Southern-eastern part of the city of

    Naples and within one of the most densely inhabited areas of the

    world, this typical stratovolcano has always conditioned human

    behaviour in this portion of the Campania region. Mount Somma

    represents the oldest volcano that concluded its activities with

    a caldera formation. Within this caldera, the Vesuvius volcano

    successively formed (Cioni et al., 1999). The volcanic history of the

    SommaeVesuvius complex is still debated. After a rst phase,

    which started circa 300e400 ka (Brocchini et al., 2001), it was only

    after the Phlegraean Campanian Ignimbrite eruption that activity

    was recorded (39 ka; Fedele et al., 2008). It was upon this eruption

    that the present volcanic complex was formed (Di Vito et al., 1998).

    Since its last eruption in 1944 AD, the SommaeVesuvius has

    experienced a quiescent status.

    From a petrological point of view, the volcanic products belong

    to the HK series and they are typical leucite-bearing rocks

    (Conticelli et al., 2004). The rst historical Plinian eruption, recor-

    ded in the archaeological layers and largely used as a stratigraphic

    marker for the Bronze Age, is the Pomici di Avellino eruption

    (4.365 ka; Santacroce et al., 2008) which deposited large volumes

    of pyroclastic falls and ows, causing the migration of the pre-

    historical population to the surrounding areas. However, the most

    important Plinian event, also from a historical point of view, is the

    79 AD Pompei eruption (Lanphere et al., 2007) directly observed

    and carefully described by Plinius the Younger. Successively, the

    472 AD Pollena eruption (Santacroce et al., 2008) also had a strong

    impact on the Vesuvius area. These latter two eruptions represent

    important events for the Via Lepanto site, as they mark the

    beginning and the end of occupancy.

    Fig. 1. Simplied geological map of Campania region (modied from Bonardi et al., 2009). Main roads (Shepherd, 1911) and clay sampling sites are also reported.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826 811

  • 3. Materials

    3.1. Pottery

    Some Late Roman potsherd dumps, sealed by Pollena products

    (472 AD), brought to light several thousands of ceramic fragments,

    mainly represented by common ware (table and cooking ware).

    Fifty-two fragments from these ceramic classes (Table 1) were

    sampled for minero-petrographical analyses. From an archaeolog-

    ical point of view, the pottery from Via Lepanto can be compared to

    similar products circulating in the region between the end of IV

    century AD and the beginning of the V century AD (De Carolis and

    Soricelli, 2005).

    Three different types of table were investigated: Red Painted

    Ware (RPW), Painted Ware (PW) and Burnished Ware (BW). The Red

    Painted Ware (17 samples), mainly represented by open shapes

    (Fig. 2a), can be easily identied by a light reddish slip that covers

    the entire internal surface and partially overlaps the external rim of

    the artefact. Macroscopic observations permit the recognition of

    two different groups of fragments. The rst is characterised by

    a ne and very hard paste. The colour of the paint is red/red-orange

    (2.5YR 4/8). A second group of samples shows a coarser and softer

    paste. The thin paint is red in colour (2.5YR 5/6). In both groups, the

    ceramic body has a redebrown colour (2.5YR 5/8) but some sand-

    wich structures can be observed (sample PVL 39 and 41, Table 1).

    Examples of RPW have been found in late IVeearly V century AD

    contexts from Somma Vesuviana (Aoyagi et al., 2007) and Mer-

    cato S. Severino (Fiorillo, 2003). These can be compared with

    pottery from other Southern Italy sites: Naples (Arthur, 1994),

    Pratola Serra (Alfano, 1992), Ordona (Annese, 2000) and Calle (Di

    Giuseppe, 1998).

    A second tableware ceramic class is represented by 5 samples of

    the Painted Ware (Whitehouse, 1966) showing a greyish ne paste

    (5YR 6/3) with a redebrown decoration applied by a paintbrush or

    a cloth. These vessels (Fig. 2b) can be compared with analogous

    products from other Campanian sites: Cuma, Miseno (Grifa et al.,

    2005b, 2009a), Benevento (Lupia, 1998) and Caudium (Perrone,

    2005; De Bonis et al., 2010). The last three samples of tableware

    are represented by small closed shapes with a ne red paste (2.5YR

    5/8) and with a shiny red cover (2.5YR 4/8) on the external surface:

    the Burnished Ware (inset of Fig. 2b). Well represented in Vesuvius

    area, this ware is common in Naples and in other Campanian sites

    (De Carolis and Soricelli, 2005).

    The Cooking Ware samples (CW, 27 samples) show a very coarse

    paste. In general, the matrix shows a red/brown colour (5YR 6/3e

    5YR 6/6) but in several samples, sandwich zoning of the ceramic

    body can be observed. Main attested shapes (Fig. 2c) are the

    casseroles that can be found in other Campanian contexts, in

    particular in Benevento (Lupia, 1998), Caudium (De Bonis et al.,

    2010), Neapolis (Carsana, 1994) and the Phlegraean area (Soricelli,

    2000). Saucepans and lids also occur. Only one sample (Fig. 2c)

    can be referred to the PantellerianWare, a cooking warewidespread

    in the Mediterranean area between IV and VI century (Grifa et al.,

    2005a).

    3.2. Clayey raw materials

    Ten samples of clayey raw materials (Table 2, Fig.1) were

    collected in order to compare their mineralogical and geochemical

    composition with that of the ceramic nds. Samples were chosen

    according to their proximity to both possible ancient sites of

    production and the main Roman roads of the Campania region

    (Fig. 1). They are mainly represented by basinal sediments, subor-

    dinate alluvial deposits and strongly weathered pyroclastic soils

    (Table 2). Basinal sediments mainly outcrop along the Apennine

    chain located in the eastern part of the Campania Region and are

    ubiquitously ascribed to different units such as the Sicilide Unit

    (samples BS1, BS2, GS1) or the Fortore Unit (sample MLV1), which

    all date from the Upper Cretaceous to the Lower Miocene (Table 2;

    Fig. 1) (Bonardi et al., 2009). Sample MLV1 was collected in the area

    surrounding the mud volcano known as the Bolle della Malvizza in

    the Miscano river valley, very close to the Traiana Roman Road

    (Fig. 1), which crossed the Apennine chain to the Adriatic coast. The

    GS1 sample crops out close to the town of Gioia Sannitica (Caserta

    province). Other basinal samples (SQ1 and TRE1), ascribed to

    Caiazzo Sandstones (Bonardi et al., 2009), come from the Northern

    Campania area, which is well-known for the presence of several

    Roman settlements. The SQ1 sample was collected near the town of

    Caiazzo (Caserta province). The TRE1 sample comes from the

    village of Treglia (Caserta province), a Roman settlement (Trebula),

    Table 1

    Archaeological information of 52 common ware ceramic samples from Via Lepanto.

    The colour code form Munsell Soil Colour Chart.

