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    BIRO KLASIFIKASI INDONESIA

    GUIDELINES

    FOR

    THE

    EXPLOSION

    PROTECTION

    OF

    ELECTRIC L EQUIPMENT

    EDITION

    2 1

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    iro

    Klasifikasi

    Indonesia

    The following Guidelines come into force on J December 2001

    Reproduction in whole or in

    part

    by any means, is subject to

    the permission in writing by Biro Klasifikasi Indonesia Head Office

    Biro Klasifikasi Indonesia Head Office

    JI.

    Yos

    Sudarso No.38-39-40 Tanjung Priok Jakarta 14320 Po Box:

    101

    O/JKU

    Indonesia

    ~ + 6 2 0 2 1 )

    497021,4300993,4301017,4301703,4353291,4353292

    lJ FAX

    +62(021) 492509,496175,4371813

    e-mail: [email protected] or

    bki1964 @indosat.net.id

    Web

    site: http://www.bki.co.id

    Published by : Biro Klasifikasi Indonesia

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    Biro Klasifikasi Indonesia

    P.T. (persero) Biro Klasifikasi Indonesia

    Head Office:

    Jl.

    Yos Sudarso No.38-39-40

    Tanjung Priok - Jakarta 14320

    PO Box:

    IOIO JKU

    Indonesia

    Telephone: +62 (021) 497021,4300993,4301017,4301703,4353291,4353292

    Telefax: +62 (021) 492509,496175,4371813

    e-mail: [email protected] or

    bki1964 @indosat.net.id

    Web site:

    http://www bki co id

    BOARD

    OF

    COMMISSIONERS

    Chairman

    Commissioner

    Secretary

    BOARD

    OF MANAGING

    DIRECTORS

    President Director

    Technical Director

    Business Director

    Finance Personnel Director

    SURVEY DIVISION

    Reporting Certification Sect.

    Monitoring Register Sect.

    Acquisition Sect.

    HULL MATERIAL

    DIVISION

    Hull Sect.

    Welding Material Sect.

    MACHINERY

    ELECTRICAL

    DIVISION

    Machinery Sect.

    Electrical Sect.

    : Pieter F.L. Maspaitella, MBA

    : Drs. Sudjanadi, SE, MBA

    Drs. F.X. Yuwono P. Setoto, M.Sc

    : Suryanto, SH

    : Iskandar Bugandarsyah Ilahude

    : Ir. Muchtar Ali

    : Darlion Djabar, AMK-C, MM

    : Drs. Donny S. Purba

    : Ir. Haryanto

    : Ir. Hadi Soetrisno

    : Ir. Purnomohadi

    : Soesetyo Adie , AMK-B, MM

    : Ir. Daniel Suli

    : Ir. Soedjarwoko

    : Ir. Sri Dewi Amalia

    : Ir. L. Manupassa

    : Ir. Agus Wijaya

    : Ir. Jeffrey

    B.

    Massie

    iii

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    iv Biro Klasifikasi Indonesia

    STATUTORY DIVISION

    Load Line Cargo Gear Sect.

    SOLAS, MARPOL ISM Sect.

    QUALITY ASSURANCE DEPARTMENT

    PLANNING DEPARTMENT

    Budget Reporting Sect.

    Information System Sect.

    : Ir. Fathorrachman Said, M.Sc

    : Ir. Bambang Tri Suharto

    : Ir. Munirdin Suki

    : Ir. Saifuddin Wijaya, MBA

    : Ir. Ajatiman

    : Taufik Hidayat, SE, MM

    : Ir. Azril Bayma

    RESEARCH DEVELOPMENT DEPARTMENT : Ir. Mohamad Sugeng

    INTERNAL CONTROL DEPARTMENT

    FINANCE DIVISION

    Finance Adm. Sect.

    Accounting Sect.

    PERSONNEL GENERAL DIVISION

    Administration General Affairs Sect.

    Personnel Training Sect.

    Legal Public Relation Sect.

    SUPERVISION CONSULTATION DIVISION

    : Ir. Rasjid Ali

    : Drs. Sukiyo

    : Ora. Yayuk Mahanani, MM

    : R. Sudaryo, SE

    : Su ad Syuhada, SE, MM .

    : Asep Sutrisna

    S

    SH, MM

    : Herry Sudrajat, SH, MM

    : Yuniati, SH

    : Hendra Bawono, MBA

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    Biro Klasifikasi Indonesia

    v

    BKI

    BRANCH OFFICES

    AMBON

    CIGADING

    Address : JI. Raya Pelabuhan, Kompleks Address : JI Gerem Raya No.

    01

    Pelabuhan, Ambon 97216

    Pulomerak KM.5, Cilegon 42438

    Telephone

    : 0911) 355036

    Telephone

    : 0254) 571007

    Telefax

    :

    0911)352745

    Telefax

    : 0254) 571007

    Head

    : Ir

    Pieter Petrus Paulus

    Head

    : Ir. Totok Achmad

    BALIKPAPAN

    CIREBON

    Address

    :

    JI

    Yos Sudarso No. 77

    Address

    :

    JI

    Tuparev KM.3

    Balikpapan 76111

    Cirebon 45153

    Telephone

    : 0542) 21562, 21570, 31850

    Telephone

    : 0231) 205266

    Telefax

    : 0542) 22831

    Telefax

    : 0231) 205266

    Head : Ir. Priyo Santosa Head : Ir. Alfonsus Susilarso, AMK-B

    Deputies

    : Ir. I.N.G. Arimbawa

    Ir. A Bachrun Saad

    DUM I

    Address

    :

    JI

    Sungai Rokan No. 96

    BANJARMASIN

    Dumai 28814

    Address

    :

    JI

    Skip Lama No. 19

    Telephone

    :

    0 7 6 5 ) 3 2 5 7 ~ 3 5 1 0 0

    Banjarmasin 70112

    Telefax : 0765) 31364

    Telephone

    : 0511) 50175,58311

    Head

    : Ir. Yunasri Zainal

    Telefax

    : 0511)50175

    Head

    : Ir. Siswanto

    JAKARTA / TANJUNG

    PRIOK

    Address

    :

    JI

    Yos Sudarso 38-39

    BELAWAN

    Tanjung Priok, Jakarta 14320

    Address

    : JI Sulawesi II - Belawan,

    Telephone

    : 021) 490990, 4300993, 4301017,

    Medan 20413

    4301701,4301703,4371488,

    Telephone : 061) 6941025

    43910583

    Telefax : 061) 6941276

    Telefax : 021) 4301702,497020

    Head : Ir. Zilzal HM.

    Head : Asikin Kusumanegara, AMK-C

    Deputy : Ir. Nurdin Gading

    BITUNG

    KEND RI

    Address : J1.DS. Sumolang. Pos Pelabuhan,

    Address : Jl. Bunga Matahari No. 64

    Bitung 95522

    Kemaraya - Kendari 93121

    Telephone : 0438) 21129

    Telephone

    : 0401) 321622

    Telefax : 0438) 21282

    Telefax : 0401) 321622

    Head : Ir. Setudju Dangkeng

    Head

    : Ir. Rachmadi S

    BATAM

    MAKASSAR

    Address

    : JI.Gajah Mada, Komplek Pondok

    Address

    :

    JI

    Sungai Cerekang No. 28

    Indah Me. Dermot Blok A No. 1

    Batam 29421

    Makassar 90115

    Telephone

    : 0778) 322178, 322083

    Telephone

    : 0411 )311993, 315460

    Telefax

    : 0778) 322118

    Telefax

    : 0411) 315460

    Head : Ir. Darwis Ali

    Head : Ir. Arsalnan Lati ef

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    Biro Klasifikasi Indonesia

    PADANG

    Address : J1 St. Syahrir No. 208

    Padang 25216

    Telephone : (0751) 61553

    Telefax : (0751) 61553

    Head

    : Ir. Bambang Noeljanto

    PALEMBANG

    Address

    :

    J1

    Perintis Kemerdekaan 5 Ilir

    Palembang 30115

    Telephone

    : (0711) 713171,713172,713680

    Telefax

    : (0711) 713173

    Head

    : Radjin Sitorus

    PONTIANAK

    Address

    : J1 Gusti Harnzah No. 211

    Pontianak 78116

    Telephone

    : (0561)39579

    Telefax

    : (0561) 39579

    Head

    : Ir. Umar Faisal

    SEMARANG

    Address :

    JI

    M.Pardi

    No.5

    Pelabuhan

    Telephone

    Telefax

    Head

    Tanjung Emas Semarang 50229

    : (024) 543917 , 545805

    : (024) 543917

    : Ir. Yansen Miri

    SURABAYA

    Address

    J1

    Kalianget No.

