The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000
Material Safety Data Sheet
I Product: CLOROX REGULAR-BLEACH
Description: CLEAR, LIGHT YELLOW LIQUID WITH A CHARACTERISTIC CHLORINE ODOR
Other Designations Distributor Emergency Telephone Nos.
Clorox Bleach EPA Reg. No. 5813-50
Clorox Sales Company 1221 Broadway
Oakland, CA 94612
For Medical Emergencies call: (800) 446-1014
For Transportation Emergencies Chemtrec (800) 424-9300
II Health Hazard Data III Hazardous Ingredients DANGER: CORROSIVE. May cause severe irritation or damage to eyes and skin. Vapor or mist may irritate. Harmful if swallowed. Keep out of reach of children. Some clinical reports suggest a low potential for sensitization upon exaggerated exposure to sodium hypochlorite if skin damage (e.g., irritation) occurs during exposure. Under normal consumer use conditions the likelihood of any adverse health effects are low. Medical conditions that may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, emphysema, chronic bronchitis or obstructive lung disease. FIRST AID: Eye Contact: Hold eye open and rinse with water for 15-20 minutes. Remove contact lenses, after first 5 minutes. Continue rinsing eye. Call a physician. Skin Contact: Wash skin with water for 15-20 minutes. If irritation develops, call a physician. Ingestion: Do not induce vomiting. Drink a glassful of water. If irritation develops, call a physician. Do not give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If breathing is affected, call a physician.
Ingredient Concentration Exposure Limit Sodium hypochlorite 5 - 10% Not established
CAS# 7681-52-9 Sodium hydroxide <1% 2 mg/m1
CAS# 1310-73-2 2 mg/m2
1ACGIH Threshold Limit Value (TLV) - Ceiling 2OHSA Permissible Exposure Limit (PEL) – Time Weighted Average (TWA) None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists.
IV Special Protection and Precautions V Transportation and Regulatory Data No special protection or precautions have been identified for using this product under directed consumer use conditions. The following recommendations are given for production facilities and for other conditions and situations where there is increased potential for accidental, large-scale or prolonged exposure. Hygienic Practices: Avoid contact with eyes, skin and clothing. Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist.
Personal Protective Equipment: Wear safety goggles. Use rubber or nitrile gloves if in contact liquid, especially for prolonged periods.
KEEP OUT OF REACH OF CHILDREN
DOT/IMDG/IATA - Not restricted.
EPA - SARA TITLE III/CERCLA: Bottled product is not reportable under Sections 311/312 and contains no chemicals reportable under Section 313. This product does contain chemicals (sodium hydroxide <0.2% and sodium hypochlorite <7.35% ) that are regulated under Section 304/CERCLA.
TSCA/DSL STATUS: All components of this product are on the U.S. TSCA Inventory and Canadian DSL.
VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Control spill. Containerize liquid and use absorbents on residual liquid; dispose appropriately. Wash area and let dry. For spills of multiple products, responders should evaluate the MSDS’s of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed, and/or poorly ventilated areas until hazard assessment is complete. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations.
Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other household chemicals such as toilet bowl cleaners, rust removers, vinegar, acids or ammonia containing products to produce hazardous gases, such as chlorine and other chlorinated species. Prolonged contact with metal may cause pitting or discoloration.
VIII Fire and Explosion Data IX Physical Data Flash Point: None Special Firefighting Procedures: None Unusual Fire/Explosion Hazards: None. Not flammable or explosive. Product does not ignite when exposed to open flame.
