PerkinElmer Arnel Turnkey GC Systems
Petrochemical & Natural Gas Applications
1
Introduction The measurement of semivolatile and volatile compounds in petrochemical feeds, processes and products can be easily accomplished with turnkey analyzers and systems designed to meet accepted standard methods. PerkinElmer has a long-standing relationship with Arnel™, a market leader in customized chromatography solutions, to provide, install, and support a full range of guaranteed analyzers, systems and accessories. This Applications booklet summarizes the features and benefits of individual Clarus™ Arnel GC analyzers that are available for a variety of petrochemical laboratory and process applications, from hydrogen to asphalt analysis. More details and specifications are available for each model by obtaining the referenced companion literature for each product. Almost 100 turnkey analyzers are presented, ensuring that consultation with a PerkinElmer representative will deliver the analyzer that will meet your needs. Tables 1, 2 and 3 below show industry-standard methods compliance for standard model Refinery Gas Analyzers (RGA), Natural Gas Analyzers (NGA) and Trace Sulfur Analyzer Systems. Other standard model analyzers for light gas, chlorine, transformer oil gas, LPG and simulated distillation through detailed hydrocarbon analyses that are compliant with ASTM and various industry standard methods are also summarized in this applications booklet. Table 1. Methods Compliance for RGA Systems
PerkinElmer Arnel RGA Model ASTM Method UOP Method 1001 D1945, D1946, D2597 539 1101 D1945, D1946, D2597 539 1201 D1945, D1946, D2597 539 1301 D1945, D1946, D2597 539 1015, 1016 D1945, D1946, D2597 539, 709 1115, 1116 D1945, D1946, D2597 539, 709 1215, 1216 D1945, D1946, D2597 539, 709 1315, 1316 D1945, D1946, D2597 539, 709
Table 2. Methods Compliance for NGA Systems
PerkinElmer Arnel NGA Model ASTM Methods GPA Methods ISO Methods IP Methods 2001, 2101 D1945, D1946, D2597 2261 6568, 6974-5 None 2201, 2301 D1945 2177, 2261 6568, 6974-5 None 2002, 2102, 2202, 2302 D1945 2261 6974-5 None
2003, 2103, 2203, 2303 D1945, D1946 2261 None None
2206, 2306 None 2165, 2177, 2186 None None 2008 D1946 2286 6975 345 2108 D1946 2286 6974E, 6974-3, 6975 345 2208 D1946 2165, 2186, 2286 6974E, 6974-3, 6975 345 2009, 2109, 2209 D1946 2286 6975 345 2000, 2100, 2200, 2300, D1945, D1946 None None None
2006, 2106 D1945, D1946 None None None 2010, 2110, 2210 D1945 2261 6974-5 None
Table 3. Methods Compliance for Sulfur Analyzer Systems
PerkinElmer Arnel Sulfur Analyzer Model ASTM Methods 4025, 4026, 4027, 4028, 4029, 4227, 4229, 4425, 4428, 4429, 4629 D5504, D5623, D6021
2
Table of Contents Refinery Gas Analyzers Model 1001…………………………………………………………………………………….….5 Model 1015………………………………………………………………………………….…….6 Model 1016………………………………………………………………………………….…….7 Model 1101……………………………………………………………………………….……….8 Model 1115……………………………………………………………………………….……….9 Model 1116………………………………………………………………………………………10 Model 1201……………………………………………………………………………………....11 Model 1215.......................................................................................................................12 Model 1216.......................................................................................................................13 Model 1301.......................................................................................................................14 Model 1315.......................................................................................................................15 Model 1316.......................................................................................................................16 Natural Gas Analyzers Model 2000......................................................................................................................18 Model 2001......................................................................................................................19 Model 2002......................................................................................................................20 Model 2003......................................................................................................................21 Model 2006………………………………………………………………………………...……22 Model 2008......................................................................................................................23 Model 2009......................................................................................................................24 Model 2010......................................................................................................................25 Model 2100......................................................................................................................26 Model 2101......................................................................................................................27 Model 2102......................................................................................................................28 Model 2103......................................................................................................................29 Model 2106......................................................................................................................30 Model 2108......................................................................................................................31 Model 2109......................................................................................................................32 Model 2110......................................................................................................................33 Model 2200………………………………………………………………………………………34 Model 2201………………………………………………………………………………………35 Model 2202………………………………………………………………………………………36 Model 2203………………………………………………………………………………………37 Model 2206………………………………………………………………………………………38 Model 2208………………………………………………………………………………………39 Model 2209………………………………………………………………………………………40 Model 2210………………………………………………………………………………………41 Model 2300………………………………………………………………………………………42 Model 2301………………………………………………………………………………...…….43 Model 2302.......................................................................................................................44 Model 2303.......................................................................................................................45 Model 2306.......................................................................................................................46 Model 2310.......................................................................................................................47 Simulated Distillation Software and Software Enhancements Model 3012.......................................................................................................................49 Model 3013.......................................................................................................................50 Model 3062.......................................................................................................................51
3