    14

    Surabaya 60165

    Telephone:

    (031)3295448,3295449,3295450,

    3295451

    Telefax (031) 3294520

    Head

    Ir. M. Nasrun Djafar

    Deputies

    Ir. Mohamad Cholil

    Ir. Agung Prihanto

    SORONG

    Address

    JI Jend. Sudirman No. 140

    Sorong 98414

    Telephone:

    (0951) 322600

    Telefax

    (0951) 323870

    Head

    Ir. Pardy Abbas

    SINGAPORE

    Address

    111 North Bridge Road 08-07

    Peninsula Plaza Singapore 179098

    (65) 8830634 - 43 -

    51

    elephone:

    Telefax

    Head

    (65) 3393631

    Ir. Onot Subagyo

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    OFFICES

    OF

    FOREIGN CLASSIFICATION SOCIETIES CARRYING OUT SURVEY

    ON BEHALF OF

    BIRO

    KLASIFIKASI INDONESIA

    1. AMERICA BUREAU OF SHIPPING

    ABS)

    Head Office : TWO WORLD TRADE

    CENTRE, 106

    th

    FLOOR,

    NEW YORK, NY 10048 USA

    Telephone : (1) (212) 839-5000

    Telefax: (1)

    (212) 839-5130

    Telex : RCA 232099 ABNYUR

    Cable : Record

    E m ail:

    ask-abs@eagle-org

    Web site : eagle-org

    2. BUREAU VERITAS ( BV)

    Head Office :

    17

    BIS, PLACE DES

    REFLETS, LA DEFENCE 2

    92400 COURBEVOIE,

    FRANCE

    Telephone :

    33) 1)

    4291-5291

    SIEGE (HEAD OFFICE)

    DIR. NAVIRES EN SERVICE

    (SHIPS IN SERVICE MAN.)

    Telefax:

    (33)

    (1)

    4291 5293

    Telex : 615370 FBVADM

    SIEGE (HEAD OFFICE)

    615368 FBVSMS

    DIR. NAVIRES EN SERVICE

    (SHIPS IN SERVICE MAN.)

    3. CHINA CLASSIFICATION SOCIETY

    (CCS)

    Head Office

    Telephone

    Telefax

    Telex

    Cable

    : 40 DONG HUANG CHENG

    GENNAN JIE,

    BEIJING - 100006

    PEOPLE S REPUBLIC OF

    CHINA

    : (86) (010) 65136633, 65136787

    : (86) (010) 65130188

    : 210407 CCSBJ CN

    : CHINAREG

    4. DET N O R S K E

    V R IT

    AS

    CLASSIFICATION AS DoV)

    Head Office

    P.O.Box

    Telephone

    Telefax

    Telex

    Cable

    :

    VERITASVEIEN

    1 N-1322

    HOVIK, NORWAY

    : 300,1322 HOVIK, NORWAY

    : (47)

    67579900

    : (47) 67579911

    : 76 192 VERIT N

    : VERIT AS OSLO

    5. GERMANISCHER LLOYD (GL)

    Head Office : VORSETZEN 32.

    D-20459 HAMBURG

    Telephone : (49) (0) 40-36149 - 0

    Telefax: (49) (0) 40-36149 - 200

    Telex : 2 12828 GLHH D

    E m ail: [email protected]

    Web site : www.germanlloyd.org

    6. HELLENIC

    REGISTER OF

    SHIPPING

    HR)

    Head Office

    Telephone

    Telefax

    Telex

    Cable

    E-mail

    : 23 AKTI MIAOULI,

    185

    35 PIRAEUS, GREECE

    : (30)(1)4221900-909

    : (30)

    (1)

    4221913 4221914

    : 2 564 24 49

    HRS GR

    : HELREGSHIP-PIRAEUS

    : [email protected]

    7. KOREAN REGISTER OF SHIPPING

    (KRS)

    Head Office : 23-7 JANG-DONG,

    YUSUNG-KU, T AEJON

    REP. OF KOREA 305-600

    P.O. Box : 29 T AEJON REP.OF KOREA

    Telephone : (82) (42) 869-9114

    Telefax:

    (82) (42) 862-6011 - 6

    Web site : http://www krs co kr

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    iro Klasifikasi Indonesia

    8.

    LLOYD S

    REGISTER OF SHIPPING

    LR)

    Head Office

    Telephone

    Telefax

    Telex

    E-mail

    Web site

    : 100 LEADEN HALL STREET,

    LONDON, EC 3A 3BP

    UNITED KINGDOM

    : 44) 171) 709 9166

    : 44) 171) 4884796

    : 888379 LR LON. G

    : it. helpdesk@org

    : www.Ir. org

    9. NIPPON KAIJI KYOKAI NK)

    Head Office : 4-7. KIOI-CHO,

    CHIYODA-KU, TOKYO

    102-8567, JAPAN

    Telephone : 81) 3) 3230-1201

    Telefax: 81) 3) 5226-2012

    E mail: cld@classnkorjp

    Web site : www.class nk or jp

    10.

    REGISTRUL

    NAVAL ROMAN

    (RNR)

    Head Office

    Telephone

    Telefax

    Telex

    : BD, DINICU GOLESCU NR. 38

    SECTOR 1

    BUCURESTI 77113

    ROMANIA.

    : 40) 01) 2223768,6146431

    :

    (40)(01)

    2231972

    : 10256 r n r r

    11. SHIP CLASSIFICATION MALAYSIA

    (SCM)

    Head Office

    Telephone

    Telefax

    E-mail

    : 1 FLOOR WISMA

    MARITIM

    PERSIARAN SUKAN,

    SECTION 13

    40100 SHAH ALAM

    SELONGOR DARUL

    EHSAN, MALAYSIA

    : 03 - 50318160

    :

    03

    - 50318189

    : [email protected]

    12. VIETNAM REGISTER VR)

    Head Office : 1C KIM NGUU STR

    Telephone

    Telefax

    E-mail

    Web site

    RONAl - VIETNAM

    : 84-49714243/8219583;

    MOBILE:

    091205853

    : 84-4-8211320/9715839

    : [email protected]

    : WWW.Vf.vnn.vn

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    ix

    COOPERATION

    WITH

    FOREIGN CLASSIFICATION SOCIETIES

    KIND OF

    NO

    CLASSIFICATION SOCIETIES

    STATE

    COOPER ATION

    1

    American Bureau

    of

    Shipping (ABS)

    USA

    Dual Class

    2

    Bureau Veritas (BV)

    France

    Dual Class

    3

    China Classification Society (CCS) China Mutual Representation

    4

    Det Norske Veritas Classification AS (DnV) Norway

    Dual Class

    5

    Germanischer Lloyd (GL)

    Germany

    Mutual Representation

    6

    Hellenic Register

    of

    Shipping (HR)

    Greece Mutual Representation

    7

    Korean Register of Shipping (KRS)

    South Korea Mutual Representation

    8

    Lloyd s Register

    of

    Shipping (LR)

    UK

    Dual Class

    9

    Nippon Kaiji Kyokai (NK)

    Japan

    Mutual Representation

    10

    Registrul Naval Roman (RNR)

    Romania

    Mutual Representation

    Ship Classification Malaysia ( SCM

    Malaysia

    Mutual Representation

    12

    Vietnam Register (VR)

    Vietnam

    Mutual Representation

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    Table of Contents

    x

    Table of

    Contents

    Page

    A. Reference to Codes and Requirements

    1

    Requirements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

    2

    Constructional Rules of Biro Klasifikasi Indonesia. . . . . . . . . . . . . . . . . . . . . . . .. 1

    B. Fundamental

    Concepts and Definitions

    1 Explosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

    2 Characteristic values

    of

    materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

    3 Explosion groups. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

    4 Temperature classes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

    5

    Types

    of

    ignition protection .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

    6 Field

    of

    applicat ions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

    C

    Explosion

    Hazard

    Areas

    1

    Classification

    of

    hazardous

    areas.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

    2 Cargo, passenger and special purpose ships. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

    3 Tankers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. 12

    4 Mobile offshore drilling

    units.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

    D Construction and Utilization of Explosion Protected Electrical Facilities

    1 Characteristic features of facilities with types of

    ignition protection Ex d,p,e,s and i

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    .. 20

    2 Portable electrical facil ities. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 29

    3

    Type

    of

    installations. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

    4 Utilization on cargo, passenger and special purposes ships. . . . . . . . . . . 33

    5 Utilization on tankers and mobile offshore drilling units. . . . . . . . . . . . . . . . . . . . . 34

    E

    Testing and

    Identification

    of

    Explosion Protected Electrical

    facilities

    1 Requirements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37

    2 Testing and approval by Biro Klasifikasi Indonesia. . . . . . . . . . . . . . . . . . . . . . . .. 37

    3 Approved testing stations. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 39

    4 List of International explosion protection provisons and code letter used. . . . . . . .. 40

    5 Examples of the identification of explosion-protected electrical facilities

    with the flame proof enclosure d type ignition protection by

    explosion groups. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    41

    F Explosion Hazard from

    Dust Air

    Mixtures

    1 Basic concepts. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

    2 Explosion hazard areas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43

    3

    Construction, testing and use

    of

    electrical facilities with dust explosion

    protection..

    43

    PPENDIXES

    Appendix

    1 : Oil products. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46

    Appendix 2:

    Gases

    46

    Appendix 3: Petrochemical product may be equated with oil products with

    regard to explosion

    hazard.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 47

    Appendix 4: Chem i c a l s 50

    Appendix 5:

    lACS Recommendation, No. 22, 1988 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 53

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    1

    A. References

    to

    Codes

    and

    Requirements

    The manufacture, installation and testing of electrical facilities for use in explosion hazard areas

    are subject to strict requirements. Since these Guidelines deal with applications

    on

    ships and

    mobile offshore drilling units, only the principal international codes and requirements applicable

    to these will be mentioned. Respective national requirements

    as

    may be applicable are to be

    observed.