Boiling point........................................................................approx. 212°F/100°C Specific Gravity (H20=1) ................................................................. ~ 1.1 at 70oF Solubility in Water ................................................................................. complete pH ...............................................................................................................~11.9
©1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 08/09
12630 Allard Street Santa Fe Springs, CA 90670 United States of America Telephone +1 (562) 406 8881 Facsimile +1 (562) 406 8887 www.CompAirUSA.com
MATERIAL SAFETY DATA SHEET
Section I: Chemical Product & Company Identification
Product Name: CS300 Applies to All Grades
Product Category: Synthetic Hydrocarbons MSDS Form: APL Manufacturer: CompAir Street: 12630 Allard Street Mfg. Phone 562-406-8881 City, State, Zip: Santa Fe Springs, CA 90670 Emergency Only (Chemtrec): 800-424-9300
Section II: Components & Hazard Data
Components: CAS Number(s) Concentration Exposure Limit Synthetic Lubricant containing This products is not a hazard 100% Total Product phthalate diester, synthetic as defined 100% in 29 CFR1910.1200 5mg/m3 for oil Hydrocarbon and additives mist hour work day Mixture
Section III: Health Hazard Data
HMIS RATING: Health: 1 Fire: 1 Reactivie: 0 Personal Protection: See Sec. VIII
Route of Exposure: Ingestion: Minimal toxicity Inhalation: Negligible hazard at 0 to 100°F. Avoid breathing vapors or mist. Eyes: Slightly irritating, but does not injure eye tissue. Skin: Low order of toxicity. Emergency Overview: This product has a low order of toxicity and does not require a cancer hazard warning.
Section IV: First Aid Procedures
Ingestion: First aid is not normally required. Inhalation: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. Eye Contact: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical help. Skin: Wash thoroughly after exposure. Remove and launder contaminated clothing.
Section V: Fire & Explosion Hazard Data
NFPA RATINGS: Health: 1 Fire: 1 Reactivity: 0 Flashpoint: >400°F, COC LEL: No Data UEL: No Data Extinguishing Media: Foam, dry chemical or water spray. Special Fire Fighting Procedures: Use water spray to cool containers and protect personnel. Fire & Explosion Hazards: Vapors may ignite. Minimize breathing vapors, gases, fumes and decomposition products. Use proper protective equipment and self-contained breathing apparatus in confined and/or enclosed areas. Products Produced From Thermal Decomposition: Fumes, smoke, carbon monoxide and oxides of nitrogen and of phosphorous.
Section VI: Physical Data
The following data is typical, approximate data and should not be used for precise design purposes.
Boiling Range: >460°F Solubility (in water): Negligible Physical Form: Oily Liquid Vapor Density (air=1): >1 Evaporation Rate (water=1): <.01 Specific Gravity: 96 % Volatile by Volume: Negligible Vapor Pressure, mmHG @ deg F: Negligible.
Section VII: Reactivity Data
Stability: This product is stable and will not react violently with water. Hazardous polymerization will not occur. Avoid contact with oxidizing agents.
Section VIII: Personal Protection & Exposure Controls
Respiratory Protection: Not usually required. Use supplied-air respiratory protection in confined or enclosed spaces, if needed. Supply sufficient ventilation so permitted exposure levels are not exceeded. Skin Protection: Use chemical resistant gloves, aprons, shoes, etc. to avoid prolonged and repeated skin contact. Launder soiled clothing before reuse. Eye Protection: Use splash goggles or face shield when eye contact may occur. Hygienic Practices: Wash thoroughly before meals, breaks, and at the end of work period. Remove contaminated clothing and launder before reuse. Product is readily removed from skin by waterless hand cleaners, followed by washing thoroughly with soap and water. Storage & Handling Practices: Do not alter or pressurize container. Do not store or use near any source of ignition or strong oxidizers.
Section IX: Transportation Information
U.S. DOT Shipping Description, Label, Number, Class: None, not regulated. For transportation spill, refer to latest DOT Emergency Response Guidebook for Hazardous Materials Incidents.
