CHEMICAL BONDS. A.Compounds 1.Are made from more than one type of atom (element) 2.Are made during a...

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Transcript of CHEMICAL BONDS. A.Compounds 1.Are made from more than one type of atom (element) 2.Are made during a...

A.Compounds1.Are made from

more than one type of atom (element)

2.Are made during a chemical chg

3.Have properties different from the elements they are made of

4.Have constant compositions

I. Chemical Compounds

B. Chemical Formulas1.Use symbols to

represent the ratios of elements in a particular compound. • Element symbols • Subscripts

I. Chemical Compounds

Fe2O3

B. Chemical Formulas

3. Practice Interpreting Formulas • NaCl

1 sodium atom; 1 chlorine atom

• H2O 2 hydrogen atoms; 1 oxygen

atom• Al2(SO4)3

– 2 aluminum atoms – 3 sulfur atoms – 12 oxygen atoms

Your Turn!

Interpret each of the following

Fe2O3 Pb(C2H3O2)2 2 iron atoms3 oxygen atoms

1 lead atom4 carbon atoms6 hydrogen atoms4 oxygen atoms

C. Atoms Combine3. To become Stable

a.Atoms are stable when they have a full valence energy level – Octet rule: Usually 8 e-

– Exception: He is stable w/ 2 e-

b.Atoms gain, lose or share e-

to achieve a full valence levelc. Atoms are held together by

a chemical bond

I. Chemical Compounds

C. Atoms Combine3. Noble gases

– Are inert– do not react because

they already have a full valence energy level

(stable octet)

I. Chemical Compounds

A. Ions are atoms which1. Have gained or lost e-

ELements to the Left of the Line Lose eLectrons

II. Ions

GAINLOSE

Neither

A. Ions are atoms which

1. Have gained or lost e-

II. Ions

A. Ions are atoms which

1. Have gained or lost e- – You can predict the # of

e- which will be gained or lost by looking at the family

II. Ions

Lose 1 e-

Gain 1 e-

Lose 2 e-

Gain 2 e-

Gain 3 e-Lose 3 e-

Varies

Will P gain or lose electrons when forming an ion? How many?

Gains 3 e-

3.Another name for charge is oxidation number

4.The formula for an ion includes its charge (oxidation number)

A. Ions are atoms which

Formula= Na1+

• Na ion Lost 1 e-

Formula= Cl1-• Cl ion Gained 1 e-

Review it Now!1. What is the difference

between an atom and an ion? 2. What is an oxidation number? 3.Write the oxidation

number for each of the following ions:a.  Li f. Alb. K g. S c. Mg h. Cld.  P i. Nee. B j. N

Ions have a charge, atoms do not

The charge on an ion

1+1+2+3-

3+

3+2-

1-03-

A.Ionic Bonds1.Are formed

a.between (+) and (-) ions

b.When one atom gains e- while the other loses e-

2.Compounds with ionic bonds are called ionic compounds

III.Compounds with Ionic Bonds

A.Ionic Bonds

3. Ionic bonds are formed between a metal and a

nonmetal!

III.Compounds with Ionic Bonds

Which of the following are ionic compounds?

1. KCl

2. CO2

3. LiF

4. CaCl2

Check Your Understanding!

IonicNot ionic

Ionic

Ionic

Step 1:Write the symbol of the (+) ion first, followed

by the symbol of the (-) ion

Step 2: Determine the ox.# for each ion and write it

above the symbols.Step 3: Crisscross the charges

and write them as subscripts.

Step 4: If the charges can be reduced, do so.

B. Formulas for Binary Cmpds

Example #1: Ba and Cl

B. Formulas for Ionic Cmpds

Example #2: Be and P

B. Formulas for Ionic Cmpds

Be3

P2

Example #3: Ba and S

B. Formulas for Ionic Cmpds

BaSBa2S2 note subscripts

can be reduced; do so!

Write the formula for each of the following compounds

1. calcium with chlorine

2. potassium with bromine

3. lithium with sulfur

4. magnesium with phosphorus

5. aluminum with nitrogen

Your Turn!

CaCl2

KBr

Li2S

AlN

Mg3P2

Step 1:Write the name of the positive element 1st.

Step 2:Write the name of the negative element 2nd.

Step 3:Add the ending -ide to the root of the second element.

C. Naming Binary Cmpds

Example #1:

What is the formula name for CaCl2?

Step 1: calciumStep 2: calcium chlorine Step 3: calcium chloride

C. Naming Binary Cmpds

calcium chloride

Example #2:

What is the formula name for Mg3P2?

