5 Underwood Court, Delran, New Jersey 08075-1229 609-461 … · 2019-12-16 · This report provides...

5 Underwood Court, Delran, New Jersey 08075-1229609-461-4003 • 215-238-0338 • Fax 609-461-4916

ITE ASSESSMENT/TECHNICAL ASSISTANCE EPA CONTRACT 68-S5-3002

9 February 1996

Mr. Patrick McManus (3HW21) ," TDD No. 9601-96Remedial Project Manager DCN B0000032U.S. Environmental Protection Agency841 Chestnut BuildingPhiladelphia, PA 19107

Subject: North Penn Area 12 Site - Trip Report

Dear Mr. McManus:

Enclosed is the North Penn Area 12 Site Trip Report for your review. Please feel free tocontact me at (215) 238-0338 Ext. 265 regarding any aspect of this repojrt.

Very truly yours.ROY F. WESTON. INC.

/' r

Colleen E. DuffySite Lead

Attachments (#1 and #2)

cc: TDD File (with attachments)

y F. Weston, Inc.FEDERAL PROGRAMS DIVISION J.In Association with Foster Wheeler Eaviresponse, Inc., Resource Applications, Inc., C.C, Johnson & Malhotra, P.C., andPRC Environmental Management. Inc. I

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYRegion III

841 Chestnut BuildingPhiladelphia, Pennsylvania 19107

FAX TRANSMITTAL

PAGE I OF__2_

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FAX NUMBER: 2 15-597- ^ f f/)

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T R I P R E P O R T

North Perm Area 12 Site TDD #9601-96Worcester Township, Montgomery County, PA__________Contract # 68-S5-3002

1.0 INTRODUCTION______________________________________

In December 1995, the Roy F. Weston (WESTON®), Site Assessment TechnicalAssistance (SATA) team was directed by the U.S. Environmental Protection Agency(EPA) Remedial Project Manager (RPM) Patrick McManus to conduct a sampling eventat the North Perm Area 12 Site located in Worcester Township, Montgomery County,Pennsylvania.

2.0 BACKGROUND______________________________________._

2.1 Site Description

North Perm Area 12 Site on Trooper Road, Worcester Township, Montgomery County,Pennsylvania is the location of a manufacturing facility for DC motors andsynchroelectric motors. The site occupies approximately 50 acres and is situated in aresidential area as illustrated on the Site Location Map (Figure 1).

2.2 Regulatory History

In 1979, the Pennsylvania Department of Environmental Resources (PADER) conducted amulti-media sampling event at the site. Elevated levels of trichloroethane (TCA) andtrichloroethene (TCE ) were found hi the ground water. Other organic chemicals ofconcern were freon-113,1,1-dichloroethene, vinyl chloride, and bis(2 ethylhexyl)phthalate. Inorganic chemicals found in elevated levels on site included arsenic andberyllium. Since 1987, the North Perm Area 12 Site has been operated by Transicoil,Inc., a subsidiary of Eagle-Picher Industries. In 1987, the site was proposed for theNational Priorities List (NPL). By 1989, the potentially responsible parties wereinvolved in the EPA investigation of the environmental issues on site. The site was listedon the NPL in 1991 when Eagle-Picher declared bankruptcy. Presently, the site is thesubject of an ongoing Remedial Investigation/Feasibility Study (RI/FS).

3.0 SITE ACTIVITIES_____________________________________

• On 28 December 1995, an EPA sampling activity was initiated to collect backgroundsamples to supplement samples previously collected on site by CH2M Hill. The objectiveof the sampling event was to document background levels of beryllium, manganese, andarsenic in the soil surrounding the North Perm Area 12 Site. The on-site personnel wereS AT A team members CoHeen Duffy, Chris Taylor, and Ken Woodlin.

A R O O I 8 1 3

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North Perm Area 12 SiteWorcester, Montgomery Co., PA

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TDD#: 9601-96iS/ C M. OrWi IPCb #: 096

North Penn Area 12 Site

: JC 19 ? IMxinnu Klappiny

Acale 1:125,000 (at center) Site cation Map

Figure 1

RBO.018

North Penn Area 12 Site TDD#9601-96Worcester Township, Montgomery County, PA__________Contract # 68-S5-3002

3.1 Site Conditions

The North Penn Area 12 Site is in a relatively flat area with small rolling hills. The soil inthe area is predominantly silt loam and loam according to the Soil Conservation Service'sSoil Survey of Montgomery County, PA.

3.2 Meteorological Conditions

The ambient meteorological conditions during the 28 December 1995 soil sampling activityare summarized below:

Temperature 30 ° FWinds 20 mph from the northwest

Conditions Clear skies, cold, snow covered groundHumidity 15%

Sampling Time 1045-1350 hours

3.3 Sampling Activities

During the 28 December soil sampling activity, SAT A collected ten soil samples and onerinsate blank, which were analyzed for beryllium, manganese, and arsenic. All sampleswere collected off site with the permission of the Worcester Township officials and theprivate property owners. At the RPM's request, samples were collected off site from soiltypes that matched soil types onsite. Sample locations are identified in the Sample LocationMap (Figure 2). Samples were extracted from the ground and placed in ziplock freezerbacks to thaw overnight. Samples were homogenized and placed hi sample jars thefollowing day. All samples were handled and packaged in accordance with the samplingplan and were shipped via Federal Express to Pace, Inc. in Minneapolis, Minnesota foranalysis.

4.0 REPORT OF RESULTS________________________________

The results of the sampling event and the QA/QC of the data are included in the DataQuality Report (Attachment 1) and the Analytical Data Package (Attachment 2),

A summary of the analytical results is provided in the following Data Summary Table.

A R O O I 8 1 5

PROGRAMS iM^n, A ioc-* i TDD #: 9601-96North Penn Area 12 SiteWorcester, Montgomery Co., PA

2938 HICKORY HILI.ROAD j

^VARIETY CUJBCAMP i

NORTH PENS AREA 12 SITE

343

Scale 1:15,625 (at center) c , T ,. x._ ' v ' Sample Location Map

Figure 2

A R O O I 8 I 6

North Penn Area 12 Site TDD#9601-96Worcester Township, Montgomery County, PA__________Contract # 68-55-3002

DATA SUMMARY TABLE

SampleLocation1AIB2A2B3A•3B4A4B5A5BRBRBC*

Arsenicmg/kg

6.35.08.38.57.97.88.75.58.613.15.0 ug/1 U23 N0.43 C

Berylliummg/kg

1.30.82 B1.71.2 B0.84 B0.74 B0.96 B0.99 B1.1 B0.90 B1.0 ug/1 U0.15 C

Manganesemg/kg

1440474148077346614899453512103353.2 ug/1 B390 N

Depth

0-6 inches>2 feet0-6 inches>2 feet0-6 inches>2 feet0-6 inches>2 feet0-6 inches>2 feet- - -_ _ _

Time

10451145122012301240125013051315134013501150_ — —

Soil Type ^

ReB2ReB2LeB2LeB2LaB3LaB3LdB2LdB2ReAReA_ _ _-. — _

RB Rinsate BlankRBC Risk-Based Concentrations •

Information obtained from the Risk-Based Concentrations Table, July- December 1995, from RoyL. Smith, Ph.D., Office of RCRA, Technical and Program Support Branch, EPA. The valuesused are the RBC for residential soil ingestion.

N Non-CarcinogenC CarcinogenB Qualifier - Indicates the value is below the quantitative value, but above the detection limits of

the instrument.U Qualifier - UndetectedReA* Reddington Silt LoamReB2* Reddington Silt LoamLeB2* Lawrenceville Silt LoamLaB3* Lansdale LoamLdB2* Lansdale Silt Loam

* Soil Survey of Montgomery County, Pennsylvania, Soil Conservation Service

5.0 FUTURE ACTIONS/ RECOMMENDATIONS

No future actions involving the SATA team are anticipated at this time.

RR001817

ATTACHMENT 1

ARQOI8I-8

5 Underwood Court, Delran, New Jersey 08075-1229K9QffiSCCK5aT'ms 609-4614003 • 215-238-0338 • Fax 609461-4916

SITE ASSESSMENT/TECHNICAL ASSISTANCE EPA CONTRACT 68-S5-3002

19 January 1996

Mr. Patrick Me Manus (3HW21) TDD No. 9512-26Removal Project Manager DCN No. B0000012U.S. Environmental Protection Agency841 Chestnut BuildingPhiladelphia, PA 19107

Subject: North Perm Area 12 Sampling Data Quality Report

Dear Mr. Me Manus:

Enclosed is the Data Quality Report for the North Perm Area 12 soil sampling. Please feelfree to call me at 238-0338 Ext. 243 should you want to discuss any aspect of this report.

Very truly yours,

ROY F. WESTON, INC.