Section X: Environmental Information
Spill or Release Information: This products may be classified as an oil under Section 311 of the Clean Water Act and Oil Pollution Act. Spills or discharges into or leading to surface waters, that cause a sheen, must be reported to the National Response Center. Recover free product. Divert product from watercourses and sewers. Contain and absorb all product. Assure conformity with all applicable governmental regulations for reporting and disposal. OSHA: Product requires a warning label. SARA Sec. 301-304: No TPQ or RQ for product or any constituent greater than 1% or 0.1% for carcinogen. SARA Sec. 311-312: Check with local Emergency Planning Committee for reportable quantity of hazardous substances. SARA Sec. 313: No toxic chemical is present greater than 1% or 0.1% for carcinogen.
Section XI: Special Information
This information contained in this Material Safety Data sheet has been complied from the most reliable and accurate sources available at the time of preparation. However, no liability shall be accepted by the seller for injury or loss resultant of the use of the products or the information contained in this document. 01/09
KEYSTONE INDUSTRIAL LUBRICANTS -- COMPAIR KELLOG CS300 -- 9150-00N043287
===================== Product Identification =====================
Product ID:COMPAIR KELLOG CS300MSDS Date:05/03/1989FSC:9150NIIN:00N043287MSDS Number: BTFZS=== Responsible Party ===Company Name:KEYSTONE INDUSTRIAL LUBRICANTSAddress:900 E 8TH AVE SUITE 104City:KING OF PRUSSIAState:PAZIP:19406Country:USInfo Phone Num:215-354-9088Emergency Phone Num:215-354-9088;800-424-9300(CHEMTREC)CAGE:HO786=== Contractor Identification ===Company Name:KEYSTONE INDUSTRIAL LUBRICANTSAddress:900 E STH AVE, SUITE 104Box:City:KING OF PRUSSIAState:PAZIP:19406Country:USPhone:215-354-9088CAGE:HO786Company Name:KEYSTONE LUBRICANTSAddress:5 N STILES STBox:City:LINDEN (WAS IN KING OF PRUSSIA,PA)State:NJZIP:07036Country:USPhone:800-344-2241CAGE:75262
============= Composition/Information on Ingredients =============
Ingred Name:DIESTER BASED PRODUCTOSHA PEL:N/K ACGIH TLV:N/K
Ingred Name:SUPP DATA:DISPOSED OF IN AN ENVIRONMENTALLY SAFE MANNER & I/A/W GOVT REGS. FOR WORK ON TANKS REFER TO OSHA REGS, (ING 3)RTECS #:9999999ZZ
Ingred Name:ING 2:ANSI Z49.1, & OTHER GOVTL & INDUS REFERENCES PERTAINING TO CLEANING, REPAIRING, WELDING OR OTHER (ING 4)RTECS #:9999999ZZ
Ingred Name:ING 3:CONTEMPLATED OPERATIONS.RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT:SKIN BY WATERLESS HAND CLEANERS FOLLOWED BY WASHING THOROUGHLY W/SOAP & WATER.RTECS #:9999999ZZ
===================== Hazards Identification =====================
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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.Routes of Entry: Inhalation:NO Skin:YES Ingestion:YESReports of Carcinogenicity:NTP:NO IARC:NO OSHA:NOHealth Hazards Acute and Chronic:HLTH STUDIES HAVE SHOWN THAT MANY PETROLEUM HYDROCARBONS & SYNTHETIC LUBRICANTS POSE POTNTL HUMAN HLTH RISKS WHICH VARY FROM PERS TO PERS. AS A PREC, EXPOS TO LIQ, VAPS, MISTS OR FUMES SHOULD BE MINIM IZED. PRLNGD/RPTD SKIN CONT W/PROD TENDS TO REMOVE SKIN OILS POSS LEADING TO IRRIT & DERM; HOWEVER, (EFTS OF OVEREXP)Explanation of Carcinogenicity:NOT RELEVANT.Effects of Overexposure:HLTH HAZ:BASED ON HUMAN EXPER & AVAIL TOX DATA, PROD IS JUDGED TO BE NEITHER A "CORR" NOR AN "IRRITANT" NOR A "SENSITIZER" BY OSHA CRITERIA. PROD CONTACTING EYE MAY CAUSE IRRIT. PROD HAS A LOW ORDER O F ORAL & DERMAL TOX. INDUCED VOM MAY CAUSE ASPIR OF PROD INTO LUNGS. INHAL & LUNG EFTS HAVE NOT BEEN ESTABLISHED.Medical Cond Aggravated by Exposure:MAY AGGRAVATE PREVIOUS SKIN CONDITION.