Step 1: magnesiumStep 2: magnesium

phosphorus Step 3: magnesium

phosphide

C. Naming Binary Cmpds

Magnesium phosphide

Name each of the following

1. Li2S

2. KBr

3. BaS

4. Al2O3

5. Na3N

Your Turn!

Lithium sulfide

Potassium bromide

Barium sulfide

Sodium nitride

Aluminum oxide

1.Binary compounds are made of two kinds of elements.– Example: BaCl2

2.Polyatomic (ternary) compounds are made of three or more elements.– Examples:

K2SO4 Mg(ClO3)2

D. Formulas for Polyatomic Ionic Cmpds

3.Polyatomic ions are a group of covalently bonded atoms that act as one atom with a charge.

D. Formulas for Polyatomic Ionic Cmpds

3.Rules for Writing Formulas

D. Formulas for Polyatomic Ionic Cmpds

Step 1:Write the symbol and ox. #Step 2: Crisscross the charges and

write them as subscripts.Step 3: Make sure you put

polyatomic ions in parentheses (if you need more than one).Step 4: Make sure the subscripts are

reduced.

Example #1: Calcium Nitrate

D. Formulas for Ionic Cmpds

Ca(NO3)2

Ca2+ and NO31-

Ca2+ and NO31-

Ca2+ and (NO3)2

2

Example #2: Calcium Phosphate

D. Formulas for Polyatomic Ionic Cmpds

Ca3(PO4

)2

Ca2+ and PO43-

Ca2+ and PO43-

23

Ca3 and (PO4)2

Write the formula for each of the following compounds

1. Sodium sulfate

2. Calcium hydroxide

3. Beryllium phosphate

4. Aluminum nitrate

Your Turn!

Na2SO4

Ca(OH)2 Be3(PO4)2

Al(NO3)3

1.Rules for Naming Polyatomic Compounds

E. Naming Polyatomic Ionic Compounds

Step 1:Write the name of the positive ion.Step 2: Write the name of the negative ion .

Example #1: Ca(NO3)2

E. Naming Polyatomic Ionic Cmpds

Calcium nitrate

Calciumnitrate

Example #2: AlPO4

E. Naming Polyatomic Ionic Cmpds

Aluminum phosphate

Aluminumphosphate

Name each of the following compounds

1. K2SO4

2. CaCO3

3. NaOH

4. NH4C2H3O2

Your Turn!

Calcium carbonate

Sodium hydroxide Ammonium acetate

Potassium sulfate

G. Special case ionic bonds: ACIDS

Acids are easy to recognize as compounds as they begin with the element hydrogen. As with other ionic bonds, acids fall into 2 categories, binary and ternary.

G. Special case ionic bonds: ACIDS

Examples of binary acids would include things like:

HF, HI, H2S and HCl

Examples of ternary acids would include things like:

H2SO4 and HNO3

G. Special case ionic bonds: ACIDS

Naming of binary acidsStep 1:Name the anion, changing the ending to “-ic”Step 2: Add the prefix “hydro-”Step 3: Slap acid on the end

Example #1: HF

G. Special case ionic bonds: ACIDS

“flourine” becomes

Example #1: HF

G. Special case ionic bonds: ACIDS

“flouric” becomes

“flourine” becomes

Example #2: HF

G. Special case ionic bonds: ACIDS

“hydroflouric” becomes

“flouric” becomes

“flourine” becomes

Example #1: HF

G. Special case ionic bonds: ACIDS

“hydroflouric acid”

“hydrochloric” becomes

“chloric” becomes

“chlorine” becomes

Example #1: HF

G. Special case ionic bonds: ACIDS

Example #2: HCl

G. Special case ionic bonds: ACIDS

“chlorine” becomes

Example #2: HCl

G. Special case ionic bonds: ACIDS

“chloric” becomes

“chlorine” becomes

Example #2: HCl

G. Special case ionic bonds: ACIDS

“hydrochloric” becomes

“chloric” becomes

“chlorine” becomes

Example #2: HCl

G. Special case ionic bonds: ACIDS

“hydrochloric acid”

“hydrochloric” becomes

“chloric” becomes

“chlorine” becomes

Example #2: HCl

G. Special case ionic bonds: ACIDS

G. Special case ionic bonds: ACIDS

Naming of ternary acidsStep 1:Name the polyatomicStep 2: Change “-ate” to “-ic” or “-ite” to “-ous”Step 3: Slap acid on the end