Marian MurphyQuality Control Officer

cc: TDD File

Notrhpennl2dql

Roy F. Weston, Inc.FEDERAL PROGRAMS DIVISIONIn Association with Foster Wheeler Environmental, Inc., Resource Applications, Inc., C.C. Jqrjtv @ tjl Jojr -jP.C., andPRC Environmental Management, Inc.

DATA QUALITY REPORT

NORTH PENN AREA 12 TDD No. 9512-26WORCESTER, MONTGOMERY CO., PA_________EPA CONTRACT No. 68-S5-3002

1.0 INTRODUCTION

This report provides a general review of the data package submitted by PACE, Inc., hiMinneapolis, Minnesota, for ten soil samples and one rinsate blank collected at the NorthPenn Area 12 Site in Worcester, Montgomery County, Pennsylvania, on 28 December1995. The samples were received at PACE, Inc., on 3 January 1996. Thfe analysesrequested were beryllium, manganese and arsenic.

2.0 ANALYTICAL METHODOLOGY_____________________

The samples were analyzed for beryllium, manganese and arsenic by U.Sl EPA ContractLaboratory Program Statement of Work ILM03.0. The beryllium and manganese wereanalyzed by Inductively Coupled Plasma (ICP) and the arsenic was analyzed by trace ICP.

3.0 COMMENTS

3.1 Chain-of-Custody Records

Signed chain-of-custody records were received.

3.2 Metals

The hold times were met. The initial and continuing calibration datk met criteria. Nometals were detected in the method blanks or rinsate blank. The ICP serial dilutionand interference checks met criteria. The matrix spike recoveries and relative percentdifference values met criteria.

4.0 CONCLUSIONi

This data was reviewed hi accordance with "Quality Assurance/Quality Control Guidancefor Removal Activities", EPA540/6-90/004, April 1990. Accept all dataas presented.

northpenn!2dqr

1820

ATTACHMENT 2

AROOI82I

ENVIRONMENTAL LABORATORIES

January 12, 1996

Roy F. WestonInorganic Case NarrativeSDG#89 |

Enclosed are the analytical results representing the analysis of 10 soil saijiples and 1water sample received at Pace January 3, 1996. All samples were analyzed following theILMO3.0 Inorganic Statement of Work. Please note the following comments concerningthe sample analysis. j

CLP Metals

Holding Times

All samples were prepared and analyzed within CLP holding times

Instrument Calibrations

All instrument calibrations met CLP criteria prior to the analysis o

Initial and Continuing Calibration Verifications

samples.

All initial and continuing calibration verification standards were within specifiedcontrol limits.

Initial and Continuing Calibration Blanks— ————————————————————— , jii

All initial and continuing calibration blanks were within specified control limits.

Method Blanks

Method blank results were within specified control limits.

Laboratory Control Samples jiLaboratory control sample results were within specified control lirjnits.

Matrix Spikes

Matrix spike recoveries for sample 1A were within specified control limits with thefollowing exception:

1710 Douglas Drive NorthMinneapolis, MN 55422TEL: 612-544-5543FAX:612-525-3377 AR 00 I 822

An Equal Opportunity Employer

Roy F. WestonSDG# 89Page 2

The matrix spike recovery for manganese (240%) is above the 125% uppercontrol limit. Since the sample concentration exceeded the level of the spike b,yat least a factor of four, corrective action was not required.

Matrix Duplicates

Matrix duplicate results for sample 1A were within specified control limits.

Serial Dilution

Serial dilution results were within specified control limits.

"I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data has been authorized by thelaboratory manager or designee, as verified by the following signature."

Sincere

Jostfpln W. Novotny ~-' DateQuality Assurance OfficerPace Analytical Services, Inc.

RROOI823

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ENVIRONMENTAL LABORATORIES

Sample Condition upon Receipt\CE Project* l(gQ/°35E>& client: KJejJ^r,________Rec. By:

Proposal* __________Client Ref.: /"^ff£>_________Date Rec.:Method of Shipment/ Control* _____£-^ TTX / * '-*-<•'-''- *->-*<>Method of ShiprnervL Control* _____£*>-?* tOC ' _ OrrV09 *?2 ~J2J>————Custody Seals: l -jssjenr) / Absent xlntact"/ Broken ( hipping CoTitairfef / Sample Bottles

v _ X >>- _ " ^——————-——_____——-^Temperature of Blarn<s upon Arrival (If not 1.0 to 4.0 Deg. C. contactPM)Temperature of Blanfc; upon Arrival (If not LO to 4.0 Deg. C. contacTPM)Cooler ID:Temp. (Celsius):

rTemperature Blank not present, condition of coolant is:List Client Sample Descriptions for any samples that are frozen:

Yes No1 Short holding time analyses requested

Short Hold Analyses: ______

2 Sampled four or more days prior to receipt (If "yes", contact supervisor and PM Immediately)

Earliest date of sampling: / (r' iT- " I -^_____________________

3 Rush Due Date (one week Or less) requested (If "yes", contact supervisor and PM Immediately)

Requested Due Date: __________________________________

4 Sample Containers are intact:- ' (List Client Sample Description and container types)

5 Samples Correspond to Client Documentation. (Note Discrepancies below)

O ' 6 Samples are properly preserved. (See preservation record)

(— \\~) 7 VOA Samples are free Of head Space. (List Client Sample Description and containers with headspace)

3 8 Sample volume appears sufficient.

Container Labeling Requirements: 3 CLP icoc (Orange Rect.) Q AEC icoc (Green rect.)Q Return Sample to Client (Green Circle) Q Hazardous (Yellow Circle) Q NONE

Notify Project Manager immediately with any concerns regarding discrepancies (circle responses)Project Manager Review:_______________Date: ______ Comments:_____. ____ _______ ____

FOOB5 DOC f

ROY F WESTONCLP METALSSDG89

AROOI826

ENVIROFORMS/INORGANIC CLP

COVER PAGE - INORGANIC ANALYSES DATA PACKAGE

Lab Name: PACE, INCORPORATED Contract: WESTON

Lab Code: PACE Case No.: 1300 SAS No.: N/A SDG No.: XXXX89*,

SOW No.: 3/90

Sample No. Lab Sample ID.XXXX1A XXX892XXXX1AD " XXX892DXXXX1AS XXX892SXXXX1B XXX906XXXX2A XXX922XXXX2B XXX930XXXX3A XXX949XXXX3B XXX957XXXX4A ' XXX965XXXX4B XXX973XXXX5A ' XXX981XXXX5B XXX990XXXXRB . XXX914

Were ICP interelement corrections applied? Yes/No YES

Were ICP background corrections applied? Yes/No YESIf yes, were raw data generated beforeapplication of background corrections? Yes/No NO

Comments:

I certify that this data package is in compliance with the terms andconditions of the contract., both technically and for completeness, forother than the conditions detailed above. Release of the data containedin this hardcopy data package and in the computer-readable data submittedon floppy diskette has been authorized by the Laboratory Manager or theManager's designee, as verified by the following signature.

Signature: //(4<&3~ CX_ CX ^ jX___ Name: Uf$&>. A-

Date: l/(Uctb Title:

COVER PAGE - IN

RRQOI827

ENVIROFORMS/INORGANIC CLPSAMPLE NO.

1INORGANIC ANALYSIS DATA SHEET

Name: PACE, INCORPORATED Contract: WESTON

Lab Code: PACE Case No.: 1300 . SAS No.: N/A

XXXX1A

SDG No.: XXXX89

Matrix (soil/water) : SOIL Lab Sample ID: XXX892

Level (low/med): - LOW Date.Received: 01/03/96

% Solids: .75.8 ' •

Concentration Units (ug/L or mg/kg dry weight):MG/KG

GAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

'6.3

1.3

1440

C Q M

P.

P

!h- •iIPUik-i

Color Before: BROWN ' Clarity Before: Texture: MEDIUM

Color After: COLORLESS • Clarity After: : Artifacts: NOi

Comments:Comme:

FORM I - INAROOI828



j_,ab Name: PACE, INCORPORATED Contract: WESTONXXXX1B

Lab Code: PACE Case No.: 1300 • SAS No.: N/A SDG No.: XXXX89

Matrix (soil/water): SOIL . Lab Sample ID: XXX906

Level (low/med): LOW Date Received: 01/03/95

% Solids: 79.6

Concentration Units (ug/L or mg/kg dry weight): MG/KG

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

5.0

0.82

474

C

B

Q M

P

P

—

P

——

Color Before: BROWN Clarity Before: Texture: MEDIUM

Color After: COLORLESS Clarity After: Artifacts: NO

Comments: • •

FORM I - IN RROOI829



Name: PACE, INCORPORATED , Contract: WESTON

Lab Code: PACE Case No.: 1300 SAS No.: N/A

XXXXRB

SDG No.: XXXX89

Matrix (soil/water): WATER Lab Sample ID: XXX914

Level (low/med): LOW . Date Redeived: 01/03/96I

% Solids: 0.0 !'