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/CLEAR WATER FOR AT LEAST 15 MINS OR UNTIL IRRITATION SUBSIDES. HOLD EYELIDS OPEN WHILE FLUSHING. IF IRRITATION PERSISTS, CALL MD. SKIN:REMOVE CONTAMINATED CLOTHING & WASH SKIN THOROUGHLY W/SOAP & WATER. INHAL:REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF DISCOMFORT PERSISTS. INGEST:DO NOT INDUCE VOMITING. CALL MD IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:COCFlash Point:525F,274CExtinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEM, CARBON DIOXIDE & VAPORIZING LIQ. WATER OR FOAM MAY CAUSE FROTHING.Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . USE WATER TO KEEP FIRE-EXPOSED CONTRS COOL. WATER FROTH MAY BE USED TO FLUSH SPILLS AWAY FROM (SUP DAT)Unusual Fire/Explosion Hazard:NONE EXPECTED.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP PROD OUT OF SEWERS & WATERCOURSES BY DIKING/IMPOUNDING. ABSORB W/SAND OR INERT MATL. SWEEP OR SCOOP UP & REMOVE. PVNT SPREAD OF SPILL. ADVISE AUTHORITIES IF PROD HAS ENTERED OR MAY ENTER SEWERS, WATERCOURSES OR EXTENSIVE LAND AREAS. (SUPP DATA)Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT INUSE. DO NOT HANDLE NEAR HEAT, SPARKS, FLAME OR STRONG OXIDANTS.
AVOID PROLONGED/ REPEATED CONTACT W/SKIN.Other Precautions:EMPTY CONTRS RETAIN RESIDUE (LIQ/VAP) & CAN BE DANGEROUS. DO NOT PRESSURIZE, WELD, CUT, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTRS TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNIT; THEY MAY EXP LODE & CAUSE INJURY OR DEATH. (SUP DAT)
============= Exposure Controls/Personal Protection =============
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Respiratory Protection:NORMALLY NOT NEEDED AT AMBIENT TEMPS. USE NIOSH/ MSHA APPRVD FILTER, DUST, FUME OR MIST RESP TYPE UNDER MISTING CNDTNS. USE NIOSH/MSHA CAN OR CARTRIDGE, GAS OR VAP RESP TYPE UNDER CNDTNS EXCEEDING TWA STD. PROD IS NOT EXPECTED TO BE MISTED.Ventilation:USE LOCAL EXHST TO CAPTURE VAPORS, MIST OR FUMES, IF NEC. PROVIDE VENT SUFFICIENT TO PVNT EXCEEDING RECOM EXPOS LIMIT.Protective Gloves:CHEMICAL-RESISTANT GLOVES.Eye Protection:SPLASH GOGGLES.Other Protective Equipment:IF SPLASHING OCCURS, USE CHEM-RESIST APRON OR OTHER IMPERVIOUS CLTHG, IF NEEDED, TO AVOID CONTAMINATING REGULAR CLTHG.Work Hygienic Practices:CLEANSE SKIN THORO AFTER CONT, BEFORE BREAKS & MEALS, & AT END OF WORK PERIOD. PROD IS READILY REMOVED FROM (ING 5)Supplemental Safety and HealthFIRE FIGHT PROC:EXPOS. MINIMIZE BRTHG GASES, VAP, FUMES OR DECOMP PRODS. SPILL PROC:ASSURE CONFORMITY W/LOCAL REGS. OTHER PREC:DO NOT ATTEMPT TO CLEAN SINCE RESIDUE IS DFCLT TO REMOVE. "EMPTY" DRUMS S HOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & RETURNED TO A DRUM RECONDITIONER. ALL OTHER CONTRS SHOULD BE (ING 2)
================== Physical/Chemical Properties ==================
HCC:V6Spec Gravity:0.96 (H2O=1)Solubility in Water:NILAppearance and Odor:GREEN TRANSPARENT FLUID.Percent Volatiles by Volume:NEGLIG
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YESAVOID CONT W/STRONG OXIDIZERS SUCH AS LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM HYPOCHLORITE OR CALCIUM HYPOCHLORITE.Stability Condition to Avoid:OPEN FLAMES.Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE & OTHER THERMAL DECOMP PRODUCTS, SUCH AS OXIDES OF CARBON IN CASE OF INCOMPLETE COMBUST.
