STATEMENT OF BASIS
for the issuance of Draft Air Permit # 762-AOP-R13
1. PERMITTING AUTHORITY:
Arkansas Department of Environmental Quality5301 Northshore DriveNorth Little Rock, AR 72118-5317
2. APPLICANT:
Albemarle Corporation - South PlantHighway 79 SouthMagnolia, Arkansas 71756
3. PERMIT WRITER: Charles Hurt
4. PROCESS DESCRIPTION AND NAICS CODE:
NAICS Description: All Other Miscellaneous Chemical Product and PreparationManufacturing
NAICS Code: 325998
5. SUBMITTALS: 11/13/2007,02/1912008
6. REVIEWER'S NOTES:
Albemarle Corporation - South Plant owns and operates a chemical manufacturing facilityon Highway 79, approximately seven miles south of Magnolia, Arkansas 71753. Thismodification incorporated all applicable requirements of 40 CFR Part 63, Subpart FFFF National Emission Standardsfor Hazardous Air Pollutants Miscellaneous Organic ChemicalManufacturing and Miscellaneous Coating Manufacturing. Albemarle also requested torevise the short term emission limits under the MaN required testing scenarios. Due to themodification permitted HCI emissions decreased by 1.1 tpy.
Based on the information submitted in the application the following limits were changed inthe permit to comply with the MaN MACT.
Source PollutantMON MACT Limit Change
(Ib HCI/yr) (Ib HCI/yr)AD-05 HCI 1,000 +1,000DB-07 HCI 1,000 -3,200
7. COMPLIANCE STATUS:
There are no enforcement issues or actions against the facility at this time. Albemarle waslast inspected in October 2007 and determined to be in compliance.
Permit #:762-AOP-R13AFIN: 14-00028Page 2 of25
8. APPLICABLE REGULATIONS:
PSD ApplicabilityDid the facility undergo PSD review in this permit (i.e., BACT,
Modeling, et cetera?Has this facility undergone PSD review in the past?
Is this facility categorized as a major source for PSD?<0 100 tpy and on the list of28 (100 tpy)?
<0 250 tpy all other
PSDNettingWas netting performed to avoid PSD review in this permit?
N
NYYy
N
Permit#
Source and Pollutant Specific Regulatory Applicability
Source PollutantRegulation [NSPS, NESHAP (part
61 & Part 63), or PSD onlYlFacility PM IO, SOb VOC, CO, NOx PSD
Facility VOC40 CFR Part 82 - Standards for the Protection
of Stratospheric Ozone
Facility PM/PM IO40 CFR Part 61, Subpart M - National
Emission Standard for AsbestosAD-17 DB-07AD-24 DE-04
40 CFR Part 60, Subpart Kb - Standards ofAD-25 DE-09AD-28 DE-12
VOCIHAP Performance for Volatile Organic Liquid
AD-29 DE-20 Storage Vessels
AB-15 TB-03flO CFR Part 61, Subpart FF - National
DECTP Process VOC/HAP IEmission Standards for Benzene Wastepperationsf:lo CFR Part 63, Subpart A - National Emission
AB-15 VOC/HAP Standards for Hazardous Air Pollutants forSource Categories, General Provisionsf:lo CFR Part 63, Subpart F - National EmissionStandards for Hazardous Air Pollutants from~e Synthetic Organic Chemical Manufacturing
AB-15ndustly
TB-03TB-31
TB-IITB-32 ~O CFR Part 63, Subpart G - National Emission
TB-17TB-33
VOCIHAPStandards for Hazardous Air Pollutants from
TB-25TB-34 he Synthetic Organic Chemical Manufacturing
TB-29TB-35 i1ndustly for Process Vents, Storage Vessels,
TB-30WW-OI Irransfer Operations, and Wastewater
~O CFR Part 63, Subpart H - National EmissionStandards for Organic Hazardous Air Pollutantsfor Equipment Leaks
Permit #:762-AOP-R13AFIN: 14-00028Page 30[25
Source PollutantRegulation [NSPS, NESHAP (part
61 & Part 63), or PSD onJyl40 CFR Part 60, Subpart VV - Standards of
TB-29 VOCIHAPPerfonnance for Equipment Leaks ofVOC inhe Synthetic Organic Chemical Manufacturingndustry
NC-1440 CFR Part 82, Part A - Protection of
ProcessOzone Depleting Substances Stratospheric Ozone, Production and
Consumption Controls40 CFR Part 82, Subpart E - Protection of
NC-14 Process Ozone Depleting Substances Stratospheric Ozone, The Labeling of ProductsUsing Ozone-Depleting Substances
NC-1740 CFR Part 63, Subpart A - National Emission
CMPUVOCfHAP Standards for Hazardous Air Pollutants for
Source Categories, General Provisions40 CFR Part 63, Subpart F - National Emission
NC-17VOCfHAP
Standards for Hazardous Air Pollutants fromCMPU he Synthetic Organic Chemical Manufacturing
Industry40 CFR Part 63, Subpart G - National Emission
NC-17 Standards for Hazardous Air Pollutants from
CMPUVOCfHAP he Synthetic Organic Chemical Manufacturing
ndustry for Process Vents, Storage Vessels,Transfer Operations, and Wastewater
NC-17 140 CFR Part 63, Subpart H - National Emission
CMPUVOCfHAP Standards for Organic Hazardous Air Pollutants
for Equipment Leaks
21-01 40 CFR Part 61, Subpart A - National Emission
21-02VOCfHAP Standards for Organic Hazardous Air
Pollutants, General Provisions
21-01 ~o CFR Part 61, Subpart J - National Emission
21-02VOCfHAP Standards for Equipment Leaks (Fugitive
Emission Sources) of Benzene
21-01 140 CFR Part 61 , Subpart V - National Emission
21-02VOCfHAP Standards for Equipment Leaks (Fugitive
Emission Sources)
21-01 ~o CFR Part 61, Subpart Y - National Emission
21-02VOCfHAP Standards for Benzene Emissions from Benzene
Storage Vessels
21-01 ~o CFR Part 61, Subpart FF - NationalVOCfHAP ~mission Standards for Benzene Waste
21-02 pperations~O CFR Part 63, Subpart JJ - National
MS-05 VOCfHAP IEmission Standards for Wood FurnitureManufacturing Operations~O CFR Part 82, Subpart E - Protection of
Facility Ozone Depleting Substances Stratospheric Ozone, The Labeling of ProductsIUsing Ozone-Depleting Substances
Pennit #:762-AOP-RI3
AFIN: 14-00028
Page 4 of25
Source PollutantRegulation [NSPS, NESHAP (part
61 & Part 63), or PSD onlylMCPU's:
DECTPDMTDA ~o CFR Part 63, Subpart FFFF - National
NC-12 !Emission Standards for Hazardous AirVOCfHAP !Pollutants: Miscellaneous Organic Chemical
NC-15 lManufacturing and Miscellaneous CoatingNC-17 lManufacturingNC-21NC-23
CCF ~O CFR Part 63, Subpart EEEE - National
All Ethylene Glycol VOCfllAP!Emission Standards for Hazardous AirlPollutants: Organic Liquids Distribution (Non-
Storage ~asoline)
9. EMISSION CHANGES:
The following table summarizes plant wide emission changes associated with this pennittingaction.