Trace Sulfur Analyzers Model 4025.......................................................................................................................53 Model 4026.......................................................................................................................54 Model 4027.......................................................................................................................55 Model 4028.......................................................................................................................56 Model 4029.......................................................................................................................57 Model 4227.......................................................................................................................58 Model 4229.......................................................................................................................59 Model 4425.......................................................................................................................60 Model 4428.......................................................................................................................60 Model 4429.......................................................................................................................60 Model 4629.......................................................................................................................60 Other Analyzers (For light gas, chlorine, transformer oil gas, LPG and simulated distillation through detailed hydrocarbon analyses) Model 4001……………………………………………………………………………………….62 Model 4002……………………………………………………………………………………….62 Model 4003……………………………………………………………………………………….63 Model 4004……………………………………………………………………………………….64 Model 4005……………………………………………………………………………………….65 Model 4006……………………………………………………………………………………….66 Model 4007……………………………………………………………………………………….67 Model 4008……………………………………………………………………………………….67 Model 4009……………………………………………………………………………………….68 Model 4010……………………………………………………………………………………….68 Model 4011……………………………………………………………………………………….69 Model 4012……………………………………………………………………………………….69 Model 4013……………………………………………………………………………………….70 Model 4014……………………………………………………………………………………….71 Model 4015……………………………………………………………………………………….72 Model 4016……………………………………………………………………………………….73 Model 4017……………………………………………………………………………………….74 Model 4018……………………………………………………………………………………….75 Model 4019……………………………………………………………………………………….76 Model 4020……………………………………………………………………………………….77 Model 4021……………………………………………………………………………………….78 Model 4022……………………………………………………………………………………….79 Model 4023……………………………………………………………………………………….80 Model 4024……………………………………………………………………………………….81 Model 4032……………………………………………………………………………………….82 Model 4033……………………………………………………………………………………….82 Model 4034……………………………………………………………………………………….82 Model 4035……………………………………………………………………………………….83 Model 4036……………………………………………………………………………………….84 Model 4037……………………………………………………………………………………….85 Model 4080……………………………………………………………………………………….86 Model 4081……………………………………………………………………………………….63 Model 4082……………………………………………………………………………………….87 Model 4083……………………………………………………………………………………….88 Model 4086……………………………………………………………………………………….89 C5=: Pentenes C6+: C6 hydrocarbons and higher
Refine Model 1001
Model 1015
Model 1016
Model 1101
Model 1115
Model 1116
Model 1201
Model 1215
Model 1216
Model 1301
Model 1315
Model 1316
Re
fin
ery
Ga
s A
na
lyze
rs
Refinery Gas Analyzers
5
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Refinery Gas Analyzers
Refinery Gas Analyzer Model 1001
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.1 to 25%; all other components - 0.01 to 100% except the C5=, C6+, H2O, NH3 composite peak - 0.01 to 40% Application note reference number with technical details: D-6620
• Simple, lowest-cost refinery/light hydrocarbon gas analysis solution • Single channel/single thermal conductivity detector (TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common
contaminants • Limited hydrogen detection range (see Model 1101 for full range capability) • 35 - 40 minute analysis time (see Model 1015 for faster analysis time) • Plumbed in sulfur-resistant materials to enhance H2S detection
6
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Refinery Gas Analyzer Model 1015
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 709, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+ composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.02 to 100%; C1 through C5 - 0.001 to 100% on FID; C5=, C6+ composite peak - 0.002 to 40%; O2, N2, CO2, CO, C1 and C2 hydrocarbons on TCD - 0.01 to 100% Application note reference number with technical details: D-6621
• Rapid, 15-minute analysis time • Dual channel/thermal conductivity detector and flame ionization detector (TCD/FID) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Limited hydrogen detection range (see Model 1115 for full range capability) • Critical 1-butene/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection
C5=
,C6+
Met
hane
Prop
ane
Prop
ylen
e
Etha
ne,E
thyl
ene
1-Bu
tene
t-But
ene-
2c-
Bute
ne-2
1,3-
Buta
dien
e
i-But
ane
Prop
adie
nen-
Buta
ne
i-Pen
tane
n-Pe
ntan
e
15 M
inut
es
Acet
ylen
e
Channel two - FIDChannel one - TCD
7
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Prop
ane
Acet
ylen
ePr
opyl
ene
i-But
ane
Prop
adie
ne n-Bu
tane
Met
hane
, Air
C5=
, C6+
, H2O
, NH
3
Etha
ne, E
thyl
ene
CO
2
i-Pen
tane
n-Pe
ntan
e
15 M
inut
es
1,3-
Buta
dien
e
c-Bu
tene
-2t-B
uten
e-2
Bute
ne-1
i-But
ylen
e
H2S
Refinery Gas Analyzer Model 1016
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 709, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.02 to 100%; C5=, C6+, H2O, NH3 composite peak - 0.2 to 40%; all other components - 0.01 to 100% Application note reference number with technical details: D-6621
• Rapid, 15-minute analysis time • Dual channel/dual thermal conductivity detector (TCD/TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Limited hydrogen detection range (see Model 1116 for full range capability) • Critical butane-1/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection
Channel two - TCD Channel one - TCD
8
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • Includes Model 3062 Software, which contains a merge program to combine
multichannel data into one report • Rugged packed columns, no degradation from H2O, NH3 or other common
contaminants • 35 - 40 minute analysis time (see Model 1015 for faster analysis time) • Plumbed in sulfur-resistant materials to enhance H2S detection
Refinery Gas Analyzer Model 1101
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2S - 0.1 to 25%; all other components - 0.01 to 100% except the C5=, C6+, H2O, NH3 composite peak - 0.01 to 40% Application note reference number with technical details: D-6620, D-6651, D-6653
9
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Refinery Gas Analyzer Model 1115
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, UOP 709, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+ composite peak Guaranteed detection ranges/concentration levels: H2S - 0.02 to 100%; C1 through C5 - 0.001 to 100% on FID; C5=, C6+ composite peak - 0.002 to 40%; He, H2, O2, N2, CO2, CO, C1, C2 hydrocarbons on TCD - 0.01 to 100% Application note reference number with technical details: D-6621, D-6651, D-6653
