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Grip change due to the presenceof an absorbingStudy conducted within
materialthe frame for the eurooean
standization process CEN TC 337 /WG4 / Wl3
ECOSORBOIL
January 2008
File 200764075
,riffi111:1:#;mxx!
Version history of the document
Ca6e followed by
POISSONNIER St€phanie - Groupe viabilité hivemale gelTé1. +33 (0)3 83 18 31 78, fax +33 (0)3 83 18 41 00Email : Stephanie.poissonnier@equipqrent. gouv.fr
p change due to the presence of an absorbing material - January 2008 -2007640'75
Summary
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L Objective of the studyThe study aims.. :
. To evaluate the performance of an absorbent product itr the contert ofthestanda.rdization work European CEN TC 337 Prerl5366::
o Part 1 [4.6]: Skid resistance ofwet absorbento Part 2 [A7]: Skid resistance ofa road surface after removal ofcontamined
absorbent
2. Test methodsThe test metllods are given in Appendix 7.3
3. CustomerRMOL SrlM. Massimo RicciVia Asti, 100/81OO9O RIVOLIITALIA
4. Absorbent products testedThe identification ofthe producl as given to the safety data sheet is attached ir an appendix tothis reporl 7 2:
. Ecosoúoil - Peholeum hydrocarbons sorbent for a road maiúenarce
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5. Results
5,t Skid resisfance of wet absorbentThe table below shows úe obtain€d results :
Ecorboil Essai I ESSar Z Essai 3 Essai 4SRT initial 63 63 62.2st{t Frnal 54.5 54.4 57 54.4
87 86 90 87qveraoe vaìue 87.7i,lin 86
Max 90itandard deviations 1 .73
5.2 Skid rèsistance oî a road surfacè after removal of contamined absorbentThe table below shows the obtained results:
Ecorboil Essai 1 Essa i2 ' Essai 4SRT inìtÌal 65 62.6 62 50.6sKt Ftnel 64.6 59.6
Ratios 99 89 90 98veft€e 94VlinVlax 993tandard deviations 5.23
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6. ConclusionAccording to the draft standard Pr EN 15366, which applies, at the time this report waswntten:
Part 1: Skid resistance ofwet absorbentThe required minimum valùes is:SRT FinalCoefficient > 80 %SRT initial Coefricient
The product Ecosorboil is conlorm.
Part 2: Skid resistance ofthe road surface after removal ofcontaminated absorbeÍtThe required minimum values is:SRT FinalCoefficient > 85 yoSRT initial Coefficient
The Droduct Ecosorboil is conform.
Document prepared at Tomblaine oll January 11rh, 2008
Le chargé d'étude
4-F-S. P\issonni€r
EcosoóoiL- RLÀ4OLSkid rcsistanceofa oad su.face after removalof contamrned
100,098,096,094.092,0
88,046,084,0
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7. Appendices
' j,ffffiiÈ .1jíffiìr ,.r:'l.'..
7.1 Thè teîetence surface festThe tests axe carried out on resin rqrlicas, from a pav€ment type airbase in Chambley(France). The replicas were made &om tlle following materíals :
. Manufacturing of a negative imprint made of a silicone coating Rhodorsil RTV 585o Manufacturiig from the negative imprint of a positive mofiar acrylic Prodofix FCl.
Verage friction value SRT base at 20 " C oft1rc three Chambley replicas is: 0.62 + 0.02 (base1993).
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7-2 Safety data sheel
Pro.luc( Name/Srîonlms Ecosorboll'q - Petîolem hydrocarbons soóent i'or road maintenance
SECTION I - PRODUCT IDENTIFICÀ.TION
RIMOL Sr',1.Via ̂ .sú, 100,43 issue Date: 1vA7/zoa710098 RTVOLI (TO) ITALYTeleÉone:+39 011 9539274F à i + 3 9 0 1 1 9 5 5 8 7 1 0 P a s e l / 5
M A T t r R I A L S A F E T Y D A T A S H t r E TDir. 9 Ul55 cE - Dii 200 UsalCE -Dir. 20041731C8
Compoúents Sand: ì1me ! cemenl watcr.
