ENV ONMENTAL PROTECTION AGENCY "TVPi j Office of Enforcement \ ^ L-^ '- if \^J

CHAIN OF CUSTODY RECORD

001506

001507

PROTECTION AGENCY HWI

INORGANICS TRAFFIC REPO(7) Case Number-

Sample Site Name/Code:0 SAMPLE CONCENTRATION

(Check One)———— Low Concentration————— Madium Concentration0 SAMPLE MATRIX

(Check One)———— Water—— *— Soil/Sediment

("$) Sampling Office: j_-Sampling Personnel:

(T\Jam<=>)fPhone* . , •Sampling Date:(Begin) fEndl

0 Shipping Information:NimeOf Carrier.

DatiaShirtpi'sf*' _.,„ . .

fiirhif] IMtimher- , , .-

@ Sample Description:(Check One!

——— Surface Water———— Ground Water——— Leachate——— Mixed Media-- ,-^- Solidsr*K-r

(specify)MATCHES ORGANIC SAMPLE NO •

(3) Mark Volume LevelOn Sample BottleCheck Analysts required

. .: Total Metals. * Cyanide

0 Ship To:"*' '* 'f ' „- : :' '

Atte: , t . . ; - . .- -'IVaiwstoar * • * * * ' '*Ship To:

0 ANALYSIS U«J- k

B^ v r3Jj)Ufl 'l(iMh<Jr\rw.^.ty \» i ^-3@Saznpld Coa6^oxt _ -On Receipt; • -

{eg broken, leakage^ chaiii$i custfxiy, etc)nin(j( :

. . . . . . .

LABHLECOPY

001508

TO Jl POI/**Inrtxrlw(T) CaaeNumher:

Sample Site Name/Code:0 SAMPLECONCENTRATION

(Check Ona)——— |l — Low Concentration————— Medium Concentration© SAMPLE MATRIX

(Check One)———— Water—— t^L- Soil/Sediment

g) Samplino Office: t y.Sampling Personnel-

(N^m^^ ' .• / -(Phone) - . _ ' ' •-'Sajnpling Date; _ ,(Beam! (Endl

(e) Shipping Information:Name Of Carrier-

/. ,

DflFA Shipped: -

fl irKil lNt.mhftr- ' t , '

© Sample Description.:(Check One)

——— . Surface Water———— Ground Water- ——— Leachate

. .Mixed Media-i..i A;'' Solids

r>Ke>r(specify)

MATTHFRORGflNTr SAMPT R NO . „,'„'.,.,.

(t\ Mark Volume LevelOn Sample BottleCheck Analysis required

„ ' Total Metals^rOyunlde

, „. —— , — „. , «, T,-W,.__, — _. ———0 B l ; "

• ' ,1 i> 7 -f **, f . r . - . ^ , ;„,-/.' . /• . f • S f / - 7 C V

_ * ( ; , • 1 , , ' , f-

Atto: '.' • ^-. - -t A- p

Trajas&HT • .Sh l! -

(?) ANALYSES LAB:*^^C]^&ftAHk\H^AR^^I. *-M * ' '"

Sample ConditionOnReoe% : i

{eg broken, Ieak»ge, c in of custody, eta.);\^' it•l• '. . •

LABFILECOPY

001509

A TU: PROTECTION AGENCY' HWT Scruple M

INORGANICS TRAFFIC(7) Case Number: , .... . , ' J 'l

Sample Site Name/Code:0 SAMPLE CONCENTRATION

(Check Ono)———— Low Concentration0 SAMPLE MATRIX

(Check One)———— Water———— Soil/Sediment

r— — ——————————————————— ——————————————————————fc$y Sampling Office:

Sampling Personnel

fMAmnl

(Phone 1Sampling Date(Beam) (End)

(s) Shipping Information:Name Of Car net.

r>»ff> .^Mpp^rf _A'rhiP NFT^V^r- n i i , p , ,. ,

© Sample Description:(Check One)

——— Surface Water——— T tarounu Water——— Leachate

Mt«-aH Media___ Solidsothfir • - • .6,'.-'- > '

(specify)MATCHES ORGANIC SAMPLE NO. —————

f$\ Mark Volume LevelOn Sample BottleCheck Analysis required

. Total Metals_ Cyanide

, „ . . . . , . . ,,,..,,,,_^ . ^ , . . , „ . . . .(«) Sb^»lG»; |1-• : ^--. »*;

AfefaxTransferSls^tTo:

© ANAI..YSIP.TO:p^Kr <'w#&Au\1 "" . •"" ^Da*«H«ririt- ' . 1 * - t'''4'

®Sample Cond^teonir*\BB *^ * ••IIMMI'I^B L ' -Un necca^t: ^

Eeg broken. Ieafeage!, ?h«iEic^ custody, ate.)M • 1 If

"." T

LABFILECOPY

001510

U.S. ENVIRONMENTAL PROTECTION AGENCY HY ~ Scrapio

INORGANICS TRAFFICT Case Number:

Sample Site Name/Code:SAMPLE CONCENTRATION

' (Check One)—— Low Concentration—— Medium ConcentrationSAMPLE MATRIX

(Check One)—— Waterii Soil/Sediment

) Sampling Office:Sampling Personnel:

(Name) .^U_TJ____:{Phone; 'Sampling Date.(Begin)_____ (End)

(e) Shipping Information:Name Of Carrier-

Date Shipped: ______j. __ _!_"_!Airbill Number: 'l

© Sample Description:(Check One)

——— Surface Water——— Ground Water——— Leachate——— Mixed Media_ _-—_ Solids___ Other __________{specify}MATCHES ORGANIC SAMPLE NO.

