7 HAZARDS Control

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    H AZARD S CO N TRO L

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    3.1 Health Hazards

    ~1) Health Hazards of Liquied Gases

    are their toxicity , oxygen deciencyand low temperatures.

    ~) !odes "y which Liquied Gascargoes and their #apours may "etoxic.

    ~$) %oxic properties of &nhi"itors.

    ~') %oxic properties of &nert Gas.

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    ~() How com"ustion of argo productsor construction materials mayproduce toxic products.

    ~*) +cute and hronic eects oftoxicity , systematic poisons andirritants.

    ~-) Lists and descri"es the criteria "ywhich toxicity is measured andexpressed.

    ~) +sphyxia and it/s symptoms.

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    ~12) 3rost 4ite and it/s symptoms.

    ~11) hemical 4urns and lists cargoes

    caustic to human s5in.~1) &nformation gi#en in the 6Health

    7ata olumn8 of the &9 argo 7ata9heet.

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    3.2 First Aid Treatment

    ~3irst +id :rocedures for accidents

    in#ol#ingargo are gi#en in the cargo data

    sheets.

    ~Liquied Gas tan5ers carrying toxiccargoes should ha#e medical rst aidequipment for accidents in#ol#ingthose cargoes on "oard.

    ~%his equipment includes oxygen

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    ~!aster or ;esponsi"le o

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    ~&!> Medical First Aid Guide for use inaccidents involving dangerousgoods(MFAG) gi#es informationregarding medical treatment.

    ~!3+G gi#es detailed informationa"out signs and symptoms ,rst aid

    and the administering the antidotes.

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    ;eacti#ity

    ~1) Liquied Gas cargo may react in a

    num"er of ways,such as ? @ with itself

    @ with air

    @ with water @ with another cargo

    @ with other materials

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    ~) 9elf ;eaction and list of Gas cargoesthat may self react .

    ~ $) :recautions against self reaction.

    ~') ;eaction with air and list of gascargoes that may react with air.

    ~() :recautions against reaction with air.

    ~*) ;eactions with water and list of gascargoes that may react with water.

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    ~ -) ommon precautions againstreaction with water.

    ~) argo ompati"ility and list ofgas cargoes that are incompati"le.

    ~0) :recautions against mixing ofincompati"le cargoes.

    ~12) 9ome Gas cargoes may reactwith materials and su"stance such as?

    @ tan5 material

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    @ gas5ets

    @ cargo hoses

    @ inert gas @ cargo compressor oils

    @ cargo pump seal oil

    ~ 11) :recautions against reactionslisted a"o#e.

    ~1) ;eacti#ity data for each liquied

    gas cargo are gi#en in &9 cargo datasheet .

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    3.4 Flammability and explosionhazards

    ~1) !ost Liquied gas cargoes areAamma"le.

    ~) &t is not liquids, "ut #apoursemitted from them , that "urn.

    ~$) Liquied Gas cargoes are carriedat or close to their "oiling point andgi#e o #apours readily.

    ~') 3lamma"le #apours can ignite and

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    ~() ertain cargo #apours can "urnand, if ignited, without "eing mixedwith air.

    ~*) 7enition of 63lashpoint8 anddescri"e ways of determining it.

    ~-) 7enition of 6+uto &gnition%emperature8.

    ~) om"ustion is a chemical reactionand descri"es the process of "urning

    of hydrocar"ons.

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    ~12) 3lamma"le range will "e dierentfor dierent cargoes.

    ~11) 3lamma"ility hart~1) the eect of increasing or

    decreasing the proportion of oxygenon the Aamma"le limits.

    ~1$) 3ire and explosion data for eachliquied gas cargo are gi#en in the&9 cargo data sheets.

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    3.5 Repairs and Hot Wor

    ~1) Do hot wor5 can "e carried out

    unless a Epermit to wor5/ is issued.~) hot wor5 includes the use of power

    tools.