1 h 1.008 3 Li 6.941 11 Na 22.99 19

37
1A (1) 8A (18) 1 1 H 1.008 2A (2) TR A N SITIO N ELEM ENTS 3A (13) 4A (14) 5A (15) 6A (16) 7A (17) 2 He 4.003 2 3 Li 6.941 4 Be 9.012 8B 5 B 10.81 6 C 12.01 7 N 14.01 8 O 16.00 9 F 19.00 10 Ne 20.18 3 11 Na 22.99 12 Mg 24.31 3B (3) 4B (4) 5B (5) 6B (6) 7B (7) (8) (9) (10) 1B (11) 2B (12) 13 Al 26.98 14 Si 28.09 15 P 30.97 16 S 32.07 17 Cl 35.45 18 Ar 39.95 4 19 K 39.10 20 Ca 40.08 21 Sc 44.96 22 Ti 47.88 23 V 50.94 24 Cr 52.00 25 Mn 54.94 26 Fe 55.85 27 Co 58.93 28 Ni 58.69 29 Cu 63.55 30 Zn 65.39 31 Ga 69.72 32 Ge 72.61 33 As 74.92 34 Se 78.96 35 Br 79.90 36 Kr 83.80 5 37 Rb 85.47 38 Sr 87.62 39 Y 88.91 40 Zr 91.22 41 Nb 92.91 42 Mo 95.94 43 Tc (98) 44 Ru 101.1 45 Rh 102.9 46 Pd 106.4 47 Ag 107.9 48 Cd 112.4 49 In 114.8 50 Sn 118.7 51 Sb 121.8 52 Te 127.6 53 I 126.9 54 Xe 131.3 6 55 Cs 132.9 56 Ba 137.3 57 La 138.9 72 Hf 178.5 73 Ta 180.9 74 W 183.9 75 Re 186.2 76 Os 190.2 77 Ir 192.2 78 Pt 195.1 79 Au 197.0 80 Hg 200.6 81 Tl 204.4 82 Pb 207.2 83 Bi 209.0 84 Po (209) 85 At (210) 86 Rn (222) 7 87 Fr (223) 88 Ra (226) 89 Ac (227) 104 Rf (261) 105 Db (262) 106 Sg (266) 107 Bh (262) 108 Hs (265) 109 Mt (266) 110 (269) 111 (272) 112 (277) IN N ER TRA N SITIO N ELEM ENTS 6 Lathanides 58 Ce 140.1 59 Pr 140.9 60 Nd 144.2 61 Pm (145) 62 Sm 150.4 63 Eu 152.0 64 Gd 157.3 65 Tb 158.9 66 Dy 162.5 67 Ho 164.9 68 Er 167.3 69 Tm 168.9 70 Yb 173.0 71 Lu 175.0 7 Actinides 90 Th 232.0 91 Pa (231) 92 U 238.0 93 Np (237) 94 Pu (242) 95 Am (243) 96 Cm (247) 97 Bk (247) 98 Cf (251) 99 Es (252) 100 Fm (257) 101 Md (258) 102 No (259) 103 Lr (260) IdealG asConstant: R=0.0821 L atm m ol -1 K -1 1 atm = 760 m m H g = 760 torr Period

Transcript of 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Page 1: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 2: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Electronic Configuration according to Quantum Mechanics

The location of an electron is described by 3 terms.

1st Term: Shell (n)

n = 1

n = 2

n = 3

lone electronof Hydrogen

Page 3: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 4: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

2nd Term: subshell - designated by s, p,d,f

1s

n = 2

n = 3

The first shell (1) has one subshell (s).

Page 5: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

2nd Term: subshell - designated by s, p,d,f - refers to the shape(s) of the area in which the electron can be located. - also designates an energy level within the shell.1s

n = 2

n = 3

The first shell (1) has one subshell (s).

The s subshell is spherical in shape and has 1 orbital

3rd Term: orbital

Page 6: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

2nd Term: subshell - designated by s, p,d,f - refers to the shape(s) of the area in which the electron can be located. - also designates an energy level within the shell.1s

n = 2

n = 3

The first shell (1) has one subshell (s).

