Vincent Gandon

Institut de Chimie Molculaire et des Matriaux dOrsay, UMR 8182 Universit Paris-sudMcanismes rctionnels en catalyse homogne :Assistance de la chimie thoriqueLes simulations numriques en chimie Paris-sud

24 octobre 2012

Asymmetric Carbocyclizations: Chiral Anion Strategy

Asymmetric Carbocyclizations: Chiral Anion Strategy

Asymmetric Carbocyclizations: Chiral Anion Strategy

Asymmetric Carbocyclizations: Chiral Anion StrategyDFT, DG298 (kcal/mol)B3LYP/LANL2DZ/6-31G**

Asymmetric Carbocyclizations: Chiral Anion StrategyChem. Eur. J. 2011, 17, 13789

Cyclization of Diynyl Esters

ACIE 2011, 6868DFT, DH298 (kcal/mol)B3LYP/LANL2DZ/6-31G**Cyclization of Diynyl Esters

Cyclization of Diynyl Esters

OL 2007, 2207 h1-Allene Gold Complexes

Linear Triquinanes: Synthesis of D9(12)-Capnellene JACS 2009, 2993

h1-Allene Gold Complexes

AuBr30.01.4+DFT, DH298 (kcal/mol)B3LYP/LANL2DZ/6-31G**h1-Allene Gold Complexes

AuBr310.00.0+DFT, DH298 (kcal/mol)B3LYP/LANL2DZ/6-31G**h1-Allene Gold Complexes

Chirality TransfersACIE 2008, 7534

exo-CyclizationsACIE 2006, 7596

Toste, Houk JACS 2008, 4517exo-Cyclizations

Polynuclear Gold Complexes

Mass spectroscopy (CAR)Polynuclear Gold Complexes

Intermediacy of Gold Acetylides?

Intermediacy of Gold Acetylides?

Intermediacy of Gold Acetylides?Chem. Sci. 2011, 2, 2417DFT, DG298 (kcal/mol)B3LYP/LANL2DZ/6-31G**

FacilitiesParis 6CRIHANICSNIDA

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