'a) Mark Volume LevelOn Sample BottleCheck Analysis required

__ Total Metals

LAB FILE COPY

TransferShip To:

® ANALYSIS LAB:Reed by: OqSJ

Date Reed:

On Receipt:(eg broken, teakftga, c^Kiin erf custody, «tc.)

001511

f AL PROTECTION AGENCY HWI Samle

INORGANICS TRAFFIC REPORT(?) Case Number: . ' M

Sample Site Name/Code:@ SAMPLE CONCENTRATION

(Check Ons}——— '• — Low Concentration————— Medium Concentration® SAMPLE MATRIX

(Check One)————— Water—— ,. — Soil/Sediment

j (J) Sampliztq Office: "- 7/T"Sampling Personnel:

fName! ' - -' • 1 - ,(Phono) / , • , *Sampling Date: - - - ' •/ » . ' /

' x <•<Beoin} (End*

(«) Shipping Information:Name Of Carrier:

r r c^DateShmped: ' •' '' '

Airbill Number: - - ' '" / -"

© Sample Description:(Check One)

———— Surface Water———— Ground Water

X'fiTCM^ ^A^r^t^*

——— SolidsOfhor 1

(specify)MATCHES ORGANIC SAMPLE NO —— t ——— i

(s) Mark Volume LevelOn Sample BottlsCheck Analysis required'Total Metals

„ -^fy&nitlB

\ V

0 SBup1)K:i:: 1:' / . J I A M "' • : . * . . • ' ; ! .

'' ' ' . • X. ' . . - - > t tl . ™ • t r ', , _ ., ? - -_Attn: - -r- ,ilfc--^^' • —— ——TransferShip To:

(?) ANALYSES UP:y u :: . , \n.t.B^.' HSV ' t r -J

Sample CondStiooOn Receipt:

(eg broken, leakage, chain of custody, etc )/ UO lU

LABFUECDPY

001512

11 January 1986

USEPANEIC Contract Audit Team12600 W. Colfax, Suite C310Lakewood, Colorado 80215Re: Contract No. 68-01-06880; Case No. 5421

CC Report No. 542 1 , SOW No. 784

Enclosed are the analytical data and quality assurance for case No, 5421received from Region VI on January 13, 1986.Please note the following:

1. Enclosed is the resume for Kathryn D. Whitwortb, a chemical technicianwho will be performing cyanide analyses for this contract.

2. One ml of LOGO ppm Barium (Spex lot # 0485RS) was added to EPA concentratewp .:84 before dilution. EPA WP 882 , which does not contain barium, is usedbecause Ca, Mg, X and N'a are at appropriate concentrations for ICPES analysis.

If you have any questions or comments about this case, please call me at thenumber listed below.

Sir.~erely,

Re> ca H. BurrisDocument Control Off i cer

RHB/clEnclosure

8501 Mo-Pac Blvd. / P.O. Box 9948 / Aust i n . Texas 78766; (5 12 )454-4797

001513

RADIAN

KATHimi D, WHITtfORTH

EBUCATIQK:Del MarBig Spring,TX, September

Corpus Chrisei, TX, January - May 1978; Howard College,September 1974 - Hay 1975; Bee County College, Beeville,

1972 - May 1973.

EXPERIENCE:

Chemical Technician, Radian Corporation, Austin, TX, February 1985-Present.Claims Clerk, Prudential Group Health Claims, Austin, TX, January1984-January 1985.Laboratory Technician, Lower Colorado River Authority, Austin, TX, May1982-December 1982 .Senior Laboratory Technician, Conquista Project, Falls City, TX, March1979-May 1982 .Laboratory Technician, Panna Maria Project , Nobsou, TX, October1978-February 1 9 7 9 .

FIELDS OR EXPERIENCE:

Ms. Whitworth has worked in Radian Analytical Services' Water QualityLaboratory since February 1984 as a Chemical Technician. Her job dutiesinclude analysis of water and wastewater by EPA and SM techniques. Sheperforms classical wet chemistry analyses by colorimetric and titrime-tric methods. Physical parameters of dissolved solids and oil and greaseare done gravimetrically. In addition, Ms. Whitworth has gainedproficiency in the following instrumental analyses: Technicon Auto-analyzer II, Beckman 915-B Carbon Analyzer , and Oil and Grease Analysesby IR. Also, secondary area of proficiency include ion chromatography(Dionex Model 16 and Model 2 1 10 i ) , automatic t itrat ion (Metrohm Auto-t itrator) , and TOX (Dohrmann Model 2 0 ) .In addition to her analytical dut ies , Ms. Whitworth performs extensivepreventative maintenance on the equipment:. She is also responsible forthe preparation of chemical standards, analysis reagents, and general labwork.Since beginning work at RAS, Ma. Whitworth has gained experience in theanalysis of cyanides in water and sediments. Due to her expertise incyanide analyses, she is a participant in Radian Analytical Services 'Contract Laboratory Program as a Classical Inorganic Techniques Analyst.Ms. Whitworth'a laboratory experience prior to Radian include environmen-tal analyses for the Lower Colorado River Authority, quantitativeanalysis for uranium mining and milling, and quality control*