Plant Wide Permitted Emissions (ton/yr)Pollutant Air Permit 762-AOP-RI2 Air Permit 762-AOP-RI3 Chane;e
PM 130.46 130.46 0PM IO 119.36 119.36 0S02 3,312.19 3,312.19 0
VOC 569.92 569.92 0CO 209.09 209.09 0
NOx 471.37 471.37 0Xylene + Ethyl Benzene 15.35 15.35 0
1,1-Dichloroethane 0.39 0.39 01,2-Epoxybutane 0.20 0.20 0
Acetaldehyde 1.80 1.80 0Benzene 8.00 8.00 0
Bromoform 4.15 4.15 0Chloroethane 2.95 2.95 0Chloroform 0.39 0.39 0
Chlorine 3.42 3.42 0Ch + Br2 0.10 0.10 0
Ch or Halogens 13.32 13.32 0Dimethyl Formide 0.39 0.39 0Ethylene Chloride 0.88 0.88 0
Ethyl Benzene 0.01 0.01 0Ethylene Dibromide 5.50 5.50 0
Permit #:762-AOP-RI3AFlN: 14-00028Page 5 of25
Plant Wide Permitted Emissions ltonlvr)Pollutant Air Permit 762-AOP-R12 Air Permit 762-AOP-RI3 Chanee
Ethylene Dichloride 0.40 0.40 0Ethylene Glycol 5.45 5.45 0
HCI 41.00 38.9 -1.1Hexane 0.05 0.05 0
Iso-Octane 0.01 0.01 0Dichloromethane 7.70 7.70 0
Methanol 33.66 33.66 0Methyl Bromide 18.25 18.25 0
Methyl Naphthalene 5.59 5.59 0Phenol 0.09 0.09 0
Phthalic Anhydride 1.24 1.24 0Toluene Diamine 0.35 0.35 0
Toluene 24.78 24.78 0Xylene 0.02 0.02 0
Br2 + HBr 82.68 82.68 0Acetone 0.30 0.30 0
Ammonia 48.40 48.40 0Br2 26.73 26.73 0
BrCI 0.88 0.88 0H20 2 9.30 9.30 0H2S 4.04 4.04 0
H2SO4 0.06 0.06 0HBr 11.89 11.89 0
Non-YOC/Non-HAP4.64 4.64 0
Refrigerants
10. MODELING:
Criteria Pollutants
Criteria pollutant emission rates were not affected with this modification. Modeling listedbelow is was conducted for a previous modification.
*
Permit #:762-AOP-RI3AFIN: 14-00028Page 6 of25
EmissionNAAQS
AveragingHighest
%ofPollutant Standard Concentration
RateQb/hr)(p2lm~
Time(p2lm1*
NAAQS
PM 10 32.1850 Annual 39.03 78.1%150 24-hour 99.24 66.2%80 Annual 20.1 25.2%
SOz 756.6 1,300 3-hour 1,178.5 90.7%365 24-hour 330.0 90.5%
NOx 177.88 100 Annual 40.66 40.7%VOC** 566.60 0.12 I-hour (ppm) 0.0299 24.9%
CO 234.3210,000 8-hour 4927 49.3%40,000 I-hour 10,802 27.0%
Includes the background concentratIon** Scheffe Method
Other Modeling
Odor modeling for sources emitting styrene.
Albemarle is not a source for styrene emissions therefore odor modeling for styrene was notperformed.
A.C.A. §8-3-103 requires hydrogen sulfide emissions to meet specific standards.
Pollutant Threshold valueModeled Concentration
Pass?(ppb)20 parts per billion
0.6 y(5-minute average)
HzS I00 parts perbillion
0.1 y(8-hour average)
nonresidential area
Non-Criteria Pollutants
1st Tier Screening (PAER)
Estimated hourly emissions from the following sources were compared to the PresumptivelyAcceptable Emission Rate (PAER) for each compound. The Department deemed PAER tobe the product, in lb/hr, of 0.11 and the Threshold Limit Value (mg/m\ as listed by theAmerican Conference of Govemmentallndustrial Hygienists (ACGIH).
Permit #:762-AOP-R13AFIN: 14-00028Page 70f25
Non-Criteria Pollutants
lst Tier Screening (PAER)
Estimated hourly emissions from the following sources were compared to the PresumptivelyAcceptable Emission Rate (PAER) for each compound. The Department deemed PAER tobe the product, in Ib/hr, of 0.11 and the Threshold Limit Value (mg/m\ as listed by theAmerican Conference of Governmental Industrial Hygienists (ACGIH).