• Rapid, 15-minute analysis time • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel/dual thermal conductivity detector and flame ionization detector
(TCD/TCD/FID) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Critical 1-butene/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection
C5=
,C6+
Met
hane
Prop
ane
Prop
ylen
e
Etha
ne,E
thyl
ene
1-Bu
tene
t-But
ene-
2c-
Bute
ne-2
1,3-
Buta
dien
e
i-But
ane
Prop
adie
nen-
Buta
ne
i-Pen
tane
n-Pe
ntan
e
15 M
inut
es
Acet
ylen
e
Hyd
roge
n
CO
2
Ethy
lene
Etha
ne
Acet
ylen
e
H2S
Oxy
gen
Nitr
ogen
Met
hane
CO 15
Min
utes
Channel three - FID Channel one and two - TCD/TCD
(electronically combined into one output )
10
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Prop
ane
Acet
ylen
ePr
opyl
ene
i-But
ane
Prop
adie
ne n-Bu
tane
Met
hane
, Air
C5=
, C6+
, H2O
, NH
3
Etha
ne, E
thyl
ene
CO
2
i-Pen
tane
n-Pe
ntan
e
15 M
inut
es
1,3-
Buta
dien
e
c-Bu
tene
-2t-B
uten
e-2
Bute
ne-1
i-But
ylen
e
H2S
Refinery Gas Analyzer Model 1116
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, UOP 709, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2S - 0.02 to 100%; C5=, C6+, H2O, NH3 composite peak - 0.2 to 40%; all other components - 0.01 to 100% Application note reference number with technical details: D-6621, D-6651, D-6653
• Rapid, 15-minute analysis time • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel/three thermal conductivity detector (TCD/TCD/TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Critical 1-butene (butene-1)/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection
Hyd
roge
n
CO
2
Ethy
lene
Etha
ne
Acet
ylen
e
H2S
Oxy
gen
Nitr
ogen
Met
hane
CO 15
Min
utes
Channel three - TCD Channel one and two - TCD/TCD (electronically combined into one output)
11
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Added liquid-sampling capability to Model 1001 • Includes sample-loop purge feature that prevents contamination when changing
sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection • Single channel/single thermal conductivity detector (TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common
contaminants • Limited hydrogen detection range (see Model 1101 for full-range capability) • 35 - 40 minute analysis time (see Model 1015 for faster analysis time) • Plumbed in sulfur-resistant materials to enhance H2S detection
Refinery Gas Analyzer Model 1201
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.1 to 25%; all other components - 0.01 to 100% except the C5=, C6+, H2O, NH3 composite peak - 0.01 to 40% Application note reference number with technical details: D-6620, D-6652, D-6653
12
Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Rapid, 15-minute analysis time • Added liquid-sampling capability to FID channel of Model 1015 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/thermal conductivity detector and flame ionization detector (TCD/FID) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Limited hydrogen detection range (see Model 1315 for full-range capability) • Critical 1-butene/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection
Refinery Gas Analyzer Model 1215
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 709, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+ composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.02 to 100%; C1 through C5 - 0.001 to 100% on FID; C5=, C6+ composite peak - 0.002 to 40%; O2, N2, CO2, CO, C1, C2s on TCD - 0.01 to 100% Application note reference number with technical details: D-6621, D-6652, D-6653
C5=
,C6+
Met
hane
Prop
ane
Prop
ylen
e
Etha
ne,E
thyl
ene
1-Bu
tene
t-But
ene-
2c-
Bute
ne-2
1,3-
Buta
dien
e
i-But
ane
Prop
adie
nen-
Buta
ne
i-Pen
tane
n-Pe
ntan
e
15 M
inut
es
Acet
ylen
e
Channel two - FID Channel one - TCD
13
Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Rapid, 15-minute analysis time • Added liquid-sampling capability to hydrocarbon channel of Model 1016 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/dual thermal conductivity detector (TCD/TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Limited hydrogen detection range (see Model 1316 for full-range capability) • Critical butene – 1/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection
Prop
ane
Acet
ylen
ePr
opyl
ene
i-But
ane
Prop
adie
ne n-Bu
tane
Met
hane
, Air
C5=
, C6+
, H2O
, NH
3
Etha
ne, E
thyl
ene
CO
2
i-Pen
tane
n-Pe
ntan
e
15 M
inut
es
1,3-
Buta
dien
e
c-Bu
tene
-2t-B
uten
e-2
Bute
ne-1
i-But
ylen
e
H2S
Refinery Gas Analyzer Model 1216
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 709, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.02 to 100%; C5=, C6+, H2O, NH3 composite peak - 0.2 to 40%; all other components - 0.01 to 100% Application note reference number with technical details: D-6621, D-6652, D-6653
Channel two - TCD Channel one - TCD
14
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Refinery Gas Analyzer Model 1301
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2S - 0.1 to 25%; all other components - 0.01 to 100% except the C5=, C6+, H2O, NH3 composite peak - 0.01 to 40% Application note reference number with technical details: D-6620, D-6651, D-6652, D-6653
• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Added liquid-sampling capability to Model 1101 • Includes sample-loop purge feature that prevents contamination when changing
sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/dual thermal conductivity detector (TCD/TCD) • Includes Model 3062 Software, which contains a merge program to combine
multichannel data into one report • Rugged packed columns, no degradation from H2O, NH3 or other common
contaminants • 35 - 40 minute analysis time (see Model 1015 for faster analysis time) • Plumbed in sulfur-resistant materials to enhance H2S detection
15
Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Rapid, 15-minute analysis time • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel / dual thermal conductivity detector and flame ionization detector
(TCD/TCD/FID) • Added liquid-sampling capability to FID channel of Model 1115 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Rugged packed columns, no degradation from H2O, NH3 or other common
contaminants • Critical 1-butene/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection
Refinery Gas Analyzer Model 1315
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, UOP 709, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+ composite peak Guaranteed detection ranges/concentration levels: H2S - 0.02 to 100%; C1 through C5 - 0.001 to 100% on FID; C5=, C6+ composite peak - 0.002 to 40%; He, H2, O2, N2, CO2, CO, C1 and C2 hydrocarbons on TCD - 0.01 to 100% Application note reference number with technical details: D-6621, D-6651, D-6652, D-6653
C5=
,C6+
Met
hane
Prop
ane
Prop
ylen
e
Etha
ne,E
thyl
ene
1-Bu
tene
t-But
ene-
2c-
Bute
ne-2
1,3-
Buta
dien
e
i-But
ane
Prop
adie
nen-
Buta
ne
i-Pen
tane
n-Pe
ntan
e
15 M
inut
es
Acet
ylen
e
Hyd
roge
n
CO
2
Ethy
lene
Etha
ne
Acet
ylen
e
H2S
Oxy
gen
Nitr
ogen
Met
hane
CO 15
Min
utes
Channel three - FID Channel one and two - TCD/TCD (electronically combined into one output)