==================== Disposal Considerations ====================
Waste Disposal Methods:ASSURE CONFORMITY W/APPLICABLE DISPOSAL REGULATIONS. DISPOSE OF ABSORBED MATERIAL AT AN APPROVED WASTE SITE OR FACILITY. CONSULT FEDERAL, STATE OR LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES.
Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.
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PROCTER & GAMBLE -- DAWN LIQUID DISHWASHING DETERGENT
MATERIAL SAFETY DATA SHEET
NSN: 793000N018770
Manufacturer's CAGE: 74188
Part No. Indicator: A
Part Number/Trade Name: DAWN LIQUID DISHWASHING DETERGENT
===========================================================================
General Information
===========================================================================
Company's Name: PROCTER & GAMBLE
Company's Street: 301 E SIXTH ST
Company's P. O. Box: 599
Company's City: CINCINNATI
Company's State: OH
Company's Country: US
Company's Zip Code: 45201
Company's Emerg Ph #: 800-543-0485
Company's Info Ph #: 800-543-0485
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 002
Status: SMJ
Date MSDS Prepared: 26JUL88
Safety Data Review Date: 17APR95
MSDS Serial Number: BLFYH
Hazard Characteristic Code: F4
===========================================================================
Ingredients/Identity Information
===========================================================================
Proprietary: NO
Ingredient: ETHYL ALCOHOL (ETHANOL)
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Ingredient Sequence Number: 01
NIOSH (RTECS) Number: KQ6300000
CAS Number: 64-17-5
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM; 9192
===========================================================================
Physical/Chemical Characteristics
===========================================================================
Appearance And Odor: CLEAR BLUE LIQUID. PRODUCT IS PERFUMED.
Specific Gravity: 1.03
Solubility In Water: COMPLETELY SOLUBLE
Percent Volatiles By Volume: 60
===========================================================================
Fire and Explosion Hazard Data
===========================================================================
Flash Point: 116F,47C
Flash Point Method: CC
Lower Explosive Limit: N/A
Upper Explosive Limit: N/A
Extinguishing Media: CO*2, WATER, OR DRY CHEMICAL.
Special Fire Fighting Proc: ALTHOUGH THIS PRODUCT HAS A FLASH PT BELOW
200F (CLOSED CUP), IT IS AN AQUEOUS SOLUTION CONTAINING ETHYL ALCOHOL WHICH
DOES NOT SUSTAIN COMBUSTION.(SUPP DATA)
Unusual Fire And Expl Hazrds: NONE.
===========================================================================
Reactivity Data
===========================================================================
Stability: YES
Cond To Avoid (Stability): NONE KNOWN.
Materials To Avoid: CHLORINE BLEACH.
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Hazardous Decomp Products: NONE KNOWN.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
===========================================================================
Health Hazard Data
===========================================================================
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry - Inhalation: NO
Route Of Entry - Skin: NO
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: EYE: MAY CAUSE MILD TRANSIENT IRRITATION.