    1. Requirements

    a. IMO - International Bulk Chemical Code IBC Code)

    b. IMO - Bulk Chemical Code BCH Code)

    c.

    IMO - International Gas Carrier Code IGC Code)

    d. IMO - Gas Carrier Code GC Code)

    e. IMO - Code for the Construction and Equipment of Mobile Offshore Drilling Units

    MODU Code)

    f. lACS - Recommendation

    No.

    22, 1988, Recommendations for the classification

    of

    areas where flammable gas or vapour risks may arise to permit the proper selection

    of

    electrical equipment

    g. SOLAS 1974, Chapter

    11-2

    Construction - Fire protection, fire detection and fire

    extinction

    h.

    IEC Publication 92-502, Part 502 : Special features - Tankers

    i. IEC Publication 79 Electrical apparatus for explosive gas atmospheres

    2.

    Constructional Rules

    of

    iro

    Klasifikasi Indonesia

    a.

    Rules for the Classification and Construction of Seagoing Steel Ships, Volume IV,

    Rules for Electrical Installations

    b.

    Rules for the Classification and Construction of Inland Waterway Vessels,

    Chapter

    3

    Electrical Installations

    c. Rules for Mobile Offshore Drilling Units and Special Purposes Units, Section 13,

    Electrical Installations, Section 14, Machinery Installations, Electrical Installations,

    and So on

    in

    Hazardous Areas

    d.

    Rules for the Classification and Construction of High Speed Craft, Section 12,

    Electrical Installations

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    2 Biro Klasifikasi Indonesia

    B

    Fundamental Concepts and Definitions

    1

    Explosion

    An explosion is a process

    o

    combustion taking place at extremely high speed,

    characterized by high temperatures and a sharp increase

    in

    pressure, and

    characteristically accompanied by a report and blast.

    The following conditions have to be satisfied for

    an

    explosion to take place:

    a

    A potentially explosive atmosphere has to be present

    in

    the right concentration and

    sufficient

    volume.

    b The potentially explosive atmosphere has to be ignited by an ignition source with

    sufficient ignition energy see also item 2.4).

    2

    Characteristic values of materials

    2 1

    Flash point

    The flash point

    o

    a combustible liquid

    is

    the lowest te

    i

    -:1perature referred to a pressure

    o 760 mmHg) at which a vapour/air mixture inflammable by external ignition can form the

    test liquid under specified conditions.

    It

    follows that a combustible liquid with a flash point higher than the prevailing ambient

    temperature does not constitute an explosion hazard unless the liquid

    is

    heated above its

    flash point. The flash point thus gives

    an

    indication of the degree

    o

    fire and explosion

    hazard

    o

    the relevant liquid.

    2 2 Ignition temperature

    The lowest temperature at which a potentially explosive atmosphere

    is

    ignited

    is

    called the

    ignition temperature. The ignition temperature of a potentially explosive atmosphere

    is

    not

    a constant but strongly depends

    on

    external conditions. For this reason, it

    is

    always

    necessary to specify the experimental conditions when stating the ignition temperature

    o

    a

    potentially explosive atmosphere.

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    3

    2.3 Explosion

    limits

    ignition limits)

    The explosion limits indicate the concentration range within which the atmosphere is

    potentially explosive. There is an upper explosion limit (UEL) and a lower explosion limit

    (LEL). If the mixture is too lean or too rich,

    an

    explosion cannot take place, because there

    is either too little combustible material or too little oxygen. The closer together the

    explosion limits, the less hazardous the material concerned, due to the lower explosion

    point and the flash point are close together.

    i

    16

    4

    upper

    explosion

    limit (UEL)J7

    lower

    explosion

    (LEL)7

    too

    rich. non-explosion

    combustible i

    supplied

    with

    air.

    /

    O ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ L L ~ ~ ~ ~ ~ ~ ~

    s

    emperature

    tIC

    upper

    explosion point

    Explosion limits (example of ethyl alcohol)

    % volume

    indicates the proportion of a combustible material mixed with the available air

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    2 4 Minimum ignition energy

    The minimum ignition energy is the smallest quantum of energy with which a potentially

    explosive atmosphere can be ignited. The following are possible sources of ignition:

    Hot surfaces

    Flames and hot gases

    Mechanically generated sparks

    Electrically generated sparks arcs etc.

    Static electricity

    Lightning

    Electromagnetic waves at radio frequencies and in the visible spectrum

    Ionizing radiation

    Ultrasound

    Adiabatic compression

    Chemical reactions.

    2 5 Ignition propagation ability

    The ignition propagation ability is the capability of hot gases to propagate ignition through

    a gap of specified length and width. Ignition propagation does not occur below a

    specified gap width as the energy of the flame has already been consumed. The

    propagation ability of exploding mixtures through gaps varies as between different

    combustible materials. An accurate knowledge of the ignition propagation ability is

    important for flameproof facilities Ex d

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    5

    The

    principle parameters

    of

    materials which are conveyed on seagoing tankers are set

    out in the table given in the appendix to these Guidelines. Some examples are given

    below

    for

    the sake of illustration:

    Explosion limits in air

    (760 mmHg, 20 DC

    Material

    vapour

    density

    CIl

    CIl

    concentration u

    r

    0

    l5

    ::J

    U

    0

    e

    W

    W

    C

    L...

    L...

    9

    ( Volume)

    ( m

    3

    ::J

    ::J

    0

    ro

    r

    c

    0

    C L...

    L...

    a

    a W

    W

    . ii

    ..c

    lower

    upper

    lower

    upper

    :z:;o

    0

    a

    CIl

    c

    E

    E 0..

    r

    u

    OlW W

    x

    I--

    W

    Acetylene

    -

    1 5 82 0

    16 0

    880

    305 T2

    IIC

    Ammonia

    -

    15 0

    28 0

    105 0

    200

    630

    T1

    IIA

    Low-boiling nephta

    21

    0 7

    5 0

    -

    -

    ~ 2 2

    T3

    IIA

    Fuel-oil

    >60

    0 6 6 5

    -

    - 250 T3

    IIA

    Methane

    -

    5 0 15 0

    33 0 100

    595

    T2

    IIA

    Methyl alcohol

    11

    5 5 26 5

    73 0

    410 455 T1

    IIA

    Kerosene

    >40

    0 6 8 0

    -

    -

    ~ 2 2

    T3

    IIA

    Propane

    - 2 1 9 5 39 0

    180 470

    T1

    IIA

    Propylene

    -

    2 0 11 7

    35 0

    210 455 T1 IIA

    Carbon disulphide

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    4. Temperature classes

    Combustible gases and vapours are classified in temperature classes in accordance with

    their ignition temperatures,

    as

    shown below:

    Ignition temperature

    Temperature class according

    o

    combustible substances 0

    C

    to IEC 79 7 and 8

    >450

    T

    >300

    T2

    >200

    T3

    >135

    T4

    >100

    T5

    >85

    T6

    The above values apply not only to electrical engineering but also to mechanical

    assemblies such as

    heat exchangers, pipework, etc. Such assemblies with high surface

    temperatures, may only

    be

    used

    in

    explosion hazard areas if the surface temperature

    does not exceed 80 of the ignition temperature of the relevant substance, due

    allowance being made for accumulations of heat. Other sources of ignition are to be

    avoided.

    5

    Types

    o

    ignition protection

    These refer to measures adopted on electrical facilities to prevent ignition

    o

    the

    surrounding potentially explosive atmosphere

    by

    these facilities. The principal facilities

    used

    on

    board ships have the following types of ignition protection:

    5 1

    Flameproof enclosure Ex d

    Parts

    o

    electrical facilities constituting sources of ignition are surrounded

    by

    pressure

    tight but not completely gas-tight) casings, whose unavoidable sealing surfaces, cable

    entries, penetrations of moving parts, etc., are rendered proof against ignition

    propagation by limitation of gap lengths and widths e.g., motors and switches). Although

    explosive mixtures penetrating into the casing may

    be

    ignited, ignition of the mixtures

    outside the casing is prevented.

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    5 2 Pressurized enclosure Ex p

    n this case, parts of electrical facilities liable to constitute sources of ignition e.g.,

    control panels or machines) are bathed in fresh air or inert gas or kept under excess

    pressure, in such a way that the explosive mixtures from the surrounding atmosphere

    cannot penetrate to the parts which constitute sources of ignition.

    5 3 Increased safety Ex e

    Electrical facilities which do not constitute sources

    o

    ignition

    in

    normal service e.g., light

    fittings, three-phase squirrel cage motors generators without sliprings and commutators

    are protected against impermissible overheating in the event of faults, to avoid the risk of

    ignition should a fault occur,

    by

    additional apparatus to limit current or voltages

    e.g., protective cutouts with appropriate characteristics, temperature monitors).

    Measures are also adopted to ensure that short-circuits are precluded with a high degree

    of probability.

    5 4 Special type of protection Ex s

    Parts electrical facilities constituting sources of ignition are, for example, sealed in a

    totally gas-tight enclosure, thus preventing access by explosive mixtures to the source of

    ignition e.g., switches in closed, gas-tight glass vessels).

    5 5 Intrinsic safety x i

    The occurrence of sparks constituting sources of ignition and impermissible overheating

    is

    precluded by limitation of current and voltage. The energy

    o

    the circuits

    is

    less than

    the minimum ignition energy e.g., in measuring, signalling and control systems).