“sulfuric acid”

“sulfuric” becomes

“sulfate” becomes

Example #1: H2SO4

G. Special case ionic bonds: ACIDS

Example #1: H2SO4

G. Special case ionic bonds: ACIDS

“sulfate” becomes

Example #1: H2SO4

G. Special case ionic bonds: ACIDS

“sulfuric” becomes

“sulfate” becomes

Example #1: H2SO4

G. Special case ionic bonds: ACIDS

“sulfuric acid”

“sulfuric” becomes

“sulfate” becomes

Example #1: H2SO4

G. Special case ionic bonds: ACIDS

Example #1: HNO2

G. Special case ionic bonds: ACIDS

“nitrite” becomes

Example #1: HNO2

G. Special case ionic bonds: ACIDS

“nitrous” becomes

“nitrite” becomes

Example #1: HNO2

G. Special case ionic bonds: ACIDS

“nitrous acid”

“nitrous” becomes

“nitrite” becomes

Example #1: HNO2

G. Special case ionic bonds: ACIDS

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Step 1: Does the name begin with “hydro-”? If yes, then…Step 2:Write the symbol for the hydrogen ion followed by the symbol for the second elementStep 3: Crisscross the charges and

write them as subscripts.

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Example: hydrosulfuric acid

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Example: hydrosulfuric acid

H+1 S-2

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Example: hydrosulfuric acid

H+1 S-2

H+1 S-2

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Example: hydrosulfuric acid

H+1 S-2

H+1 S-2

H2S

Rules for Writing Formulas for ternary acids

G. Special case ionic bonds: ACIDS

Step 1: Does the name begin with “hydro-”? If no, then…Step 2:Write the symbol for the hydrogen ion followed by the appropriate polyatomic ionStep 3: Crisscross the charges and

write them as subscripts.

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Example: sulfuric acid

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Example: sulfuric acid

H+1 SO4-2

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Example: sulfuric acid

H+1 SO4-2

H+1 SO4-2

Rules for Writing Formulas for binary acids

G. Special case ionic bonds: ACIDS

Example: sulfuric acid

H+1 SO4-2

H+1 SO4-2

H2SO4

1. HI

2. phosphoric acid

3. hydrobromic acid

4. H2SO3

Name the chemical or write the symbol

G. Special case ionic bonds: ACIDS

hydroiodic acid

1.

2. phosphoric acid

3. hydrobromic acid

4. H2SO3

Name the chemical or write the symbol

G. Special case ionic bonds: ACIDS

H3PO4

hydroiodic acid

1.

2.

3. hydrobromic acid

4. H2SO3

Name the chemical or write the symbol

G. Special case ionic bonds: ACIDS

HBr

H3PO4

hydroiodic acid

1.

2.

3.

4. H2SO3

Name the chemical or write the symbol

G. Special case ionic bonds: ACIDS

sulfurous acid

HBr

H3PO4

hydroiodic acid

1.

2.

3.

4.

Name the chemical or write the symbol

G. Special case ionic bonds: ACIDS

A.Covalent Bonds1.Are formed when

atoms share e-

IV.Compounds with Covalent Bonds

A.Covalent Bonds2.Are formed

Between two nonmetals

IV.Cmpds with Covalent Bonds

State if each of the following compounds is ionic or covalent

1. CO2

2. MgS

3. Na2O

4. PI3

Your Turn!

State if each of the following compounds is ionic or covalent

1. CO2

2. MgS

3. Na2O

4. PI3

Your Turn!

covalent

State if each of the following compounds is ionic or covalent

1. CO2

2. MgS

3. Na2O

4. PI3

Your Turn!

covalentionic

State if each of the following compounds is ionic or covalent

1. CO2

2. MgS

3. Na2O

4. PI3

Your Turn!

covalentionic ionic

State if each of the following compounds is ionic or covalent

1. CO2

2. MgS

3. Na2O

4. PI3

Your Turn!

covalentionic ionic covalent

B.Writing Covalent Formulas1.Greek Prefixes

IV.Cmpds with Covalent Bonds

mono-one

di- two

tri-threetetra- fourpenta-five

hexa- sixhepta-sevenocta- eightnona- ninedeca- ten

2.Rules

B. Writing Covalent Formulas

Step 1: Write the symbol of the first nonmetal.Step 2: Use the nonmetal’s prefix as a subscript

2.Rules

B. Writing Covalent Formulas

Step 3: Write the symbol of the second nonmetal.Step 4: Use the nonmetal’s prefix as a subscript.Note: If there is no prefix,

there is no subscript.