Hazùdoùs Componcnts(Dtr.67l548 Ctl) Perccnl bv Weight C A S No.
^luntnium 0,05 1129 9A 5
Potential Hcdlih Elfects:Bves None kno*n.Skin: None knoMbhalation: No hazard in noIml usc of lroductlnsèsiion: No hazaîd in nomaÌ usc ofprodùct
SECTION tr - COMPOSITION, INÌORMATION ON INGREDIENTS
SECTION III - }IAZARDS IDENTITICATION
StrCTION IV - FIRST AID MEASURES
Flîst Ard Procedures:Eycs: IfFitalion occuts, fluh eyes imediately *ìrh laîge amounts olwatcr for at ìcas(
10 minuies and continue flushins mlil imlation sùbsides. If iútation, redness orteadng occur ànd peîsist, consult a physician.
Skin: Use good personal hygide and ùash thoroueHy after handline lf redness orir;tation persisl, contact a physician
lnhalation: Remore to frcsh air. lf sYmptons lersist. consull a phl sicúnIngef;on Contact a physician
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RIMOL S.r.l.Via Asti- 100/8 Issue Date: 1810712007r0098 Rivol-r (To) TTALYîolephone:+39 011 9539274Fax: +39 0l I 9558730 Page 2 / 5
MATERIAL SAFETY DATA SHEETDir. 91/155 CE-Dir. 2001/58/CE- Dir. 2004/73lG
SECTION V - FIRX FIGHTING MEASURES
Flash Poix(Specify Melhod): N.A llalnÌnable (Explosivc) LimitsFlammability Class: N.A. lPercent by VorumerFire Extinguishidg Media: None Lower Explosive Limit: N.A.Special Fire Fighting Procedures: None Upper Explosive Limit: N.A.Unusual Hazards: Refer to absoóed liquid(s) MSDS(s)
SECTION !T - ACCIDENÎAL RELEASE MEASURES
SpÌll or Leak proceduÌeslIfmaterial is unused. s$'eop or vacuum product and dispose of as a non-hazardous lìlaterial- touse agam.
SECTIO\ VII - HANDLINC A\D STORAGE
Handling aDd Stomgc Prccautions: None.Storage pressure: Not applicableShelflife: Not applicableGeneml: Store in a dry place.
SECTION VIII - EXPOSURN CONTROLS, PERSONA], PROTECTION
Eye Protection: Saîcty glasses with side shields is a good industrial pmctice.Gloves: Not normally required. However, use of cloth, canvas or leather gloves is a good
industrial practicc.Respiratory: Nono requùcd 10 nomal use.Ventilation: None rcqrdred to normal use.Other: Use good personal hygiene practiccs: Wash hands belore eating. abhking or usirg
toilet facility.
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RfMOL S.r.l.Via Asti, 100,ts ìssue Date: 18107/200710098 Rtvolr (To) ITALYTclcphoro:+39 0l I 9539274Fax: +39 0l l 9558730 Pagc 3 /5
MAT ERIAL SAFETY DATA SHEETDir. 91/155 CE - Dir. 2001/58/CE Dir. 2004/73lCE
SECTION IX - PHYSICAL AND CHEMICAI, PROPERTIES
Appearance Solid Vapour Pressure(mm of mcrcury): N.A.Odour: N.A. Evaporation Ratcr N.A.Coloul: Light grey Boiling Potut: . N.A.Densitv : 0-5'73 Frcczing Point: N.A.Vapour densitl: N.A. SolubiiiB in Water: 3.3 %
SECTIONX - STABILITY AND REACTI\,'ITY
General Reactivìt]: StableIncompatibilit!: Product may be affectod bv acids.HazadousDccompositionPrcduclsr NotestablishedHazardous Polymerization: ..X.. Will Not Occur ..... Will OccurConditions to Avoid: N A.
SECTION XI - TOXICOLOGICAI INFORMATION
Reporled Human Effects:
Acutc toxicit),:Pimaf, irrìtabihy:
Skin: Not occur.El'c: Nol occur
Reported Arìmal Effects:
Toxicological studies on birds and small mammals have not underlined risks for thc saÌre
SECTION XII - ECOLOGICAI, INFORMATION
Ecotoricil]:
hìcrt prcduct, rlol cnvironmental dangerous.