INGEST: MAY CAUSE TRANSIENT GASTROINTESTINAL IRRITATION. SKIN: TRANSIENT
IRRITATION W/PROLONGED EXPOSURE TO CONCENTRATED MATERIAL.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NOT RELEVANT
Signs/Symptoms Of Overexp: EYE: MAY CAUSE STINGING, TEARING, ITCHING,
SWELLING, &/OR REDNESS. INGEST: MAY RESULT IN NAUSEA, VOMITING, &/OR
DIARRHEA. SKIN: PROLONGED CONTACT W/CONCENTRATED MATERIAL MAY BE DRYING.
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: EYE: FLUSH W/WATER FOR A MINIMUM OF 15 MINUTES.
INGEST: DRINK 1 OR 2 GLASSES OF WATER. SKIN: IF PROLONGED CONTACT OCCURS,
RINSE THOROUGHLY W/WATER. IF SPILLED ON CLOTHING, CHANGE CLOTHES. IF
SYMPTOMS PERSIST OR REOCCUR, SEEK MEDICAL ATTN. INHAL: REMOVE TO FRESH AIR.
SUPPORT BRTHG (GIVE O*2/ARTF RESP) (FP N).
===========================================================================
Precautions for Safe Handling and Use
===========================================================================
Steps If Matl Released/Spill: FLUSH DOWN ACCEPTABLE SEWER (CONTAINS
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BIODEGRADABLE SURFACTANTS). PREVENT LARGE SPILLS FROM REACHING A WATERWAY.
SORBENTS MAY BE USED.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE W/
FEDERAL, STATE, & LOCAL REGULATIONS. SMALL OR HOUSEHOLD QUANTITIES MAY BE
DIPOSED OF IN SEWER. FOR LARGER QUANTITIES, INCINERATION IS PREFERRED. DO
NOT LANDFILL.
Precautions-Handling/Storing: NO UNUSUAL PRECAUTIONS NECESSARY.
Other Precautions: CONSUMER PRODUCT PACKAGE HAS NO CAUTION STATEMENT. DO
NOT MIX WITH CHLORINE BLEACH AS HAZARDOUS FUMES MAY RESULT.
===========================================================================
Control Measures
===========================================================================
Respiratory Protection: NONE REQUIRED WITH NORMAL USE. IF NECESSARY, USE
NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
NORMAL/GENERAL DILUTION VENTILATION IS ACCEPTABLE.
Protective Gloves: NONE REQUIRED W/NORMAL USE. (SUPP DATA)
Eye Protection: NONE REQUIRED W/NORMAL USE. (SUPP DATA)
Other Protective Equipment: NONE NECESSARY UNDER NORMAL USE.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Suppl. Safety & Health Data: FIRE FIGHT PROC: WEAR NIOSH/MSHA APPROVED
SCBA & FULL PROTECTIVE EQUIPMENT (FP N). PROT GLOVES: RUBBER, NEOPRENE
GLOVES SHOULD BE USED FOR PROLONGED DIRECT CONTACT. EYE PROT: IF A SPLASH
IS LIKELY, CHEMICAL WORKERS GOGGLES MAY BE NEEDED.
===========================================================================
Transportation Data
===========================================================================
Trans Data Review Date: 91339
DOT PSN Code: GJL
DOT Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
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DOT Class: 3
DOT ID Number: UN1993
DOT Pack Group: III
DOT Label: FLAMMABLE LIQUID
IMO PSN Code: HIA
IMO Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. o
IMO Regulations Page Number: 3345
IMO UN Number: 1993
IMO UN Class: 3.3
IMO Subsidiary Risk Label: -
IATA PSN Code: MCA
IATA UN ID Number: 1993
IATA Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. *
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
AFI PSN Code: MCA
AFI Prop. Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
AFI Class: 3
AFI ID Number: UN1993
AFI Pack Group: III
AFI Basic Pac Ref: 7-7
===========================================================================
Disposal Data
===========================================================================
===========================================================================
Label Data
===========================================================================
Label Required: P
Technical Review Date: 23SEP91
Label Date: 23SEP91
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Label Status: G
Common Name: DAWN LIQUID DISHWASHING DETERGENT
Chronic Hazard: NO
Signal Word: CAUTION!