Concentration Units (ug/L or mg/kg dry weight): UG/L

CAS ' No „

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMerquryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

5.0

1.0

3.2

C

U

u

B

Q M

PIP .

1

i

1

P!1

f-I -j .i

Color Before: COLORLESS ' • Clarity Before: CLEAR Texture:

Color After: COLORLESS . Clarity After: CLEAR Artifacts:

.ents:

FORM I - IN AHOOI 830


. 1INORGANIC ANALYSIS DATA SHEET

Lab Name: PACE, INCORPORATED Contract: WESTONXXXX2A

Lab Code: PACE Case No.: 1300 SAS No.: N/A SDG No.: XXXX89

Matrix (soil/water): SOIL . Lab Sample ID: XXX922


% Solids: 75.2

Concentration Units (ug/L or. mg/kg dry weight) : MG/KG

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

8.3

1.7

• 1480

C Q M

P

P

P

///>/<?&* Color Before: BROWN Clarity Before: Texture: -MEDIUM

^ /*\ t~* ** •** **"


C^Timents:

FORM I - IN



I XXXX2BName: PACE, INCORPORATED ' Contract: WESTONj _______

Lab Code: PACE • Case No.: 1300 SAS No.: N/A SDG No..: XXXX89

Matrix (soil/water): SOIL Lab Sample ID: XXX930!

Level (low/med): LOW Date Received: 01/03/96i

% Solids: 76.6 • ' -

• Concentration Units (ug/L or mg/kg dry weight): IMG/KG

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440.-62-27440-66-6

Analyte


Concentration

8.5

1.2

773

C

B

Q

i

M

i||P!

r~r-i

p—

r

i-

Color Before: BROWN Clarity Before: Texture: MEDIUMI

Color After: COLORLESS Clarity After: JArtif acts:. NO

ents:

FORM I - IN ARO.OI83I2



Lab Name: PACE, INCORPORATED ' Contract: WESTONXXXX3A


Matrix (soil/water): SOIL Lab Sample ID: XXX949


% Solids: 75.9


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

7.9

0.84

466

C

B

Q M

P

P

P

Color Before: BROWN Clarity Before: Texture: COARSE


Continents :

FORM i - IN AROOI833


.1INORGANIC ANALYSIS DATA SHEET

XXXX3Bb Name: PACE, INCORPORATED Contract: WESTON




% Solids: 80.3

SDG No.: XXXX89

Concentration Units (ug/L or mg/kg dry weight):

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

7.8

0 .74

148

C

B

Q M

P

P

P

MG/KG

Color Before: BROWN Clarity Before:

Color After: COLORLESS Clarity After:

Texture: COARSE

Artifacts: NO

Comments :

FORM I - INi

AR00183U


.1INORGANIC ANALYSIS DATA SHEET

uab Name: PACE, INCORPORATED Contract: WESTONXXXX4A




% Solids: 78.8


CAS No.

7429-90-57440-36-07440-38-2-7440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAnt imonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

8.7

0.96

994

C

B

—

Q M

P

P

P

, Color Before: BROWN . Clarity Before: Texture: COARSE


Comments:

FORM i - IN


1INORGANIC ANALYSIS,DATA SHEET

b Name: PACE, INCORPORATED Contract: WESTONji


XXXX4B

SDG No.i XXXX89



% Solids: 84.2 •


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-7 .7782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimony .ArsenicBariumBerylliumCadmiumCalcium •ChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide'

Concentration

5.5

0.99

535

C

B

Q M

P

P

IP

i

.Color Before: BROWN Clarity Before: Texture: COARSE


FORM I - IN AROOI836


1 ' 'INORGANIC ANALYSIS DATA SHEET

Lab Name: PACE, INCORPORATED Contract: WESTONXXXX5A


Matrix (soil/water): SOIL " Lab Sample ID: XXX981


% Solids: 75.7


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalcium •ChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concent rat ion

8.6

1.1

'1210

C

B

—

—

Q M

P

P

P

Color Before: BROWN Clarity Before: Texture: COARSE


Comments:

FORM I - INAROOI837

ENVIROFORMS/INORGANIC CLP| SAMPLE NO.


Name: PACE, INCORPORATED Contract: WESTON


XXXX5B

SDG No.: XXXX89

Matrix (soil/water): SOIL - Lab Sample ID: XXX990!


% Solids: 74.9 .

Concentration Units (ug/L or mg/kg dry weight):MG/KG

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

13.1

0.90 .

335

C

B

Q M

P

P

!' "

IP!

1

S

!_

Color Before: BROWN Clarity Before: Texture: MEDIUM


ents:

FORM I - IN AROOI838


2AINITIAL AND CONTINUING CALIBRATION VERIFICATION



Initial Calibration Source: INORG VENTUR

Continuing Calibration Source: INORG VENTUR

Concentration Units: ug/L

Analyte


Initial CalibrationTrue Found %R(1)

250.0

2500.0

253.33

2507.74

101.3

100.3'

Continuing CalibrationTrue Found %R(1) Found %R(1)

250.0

2500.0

255.45

2555.28

102.2

102.2

255.40

2546.98

102.2

101.9

M

P~

1——

—

P—

—

>

(1) Control Limits : Mercury 80-120; Other Metals 90-110; Cyanide 85-115

FORM II (PART 1) -- IN

AROOI839


2AINITIAL AND CONTINUING' CALIBRATION VERIFICATION






SDG No. : XXXX89

Analyte

AluminumAntimonyArsenicBariumBerylliumfctedmiumHalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverS.odiumThalliumVanadiumZincCyanide

Initial CalibrationTrue Found %R ( 1 )

>

Continuing CalibTrue Found %-R ( 1 )

250.0

2500.0

256.87

2564.40

102,7

102.6

rationFound %R ( 1 )

Ii!ii

1I!ii|!1i!

M

—

P

P~

—

—

—

1) Control Limits : Mercury 80-120; Other Metals 90-110; Cyanide 85-115

FORM II (PART 1) - IN

~ &RQQI8UQ


. 2AINITIAL AND CONTINUING CALIBRATION VERIFICATION






Analyte



2500.0 2521.98 100.9

Continuing CalibrationTrue Found %R(1) Found %R(1)

2500.0 2543 .72 101.7 2549.55 102.0

M

P_

I—

—

—

—

— - —

»

(1) Control Limits : Mercury 80-120; Other Metals 90-110; Cyanide 85-115

FORM II (PART 1) - IN'

RRQ018M

. ENVIROFORMS/INORGANIC CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: PACE, INCORPORATED . Contract: WESTON





SDG No.: XXXX89

Analyte

AluminumAntimonyArsenicBariumBerylliumhtedmium^alciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide


>

Continuing CalibTrue Found %R(1)

2500.0 2551.35 102.1

rationFound %R(1)

|

i

I1

M

P~

—

—

—

—

— •

—

—

—

i

1) Control Limits : Mercury 80-120; Other Metals 90-110; !cyanide 85-115


ARDOUR


2BCRDL STANDARD FOR AA AND ICP



AA CRDL Standard Source: INORG VENTUR

ICP CRDL Standard Source: INORG VENTUR


Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

CRDL St

True

;andard foi

Found

- AA

%R True

10.0

30.0

CRDL StarInitialFound

9.52

28.53

idard J

%R

95.2

95.1

:or ICPFounc

Found

9.76

29.02

1%R

Cn C

=«

96.7


RROOI8U3


2BCRDL STANDARD FOR AA AND ICP

Lab Name: PACE, INCORPORATED ' Contract: WESTON


AA CRDL Standard Source: INORG VENTUR

ICP CRDL Standard Source: INORG VENTUR ;


SDG No.: XXXX89

Analyte

AluminumAntimonyArsenicBariumBeryllium•tedmiumHklciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilver-SodiumThalliumVanadiumZinc

CRDL St

True

:andard foi

Found

: AA

%R True

20.0

CRDL StarInitialFound

21.38

idard

%R

106.

i

9

•or ICPFounc

Found

22.07

1%R

110.4


AROOI8H


.3BLANKS



Preparation Blank Matrix (soil/water): SOIL

Preparation Blank Concentration Units (ug/L or mg/kg): MG/KG

Analyte


InitialCalib.Blank(ug/L) C

1.0

2.0

U

U

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

1.0

2.0

U

U

1.0

2.0

U

U

1.0

2.0

U

U

Prepa-rationBlank C

1.000

0.200

0.400

U

U

U—

M

P

P~~

*

P

—

FORM III - IN

ftROO 181*5

ENVIROFORMS/INORGAN-IC CLP

3BLANKS


Lab Code: PACE - Case 'No.: 1300 SAS No.:NN/A

Preparation Blank Matrix (soil/water): WATER/

Preparation Blank Concentration Units (ug/L or mg/kg) : UG/lL

SDG No.: XXXX89

Analyte


InitialCalib.Blank(ug/L) C

5,0 U

Continuing CalibrationBlank (ug/L)

1 C. 2 C 3 C

5.0 U 5.0 U 5.0 U

—

Prepa-rationBlank C

1.0

1.0

'

2.0

U

U

U

M

P~~

P

P

FORM III - IN

AROOI8U6


4ICP INTERFERENCE CHECK SAMPLE


Lab Code: PACE ' Case No.: 1300 SAS No.: N/A SDG No.: XXXX89

ICP ID Number: ICP2Q1 ICS Source: INORG VENTUR


Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLead.MagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

TrueSol. Sol.A AB

500

500

Initial FoundSol. Sol.A AB %R

1

-10

450.7

451.9

90.1

90.4

Final FoundSol. Sol.A AB %R

1

-11

463 .3

463.9

92.7

————— 1

92.8

^

FORM IV - IN

AROOI8«4?