16
Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Rapid, 15-minute analysis time • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel/three thermal conductivity detector (TCD/TCD/TCD) • Added liquid-sampling capability to FID channel of Model 1116 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Critical butane-1/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection
Prop
ane
Acet
ylen
ePr
opyl
ene
i-But
ane
Prop
adie
ne n-Bu
tane
Met
hane
, Air
C5=
, C6+
, H2O
, NH
3
Etha
ne, E
thyl
ene
CO
2
i-Pen
tane
n-Pe
ntan
e
15 M
inut
es
1,3-
Buta
dien
e
c-Bu
tene
-2t-B
uten
e-2
Bute
ne-1
i-But
ylen
e
H2S
Refinery Gas Analyzer Model 1316
Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, UOP 709, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2S - 0.02 to 100%; C5=, C6+, H2O, NH3 composite peak - 0.2 to 40%; all other components - 0.01 to 100% Application note reference number with technical details: D-6621, D-6651, D-6652, D-6653
Hyd
roge
n
CO
2
Ethy
lene
Etha
ne
Acet
ylen
e
H2S
Oxy
gen
Nitr
ogen
Met
hane
CO 15
Min
utes
Channel three - TCD Channel one and two - TCD/TCD (electronically combined into one output )
Natural Model 2000
Model 2001
Model 2002
Model 2003
Model 2006
Model 2008
Model 2009
Model 2010
Model 2100
Model 2101
Model 2102
Model 2103
Model 2106
Model 2108
Model 2109
Model 2110
Model 2200
Model 2201
Model 2202
Model 2203
Model 2206
Model 2208
Model 2209
Model 2210
Model 2300
Model 2301
Model 2302
Model 2303
Model 2306
Model 2310
Na
tura
l G
as A
na
lyze
rs
Natural Gas Analyzers
18
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Simple, low-cost solution • Single channel/single FID • Only hydrocarbons detected and measured, no interference from air or CO2 • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG.
Natural Gas Analyzer Model 2000
2 4 6 8 10 12 14Time (min)
i - P
enta
ne
n - P
enta
ne
i - B
utan
e
n - B
utan
e
Prop
ane
Etha
ne
C6+
Met
hane
Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas Compounds separated: C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: All components except C6+ - 0.005 to 100%, C6+ - 0.005 to 10% Application note reference number with technical details: D-6622, D-6623
All compounds measured by FID
19
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Simple, low-cost solution • Single channel/single thermal conductivity detector (TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis
Natural Gas Analyzer Model 2001
Published methods met: ASTM D1945, GPA 2261, ISO 6568, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10% Application note reference number with technical details: D-6622, D-6624
0 2 4 6 8 10 12 14Time (min)
i - P
enta
ne
n - P
enta
ne
i - B
utan
e
n - B
utan
e
Prop
ane
Etha
neC
O2
C6+
O2/N
2
Met
hane
H2S
20
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Baseline separation of O2, N2 composite and methane, argon measurement • Single channel/single thermal conductivity detector (TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2002
Published methods met: ASTM D1945, GPA 2261, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: Ar; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.01 to 4%, H2S - 0.1 to 5%, C6+ composite - 0.01 to 10%, all other components - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6625
10 20Time (min)
Prop
ane
C6+ i -
But
ane
n - B
utan
e
i - P
enta
ne
n - P
enta
ne
O2 /
N2
Met
hane
Argo
n
CO
2
Etha
ne
H2S
21
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Single channel/single thermal conductivity detector (TCD) • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2003
Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626
2 4 6 8 10 12 14Time (min)
C6+
H2S
Prop
ane
i-But
ane
n-Bu
tane
i-Pen
tane
n-Pe
ntan
e
CO
2Et
hane
Oxy
gen
Nitr
ogen
Met
hane
22
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: None Types of sample analyzed: Gas Compounds separated: O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10%, Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627
• Capillary channel added to Model 2001 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2006
0 2 4 6 8 10 12 14Time (min)
i - P
enta
ne
n - P
enta
ne
i - B
utan
e
n - B
utan
e
Prop
ane
Etha
neC
O2
C6+
O2/N
2
Met
hane
H2S
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel one - TCD Channel two - FID
23
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas Compounds separated: O2; N2; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 and C6+ composite - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C5 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6628
• Capillary channel added to Model 2003 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2008
2 4 6 8 10 12 14Time (min)
C6+
H2S
Prop
ane
i-But
ane
n-Bu
tane
i-Pen
tane
n-Pe
ntan
e
CO
2Et
hane
Oxy
gen
Nitr
ogen
Met
hane
Channel one - TCD
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel two - FID
24
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas Compounds separated: O2; N2; CO2; H2S; C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C4 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6629
• “Fast Model 2008” – C4 + compounds backflushed to vent on TCD channel • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Separation and measurement of O2 and N2 individually • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2009
Channel one - TCD
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel two - FID
25
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Model 2001 with C6+ backflush to FID channel (no water interference/better sensitivity) • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2010
Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas Compounds separated: O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25% Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630
i-But
ane
N-Bu
tane
Prop
ane
I-Pen
tane
Met
hane
n-Pe
ntan
e
Etha
ne
Air
Carb
on D
ioxi
de
H 2S
TCD channel – C6+ backflushed to FID
26
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/thermal conductivity detector, flame ionization detector (TCD/FID) • Hydrocarbons detected and measured, no interference from air or CO2 • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software included containing template for heating value calculation and other sample specifications, plus merge and custom report formatting • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2100
Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas Compounds separated: He; H2; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: He, H2 – 0.01 to 100%; all other components except C6+ composite - 0.005 to 100%; C6+ - 0.005 to 10% Application note reference number with technical details: D-6622, D-6623, D-6651
H2 measured by TCD and the remaining compounds measured by FID
27
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2101
Published methods met: ASTM D1945, GPA 2261, ISO 6568, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: He, H2, C1 through C5 – 0.01 to 100%; O2, N2 composite and CO2 – 0.01 to 20%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10% Application note reference number with technical details: D-6622, D-6624, D-6651
H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas.