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F |1e 2007 610'1 5
RIMOL S.r.l.Via Asti, 100/B Issue Datc: 181071200710098 RIVOLI (TO) ITALYTelephonc:+39 011 9539274Fax: +39 0l l 9558730 Page4t5
MATERIAL SAFETY DATA SHEETDir.91/155 CE - Dir. 2001/58/CE - Dir. 2004/73lCE
SECTION XIII - DISPOSAL CONSIDERATION
Waste Disposal Mothods:
Il unuscd, no special precautions are necessary. Dispose in accordance with CE. nationat ondlocal regulations. Be a'ware that natioDal and local requirements may differ widely depending onlocation and may in many cases be different from intemalional rules.
Waste code:
Refer to absorbed liquid(s) MSDS(s)
SECTION XIV - TRAI{SPORTATION INFORMATION
Transport Information:
Materìal not dangerous. No disposition for road hansport (ADR): sea trarsport (lMO); rail.ivayÍansport (RID); ù hansport (ACAO/IATA).No special labels are required.
SECTION XV. REGULATORY INFORMATION
Dispositlon CE
Non regulatedConformed XXIX adcguament
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RIMOL S.r.l.ViaAsti. 100/8 Issue Date: 181071200710098 RIVOLI (TO) ITALYTelophone:+39 01 I 9539274Fax: +39 0l I 9558730 Page 5 / 5
MATERIAL SAFETY DATA SHEETDir. 91/1s5 CE - Dir. 2001/58/CE - Dir. 2004/?3/CE
SECTIONXVI - OTHER INTORMA TION
Ratings are based on Rimol guideliacs, and are intonded for intemal use
Important Notice:
All statemcnts, technical information alld tecommendations set foth hereininfòmation or lests which fumol believes to be reliable as oî the date of this material safetv datasheet. However, nothing contained in this inlormation is to bc taken as a representatLon,guarantee, or waÍanty. fumol rùges persous receiving this infomation to make their o*,1ìdetermination as to the information's suitabilib, and completeness for thoir particularapplication(s).
The data in this Material Safety Data Shcet rclates only to the specific naterial designated hereinand does not relate to use in combination.with any othsr material or in any process.
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7.3 Annex A Pr EN 15 366 : Determination oî the vaiation in the skidresisfance of a road surtace or traflic area caused by the presence of anahsorbent.
Anner A{nomative}1l l
Ileterminriion of tfie variation tu Itre skid resistance of a rsrd 5ulfflce orbafnc area cauBed by the presencé of an aborbéÍi
l- sf{pe'fhb
Fsecol d€É.rlcs hhtrÈbry lest ÍreúodE b rsEÉsE tlE E Íalc.t in *rè slid rÈ6iElrÉ of a rDEd 5urfdcÈflfficr€afce irg hltfsdù.n po did\ btaEd rih ú ibrdbeîL
Part 1: glftt IlsiEkE of wEt*!.rbErd
Fén 2: Slld rEsisàE.I&e rEd surf*è ftrrslEEl €a @ÈÍir# eharùsr
2- RÉfereíffi
RÉJErh Eiardard5 E 5!Orrd EX 1423t e|ld Etl llIÍ16-1 FJÉrd EurDpee.r 5Èndad...1
3- FirciplE
ThÈ lest netlld.orEists !f deùnrùinB úe vri*n in lhe Elil rEEiEÈncè of e |!d-srÉce cr t-dffc arÈótulhriing hÉEÉaÈm Follutií. ha{Èd wilt abs!.bs* lo be led€d.