    5 6 Oil immersed Ex

    This involves placing equipment in oil-filled tanks to prevent gas from reaching any arcs

    that may

    be

    produced.

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    5.7

    Sand filled x

    q

    Same idea as the oil immersed except that quartz sand is used rather than oil. An HRC

    (High Rupture Capacity) fuse-link is sand filled.

    6. Fields of

    application

    According to IEC 79-0, electrical facilities for explosion hazard areas are to be divided to

    the following groups:

    Group I

    Group

    Electrical facilities for mines with a firedamp hazard (mining)

    Electrical facilities for explosion hazard areas.

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    C. Explosion Hazard Areas

    Explosion hazard areas are ones

    in

    which a potentially explosive atmospheres may occur

    in

    a dangerous quantity. Identification of explosion hazard areas is often difficult, as these depend

    substantially on the construction of the relevant parts of the ship, working conditions and the

    characteristics and quantity of the explosive gas-air mixture to

    be

    expected.

    In

    assessment of

    the concentration of the mixture, it should be remembered that most vapour/air mixtures are

    heavier than air and therefore accumulate in the lower parts of rooms. Hydrogen, methane,

    ammonia, acetylene, carbon monoxide and ethylene, on the other hand, are lighter than air and

    therefore become distributed through out the room, with a stronger concentration at higher

    levels.

    The constructional measures used on ships and mobile offshore drilling units should in all cases

    be directed towards minimizing the accumulation of hazardous gas-air mixtures. Such measures

    on

    tankers include, for example, gas displacement lines and high-speed valves, as well as

    appropriate design of the tank deck, superstructures and entrances. The actual explosion

    hazard areas can be limited

    by

    such measures. These measures are known as primary

    explosion protection.

    Other measures in the field of primary explosion protection are a high rate of air change in, or the

    inertization of, hazard areas, disconnection of electrical facilities, e.g.,

    on

    cargo ships, during

    transport of hazardous sea cargoes, and the installation of gas detection equipment.

    Only when all design and constructional measures have been fully exploited should secondary

    explosion protection measures

    be

    adopted - i.e., the electrical equipment for installation

    in

    the

    still remaining hazard areas is to be of explosion-protected construction.

    1.

    lassification

    of hazardous areas 1

    1

    It is appropriate for operational reasons to specify the extent of the protective measures in

    accordance with the probability of occurrence of a potentially explosive atmosphere. For

    this reason, explosion hazard areas are divided into zones.

    For proper selection of electrical equipment in hazardous areas

    of

    ships carrying coal cargoes in bulk and ships

    where oil or other liquids of similar hazard having flash point temperature not exceeding 60 0 C close cup test)

    are handled, stored or processed reference are to be made to the lACS Reccmmendation, No. 22, 1988

    see appendix

    5

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    This zone classification is being used increasingly in the literature and in test certificates for

    electrical facilities, and will therefore now be discussed in greater detail.

    Zone 0

    Zone 1

    Zone 2

    Covers areas in which a hazardous, potentially explosive atmosphere

    is

    present

    constantly or

    on

    a long-term basis e.g., interior o cargo tanks, pipework and

    other tanks and containers).

    Covers areas in which a hazardous. potentially explosive atmosphere is liable to

    occur occasionally e.g., the immediate area around Zone 0 and around loading

    stations and degassing openings, where explosive mixtures may also occur

    under normal working conditions).

    Covers areas in which a hazardous, potentially explosive atmosphere is liable

    to occur only seldom, and then only on a short-term basis e.g., areas

    surrounding Zones 0 and 1 or areas in which explosive mixtures may occur on a

    short-term basis in the event of faults or special working conditions)

    Electrical facilities are to be selected in such a way that excessive temperatures cannot

    arise and that the following conditions are met

    in

    the zones specified:

    Zone 0

    Zone 1

    Zone 2

    Ignition sources are avoided even

    in

    the case of faults occur rarely, e.g. ignition

    protection Ex ia.

    Ignition sources outside the facility are precluded even in the case o faults

    liable to occur relatively frequently, e.g. , types o ignition protection Ex d p. e. s

    and

    ib.

    Ignition sources are not liable to occur in the course o normal working e.g.,

    three-phase squirrel cage motors), or in the case o facilities where ignition

    sources are liable to occur in normal operation, a casing is present for protection

    against the penetration short-term gas clouds minimum protection class IP 55).

    Facilities to be installed in Zones 0 and 1 are to undergo

    an

    explosion protection test by

    a recognized testing institution see E 3 and 4).

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    11

    2

    Cargo passenger and special purpose ships

    Accumulations of potentially explosive atmospheres

    in

    dangerous quantities are liable

    to occur occasionally

    in

    the following areas comparable with Zone

    1)

    :

    2 1 Storage battery rooms.

    2.2

    Rooms containing acetylene and oxygen bottles

    2 3 Rooms containing paint and kerosene lamps

    2.4

    Rooms for the storage of fuels with a flash point

    of.::: 60C

    2.5

    Heated fuel tanks heating above 15

    c

    below flash point).

    2 6 Holds for the transport of hazardous sea cargoes

    2 7

    Holds for the transport of motor vehicles driven

    on

    and off the ship under their own power,

    as follows:

    2 7 1

    Cargo holds

    on

    cargo ships and enclosed motor vehicle decks

    on

    passenger ships above

    the main deck up to a height of 45

    cm

    above deck.

    2 7 2

    Cargo holds

    in

    passenger ships below the main deck entire height) .

    2 8

    Cargo holds for dredging spoil.

    Note:

    Methane CH

    4

    and hydrogen sulphide

    H

    2

    S) may be given off by dredging spoil.

    Adjoining the direct explosion hazard area - for example, adjoining holds for motor vehicle

    transport 2.7.1) - there may be extended hazard areas,

    in

    which a potentially explosive

    atmosphere is liable to occur seldom, and then only

    on

    a short-term basis comparable

    with Zone

    2).

    Such areas are for example, ones above a level of 45 cm right up to the

    top

    of

    the hold, as specified

    in

    2.7.1.

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    3.

    Tankers

    The specification of the explosion hazard areas set out below applies only to tankers

    including chemicals and gas tankers) with cargoes having a flash point of

    6 C

    comparable with Zones 0 and

    1

    .

    3.1

    Cargo tanks and cargo container systems.

    3.2 Cofferdams adjoining cargo tanks.

    3.3 Cargo pump rooms and cargo compressor rooms.

    3.4 Closed or semi-enclosed rooms immediately above cargo tanks or with bulkheads above

    or

    in

    line with cargo tank bulkheads.

    3.5 Closed or semi-enclosed rooms directly above cargo pump rooms or above cofferdams

    adjoining cargo tanks, unless these are separated from each other

    by

    a gas-tight deck

    and adequately ventilated.

    3.6 Rooms

    in

    which cargo hoses are stowed.

    3.7 Other rooms serving

    as

    cofferdams, adjoining cargo tanks and extending to a level below

    the upper edge of cargo tanks e.g., trunks, service gangways and cargo holds).

    3.8 Areas

    on

    the open deck, including semi-enclosed rooms within a spherical radius

    of 3 meters around tank outlets or outlets of pump rooms or cofferdams e.g., cargo tank

    hatches, flanges, inspection ports, ventilation openings of pump rooms or cofferdams,

    entrances to cargo pump rooms).

    3.9 The open deck above cargo tanks,

    plus 3 meters fore and aft and across the full width

    of

    the ship even if there are lateral ballast tanks),

    up

    to a height

    of

    2,4 meters above deck.

    3.10 Closed or partially enclosed rooms having a direct opening to a hazard area.

    3.11

    Closed or partially enclosed rooms containing pipework through which cargo

    is

    conveyed.

    3.12 If the cargo presents a greater hazard, for example, carbon disulphide the 3 meters

    2,4 meters) areas mentioned above are to

    be

    extended to at least 4,5 meters.

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    3 13

    Closed or partially enclosed rooms not in themselves presenting a hazard but having

    openings to the hazardous area on the open deck are to

    be

    regarded

    as

    at risk, unless

    they satisfy the following conditions e.g.,

    on

    gas tankers) :

    a Access is by way of gas locks. There is to

    be

    an audible and visual alarm system

    which gives a warning signal

    on

    both sides of the gas lock if the locking devices

    on

    more than one door are not completely closed.

    b Excess air pressure relative to the external hazard area is present

    c The excess pressure or air flow is to be monitored and, if the ventilation fails, an

    audible and visual alarm is to

    be

    given and the power supply to all equipment not o

    explosion-protected construction is to be disconnected automatically, if necessary

    after a time lag. Equipment which presents a serious hazard if disconnected is not

    to be disconnected.

    d) All equipment which has to

    be

    operated even if the ventilation fails is to be of

    explosion-protected construction e.g., lighting, general alarm and telephone).

    e

    Interlocking facilities are required to ensure that non-explosion-protected

    equipment can only be connected after adequate prior ventilation, e.g., after at

    least 10 changes of air.

    Adjoining the direct explosion hazard areas there may

    be

    extended hazard areas where a

    potentially explosive atmosphere is liable to occur seldom, and then only on a short-term

    basis, under specific conditions, such as loading, unloading or degassing comparable

    with Zone 2):

    3 14 Areas

    on

    the entire open deck and above and aft of superstructures.