28
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Baseline separation of O2, N2 composite and methane, argon measurement • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2102
Published methods met: ASTM D1945, GPA 2261, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He; H2; Ar; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.01 to 4%, H2S - 0.1 to 5%, C6+ composite - 0.01 to 10%, all other components - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6625, D-6651
H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas.
29
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2103
Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; He, H2, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626, D-6651
H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas.
30
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: None Types of sample analyzed: Gas Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25%; C6+ composite - 0.01 to 10%; Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627, D-6651
• Capillary channel added to Model 2101 • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel/ two thermal conductivity detector, flame ionization detector (TCD/TCD/FID) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2106
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel one and two – TCD/TCD Channel two - FID
31
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6974E, ISO 6974-3, ISO 6975 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): He, H2, O2 and C6+ composite - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; CO2 and C1 through C5 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6628, D-6651
• Capillary channel added to Model 2103 • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2108
Channel one and two - TCD
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel three - FID
32
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; He, H2, CO2 and C1 through C4 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6629, D-6651
• “Fast Model 2008” – C4 + compounds backflushed to vent on main TCD channel • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • Separation and measurement of O2 and N2 individually • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2109
Channel one and two – TCD/TCD
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel two - FID
33
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Model 2101 with C6+ backflush to FID channel (no water interference/better sensitivity) • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2110
Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25% Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630, D-6651
i-But
ane
N-Bu
tane
Prop
ane
I-Pen
tane
Met
hane
n-Pe
ntan
e
Etha
ne
Air
Carb
on D
ioxi
de
H 2S
He, H2 measured by TCD using Nitrogen carrier gas. C6+ backflushed to FID, all other compounds measured using TCD with Helium carrier gas.
34
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Natural Gas Analyzer Model 2200
2 4 6 8 10 12 14Time (min)
i - P
enta
ne
n - P
enta
ne
i - B
utan
e
n - B
utan
e
Prop
ane
Etha
ne
C6+
Met
hane
Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: All components except C6+ - 0.005 to 100%, C6+ - 0.005 to 10% Application note reference number with technical details: D-6622, D-6623, D-6652
• Added liquid-sampling capability to Model 2000 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Only hydrocarbons detected and measured, no interference from air or CO2 • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
All compounds measured by FID
35
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Published methods met: ASTM D1945, GPA 2177, GPA 2261, ISO 6568, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10% Application note reference number with technical details: D-6622, D-6624, D-6652
• Added liquid-sampling capability to Model 2001 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Single channel/single TCD • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2201
0 2 4 6 8 10 12 14Time (min)
i - P
enta
ne
n - P
enta
ne
i - B
utan
e
n - B
utan
e
Prop
ane
Etha
neC
O2
C6+
O2/N
2
Met
hane
H2S
36
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Baseline separation of O2, N2 composite and methane, argon measurement • Added liquid-sampling capability to Model 2002 • Single channel/single thermal conductivity detector (TCD) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2202
Published methods met: ASTM D1945, GPA 2261, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: Ar; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.01 to 4%, H2S - 0.1 to 5%, C6+ composite - 0.01 to 10%, all other components - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6625, D-6652
10 20Time (min)
Prop
ane
C6+ i -
But
ane
n - B
utan
e
i - P
enta
ne
n - P
enta
ne
O2 /
N2
Met
hane
Argo
n
CO
2
Etha
ne
H2S
37
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Single channel/single thermal conductivity detector (TCD) • Separation and measurement of O2 and N2 individually • Added liquid-sampling capability to Model 2003 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2203
Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626, D-6652
2 4 6 8 10 12 14Time (min)
C6+
H2S
Prop
ane
i-But
ane
n-Bu
tane
i-Pen
tane
n-Pe
ntan
e
CO
2Et
hane
Oxy
gen
Nitr
ogen
Met
hane
38
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: None Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10%, Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627, D-6652
• Capillary channel added to Model 2001 • Added liquid sampling capability to Model 2006 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Channel two - FID
Natural Gas Analyzer Model 2206
0 2 4 6 8 10 12 14Time (min)
i - P
enta
ne
n - P
enta
ne
i - B
utan
e
n - B
utan
e
Prop
ane
Etha
neC
O2
C6+
O2/N
2
Met
hane
H2S
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel one - TCD
39
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: ASTM D1946, GPA 2165, GPA 2186, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2; N2; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 and C6+ composite - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C5 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6628, D-6652
• Capillary channel added to Model 2003 • Added liquid-sampling capability to Model 2008 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2208
2 4 6 8 10 12 14Time (min)