4ICP INTERFERENCE CHECK SAMPLE

Lab Name: PACE, INCORPORATED . . Contract: WESTON


ICP ID Number: ICP4Q1 ICS Source: INORG VENTUR


Analyte

AluminumAntimonyArsenicBariumBeryllium^admiumPcalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

True :Sol. Sol.A AB

*

Initial FoundSol. Sol.A AB %R

-2 -0.5

ESol.A

-4

inal FoundSol.AB %R

-1.9•

'

«

FORM IV - IN


5A ' SAMPLE NO.SPIKE SAMPLE RECOVERY

XXXX1ASLab Name: PACE, INCORPORATED Contract: WESTON


Matrix (soil/water): SOIL Level (low/med): LOW% Solids for Sample: 75.8


Analyte


ControlLimit%R

75-125

75-125

Spiked Sample, Result (SSR) C

527.8502

14.8654

1759.7810

*

—

SampleResult (SR) C

6.2901

1.2665

1443.3747

—

B

SpikeAdded (SA)

527.70

13.19

131.93

%R

98.8

103.1

239.8

Q

—

M

NRNRPNRPNRNRNRNRJ

1NR]NRPNRNRNRNRNRNRNRNRNRNR

Comments:

FORM V (PART 1) - INA.ROOI8U9


6DUPLICATES

SAMPLE NO.

XXXX1ADab Name: PACE, INCORPORATED Contract: WESTON


Matrix (soil/water): SOIL . Level (low/med): LOW

% Solids for Sample: 75.8 % Solids for! Duplicate: 75.8ii


Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromium! CobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

ControlLimit

2.6

Sample (S)

6.2901

1.2665

1443.3747

C

B

Duplicate (D)

6.3120

1.1530

1362.3113

c

1"1B!

i!

RPD

0.3

9.4

5.8

'

Q M

P

P

P

FORM VI - IN

AROOI850


7LABORATORY CONTROL SAMPLE



Solid LCS Source: INORG VENTUR .' • !

Aqueous LCS Source: INORG VENTUR

Analyte

AluminumAnt imonyArsenicBariumBerylliumCadmiumalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Aqueous (ug/L)True Found %R

5000.0

1000.0

1000.0

4783.00

972.76

978.48

95.7

97.3

97.8

Solid (mg/kg)True Found C Limits %R

62.6

90.9

215.0

76.8

103.1

231.9

—

—

—

30.8

57.8

149.0

93.3

127.0

290.0

122.7

113.4

d*

107.9

FORM VII - IN

AR00185I


9


ICP SERIAL DILUTIONS _

XXXX5BL

SAMPLE NO.

Lab Code: PACE Case No.: 1300 SAS No.: N/A j SDG No.: XXXX89j

Matrix (soil/water): SOIL : Level (low/med): LOW

Concentration Units: ug/L ;

Analyte


Initial. SampleResult (I) C

49.23

3.38

1253.22

B

—

SerialDilutionResult (S) C

SI. 46

5.00

1342.25

U

—

—

*Differ-ence

i

24.8

io;o'.o!1

s•11

17.1!

iIiI1

• 1 .

Q

—

«

M

P

P——

P——

——

FORM IX - IN

1852


9 SAMPLE NO.ICP SERIAL DILUTIONS

Lab Name: PACE, INCORPORATED Contract: WESTONXXXXRBL


Matrix (soil/water): WATER ' . Level (low/med): LOW

'Concentration Units: ug/L

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThallium •VanadiumZinc

Initial SampleResult (I)

5.00

1.00

3.16

C

U

U

B

SerialDilutionResult (S)

25.00

5.00

10.00

C

U

U

U

%Differ-ence

'

100.0

Q M

P

P

P

FORM IX - IN

AROOI853


10INSTRUMENT DETECTION LIMITS (QUARTERLY)

b Name: PACE, INCORPORATED Contract: WESTON

Lab Code: PACE . Case No. : 1300 SAS No. : N/A

ICP ID Number: ICP2Q1 Date: ' 01/01/96• !

Flame AA ID Number:

Furnace AA ID Number: ;

SDG No.: XXXX89

torrTnments:ICP #2 JARRELL ASH1st Quarter 1996

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincMoly

Wave-length(nm)

308.22206.84193.70493.41313.04228.80370.60267.72228.62324.75271.44220.35279.08257.61231.60766.49196.03328.07589.00190.86292.40213.86202.03

Back-ground

CRDL(ug/L)

' 200,0• 60.0

10.0200.05.05.0

5000.010.050.025.0100.03.0

5000.015.040.0

5000.05.010.0

5000.010.050.020.014.0

IDL(ug/L)

29. 047.o:58.01.0i.o;5.0;41. o;4.06.03.04.0!

61.0!26.02.016.0516.0!69.015.0!

, 31.0!141. OS5.0!4.0!14.0|

M

P~P

P~PPPPPPP

PPPP_

P~P

PPP

FORMX - IN


10INSTRUMENT DETECTION LIMITS (QUARTERLY)

uab Name: PACE, INCORPORATED Contract: WESTON


ICP ID Number: ICP4Q1 Date: 01/01/96

Flame AA ID Number:

Furnace AA ID Number:

Analyte

AluminumArsenicCalciumIronLeadMagnesiumSeleniumThalliumCadmium

Wave-length(nm)

308.20189.00317.90271.40220.30279.00196.00190.80226.50

Back-ground

CRDL(ug/L)

200.010.0

5000.0100.03.0

5000.05.010.05.0

IDL(ug/L)

13.05.07.0

21.03.0

12.05.05.01.0

M

P~

P~

P~~P

Comments:ICP#4 JARRELL ASH SUPER TRACE1st Quarter1996

FOEMX-INAROOI855


HA , ,ICP INTERELEMENT CORRECTION FACTORS (Annually)


Lab Code: PACE Case No.: 1300 SAS No.: N/Ai

ICP ID Number: ICP2 Date: 01/01/96

SDG No.: XXXX89

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumhhromiumpDbaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincMoly

Wave-length(nm)

308.22206.84197.00493 .41313 .04228.80370.60267.72228.62324.75271.44220.35279.08257.61

231.60766.49196.03328.07589.00190.86292.40213 .86202.03

Interelement Correction Factc

Al Ca Fe iy

0.0079200

0.0011720

0 .00029900.00175400.0003670-0.0000360

0.0000990

-0.0008390

-0.0000500-0.0540090

-0.0000600

0.0002300

-0.0002420

0.0024000

0.00349900.00000500.0001500-0.0001000

rs for:

g

-0. 0000470

0.0000180

1

-0.00:042001"1

0.00|10070

I1

! •

jnments :

FORM XI


11AICP INTERELEMENT CORRECTION FACTORS (Annually)




Analyte


Wave-length

(nm)

308.22

189.04

226.50317.93

271.44220.35279.08

196.02

190.86

Interelement Correction Factors for':

Al Ca Fe Mg

0.00014500.0003710

0.0000450

0.0000440

0.0001020

-0.0001100

— (I

^omments:The lead and selenium wavelengths listed are the 1st order

FORMXI (PART1) -f ROD I 857


11BICP INTERELEMENT CORRECTION FACTORS (Annually)


Lab Code: PACE " Case No.: 1300 SAS No.: N/A

ICP ID Number: ICP2 Date: 01/01/S6

SDG No.: XXXX89

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumXlalcium•thromiumPobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

Wave-length(nm)

308.22

228.80

271.44

589.00

Ir

AS

•

0.0135310

iterelement

ZN

-0.0001370

0.0001380

0.0004230

Correction Factcrs f 01

«

mments:

FORM XI (PART 2) - IN RROOS858


11B 'ICP INTERELEMENT CORRECTION FACTORS (Annually)




Analyte


Wave-length(nm)

220.35

196.02

Ir

AL

-0.0001580

iterelement

FE

0.0000260

-0.0005310

Correction Factors foi

»

Comments: ^ ^The wavelengths listed for lead and selenium are 2nd order wavelengtl H|

FORM XI (P.