    3 15 Areas in front of cargo tanks at the same level as, or below, the tank deck and having a

    direct opening to the main deck.

    3 16 Ventilated rooms above cofferdams adjoining cargo tanks and with oil-tight and gas-tight

    separation from the latter.

    3 17

    Rooms for the installation of electric drive motors for cargo pumps or residuals pump

    above pump rooms.

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    Explosion hazard areas

    o

    a tanker for cargo with a flashpoint 60 0 C example)

    ~ . ' . ' ~ , , Y ~ : - ~ ~ ' ~

    ~ ' ' ' ' ' ' ' ' ' ~ ' ' , ' \ . . ~ , , ~ ~ ' ' ' ~ '

    42V are to

    be

    of impact-resistant construction to IEC 79-0. Impact

    resistant incandescent lamps are marked Ex .

    d. Special

    types of

    prote tion Ex s

    Type Ex s ignition protection refers

    to

    measures differing from the conditions of the other

    ignition protection types and which ensure equipment safety

    by

    other means. This method

    of protection

    is

    often used in conjunction with other types of ignition protection. It is most

    usually achieved by encapsulation with epoxy resin. This is an economic method

    achieving a high degree of protection against ignition hazards.

    One of the possible applications

    is

    the encapsulation of connection chambers or linking

    components between switch compartments with non-ignition propagating enclosures and

    connection chambers with increased safety Ex e ignition protection. Electronic modules

    are often resin-encapsulated.

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    e Intrinsic safety x i

    A circuit is intrinsically safe if sparks or thermal agencies arising

    in

    normal operation (e.g.,

    when the circuit is made or broken) or

    in

    the event of faults (e.g., short-circuits and earth

    faults) cannot ignite a potentially explosive atmosphere.

    Examples of application: Measuring, control, signalling and alarm equipment.

    A definite and universally valid limit for the minimum ignition energy cannot

    be

    specified,

    as many factors are involved, including the resistance, inductances and capacitances in

    the circuit, the material of the contact electrodes and the form of the electrodes. The

    intrinsic safety of a circuit may be cancelled out by external agencies, such as cable

    capacitance or stray electrical and magnetic fields. Where necessary, the maximum

    permissible inductances and capacitances within intrinsically safe circuits are specified in

    the test certificates. However, a power of about 1 watt can

    be

    specified as a rough guide.

    To prevent stray voltage effects from non-intrinsically-safe circuits, electrical separation,

    e.g., by the use of transformers, relays or optocouplers, should preferably be used.

    Safety barriers are also sometimes used, the effective voltage in the intrinsically safe

    circuit here being limited by zener diodes, which afford protection without electrical

    separation.

    Only intrinsically safe circuits with separation from the ship's or unit's mains are

    permissible

    on

    board tankers and mobile offshore drilling units. Where safety barriers are

    used, additional electrical separation may also be necessary.

    In equipment with intrinsically safe circuits for Zone 0 only the ia type of ignition

    protection to l e 79-2, may be used, unless the test certificate expressly allows use in

    Zone O Facilities, such as hermetically sealed contacts, for use in Zone 0 require special

    approval, even if they are included in

    an

    intrinsically safe circuit Ex ia.

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    The type of ignition protection for equipment with intrinsically safe circuits for Zone 1 is to

    be at least ib to IEC 79-2. Ordinary electrical facilities without a specified type of ignition

    protection may

    be

    used within intrinsically safe circuits for use

    in

    Zone 1 provided that the

    intrinsic safety of the circuit is not endangered

    by

    for example, additional capacitances

    and inductances.

    In measuring and control cabinets and similar equipment, the connection terminals are to

    be located separately from those of non-intrinsically-safe circuits. This condition is

    deemed to be met if there is an insulating partition or if the distance between the strips is

    at least 50 mm. This also applies to the separation from each other of intrinsically safe

    circuits

    of

    Zone 0 and Zone 1. Conductors of intrinsically safe circuits and other

    conductors may not be run together in cables, lines, conduits and cable ducts. Only metal

    sheathed or metal-shielded cables and lines may be used for permanent wiring. The

    distance between cables of intrinsically safe circuits and other cables is to be at

    least 50 mm.

    Intrinsically safe circuit may not earthed and may not be connected together, unless this

    expressly permitted

    in

    or required by the certificate, e.g, at safety barriers.

    Cables, lines and intrinsically sate facilities which are not immediately recognizable as

    belonging to the intrinsically safe system are to be coded; they may, for example, be

    colour-coded light blue.

    2 ortable electrical facilities

    Only portable electrical facilities having their own power source may be used in the

    explosion hazard area (Zones 0 and 1).

    Exceptions are permissible only if the facility is supplied via an intrinsically safe

    circuit Ex i.

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    A test requirement for portable electrical facilities is that they are to be dropped

    in

    working condition four times from a height of at least 1 meter on to a flat horizontal

    concrete surface. This test may not cause any damage which impairs the ignition

    protection of the electrical facility. Where it is possible for the facility to fall further e.g.

    when being carried over a cargo tank measures are to

    be

    taken to protect the facility

    from falling.

    Portable lights for use on the tank deck and in cargo tanks should preferably be of the

    type with Ex p ignition protection having a built-in generator driven by compressed air.

    These lights have the advantage of requiring no electricity supply line and they are also

    available for use in Zone

    0.

    Where portable electrical facilities are used it is essential to ensure that the type of

    ignition protection is sufficient for the relevant application. To give as wide a range

    o

    application as possible the minimum requirement to be observed should be:

    Temperature class T3

    and for facilities with Ex d ignition protection additionally;

    Explosion group

    II

    C.

    In the case of facilities to

    be

    used

    in

    Zone

    0

    suitability for this use must be demonstrated.

    Use of the above ignition group and explosion class takes account of the most frequently

    occurring gas-air mixtures on board ships and mobile offshore drilling units thus as far as

    possible precluding incorrect utilization.

    It is recommended that all portable electrical facilities used on board tankers - e.g.

    portable radio telephones torches etc. - be of explosion-protected construction whether

    or not they are intended for use

    in

    the explosion hazard area.

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    31

    3

    Types

    of

    installation

    The following main types of installation are used for explosion-protected electrical

    facilities with type Ex d ignition protection:

    1 Cable system indirect entry)

    2 Direct cable entry

    3 Conduit system direct entry)

    Flameproof

    equipment

    chamber

    Stuffing

    box type

    threaded connection

    for

    permanent

    wiring diagram

    Indirect entry

    Cable system)

    Flameproot

    chaniber

    Flameproof

    cable armouring

    Direct

    entry

    Cable system)

    lion

    er

    Igni

    b m

    / /

    Equipment

    chamber

    explosion-proof)

    t ~ l .

    or

    connect

    conduit

    mg line

    Direct entry

    Conduit system)

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    3 1 Indirect cable entries

    In the cable system, high-grade cables and lines e.g., H07RN-F) are used and fed

    indirectly into the flameproof casings of the electrical facilities. This type of installation is

    based primarily on the lEG requirements.

    With this system of installation, cables and lines are fed through cable entries into a

    terminal box with type Ex e ignition protection and connected to the relevant terminals,

    which are of type Ex e ignition protection. Individual conductors are taken from here

    through cable entries into the flameproof enclosure containing the electrical facilities.

    Where cables are liable to

    be

    mechanically damaged, they are to

    be

    run

    in

    conduits. To

    avoid damage due to condensation, these conduits may not constitute a totally enclosed

    system but are to have drain openings at low points.

    3 2 Direct cable entry

    With this system, it is possible to feed cables and lines directly into flameproof casings,

    the necessary cables and lines and their entries forming part of the Ex d protective

    measures. There are two main forms of this type of installation: the French system, with

    non-armoured

    cables, and the British system, whereby the cables are fed into the

    flameproof enclosures by special screwed cable connections. It is essential to ensure

    that the correct connections are used for the type of cable and its construction and for the

    relevant site.

    3 3 Conduit system

    Only metal conduits with drawn-through or mineral-insulated cables are permitted

    in

    the

    lEG Zones and 1

    In

    practice, metal conduits are usually used, while mineral-insulated

    cables are employed primarily as heating lines and fire-resistant 2 signal and control

    lines.

    In the design of the conduit system, it is essential to ensure that each casing containing

    electrical switchgear

    is

    separated from the connected conduits by ignition barriers. In

    addition,

    in

    the case of long lengths and large diameters, supplementary ignition and gas

    barriers are to be incorporated at specified intervals, to limit the explosion pressure in the

    event o the ignition of any explosive mixture which may be present in the conduit.

    2

    Only conditional fire resistance is feasible

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    Fields o application for this system are offshore drilling platforms and American-type

    process platforms.

    Transitions from one installation system to another are permissible

    in

    all cases. Where

    equipment subject to different requirements is installed together, the measures to e

    taken are to e agreed upon with SKI.

    One method of working transition from the conduit system to indirect cable entry and vice

    versa is to use adaptor, whose flame proof chamber is assembled to the electrical

    facility by means

    o

    the conduit system via a short length of conduit, usually without

    ignition barriers. The electrical potential is fed from the flameproof chamber

    o

    the

    adaptor via cable entries into a chamber with the increased safety type

    o

    ignition

    protection, further connections being made by the usual techniques in this chamber.