PollutantTLV PAER (lb/hr) Proposed
Pass?(mwm3) = O.l1*TLV Ib/hr
Benzene 1.6 0.176 8.00 NBromoform 5.16 0.567 5.03 N
Chlorine 1.45 0.160 5.36 NEthyl Chloride 262.78 28.91 2.60 Y
Dimethyl Formide 30.00 3.30 0.09 yEthylene Dibromide 154.00 16.94 4.60 yEthylene Dichloride 40.00 4.40 0.19 Y
Ethylene Glycol 125.00 13.75 1.17 yHCI 2.98 0.32 15.48 N
Methanol 262.08 28.82 61.23 NMethyl Bromide 19.00 2.09 17.91 N
Methyl Naphthalene 20.00 2.20 1.36 yMethylene Chloride 174.00 19.14 1.74 yPhthalic Anhydride 6.10 0.67 3.93 N
Toluene 188.40 20.72 50.95 NToluene Diamine 2.00 0.22 0.08 y
Xylene 434.00 47.74 4.03 yEthyl Benzene 434.00 47.74 3.56 Y
Phenol 19.00 2.09 0.10 yHexane 176.00 19.36 3.89 y
Acetaldehyde 45.04 4.95 0.20 YIso-Octane 25.00 2.75 0.40 y
1,2-Epoxybutane 117.99 12.98 0.20 y
ISCST3 air dispersion modeling was performed on the estimated hourly emissions from thefollowing sources, in order to predict ambient concentrations beyond the property boundary.The Presumptively Acceptable Impact Level (PAIL) for each compound was deemed by theDepartment to be one one-hundredth ofthe Threshold Limit Value, as listed by the ACGIH.
Permit #:762-AOP-RI3AFIN: 14-00028Page 8 of25
Pollutant(pAIL, pglm) = 11100 of Modeled Concentration
Pass?Threshold Limit Value (p.vm)
Benzene 16.0 15.78 y
Bromoform 51.6 21.02 y
Chlorine 14.5 5.76 y
HCI 30.00 20.70 y
Methanol 2620 1256.00 YMethyl Bromide 39.0 38.9 y
Phthalic Anhydride 61.00 53.75 y
Toluene 1884 1045 Y
11. CALCULATIONS:
Emission Emission ControlControl
Comments (Emission
SNFactor Source Factor and Equipment
Equipmentfactor
(AP-42, units (lbs/ton, Type (if controlled/uncontrolled,Testine;, etc) Ibs/hr, etc) any)
Efficiencyetc)
BR-OI Testing 1.5 Iblhr VOC Scrubber99% Control for Bromine
and ChlorineBR-04 Testing 3.81 Iblhr VOCBR-08 Tanks 0.04 Iblhr HCI
BR-09 Mass Balance0.02 Iblhr HBr0.02 Iblhr Br2
BR-12 Testing0.10 Iblhr Ciz
Scrubber 99.90.30 Iblhr Br2
BR-14 SOCMI 0.50 Iblhr VOC
BR-15 Testing1.63 IblhrHalogens
SL-Ol AP-42 See Section 14. ISL-02 Mass Balance 0.12 Iblhr VOCSR-OI AP-42 See Section 14.1SR-02 SOCMI 0.50 Iblhr VOCCB-OI Mass Balance 0.1 Ib/hr PM IO
CB-02 Mass Balance 0.27 Iblhr VOCCB-04 Mass Balance 26.00 Iblhr VOCCB-16 Mass Balance 0.27 Iblhr VOCCB-17 SOCMI 1.80 Iblhr VOCCB-18 Mass Balance 0.1 Iblhr PM IO
CB-02Test 9.00 Iblhr VOC
CB-16ADMA Brine Storage Tank
DE-OI Mass Balance 0.5 Iblhr VOC (Additional ADMA StorageScenario)
DE-04 Tanks 8.96 Iblhr VOC
Permit #:762-AOP-R13AFIN: 14-00028Page 9 0[25
Emission Emission ControlControl
Comments (Emission
SNFactor Source Factor and Equipment
Equipmentfactor
(AP-42, units Obs/ton, Type (if controUed/uncontroUed,Testine:, etc) Ibslhr, etc) any) Efficiency
etc)DE-06 Tanks 0.62 Ib/hr VOCDE-07 Tanks 0.62 Ib/hr VOCDE-08 Tanks 0.62 Ib/hr VOCDE-lO Tanks 0.62 Ib/hr VOCDE-II Tanks 0.62 Ib/hr VOCDE-12 Tanks 0.62 Ib/hr VOCDE-17 AP-42 See Section 14.1DE-18 AP-42 See Section 14.1DE-19 Mass Balance 8.00 Ib/hr VOCDE-20 Tanks 9.40 lb/hr VOCDE-21 AP-42 See Section 14.1DE-22 SOCMI 9.40 Ib/hr VOCDE-23 Mass Balance 2.83 Ib/hr VOCDE-24 Mass Balance 12.70 Ib/hr VOCDE-28 Mass Balance 23.60 Ib/hr VOCAD-OI Tanks 0.16 Ib/hr VOCAD-02 Tanks 0.16 Ib/hr VOCAD-03 Tanks 0.26 Ib/hr VOC
VOC Tanks0.20 Ib/hr VOC
AD-05 HCI MassBalance
0.10 lb/hr HCI
AD-07 Tanks 0.05 Ib/hr VOCAD-08 Tanks 0.05 Ib/hr VOCAD-09 Tanks 0.05 Ib/hr VOCAD-IO Tanks 0.26 Ib/hr VOCAD-II Tanks 0.26 Ib/hr VOCAD-12 Tanks 0.26 Ib/hr VOCAD-13 Tanks 0.26 lb/hr VOCAD-14 Tanks 0.26 Ib/hr VOCAD-15 Tanks 0.26 Ib/hr VOCAD-17 Tanks 0.26 Ib/hr VOCAD-18 Tanks 0.26 Ib/hr VOCAD-20 Tanks 0.16Ib/hrVOCAD-21 Tanks 3.45 Ib/hr VOCAD-23 Tanks 0.03 Ib/hr VOCAD-24 Tanks 0.26 Ib/hr VOCAD-25 Tanks 0.26 Ib/hr VOCAD-26 AP-42 See Section 14.1AD-27 Tanks 0.26 Ib/hr VOCAD-28 Tanks 0.08 Ib/hr VOC
Pennit #:762-AOP-RI3AFIN: 14-00028Page 10 of25
Emission Emission ControlControl
Comments (Emission
SNFactor Source Factor and Equipment
Equipmentfactor
(AP-42, units (Ibslton, Type (if controUedJuncontroUed,Testine, etc) Ibslhr, etc) any) Efficiency etc)
AD-29 Tanks 0.08 Ib/hr VOC0.22 Ib/hr PM IO
See0.09 lb/hr SOz
AD-35Application