3.Practice problem #1

B. Writing Covalent Formulas

Write the formula for carbon dioxide

C

3.Practice problem #1

B. Writing Covalent Formulas

Write the formula for carbon dioxide

CO

3.Practice problem #1

B. Writing Covalent Formulas

Write the formula for carbon dioxide

CO2

3.Practice problem #1

B. Writing Covalent Formulas

Write the formula for carbon dioxide

CO2

No Prefix = No Subscript

3.Practice problem #2

B. Writing Covalent Formulas

Write the formula for dinitrogen trioxide

3.Practice problem #2

B. Writing Covalent Formulas

Write the formula for dinitrogen trioxide

N

3.Practice problem #2

B. Writing Covalent Formulas

Write the formula for dinitrogen trioxide

N O

3.Practice problem #2

B. Writing Covalent Formulas

Write the formula for dinitrogen trioxide

N2O3

3.Practice problem #3

B. Writing Covalent Formulas

Write the formula for dichlorine hexabromide

3.Practice problem #3

B. Writing Covalent Formulas

Write the formula for dichlorine hexabromide

Cl

3.Practice problem #3

B. Writing Covalent Formulas

Write the formula for dichlorine hexabromide

Cl

Br

3.Practice problem #3

B. Writing Covalent Formulas

Write the formula for dichlorine hexabromide

Cl

2Br6

3.Practice problem #3

B. Writing Covalent Formulas

Write the formula for dichlorine hexabromide

Cl

2Br6Note: Do Not Reduce subscripts!

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

CCl4

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

Cl3Br7

CCl4

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

Cl3Br7

N2O

CCl4

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

Cl3Br7

N2O

CO

CCl4

C.Naming Covalent CmpdsStep 1: Name each

element.Step 2: Change the ending

of the 2nd element to -ide

Step 3: Add Greek prefixes to indicate the # ofatoms of each element

IV.Cmpds with Covalent Bonds

Note: Do not use mono on the first element!

2.Practice problem #1

C. Naming Covalent Cmpds

Write the name for CO

2.Practice problem #1

C. Naming Covalent Cmpds

Write the name for CO

Carbon

2.Practice problem #1

C. Naming Covalent Cmpds

Write the name for CO

Carbonoxygen

2.Practice problem #1

C. Naming Covalent Cmpds

Write the name for CO

Carbonoxygenoxide

2.Practice problem #1

C. Naming Covalent Cmpds

Write the name for CO

CarbonMonoxide

2.Practice problem #1

C. Naming Covalent Cmpds

Write the name for CO

Carbon

Carbon Monoxide

Monoxide

2.Practice problem #2

C. Naming Covalent Cmpds

Write the name for Cl2O3

2.Practice problem #2

C. Naming Covalent Cmpds

Write the name for Cl2O3

chlorine

2.Practice problem #2

C. Naming Covalent Cmpds

Write the name for Cl2O3

chlorine

oxygen

2.Practice problem #2

C. Naming Covalent Cmpds

Write the name for Cl2O3

chlorine

oxide

2.Practice problem #2

C. Naming Covalent Cmpds

Write the name for Cl2O3

chlorine

oxygenoxidetrioxideDichlorine

trioxide

2.Practice problem #2

C. Naming Covalent Cmpds

Write the name for Cl2O3

chlorine

oxygen

Dichlorine trioxide

oxidetrioxideDichlorine

trioxide

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

CCl4

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

Cl3Br7

CCl4

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

Cl3Br7

N2O

CCl4

Write formulas for the following compounds

1. Carbon tetrachloride

2. Trichlorine heptabromide

3. Dinitrogen monoxide

4. Carbon monoxide

Your Turn!

Cl3Br7

N2O

CO

CCl4

Name the following compounds

1. PBr5

2. NO

3. S2I3

Your Turn!

Name the following compounds

1. phosphorus pentabromide

2. NO

3. S2I3

Your Turn!

Name the following compounds

1. phosphorus pentabromide

2. nitrogen monoxide

3. S2I3

Your Turn!

Name the following compounds

1. PBr5

2. nitrogen monoxide

3. disulfur triiodide

Your Turn!

phosphorus pentabromide

THAT’S ALL FOLKS!!!

Now you can name not only covalent bonds but binary and ternary ionic bonds, including acids. That being said, now…

GO DO!!!