    Sample Class Body Zoning Heart Rim Slip

    PVL 1 BW 2.5YR 5/8 2.5YR 4/8

    PVL 2 BW 2.5YR 5/8 2.5YR 4/8

    PVL 3* BW 2.5YR 5/8 2.5YR 4/8

    PVL 4* PW 5YR 6/3

    PVL 5* PW 5YR 6/3

    PVL 6 PW 5YR 6/3

    PVL 7* PW 5YR 6/3

    PVL 8 PW 5YR 5/6

    PVL 9* CW 5YR 6/3

    PVL 10* CW 5YR 6/6

    PVL 11 CW 5YR 6/6

    PVL 12* CW faded 5YR 6/3 2.5YR 5/8

    PVL 13 CW faded 5YR 6/3 2.5YR 5/8

    PVL 14 CW faded 5YR 6/3 2.5YR 5/8

    PVL 15* CW faded 5YR 6/3 2.5YR 5/8

    PVL 16 CW 5YR 6/3

    PVL 17 CW 5YR 6/3

    PVL 18 CW faded 5YR 6/3 2.5YR 5/8

    PVL 19* CW 5YR 6/3

    PVL 20 CW faded 5YR 6/3 2.5YR 5/8

    PVL 21* CW 5YR 6/3

    PVL 22 CW faded 5YR 6/3 2.5YR 5/8

    PVL 23 CW 5YR 5/6

    PVL 24 CW sharp 5YR 6/3 2.5YR 5/8

    PVL 25 CW 5YR 6/6

    PVL 26* CW faded 5YR 6/3 2.5YR 5/8

    PVL 27* CW 5YR 6/6

    PVL 28 CW 5YR 6/6

    PVL 29 CW faded 5YR 6/3 2.5YR 5/8

    PVL 30 CW 5YR 6/6

    PVL 31 CW faded 5YR 6/3 2.5YR 5/8

    PVL 32 RPW 2.5YR 5/8 2.5YR 4/8

    PVL 33 RPW 2.5YR 5/6

    PVL 34* RPW 2.5YR 5/8 2.5YR 5/6

    PVL 35* RPW 2.5YR 5/8 2.5YR 4/8

    PVL 36 CW sharp 5YR 6/3 2.5YR 5/8

    PVL 37 CW sharp 5YR 6/3 2.5YR 5/8

    PVL 38* RPW 2.5YR 5/8 2.5YR 4/8

    PVL 39* RPW sharp 5YR 6/3 2.5YR 5/8 2.5YR 4/8

    PVL 40 RPW 2.5YR 5/8 2.5YR 4/8

    PVL 41 RPW sharp 5YR 6/3 2.5YR 5/8 2.5YR 4/8

    PVL 42 RPW 2.5YR 5/8 2.5YR 4/8

    PVL 43 RPW 2.5YR 5/8 2.5YR 4/8

    PVL 44 RPW* 2.5YR 5/8 2.5YR 5/6

    PVL 45 CW 2.5YR 5/8

    PVL 46 RPW* 2.5YR 5/8 2.5YR 4/8

    PVL 47 RPW 2.5YR 5/8 2.5YR 4/8

    PVL 48 RPW 2.5YR 5/8 2.5YR 4/8

    PVL 49 RPW 2.5YR 5/8 2.5YR 4/8

    PVL 50 RPW 2.5YR 5/8 2.5YR 5/6

    PVL 51 RPW 2.5YR 5/8 2.5YR 5/6

    PVL 52 CW 5YR 4/3

    BW Burnished Ware; PW Painted Ware; CW Cooking Ware; RPW Red Painted

    Ware, * Samples studied by image and modal analyses.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826812

  • where an ancient ceramic workshop is reported to have existed

    (Livadie, 1994).

    The PMV2 alluvial clayey sediment (Piana di Monte Verna,

    Caserta province) of the Volturno River plain is a holocenic clay

    collected two meters below the ground level, in which bricks of

    Roman age were also found. VEL1 is an Alento River sediment

    (PleistoceneeHolocene), sampled in a former clay quarry in the

    area surrounding Velia, the ancient Greek colony of Elea. Other

    clayey raw materials derive from strongly weathered pyroclastic

    deposits that were widespread in the volcanic areas of the region.

    Such materials were most likely exploited in the past for pottery

    productions, especially in the Bay of Naples area, and are still used

    for the manufacturing of bricks for wood-burning ovens or cooking

    wares, following ancient techniques and taking advantage of their

    refractory properties. One sample (SO1) comes from a brownish

    lahar-like deposit of the Sorrento Peninsula, deriving from the

    activity of SommaeVesuvius. The other sample (CSC1) comes from

    the pyroclastic soils of the Roccamonna volcano (De Bonis, 2011).

    4. Analytical techniques

    The mineralogical and textural properties of the pottery frag-

    ments were investigated on thin sections with a Leitz Laborlux

    12POL polarising microscope. On selected representative samples

    of each ceramic class, accurate measurements of the non-plastic

    inclusions were carried out with an image analysis software

    (Leica Q-Win). Point-to-point modal analyses were carried out on

    Fig. 2. The variegated repertoire of the common ware ceramic from Via Lepanto; a) the Red Paint Ware (RPW), bowls and dishes; b) the Painted Ware (PW), bowls and dishes, in the

    inset the shape representative of the Burnished Ware (BW); c) The Cooking Ware (CW), pans, pots, saucepan and lids, in the inset a typical saucepan of Pantellerian Ware.

    Table 2

    Clayey deposits description.

    Sample Locality Geological origin Description

    BS1 Bisaccia (AV) Basinal sediment Blue-greenish

    clayey silt

    BS2 Bisaccia (AV) Basinal sediment Reddish clayey silt

    GS1 Gioia Sannitica (CE) Basinal sediment Reworked brown-

    yellowish sediment

    MLV1 Montecalvo

    Irpino (AV)

    Basinal sediment Greyish clayey

    sediment

    SQ1 Castel Campagnano

    (CE)

    Basinal sediment Reworked brownish

    silty sediment

    TRE1 Pontelatone (CE) Basinal sediment Reworked brownish

    silty sediment

    PMV2 Piana di Monte

    Verna (CE)

    Alluvial sediment Yellowish clayey silt

    VEL1 Velina di Castelnuovo

    Cilento (SA)

    Alluvial sediment Yellowish sandy silt

    CSC1 Cascano di Sessa

    Aurunca (CE)

    Pyroclastic deposit Reddish clayey silt

    SO1 SantAgnello (NA) Pyroclastic deposit Brownish sandy silt

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826 813

  • ca. 3000 points for each sample, evaluating the abundance of paste

    constituents (grains, matrix and pores). Using a manual procedure,

    image analyses also permitted measuring some shape parameters

    of the inclusions, such as the minimum (Am) and maximum (AM)

    axis of single grains, assuming the grain inscribed in an ellipse. The

    two axes were used to calculate the Krumbein f size (f!log2 AM;

    Krumbein and Sloss, 1963) and the Am/AM axis ratio that was

    assumed, in this study, as a shape factor (SF). As SF values range

    from nearly 1.0 for circular grains to nearly 0.0 for elongated grains,

    a logit transformation, Logit (SF) Ln(SF/(1 ! SF)), was applied

    (Prakongkep et al., 2010). Optical conditions for particles

    measurements varied as a function of the inclusion grain size.

    Image resolution was 1280 " 1024 pixel, for ner grains captured

    with 40" magnication (1 mm 480 pixel) and for coarser grains

    captured using 25" magnication (1 mm 320 pixel). All images

    were captured in parallel-polarized light in order to avoid extinc-

    tion problems.

    Bulk chemical compositions of the shards and the reference clay

    samples were evaluated by XRF (Philips PW 1400): ten major

    elements (Si, Ti, Al, Fe, Mn, Mg, Ca, Na, K, P as oxide %) and 9 trace

    elements (Ni, Rb, Sr, Zr, Nb, Sc, V, Cr, Ba in ppm)were determined on

    pressed pellets. Analytical procedureswere carried out according to

    Melluso et al. (2005). Volatile content (LOI) was determined

    measuring mass lost (1 g of powdered sample) heated at 1000 #C.

    XRF analyses were not performed for sample PVL 28 and 41 due to

    a lack of sufcient material. A statistical multivariate approach was

    carried out on the XRF data set to better evaluate the chemical

    behaviour of the ceramic fragments in a multidimensional space

    and to verify homogeneity in the different data populations.

    Statistical treatment of the Grain-Size Distribution (hereafter GSD)

    and the XRF data was carried out using the R version 2.10.0 soft-

    ware (R Development Team, 2005).

    Two analytical approaches were united in order to evaluate the

    ring temperatures of the ceramic shards. X-ray diffraction (XRD)

    permitted the identication of the mineralogical composition of

    the potsherds, which depends on the base-clay and possible sub-

    microscopic phases related to the ring dynamics (Philips PW

    1730/3710 diffractometer, CuKa radiation 40 kV, 30 mA, curved

    graphite monochromator, scanning interval 3e80#, step

    size 0.020# 2q, counting time 5 s per step). Scanning Electron

    Microscopy (SEM Jeol JSM 5310) observations, carried out on gold-

    coated fresh-fractured fragments, provided information in terms of

    microstructures and the sintering degree of the clay matrix

    (Maniatis and Tite, 1981). Bulk mineralogy of clay-rich sediments

    was investigated by XRD on randomly oriented powders; clay

    minerals were identied on the

  • red slip (Fig. 3a). The modal analysis carried out on the PVL 3

    sample evidenced a low porosity (5.63%), tiny particles of quartz

    and feldspars (28.6%) and subordinate volcanic grains such as:

    obsidians (4.13%), clinopyroxene (pale green Fe-rich diopside and

    colourless diopside, 3.62%), scoriae (3.38%), sanidine (2.23%),

    pumices (1.63%) and plagioclase (1.00%) attesting a high total

    inclusions content (Fig. 4a).