    4. Utilization o cargo passenger and special-purpose ships

    For explosion hazard areas, see C.2.

    The required types of ignition protection

    in

    the different explosion hazard areas are set

    out in the following table. The ignition groups, and also the explosion classes for facilities

    with Ex d type o ignition protection, are given. The values specified are minimum

    requirements.

    SKI's Construction Rules are to e observed concerning limitation

    o

    the use

    o

    electrical

    facilities in explosion hazard areas.

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    34 Biro Klasifikasi Indonesia

    Type

    of

    ignition protection in Explosion

    Group and Temperature Class to

    IEC

    79

    n accor-

    Explosion hazard areas

    dance

    with C 2

    Abbreviated description

    d

    p

    e

    s

    i

    2 1 Storage battery rooms

    IIC

    T1

    T

    T

    T

    T1

    2 2 Acetylene and oxygen

    bottle rooms

    IICT2

    T2

    T2

    T2

    T2

    2 3 Paint and kerosene lamp

    liB

    T3

    T3 T3

    T3

    T3

    rooms

    A

    Rooms for the storage of

    T3

    T3

    fuels with a flash point of liB T3

    T3

    T3

    ~

    60

    0

    C

    2 5

    Fuel tanks only when

    T3

    T3

    T3

    T3

    heated above 15 0 below

    IIAT3

    flash point

    2 6

    Cargo holds for the

    transport of hazardous sea

    According to cargo

    cargoes

    2 7

    Holds for c o n v e ~ n c e of

    motor vehicles riven

    on

    and off under own power

    2 7 1

    On cargo ships and

    enclosed motor vehicles

    IIA

    T3 T3

    T3 T3 T3

    decks above the main deck

    on

    p s s e n ~ e r

    ships u ~ to a

    maximum eight of 4 cm

    2 7 2

    Cargo holds on passenger

    IIAT3

    T3

    T3 T3

    T3

    ships below the main deck

    full height of hold)

    2 8

    carwo holds for dredging

    IIA T3

    spoi methane and

    hydrogen sulphide)

    T3

    T3 T3

    T3

    5

    tilization on tankers

    and

    mobile offshore drilling units

    Only explosion-protected electrical facilities of at least the following ignition group and

    explosion class may be used in the explosion hazard areas specified in C.3 and C for

    seagoing ships and mobile offshore drilling units:

    Temperature class T3

    and, for facilities of type

    Ex

    d ignition protection, additionally;

    Explosion group II

    B

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    5

    BKl s Construction Requirements on limitation of the use of electrical facilities in explosion

    hazard areas are to be observed.

    More stringent explosion protection requirements may be necessary in ships used for

    transporting special cargoes, e.g., carbon disulphide:

    Temperature class T5

    and, for facilities with type Ex d protection, additionally;

    Explosion group IIC.

    Special measures

    in

    addition to the general requirements are to be stipulated in these

    cases. In addition, when acids which do not normally present an explosion hazard are to

    be transported, a reaction may occur if these acids come into contact with iron, hydrogen

    being thereby released. The cargo tanks are to be constructed so that such a reaction

    cannot take place, but adjacent areas which may come into contact with acid

    in

    the event

    of

    damage do require attention. These include all areas where acid may be present in

    the event of damage - e.g., cofferdams and pump rooms.

    Measures to prevent explosions

    in

    the event of accumulations of hydrogen are required

    in

    these areas:

    Temperature class T1

    and, in the case for facilities with type Ex d ignition protection, additionally;

    Explosion group

    II C.

    Only explosion-protected circuits with ignition protection of type Ex i may be used in

    areas where electrical assemblies come into direct contact with the cargo, e.g., in the

    interior of cargo tanks, pipework, pumps, etc. (see Zone 0). Their suitability is to

    be

    confirmed

    in

    the test certificate for Zone 0 (

    ia .

    Type Ex s ignition protection may

    possibly also be used.

    All other types of ignition protection, including Ex i circuits not suitable for use in Zone 0

    (ib), may not be used for this application. The identifying symbols for intrinsically safe

    circuits for use in the interior of cargo tanks, pipework, pumps etc., are as follows; Ex

    ia

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    Submerged pumps for use

    on

    gas tankers are excluded from these requirements.

    Submerged pumps including their electric drive motors and supply cables may be

    installed direct in the cargo tanks without any specific type of ignition protection but the

    following conditions are then to be met:

    i

    The pump motors may only

    be

    operated below the surface of the liquid. Reliable

    means of preventing operation in a gas-air mixture are required.

    ii

    Automatic disconnection with alarm

    in

    the cargo monitoring room is required

    in

    the

    event of:

    a

    Low liquid level or

    b

    Low pump discharge pressure or

    c Low motor current.

    For safety reasons a combination of several disconnection criteria should be used with a

    safety circuit - e.g. a 1-out-of-2 or preferably a 1-out-of-3 circuit.

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    37

    E. Testing and

    Identification

    of Explosion-Protected Electrical Facilities

    1.

    Requirements

    The following governs the construction and testing

    of

    explosion protected electrical

    facilities:

    lEG 79-0, General Requirements

    lEG 79-2, Pressurized enclosure p

    lEG 79-1, Flameproof enclosure d'

    lEG 79-7, Increased safety e

    lEG 79-11, Intrinsic safety i

    Tests conducted

    on

    the basis

    of

    the equivalent standards will be recognized by SKI, if

    their equivalence is demonstrated.

    2. Testing and approval by Biro Klasifikasi Indonesia

    SKI does not conduct tests of electrical facilities to verify conformity with the explosion

    protection requirements. Test certificates

    of an

    approved testing station (see E.3 and

    E.4) confirming that the above requirements are satisfied, are to be submitted to

    SKI.

    Since these test requirements are based on the environmental and operating conditions

    of shore installations,

    an

    assessment by SKI as to observance of the particular

    environmental and operating conditions on board ships or mobile offshore drilling units is

    required in addition to submission of the test certificate. The environmental conditions,

    and hence the requirements, differ as between shore and marine installations

    in

    particular

    in the following points:

    Environmental

    Shore installations

    Ships (BKI and lEe 92-504)

    conditions

    Ambient temperature

    C

    45 0 C up to

    60

    0 C)

    Vibration

    -

    General:

    freq.

    =2 - 80 Hz,

    acc.

    = 0,7 9

    Specific: freq.

    =

    2

    -100 Hz,

    acc.

    =

    4 9

    Atmospheric humidity

    -

    Up to 100 Relative Humidity at

    45

    0 C

    Inclinations

    -

    Up to 45

    0

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    Additional tests for the purposes of type approval may cover the following, depending on

    the type

    o

    equipment:

    Vibration test

    Accelerated climatic test

    High-temperature test

    Salt mist test

    Inclined orientation test

    Reference should be made to the

    Regulations for the Performance o Type

    Tests.

    In

    addition to these tests,

    SKI

    will examine the equipment and its individual components

    on board to verify the following:

    i Observance of SKI's Instruction Requirements

    ii Suitability of the facility for the site of installation and purpose

    iii. Conformity of the test certificate number with the unit concerned, and compliance

    with any other requirements

    iv

    Correct installation and wiring

    v Functional test.

    The installer

    o

    the explosion-protected electrical equipment is to supply

    SKI

    with

    a confirmation

    o

    explosion-protected construction of the electrical equipment in explosion

    hazard areas on form F.212-2000.

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    39

    3 pproved testing stations

    According to IEC 79-9, the following testing stations (examples) are approved in various

    countries:

    Austria

    Belgium

    Canada

    France

    Germany

    Italy

    Japan

    Norway

    UK

    USA

    EVTA (Elektrotechnische Vershucanstalt)

    INIEX (Institut National des Industries Extractives)

    CSA (The Canadian Standards Association)

    CERCHAR (Laboratoire de Centre d Etudes et Recherces des

    Chabonages de France)

    LCIE (Laboratorie Central des Industries Electriques)

    PTB (Physikalisch Technische Bundensantalt)

    BVS (Bergwerkschaftliche Versuchsstrecke)

    CESI (Cestro Electrotechnico Sperimentale Italiano)

    REIS (Research Institute of Industrial Safety)

    SRI (Ships Research Institute)

    NEMKO (Norges Elektriske Materiellkontroll)

    BASEEFA (British Approvals Service for Electrical Equipment

    in

    Flammable Atmospheres)

    FM

    (Factory Mutual Research Corporation)

    UL (Underwriters Laboratories)

    Identification of explosion-protected facilities (examples) : IEC identification letters

    Types

    of

    ignition protection lEe Publication

    79

    d

    Ex d IIA T3

    p

    Ex P II T1

    e

    Ex ell T3

    i

    Ex ia IIC T5

    Ex ib liB T5

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    Biro Klasifikasi

    Indonesia

    4. List of international explosion protection provisions and code letters used

    J l

    c

    c

    0

    II>

    c

    l

    1:

    J

    E

    0 ;:J

    c

    l

    ;0

    1:

    OJ

    11

    l

    6

    .. 11>

    0

    e

    c

    s

    11

    Co

    i

    u

    0 Co

    c

    g

    ;:;

    " l

    W

    E

    ;:J

    c

    1:

    6

    u

    2

    .gJ

    6

    e

    II>

    f

    .