12ICP LINEAR RANGES (QUARTERLY)



ICP ID Number: ICP2Q1 Date: 01/01/9^'

SDG No.: XXXX89

^ niments :ICP#2 JARELL ASH1st QUARTER L.R. 1996

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincMoly

Integ.Time(Sec.)

1.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.00

Concentration(ug/L)

-600000,. 0100000.0100000.0 .50000.05000.0

100000.01000000.0100000.0100000.0100000.0500000.0100000.0600000.050000.0

100000.01000000.0100000.050000.0250000.0100000.0100000.050000.0100000.0

M

pppppppp.ppppppppppppppp

FORM XII - IN RROOI860


12ICP LINEAR RANGES (QUARTERLY)



ICP ID Number: ICP4Q1 Date: 01/01/96

Analyte


Integ.Time(Sec.)

5.00

5.00

5.005.00

5.005.005.00

5.00

5.00

Concentration(ug/L)

600000.0

10000.0

5000.0500000.0

200000.010000.0500000.0

10000.0

10000.0

M

P

P_

PP_

P~~PP_

P_

P~

Comments;ICP#4 JARRELL ASH SUPER TRACE1st Quarter1996

FORM XII - IN AROOI86I


13Preparation Log

Name:. PACE, INCORPORATED Contract: WESTON

Lab Code: PACE Case No.: 1300 SAS No.: N/A . SDG No.: XXXX89

Method: P

FORM XIII - IN

SampleNo.

LCSSPBSXXXX1AXXXX1ADXXXX1ASXXXX1BXXXX2AXXXX2BXXXX3AXXXX3BXXXX4AXXXX4BXXXX5AXXXX5B

PreparationDate

01/05/9601/05/9601/05/9601/05/9601/05/9601/05/9601/05/9601/05/9601/05/9601/05/9601/05/9601/05/9601/05/9601/05/96

Weight(gram)

1.001.001. 001.001.001.001.001.001.001.001.001.001.001.00

Volume(ml)

200200200200200200200200200200200200200200

RROOI862


13Preparation Log

L,ab Name: PACE, INCORPORATED Contract: WESTON


Method: P

SampleNo.

LCSWPBWXXXXRB

PreparationDate

01/05/9601/05/9601/05/96

Weight(gram)

Volume(ml)

100100100

FORM XIII - IN

flROQI863


14Analysis Run Log

b Name: PACE, INCORPORATED Contract: WESTONLab Code: PACE Case No.: 1300 SAS No.: N/A SiDG No.: XXXX89Instrument ID Number: ICP2Q1 Method: PStart Date: 01/08/96 • End Date: 01/08/96

V

SampleNo.

ICVICBCRIIICSAIICSABIZZZZZZPBWLCSWXXXXRBPBSLCSSCCV1CCB1l fc —•PHLII•pnjyzTXXXX1ASXXXX1BXXXX2AXXXX2BXXXX3AXXXX3BCCV2CCB2XXXX4AXXXX4BXXXX5AXXXX5B^^v v o n (XT"**

XXX~XRBLCRIFICSAFICSABF

D/F

1.001.001.001.001. 001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.005.005.001.001.001.00

Time

07120715071807210730073407390742074607490752075507580802080508080811081408170820082308270830083308360839084208450850085408570900

% R

Analytesii

ALSBASBA

BE

XXXXX

XXXXXXXXXXXXXXXXXXXXXXXXXX

cDcAcRc0cu

•

FEPB

MG

1

MN

XXXXX

XXXXXXXXXXXXXXXXXXXXXXXXXX

HGN

Fl1

1I

i1

!1

!iI

iiii

i

1

iii1

K SEAGNATLV ZNCN

FORM XIV - IN


14Analysis Run Log

Lab Name: PACE, INCORPORATED Contract: WESTONLab Code: PACE Case No.: 1300 SAS No.: N/A SDG No.: XXXX89Instrument ID Number: ICP2Q1 . Method: PStart Date: 01/08/96 End Date: 01/08/96

SampleNo.

CCV3CCB3

D/F

1.001.00

Time

09030906

%• R

————

————

————

————

Analytes

ALSBAS

BA

BE

XX

cDCA

CRCOCUFEPB

MGMN

XX

HGNIK SEAGNATLV ZNCN

FORM XIV - IN

AROOI865


14Analysis Run Log

Name: PACE, INCORPORATED Contract: WESTONab Code: PACE Case No.: 1300 SAS No.: N/A SDG No.: XXXX89Instrument ID Number: ICP4Q1 . Method: PStart Date: 01/08/96 ' • End Date: 01/08/96

Sample'No.

2ICV2ICB2CRIIICSAI2ICSABI2ZZZZZZPBWLCSWXXXXRBXXXXRBLPBSLCSS2CCV1jflfel^ RlAXXXX1ADXXXX1ASXXXX1BXXXX2AXXXX2BXXXX3AXXXX3BXXXX4AXXXX4B2CCV22CCB2XXXX5AXXXX5B

2CRIFICSAF2ICSABF2

D/F

1.001.001.001.00l.'OO1.001.001.001.005.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001. 005.001.001.001.00

Time

07550759080108030806080808100812081608180821082308250828083108330835083908410843084608480850085208540858090009030905090709090912

% R ALSBAS

XXXXX

XXXXXXXXXXXXXXXXXXXXXX

XXX

BA

BECDCA

;CR

\ni

CO

al}

Cu

rte

FE

5S

PBMGMNHGNIK SEAGNATLV •zNCN

FORM XIV - IN |AR00 I 866

ENVIROFQRMS/INORGANIC CLP

14Analysis Run Log

_,ab Name: PACE, , INCORPORATED Contract:' WESTONLab Code: PACE Case No.: 1300 , SAS No.: N/A SDG No.: XXXX89Instrument ID Number: ICP4Q1 - Method: PStart Date: 01/08/96 • End Date: 01/08/96

Sample.No.

2CCV32CCB3

- --

i

D/F

1.001.00

•

Time

09140917

% R

_

ALSBAS

XX

fiA

BECDCA

f

CR

m.5

C0

ill

Cu

'te

FE

>s

PB

MGMNHGNIK SEAGNATLV ZNCN

j

FORM XIV - IN

&RQ01867

ICP RAW DATA

AROOI868

/Analysis Narrative Comments

Date t-g-^k (gcffiLot SA Batch # ~*lei\S'_Parameter g,^ yv\f> Instrument ID \___ _____

Analyst

Summary : No unusual problems were encountered during the analysis of these samples withthe exception of the following:

CalibrationInitial — — • — ,

/(

Continuing

Prep Blank

MS/MSD ( Accuracy & Precision )

c

LCS (Accuracy)

I~7

Comments SCLC \ « * A A i \\x.\ \ O /N H-Q r- toII , M i l l - l..l 1.4 I | , ,| W^lllf 1 I ••——— -••!• I- ™ >!•£•• ••J llll 11^——————I H I ••••III .»..!.. !!•..• •• ^ .—— I. I W

Inc.®MNINORG FORM MN306S

RR001869

{NVMONMCNTAL IMORATOftKS

| Page No: 79ICP Instrument Run Log Book No: 3182

ICP-2 !

I

PEIement(s): fee . f^W . Ps\ , ft V- "C1f1Fc

1C

1

)ate:"ime:

^ _ <g .c{ k 'Ol \ V

AEC: M ft.Client: fto^* ft OOe^Vo^SDGNo.: ^ -q^

analyst: . ^<vvv-"ask:"ile:

r*\«\Fs oxo^0!

Standards IDs3V/CCV C\~\V "S:RI

ICSA

Project No.: ikl/V

HI* -°lM~\^*\M ICSAB MT)--

Initial Calibration SequenceBlank QCalib Std 1 U"l^-\^5Calib Std 2 Mn^-A^Calib Std 3 N yACalib Std 4 1_

Analytical Sequence1.

I2'3-4-5.6.7.8,9.10.•11.12.13.14.15.16.17.18.19.20.