    For all the samples, a theoretical skew-t (Azzalini and Genton,

    2008; Azzalini, 2006) Probability Density Function (PDF, dashed

    curves in Fig. 5) was plotted (using the same mean and standard

    deviation values) in order to compare the real and the theoretical

    curves. The density GSD histogram (Fig. 5a) showed a skewed f size

    curve from main coarse silt/ne sand particle sizes (median value

    3.93; z0.70 mm, mean value 3.88) to subordinate coarse/very

    coarse sand (weak negative spread). The standard deviation value

    (sf 0.61) expressed a moderately well sorted distribution of

    the inclusions (Folk, 1974). Moreover, the logit (SF) histogram

    highlighted moderately to poorly elongated shapes of grains as

    illustrated by the tail toward positive values of the PDF curve

    (Fig. 5b).

    The PW pasteswere formed bypredominant grey (PVL 4, 6, 7 and

    8) to red-brown isotropic matrixes (PVL 5), ranging from 62.4 to

    65.2% in PVL 4 and PVL 5, respectively, and subordinate inclusions

    (from 27.2 in PVL 5e30.7% in PVL 7). This ceramic class is

    characterised by the highest matrix/inclusions ratio (>2) and

    lowest volcanics and inclusions content when compared to the

    others (Fig. 4a, Table 3). Furthermore optical properties of the clay

    matrix (Fig. 3b), PVL 5 also showed a different GSD, namely,

    a skewed PDF curve (main medium silt/medium sand, Fig. 5c) with

    a tail toward coarser grains (coarse sand), due to a higher volcanic

    grains content (6.00%) and the moderate sorting (sf 0.75). The

    inclusions are mainly constituted by microcrystalline quartz and

    feldspars (21.2%) and subordinate volcanic elements, such as clino-

    pyroxene (2.20%), sanidine (1.4%), scoriae (1.2%), plagioclase (0.8%),

    Fig. 3. Micrographs showing some optical properties of the analysed samples. a) paste and cover, sample PVL 1, parallel polars; b) matrix and inclusions, sample PVL 5, parallel

    polars; c) matrix and inclusions, sample PVL 4, parallel polars; d) grain and matrix of RPW group 1 representative sample, sample PVL 34, parallel polars, e) grain and matrix of RPW

    group 2 representative sample, sample PVL 44, crossed polars; f) coarse-grained CW sample, sample PVL 9, crossed polars; g) coarse-grained CW sample, sample PVL 15, crossed

    polars; h) anorthoclase crystal, sample PVL 52, crossed polars.

    Fig. 4. Diagrams showing some modal parameters.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826 815

  • leucite-bearing scoriae (0.2%) and obsidian fragments (0.2%). The

    grain shape varies from subrounded to poorly elongated (Fig. 5d).

    In contrast, samples PVL 4 and PVL 7 (Fig. 3c) showed approx-

    imately normal GSD diagrams (Fig. 5e), ranging frommedium silt to

    ne sand, and moderately well sorted grains (sf 0.50 and 0.67,

    respectively) composed of quartz and feldspar particles and very

    subordinate volcanic grains (Table 3). Logit (SF) curves evidenced,

    for each sample, a moderately elongated shape of the grains

    (Fig. 5f). Porosity ranged from 6.00% in PVL 7 up to 10.1% in PVL 4.

    The RPW samples can be grouped in accordance with their

    different textures, despite their similar stylistic character. All the

    samples generally showed a red-to-red-orange coloured isotropic

    matrix. Occasional colour zoning can be related to a different

    optical activity of the clay matrix. Group 1 (PVL 32, 34, 35, 38, 39,

    40, 41, 42, 47, 48 and 49, Fig. 3d) showed a slight lower matrix (50%

    vs. 54%, on average), volcanic grains (14% vs. 23%, on average) and

    a higher quartz-feldspar fraction (23% vs. 14%, on average; Figs. 3d

    and 4b and Table 3), when compared to the samples of group 2 (PVL

    33, 44, 46, 50 and 51, Fig. 3e). Volcanic grains were constituted by

    scoriae (2.20e4.29%, average values), obsidians (1.72e3.42%),

    plagioclase (1.20e2.78%), pumices (1.12e4.67%), sanidine (1.43e

    2.76%), biotite (0.60e2.64%) and clinopyroxene (0.12e0.80%). A

    skewed GSD from medium silt to medium sands, with the tail

    towards coarser grains up to coarse sand (Fig. 5g) was evidenced

    for the group 1 samples. The inclusions varied from moderately

    well (PVL 34) tomoderately sorted (PVL 35, 38, 39), as illustrated by

    the sf values (Table 3). The logit (SF) evidenced a mainly elongated

    shape of inclusions (Fig. 5h).

    The samples of group 2, on the other hand, show higher sfvalues, indicating a moderate (PVL 44) to poor (PVL 46) sorting. In

    Fig. 5. f size and logit (SF) frequence diagrams for some representative samples of the studied potsherds. a), b) PVL 3, BW sample; c), d) PVL 5, PW sample; e), f) PVL 4, PW sample;

    g), h) PVL 39, RPW sample; i), l) PVL 44, RPW sample; m), n) PVL 10, CW sample; o), p) PVL 15, CW sample.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826816

  • Fig. 5. (continued).

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826 817

  • reference to this group, the GSD diagrams (Fig. 5i) showed a skewed

    distribution (medium silt to coarse sand) with a more pronounced

    tail (higher density) toward coarser grains. Non-crystalline

    elements, such as scoriae (leucite-bearing scoriae in PVL 44),

    pumices and obsidians still represent the most abundant volcanic

    component. Subordinate sanidine, plagioclase, clinopyroxene and

    biotite were also observed (Table 3). RPW group 1 showed a higher

    porosity than group 2 (12% vs. 6%, on average). The logit (SF) again

    evidenced a mainly elongated shape of inclusions (Fig. 5j).

    TheCW samples (PVL9,10,11,12,13,14,15,16,17,18,19, 20, 21, 22,

    23, 24, 25, 26, 27, 28, 29, 30, 31, 36, 37, 43, 45 and 52) showed wider

    differences in textures namely, GSD and inclusions content and

    optical characters of the matrix (Fig. 3f, g). The inclusions range

    between 35.6% (PVL 9) and 46.0% (PVL 10), dened matrix/inclu-

    sions ratios from 1.02 (PVL 10) to 1.79 (PVL 15) (Fig. 4a). GSD

    diagrams varied from slightly positive skewed (PVL 10, Fig. 5k) to

    bimodal textures (PVL 15, Fig. 5m). The sorting rate ranged from

    moderately well sorted (sf 0.67 in PVL 19) to moderately sorted

    (sf 0.95 in PVL 21). In comparison to the other ceramic classes, the

    GSD curve of the CW samples evidenced a shift toward larger grain

    size and ahigherdensity of coarse grains, fromcoarse silt tomedium

    sand (Fig. 5k, m). The shape of the grains is generally elongatedwith

    a weak tail toward more rounded grains (Fig. 5l, n). Along with the

    quartzefeldspar component (ranging from 7.98% up to 29.1% in PVL

    15 and PVL 26, respectively), volcanic grains always occur and are

    mainly constituted by sanidine (4.04e12.17%), plagioclase (2.43e

    4.50%), scoriae (1.13e7.71%), clinopyroxene (0.52e2.67%), obsidian

    (0.38e4.75%), biotite (0.30e2.76%) and pumices (0.22e1.25%).