+ AIÍaratu84-l AFFarafuE
A FetrdÍm ftfin iesbr. as desÈribÉ*l ìn Et{ !9:t1. ril bÈ uE€d todÈb|nú|e the Étii rerthB.e ol{E ro#strfdEe.
ill Re_fetE aa i€sl suÉ*es
TIE rEkErEe lest qrf# re m* .a rEp5ca5 oa rsd BrÍec.5 rftedè of leir rl nhi.h !i* iE 2gl ht2110rnlroftheW10nrtrElE|ni{ÈrfrasÉallcE.ÉÉlellFe,yrihabéíèSRTfrijirf|a#fi.ie.lrsìhEàùm! stid rEsislur in humld corrfóoís $Eaùf ù 5lL es defned i!î El{ 14231, erd E Írm narr!lEqùrE dèpúrSré#th'lo.Etrv, ódefriÉd inE t3{X}E-1_
4: DeionizEd c. demÈtelalized uibr
4-4 ReferEncÉ hddrocarùon
tÈ ÉEtF ludrKrbc.r l|5ed b cqlkntlib'ttE tÉd erh.É rnd the rhEd.ù€nl is of tlE úe5el fuèl ùFè(Etl 590 - Itr 1S - liínerdl €a - Hqrrlal q!+ - Sunrrs tyFe h coú*jes natiE a di5Mjon ryitl !eaÈcns).
4 E€pE rfl# olfEsÍ bl p E nb a rElè futùeacad dt !tè road $rlEce. ^rEEr€íE€ flrm mir !e oÈt{mdb' cnffiq le FfsEl1 L..bc€tie cerFt rt€É PúrE el ct€tEèeÉ {LcFc. ÈlEti rfi[:ÀtÍ.*jcficf+
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A.4.5 Mould
iJ=É e rn- d taÉSaaÈd frDfr i fÉ1 gh€€i 4mn ihilk icm whr:h J rÈ{trnqulrr sprticn !0&1ù0rîm hàs bÈen
5- SFecialinslruelions
These il5ts.cticns are inlmc€s tc t":rsniÉe t"e reF.€{ùeibilù sf hE meislJrerEniE si ìhe skid rEsì5t cefu lls$ng contsrninaiion ty hiEr*3rbcns.
Measureneng will :+ hken in 3 laboralcry it a con5tltnt ierrFèGriLrÈ i21:3'Ci. ne .niterial: rndmeasurerîent apparà1l]E rr bÉ stcred sl ihis teFF€rature.
Miurding of ihe re9 n 5"i, aaé ifl,. df t"è pend" ;:n 5hall be r€ d. CauBcn murt b€ tik€n on:he F'tidon Éi:he refÈr€nce s|.fiace .
-]e rare alee of lnctcn Ehould be *ept fcr ill t"É ffeas[fEíìenls in $ieh
FrÈcEd,rE.rhe heE"l qi fie pEne!ùm shoulC rÈmà:r frÈC ior àl t.e b:sb. C€re nuri bÈ:aien b slsu|e:hit :f'èrÈ ia nt mùveÍEîl rf the r"aia4É c,rflg ihe Euing si úÉ pendul-m, ind care shculd be :ikeflò;D- ìo Èhangè t"€ die:rErr ùflhe lest surfrce durin€:fÈ b?st FroaÈdure.
Ti È'.irscteriEE an Bb5'irbÈnt use l"e Earè oF{àiive 5RT pai a!écrEnE EN '4231 íor all themeaSurefrÈnt5.
EÈfure Èic^ SET nÉaturene.t:
Clen rr.'Écienl q"9V the aelÈrEme surf3'les
Érug" the sànÈe unis hot iyliÈr tvih B deÌergenl dnd ring€ it i.rìt" ryÀ:F ì
c eiE the s3roèlliih prcpanol fi E€. lalE ti;
dry rY ih crrìprcssÈC air
Cl€ff t"e pad
bÍ rubbing ry ih r dcif sa:kei in praaancl ,]f eqlrvilenti
'eave fie oe in uúaÌÉr beÌÌreen lhe lheBsurÈn€l1ig
Cle*Ì t"e brush ?itl orsB;i6 -
6- Procedur€ fo{ D6rl1: rkid resiEtanse of wEt abÈerberit
Repsatthè lrocedurF àt lea5Ì ,.rìce-
A.È-1 DètÉnîinè thÈ initrl SR- Éetq|l íatrtf cf i"è,r,Jel .ElÈÉrce 5"ía.e by sFr3frB the $rf,e.É wthyratÈr l5eÉ,1..4.31 bÈflrÈ erÈh aèlé*e R€iÈ,rt the drìrp e,i:he pad .ntil aìre ìlelùes a.è r.Èisr{s \y th n,l ntErelhin 3 Foifìis derièiÈí . lhe inil a SRI irict cfl fuÈtcr - ìhe ivE 3{e v3hte of ihp llel fvé relea5es.