C6+
H2S
Prop
ane
i-But
ane
n-Bu
tane
i-Pen
tane
n-Pe
ntan
e
CO
2Et
hane
Oxy
gen
Nitr
ogen
Met
hane
Channel one - TCD
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel two - FID
40
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2; N2; CO2; H2S; C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; CO2 and C1 through C4 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6629, D-6652
• “Fast Model 2008” – C4 + compounds backflushed to vent on TCD channel • Added liquid-sampling capability to Model 2009 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Separation and measurement of O2 and N2 individually • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2209
Channel one – TCD
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel two - FID
41
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Model 2201 with C6+ backflush to FID channel (no water interference, better sensitivity) • Added liquid-sampling capability to Model 2010 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2210
Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630, D-6652
TCD channel – C6+ backflushed to FID
42
Analyzer Description
Major Features and Benefits
Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: He, H2 – 0.01 to 100%; all other components except C6+ - 0.005 to 100%; C6+ - 0.005 to 10% Application note reference number with technical details: D-6622, D-6623, D-6651, D-6652
• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Added liquid-sampling capability on FID channel of Model 2100 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/thermal conductivity detector, flame ionization detector (TCD/FID) • Hydrocarbons detected and measured, no interference from air or CO2 • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software included containing template for heating value calculation and other sample specifications, plus merge and custom report formatting • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Typical Chromatogram
Natural Gas Analyzer Model 2300
H2 measured by TCD and the remaining compounds measured by FID
43
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Published methods met: ASTM D1945, GPA 2177, GPA 2261, ISO 6568, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: He, H2, C1 through C5 - 0.01 to 100%, O2, N2 composite and CO2 – 0.01 to 20%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10% Application note reference number with technical details: D-6622, D-6624, D-6651, D-6652
• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Added liquid-sampling capability to Model 2101 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/dual thermal conductivity detector (TCD/TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2301
H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas.
44
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Baseline separation of O2, N2 composite and methane, argon measurement • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Added liquid-sampling capability to Model 2102 • Dual channel/dual thermal conductivity detector (TCD/TCD) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2302
Published methods met: ASTM D1945, GPA 2261, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; Ar; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.01 to 4%, H2S - 0.1 to 5%, C6+ composite - 0.01 to 10%, all other components - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6625, D-6651, D-6652
H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas.
45
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • Added liquid-sampling capability to Model 2103 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2303
Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; He, H2, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626, D-6651, D-6652
H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas.
46
Analyzer Description
Typical Chromatograms
Major Features and Benefits
Published methods met: None Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25%; C6+ composite - 0.01 to 10%; Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627, D-6651, D-6652
• Capillary channel added to Model 2301 • Added liquid-sampling capability to Model 2106 • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2306
Buta
nes
Pent
anes
Hex
ane
Hep
tane
Oct
ane
p-Xy
lene
n-Pr
opyl
benz
ene
Dec
ane
n-Bu
tylb
enze
ne
Time (min)2010
Channel one and two – TCD/TCD Channel three - FID
47
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25% Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630, D-6651, D-6652
• Model 2301 with C6+ backflush to FID channel (no water interference, better sensitivity) • Added liquid-sampling capability to Model 2110 • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid
sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon
unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.
Natural Gas Analyzer Model 2310
He, H2 measured by TCD using Nitrogen carrier gas. C6+ backflushed to FID, all other compounds measured using TCD using Helium carrier gas.
Simulat Model 3012
Model 3013
Model 3062
Sim
ula
ted
Dis
tilla
tio
n S
oft
wa
re
Simulated Distillation Softwareand Software Enhancements
49
Software Description
Typical Chromatogram and Report
Major Features and Benefits
Chromatogram of Reference Gas Oil (RGO) standard for ASTM D2887
Simulated Distillation Software Model 3012
Published methods met: ASTM D2887, ASTM D3710, ASTM D5307 Types of sample analyzed: Liquid Compounds analyzed: C4 through C110, depending upon method Application note reference number with technical details: D-6631
• Runs with PerkinElmer TotalChrom and Turbochrom Workstation or Client Server software
• Up to eight Sim Dis analyzers per each software license
• Step-by-step instruction manual
• Long and short reporting formats
• Cut point reports
• Setup templates for each Sim Dis Method
• Auto sequence multiple methods
• Batch reprocessing
• Reports to printer, disk or screen
10 20 30 40 50 60 70 80 90
100 110 120 130
ASTM D2887 report for the RGO sample
50
Analyzer Description
Typical Chromatogram and Report
Major Features and Benefits
Chromatogram of Reference Gas Oil (RGO) standard for ASTM D2887
Simulated Distillation Software Model 3013
Published methods met: ASTM D2887, ASTM D3710, ASTM D5307 Types of sample analyzed: Liquid Compounds analyzed: C4 through C110, depending upon method Application note reference number with technical details: D-6631
