8. Renewable Energy - Biomass

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    Renewable energy – biomass

    Prepared by

    Wan, Man Pun

     Assistant Professor

    School of Mechanical & Aerospace Engineering

    MA0100  – Environmental Sustainability

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    Biomass

     All non-fossil material of biological originSolar energy, converted to chemical energy by photosynthesis, is stored

    in a variety of organic materials (biomass)World primary energy supply, 1971 - 2010

    *Other includes wind, solar, geothermal, etc.

    [IEA, 2012]

       M   i   l   l   i  o  n   t  o  n  o   i   l  e  q  u   i  v  a   l  e  n   t   (   M   t  o  e   )

     10%

    2

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    Biomass

    Global carbon cycle 

    [earthobservatory.nasa.gov]3

    Global fast carbon cycle (in Gt/year)

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    Biomass resources

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    Metabolic pathways for carbon fixation in photosynthesis

    C3 system  Produces

    3-carbon organic acid (3-phosphoglyceric acid) from

    carbon fixation

    E.g., rice, wheat, potato,

    etc.

    represents 95% of Earth’s plant

    biomass.Most common in temperate and cold

    climate.

    Utilizes 15 –30 mg CO2/dm2/h with

    light saturation already at 0.8 –2.4

    J/cm2/min

    C4 system Produces 4-carbon organicacids (malate

    and aspartate) from carbon

    fixation

    E.g., sugarcane, maize, etc.

    represents 3% of Earth’s plant

    biomass.

    More common in warm climate.

    Utilizes 70 –100 mg CO2/dm2/h with

    light saturation around 4.2 –5.9

    J/cm2/min

    CAM

    (Crasulacean

     Acid

    Metabolism)

    system

    Produces 4-carbon organic

    acids (malate

    and aspartate) from carbon

    fixation

    E.g., pineapple, sisal, etc.

    Can capture light during the day and

    later fix the CO2 during the night

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    Biomass resources

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    Wastes from crops used primarily for food

    [http://www.wikipedia.com]

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    Energy cropPlants that are low cost and low maintenance to grow and harvest, and

    have high energy content.

    Solid biomass

    High-yield crop species burnt to generate power

    Biomass resources

    Poplar

    Elephant grass

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    Energy crop

    Gas biomassEnergy crops used for production of biogas in anaerobic digesters.

    E.g., maize, wheat, carrot, cabbage, cauliflower, etc.

    Bio-diesel

    E.g. copra, oilseed rape, sunflower, soya, peanut, mustard seed, etc.

    Bio-ethanol

    E.g. switchgrass, maize, sugarcane

    Biomass resources

    Copra (coconut kernel)

    Sugarcane

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     Animal wasteBiogas production from animal

    waste

     AlgaePhotosynthetic organisms that

    span length scales from just a

    few microns up to 50 m 

    Biomass resources

    [http://international.bio-energie.de]

    Kelp (macroalgae)Chlorella (single-cell microalgae)

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    Biomass

    Biomass composition

    Can be > 50% Ultimate

    analysisProximate

    analysis

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    Biomass energy technologies:

    - Firing and co-firing

    - Gasification/pyrolysis

    - Fermentation

    - Production of other fuels

    Biomass energy utilization

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    Biomass combustion

    Firing and co-firing

    Fuel Net Calorific

    Value by mass(MJ/kg)

    Adiabatic flame

    temperature(oC)

    Wood chips (30% MC) 12.5 530-840

    Wood pellet (10% MC) 16.4 1,140

    Grass (18% MC) 13.7 1,020

    Straw (15% MC) 14.5 1,065

     Anthracite 33.0 2,180

    Heating oil 42.5 2,100

    Propane gas 46.1 2,392

    MC – moisture content

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    Biomass as fuel for domestic cooking and heating

    Firing and co-firing

    Wood as fuel for cooking and heating Dung as fuel for cooking

    Yak dung being dried

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    Common types of modern furnace

    Firing and co-firing

    [http://www.rath-group.com]

    [https://reader010.{domain}/reader010/html5/0603/5b141052861c1/5b14105ab106b.jpg]

    [http://www.canadianbiomassmagazine.ca/images/

    stories/2009/June-2009/WellonsCombustorCellProcess.jpg]

    Fixed-bedfurnace

    Fluidized-bed furnace

    Cyclone furnace

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    Common types of modern furnace

    Firing and co-firing

    [http://www.sciencedirect.com]

    Sloping-grate furnace

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    Gasification processes1. Dehydration – removal of moisture content at about 100oC

    2. Pyrolysis – release of volatile content and formation of char. 200 – 

    300oC

    3. Combustion – combustion of volatile content and some of the char

    with the addition of oxygen to provide energy for the subsequent

    gasification process. Carbon dioxide (CO2) formed.

    4. Gasification – char reacts with carbon and steam (from step 1) to

    form carbon monoxide (CO) and hydrogen (H2)

    5. Further reactions occur when the formed CO and residual waterfrom the organic material react to form methane (CH4) and excess

    CO2

    Gasification/pyrolysis

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    Wood gas

    Net calorific value: 5.7 MJ/kg

    Gasification/pyrolysis

    Element % by volume

    Nitrogen 50.9

    Carbon monoxide 27.0

    Hydrogen 14.0

    Methane 3.0

    Carbon dioxide 4.5

    Oxygen 0.6

    Car ran on wood gas during WWII

    Car with a wood gasifier in its trailer

    [http://www.drboblog.com/wp-

    content/uploads/2013/01/mr-fusion-back-to-the-future.jpg]

    Remind you this?

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    Fermentation of sugar Anaerobic (process conducted under the absence of oxygen)

    degradation of sugars (glucose, sucrose and fructose) by yeast with

    ethanol and carbon dioxide as by products.

    FeedstockSugarcane, sugar beet

    Starchy plants: potato, corn, cassava

    Fermentation

    Fermenting sugar[http://www.hitachizosen.co.jp]

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    Commercialized ethanol fuel mixtures

    Fermentation

    Major bio-ethanol producers

    [http://www.wikipedia.org]

    [Asia Biomass Office]

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    Biodiesel production process

    Biodiesel

    [http://teenbiotechchallenge.ucdavis.edu]

    Crop Liter/Ha/yearPalm 5238

    Jatropha 1684

    Castor 1216

    Canola 1076

    Sunflower 842

    Soybean 561

    Crops for biodiesel production

    and potential annual production

    Palm treesJatropha

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    Biodiesel net calorific values

    Biodiesel

    Diesel type Net calorific

    value (MJ/kg)

    No.2 diesel (petroleum diesel) 42.5

    B2 blend biodiesel

    (2% biodiesel, 98% petroleum diesel)

    42.3

    B20 blend biodiesel

    (20% biodiesel, 80% petroleum diesel)

    41.4

    Biodiesel (B100) 37.5

    Light-blend

    No / minor

    modification to

    equipment

    needed

    Equipment

    modifications using

    biodiesel-

    compatible

    materials

    Gas station providing ethanol fuel and biodiesel

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    Major biodiesel producers

    Biodiesel

    [Asia Biomass Office]

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    End

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