TCA/TCfLA(KLSlE"X-Cs«si:tn.c.sv\€>ir~Z_~LJX.T.T.T

PS -slUCLSOOoo^lMfBSLCSS

CCVJ\cct\© OoS'i .i.OOO^lOOoo 'iJ.Sooo^bfeoo o*vi. X^ o o °\ 3~6Ooo^HS

•

/oi

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L005I.DOC(7/95) A H CJ) 0 I 8 7 0Minnesota Laboratory ,

Analysis Report Averages . Mon 01-08-96 09:11:28 AM page 2

# Sample Name (Mn2576J A13082 Mg2790 Fe2714 (Be3130

1 ICV 2.508 9.864 25.49 5.001 .25332 ICB .0000 .0073 .0194 .0018 -.00043 CRII .0285 * .0058 .0208 .0028 .00954 ICSAI -.0098 466.9 479.1 174.6 .00095 ICSABI .4519" 458.5 472.9 172.0 .45076 ZZZZZZ .0023 .6721 .7321 .2280 .00037 PBW .0000 , .0399 .0433 .0250 -.0007/8 LCSW .9785" .9545 .0052 .9798 .97289 000914 .0032 ' .1237 .0586 .0459 .0002

10 PBS .0000' .0089 .0122 .0010 -.000511 LCSS 1.160- 21.31 17.93 31.52 .5156""12 CCV1 2.555: 9.910 25.69 5.054 .2555"13 CCB1 .0000 .0070 .0217 .0044 -.000314 000892 5.470 87.14 11.14 104.6 .004815 000892D 5.J.6J3 63.94 9.373 80.03 .004416 000892S CHlZQlj 89.82 10.77 105.5 .056317 000906 1.886 105.3 14.91 135.8 .003318 000922 5.562 94.54 10.89 108.5 .006419 000930 2.962 124.5 14.69 157.0 .004720 000949 1.768 74.62 11.83 114.9 .003221 000957 .5957 99.18 10.88 108.4 .0030 ,22 CCV2 2.547" 9..817 25.59 5.050 .2554 --23 CCB2 .0005"" .0183 .0149 .0145 -.000224 000965 3.918 76.91 88.13 85.85 .003825 000973 2.252 89.04 104.3 104.0 .004226 000981 4.571 84.70 10.91 95.69 .004327 000990 1.253 132.3 16.68 160.0 .003428 000990L .2685" 28.12 3.599 34.65 .000729 OOtffSTL DoollHv. .0000 .0272 .0206 .0224 -.0003 •30 CRIF ^^ t-VTb .0290 .0372 .0195 .0355 .009831 ICSAF -.0107 463.0 479.7 174.4 .000932 ICSABF .4639 464.7 484.4 176.8 .4633x33 CCV3 2.564 9.851 25.82 5.061 .256934 CCB3 .0000 .0233 .0498 .0111 -.0002

&R001871

Analysis Report Summary Mon 01-08-96 09:11:28 AM page 1i •t

# Sample Name File Method Date Time OpID Type ModeI

1 ICV A010896 MN 01/08/96 07:lb TEM S CONC2 ICB A010896 MN 01/08/96 07:15 TEM S CONC3 CRII A010896 MN 01/08/96 07:18 TEM S CONC4 ICSAI A010896 MN 01/08/96 07:21 TEM S CONC5 ICSABI A010896 MN 01/08/96 07:3b TEM S CONC6 ZZZZZZ A010896 MN 01/08/96 07:34 TEM S CONC7 PBW A010896 MN 01/08/96 ' 07:39 TEM S CONC8 LCSW A010896 MN 01/08/96 07:42 TEM S CONC9 000914 ft& A010896 MN 01/08/96 07:4 TEM S CONC10 PBS A010896 MN 01/08/96 07:49 TEM S CONC11 LCSS A010896 MN 01/08/96 07:5 TEM S CONC12 CCV1 A010896 MN 01/08/96 07:55 TEM S CONC13 CCB1 A010896 MN 01/08/96 07:58 TEM S CONC14 000892 tft A010896 MN 01/08/96 08:02 TEM S CONC15 000892D Dup A010896 MN 01/08/96 08:05 TEM S CONC16 000892S 6p-,*.£ A010896 MN 01/08/96 08:08 TEM S CONC17 000906 i& A010896 MN 01/08/96 08:11 TEM S CONC18 000922 uft. A010896 MN 01/08/96 08:14 TEM S CONC19 000930 ZG A010896 MN 01/08/96 08:17 TEM S CONC20 000949 3ft A010896 MN 01/08/96 08:26 TEM S CONC21 000957 2>& A010896 MN 01/08/96 08:23 TEM S CONC22 CCV2 A010896 MN 01/08/96 08:27 TEM S CONC23 CCB2 A010896 MN 01/08/96 08:30 TEM S CONC34 000965 yA A010896 MN 01/08/96 08:33 TEM S CONC25 000973 V6 A010896 MN 01/08/96 08:36 TEM S CONC26 000981 5ft A010896 MN 01/08/96 08:39 TEM S CONC27 000990 5C> A010896 MN 01/08/96 08:42 TEM S CONC28 000990L 5SL A010896 MN 01/08/96 08:45 TEM S CONC29 000941L RBt- A010896 MN 01/08/96 08:56 TEM S CONC30 CRIF^rtA,/ . A010896 MN 01/08/96 08: 5^ TEM S CONC31 ICSAF A010896 MN 01/08/96 08:57 TEM S CONC32 ICSABF A010896 MN 01/08/96 09:00 TEM S CONC33 CCV3 A010896 MN 01/08/96 09:03 TEM S CONC34 CCB3 A010896 MN 01/08/96 09:0 TEM S CONC

&RQQI872

Mon 01-08-96 07:04:44 AM page 1

Method: MN Standard: STDl-Blank

ElemAvgeSDev%RSD

#1#2

Method:

ElemAvgeSDev%RSD

#1#2

Method:

ElemAvgeSDev%RSD

#1#2

Mn2576.0000.0000.0000

.0000

.0000

MN

Mn2576.9112.0037.4103

.9086

.9139

MN

Mg279011.46

.11.9810

11.3811.54

A13082.0004.0010278.1

-.0003.0010 .

Standa

A130822.410.005.2204

2.4142.406

Standa

Mg2790-.0009.0002

24.73

-.0007-.0010

rd: STD2

Fe27142.478.006

.2371

2.4742.483

.rd: STD3

Fe2714.0004.000367.54

.0002

.0006

Be31304.191.017.4121

4.2044.179

Be3130 ^.0050.0000.0000

.0050

.0050

1

Method: MN Sample Name: ICV Operator: TEMRun Time: 01/08/96 07:12:03Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge 2.508 9.864 25.49 5.001 .2533SDev .014 .095 .18 .027 .0015%RSD .5573 .9615 .7133 .5478 .6000

#1 2.498 9.797 25.36 4.981 .2523#2 2.518 9.931 25.62 5.020 .2544

Method: MN Sample Name: ICB Operator: TEMRun Time: 01/08/96 07:15:32Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .0000 .0073 .0194 " .0018 -.0004SDev .0000 .0027 .0011 .0014 .0003%RSD 132.5 36.18 5.880 79.00 66.71

#1 .0000 .0092 .0186 .0028 -.0002*2 .0000 .0055 .0203 .0008 -.0006

Method: MN Sample Name: CRII Operator: TEMRun Time: 01/08/96 07:18:40 !Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be31'30Units ppm ppm ppm ppm ppmAvge .0285 .0058 .0208 .0028 .0095SDev .0000 .0050 .0079 .0000 .0000%RSD .0011 86.52 37.81 .6122 .0000

#1 .0285 .0093 .0153 .0028 .0095#2 .0285 .0022 .0264 .0028 .0095

Method: MN • Sample Name: ICSAI Operator: TEMRun Time: 01/08/96 07:21:47 'Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130fJnits ppm ppm ppm ppm ppinvge -.0098 466.9 479.1 174.6 .0009SDev .0008 .0 .2 .1 .0000%RSD 8.506 .0016 .0371 .0754 ' .0000

#1 -.0093 466.9 479.2 174.5 .0009#2 -.0104 466.9 479.0 174.7 .0009 |

j

Method: MN Sample Name: ICSABI Operator: TEMRun Time: 01/08/96 07:30:59 !Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mh2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .4519 458.5 472.9 172.0 .4507SDev .0044 5.0 2.7 1.2 .0023%RSD .9733 1.092 .5711 .6960 .5036

#1 .4550 462.0 474.8 172.8 .4523#2 .4488 454.9 471.0 171.2 .4491

Method: MN Sample Name: ZZZZZZ Operator: TEMRun Time: 01/08/96 07:34:06 !mment: SDG 89 ICP2 RUN1de: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppm

Avge .0023 .6721 .7321 .2280 .0003SDev .0031 .1101 .1158 .0393 .0002%RSD 137.8 16.38 15.82 17.25 66.55

#1 .0045 .7500 .8140 .2558 .0004#2 .0001 .5943 .6502 .2002 .0001

Method: MN Sample Name: PBW- Operator: TEMRun Time: 01/08/96 07:39:52Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm • ppmAvge .0000 .0399 .0433 .0250 -.0007SDev .0000 .0129 .0142 .0006 .0001%RSD 12.98 32.48 32.84 2.425 11.12

#1 .0000 .0307 .0534 .0245 -.0006#2 .0000 ' .0490 .0333' .0254 -.0007

Method: MN Sample Name: LCSW Operator: TEMRun Time: 01/08/96 07:42:59Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1 •

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .9785 .9545 .0052 .9798 .9728SDev .0000 .0244 .0029 .0082 .0062%RSD .0001 2.554 55.64 .8402 .6327

#1 .9785 .9718 .0072 .9740 .9684#2 .9785 .9373 .0031 .9856 .9771

Method: MN Sample Name: 000914 Operator: TEMRun Time: 01/08/96 07:46:12Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .0032 .1237 .0586 .0459 .0002SDev .0000 .1103 .1472 .0358 .0008%RSD .3150 89.21 251.2 78.02 424.3