• Model 3013 includes method development, using Model 3012 Software
• Customer purchases total system specified for their desired methodology
• Sampling procedure and report format developed
• Chromatographic parameters established for the method
• Column identified
• Operating conditions identified
• Calibration material chosen
• Calibration and actual customer sample run, if supplied
• Sample interpreted
• Sample run at on-site installation by PerkinElmer
10 20 30 40 50 60 70 80 90
100 110 120 130
ASTM D2887 report for the RGO sample
51
Software Description
Typical Heating Calculation Report
Major Features and Benefits
Software Enhancements Model 3062
Published methods met: ASTM D3588 Types of sample analyzed: All Application note reference number with technical details: D-6632
• Combine two Turbochrom or TotalChrom reports into a single report
• Full computational power of Excel™
• Full reporting power of Excel
• Translation of report into local language
• Automatic output to paper and/or computer file path
• Typical uses include Natural gas computations using the supplied template and multiple detector analyzers report merge
• Changing the Turbochrom or TotalChrom report to match a company format
• Special calculations based upon measured concentrations
• Examples supplied include two detector-bridged Natural Gas Analyzer heat calculation and Refinery Gas Analyzer two-integrator channel merge
Sample Name: 3062 Demo Time: 08/07/98 12:05:42 PMOperator: M. Taylor Study: Default SequenceInstrument: TABLE_2_________(2B) Data Acquisition Time: 06/06/97 01:50:24 PM
Compressibility: 0.9977Heat (Saturated): 1045.63Heat (Dry): 1064.15 Specific Gravity (R 0.6484
Sequence File: C:\Userprog\Tc6demo\Nga\Nga32.seqInst Method: C:\TC4\1METHOD\2306F from c:\userprog\tc6demo\nga\pack.rst
Channel:BRaw Data File: c:\userprog\tc6demo\nga\pack.rawResult File: c:\userprog\tc6demo\nga\pack.rstProc Method: C:\USERPROG\tc6DEMO\NGA\PACKED.mthCalib Method: C:\USERPROG\tc6DEMO\NGA\PACKED.mth
Channel:ARaw Data File: c:\userprog\tc6demo\nga\cap.rawResult File: c:\userprog\tc6demo\nga\cap.rstProc Method: C:\USERPROG\tc6DEMO\NGA\CAP.mthCalib Method: C:\USERPROG\tc6DEMO\NGA\CAP.mth
A/B Component Mol % Mol Fraction Mol FractioSpecific GrCalorific Compressibilty Rleative Density Calorific Value CompressibilityName Bridged Normalizedfraction Fraction Fraction Btu/ft3 sqr rt (b)
B Hydrogen 5 0.05001 0.05 0.00348 16.25 0.0696 324.9B Air 3.85 0.03849 0.03848 0.03848 0 0.00078 1 0.0202B Argon 0.99 0.00995 0.00994 0.01372 0 0.00027 1.3792 0.0276B Methane 81.52 0.81524 0.81502 0.45144 824.8 0.03553 0.5539 1012 0.0436B CO2 0.41 0.00408 0.00407 0.00619 0 0.00026 1.5194 0.064B Ethane 3 0.03002 0.03001 0.03116 53.21 0.00275 1.0382 1772.9 0.0917B Propane 2.02 0.02021 0.0202 0.03075 50.96 0.00271 1.5224 2523 0.1342B i-Butane 1.01 0.01011 0.01011 0.02029 32.96 0.00185 2.0067 3260.1 0.1825B n-Butane 0.99 0.00989 0.00989 0.01984 32.32 0.00176 2.0067 3269.6 0.178B i-Pentane 0.49 0.00493 0.00493 0.01228 19.76 0.00117 2.491 4009.4 0.2376B n-Pentane 0.48 0.00479 0.00478 0.01192 19.22 0.00114 2.491 4018.5 0.2377A i-Pentane 0.49A n-Pentane 0.48A 2,2-dimethylButane 0.26 0.00256 0.00256 0.00761 12.16 0.00072 2.9753 4758 0.283
1.00028 1 0.64715 1061.65 0.04895
Trace S Model 4025
Model 4026
Model 4027
Model 4028
Model 4029
Model 4227
Model 4229
Model 4425
Model 4428
Model 4429
Model 4629
Tra
ce
Su
lfu
r A
na
lyze
rs
Trace Sulfur Analyzers
53
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Trace Sulfur Components Analyzer Model 4025
H2S
CO
SSO
2
Met
hylm
erca
ptan
Ethy
lmer
capt
an
Dim
ethy
lsul
fide
t-But
ylm
erca
ptan
Prop
ylm
erca
ptan
Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643
• Analyzes samples such as refinery gas, natural gas, process gas, and Kraft gas • Uses a Sievers Sulfur Chemiluminescence Detector (SCD)
• The SCD has an equimolar response to sulfur compounds, lack of carbon
interference and requires simple calibration
• Capillary column solution
• Can be modified with a second or third channel to perform additional analyses
• Can be modified to analyze liquid and pressurized liquid samples (Model 4028)
• Can be designed to be on-line and/or a multistream system
54
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Trace Sulfur Components Analyzer Model 4026
H2S
CO
SSO
2
Met
hylm
erca
ptan
Ethy
lmer
capt
an
Dim
ethy
lsul
fide
t-But
ylm
erca
ptan
Prop
ylm
erca
ptan
Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Liquid, pressurized liquid (valve injection) Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643
• Analyzes samples such as LPG, naphtha, gasoline and other liquid petroleum products • Uses a Sievers Sulfur Chemiluminescence Detector (SCD)
• The SCD has an equimolar response to sulfur compounds, lack of carbon interference
and requires simple calibration
• Capillary column solution
• Can be modified with a second or third channel to perform additional analyzes
• Can be modified to analyze gas samples (Model 4028)
• Can be designed to be on-line and/or a multistream system
55
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Analyzes samples such as naphtha, gasoline and other liquid petroleum products that can be syringe injected
• Uses a Sievers Sulfur Chemiluminescence Detector (SCD)
• The SCD has an equimolar response to sulfur compounds, lack of carbon
interference and requires simple calibration
• Capillary column solution
• Can be modified with a second or third channel to perform additional analyses
• Can be modified to analyze gas samples (Model 4029)
• Can be designed to be on-line and/or a multistream system
Trace Sulfur Components Analyzer Model 4027
H2S
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Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Liquid (syringe injection) Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643
56
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Trace Sulfur Components Analyzer Model 4028
H2S
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Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643
• Analyzes samples such as refinery gas, natural gas, process gas, Kraft gas, LPG, naphtha, gasoline and other gaseous and liquid petroleum products
• Uses a Sievers Sulfur Chemiluminescence Detector (SCD)
• The SCD has an equimolar response to sulfur compounds, lack of carbon
interference and requires simple calibration
• Dual-capillary column solution