1.22 lb/hr VOC0.06 Ib/hr CO0.701b/hrNOx
AD-36 SOCMI 4.13 lb/hr VOCAD-37 Tanks 0.05 lb/hr VOC
ADMA Additional Storage
AD-39 Mass Balance 0.1 lb/hr VOCAlternate OperatingScenario Loadout
EmissionsAD-40 Mass Balance 0.26 lb/hr VOCAB-15 Testing 1.20 lb/hr VOCAB-16 SOCMI 7.50 Ib/hr VOC
DB-OI Mass Balance0044 lb/hr
ScrubberIncludes assumed scrubber
Halogens efficiency of99.9%Manufacturer 1.8 Ib/hr PM IO
Specification 0.14 Ib/hr SOzDB-04 (combustion) 0.96 Ib/hr VOC
Mass Balance 3.6 Ib/hr CO(PM) 1.6 Ib/hr NOx
DB-OS Mass Balance 0.3 Ib/hr PM IO
DB-06 Mass Balance 0.3 Ib/hr PM IO
DB-07 Mass Balance O.IOlb/hrVOCDB-08 Mass Balance 1.I Ib/hr PM IO
DB-IO Mass Balance 0.01 Ib/hr VOCDB-16 SOCMI lAO Ib/hr VOC
DB-17 Mass BalanceO.IOlb/hrHalogens
DB-18 Mass Balance0.06 g/fe @ 460
99.9%fe/min
DB-19 Mass Balance1.00 Ib/hr Brz
40%+HBr
TB-03Mass Balance 2.57 Ib/hr VOC
(MeBr)TB-03
Mass BalanceO.IOlb/hr
(NaBr) HalogensTB-03
Mass Balance 10.70 lb/hr VOC(EtBr)
Permit #:762-AOP-R13AFIN: 14-00028Page II of25
Emission Emission ControlControl
Comments (Emission
SNFactor Source Factor and Equipment
Equipmentfactor
(AP-42, units (Ibs/ton, Type (if controlled/uncontrolled,Testin2, etc) Ibslbr, etc) any) Efficiency
etc)TB-04(NC- Mass Balance 0.90 Ib/hr PM IO
22)TB-08(NC- Mass Balance 0.30 lb/hr PM 10
22)TB-II
Tanks 2.91 Ib/hr VOC(MeBr)
ADMA Brine Storage TankTB-II Mass Balance 0.1 Ib/hr VOC (Additional ADMA Storage
Scenario)TB-12
Tanks 0.10 lb/hr VOC(MeBr)TB-12
Tanks 0.53 Ib/hr VOC(EtBr)TB-14
0.301b/hr(Stabro Mass Balance
Halogensm)
TB-14O.IOlb/hr
(NC- Mass BalanceHalogens
22)TB-25
Mass Balance 0.40 Ib/hr VOC(MeBr)TB-29
SOCMI 0.93 Ib/hr VOC(MeBr)TB-29
0.301b/hr(Stabro SOCMI
Halogensm)
TB-29SOCMI 3.47 lb/hr VOC
(EtBr)TB-29(NC- SOCMI 1.33 lb/hr VOC22)
TB-30Tanks 11.80 lb/hr VOC
(MeBr)TB-30
Tanks 11.30 lb/hr VOC(EtBr)TB-37
Mass Balance 1.34 Ib/hr VOC(EtBr)
Pennit #:762-AOP-RI3AFIN: 14-00028Page 12 of25
Emission Emission ControlControl
Comments (Emission
SNFactor Source Factor and Equipment
Equipmentfactor
(AP-42, units (Ibslton, Type (if controlled/uncontrolled,Testine:, etc) Ibs/hr, etc) any)
Efficiency etc)
TB-41(NC- Mass Balance 6.40 Ib/hr VOC22)
TB-42(NC- Tanks 0.09 Ib/hr HBr22)
TB-43(NC- Mass Balance 0.25 Ib/hr VOC22)
15-02 Mass Balance0.201b/hr
Scrubber 99.99%Halogens
15-09 Tanks 0.03 Ib/hr VOC15-12 AP-42 See Section 1.415-13 AP-42 0.07 Ib/hr VOC15-15 SOCMI 4.23 IbJhr VOC15-16 Mass Balance 1.20 Ib/hr VOC15-17 Mass Balance 0.69 Ib/hr VOC15-18 Mass Balance 0.10 Ib/hr VOC
16-01 Mass Balance0.50 Iblhr S020.10 Iblhr PM IO
16-02 Mass Balance0.40 Iblhr S02
0.10 Iblhr VOC16-05 Mass Balance 0.10 Iblhr VOC
16-06 Mass Balance0.10 Iblhr VOC0.40 Iblhr VOC
16-07 Testing 0.30 Iblhr PM 10
16-08 Testing 0.30 Iblhr PM IO
16-10 Testing 0.50 Iblhr PM IO
16-11 Testing 0.10 Iblhr PM IO
16-12 Testing 0.1 0 Iblhr PM 10
16-13 Mass Balance 0.10 Iblhr S0216-14 Mass Balance 0.10 Ib/hr VOC16-15 Mass Balance 0.01 Iblhr VOC16-16 Mass Balance 0.10 lblhr S0216-17 Mass Balance 0.02 Iblhr VOC16-18 AP-42 See Section 1.4
Testing
16-19(PM IO) 0.30 Iblhr PM 10
Mass Balance 0.10 Iblhr S02(S02)
Permit #:762-AOP-R13AFIN: 14-00028Page 130[25
Emission Emission ControlControl
Comments (Emission
SNFactor Source Factor and Equipment
Equipment factor(AP-42, units (Ibs/ton, Type (if controUed/uncontroUed,
Testin2, etc) Ibs/hr, etc) any)Efficiency
etc)7.6lb/MMscf
AP-42PM IO
(PM, S02,0.60 Ib/MMscf
S0216-20
NOx)100 Ib/MMscf
VendorNOxSpecification
0.19 Iblhr CO(CO, VOC)
0.13 Iblhr VOC
Testing
16-21(PMIO) 0.20 Ib/hr PM 10
Mass Balance 0.40 Ib/hr VOC(VOC)
16-22 Mass Balance0.01 Ib/hr PM IO
0.01 Iblhr VOC16-23 SOCMI 6.60 Ib/hr VOC16-24 Mass Balance 1.80 Iblhr S03
16-25 Mass Balance0.40 Iblhr PMIO Includes assumed 99%1.02 Iblhr VOC PM IO control efficiency
16-26 Testing 0.30 Iblhr PM16-27 Testing 0.30 Iblhr PM16-28 Mass Balance 0.10 Iblhr S0216-31 Mass Balance 3.83 Iblhr VOC
Testing2.59 Iblhr PM IO(S02, VOC,5.60 lblhr S02
Emission rates are for eachBH-OI NOx, CO) 1.87 Iblhr VOC
boiler except S02. TheBH-02 AP-42
13.60 Iblhr COemission rate for S02 is
(PM IO)47.601blhrNOx
bubbled for both sources.