001514

DOCUMEKT

H3H£s Serial * *> €ag$ # - Region - Ifcea&gsd Document

DQCUt-lBffiS

REPORTSTAGS (NEIC only)

(L^CHAIN OF CUSTODY ( "(IKAIRBILL { "f^Y RADIAN SATtPLE RECEIPT ("(t-T^ADIAN IORKORDER ( "( } TELEPHOME LOG

REPOPT PKG

ICP DM*A(-^Benchsheet?(i^lnstr Log J '( *TStd Sources - /

Data

GRAPHITE FURfJACE DATA<T CALCULATION SHEETS

AS

nstr LogPaw Data

SEBI&L # OP PM5RS

0102030405

j- 06-- 07

.- 10

— Tfl

25

30

CASE I - REGIO!ORIGIHM.

001515

M» *•»« •!• . • •:C O R R O Wl»T ION

PA6E 1CLIENT:PROJ:COMPANY

FACILREP

PHONE

TAKEN^TRANS^P TYPE

REPORTTO

AfTENINVOICE

TO

ATTENP 0 #

Jt PREV

Analytical 5e?v WORK ORDERCLP 1NORS CON: WJFORD GAT:6RQUP 10 01/13/86 13 : 17 :59USEPA .. . . . . . . . . . . . . . . . . . __„.. . . . . . . . . . INVOICE BY R DEPTS/ DASHinof oanic ...... XFB..^...Linda Haas . . . . .7Q3-557-34TO .case 5421. rfc&J&n 6CDM£e^ Ex . . . . . . . . . . . : . . . , .

USEPAContract Labor.atoru ProaramBox 818 . . . _ . . . .^^tJt»TWir4fl-» 1VftJ22J|^3SMOAccounting .Qf.£lc« <PH5'-32)Financial fla&a&aaieftt DivisionResearch Trian*ale ParkNC S7711Accountina Of $!c«r_contract &S—Oiii^fo^©0TRf^^OIlT Re^O^TED INVOICED

X SURCHARGE TESTS% DISC: AU-

TEST/JOS 02 A# REP/INV 3 3 03 144

SAMPLES &KEEP FOR 6OKEEP TIL O4/13/8&

DISP SQUOTED *SAHPLE * 2352. OO 11 5

MISC *TOTAL * 2332, OO

INV #CREATED Ol/ 13/36WRITTEN 01/13/86

TRANSMIT Ql/13/86COMPLETEREPORTEDINVOICEDTOTAL *

Q1AO1B02AO2BO3AO3BO4A04BO5A05B06AG68

——— -

LAB 1 86-01-04?RCVD: 01/13/86 DUE: 02/12/86STAT: TRANSMITTED 01/13/86

SAMPLE IDENTIFICATION JQSMFC O2O Iw -fie lds blank 1AND2MFCMFCMFCMFCMFCMFCMFCMFCMFCMFCMFC

O2O Itii field blank038 Is038 IsO39 Is039O4O l-s040041 Is041042 IsO42

1 2 31 2 31 2 31 2 31 2 3

WORK ORDER COMMENTS

001516

U.S. ££A Contract Laboratory ProgramSaaplfi Managatoant OfficeP.O. Box 8Ib - Alexandria, VA 22313703/557-2490 TO: 8-557-2*90 Date

COVER PAGEANALYSES DATA PACKAGE

SOW Q.C. Report No

Ub ID No. EPA No. Lab ID No

Cotmienes:<^

ICP Interelement and background corrections applied? Yes No ___.If yes, corrections applied before v or after ____ generation of raw data,Footnotes:NR - not required by contract at this timeForta I:Value - If the resulc is a value greater than or equal to the instrument

detection limit but lass than the contract required detection limit,report che value in brackets ( i .e . , [ I O J ) . Indicate the analyticalawthod used with P (fot ICF/Flamc AA) or F (for furnace).

- Indicates element was analyzed for but not detected. Report with thedetection limit value ( e .g . , 10U) .

- Indicates a value estimated or not reported due to the preaanca ofinterference. Explanatory note included on cover page.

" Indicates value determined by Method of Standard Addition.- Indicates spike sample recovery is not withia control limits.- Indicates duplicate analysis is not within control limits.- Indicates the correlation coefficient for method of standard addition isless than 0.995

0

- 6

001517

Fora IU.S. £?A Concracc Laboratory ProgramSae?i& Manageseae OfficeP.O. Bex 81* - Alexandria. VA 22313703/517-2490 ft!:. 8-557*2490

SAMEsou so.LAS SAMPLE ID. NO.

|EPA saapla No

DaceINORGANIC ANALYSIS DATA SHEET

CASE MO.