A.É-2 Dry llrih ocfltprBseÉ{ 3ir
A.E-3 Li l0 nrn eÈpth cft^e abE rbent in ecr: cal !iève9 a9 refuned nAnoexÉ+.1-
A-È-4 In'mÉlsè ihÈ ,rrniasl sieÌps in r trflk illl oi derÍinÈralized rÈr k20 mft.
4.6.5 r4it'drdlv and al'cw (o dra,', '!. 30 Tìrn.
4.6,6 FaÉ 3 loat ai sriuràied absqd:ÉflÍ r/hic" ìs 4 rfln thicì( Éll lc Ìhe re|.erenc€ 5udtsce.
Grip change due to the presence ofan absorbing material - January 2008 Pase 14l18
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Fàr:l a 4 |Im deep Eavity by posilìoning thÈ mould m lie ref€.ence surfts,F. Fill thÉ t3v.ly |f-1h 'Èhirat€dibsErbèrt and iEarel vrih a Ecraper l-eBl|e the mo,ild in plaaè dllrirB tiE È!15.
A.È7 Delem-he fie fnÈl SRT fric.lilat laetcr of ifrÉ lrf€rÈicÈ gir{Èc+ corE ed fith abscrbent. Bo nst edd$eùer itd do rlo1 dern the F6d behtèer ltp drirps. Repst dìe drr]F cf ÍrE Pid umilfipÈ vahÈE rF né!6uredwilh ro rcre than 3poialÈ deviaÉEo. TtlE fìna SRT iriEfsl fsctcr is lhe aeeragp velug {t lhe lasl fve reléaseg.
7- Precedure for p6rt 2: skid resisÈance of the rosd surfrce after removEl ofccntaminated ab3(}f bent
ReÉiî lhe Emae{ùre at least tì{ice.
A.Î.1 Sehffr-ne thE infitsl SRT ficticn laehr {t ùe rl+Ét ÈlÈrÈrcÈ Éjrr-úce by Eprrying tiÉ surface rfiihd€icnis€d $-dter isÈe 4.4-3) befure eaèl reèase. ReFÉat lt e óop of tj:e Pie úniil f,]lre vè:LÉs arÈ fléasulEtr,Ìitr rio mqrÈ U'in Ì Foinh devbiion. The inifsl sRT friclion i*ior is lhe ilreriÉE yalue cf úe ast fEr€leEEPs.
A.?.2 gry wit* :srpre5sed Èi.
4.7.3 ApFly, ard spÈaé evenly 1IB mLfn: i 5 mì,F of hydmrnrbcn u5irE a íif brush wih sFlhèticbri5les, rhEffiy saùraled rrìh úé h'tCi.{róon lree A,4.4J. ThE bruÉh +!ùuld bè held t6 drain ié. ? minutesafter bei:S irl'mÈÌsed- The p!É of thÈ b.u5h wtEra tte brìsllp5 ele attachEd t àù.c be eirìr aliriih a dianÈ',É.beiYreen 4 atn, slrd E cÍn.
A.7-4 AFFIy a fr5ì ':Éa1d ab6c.bèR1:i ol M0 m!!nl : 50 m Jn; on Lnr 'Efliàr{nrt€d le erenc+ g!r,rEe-
4.7.5 Mi{:S seÈor*s, leîE $e sar|e bri,eh :rd ìeare fur 5 nin.
A.?,6 Mix .a.ràgene+.!ly r$Ìn tr'e 53me bruEa-
A.7.7 LÈ3lre lEr a lúlher 5 nrrin E rs hen rcfiDve thè lrBl Èo-t €FFi€d in A.l-J. frcm tie sd.,ere by brurhirE.