    Garnet (0.11%) was observed in samples PVL 10, 15 and 21; leucite-

    bearing scoriae were only recorded in PVL 19. The presence of

    secondary calcite was noticed in PVL 9, 10, 12, 15, 19, 21, 26 and 46.

    Some relevant exceptions should also be noted: samples PVL 24, 25,

    26 lack volcanics, whereas the PVL 52 sample showed distinctive

    exotic volcanic grains such as quartz, anorthoclase (Fig. 3h), green

    clinopyroxene, subordinate aenigmatite.

    5.2. XRF

    All the ceramic fragments are characterised by a low CaO

    content (3.50 wt

    %). The low CaO samples, excluding silica (58.3 wt% in PVL 44 up to

    67.2 wt% in PVL 2), are all characterised by a good chemical

    homogeneity, as illustrated in diagram Fig. 6. A higher Na2O content

    (3.2 wt%) was recorded for sample PVL 52. North America Shale

    Composition (NASC)-normalized (Gromet et al., 1984) spider

    diagrams permitted a simultaneous comparison of the trace

    elements abundance. Similar patterns (Fig. 7a and b) were recog-

    nised for samples from the BW and RPW classes, which only differ

    from the NASC by a slight Rb enrichment. The high CaO samples

    (PVL 4, 6, 7 and 8) of the PW group (Fig. 7c) have similar patterns,

    withmarked positive Sr and Nb peaks when compared to the NASC;

    Rb, Zr and Nb are denitely enriched in sample PVL 5.

    With regards to trace elements, the CW group identied similar

    patterns for a large number of samples (shaded elde Fig. 7d). Only

    Nb and subordinately Sc experienced a wider variation. However,

    within this group few samples can be distinguished: PVL 52

    showed a bell-shaped pattern attesting very low content in the Nie

    Cr pair and enrichment with respect to the NASC in ZreNb. Samples

    PVL 24 and 25 differ by way of the lowest Nb content. PVL 26

    showed a marked Sr and Sc enrichment. LOI values (Table 5) range

    from 0.15 wt% in PVL 35 up to 9.80 wt% in PVL 46.

    All clayey samples show low CaO contents, ranging from 0.28 to

    4.3 wt%. Silica ranges from 55.2 wt% (GS1) to 69 wt% (SQ1). These

    values are negatively correlated with Al2O3 (from 16.3 wt% in SQ1

    to 27.1 wt% in GS1) and these are likely due to different contents of

    quartz/feldspar and clay minerals as evidenced in XRD analyses

    (see Section 5.3). Fe2O3 content ranges from 5.2 wt% (GS1) to

    10.5 wt% (BS2).

    With regards to alkali elements, K2O shows an average content

    of 3.27% in basinal and alluvial sediments (BS1, BS2, GS1, MLV1, SQ1,

    TRE1, PMV2, VEL1). Samples of weathered pyroclastics evidenced

    higher values (SO1 4.04%; CSC1 6.11%); basinal sample MLV1

    shows a very high sodium oxide content (4.43 wt%), which most

    probably is due to the peculiar conditions of the outcrop located in

    a mud volcano environment, where gas emission and highly saline

    (NaeCl) thermal springs exist (Duchi et al., 1995).

    Major oxides of clayey sediments and potsherds were plotted in

    a binary variation diagram, using CaO as a differentiation index

    (Fig. 6). Despite a wide chemical afnity, some raw materials differ

    from the artefacts for some oxides content. Strong differences were

    noticed for MLV1 that can be distinguished for its higher Na2O

    (4.43 wt%) and CaO (4.57 wt%) values. GS1 shows the highest Al2O3(27.12 wt%) and the lowest SiO2 content (55.21wt%). CSC1 differs by

    way of a high alkali content (Na2O 2.32 wt%; K2O 6.11 wt%).

    Sample SO1 is marked byminor differences (slight higher alumina).

    Samples BS1 and BS2 show higher MgO contents (4.34 wt% and

    3.42 wt%, respectively); sample TRE1 is characterized by a higher

    CaO value (4.09 wt%); PMV2, VEL1, and SQ1 show slightly lower

    Fe2O3 contents (6.18, 6.47 and 5.26 wt%).

    Trace elements of clayey sediments in NASC-normalised

    diagrams (Fig. 7e, f and g) permitted the identication of a group

    of three samples (SQ1, VEL1, and TRE1) which showed similar

    patterns comparablewith the low CaO potsherds group.Weathered

    pyroclastics (CSC1 and SO1) clearly differ for their lower Cr and Ni

    values and higher Rb, Sr, Zr contents. These chemical features are

    quite far from those of the ceramic potshards. Concerning the trace

    elements of the four basinal samples (BS1, BS2, MLV1, and GS1),

    they also show substantial differences with the investigated

    potsherds. In particular, they are characterised by a higher Cr

    content, more pronounced in BS1 and BS2, and by a variable Sr

    content (higher in MLV1 and lower in GS1).

    Multivariate statistical analysis (Hierarchical Cluster Analysis,

    HCA, Fig. 8) on the XRF data of the potsherds and clayey deposits

    were carried out. Raw data was log-10 transformed (Aruga, 2003;

    Hall, 2004). MnO, P2O5 and Ba were omitted from the dataset, as

    they could be affected by post-earthen alteration (Fabbri et al.,

    1994; Maggetti, 2001). Statistical data treatment largely conrms

    the homogeneities of the low CaO main group, namely all the

    potsherds, the BW, RPW and CW classes, as well as one PW sample

    (PVL 5). The alluvial deposits (VEL1 and PMV2) and two marine

    (basinal TRE1 and SQ1) sediments can be closely associated to this

    main group.

    The high CaO PW samples (PVL 4, 6, 7, 8) and one RPW sample

    (PVL 40) belong to a different group. All the other potsherds (CW:

    PVL 24, 25, 26, 52; RPW: PVL 43) as well as the other clay samples

    scatter from the above reported groups.

    5.3. XRD

    The XRD data (Table 6) on the pottery samples, generally

    conrmed the optical microscope observations, evidencing the

    abundance of quartz and feldspar and subordinate sanidine and

    pyroxene. In contrast, the occurrence of pyroxene, not documented

    by optical microscopy, was reported for most of the PW group

    samples (PVL 4, 6 and 8). Consequently, in these samples the Ca-

    pyroxene was interpreted as a high-temperature phase (Grifa

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826818

  • Fig. 6. Major elements binary diagrams.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826 819

  • et al., 2009b) due to the calcareous character of the raw materials.

    An almost ubiquitous occurrence of illite was detected (except for

    PVL 3, 4, 6, 8, 11, 25, 29 and 41), with the highest content for the

    RPW samples PVL 32, 38, 50 and 51. Hematite was recorded in

    samples PVL 5, 6, 10, 12, 15, 19, 25, 41, 47, 48, 49 and 52. Fe-

    hydroxide (goethite) in samples PVL 2, 6, 10, 11, 15, 17, 25 and 32

    was most likely formed after hematite hydroxylation during post-

    earthen processes (Secco et al., 2011).

    All the basinal and the alluvial clayey sediments are mainly

    composed of quartz and feldspar with subordinate illite/mica group

    minerals (Table 6). Minor calcite was noticed in TRE1 and MLV1;

    hematite in BS2 accounts for its reddish colour. Among the clay

    minerals, kaolinite, illite/smectite mixed layer and chlorite were

    ubiquitous; the only exceptions are for the GS1, PMV2 and VEL1

    samples in which chlorite was absent. Weathered pyroclastics are

    mainly constituted by feldspar (sanidine) and illite/mica (biotite).

    Fig. 7. NASC normalized spider diagram.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826820

  • Clinopyroxene is abundant in SO1. Quartz occurs only in traces

    along with hematite in CSC1. Kaolinite and/or halloysite are the

    main occurring clay minerals.