QC REPORT MO.

Elements Idencified and MeasuredjConcentrat ion: Low *•

Mac

I.2 .3 .4.5.6 .7 .8 *9.10.1 1 .12 .

nx: Water Soil

,— *— 7 //Aj-uainua O / {/(Ancisonv 1 ty Ll $\Arsenic /. ^?^/,> ^Sariua 1 1 L{ServLliuo ,V7WCadaiua /, ^,/Caicma C_5~7 \Chrataiura -3-^lLCabals j~T. / /Coooer ^2. 8Utron I3.ULLead /./^- /t

^^*-~~*~' ~*X

rfg/!cg/r£f*PPpp9P9P

f-Cyanide ri4Ld£~ fcnn H A

1 4

15161 718192021222324

MediuaSludge Ocher

weight (Circle One)Matmesium f? / IA~Manganese . ~7 (AMercur'' 0.&3&H

. Nickel & {&UPoe^ss iua /(JolsLSelenxaa /• £ tjSilver c^?- 3LLSodium t- / 3tf )

. Thallium $ . $7u

. Tin 4-. ^7^4 f

. Vanadiua I^Hi

. Zinc 3' 3 H

/? &v*pp#. ffc ppff}p

Percent Solids (*) \;f€&'C(ft?1/W&lfe>Footnotes: For reporting results to EPA, standard result qualifiers ara used

as defined on Cover Page. Additional flags or foocnotas explainingresults Are encouraged. Definition of such flags muse be explicitand contained on Cover Page, however.

_!xAn_aau.eQu$ $g] L blank ' -fn ft,

Lab .'Unager

001518

Fora IU.S- SPA Concrace Laboratory PrograaSacpie Management OfficeF,0. Box 818 - Alexandria. VA 22313703./S57-249Q FTS;. * *557-2t90

IE? A aaapia No,

SOU NO. ____LAS SAMPLE ID. ;

BacssANALTStS DATA SH££t

CASE NO.

QC REPORT NO.

Elements IdetiCifitsd and MeasuredConcentrat ion:Matrix: Water

1. Aiuainua2. ABCiaonv3. Arsenic

Low 2</</-^^ MediuaSoil ->* Sludge Ocrter

/ug/L 'or sag/kg dry weight (Circle One )

1 ^ . Manzanese15 . Hercurv

4, Sanuai 16. Nickel5. Bervlliua6. Cadalun7. Calciuo8. Chrasaiua9. Cobalt10. Coooer1 1 . Iron12. LeadCyanide __ /Of

17 . Potass ium18. Seler-iuta19 . Silver20. Sodiua21 . thallium22. Tin23. Vanadium24. Zinc

I/ SL- Percent Solids (*)Footnotes : Foe reporting results to EPA, standard result qualifiers aca used

as defined on Cover Page. Additional flags or footnoeas explainingrasulta are encouraged. Definit ion of such flags oust be explicitand contained on Cover Page, however.

Consents:

Ub Manager

001519

Fora IU.S. E?A Contract Laboratory Program

ii Manageaeat Office, Sox 816 - &l*x«ndri*, VA 22313

E? A No.

DaceANALYSIS DATA SHEET

CASE »0.sow so. ?^^LAB SAMPLE ID. NO, I^DIDLf?"t

ElementsConcentrat ion: Lotf vMatr ix : Water Soil

ug/L or aV.

1 . AJ. as! sum fa (0CO_ i r - -. O / /V O

3. Arsen ic ^i j?, b 1 & /t

03. QC REPORT NO, 5^?/

Identified and Measured

s42—-""

P

f

MediuaSludge Ocner

)dry weight (Circle One)13. Magnesium / Qff^-) J P14. Manzanese 13 - l\ P15. Mercur*' f 0 . £-4-~~] cvrftf

ft. Sanum /. 3_ O 73 /^ 16. Nickel h> &LL. p5. 8«rvi:iua . fyQLL6. Cadoiua /. $ UL7, Caici.ua / /£r'/'£)_^8. Chrcaiua / ^,$ _j9 . Co bal t ^, *5 (jL10. Cotsner -*},OLL-U. Iron _337<012. Lea^d _ ^/ ^Cyanide ^ ^. -^//y, x^FoocnoGcs : Foe reportir .tr results

PPPPPPP/r

to F

17. Potassium ^^^^ _> p18 . Selenium / * & ? £ - * • $ £ X=19. Silver o>- 5 IL R p20. Sodium ^5!O"7"3 /°21. Tha.Uium ^. ,?/^< A22. Tin .^, 0 M ^23. Vanadium I^LL f>24. 2inc /T^-7~3 /*Percent Solids f") <7^

:PA, standard result aualif iers are ustas defin«d on Covar Page. Additional flags oc foocnocas explainingresults ar« encouraged. Definition of such flags muse be axpiici:and contained on Covee Page, however.