Testing 0.10 Iblhr PM IO
(PM IO) 0.01 Iblhr S02 Emissions are calculated21-01 Mass Balance 1.71 Iblhr VOC
every six months.(VOC, S02, 3.80 Iblhr VOCCO, NOx) 0.50 Iblhr NOx
21-02 SOCMI 3.72 Iblhr VOC
21-03 Mass Balance 0.01 Iblhr VOCEmissions are calculated
annually.21-04 Testing 0.80 Ib/hr VOC23-01 SOCMI 1.12 Iblhr VOC23-02 Mass Balance 0.10 Iblhr PM IO
23-03 Testing 0.35 Iblhr VOC
Permit #:762-AOP-R13AFIN: 14-00028Page 14 of25
Emission Emission ControlControl
Comments (Emission
SNFactor Source Factor and Equipment Equipment
factor(AP-42, units Obs/ton, Type (if controlled/uncontrolled,
Testin2, etc) Ibslhr, etc) any)Efficiency
etc)23-04 Mass Balance 0.44 Iblhr VOC23-05 Testing 2.90 Iblhr VOC
23-06Mass Balance
23-07(PM 10) 0.30 Iblhr PM IO
23-08Testing 3.80 Iblhr VOC(VOC)
23-09 Mass Balance 0.10 Iblhr PM 10
23-10 Mass Balance 0.10 Iblhr PM \0
23-IIAMass Balance 0.10 Ib/hr PM 10
23-IIB23-12A
Mass Balance 0.101blhrPM 1o23-12B23-13 Mass Balance 0.10 Ib/hr PM IO
BT-Ol Mass Balance0.01 Ib/hr VOC0.141blhrH2S
0.01 Ib/hr VOC
BT-II0.01 Iblhr H2S Emission rates for each
BT-13Mass Balance 0.20 Iblhr NH3
0.03 Iblhrsource.
HalogensBT-12,BT-23,
0.01 Iblhr VOCBT-24, 0.20 Iblhr NH3 Emission rates for eachBT-25, Mass Balance
0.031blhrBT-26,
source.
BT-27,Halogens
BT-28BT-16,
Mass Balance30.00 Iblhr VOC Emission rates for each
BT-29 0.01 Iblhr H2S source.
BT-17 Tanks16.40 Iblhr VOC0.01 Iblhr H2S
4.121blhrPM IO
3.37 Iblhr VOCBT-21 Mass Balance 10.23 Iblhr NH3
2.891blhrHalogens
BT-22Engineering
0.02 Iblhr VOCEstimate
DM-OI Tanks 0.03 Iblhr VOCDM-02 AP-42 See Section 1.4
Permit #:762-AOP-R13AFIN: 14-00028Page 150[25
Emission Emission ControlControl
Comments (Emission
SNFactor Source Factor and Equipment
Equipmentfactor
(AP-42, units Obslton, Type (if controUed1uncontroUed,Testing, etc) Ibslhr, etc) any) Efficiency
etc)DM-03
Tanks 0.81 lb/hr HzOzEmission rates for each
DM-06 source.DM-07 SOCMI 3.18 lb/hr VOC
MS-Ol Mass Balance 4.00 lb/hr VOCCalculate emission rateonce every six months
MS-02 Mass Balance 0.10 lb/hr VOCCalculate emission rateonce every six months
MS-03 Mass Balance 0.30 Ib/hr VOCCalculate emission rateonce every six months
MS-05 Mass Balance 0.67 lb/hr VOC
MS-06 Mass Balance0.50 Ib/hr SOl7.00 lb/hr VOC
MS-07 Tanks 47.70 lb/hr VOCEmission rates are based on
3.00 lb/hr PM IO worst case fuel combustion.2.80 lb/hr SOz VOC emission rate includes
MS-08 AP-42 8.10 Ib/hr VOC an estimate for non-162.5 lb/hr CO combustion emissions
41.60 lb/hr NOx (evaporation, crankcase,and refueling losses).Combined all Non-
MS-12 SOCMI1.061b/hr VOClNon-HAP Refrigerant
Refrigerant emissions for the entirefacility
2.00 Ib/hr VOC Primary Operating
24-01 Mass Balance0.10 Ib/hr HBr VOC emissions from the
0.10 Ib/hr Acetone reactor before flaring are0.10 Ib/hr HCl 48.51b/hr
48.5 lb/hr VOCVOC missions are not sent
to a flare but emitted24-01 Mass Balance
0.10 lb/hr HBrdirectly to the atmosphere
0.10 Ib/hr AcetoneHBr and HCI are scrubbed
0.10 Ib/hr HCl out by the wash column.1.1 Ib/hr VOC0.1 lb/hr HBr
24-02 SOCMI0.1 Ib/hr Acetone
1.3 Ib/hr HCI0.1 lb/hr 1,2-Epoxybutane
Permit #:762-AOP-R13AFIN: 14-00028Page 16 of25
12. TESTING REQUIREMENTS:
This permit requires stack testing of the following sources.