#1 .0032 .2016 .1627 .0712 .0007#2 .0032 .0457 -.0455 .0206 -.0004

Method: MN Sample Name: PBS Operator: TEMRun Time: 01/08/96 07:49:25Comment: SDG 89 ICP2 RUN1

&RQQI875

Mode: CONC Corr. Factor: 1

I Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .0000 .0089 .0122 .0010 -.0005SDev .0000 .0166 .0113 .0014 .0002%RSD 137.4 185.5 93.05 148.7 36.50

#1 .0000 .0207 .0042 -.0000 -.00.03 I#2 .0000 -.0028 .0202 .0020 -.0006 |

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _._ _.I

Method: MN Sample Name: LCSS Operator: TEMRun Time: 01/08/96 07:52:31Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppm !Avge 1.160 21.31 17.93 31.52 .5156 jSDev .004 .06 .04 .04 .0002 j%RSD .3253 .2599 .2193 .1323 .0328 ||#1 1.157 21.35 17.96 31.55 .5157#2 1.162 21.27 17.90 31.49 .5155

ethod: MN Sample Name: CCV1 i Operator: TEMn Time: 01/08/96 07:55:45

eminent: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 ,Be3130Units ppm ppm ppm ppm ppmAvge 2.555 9.910 25.69 5.054 .2555-SDev .012 .010 .09 .019 .0008%RSD .4520 .1049 .3585 .3665 .3306

#1 2.547 9.903 25.75 5.040 .2561#2 2.563 9.918 25.62 5.067 .2549

eMethod: MN Sample Name: CCB1 Operator: TEMRun Time: 01/08/96 07:58:59 1Comment: SDG 89 ICP2 RUN1 jMode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .0000 .0070 .0217 .0044 -.0003SDev .0000 .0025 .0155 .0006 .0001%RSD 25.02 35.97 71.61 12.93 31.04

1 , .0000 .0052 .0327 .0048 -.00022 .0000 .0088 .0107 .0040 -.0004

AR001876!


Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm • ppm ppm ppmAvge 5.470 87.14 11.14 104.6 .0048SDev .010 .15 .00 .0 .0000%RSD .1861 .1695 .0265 .0053 ' .0000

#1 . 5.478 87.04 11.14 104.6 .0048#2 5.463 87.25 11.14 104.6 .0048

Method: MN Sample Name: 000892D Operator: TEMRun Time: 01/08/96 08:05:14Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge 5.163 63.94 9.373 80.03 .0044SDev .026 .26 .069 .45 .0002%RSD .5095 .4128 .7357 .5665 3.861

#1 5.145 63.76 9.324 79.71 .0043#2 5.182 64.13 9.422 80.35 .0045

Method: MN Sample Name: 000892S Operator: TEMRun Time: 01/08/96 08:08:21Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

-Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge 6.670 89.82 10.77 , 105.5 .0563SDev .039 .01 .04 .5 .0004%RSD .5835 .0128 .3942 .4475 .6370

#1 6.697 89.83 10.74 105.8 .0561#2 6.642 89.82 10.80 105.1 .0566



#1 1.897 105.6 14.92 136.4 .0034#2 1.875 105.1 14.91 135.3 .0031

AR001877

tethod: MN Sample Name: 000922 Operator: TEMun Time: 01/08/96 08:14:36 |

Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1


#1 5.570 94.36 10.89 108.6 .0064#2 5.554 94.71 10.88 108.5 .0065

Method: MN Sample Name: 000930 Operator: TEMRun Time: 01/08/96 08:17:42 !Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge 2.962 124.5 14.69 157.0 .0047SDev .026 1.0 .07 1.1 .0000RSD .8778 .8190 .5088 .6820 .0000

#1 2.980 125.2 14.75 157.7 .0047#2 2.943 123.7 14.64 156.2 .0047

Method: MN Sample Name: 000949 Operator: TEMRun Time,: 01/08/96 08:20:49 !Comment: SDG 89 ICP2 RUN1 |Mode: CONC Corr. Factor: 1 !

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130 |Units ppm ppm ppm ppm ppm IAvge 1.768 74.62 11.83 114.9 .0032 |SDev . .016 .24 .04 .8 .0002 I%RSD .8893 .3156. .3787 .6882 5.312 |

i#1 1.779 74.79 11.86 115.5 .0033 |#2 1.757 74.45 11.80 114.3 .0031 |

I

jMethod: MN Sample Name: 000957 Operator: TEMRun Time: 01/08/96 08:23:56 iComment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1,

lem Mn2576 A13082 Mg2790 Fe2714 Be3130nits ppm ppm ppm ppm ppm

Avge .5957 99.18 10.88 108.4 ,0030SDev .0017 .43 .07 .4 .0001%RSD .2795 .4328 .6179 .3773 3.174

iROQI878

#1 .5946 98.88 10.83 108.1 .0031#2 .5969 99.49 10.92 108.7 .0029

Method: MN Sample Name: CCV2 Operator: TEMRun Time: 01/08/96 08:27:03Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge 2.547 9.817 25.59 5.050 .2554SDev .025 .192 .43 .078 .0043%RSD .9680 1.953 1.693 1.538 1.682

#1 2.530 9.682 25.29 4.995 .2524#2 2.564 9.953 25.90 5.105 .2584

Method: MN Sample Name: CCB2 Operator: TEMRun Time: 01/08/96 08:30:20Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1


#1 .0010 .0173 .0183 .0182 -.0001#2 .0000 .0194 .0116 .0109 -.0002



#1 3.913 76.96 88.23 85.77 .0036#2 3.922 76.86 88.03 85.93 .0040


Elem Mn2576 A13082 Mg2790 Fe271_4 Be3130Units ppm ppm ppm ppm ppm

RROOI879

f\

•Avge 2.252 89.04 104.3 104.0 .0042SDev .014 .89 .9 .6 .0000RSD .6271 1.004 .8242 .5513 .0000

#1 2.242 88.41 103.7 103.6 .0042#2 2.262 89.67 104.9 104.4 .0042



#1 4.558 84.50 10.92 95.49 .0044#2 4.583 84.90 10.91 95.90 .0042

Method: MN Sample Name: 000990 Opeirator: TEMRun Time: 01/08/96 08:42:47Comment: SDG 89 ICP2 RUN1de: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppraAvge 1.253 132.3 16.68 160.0 .0034SDev .007 .7 .02 .8 .0000%RSD .5282 .5494 .0932 .4936 .0000

#1 1.249 131.8 16.69 159.5 .0034#2 1.258 132.8 16.67 160.6 .0034

Method: MN Sample Name: 000990L Operator: TEMRun Time: 01/08/96 08:45:54Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .2685 28.12 3.599 34.65 .0007 !SDev .0032 .35 .043 .31 .0002 j%RSD 1.189 1.230 1.193 .9002 28.93 : '

I •#1 .2707 28.37 3.630 34.87 .0005 |#2 .2662 27.88 3.569 34.43 ' .0008 |_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ „ _ _ _ _ _ _ > _ _ _ _ _ _ _ _ _ _ _

ithod: MN Sample Name: 000941L Operator: TEM

Run Time: 01/08/96 08:50:01 \Comment: SDG 89 ICP2 RUN1

ARQOI88Q

Mode: CONC Corr. Factor: 1


#1 .0000 .0209 .0191 .0238 -.0004#2 .0000 .0334 .0222 .0210 -.0002

Method: MN Sample Name: CRIF Operator: TEMRun Time: 01/08/96 08:54:03Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .0290 .0372 .0195 .0355 .0098SDev .0007 .0075 .0013 .0086 .0001%RSD 2.332 20.15 6.470 24.17 1.514

#1 .0295 .0319 .0186 .0294 .0099#2 .0285 .0425 .0204 .0416 .0097

Method: MN Sample Name: ICSAF Operator: TEMRun Time: 01/08/96 08:57:10Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge -.0107 463.0 479.7 174.4 .0009SDev .0000 3.6 2.2 .2 .0000%RSD .4136 .7737 .4578 .1074 .0000

#1 -.0106 465.5 481.3 174.3 .0009#2 -.0107 460.4 478.2 174.6 .0009

Method: MN Sample Name: ICSABF Operator: TEMRun Time: 01/08/96 09:00:18Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .4639 464.7 484.4 176.8 .4633SDev .0058 .5 1.2 1.3 .0017%RSD 1.258 .1130 .2396 .7166 .3645

#1 .4680 464.3 483.6 17,7.7 .4621#2 .4598 465.0 485.2 175.9 .4645

A R O O I 8 8 I

Method: MN Sample Name: CCV3 Operator: TEMRun Time: 01/08/96 09:03:32 I .eminent: SDG 89 ICP2 RUN1 I'ode: CONC Corr. Factor: 1 i

i

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge 2.564 9.851 25.82 5.061 .2569SDev .009 .083 .02 .018 .0000%RSD .3634 .8457 .0731 .3489 .0000