Co cm eat s :

Lab Managar

001520

uOQc

133

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340coT3Oc--4*du?•TJC*

001521

Fora IU.S . £PA Coneraee Laboratory ProgramSacple Manageaeat OfficeP.O. Box SIS - Alexandria, VA 22313703/557*2490 ?T$J

|E? A Saapie No

INORGANIC ASALmS DATA SHEET___. . . CASE NO. _.g>MjM

sow sc.LAB SAMPLE ID. MO. Tl0QlO{47'03 QC REPORT MO.

Elements Identified and MeasuredConcencracion:Macr ix : Uacar

1. Aluminum2. Anciscnv3. Arsen ic4, Bariua5. Berviiiuta6. Cadaiua7. Calciua8. Chrataiuta9. Cobai:10 , Coocer1 1 . Iron12. LeadCyanide

Low vSoil i/^

ug/L °r/^AgJlir7JWDO 1> u^53 /? ^ u

Q.& ^ /L ? 15^"^<? 3 ^ 1 6^"o2, "1 /^ i7

t.5U P is3^5/9 ^ 19£7 p 20^O ^ 21^4 ^ 22i-l <55£Q P 23^.^ A. .5- X 24

HediuGSludge

weight: (CircleHasnesiufflManaanese

. Kercurv ,. Nicxel

PoeassiuTa iSeleniua

. Si lverSodiumThallium

. TinVanadium

. Zinc

Oc.ner

One).3 /CO _.. P*-li£ft R P

<?.0f& u Cv##4-0 Pr^uo] P/.3u$ ^_ ^

o?, k>« /? /^fi030~l Pf. 9-^u ^.#I/.^_- ... . . . . . ^703 ^f-fO P

O.ljtu % Percenc Solids (t) ^/5_Foocnocas : For capocclng results to SPA, standard rasulc qualiftars are used

as dafined on Covar Page. Additional flags or foocnoces «xplaiair.geaaulcs are encouraged. Definit ion of such flags muse be explicitand contained on Covar Page, hou«v«r.

Cotamants

Lab Manager

001522

Fora IU.S . E?A Contract Laboratory PrograaSadpla Managesent OfficeP.O. Box 818 - Alexandria, VA 22313703/557-2490 fTSi 8»5S7*2490

Saapit .No

Date

ussou so.

ANALYSIS DATA SHUTCASE MO.

LAB SAMPLE ID. NO. <5(&Q\ 0^47 QC R£?ORT MO.

Concentrat ion:Matrix: Water

Elements Identified and MeasuredLow

SoilMedina

Sludge ___ Ocner

1 .2.3.4.5.6.7 .8 .9.10 .1 1 .12 .

Alusunum

Arsenic3ariua

CaiciuaChrsaiuaCobaltCoonerIronLead

Cyanide

ug/L or jfig/tcgjlry weight (Circle One)P 13. Maenesiura

.5114

&J.

Cctoaencs:

R

£P

Percent Solids

P14 .

15 .16 .1 7 .1 8 .19 .20.2 1 .22 .23 .26.

Manganese o?*-/Her cur*' & •# 3*7 Nickel __ /^ / UPocass iua £*d2. / *? 7^Selenma / y'^-/,^ ^Silver o?. 6? i^Sodium ^_\ "5>(-?/ ^3Thallium ^ , *7/^/Tin ^- / u tfVanadium /^ ^,(2inc /LA S^^ 5

/? p0p

£ fp/=•fp

Foocnocaa: For reporting resales to EPA, standard rasulc (tuali*i*rs are usedas defined on Cover Page. Additional flags or faacnocas explainingresults are encouraged. Oefinic ion of such flags BJUS: be axplici:and concainad on Cover Page , however.

Lab :una««:

001523

Fora IU*S. £?A Concraec Laboratory ProgramSac?la Managasenc Off icef.O* Box 818 - AlaxandrtA, VA 22313

sow N°-LA3 SAMPLE ID. NO. Qjj [7~

[EfA baa? la So.

DaceXH0RGANIG AWALTSIS 0AtA SHE&T

CASE NO.

R£?ORT MO.

Identified and MeasuredConcencrac ion :Macr i . t : ' »Jacer

1 .2 .3 .4.5 .6 .i8 .9 .10 .1 1 .12 .

AluainuasAncizonvArsenicBariua8er''lliuaCadaiuaCalciuaChrataiasCobal:CoolerIronLead

Low ySoil v^

/- —— Nug/t or^jag/k-gyd

^-5 /? /c?/4 J £. £

/Oh P.f53Lt P/, ts?U P%3ffOD P

- ./.9, ^_/"77"7 . . .. ^./"//T" /^-g- —— UL~_j ————————————— ™,

"7 / "vWn /9<V--/ oL.-'LJ r6". <=> J- ^

Cyanide & . iJ / ,, tf"Illar i .if in B _- '. ' . L \. __ . /!_ - . _ . _ . . . .. . . . . ..

ry ^13 .

15 .16 .1 7 .18 .19 .20.2 1 .22 .23 .