SN(s) PollutantTest
Test IntervalJustification For Test
Method RequirementBR-Ol
VOC 18/25A 5 year Compliance VerificationBR-04BR-OI
Br2BR-04 26A 5 year Compliance VerificationBR-12
CI2
SR-OI S02 6C 5 year Compliance VerificationCB-02
Br2 26A 5 year Compliance VerificationCB-16CB-02
VOC 18or25AEvery 365
Compliance Verification(Alternate) days operation
CB-16VOC 18or25A
Every 365Compliance Verification
(A Iternate) days operationDE-21 VOC 18 or 25A 5 year Compliance VerificationDE-23 VOC 18or25A 5 year Compliance VerificationDE-23 HCI 26 5 year Compliance VerificationDE-23 Chloroethane 18 5 year Compliance VerificationAD-05 VOC 18 or 25A 5 year Compliance Verification
AD-05HBr 26A
5 year Compliance VerificationBr2 26A
PM 10 5S02 6C
AD-25 VOC 18/25A 2 years Compliance VerificationCO lOB
NOx 7E
AD-35HBr 26A
5 year Compliance VerificationBr2 26A
DB-OI Br2 26A 5 year Compliance VerificationDB-04 Br2 26A 5 year Compliance Verification
HBr 26AEvery 8760
TB-03Br2 26A
hrs of Compliance Verificationoperation
TB-14 Br2 26A Every 8760
(Stabrom)BrCI 26A hrs of Compliance VerificationCh 26A operation
15-12 VOC 18 or 25A 2 year Compliance Verification15-12 PM 10 5 2 year Compliance Verification15-12 Br2 26A 5 year Compliance Verification15-16 PM IO 5 2 year Compliance Verification
Permit #:762-AOP-R13AFIN: 14-00028Page 17 of25
SN(s) PoUutant Test Test IntervalJustification For Test
Method Requirement
16-01 S02Approved
5 year Compliance VerificationMethod
16-02 Br2 26A 5 year Compliance Verification
16-02 S02Approved
5 year Compliance VerificationMethod
16-24 S02Approved
5 year Compliance VerificationMethod
16-25 VOC 25 A 5 year Compliance VerificationSOl 6C
BH-OI VOC 18/25A5 year Compliance Verification
BH-02 CO lOBNOx 7E
Approved5 year after
21-04 VOC initial Compliance VerificationMethod
compliance23-03 VOC 18 5 year Compliance Verification23-05 VOC 18 5 year Compliance Verification
23-065 year, one
23-07 VOC 18silo, must be
Compliance Verificationin receiving
23-08mode
23-065 year, one
23-07 HBr 26Asilo, must be
Compliance Verificationin receiving
23-08mode
PM 10 5
DM-02VOC 18
5 year Compliance VerificationCO lOB
NOx 7EDM-02 S02 6C 2 year Compliance Verification
13. MONITORING OR CEMS
The permittee must monitor the following parameters with CEMs or other monitoringequipment (temperature, pressure differential, etc), frequency of recording and the need forrecords included in any annual, semiannual or other reports.
Parameter or Method of Monitoring (CEM, ReportSN PoUutant to be Frequency*
MonitoredPressure Gauge, etc) (Y/N)**
BR-OlFlow Rate Flow Rate Monitor Continuously y
BR-04SR-OI Temperature Thermocouple Continuously N
Pennit #:762-AOP-RI3AFIN: 14-00028Page 180[25
Parameter or Method of Monitoring (CEM, ReportSN Pollutant to be Frequency*
MonitoredPressure Gauge, etc) (YIN)**
DE-21 Temperature Thermocouple Continuously NDE-23 Flow Rate Flow Rate Monitor Continuously NAD-05 Flow Rate Flow Rate Monitor Continuously NAD-35 Temperature Thermocouple Continuously N
TB-13Liquid to Gas Mass
Flow Rate Monitor Continuously NFlow Rate
TB-13Stripper
Thermocouple Continuously NTemperature
TB-25 CoolantThennocouple Continuously N
(NC-24) Temperature15-02 Br2 CEM Continuously N15-12 Br2 CEM Continuously N
16-01Scrubber Media
Flow Rate Monitor Every 3 hours NFlow Rate
16-01 Scrubber Media pH pH Monitor Every 3 hours N
16-02Scrubber Media
Flow Rate Monitor Every 3 hours NFlow Rate
16-02 Scrubber Media pH pH Monitor Every 3 hours N
16-05Scrubber Media
Flow Rate Monitor Every 3 hours NFlow Rate
16-05 Scrubber Media pH pH Monitor Every 3 hours N
16-06Scrubber Media
Flow Rate Monitor Every 3 hours NFlow Rate
16-06 Scrubber Media pH pH Monitor Every 3 hours N
16-13Scrubber Media
Flow Rate Monitor Every 3 hours NFlow Rate
16-24Scrubber Media
Flow Rate Monitor Every 3 hours NFlow Rate
16-25Scrubber Media
Flow Rate Monitor Every 3 hours NFlow Rate
16-25 Scrubber Media pH pH Monitor Every 3 hours NContinuously for
BH-OI H2S Concentration / H2S Concentration Monitor / Flowconcentration
BH-02 Gas Flow Rate Rate MonitorOnce every six Nhours for flow
rate
21-01Process Gas Flow
Flow Rate Monitor Continuously NRate into Oxidizer
21-01Combustion Zone
Thermocouple Continuously NTemperature
Permit #:762-AOP-RI3AFIN: 14-00028Page 19 of25
Parameter orMethod of Monitoring (CEM, Report
SN Pollutant to be Frequency*Monitored
Pressure Gauge, etc) (YIN)**
23-03Scrubber media
Flow Rate Monitor Continuously NFlow Rate
23-05Scrubber media
Flow Rate Monitor Continuously NFlow Rate
DM-02Combustion Zone
Thermocouple Continuously NTemperature
Water Flow Rate Flow Rate Monitor24-01 Chilled Water
ThermocoupleContinuously N
Temperature* Indicate frequency of recordmg reqUIred for the parameter (Contmuously, hourly, dally, etc.)** Indicates whether the parameter needs to be included in reports.
14. RECORD KEEPING REQUIREMENTS
The following are items (such as throughput, fuel usage, VOC content of coating, etc) thatmust be tracked and recorded, frequency of recording and whether records are needed to beincluded in any annual, semiannual or other reports.