Acute Health Hazard-Slight: X
Contact Hazard-Slight: X
Fire Hazard-Slight: X
Reactivity Hazard-Slight: X
Special Hazard Precautions: ACUTE: MAY CAUSE MILD TRANSIENT EYE AND SKIN
IRRITATION. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. WASH THOROUGHLY
AFTER HANDLING. DO NOT MIX WITH CHLORINE BLEACH, AS HAZARDOUS FUMES MAY
RESULT. CHRONIC: NONE LISTED BY MANUFACTURER.
Protect Eye: Y
Protect Skin: Y
Label Name: PROCTER & GAMBLE
Label Street: 301 E SIXTH ST
Label P.O. Box: 599
Label City: CINCINNATI
Label State: OH
Label Zip Code: 45201
Label Country: US
Label Emergency Number: 800-543-0485
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MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name Dawn Manual Pot and Pan Detergent - Diluted for use per label instructions
Product Code 95121663d, 95299364d
Version # 06
Revision date 11-01-2010
P&G Telephone Number: 1-800-332-7787
Emergency 24-hrTelephone #:
CHEMTREC 1-800-424-9300
Manufacturer
Address
Procter & Gamble Professional
2 P&G Plaza
Cincinnati
Ohio
45202
US
2. Hazards Identification
Potential health effects
Routes of exposure Ingestion. Inhalation. Skin contact. Eye contact.
Eyes Health injuries are not known or expected under normal use. Accidental exposure to the eyes mayproduce a mild but transient irritation.
Skin Health injuries are not known or expected under normal use. Substance does not generally irritateand is only mildly irritating to the skin.
Inhalation Health injuries are not known or expected under normal use.
Ingestion Health injuries are not known or expected under normal use. Ingestion may cause gastrointestinalirritation, nausea, vomiting and diarrhea.
Potential environmentaleffects
Considering the limited amount applied during use and the size of the container, the risk ofadverse effects is considered small.
3. Composition / Information on Ingredients
The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.
4. First Aid Measures
First aid procedures
Eye contact Rinse with water. Get medical attention if irritation develops and persists.
Skin contact Not applicable. If irritation occurs, wear suitable protective gloves.
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Ingestion Rinse mouth thoroughly. Get medical attention if any discomfort occurs.
5. Fire Fighting Measures
Environmental precautions Prevent further leakage or spillage if safe to do so.
Extinguishing media
Suitable extinguishingmedia
Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Protection of firefighters
Protective equipmentand precautions forfirefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Material name: Dawn Manual Pot and Pan Detergent - Diluted for use per label instructions
MSDS No. 95121663d, 95299364d Version #: 06 Revision date: 11-01-2010 Print date: 11-01-2010
MSDS US PGP
1 / 4
6. Accidental Release Measures
Personal precautions Not applicable.
Environmental precautions Prevent further leakage or spillage if safe to do so.
Clean-up methods andmaterials and containmentmeasures
In case of spills, beware of slippery floors and surfaces. Flush with plenty of water to clean spillagearea.
7. Handling and Storage
Handling Use care in handling/storage. Avoid release to the environment.
Storage Store in properly labeled containers. Store in accordance with local/regional/national/internationalregulation.
8. Exposure Controls / Personal Protection
Engineering controls Provide adequate ventilation.
Personal protective equipment
Eye / face protection Not normally needed.
Skin protection Not normally needed.
Respiratory protection Not normally needed.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.
9. Physical & Chemical Properties
Color Colorless.
Odor Scented
Odor threshold Not available.