    5.4. Firing temperature estimation

    Based on mineralogical data, 14 samples were selected for

    Scanning Electron Microscope analyses in order to investigate the

    sintering degree of the clay matrix in order to obtain information

    on ring temperatures (Maniatis and Tite, 1981). The estimated

    ring temperatures are reported in Table 4. The evaluation of this

    parameter, in addition tomineralogical andmicrotextural data, also

    takes into accounts the CaO content of the raw material and the

    redox conditions in the kiln. All the samples were red in oxidative

    conditions of the kiln, as conrmed by OM and macroscopic

    observations. Furthermore, the raw material did not contain

    important amounts of carbonates, except for the PW sample PVL 4.

    The presence of illite along with a low sintered matrix (NV, Fig. 9a)

    in the BW samples (PVL 1 and 2) permits hypothesizing a ring

    temperature lower than 800 #C.

    Regarding the PW ceramic class, sample PVL 4 showed a higher

    sintering stage of the matrix as testied by the complete loss of the

    crystalline structure of the clay minerals and the ne pore size

    (CVFB, Fig. 9b). The ring temperature of this sample ranged

    between 950 and 1050 #C; the low sintering stage of sample PVL 5

    accounts for lower ring temperatures (NV, T < 800 #C).

    The illite-bearing RPW samples (PVL 35, 50 and 51) showed

    a vitrication of the ceramic body (V, Fig. 9c), indicating ring

    temperatures ranging between 850 and 950 #C. The advanced

    sintering degree (CVFB, Fig. 9d) of a hematite-bearing sample (PVL

    41) conrms higher ring temperatures (>950 #C) coherent with

    the type of original clay (low CaO).

    A wider variability in microtextures was observed for the CW

    samples, which except for sample PVL 11, always showed the

    presence of illite along with a low sintering stage (NV), leading to

    the possibility to hypothesize ring temperatures lower than

    800 #C. Samples PVL 16,17 and 18 showed an Initial Vitrication (IV,

    Fig. 9e) with clear evidence of the sintering of phyllosilicates that

    tend to clump in homogeneous aggregates. The presence of illite

    and the observed microtextures permitted estimating ring

    Fig. 7. (continued).

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826 821

  • temperatures ranging from 800 to 850 #C. Higher ring tempera-

    tureswere estimated (between 850 and 950 #C) for the CW samples

    PVL 36 and 37, for which a sintered paste (V) was observed (Fig. 9f).

    6. Discussion

    A careful investigation on fragments of table and cooking ware

    selected among thousands of shards from some pottery dumps of

    Via Lepanto site (Pompeii) provided relevant information on the

    role of ceramics as a possible socialeeconomic indicator of a deeply

    proven land after the 79 AD Pompeii eruption and up to 472 AD (the

    Pollena eruption). However, it should be noted, that neither kiln

    wastes nor furnace structures have been identied in this archae-

    ological site. Hence, in the rst instance, the provenance of the

    pottery can only be hypothesized via the comparison of mineral-

    ogical and geochemical data on ceramics and raw materials.

    Microscopical observations on a thin section indicated the

    presence of a volcanic component characterised by sanidine, pale

    green Fe-rich diopside and colourless diopside, plagioclase, biotite

    crystals along with obsidians, pumices and scoriae. This volcanic

    body, common to all the ceramic classes with the exception of a few

    scattered samples (see below), shows a paragenesis that can be

    related not only to the differentiated products of SommaeVesuvius

    but also to that of the Campi Flegrei magmatic activity or Ischia too.

    From a rst approximation, a provenance from the so-called Bay of

    Naples can be asserted. In effect, the presence of some minor

    components of the paste, such as garnet crystals or leucite-bearing

    scoriae, suggests a temper supply area located close to the Sommae

    Vesuvius, including sand beach deposits (Morra et al., 2012).

    Leucite, in fact, is the typical feldspathoid, almost ubiquitous in the

    activity of SommaeVesuvius and completely lacking in the prod-

    ucts from Campi Flegrei and Ischia, whereas garnet only appears in

    the sialic products (phonolite) of SommaeVesuvius (Santacroce

    et al., 2008). Moreover, the entire volcanic inclusions observed in

    the samples are well consistent with those usually found in

    production indicators (kiln wastes, spacers and bricks from the

    furnace structures) from the Pompeii area (Cavassa, 2009; Grifa and

    Morra, 2009). These production indicators come from a Roman

    furnace (then re-adapted to a tannery) in the insula 5/Regio I, rep-

    resenting so far, the second nd of a pottery furnace, after the well-

    known lamp furnace (Cerulli Irelli, 1977).

    Following these assumptions and taking into account the

    compositional homogeneity of the BW, RPW and CW samples,

    a local production for these ceramic classes could be hypothesized.

    However, some exceptions in the CW group were noticed. For

    example, samples PVL 24, 25, 26 showed quartzefeldspars temper

    grains, phases almost absent among the inclusions of the potsherds

    from the Bay of Naples and reasonably compatible with sandy-like

    deposits from the inland Apennine chain. The lack of specic

    comparisons does not permit attributing these samples to a reliable

    production centre. On the contrary, the PVL 52 CW sample can be

    easily attributed to the Late Roman Pantellerianware ceramic class,

    widespread in the Mediterranean area and conrmed in other

    Campanian sites (e.g. Sacello degli Augustali, Grifa et al., 2005a).

    This is due to its very distinctive volcanic temper composed of

    differentiated peralkaline rock grains (quartz, anorthoclase, green

    pyroxene and brown amphibole).

    The PW group showed a quite different chemical composition,

    namely a higher Ca and Sr content along with lower silica and

    alumina. The only exception is sample PVL 5 that can be denitely

    attributed to the PW group due to its similar typological character

    although it presents a different texture and chemical composition.

    The high-CaO PW group can be related to the Phlegraean broad-

    line production (Whitehouse, 1966) from Cuma. Those samples

    showed wide homogeneity, both from a chemical and minero-

    petrographical point of view, with the reference group dened by

    Grifa et al. (2009a). Nevertheless, sample PVL 5, which showed

    typological afnities with the Phlegraean broad-line production but

    technological properties very similar to the BW, RPW and CW,

    suggests a local production of the PW. Investigation on a larger

    number of samples could provide further support to this hypothesis.

    Fig. 8. Hierarchical Cluster Analysis of potsherds and clayey materials.

    Table 4

    Evaluation of ring temperatures after SEM observation.

    Sample Clay

    type

    Residual/newly

    formed phases

    Atmosphere Vitrication Temperature #C

    BW PVL 1 NC illite Ox NV

  • While the mineralogy of grains inferred the provenance of

    potsherds, the way those grains are arranged in the clay matrix

    highlighted important aspects of ceramic technology. The GSD

    curve of the pottery (Fig. 5) showed that ner particles (skeleton)

    are mainly composed of quartz, feldspars and sometimes micas,

    with a normal distribution due to the natural selection of grains

    during clayey sediment deposition (Boggs, 2009). A tail towards

    coarser grains turning to a bimodal distribution was observed as

    the volcanic content increases to about 18% (Fig.10a), modifying the

    samples with a skewed distribution and lower sorting (e.g. PVL 4) in

    samples with a bimodal GSD and higher sorting (e.g. PVL 15). The

    CW, RPW and BW samples (Fig. 10b) share the same ranges of

    volcanic content (from 8.64 to 25.51%) and sorting (from moder-

    ately to poorly sorted). However, the CW samples can be clearly

    distinguished due to a coarser grain size as showed by f median

    values that reach coarse sand grain sizes (f 0.75e0.25). More-

    over, median and mean logit (SF) values of the majority of the CW

    samples (Fig. 11a, b) attested slightly elongated particles (Am/

    AM ca. 1/2) in comparison with the other ceramic classes which

    vary from strongly elongated to circular shapes.

    Despite the presence of negative skewness (tail) and a bimodal

    distribution of grain size ascribable to different sources of grains

    during deposition of clays, all the data set (in particular the optical

    and image analyses) permits hypothesizing the addition of

    a selected volcanic temper to the clayey raw material in order to

    achieve the best technological performances of the pottery. The

    different amount of temper in a range not higher than 15%, does not

    affect the bulk chemical composition of the potsherds, as showed

    by XRF and HCA analyses (Figs. 6e8), in particular for themain low-

    CaO group (except for sample PVL 26). This accords well with Grifa

    et al. (2009b) and De Bonis (2011) that highlighted the slight

    chemical changes in ceramic replicas with up to 30% of volcanic

    temper addition.