SN Recorded ItemLimit (as established in
Frequency*Report
permit) (YIN)**
BR-OIEstablished according to
BR-04Brine Solution Flow Rate most recent satisfactory Continuous Y
test
Pump Discharge Valve PositionEstablished according to
BR-12and Run Light
most recent satisfactory 3 hours y
testStrength of caustic
EachBR-12
Caustic Concentration of solution as established RailCar/Truck yScrubber Media according to most recent
Unloadingsatisfactory test
SR-OI Flare Temperature 1200 of or above Continuous N
CB-04 Methanol Throughput106 gallon per
Monthly Yconsecutive 12 months
CB-02 Batch Production 1460 batches perMonthly Y
CB-16 (Alternate Scenario) consecutive 12 monthsDE-21 Combustion Zone Temperature 1400 OF or above Continuous N
Established according toDE-23 Scrubber Media Flow Rate most recent satisfactory 3 hours N
test
Pennit #:762-AOP-R13AFIN: 14-00028Page 20 of25
SN Recorded ItemLimit (as established in Frequency*
Reportpermit) (YIN)**
Strength of causticEach
DE-23Caustic Concentration of solution as established
RailCar/Truck NScrubber Media according to most recent
Unloadingsatisfactory test
Established according toAD-05 Scrubber Media Flow Rate most recent satisfactory 4 hour N
testStrength of caustic
Caustic Concentration ofsolution and change out
AD-05Scrubber Media
as established according 12 hour Nto most recent satisfactory
testNot to exceed 4380 hours
AD-21 Period of Storage ofC8 Olefin per consecutive 12 Monthly Nmonths
AD-35 Flare Temperature I500 of or above Continuous NDuration of each Alternate 2.9 tpy VOC as
AD-39 Scenario Event and Vapor calculated from mass Per Event NPressure balance and records
Carbon Bed Regenerate every 12AB-15 Regeneration/Carbon hours N/A N
Replacement Replace Every 10,220 hrs
DB-OICaustic Concentration of
Must be greater than 5% 12 hour NScrubber Media
DB-07 Dried Tanks of Diphenyl Oxide 150 tanks per year Monthly N
TB-03Liquid to Gas Mass Flow Rate
L/G 2: 15.5 Continuous NRatio
TB-03 Stripper Temperature 169.7 of or above Continuous y
TB-03Hours of EtBr Production
1400 hours perMonthly y
(EtBr) consecutive 12 monthsTB-25
Glycol Coolant TemperatureMaximum Daily Ave
Daily N(NC-24) 40 of
15-18DPE Production By-Product 69,630 Ibs/week By-
Weekly NGeneration Product
16-01 Scrubber Media Flow Rate 6 gpm 3 hours NEstablished according to
16-01 Scrubber Media pH most recent satisfactory 3 hours Ntest
16-02 Scrubber Media Flow Rate 60gpm 3 hours NEstablished according to
16-02 Scrubber Media pH most recent satisfactory 3 hours Ntest
16-05 Scrubber Media Flow Rate 4gpm 3 hours N
Pennit #:762-AOP-RI3AFIN: 14-00028Page 21 of25
SN Recorded ItemLimit (as established in
Frequency* Reportpermit) (YIN)**
Established according to16-05 Scrubber Media pH most recent satisfactory 3 hours N
test16-06 Scrubber Media Flow Rate 6gpm 3 hours N
Established according to16-06 Scrubber Media pH most recent satisfactory 3 hours N
test16-13 Scrubber Media Flow Rate 4gpm 3 hours N16-14 Carbon Canister Replacement Once every year Annually N16-15 Carbon Canister Replacement Once every year Annually N16-22 Carbon Canister Replacement Once every year Annually N
-16-24 Hours of Operation 1,752 hours per year Per Event N16-24 Scrubber Media Flow Rate 6gpm 3 hours N16-25 Scrubber Media Flow Rate 25 gpm 3 hours N
Established according to16-25 Scrubber Media pH most recent satisfactory 3 hours N
test
16-31 Phthalic Anhydride Throughput18.25 MM Ib per
Monthly Yconsecutive 12 months
BH-OIEstablished according to
BH-02H2S Concentration in fuel most recent satisfactory 6 hours N
test for S02
BH-OIEstablished according to
BH-02Fuel Flow Rate most recent satisfactory 6 hours N
test21-01 Process Gas Velocity 19 ft/sec Continuous N21-01 Combustion Zone Temperature 1400 of Min. Continuous N
Number of Batches Produced
NC-22Scenario A Batches are
1,925 batches permultiplied by 1.54 Monthly Y
UnitScenario B Batches are
consecutive 12 months
multiplied by 1.00Minimum flow rate set
23-03 Scrubber Media Flow Ratepoint established
Continuous Naccording to most recent
satisfactory test.23-04 By-Product Drum Turnovers 96 turnovers per day Daily N
Minimum flow rate set
23-05 Scrubber Media Flow Ratepoint established
Continuous Naccording to most recent
satisfactory test.
Permit #:762-AOP-RI3AFIN: 14-00028Page 22 of25
SN Recorded ItemLimit (as established in
Frequency*Report
pennit) (YIN)**If less than 75 cycles per
year then monthlyMonthly
recordkeeping of number
23-14 Cleaning Cycles of cycles. yIfmore than 75 cycles per
year then complianceMonthly
demonstrated throughemission calculations.
NC-23 Primary Reactor Throughput for 1.725 Million Pounds ofMonthly Y
CMPU ABRMI ABRMI per year
DM-02 Combustion Zone Temperature 1200 OF or above 24 hours N
MS-02Amount of Solids Transferred to Based on Semi-Annual
Monthly NLandfill (MS-06) Emission Calculations
MS-03 Amount of Water Recovered82.0 million gallons per
Monthly Nyear (total)
MS-05 Coating and Adhesives Usage 100 gallons per year Monthly N
MS-06 All Matter Disposed24 million pounds per
Monthly Nconsecutive 12 months
MS-07 Gasoline Throughput200,000 gallons per
Monthly Nconsecutive 12 months
MS-08 Emergency Power Generation64,500 kW-hrs per
Monthly Yconsecutive 12 months
Emergency Power Maximum1000 kW (total) of which
MS-08Output
only 275.5 kW may be Monthly Ygenerated by gasoline
Water Flow RateMinimum Daily Ave.
24-011,500 Ib/hr
Daily NMaximum Daily Ave.
Chilled Water Temperature 60 OF
Duration of each event while0.60 tpy VOC calculated
24-01operating in alternate Scenario
based on mass balance andrecordkeeping
Gallons of Product 1,500,000 gallons per year1,2-Epoxybutane Usage 50,000 gallons per year
NC-24 24-hours per consecutive
Unit 12 months. Ifventing Monthly YVenting to SN-AD-26 exceeds 24 hours
calculate emissions foreach event.