A.Î.8 ÉrEn,y spdnkle 5ft{her c6at cf rbscrberìi cf 10{1! tnurni , ;50 lIuml.
4.7-g LÉ3vÉ hr i iElher 5 riin 3txi hen nfiBvÈ all tF€ abscrbent by bnrshing.
A.Zl0 srtùréle ilè grrfaoe by Foi.. S EoÍè tìÈÌèr lsEe A.4.3J.
A.?.ll DÉtem nE tfÈ f nel SRT fri.rion faÈlor of tÌ:e csntamft;,ted lEÈlencé srrfgré b! sFrdyinE tlp surface'Àih rtater E€.f€re eaeh reiea6e. R€{+at úe df{p cf fie Pad ùriil fivè !a!ps ile dÉasurEd rrilh ns ÍErÈ thx!3 ports dÈviit€fi. fhE ínii SRT fricr'att faútcr s lhe iysrge yalue of lf|e lasl fwè releises.
8- Erpre3sing lhe resultB
4.8.1 Part 1 : Bkid re"isiance of Et nb*orhent
DÉtÈdt ne $e ÉtiE lexp.eseed in -"ril bÉtvreen the find sRT iritrion fanar afier perforFÌing the tesl lp,ú.?l *1dihÉ ìniiisl 5R; irurlsr fgclDl cf the y.et rÉieren!è suriaoE IA.6.î1. 11"È reliE ;E the SFjI eaefi4ient. lf lhÉdifierenaÈ beì.Fn |l.e I'i.! SRT .oeÉ]èiÈnts € br5 tîln or equal 1E 5 uniiE lùnih n% l ihe in.l .esult will b€tfìe rr,Éafr 'Df the nra cceifc:€rÉ5
Grip change due to the presence ofan absorbing mateîia1- Jaruary 2008File 200764075
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,n,,:.!iffia'ffi.È-€fl ffi.i; Jr::' !Ìf i'r'
FoohoG : FUH n te FoÈ*le ù iEk dè (eg i| an ÉFcnr5ù fte rEne oa ùe gtrrÉitiriiacní+|$ilgrhi:h keep thÉ RÈdi:a ? Of|eniEe, lrr rrill tèEftU lab5lrs CErÉ to fnd !?
lf rd. nÉè analhÉ let af iÉ nEsiulEn|Er|lr ahd llEn ú|e rÉst nf ùF ÈúEel SRÎ {ffrjert ir thé r* oft|èftEÈ dcd SRT {EèfcÈ.È.
A.8.1 Pcrt 3 : s*id r€Éis'EG 0l AlÉ roid illfrfè aftEr Hnod oa canb|tlùrH*flùent
D#r-F {É rJi} {€ryEisEú ir *l betrEgr lE tud sfiT nidior * ak perhnnnE úe H (À7.11}.d t|t ùiliJ EEf fidinfi ffir.a f* nel |Eftr:ncè írri* l,L?-l!. nE rrlb b lhe gRT.oÉfirÈgl{. ff lhetrùere ùdrEg| lBtÉ Snît!# b iÈÈEùE|!. e4El b 5 úiÈ{trts bhlÉrtlEtuit|€lultnt be{he r*{ dlhè tro oaaffrieib-
f nGt n!*É atdÉ !d dth |tEisrEístr rrd thdr $è rÉrt d &è fu SRT Eo.fi.jsrl b ùE dBú oafi eàEÈ *€ElSRT.oEficÈrÉ3
+ Tcrt rEpstg
fheB lepoÉrrú búcdH
- -nÉH qEaÈúrErEkE Ee;
- AlihîEdd| leqsiedb idBÌfryùEr|rkÈl ErvÉtf
- An ihe |eqdb ottt*Ed
- Tàèfu |Edand i5 c!íhr't'rtytrtr! ihè EbrÈrd
- *stH!|DcEdxE drÍEnd rEAÍrEd l,y fie#arodioÍd deÈilE
- Art ih.iledr$at ÍEf lEré *# ùE tl6!k
Grip change due to the presence of ao absorbi[g material - January 2008 -File 200764075
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