    Co

    m

    l

    ,

    .5

    D>

    ""

    rn

    I I > ~

    e

    11

    ~

    .I I

    e, =

    tlW

    c

    c

    c

    0

    .::

    OJ

    Co

    I

    I I )

    .sOl

    u=s

    i

    .Y

    e:

    D>

    0.0

    .

    i

    :8

    rn

    ;:J

    iii

    8.

    .2

    OJ

    rn

    c

    "iG

    Ole:

    11

    :z;-g

    ~

    .,

    e:

    l

    E

    OJ

    ""

    ~ ~

    aVi

    u

    l

    '1:

    .s: OJ

    0 .. 0

    :s

    c

    )

    ().

    f:

    ) )

    Il..

    f: Do

    I f )

    ustria A OVE 171 OVE 165 cab

    Ex d

    13n

    e

    1

    i

    s

    GlG5

    EVTA

    Wien

    Electr. Gas

    Belgium B d:#8#286

    Reg. gen

    cab+ Ex

    ADF

    I, e

    N.O,

    0,1,2 IN EX

    e:#8#717 con

    lIa..,

    (SA) (SI) (i)

    P,Q

    end

    3

    C.E.B

    1:#8#683

    p:#8#716

    2c-f

    Gl-G5

    Canada

    CON

    CSAStd. CSASld. con

    Exp C.1.1 DA

    .

    .

    TlT6

    1,2 CSA

    C22.2 No.3D C.22.1

    CSA

    Endosures)

    (Ind.)

    (SA

    C.22.2 C.22.5

    No.145

    (for mines)

    (MoIolS)

    CENELEC CLC CC31

    EX d I, e p l a b

    TlT6

    EG

    Harmonis

    EEx IIA-C

    Denmark

    OK

    Reg.

    fsinit cab Ex

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    41

    5 Examples of the identification of explosion protected electrical facilities with the

    flame proof enclosure d type of ignition protection by explosion groups

    Explosion groups to IEC

    I

    II

    liB

    IIC

    Hydrogen H2

    Example for gases

    Methane

    Benzene

    Ethylene

    Carbon disul-

    CH

    4

    C

    n

    H

    +

    2

    CH

    2

    -CH

    2

    phide CS

    2

    Acetylene

    CH-CH

    Austria

    A

    Sch) d

    Ex)

    d1

    Ex)d2

    Ex) d3a, 3b, 3c

    Belgium

    B

    Ex I

    Ex lIa

    Ex lib

    Ex IIc

    CSSR

    CS

    Ex3M

    Ex

    3 P

    Ex 3 S

    Ex3 H

    2

    , CS

    2

    , C

    2

    H

    2

    France

    F

    ADFGI

    ADFGII

    ADFGIII

    ADF GIV

    Germany

    D

    Sch) d

    Ex)d 1

    Ex)d 2

    Ex) d 3a, 3b, 3c

    Hungary

    H

    Sb-n I

    Rb-n II

    Rb-n

    III

    Rb-n IVa, IVb, IVc

    Int. Elect

    IEC

    Exd I

    Exd

    II

    A

    Exd

    liB

    Exd

    IIC

    Comm.

    Jugoslavia

    J

    S t I

    StllA

    StllB

    S t IIC.

    Netherlands

    NL

    1M

    1

    II

    1

    III

    1 IV

    NEM 3125

    ExF

    IIA

    Ex F liB ExF IIC

    Poland

    PL

    BM

    Ex-M IIA-

    Ex-M

    III

    Ex-M IVa, IVb, Ivc

    Russia

    R

    BI

    B

    B3 B4

    PB

    a

    Sweden

    S

    xt1

    x t xt3

    Switzerland

    CH

    Ex)d1

    Ex)d2 Ex) d3

    United Kingdom

    UK Ex FLP

    Gr 1

    Ex

    FLP

    Gr II

    Ex FLP

    Gr

    III Ex FLP Gr.

    III

    United State

    of

    USA C1.1.Gr. D

    C1.I.GrD

    C1.I. Gr. C C1.I.Gr,B,B,A

    America

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    F Explosion Hazard from Dust air Mixtures

    1 Basic concepts

    n

    addition to the hazard of potentially explosive gas-air mixtures discussed above, there

    may also

    be

    a hazard due to potentially explosive dust-air mixtures. The main possible

    sources of ignition are the forms of energy mentioned

    in

    B.2.4. Inflammability from hot

    surfaces is particularly important with dust-air mixtures.

    Self-ignition due to high temperatures

    is

    possible. The ignition temperature of a dust-air

    mixture

    is

    defined as the lowest temperature of a hot surface which still gives rise to ignition

    of a dust-air mixture blown

    on

    to that surface. Self-ignition initially causes a smouldering or

    glowing fire, which may cause the dust-air mixture to explode. The smouldering

    temperature of deposited dust is defined as the lowest temperature of a heated, exposed

    surface at which a 5

    mm

    thick layer of dust

    on

    this surface is ignited and smoulders) . The

    smouldering temperature may

    be

    substantially lower

    in

    the event of additional thermal

    insulation, e.g., by thicker deposits of dust, or if the dust

    is

    particularly fine.

    A smouldering fire

    in

    a dust deposit is always provoked at lower temperatures than

    explosion of the same dust as a dust-air mixture. However, although the smouldering fire is

    harmless

    in

    itself, the dust particles may be stirred up and constitute a source of ignition for

    a dust-air mixture,

    so

    that the smouldering temperature

    is

    a very important safety parameter

    of dusts. As

    in

    the case of gases and vapours of combustible liquids, dust-air mixtures also

    have a lower and an upper explosion limit see B.2.3), i.e., they also have an ignition range.

    The lower explosion limit of the more common combustible technical dusts can

    be

    estimated

    from the visibility.

    If a 25 W incandescent lamp can no longer

    be

    seen from a distance of 2 meters, a dust-air

    mixture between the eye and the lamp will then have approximately reached the lower

    explosion limit.

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    43

    The following table sets out some characteristics of the principle

    Particle size Bulk density Smouldering

    Ignition

    Dusts

    IJm

    kg/l

    temperature

    temperature

    5

    mm

    thickness)

    from

    to

    of a hot surface C

    Soot

    10

    20

    535

    >690

    Iron dust

    100

    150

    1,6

    240

    430

    Zinc

    10

    15

    4,9

    430

    530

    Rye flour

    50

    100

    0,19

    305

    430

    - 500

    Fishmeal 80 100

    0,66

    carbonized,

    charred

    485

    Peat mould

    300

    500

    0,07

    295

    420

    Lignite

    2

    3

    0,3 - 0,4

    260

    350 - 450

    Coking coal

    5

    10

    0,42

    280

    610

    Charcoal

    1

    2

    0,36

    340

    595

    2

    Explosion hazard areas

    Explosion hazard areas are ones

    in

    which a potentially explosive atmosphere may occur

    owing to a dangerous quantity of a dust-air mixture. These areas are classified

    in

    zones

    in

    the same way as for shore installations and

    by

    similar criteria to those set out in C.1, but

    the zone identification differs:

    Zone 10 Covers areas in which a dangerous potentially explosive atmosphere is present

    because of dust for a long period or frequently.

    Zone

    11

    Covers areas where a dangerous potentially explosive atmosphere may

    occasionally occur for a short-period owing to the raising of deposited dust

    e.g., bulk product cargo holds).

    3 Construction

    testing

    and use of electrical facilities with

    dust

    explosion protection

    Where facilities are used

    in

    areas presenting a dust explosion hazard, such as cargo holds,

    it should be remembered that not only dust-air mixtures but also gas-air mixtures constitute

    a potential explosion hazard, as for example with cargoes of gas-releasing coal.

    In

    such

    cases, only facilities protected against both hazards may be used.

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    3 1 Requirements for electrical facilities

    in

    Zone 10

    Only facilities specifically approved for this purpose, and intrinsically safe circuits with type

    Ex i Zone 0 ia) protection, may be used.

    3 2 Requirements for electrical facilities

    in

    Zone

    11

    Facilities without specific approval may

    be

    used, but they must satisfy at least the

    following requirements:

    3 2 1

    The facilities are to be so constructed that neither potentially explosive dust-air mixtures

    nor dangerous deposits of dust can form inside them. These requirements are met if the

    facilities conform at least to protection class IP 55.

    3 2 2

    The surface temperature of the facilities may not be high enough for it to be possible for

    raised dust or dust deposited on the facilities to be ignited. For this purpose, the following

    conditions are to be met:

    a The surface temperature may not exceed 2/3 of the ignition temperature in D

    of the relevant dust-air mixture.

    b

    On surfaces on which the dangerous deposition of dust liable to smoulder is

    not effectively prevented, the surface temperature may not exceed the

    smouldering temperature of the relevant dust less 75

    K.

    c) The relevant surface temperature is the lower of the values determined in

    accordance with a and b .

    d) Facilities are to be marked with the surface temperature occurring during

    continuous operation if this exceeds 80 DC. The surface temperature is to be

    related to

    an

    ambient temperature of 45 DC.

    3 2 3

    Facilities with the types of ignition protection specified in

    0.1

    may be used provided that

    the requirements of 3.2.1 and 3.2.2 are met.