    Another fundamental aspect concerning ceramic technology is

    the type and the properties of the clay raw materials used to

    handcraft such ceramic productions. They can be inferred by the

    chemical composition of the potsherds and the mineralogy of no-

    plastic inclusions. Such information could permit identifying the

    exploited source of the raw material or associate it to a specic

    Fig. 9. SEM micrographs of some analysed samples. a) No Vitrication (NV), sample PVL 1; b) Continuous Vitrication-ne bloating pores (CVFB), sample PVL 4; c) Vitrication (V),

    sample PVL 35; d) Continuous Vitrication-ne bloating pores (CVFB), sample PVL 41 e) Initial Vitrication (IV), sample PVL 16; f) Vitrication (V), sample PVL 37.

    Fig. 10. Diagrams showing the relationship between volcanic content and grain size

    parameters.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826 823

  • geological context (epivolcanic, marine or alluvial). The clays used

    to craft the pottery studied (with the exception of samples PVL 4, 5,

    6, 24, 25, 26 40 and 52) were characterized by low CaO and high

    SiO2, Al2O3, Ni and Cr. Moreover, quartz and feldspar were always

    recorded by the XRD and observed as ner skeleton particles by

    optical microscopy investigations. Some investigated clayey

    deposits (MLV1, GS1, and CSC1 e see Fig. 6 and Table 5) sensibly

    differ from the main chemical composition of the pottery thus

    permitting their exclusion as possible raw materials. Some other

    clay samples show minor discrepancies only in their major oxides

    content (BS1, BS2, SQ1, TRE1, PMV2, VEL1, SO1), which are not

    sufcient to exclude them as potential rawmaterials. As a matter of

    fact, only trace elements may likely provide information on the

    original clay materials used for the production of the potsherds.

    As far as the epivolcanic deposits are considered, SO1 displays

    lower Ni, Cr and higher Rb, Sr, Zr, Nb contents with respect to the

    ceramics. In general, both the epivolcanic deposits (SO1 and CSC1)

    did not evidence quartz grains among the ner particles, as they are

    the product of weakly to strongly undersaturated weathered

    pyroclastics. However, these epivolcanic deposits are nowadays

    used for traditional ceramic productions (De Bonis, 2011; De Bonis

    et al., 2012). Local workshops in Sorrento exploit the SO1 deposits

    to make refractory wood-oven bricks and a semi-traditional cook-

    ing ware production is present in northern Campania using Roc-

    camonna epivolcanic deposits (CSC1). The Varicolori clays (BS1,

    BS2 and GS1) also differ from the potsherds for their higher Sc, V, Cr

    and lower Ba contents.

    An overall similar chemical and mineralogical composition with

    the local pottery was observed for some alluvial (PMV2 and VEL1)

    and marine deposits (SQ1 and TRE1). It should be noted that the

    presence of alluvial type deposits from the Sarno River plain was

    recognized in the area. In fact, the geomorphological setting of the

    Vesuvius area was profoundly different from its current setting and

    the pre-79 AD paleo-environmental reconstruction (Vogel and

    Marker, 2011 and references therein) have evidenced large

    uvial/lacustrine deposits partially covered by the 79 AD products

    and by those of the following volcanic activities (e.g. 472 AD Pollena

    eruption). The above reported data permits hypothesizing that

    alluvial deposits are the most likely raw materials.

    The whole data set evidenced a close relationship of the clay

    type and temper (grain size, sorting and abundance of volcanic

    inclusions) with the ceramic classes, which accounts for the precise

    protocols, the material culture of the potters, followed in Pompeii

    Late Roman workshops to produce table and cooking ware. Such

    protocols also included the nal transformation process of raw

    material and the ring process. On this account, the tableware

    production attested different ring temperatures, showing lower

    values for the BW rather than the RPW samples. Moreover, within

    the RPW ceramic class, two different groups e group 1 red at

    slightly higher temperatures than group 2 (>950# and 850e950 #C

    respectively) e can be distinguished based on their sintering

    structures and illite content. A well-developed pore system along

    with diffused Ca-pyroxene formation in the PW CaO-rich samples

    account for ring temperatures close to 1000 #C as veried for the

    same Phlegraean production from Cuma (Grifa et al., 2009a).

    Finally, as expected, CW shards experienced low ring treatments,

    mainly ranging from 800# to 850 #C in order to minimize the

    thermal shocks, thus preventing damage of the potsherds during

    food cooking.

    7. Conclusions

    The whole archaeological and archaeometric data set on pottery

    from the Via Lepanto site permitted identifying the production area

    of the cooking ware and part of the ne ware in the Vesuvius

    district, contributing to outline some important social and

    economic aspects of this region between IV and V century AD,

    when new settlements most probably formed (Soricelli, 2001).

    First of all, it should be remarked that archaeologists, due to the

    occurrence of African Red Slip Ware, dated the occupancy of this

    rural settlement not later than the second half of the II century AD,

    thus contradicting the historical sources that hypothesized a later

    reoccupation of these lands (not before the III century AD). This

    present research conrms the archaeological data on the basis of

    the analytical investigation carried out on the potsherds of the Via

    Lepanto site and the relative raw materials, bearing witness not

    only to the activity of a rural settlement immediately before its

    abandonment (472 AD) but also to the local production of these

    potteries. The technology applied in the workshops followed

    accurate choices in terms of raw materials, temper and ring

    temperatures in order to produce performing pottery.

    The most relevant aspects pointed out by the present research

    are briey summarized as follows:

    -) with regards to the ne ware, it is possible to hypothesize

    a Vesuvius provenance of the BW pottery and a Phlegraean

    origin for 4 samples of the PW out of 5. Mineralogical and

    petrochemical data on one sample permitted hypothesizing

    a local production of the PW pottery. The PW samples account for

    medium-distance exchanges (approximately at a distance of

    40 km from Pompeii) as well documented in Cuma and Miseno

    (Grifa et al., 2005b, 2009a).

    -) The RPW pottery was also crafted in Vesuvian workshops. Two

    groups of fragments were distinguished and characterized by

    a common repertoire. The existence of two different technolog-

    ical protocols was inferred, one using low inclusions/high ring

    temperatures yielding a ne and very hard paste and a second

    Fig. 11. Diagrams showing the relationship between grain size parameters.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826824

  • using high inclusions/low ring temperatures with a coarse and

    softer paste. This information supported two hypotheses, the

    presence of different workshops acting in the area, or the

    parallel circulation of a low quality (group 1) along with a higher

    quality (group 2) production, which only share typological

    characters (shape and red decoration). The quality of the table-

    ware was enhanced by selecting the raw materials and choosing

    specic ring temperatures with consequent longer

    manufacturing times and higher fuel consumption, thus inu-

    encing the nal cost of the pottery.

    -) Most of the CW samples also accounts for a production from

    Pompeian workshops set in a local circuit of distribution (Bay of

    Naples) as well as medium to long-distance exchanges (e.g.

    Apenninic contexts).

    -) Some samples of the CW such as PVL 23, 24 and 25 (likely

    Apennine production) and PVL 52 (Pantellerian Ware) along

    with African Red Slip Ware, Oriental and Iberian Amphorae (not

    included in this study) inferred long-distance exchanges.

    It is possible to hypothesize that the Via Lepanto site was part of

    a well-developed exchange network and included in a periodic e

    high frequency system of market (the nundinae), as supported by

    epigraphic documents of the Northern Campania/Southern Lazio

    region (Storchi Marino, 2000). The pottery, locally produced or

    imported, was individually distributed in this network market. In

    addition to these important aspects concerning the economic

    activities and human relationships of the inhabitants of this Late

    Roman site, this research also sheds new light on the technological

    ability of the workers, who exploited local low-CaO alluvial clayey

    deposits, mixed with selected volcanic grains (probably beach

    sands, Morra et al., 2012), red at different temperatures, in order

    to enhance the thermal or shock resistance of the potshards.