MedianSludge Other

/eight (Circle One)Matrnesiua £>$*JOMansanese 7/ 9Mercur*' ^. ^?Mickel o{ 7Pocaas iusn o2(^o?fy

Si lver <3.~7USodiuta / o "3/>2 >Thallium & . tf$nTin 5T 4 uVanadium r*5 /Zinc 3^

Pereanc So Lids ( *) ( ,P

pf{ p(f t/tftf

pp£d Pj)prPP

Fooenoce s : For reporting results to EPA, standard rasulc qualifiers are usedas daflned on Co^er Page . Additional flags or footnotes *x?lainir.gresults are sncouraged. Definition at" such flags ausc be axpiici:and concainsd on Cover Page, however.

Coomenes:

Lab Manager

a -

001524

Fora IU.S . £?A Cone race Laboratory ProgranSacale Manageaanc Ofiicef .0 . 3ox 818 * AlAxandria. VA 22313703/537-2450 fT3: 8-557-2490

E? A Saapii No

INORGANIC ANALYSIS DATA SKtETLAB »AM£ JSQJWrsow so, "7^LAB SAMPLE ia. .vo.

wJl^Oum-l-O^CASE SO. ,3*-fc*ZI

QC REPORT N'O. ^Mj '

Element s Identified and MeasuresConcentrat ion:Matrix: Wacar

1. Al^2Linuoi2. Ancisonv3. Arsan i c4. 3arlua5. aer-'ii iua6. Cadaiu=7. Caiciua8. Chrooiuo9. Cobalt10. Coooer1 1 . Iron12. LeadCyaniie ^.Footnote s : For rap

Low \/Soil v/

/*—ug/L argg/fcj

^/ ^ ^/4 j JL f

135 P5*4 IL ^l.bU P

G3CD P-}^ P&< / r

1*4 P<338PO P/1 £ ?$#u SLorcing results to

MediuaSludge Otner

pdry weight (Circ le One )13. Maenesiuta L33&O1 < * . Manzaneaa <=»-?c2 /15. Mercur 1 ' /• &16. Nickel £/ <717 . Potasa iua ^/^r^t^?18. Seleniua /,3u$ &19. Si lver c?*7U20. Sodium ZT^TfO ~^>21. Thailiua <T . ^//22. tin *?.$&&23. Vanadium ^(J24. 2tnc ^>J2_Percanc Solids (*) QO

£PA. standard result qualifiers

pR PfiP^

/? PpfI*PP

are usias defined on Cover Page. Additional flags or footnotes explain!?.;results are encouraged. Definit ion of such flags muse be explicl:and contained on Cover ?aga,

Cooaenes:

Lab anagert>CQ

001525

UA HAttf

II-Q. C. (Upoe-t Ho.

IHZTUL AWD eOKtlHUlHft CALIBRATIONass HO.SOW 80.

Co^rol

.X./5" r/_7.Calihracion Source /-CQnciauing caabraci« Source

* a I , " "CUr7 "d TlnIndicac* Analyeical Machod Ug«d: P - AA; F - ruraace

B " 8

001526

1A

001527

FeraII -AQ. C. Report No*

LAS NAME

OATS //* /*&

INITIAL AND CONTINUING CALIBRATION VERIFICATION3

_____ CASE NO.SOU NO.

___ QUIZSConpound Initial Continuingit1 . Aluminum2. Ancioony

JL3. Arsenic*. Barium5. 8«ryllius6. Cadoium7. Calcium8. Chromium9. Cobalt

10. Coooer11. Iron12. Lead13. Magnesiua14. Manganese15. Mercur^— — • —— '— - —16. Nickel17. PotassiumIS. Selaniua19. Silver20. Sodium21. Thallium22. Tin23. Vanadium26. ZiacOther:

Cvanidc

Tru* Valu*ii_ _ i<J3 |

1it1

Found '

S3

2K

^/

„. 1

1

trua Value

4-3

1

Found

¥^

MR

/0$

Found

4-5-

Xft

/£F

\

Method4

/*

'

iiI

i Initial Calibration Source ffii^Jt/f/, 2 Continuing Calibracicsa Source3 Control Limits: Mercury and Tin 80-120; All Other Compounds '90 - 1 104 Indicate Analytical Mechod Used: P - ICP/Flama AA; F - Furnace

- 8

001528

fit PC

Q. C, Report No.

tAB HAHE

CATS

INITIAL AND CONTINUING CALIBRATION VERIFICATION3

CASE KG.

WHOCoHpautid Initial Calib. * Concinuin? Calibration^Metals :i. Aluminum2. Aneinsony3. Arsenic4, Barium5. B«rylliua6. Cadmium7. Calcium8. Chromium9. Cobalt

10. Copper

True Value £2u£i

11, Iron12. Lead13. Magnesium14. Manganese

ZR True Value Found

11

15. Mercurv <$.£> ^ •%16. Nickeli". Potass ium18. Selenium19. Silver20- Sodium21. Thallium22. Tin23, Vanadium24. Zinc^^ iOeher:

Cvanide

**

t

j.f 3.3

*H found

1

ZR

iii

Method*

1ii1

j i!fff \ -» " s*

\111

C,V&?