The s subshell is spherical in shape and has 1 orbital

3rd Term: orbitalEach orbital can accommodate2 electrons

Page 7: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

The Electronic Configuration of Hydrogen

1s

The first shell (1) has one subshell (s).The s subshell is spherical in shape and has 1 orbital

H 1s1

shell

subshell

# of electrons present

energy

H 1s

Electronic configuration

Orbital Energy Level Diagram

Page 8: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

The Electronic Configuration of Helium He: Atomic # of 2, 2 electrons in a neutral He atom

1s

Page 9: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

The Electronic Configuration of Helium He: Atomic # of 2, 2 electrons in a neutral He atom

H 1s1

He 1s2

He 1s

1s

**if there are 2 electrons in the same orbitalthey must have the opposite spin. (Pauli’s Exclusion Principle)

Page 10: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 11: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1s

The Electronic Configuration of Lithium (Li)Li: Z=3 Li has 3 electrons.

2nd shell (2)

Page 12: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1s

The Electronic Configuration of Lithium (Li)Li: Z=3 Li has 3 electrons.

2nd shell

- The 2nd shell (n= 2) has 2 subshells which are s and p.

2s2p

Page 13: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1s

The Electronic Configuration of Lithium (Li)Li: Z=3 Li has 3 electrons.

2nd shell

2s2p

Li 1s22s1

2s

Li 1s Electronic configuration Orbital Energy Level Diagram

Page 14: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1s

The Electronic Configuration of Berylium (Be)Be: Z=4 Be has 4 electrons.

2nd shell

2s2p

Be 1s22s2

2s Be 1s

Electronic configuration Orbital Energy Level Diagram

Page 15: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 16: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

subshell - designated by s, p,d,f - refers to the shape(s) of the area in which the electron can be located. - also designates an energy level within the shell. - relative energy: s < p < d < f

s subshell: spherical1 orbital

p subshell: pair of lobes

x y z

x

y

z

Page 17: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Our Orbital Picture of Be

The first shell (1s) is filled.The 2s orbital has 2 e- present.The 2p orbitals are empty.The 2p orbitals have room for 6 e-

Page 18: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 19: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1s

The Electronic Configuration of Boron (B)B: Z=5 B has 5 electrons.

2nd shell

2s2p

1s2nd

shell2s

2p

Be 1s22s2

2s

Be 1s

B 1s22s22p1

2p 2s

B 1s

Page 20: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1s

The Electronic Configuration of Carbon (C)C: Z=6 C has 6 electrons.

2nd shell

2s2p

1s2nd

shell2s

2p

B 1s22s22p1

2p 2s

B 1s

C 1s22s22px1py

1

2p 2s

C 1s

Page 21: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Our Orbital Picture of C

The first shell (1s) is filled.The 2s orbital has 2 e- present.2 2p orbitals have 1 e- each.

Page 22: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 23: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

d subshell: double dumbells

xy

z2

xz

x

y

yz

x2-y2

Page 24: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 25: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 26: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Atomic Radii within a Group

Lithium (Z=3); n = 2

Sodium (Z=11); n = 3

++

+

e- 2e-

8e-

2e-

++++

e-

+

e-

Hydrogen (Z=1); Shell (n)=1

Page 27: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Lithium (Z=3)n = 2

++

+

e- 2e-

Beryllium (Z=4)n = 2

Boron (Z=5)n = 2

++

+

e- 2e- e-

+ ++

+

e- 2e-e-

e-

++

If protons were light bulbs….and electrons were moths…...

B

e-

e-

e-

Be

e-e-

Li

e-

++

+

e-

2e-

++

+

e- 2e- e-

+

Page 28: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Lithium (Z=3)

++

+

e-

2e-

Beryllium (Z=4) Boron (Z=5)

++

+

e- 2e- e-

+ ++

+

e- 2e-e-

e-

++

In

crea

sin

g

Increasing

Page 29: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

1A(1)

8A(18)

11H

1.0082A(2)

TRANSITION ELEMENTS 3A(13)

4A(14)

5A(15)

6A(16)

7A(17)

2He

4.003

23Li

6.941

4Be

9.012 8B

5B

10.81

6C

12.01

7N

14.01

8O

16.00

9F

19.00

10Ne

20.18

311Na

22.99

12Mg

24.31

3B(3)

4B(4)

5B(5)

6B(6)

7B(7)

(8) (9) (10) 1B(11)

2B(12)