    Acknowledgements

    This research was funded by a Dipartimento di Scienze della

    Terra (Universit Federico II di Napoli) grant (VM). The authors are

    grateful to Germana Barone and three anonymous referees whose

    suggestions considerably improved the paper. The authors also

    thank Antonietta Longo for the last revision of the manuscript. The

    authors would like to thank Leone Melluso and Vincenzo Monetti

    for the XRF analyses, Stefano M. Pagnotta for his useful discussions

    and support on statistics and Antonio Canzanella for the SEM

    analyses. The authors kindly thank dr. E. de Carolis and Soprin-

    tendenza Speciale per i Beni Archeologici di Napoli e Pompei.

    Appendix A. Supplementary data

    Supplementary data related to this article can be found at http://

    dx.doi.org/10.1016/j.jas.2012.08.043.

    References

    Alfano, L., 1992. Ceramica tardoantica e altomedievale. In: Peduto, P. (Ed.),S. Giovanni di Pratola Serra, Archeologia e storia nel ducato longobardo diBenevento. Laveglia Editore, Salerno, pp. 167e196.

    Annese, C., 2000. Le ceramiche tardoantiche della domus B. In: Volpe, G. (Ed.),Ordona X, Ricerche archeologiche a Herdonia (1993e1998). Edipuglia, Bari,pp. 285e342.

    Aoyagi, M., Mukai, T., Sugiyama, C., 2007. Cramique de lantiquit tardive dun siteromain de Somma Vesuviana, Italie. In: Bonifay, M., Trglia, J.-Chr (Eds.), LRCW2, Late Roman Coarse Wares, Cooking Wares and Amphorae in the Mediterra-nean: Archaeology and Archaeometry. BAR Int. Ser. 1662. Archaeopress, Oxford,pp. 439e449.

    Arthur, P., 1994. Ceramica comune tardo-antica e alto-medievale. In: Arthur, P. (Ed.),Il Complesso Archeologico di Carminiello ai Mannesi, Napoli (Scavi 1983e1984).Congedo Editore, Galatina, pp. 181e220.

    Aruga, R., 2003. The problem of multivariate classication of samples with radial (orV-shaped) chemical data. Talanta 60, 37e44.

    Azzalini, A., 2006. R package sn: the skew-normal and skew-t distributions (version0.4e2). URL: http://azzalini.stat.unipd.it/SN.

    Azzalini, A., Genton, M.G., 2008. Robust likelihood methods based on the skew-tand related distributions. International Statistical Review 76, 106e129. http://dx.doi.org/10.1111/j.1751-5823.2007.00016.x.

    Barone, G., Belore, C.M., Mazzoleni, P., Pezzino, A., Viccaro, M., 2010. A volcanicinclusions based approach for provenance studies of archaeological ceramics:application to pottery from southern Italy. Journal of Archaeological Science 37,713e726.

    Boggs, S., 2009. Petrology of Sedimentary Rocks, second ed. Cambridge UniversityPress, Cambridge, England, 600 pp.

    Bonardi, G., Ciarcia, S., Di Nocera, S., Matano, F., Sgrosso, I., Torre, M., 2009. Cartadelle principali unit cinematiche dellAppennino meridionale. Nota illustrativa.Italian Journal of Geoscience 128, 47e60.

    Brocchini, D., Principe, C., Castradori, D., Laurenzi, M.A., Gorla, L., 2001. Quaternaryevolution of the southern sector of the Campanian Plain and early Somma-Vesuvius activity: insights from the Trecase I well. Mineralogy and Petrology73, 67e91.

    Carsana, V., 1994. Ceramica da cucina tardo antica e alto medievale. In: Arthur, P.(Ed.), Il Complesso Archeologico di Carminiello ai Mannesi, Napoli (Scavi 1983e1984). Congedo Editore, Galatina, pp. 221e258.

    Cavassa, L., 2009. La production de cramique commune Pompi. Un four depotier dans linsula 5 de la regio I. In: Les cramiques communes dItalie et deNarbonnaise. Napoli, 2, 3 novembre 2006. Centre Jean Brard, pp. 95e104.

    Cerulli Irelli, G., 1977. Una ofcina di lucerne ttili a Pompei. In: Linstrumentumdomesticum di Ercolano e Pompei nella prima et imperiale, Roma, 1977, pp.53e72.

    Cioni, R., Santacroce, R., Sbrana, A., 1999. Pyroclastic deposits as a guide forreconstructing the multi-stage evolution of the Somma-Vesuvius Caldera.Bulletin of Volcanology 61, 207e222.

    Conticelli, S., Melluso, L., Perini, G., Avanzinelli, R., Boari, E., 2004. Petrologic,geochemical and isotopic characteristics of potassic and ultrapotassic magma-tism in Central-Southern Italy: inferences on its genesis and in the nature ofmantle sources. Periodico di Mineralogia 73, 135e164.

    De Bonis, A., Grifa, C., Guarino, V., Langella, A., Morra, V., 2012. Argille campanequali materie prime di produzioni ceramiche archeologiche. In: Scienze Natu-rali e Archeologia. Il paesaggio antico: Interazione uomo/ambiente ed eventicatastroci. Museo Archeologico Nazionale di Napoli, 14e16 ottobre 2010.Roma, Aracne, ISBN 9788854835252, pp. 111e118. http://dx.doi.org/10.4399/978885483525220.

    De Bonis, A., 2011. Caratterizzazione mineralogico-petrograca di argille campanequali materie prime per produzioni ceramiche dinteresse archeologico.Unpublished PhD Thesis (XXIII ciclo), Universit degli Studi di Catania, 229 pp.

    De Bonis, A., Grifa, C., Langella, A., Mercurio, M., Perrone, M.L., Morra, V., 2010.Archaeometric study of roman pottery from Caudium area (Southern Italy).Periodico di Mineralogia 79, 73e89.

    De Carolis, E., Soricelli, G., 2005. Il sito di via Lepanto a Pompei: brevi note sulTardoantico in area vesuviana. In: Volpe, G., Turchiano, M. (Eds.), Paesaggi einsediamenti rurali in Italia Meridionale fra Tardoantico e Altomedioevo. Edi-puglia, Bari, pp. 513e527.

    De Carolis, E., Grifa, C., Langella, A., Morra, V., Soricelli, G., 2009. Ceramiche tardoantiche da Pompei. In: Les cramiques communes dItalie et de Narbonnaise.Napoli, 2, 3 novembre 2006. Centre Jean Brard, pp. 651e671.

    Di Giuseppe, H., 1998. La fornace di Calle di Tricarico: produzione e diffusione. In:Sagu, L. (Ed.), Ceramica in Italia: VIeVII secolo. Edigiglio, Firenze, pp. 735e752.

    Di Vito, M., Sulpizio, R., Zanchetta, G., Calderoni, G., 1998. The geology of the SouthWestern slopes of Somma-Vesuvius, Italy, as inferred by borehole stratigraphiesand cores. Acta Vulcanologica 10 (2), 383e393.

    Duchi, V., Minissale, A., Vaselli, O., Ancillotti, M., 1995. Hydrogeochemistry of theCampania region in southern Italy. Journal of Volcanology and GeothermalResearch 67 (4), 313e328.

    Fabbri, B., Guarini, G., Arduino, E., Coghe, M., 1994. Signicato del fosforo nei reperticeramici di scavo. In: Proceedings of the 1st European Workshop on Archaeo-logical Ceramics, Roma. 10e12 Ottobre 1991, pp. 183e192.

    Fedele, L., Scarpati, C., Lanphere, M., Melluso, L., Morra, V., Perrotta, A., Ricci, G.,2008. The Breccia Museo formation, Campi Flegrei, southern Italy: geochro-nology, chemostratigraphy and relationship with the Campanian Ignimbriteeruption. Bulletin of Volcanology 70, 1189e1219.

    Fiorillo, R., 2003. La ceramica della plebs di S. Maria di Rota a Mercato S. Severino(Sa): simbolismo bizantino e tradizione longobarda nella produzione campanaaltomedievale. In: Atti del III Congresso Nazionale di Archeologia Medievale.Firenze, pp. 127e134.