* Initial Calibration Source Mfi&rfz #& 2 Continuing Calibration Source3 Control Limits: Mercury and Tin- 80-120; All Other Compounds ' 90 - 1 104 Indicate Analytical Method Used: P - ICP/Flame AA; F - Furnace

Si #3

B - 8

001529

03'&

Fora ll-CIQ. C. Report No.

NAMEINITIAL AND CONTINUING CALIBRATION VERIFICATION3

________ CASE MO.SOW NO.UNITS

Coapound Initial Calib.1

Hetals :1. Aluminum2-. Ancitaony3. Arsenic4, Barium5. Serytlius6 . Cadmiutn7. Calcium8. Chroaiuo9. Cobalt

10. CoooerII. Iron12. Lead13. Magnesium14. ManganeseIS. Mercurv16. Nickel17. Potass ium18. Seleniua19. Silver20. Sodium21. Thalliuts22 . Tin23. Vanadium26. ZincOther:

Cvanide

True Value

&.$

Found

. _

£.*j

XR

|1

I

^1

True Value

i

1s.s

Found

<?• 4-

a

^

Found aIMethod6

1

ev#/?

(

Continuing Calibration SourceInitial Calibration SourceConcrol Limits: Mercury and Tin- 80-120; All Other Compounds '90-1 10Tndicaca Analytical Mechod Used: P - ICP/Flame AA; F - Furnace

B - 8

001530

ForaQ. C. Report No.

LAB HAMS CASEONUS

Preparation CalibrationBlank Value

Blank Value Preoaracion Blanlc1 2

1 . Aluminum U.2* Antimony Wit3 * Arsenic

Barium5, BtryUUua6. Cadmium7 . Calcium8 • Chromium9. Cobalt1011

ItuCooer ,C u 6. OnIron £/

12. Laad13. Maonesiura14. Manganese /.0U.

15. Mercury16. Nickel I [llSl1?. PotassiumIS. Selaniuta19. Silver20. Sodium L2 £Z^*- L-UL"~~JL:-LI

21. Thallium /.I LL22. Tin__23 * Vanadium24. ZincOther:

Cvanida /OILfire-p

001531

FormQ. C. Report Ho.

BUNKSLAB CASE HO,

ONUSM-acris

rCCattbrate 3,

PreparationCotaoound

SUtals:1 . Alualnum2. Aseiaony3. Ara«n±c4, Baritua5 . B«rr Ilium6. Cadmium7 . CdXclum3 . Chromium9 . Cobalc10. Cooa«r11, Iron

j^^eiaj^CalibracioaBlank Valu«

<^-^^c

T1

C00£j

I

^-^^

11

suiSKnCj!Blank V

2

f — "" " '

libfaticFalu«

3

_____

a

4Praearae

Iion Blank

2

... -iii

U. UadVrf » *13stn€3 1, tlQl

14, Manganese13. Mercury16. Hickal17. PocasaiumIS. S«l«aium19, Silver20. Sodium21. Thallium2*. Tin23. Vaoadiua24. ZincOther:

Cwanide

I

i•

I

| ______ ,|_

—————

I11

11

. , ! , ._ • i ii

B - 9

001532

fora III -Q. C. Report No.

BLANKSCASE MO.OHITS

CalibraclonPreparationCemoaund Praearacioe Blank

PocaastumSelanium

SodiumThalliumTia

001533

FoemQ* C. Raport Mo.

BLANKSus CASE MO.

owns

fropafaeidaCoooouod

Metals :1 . Aluainua2. Aatiaony3 . Ara sale4. Bariua5. Barvtlium6. Cadmiua7. Calcium3 . Chromium9. Cabal £10. Coot»«r11. Iron12. Uad13. Magnesium

JH4S&&CalibtacionBlaak ?alu«

1

C<5tUi

I

nui flft CjBlank ^

2

i i HE tt £«L-£alu*

3

-

rg

4

1

?r*parae.1

i

Ion Blank ,2

1

1

I

14. Manganese15. H«rcury16. Nickel17. Pocaaaiuai13. Selenium19. Silver20* Sodiua21. thallium^22. Tin .___23. Vanadium24. 2iacOchsr:

C. /£ u.

•

idie*

\\

.

<=?' /-P w.!

i

i ii-iCvanida

B - 9

001534

Q. C. Report Mo.BLANKS

PreparacionCotaoound

|jj&Ct*$CalibracidflBlank Valua

Calibf aciQQBlank Valua Preparation Blank(

1 2 IMctali:1. Aluminum2.3.

Barium5. Beryllium6. Cadmium7, Calcium3.9. Co bait10. Cooe r11* tr_an12.13. Maeneslua14.15. Mercury £0. '3716. Miekei17. Poeasaluta IIB* S«leaius19. Silver20. Sodium21* Thallium22- Yin TF23* Vanadium24, ZincOcher:

Cvanide

w g

001535

JVQ. C. Report No*

ICP INTfiRFEKNCi CHECK SAMPLECASE NO.

19. Silver20. jjpdiua21. Thallium22. Tin23. Vanadlun

1 Mean value based on nICP Interference Check Sample or

B - 10

•rt*.. i:

001536

LA3 N'AME

DATE

Fora V). C. Eteporc No. __ _SPI:<£ SAMPLE RECOVERY

CASE NO,EPA S«a?:« N'o-Lab 5aapi« 10Units

ICentral Limit | Spik«d Sa«ol« I SaaoU• ^^ . •** * **a^""""«^^™* BIfc* I «*H* HMACompound [ It | R**uU (3SR)

M«t1.2.3.