13Al

26.98

14Si

28.09

15P

30.97

16S

32.07

17Cl

35.45

18Ar

39.95

419K

39.10

20Ca

40.08

21Sc

44.96

22Ti

47.88

23V

50.94

24Cr

52.00

25Mn

54.94

26Fe

55.85

27Co

58.93

28Ni

58.69

29Cu

63.55

30Zn

65.39

31Ga

69.72

32Ge

72.61

33As

74.92

34Se

78.96

35Br

79.90

36Kr

83.80

537Rb

85.47

38Sr

87.62

39Y

88.91

40Zr

91.22

41Nb

92.91

42Mo

95.94

43Tc

(98)

44Ru

101.1

45Rh

102.9

46Pd

106.4

47Ag

107.9

48Cd

112.4

49In

114.8

50Sn

118.7

51Sb

121.8

52Te

127.6

53I

126.9

54Xe

131.3

655Cs

132.9

56Ba

137.3

57La

138.9

72Hf

178.5

73Ta

180.9

74W

183.9

75Re

186.2

76Os

190.2

77Ir

192.2

78Pt

195.1

79Au

197.0

80Hg

200.6

81Tl

204.4

82Pb

207.2

83Bi

209.0

84Po

(209)

85At

(210)

86Rn

(222)

787Fr

(223)

88Ra

(226)

89Ac

(227)

104Rf

(261)

105Db

(262)

106Sg

(266)

107Bh

(262)

108Hs

(265)

109Mt

(266)

110

(269)

111

(272)

112

(277)

INNER TRANSITION ELEMENTS

6 Lathanides58Ce

140.1

59Pr

140.9

60Nd

144.2

61Pm

(145)

62Sm

150.4

63Eu

152.0

64Gd

157.3

65Tb

158.9

66Dy

162.5

67Ho

164.9

68Er

167.3

69Tm

168.9

70Yb

173.0

71Lu

175.0

7 Actinides90Th

232.0

91Pa

(231)

92U

238.0

93Np

(237)

94Pu

(242)

95Am

(243)

96Cm

(247)

97Bk

(247)

98Cf

(251)

99Es

(252)

100Fm

(257)

101Md

(258)

102No

(259)

103Lr

(260)

Ideal Gas Constant: R=0.0821 L atm mol-1K-1

1 atm = 760 mm Hg = 760 torr

Period

Page 30: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

First Ionization Energy

Lithium (Z=3)

Sodium (Z=11)

Hydrogen (Z=1)

+ e-

++

+

e-

8e-

2e-

++++

e-

+

e-H+

++

+

e- 2e-

Li+

e-

8e-

2e-

++++

Na+

Page 31: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

First Ionization Energy

++

+

e-

Lithium (Z=3)

8e-

Sodium (Z=11)

2e-

2e-

++++

e-

+

Hydrogen (Z=1)

e-

D

ecre

asin

g

Page 32: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Lithium (Z=3)3 protons screened

by 2 e-

++

+

e-

2e-

Beryllium (Z=4)4 protons screened

by 2 e-

Boron (Z=5) 5 protons screened

by 2 e-

++

+

e- 2e- e-

+ ++

+

e- 2e-e-

e-

++

1 e- removed = 2s0 1 e- removed = 2s1 1 e- removed = 2s22p0

D

ecre

asin

g Decreasing

Page 33: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Lithium (Z=3)3 protons screened

by 2 e-

++

+

e-

2e-

Beryllium (Z=4)4 protons screened

by 2 e-

Boron (Z=5) 5 protons screened

by 2 e-

++

+

e-

2e- e-

+ ++

+

e- 2e-e-

e-

++

D

ecre

asin

g Decreasing

Page 34: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

In

crea

sin

g

Increasing

Trends in the Periodic Table

Atomic Radii (Size)

First Ionization Energy

D

ecre

asin

g Decreasing

Page 35: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Electron Affinity

++

+

e-

Fluorine (Z=9)

8e-

Chlorine (Z=17)

2e-

2e-

++++

7e-

7e-

++

+

2e-

8e-

F-

e-

8e-

2e-

++++

8e-

Cl-

Page 36: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Trends in the Periodic Table

D

ecre

asin

g

Decreasing

Electron Affinity

First Ionization Energy

D

ecre

asin

g Decreasing

Page 37: 1 h 1.008 3 Li 6.941 11 Na 22.99 19

Predicting Stable Ions

8e-

Sodium (Z=11)

2e-

++++

e-

e-

8e-

2e-

++++

Na+

8e-

Chlorine (Z=17)

2e-

++++

7e-

e-

8e-

2e-

++++

8e-

Cl-