Permit #:762-AOP-R13AFIN: 14-00028Page 24 of25
Compliance
Opacity JustificationMechanism (daily
SN% (NSPS limit, Dept. Guidance, etc)
observation, weekly,control equipment
operation, etc)15-02 5 Department Guidance Inspector's Observation15-12 5 Department Guidance Inspector's Observation15-16 5 Department Guidance Inspector's Observation15-18 5 Department Guidance Inspector's Observation16-01 5 Department Guidance Inspector's Observation16-02 5 Department Guidance Inspector's Observation16-06 5 Department Guidance Inspector's Observation16-07 5 Department Guidance Inspector's Observation16-08 5 Department Guidance Inspector's Observation16-10 5 Department Guidance Inspector's Observation16-11 5 Department Guidance Inspector's Observation16-12 5 Department Guidance Inspector's Observation16-18 5 Department Guidance Inspector's Observation16-19 5 Department Guidance Inspector's Observation16-20 5 Department Guidance Inspector's Observation16-21 5 Department Guidance Inspector's Observation16-22 5 Department Guidance Inspector's Observation16-25 5 Department Guidance Inspector's Observation16-26 5 Department Guidance Inspector's Observation16-27 5 Department Guidance Inspector's Observation16-29 5 Department Guidance Inspector's ObservationBH-Ol 5 Department Guidance Inspector's ObservationBH-02 5 Department Guidance Inspector's Observation21-01 5 Department Guidance Inspector's Observation23-02 5 Department Guidance Inspector's Observation23-06 5 Department Guidance Inspector's Observation
23-11A 5 Department Guidance Inspector's Observation23-11 B 5 Department Guidance Inspector's Observation23-12A 5 Department Guidance Inspector's Observation23-12B 5 Department Guidance Inspector's Observation23-13 5 Department Guidance Inspector's ObservationBT-ll 5 Department Guidance Inspector's ObservationBT-12 5 Department Guidance Inspector's ObservationBT-13 5 Department Guidance Inspector's ObservationBT-21 5 Department Guidance Inspector's Observation
Permit #:762-AOP-R13AFIN: 14-00028Page 23 of25
SN Recorded ItemLimit (as established in
Frequency*Report
permit) (YIN)**
DB-19T Hours ofOperation I, 080 hours totalPer Period of
NOperation
* Indicate frequency of recordmg reqUired for the Item (Continuously, hourly, daily, etc.)** Indicates whether the item needs to be included in reports
15. OPACITY
Compliance
Opacity JustificationMechanism (daily
SN observation, weekly,% (NSPS limit, Dept. Guidance, etc)
control equipmentoperation, etc)
BR-Ol 5 Department Guidance Inspector's ObservationBR-04 5 Department Guidance Inspector's ObservationBR-09 5 Department Guidance Inspector's ObservationBR-12 5 Department Guidance Inspector's ObservationSL-Ol 5 Department Guidance Inspector's ObservationSR-Ol 5 Department Guidance Inspector's ObservationCB-Ol 5 Department Guidance Inspector's ObservationCB-02 5 Department Guidance Inspector's ObservationCB-16 5 Department Guidance Inspector's ObservationCB-18 5 Department Guidance Inspector's ObservationDE-17 5 Department Guidance Inspector's ObservationDE-18 5 Department Guidance Inspector's ObservationDE-21 5 Department Guidance Inspector's ObservationDE-23 5 Department Guidance Inspector's ObservationAD-05 5 Department Guidance Inspector's ObservationAD-26 5 Department Guidance Inspector's ObservationAD-35 5 Department Guidance Inspector's ObservationDB-Ol 5 Department Guidance Inspector's ObservationDB-04 5 Department Guidance Inspector's ObservationDB-05 5 Department Guidance Inspector's ObservationDB-06 5 Department Guidance Inspector's ObservationDB-08 5 Department Guidance Inspector's ObservationDB-17 5 Department Guidance Inspector's ObservationDB-19 5 Department Guidance Inspector's Observation
DB-19T 5 Department Guidance Inspector's ObservationTB-04 5 Department Guidance Inspector's ObservationTB-08 5 Department Guidance Inspector's ObservationTB-14 5 Department Guidance Inspector's Observation
Permit #:762-AOP-R13AFIN: 14-00028Page 25 of25
Compliance
Opacity JustificationMechanism (daily
SN% (NSPS limit, Dept. Guidance, etc)
observation, weekly,control equipment
operation, etc)DM-02 5 Department Guidance Inspector's ObservationMS-08 20 §19.503 and Part 52, Subpart E Inspector's Observation
16. DELETED CONDITIONS:
No specific conditions were deleted for 762-AOP-12.
17. VOIDED, SUPERSEDED OR SUBSUMED PERMITS
List all active permits voided/superseded/subsumed by issuance of this permit for thisfacility.
Permit #
762-AOP-RI2
18. CONCURRENCE BY:
The following supervi or concurs with the permitting decision:
Fee Calculation for Major Source
$/ton factorPermit Type
Minor Modification Fee $Minimum Modification Fee $Renewal with Minor Modification $If Hold Active Pennit, Amt of Last Annual Air Pennit Invoice $
Total Permit Fee Chargeable Emissions (tpy)
Annual Chargeable Emission (tpy)Permit Fee $
4726.41000
Pollutant
Check ifChargeableEmission
OldPermit
NewPermit
Permit FeeChange in ChargeableEmissions Emissions
AnnualChargeableEmissions
PM
PM10
SOz
VOC
CO
NOx
Xylene + Ethyl Benzene
I, I Dichloroethane
1,2-Epoxybutane
Acetaldehyde
Benzene
Bromoform
Chloroethane
Chloroform
Chlorine (CI2)
Cl2 or Halogens
(C12 + Br2)
Dimethyl Formide
Ethylene Chloride
Ethyl Benzene
Ethylene Dibromide
Ethylene Dichloride
Ethylene Glycol
HCl
Hexane
Iso-Octane
Dichloromethane
Methanol
Methyl Bromide
Methyl Naphthalene
Phenol
Phthalic Anhydride
Toluene Diamine
Toluene
Xylene
Br2+HBr
Acetone
Ammonia (NH3)
Br2
BrCI
H202
H2S
H2S04
HBr
Pollutant )
Check ifChargeableEmission
OldPermit
NewPermit
Permit FeeChange in ChargeableEmissions Emissions
AnnualChargeableEmissions
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