#1 2.571 9.910 25.83 5.073 .2569#2 2.558 9.792 25.80 5.048 .2569

Method: MN Sample Name: CCB3 Operator: TEMRun Time: 01/08/96 09:06:49Comment: SDG 89 ICP2 RUN1Mode: CONC Corr. Factor: 1

Elem Mn2576 A13082 Mg2790 Fe2714 Be3130Units ppm ppm ppm ppm ppmAvge .0000 ,0233 .0498 .0111 -.0002SDev .0000 .0080 .0168 .0015 .0000%RSD 13.08 34.58 33.74 13.28 .0000

#1 .0000 .0290 .0617 .0121 -.00022 .0000 .0176 .0380 .0100 -.0002

SROOI882

Analysis Narrative CommentsDate /- 03 -1t* SDG/Lot ^ Batch #

Parameter f\s ~ Instrument ID tJTcf VAnalyst cS

Summary : No unusual problems were encountered during the analysis of these samples withthe exception of the following:

CalibrationInitial (\\( Q tC

Continuing

Prep Blank

\\

M S/M S D ( Accuracy & Precision ) |I\

f \\X\\

LCS (Accuracy)

Comments

pace, Inc.MNINQRftF/ 5

ff

flIJ

I

ICP Instrument Run LogICP-4

Page No: 31Book No: 3210

Element(s): ^L£_— r-Date:Time:

AEC: /xj i — ^ v>- *~i t disnti t/o<z- r ~f"c»>v'O!?co SDG No.: g" ).

Analyst: fC 'LTask:File:

A-/-

Standards IDsICV/CCV vfrCRI H1"L

$•0? -^to

L- j 7 V ICSA

Project No.: rJ•

IT-- -7- J ICSAB V) ' J3

Initial Calibration SequenceBlankCalib Std 1Calib Std 2Calib Std 3Calib Std 4

0Wil- i"7

rJ»c— i ——Analytical Sequence1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19,20.

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21.22.23.24.25.26.27.28.??•30.m-32,33.34.35,36.•37-"

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|

INSTRUMENT MAINTENANCE/ COMMENTS:-

L0051.DOC (7/95) 'Minnesota Laboratory B R D 0 i 88^

~ --•-'x -- a \

Analysis Report Averages Mon 01-08-96 09=20=49 AM page 2

tt Sample Name Asl890

2 ICE3 CRII 21 .384 ICSAI • -i.3235 1CSABI • -.4696

7 P51J 1 . --,09 -

," 0 0 0 J1 -r ' ' 3.31510 000914L 1 .158' 'il P35 . -3.840 -

13 CCV1 2544 .-"14 CCBi -.718215 000892 '23 .8416 000892D 23.9217 000892S 2001 . 16 000906 . 19.811" 000922 ' 31".3820 000930 32.7321 000949' 30.1422 000957 .31.3023 000965 34.0924 OO0973 23.23~" CCV2 2550^

CCB2 .138127 000981 32.6828 000990 49.2329 000990L 12.2930 CRIF 22.0731 ICSAF -3.86732 ICSABF " -1 .-90633 CCV3 2551.^34 CCB3 , 1 .022

AROOI885

Analysis Report Summary Mori 01-08-96 09:20 = 49 AM page 1

I

# Sample Name .File Method Date Time OpID Type Mode

_ ;.:v . z:ij2/i. AS. oi/08/9i 07:55.-SWE s •:;-:•'..:2 IC2 " . ZOI0396 AS ,01/08/96 07': 59 SJAJE S CONC2 CRII . : Z010896 AS 01/08/96 OB: 01 SUE 5. CGNC4 "ICSAI . Z01O8"96 AS ' 01/08/95 08:03"SWE 5 CONC5 ICSABI Z010896 AS 01/08/96 08:06 SWE 5 CONC6 ZZZZZZ .""" Z~10896 A5 . 01/03/96 08:08 SÊ" 5 CO.1'';.;"7 P£U- ' .ZC"iO896 AS Oi/08/96 ' OB : 10 'St-JE S CONCd LC3W- . " . - ZClOSî AS Cl/08/96 Ofe:12 3JAJE S ' 'CONC'•} 000914 W> ZC 1069o AS 0'l/'03/9& 015.16 SÊ S CCNC

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27 OOO981 SA Z01O896 AS O1/O8/96. O9: OO Sl|siE S CONC28 000990 SB Z010896 .AS 01/08/96 09:03 SWE S CONC29 000990L L Z010896 AS 01/08/96 .09:05 SWE S CONC30 CRIF • Z010896 AS 01/08/96 09:07 SI E S CONC31 ICSAF Z010896 AS 01/08/96 09 "-0.9 SWE S CONC32 ICSABF Z01.0896' AS • 01/08/96 09:12 SWE S CONC33 CCV3 • Z010896 AS 01/08/96 09:14 SWE S CONC34 CCB3 Z010896 , AS 01/08/96- 09:17 SWE S CONC

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Method: AS Standard:- STD1

,.n•*iV~--" — r>547iDev , .1412%RSD 253.3

31 -.020032 .066032 -.2100

Method: AS Standard

Eiem Asl890Avge 48.21SDev' .37 '%RSD .7613

SI 48.61#2 47.8933 45.13

Method'- AS Sample Name: ICV Operator: SUERun Time: 01/08/96 07:55:43 'Comment". WESTON SDG 89 ICP4

-\e- CONC Corr . Factor: 1

Elem Asl890Units ppbAvge 2522. - -SDev 9.%RSD .3577

31 2519.32 2532. •33 2515.

Method: AS Sample Name: ICB Operator: SWERun- Time: 01/08/96 07:59:33Comment: WESTON SDG 89 ICP4Mode: CONC Corr. Factor: 1

Elem Asl890Units ppbAvge -.3315SDev 1.9423%RSD 585.9

31 1.105H2 -2.541 '3 .4420

Method: AS Sample Name: CRII ' -Operator: SWE

HROOI887

Run Time: 01/08/96 08:01:46Comment: WESTON 'SDG 89 ICP4Mode: CONC • Corr . Factor-" 1

Avge 21.38SDev 1 .99"iRSD ?.3O5

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Elem Asl890 •Units ppbAvge - -1.823 - ' - .SDev 8.031 . • .

440.5 .

SI -10.41#2 5.497S3 • -.5525

Method: AS Sample Name: ICSABI Operator: SWE=un Time: 01/08/96 08:06:12Comment: WESTON SDG 89 ICP4-lode: CONC Corr. Factor: 1 .

Elem Asl890Units ppbAvge -.4696 . • • 'SDev 9.2861 '•-%RSD 1977.

#l' 2.017tt2 7.320S3 -10.75 '

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Elem Asl890 ' "Units ppb

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AROOI888

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Method: AS Sample Name: PSW . Operator: SWEvan -Time: 01/08/96 OS: 10:38 .' " "' 'romtnent "• WESTON SDG 89 ICP4 • ,"Mode: CONC Corr . Factor'- 1 " " . '"

Hiem Asl89O - ' .L'n^tJ- Ppbrtv^-i i .40? ' . • ' .SDev 5.0292.RSQ 357.0 . . . . ..

»1 ' -4.365 • . •»2 3.757S3 4.834

method- AS Sample Name: LCSW Operator: SWE~un Time: 01/08/96 03:12:50Comment: WESTON SDG 89 ICP4•iode'- CONC Corr. Factor: 1

Elem AS1890Units ppb

ge 4783., - ev 8 .°sRSD .1761 -

ttl 4792.tt2 ' 4776.S3 4782.'

Method: AS Sample Name: 000914 Operator: SWERun Time'- 01/08/96 08 = 16:35Comment: WESTON SDG 89 ICP4Mode: CONC Corr. Factor: 1

Elem Asl890 ' •Units ppbAvge 3.315SDev 6.097%RSD 183.9

SI 6.326 . . ' '#2 -3.702S3 7.320

AS Sample Name: 000914L Operator : SWE= Time: 01/08/96 08:18:47Comment: WESTON SDG 89 ICP4

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Method: AS Sample Name: CCV1 Operaior: SWE=:un Time: 01/08/96 08 = 25:27Comment: WESTON SDG 89 ICP4v!ode : CONC Corr . 'Factor : 1

Elem Asl890Units ppbAvge '2544.SDev 7. .

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COMC Corr. Factor* 1 . .

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Method: AS Sample Name: 000892D Operator: SWE^un Time: 01/08/96 08:33:24Comment: WESTON SDG 89 ICP4'•lode: CONC Corr. Factor: 1

Elem Asl890Units ' ppbAvge 23.92SDev 2.95%RSD 12.35 . ' '

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Method: AS Sample Name: 000892S Operator: SWE":un Time: 01/08/96 08:35:37Comment: WESTON SDG 89 ICP4

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