5.6.7 .8.9 .10 .1 1 .u.1 3 .U.1 5 .1 6 .1 7 .13 .19 .20.2 1 .22 .2 3 .24 .

iAluainuffl | 75- 125Anciaony f " /3&Arsen i c 1 " f?3ariua | " /C3QSeryUitrat " | c2£?Cadaiua | " ^2^Calciua (Chroaiua I " | / / 3>£obalc - ^S^Coooer • ILL Ironlead 1 5 Magnes iumManzar.ese ' . =2 *•?Merc-jrv - ^7, ^^Nickel ' o2*?/}Pocass iua " 1Seleniaa - /. ^^Silver - /<9SodiuaThalliua * $ 0^Tin - ^-7^i i"** / j*^t

* t) * * o G J» LiCJI ^ \ **^fi v7—— » — « ————— . _JX v»— *^*r^^

Zinc - ! ^27*4Other :

Cvanidt

| Ram 1C (SB) Add*d fSA) f ?R:

ii i/S53 All ! V/' f.^ ^/ * ^^t ^T9^3 /^7 ! ^6*

r""™^5 *^ "v^ "N ^f , y t-f/ i^' » c^ _j *yt- I iiil.fjtL A1 » /?4i57 i LO^L ' 7^^D j? 7<2 ' SV^^f 7^6^ ( Jff\6-3 <?£ \ /at.

\^(^ c£7<^ \ <3<^LC . Q £&* P && ! /^^Ltr\ ^7.2 i ^) 5

i/ • j */ S • J \ &cv. (j(?\.s\ <=*• 1 t /t-'

j 1^.^c/ ^^ 1 /$<r./u, £•?-& 1 //^/jC3 ^?7c2 ' ^6^

f ^ <9 ^7O- ' ?O1

| ___ iI

- SRJ/5A , x ioo"R"- ^uc cc concrol-oeccncs:

8 - 1 1

001537

001538

gsrg VIQ. C. Report No,

;a?r_:

r? Ko* gfaOtpyi'DZ.

C^ar.zde* Out or Control

ro be added at a later dace . ._ _ l |U

- Son calculable RPD due co valu«(s) less chan CRDLRPD D ) / : j ] x 100

B - 12

001539

VIIQ.C. Sapost Ho.

WSTWMfiHT DETECTION LIMITS AKDLABORATORY CONTROL 5AMPLE

us HAMS KOAWiiLOATS &J/6/ $bi

Compound

1 * Aluminum2. Antimony3* Arsenic4. Barium5. Beryllium6 . Cadmium7. Calcium8. Chromium9. Cobalc10. Coooer11. Iron

Reduirad Dec ace ionLimits (CRDL)-U!?/1

2CO6010

20055

30001050

CAS£ HO.LCS UHITS

;lageruaene Deeaceion |Uffllea (ICL)-y?/l |ICP/AA Furnace 1

/32 !

, , , „ , , ^& fflg/»fi(Circia One)

|Lab Control Satn&le jTru« Found t%_ . .„.„,„n%n / -7*^ /o /^^ //* /^J HT rS

j V/ ! £OOO\ M3P ID fi33

^•^ i &O0 /#& <9& \t j I^DrfY)\'i "7///OA '5<y'7[ 1 a£\J,U(JU \ j /t-fisLA 0 l

1.0 \ £35 £0^ ^13<O 3<1 33 ?S70

25/ /

£jbl 3£7 ?71 £b / £30 %% f

£>,£ j 33^ 305 qOtoo II a.b \ 7Q b 73£> 100

12. Lead 5 113. Magnesium! 500014. Manganese15. X-ireury16. Nickel17. Potassium13* Selenium19. Silver20. Sodium21- Thallium22. Tin23. Vanadium

150 .2

405000

5 ..... .

J. X 1 £$£> 1 -*/-!» ^V

/^^ \3D.OCQ ifflQQ <?/I>O .3^g 5// ^9 f

-*-f) .££> J^tj \f&/nP M~4sT\&££.

/JL£33-

103000

104050

24. Zinc 20Other:

j.4&.Oqq

/,^_

3,0 3.6 /£<?<5C* ' /^v o 7

'"vn fYY)\ i '/^/*y) 0 /O.5"<2 _5"/? /^) ^7~~)f~y^rji \ ~Jt-lf} ^ ~73 *?/) *) 3 *? f3 £/ irtjvtx t&^yZ* ' / i

* | / A

3D gift*, 741 ?Y7. 0 ///r 377 3n

i 1C/anids I 10 /C

i ix^yi // 3? ^J7/&<O 110 i a

8 - 1 3

001540

Q.C* Report So.STANDARD

2 Concensration as deceased by USAr"r" is Ch« correiacion coefficient.

is outside

________________,________-J———————1——added, ABS. is Che iuscrutnent readout in absorbance or

001541