Physical state Liquid.
pH Not available.
Melting point Not available.
Freezing point 32 °F (0 °C)
Boiling point 212 °F (100 °C)
Flash point >= 202 °F (>= 94.4 °C)
Evaporation rate Not available.
Vapor pressure Not available.
Specific gravity Not available.
Solubility (water) Not available.
Partition coefficient(n-octanol/water)
Not available
VOC 0.002492 % estimated
Percent volatile 99.9804 % estimated
10. Chemical Stability & Reactivity Information
Chemical stability This is a stable material.
Conditions to avoid None known.
Hazardous decompositionproducts
No hazardous decomposition products are known.
Hazardous polymerization Will not occur.
11. Toxicological Information
Sensitization Not available.
Chronic effects Not available.
Skin corrosion/irritation Not available.
Material name: Dawn Manual Pot and Pan Detergent - Diluted for use per label instructions
MSDS No. 95121663d, 95299364d Version #: 06 Revision date: 11-01-2010 Print date: 11-01-2010
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12. Ecological Information
Environmental effects Based on ecotoxicity and fate data for the individual ingredients in this specific formulation, and forrelated consumer household cleaning products formulations, this product is not considered harmfulto aquatic organisms or to cause long-term adverse effects in the environment at relevantenvironmental concentrations. This product is intended for dispersive use and should not bedisposed of directly into the environment.
13. Disposal Considerations
Disposal instructions This product, in its present state, when discarded or disposed of, is not a hazardous wasteaccording to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of theuser of the product to determine, at the time of disposal, whether the product meets RCRA criteriafor hazardous waste. Dispose in accordance with all applicable regulations.
14. Transport Information
DOT
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA HazardCommunication Standard, 29 CFR 1910.1200.
CERCLA (Superfund) reportable quantity
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Section 302 extremelyhazardous substance
No
Section 311 hazardouschemical
Yes
State regulations
ILLRTK
Contains no Illinois Right To Know toxicsubstances.
US - Massachusetts RTK - Substance: Listed substance
Contains no Massachusetts Right To Knowsubstances.
US - New Jersey RTK - Special Hazard: Listed substance
Contains no New Jersey Right To Knowspecial hazards.
US - New Jersey RTK - Substances: Listed substance
Contains no New Jersey Right To KnowSubstances
US - Pennsylvania RTK - Hazardous Substances: Listed substance
Contains no Pennsylvania Right To Knowhazardous substances
US - Rhode Island RTK - Hazardous Substances: Listed substance
Contains no Rhode Island Right To Knowhazardous substances.
Canadian regulations All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product hasbeen classified in accordance with hazard criteria of the Controlled Products Regulations and theMSDS contains all the information required by the Controlled Products Regulations.
Material name: Dawn Manual Pot and Pan Detergent - Diluted for use per label instructions
MSDS No. 95121663d, 95299364d Version #: 06 Revision date: 11-01-2010 Print date: 11-01-2010
MSDS US PGP
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Country(s) or region Inventory name On inventory (yes/no)*
Inventory Status
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
16. Other Information
HMIS® ratings Health: 0Flammability: 1Physical hazard: 0
NFPA ratings Health: 0Flammability: 1Instability: 0
Disclaimer This MSDS is intended to provide a brief summary of our knowledge and guidance regarding theuse of this material. The information contained here has been compiled from sources consideredby Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. Itis not meant to be an all-inclusive document on worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate theconditions of use and design the appropriate protective mechanisms to prevent employeeexposures, property damage or release to the environment. Procter & Gamble assumes noresponsibility for injury to the recipient or third persons, or for any damage to any propertyresulting from misuse of the product.
Material name: Dawn Manual Pot and Pan Detergent - Diluted for use per label instructions
MSDS No. 95121663d, 95299364d Version #: 06 Revision date: 11-01-2010 Print date: 11-01-2010
MSDS US PGP
4 / 4
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