    Folk, R.L., 1974. Petrology of Sedimentary Rocks: Austin. Hemphill PublishingCompany, Texas, 182 pp.

    Gazzetti, A., 1976. From Tiberius to the Antonines: a History of the Roman Empirefrom AD 12-192. Methuen & Co. Ltd., London, 876 pp.

    Grifa, C., Langella, A., Morra, V., Soricelli, G., 2005a. Pantellerian ware from Miseno(Phlegraean elds, Naples). Periodico di Mineralogia 74 (1), 69e86.

    Grifa, C., Langella, A., Morra, V., Munzi, P., De Rossi, G., 2005b. Studio archeometricosu ceramica altomedievale proveniente dai Campi Flegrei (Napoli). Atti delCongresso AIAR 2005, Caserta, pp. 269e282.

    Grifa, C., Morra, V., Langella, A., Cultrone, G., Sebastn, E., 2006. Technologicalfeatures of glazed Protomajolica ware from Benevento (Italy). In: Fort, R.,

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826 825

  • Alvarez de Buergo, M., Gomez Heras, M., Vasquez-Calvo, C. (Eds.), Heritage,Weathering and Conservation. Taylor & Francis/Balkema, pp. 123e135.

    Grifa, C., Morra, V., Langella, A., Munzi, P., 2009a. Byzantine ceramic productionfrom Cuma (Campi Flegrei, Napoli). Archaeometry 51 (1), 75e94.

    Grifa, C., Cultrone, G., Langella, A., Mercurio, M., De Bonis, A., Sebastin, E., Morra, V.,2009b. Ceramic replicas of archaeological ndings in Benevento area (Italy):petrophysical changes induced by different proportions of clays and temper.Applied Clay Science 46, 231e240.

    Grifa, C., Morra, V., 2009. La production de cramique commune Pompi. Studiopetrograco sui reperti ceramici. In: Les cramiques communes dItalie et deNarbonnaise. Napoli, 2, 3 novembre 2006. Centre Jean Brard, pp. 105e107.

    Gromet, L.P., Dymek, R.F., Haskin, L.A., Korotev, R.L., 1984. The North American shalecomposite: its compilation, major and trace element characteristics. Geo-chimica et Cosmochimica Acta 48, 2469e2482.

    Hall, M.E., 2004. Pottery production during the Late Jomon period: insights from thechemical analyses of Kasori B pottery. Journal of Archaeological Science 31,1439e1450.

    Krumbein, W.C., Sloss, L.L., 1963. Stratigraphy and Sedimentation, second ed.Freeman & Co, San Francisco, 660 pp.

    Lanphere, M., Champion, D., Melluso, M., Morra, V., Perrotta, A., Scarpati, C.,Tedesco, D., Calvert, A., 2007. 40Ar/39Ar ages of the AD 79 eruption of Vesuvius,Italy. Bulletin of Volcanology 69, 259e263.

    Livadie, C.A., 1994. Pontelatone (Caserta). Frazione Treglia. Localit Monte Castello.Fornace tardoarcaica. Bollettino diArcheologia, vol. 11e12. Ministero per i beni ele attivit culturali, Roma, pp. 149e151.

    Lupia, A., 1998. Testimonianze di epoca altomedievale a Benevento. Lo scavo delMuseo del Sannio. La Buona Stampa, Napoli.

    Maggetti, M., 2001. Chemical analyses of ancient ceramics: what for? Chimia 55,923e930.

    Maniatis, Y., Tite, M.S., 1981. Technological examination of Neolithic e Bronze agepottery from central and southeast Europe and from near East. Journal ofArchaeological Science 8, 59e76.

    Marturano, A., Aiello, G., Barra, D., Fedele, L., Grifa, C., Morra, V., Berg, R., Varone, A.,2009. Evidence for Holocenic uplift at Somma-Vesuvius. Journal of Volcanologyand Geothermal Research 184, 451e461.

    Melluso, L., Morra, V., Brotzu, P., Tommasini, S., Renna, M.R., Duncan, R.A.,Franciosi, L., DAmelio, F., 2005. Geochronology and petrogenesis of the Creta-ceous AntampombatoeAmbatovy complex and associated dyke swarm,Madagascar. Journal of Petrology 46, 1963e1996.

    Moore, D.M., Reynolds, R.C., 1997. X-ray Diffraction and the Identication andAnalysis of Clay Minerals. Oxford University Press, New York, 400 pp.

    Morra, V., De Bonis, A., Grifa, C., Langella, A., Cavassa, L., Piovesan, R., 2012. Minero-petrographic study of cooking ware and Pompeian Red Ware (Rosso Pompeiano)

    from Cuma (Southern Italy). Archaeometry. http://dx.doi.org/10.1111/j.1475-4745.2012.00710.x.

    Perrone, M.L., 2005. Dinamiche insediative e occupazione del territorio nella ValleCaudina (dalla preistoria allet tardo antica). Unpublished PhD thesis, SecondaUniversit di Napoli, 205 pp.

    Prakongkep, N., Suddhiprakarn, A., Kheoruenromne, I., Gilkes, R.J., 2010. SEM imageanalysis for characterization of sand grains in Thai paddy soils. Geoderma 156,20e31.

    R Development Team, 2005. R: a Language and Environment for StatisticalComputing. R. Version 1.1.0 for Mac. http://microarrays.unife.it/CRAN/.

    Santacroce, R., Cioni, R., Marianelli, P., Sbrana, A., Sulpizio, R., Zanchetta, G.,Donahue, D.J., Joron, J.L., 2008. Age and whole rockeglass compositions ofproximal pyroclastics from the major explosive eruptions of Somma-Vesuvius:a review as a tool for distal tephrostratigraphy. Journal of Volcanology andGeothermal Research 177, 1e18.

    Shepherd, W.R., 1911. Reference Map of Ancient Italy, Southern Part. Historical Atlas.Henry Holt and Company, New York, 257 pp.

    Secco, M., Maritan, L., Mazzoli, C., Lampronti, G.I., Zorzi, F., Nodari, L., Russo, U.,Mattioli, S.P., 2011. Alteration processes of pottery in lagoon-like environments.Archaeometry 53, 809e829.

    Soricelli, G., 2000. Il materiale ceramico. Ceramica ne da mensa, lucerne, ceramicada fuoco. In: Miniero, P. (Ed.), Il sacello degli Augustali di Miseno. MondadoriElecta, Napoli, pp. 63e74.

    Soricelli, G., 2001. La regione vesuviana tra secondo e sesto secolo d.C. In: LoCascio, E., Storchi Marino, A. (Eds.), Modalit insediative e strutture agrarienellItalia meridionale in et romana. Edipuglia, Bari, pp. 455e472.

    Soricelli, G., 2002. Divisioni agrarie romane e occupazione del territorio nella piananocerino-sarnese. In: Franciosi, G. (Ed.), Ager Campanus. Jovene Editore, Napoli,pp. 123e129.

    Storchi Marino, A., 2000. Reti interregionali integrate e circuiti di mercato periodiconegli indices nundinarii del Lazio e della Campania. In: Lo Cascio, E. (Ed.),Mercati permanenti e mercati periodici nel mondo romano. Atti degli IncontriCapresi di Storia dellEconomia Antica (Capri 13e15 ottobre 1997). Bari,Edipuglia, pp. 93e130.

    Vogel, S., Mrker, M., 2011. Characterization of the pre-AD 79 Roman paleosol southof Pompeii (Italy): correlation between soil parameter values and paleo-topography. Geoderma 160, 548e558.

    Whitehouse, D., 1966. Medieval painted pottery in South and Central Italy. MedievalArchaeology 10, 30e44.

    Williams, J., LL., W., Levi, S., 2008. The Ausonian Pottery of Lipari (Aeolian Islands,Sicily), A typological and petrological assessment. In: Proceedings of thePrehistoric Society, vol. 74. University Museum of Archaeology and Ethnology,Prehistoric Society, London, England, pp. 141e170.

    C. Grifa et al. / Journal of Archaeological Science 40 (2013) 810e826826