    3 2 4

    Sodium vapour lamps may not

    be

    used. Ballasts o fluorescent lamps are to be protected

    by temperature-limiting devices unless the surface temperature required by 3.2.2

    is

    not

    exceeded even in the event of a short-circuit.

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    3 2 5 Power sockets are to

    be

    oriented

    so

    that the plug opening points downwards. Insertion

    and removal of the plug may

    be

    possible only with the power off. When the plug is not

    inserted the plug opening of the socket is to be closed off with a captive cover in such a

    way that the conditions of protection

    P

    55 are satisfied. Sockets are to be permanently

    installed. Coupler plugs and sockets and adaptors may not be used.

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    APPENDIXES

    Appendix :

    Appendix :

    Appendix

    3:

    Appendix 4:

    Appendix

    5:

    Oil products

    Gases

    Petrochemical product may be equated with oil

    products with regard to explosion hazard

    Chemicals

    lACS Recommendation No. 22 1988

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    6

    Appendix : Oil Products

    Name

    o

    substance

    Flash pOint

    Explosion

    Temperature

    Explosion

    0C)

    group

    class

    protection

    Petrol

    < 20

    IIA

    T3

    X

    Jet fuel

    < 20

    IIA

    T3

    X

    Diesel fuel

    >60

    IIA

    T3

    -

    Petroleum

    >21

    IIA

    T3

    X

    Fuel oil light/medium)

    >60

    IIA

    T3

    -

    Fuel oil heavy)

    >65

    IIA

    T3

    -

    Petroleum ether

    < 20

    IIA

    T3

    X

    Kerosene

    IIA

    T3

    X

    Lubricating oil

    >100

    -

    Appendix 2

    Gases

    Name of substance Flash pOint Explosion Temperature

    Explosion

    0C)

    group class

    protection

    Acetylene

    -

    IIC T2

    X

    Ammonia -

    IIA T1

    X

    Butane

    -

    IIA

    T2

    X

    Butylene

    -

    IIA T2

    X

    Natural gas methane)

    -

    IIA

    T2

    X

    Liquefied gas

    -

    IIA

    T2

    X

    Coking gas

    -

    liB

    T1

    X

    Coal gas town gas)

    -

    liB

    T1

    X

    Motor methane

    -

    IIA T1

    X

    Propane

    - IIA T1

    X

    Propylene

    -

    IIA T1

    X

    Hydrogen sulphide

    -

    IIA

    T3

    X

    hydrogen

    -

    IIC

    T1

    X

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    Appendix

    Petrochemical product which may

    e

    equated with oil products

    with regard to explosion hazard

    n

    n

    c

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    0

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    3

    :p

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    c

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    substance

    a..

    . ii

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    c

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    0

    substance

    a..

    . ii

    ..c

    0

    n

    c

    r

    > 7

    sec-n

    Diacetone alcohol

    58

    IIA

    Amyl alcohol-sec-

    30

    IIA

    X

    iso

    Dibutyl phthalate

    166

    Amyl alcohol-tert

    30

    IIA

    T2

    X

    Dicyclopentadiene

    32

    IIA

    Benzyl alcohol

    100

    T2

    Diethylbenzene

    56 IIA

    Butyl acetate-iso

    18

    IIA

    T2

    X

    Diethylene glycol

    124

    Butyl acetate-n

    22

    IIA T2

    X

    Diethylene glycol

    82

    Butyl acetate-sec

    19

    IIA

    T1

    X

    diethyl ether

    Butyl alcohol-iso

    27

    IIA

    T2

    X

    Diethylene glycol

    107

    Butyl alcohol-n

    29 IIA

    T2

    X

    monobuthyl ether

    Butyl alcohol-sec

    24

    IIA

    T2

    X

    Diethylene glycol

    116

    monobuthyl ether

    Butyl alcohol-tert

    11

    IIA

    T1

    X

    acetate

    Butyl benzyl

    199

    Diethylene glycol

    96

    phthalete

    monoethyl

    ether

    Butylene glycol

    >65

    T2

    Diethylene glycol

    110

    monoethyl ether

    Gamma-

    98

    acetate

    Butyrolactone

    Diethylene glycol

    93

    Cumene

    31

    X

    monomethyl ether

    Cyclohexane

    18

    IIA

    T3

    X

    Diethylene glycol

    82

    Cyclohexanol

    68

    monomethyl ether

    acetate

    n

    c

    n

    r

    0

    3

    1:5

    Q

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    0

    a..

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    c

    a..

    0

    E

    E

    c

    2>

    T2

    X

    T3

    T3

    T2 X

    X

    T1

    X

    T3

    X

    T2

    X

    T3

    T3

    -

    X

  • 7/24/2019 25. Guidelines for the Explosion Protection of Electrical Equipment

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    Appendix 3

    Petrochemical

    product

    which may be equated with

    oil products

    with regard to

    explosion

    hazard (continued)

    I / )

    c

    /)

    a.

    U

    0

    0

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    3

    0

    e

    2

    Name

    of

    substance

    -

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    0

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    5

    0

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    a.

    0

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    0

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    Name of substance

    + -

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    0

    0

    a.

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    .c

    0

    I / )

    a.

    ttl

    X

    u

    W

    Diisooctyl

    204

    -

    Ethylene glycol

    49

    IIA

    phthalate

    monomethyl ether

    Dioctyl phthalate

    218

    acetate

    -

    Dipentene 45

    IIA

    T3

    X

    Ethylene glycol

    121

    monophenyl ether

    Dipenyl ether

    115 T1 -

    Farmamide

    154

    Dipropylene glycol 138

    -

    Furfuryl alcohol

    65

    Dipropylene glycol

    85 -

    monomethyl ether

    Glycerine

    160

    Dodecyl alcohol

    >100

    -

    Heptane-n

    4

    IIA

    Dodecyl benzene 130

    -

    Heptanol-all

    74

    isomers

    Dodecyl phenol 163

    -

    Heptene

  • 7/24/2019 25. Guidelines for the Explosion Protection of Electrical Equipment

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    49

    Biro Klasifikasi

    Indonesia

    Appendix

    Petrochemical product which may be

    equated

    with oil products

    with

    regard

    to explosion hazard continued)

    en

    en

    c

    0

    co

    0

    )

    ::l

    0

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    0

  • 7/24/2019 25. Guidelines for the Explosion Protection of Electrical Equipment

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    50

    Appendix

    : Chemicals

    f/

    f/

    c

    a.

    ro 0

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    a.

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    x

    Q)

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    u

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    l

    E

    Acetic Acid

    40

    IIA

    T1

    X

    Carbon Tetrachloride

    Acetic Anhydride

    49

    IIA

    T2

    X

    Caustic Potash

    Acetone

    75

    Solution

    Cyanohydrin

    Caustic Soda

    Acetonitrile 2 IIA

    T1

    X

    Solution

    Acrylic Acid

    54

    X

    Chlorobenzene

    28

    IIA

    T1

    X

    Acrylonitrile

    -5

    liB T1

    X

    Chlorethanol-2

    55

    IIA T1

    X

    Adiponitrile

    93

    Chloroform

    Allyl Alcohol

    21

    liB

    T2

    X

    Chlorohydrins,

    IIA

    X

    Crude

    Ally Chloride

    81

    T1

    isomers)

    n-Butyl Acrylate

    41

    X

    Crotonaldehyde

    13

    liB T3

    X

    iso-Butyl Acrylate

    X

    Cyclohexanone

    43

    IIA T2 X

    n-Butyl Ether 25

    X

    Cyclohexylamine 32 IIA T3

    X

    Butyl methacrylate 54

    X

    Decyl Acrylate

    n-Butyraldehyde

  • 7/24/2019 25. Guidelines for the Explosion Protection of Electrical Equipment

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    Appendix : Chemicals

    continued)

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    Formaldehyde

    1,2 Dichcloropropane 15 IIA

    T1

    X Solutions (45 or

    >50

    liB

    T2

    X

    1,3 Dichcloropropene

    29

    IIA

    X

    less)

    Formic Acid

    69

    T1 X

    Diethanolamine

    138

    T1

    -

    Furfural

    60 IIA

    T2 X

    Dietheylamine

  • 7/24/2019 25. Guidelines for the Explosion Protection of Electrical Equipment

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    Biro

    Klasifikasi

    Indonesia

    52

    Appendix 4 :

    Chemicals

    continued)

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    ortho-Nitrotoluene

    106

    -

    Sulfuric Acid

    -

    -

    -

    -

    para-Nitrotoluene

    106

    -

    Sulfuric Acid

    -

    -

    -

    -

    Oleum

    -

    -

    -

    -

    (Spent)

    Paraldehyde

    17

    T3

    X

    Tetrachloroethane

    -

    Pentachlorothane

    -

    Tetrahyd rofu ran

    -17

    liB

    T3

    X

    Phenol

    79

    T1

    -

    Toluene

    135

    -

    Diisocyanate

    Phosphoric Acid

    -

    -

    -

    -

    Trichloroethylene

    32

    IIA

    T2

    -

    Phosphorus

    -

    -

    -

    -

    (yellow

    or

    white)

    Tricresyl

    -

    Phosphate

    238

    Phthalic

    152

    T1

    -

    1 % ortho-)

    Anhydride

    Triethanolamine

    179

    -

    B-Propiolactone

    74

    -

    Triethylamin