• Can be modified with a second or third channel to perform additional analyzes
• Can be designed to be on-line and/or a multistream system
57
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Analyzes samples such as refinery gas, natural gas, process gas, Kraft gas, naphtha, gasoline and other liquid petroleum products that can be syringe injected
• Uses a Sievers Sulfur Chemiluminescence Detector (SCD)
• The SCD has an equimolar response to sulfur compounds, lack of carbon
interference and requires simple calibration
• Dual-capillary column solution
• Can be modified with a second or third channel to perform additional analyses
• Can be modified to analyze pressurized liquid samples by adding a liquid sampling valve (Model 4229)
• Can be designed to be on-line and/or a multistream system
Trace Sulfur Components Analyzer Model 4029
H2S
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Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas, liquid Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643
58
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Analyzes samples like naphtha, gasoline and other liquid petroleum products that can be syringe injected
• Uses a Sievers Sulfur Chemiluminescence Detector (SCD)
• The SCD has an equimolar response to sulfur compounds, lack of carbon
interference and requires simple calibration
• Includes a secondary filter and back-pressure regulation for proper liquid sample introduction
• Capillary column solution
• Can be modified to analyze gas samples (Model 4229)
• Can be designed to be on-line and/or a multistream system
Trace Sulfur Components Analyzer Model 4227
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Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Liquid (syringe injection), liquid and pressurized liquid (valve injection Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643
59
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Analyzes samples like refinery gas, natural gas, process gas, Kraft gas, LPG, naphtha, gasoline and other liquid petroleum products
• Uses a Sievers Sulfur Chemiluminescence Detector (SCD). The SCD has an
equimolar response to sulfur compounds, lack of carbon interference and requires simple calibration
• Includes a secondary filter and back-pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection
• Dual-capillary column solution
• Can be modified with a second or third channel to perform additional analyses
• Can be designed to be on-line and/or a multistream system
Trace Sulfur Components Analyzer Model 4229
H2S
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Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643, D-6652
60
Analyzer Description
Chamber Schematic
Major Features and Benefits
Trace Sulfur Components Analyzer Models 4425, 4428, 4429 and 4629
Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643
• Adds an integrated permeation tube chamber for calibration option to Trace Sulfur Components Analyzer Models 4025, 4028, 4029 and 4229
• Saves both space and cost
• Mounts on top of the analyzer for easy access
• Manual valve is used to select the calibration chamber or the sample input • Permeation tube chamber can accommodate up to four permeation tubes or wafers
for calibration of other non sulfur compounds
• Includes certified dimethyl-sulfide permeation tube
• Permeation tube shipped with the product is tested with the analyzer, against an NBS traceable calibrator for accuracy
Model 4001 Model 4002 Model 4003 Model 4081 Model 4004 Model 4005 Model 4006 Model 4007 Model 4008 Model 4009 Model 4010 Model 4011 Model 4012 Model 4013 Model 4014 Model 4015 Model 4016 Model 4017
Model 4018 Model 4019 Model 4020 Model 4021 Model 4022 Model 4023 Model 4024 Model 4032 Model 4033 Model 4034 Model 4035 Model 4036 Model 4037 Model 4080 Model 4082 Model 4083 Model 4086
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Other Analyzers
Analyzers for Light Gas, Chlorine, Transformer Oil Gas,LPG and Simulated Distillation through DetailedHydrocarbon Analyses
62
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Published methods met: ASTM D4815-99 Types of sample analyzed: liquid Compounds separated: Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons Guaranteed detection ranges/concentration levels: MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12% Application note reference number with technical details: D-6633
Standard Method (ASTM D4815) Analyzers Model 4001/4002
• Guaranteed to meet the scope of ASTM D4815-99 methodology
• Fully automated
• Low cost of operation
• Available with thermal conductivity detector (Model 4001) or flame ionization detector (Model 4002)
• The determination of benzene, separated by this valve/column system, is not
qualified by this method. To analyze benzene, refer to Model 4013 (ASTM D3606) or Model 4006 (ASTM D4420). Model 4013 or Model 4006 can be incorporated as a second channel in the Model 4001/4002 (see Models 4009, 4010 or 4007, 4008).
63
Analyzer Description
Typical Chromatogram
Major Features and Benefits • Model 4081 Transformer Oil Gas Extraction Apparatus and Model 4003 Analyzer meets
the scope of ASTM D3612-01, Method A • Dual detector (TCD/FID) • Model 4003 can be connected to a Headspace Sampler to meet ASTM D3612-01,
Method C • Purged sampling valve housing on Model 4003 Analyzer • Passivated tubing for optimum CO response
• Injection port and gas sampling valve for various sample introductions
• High capacity methanizer
Transformer Oil Gas Analyzer Model 4003/4081
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Published methods met: ASTM D3612-01 Types of sample analyzed: Gas Compounds separated: H2, O2, N2, CO2, CO, CH4, C2H6, C2H4, C2H2, C3 and C4 hydrocarbons Guaranteed detection ranges/concentration levels: CO2, CO, CH4, C2H6, C2H4 – 1.0 ppm; C2H2 - 2.0 ppm; C3s, C4s – 3.0 ppm; H2 – 50 ppm; O2, N2 – 500 ppm Application note reference number with technical details: D-6634
64
Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002), as well as the benzene, toluene, ethylbenzene and other aromatics, as required, (see Model 4005) in gasoline
• The same column system is utilized for both methods
• ASTM D5580 requires a flame ionization detector (FID). For this reason and since the
same column system is utilized for both methods, only the FID performing ASTM D4815 is appropriate for this analyzer
• See Models 4002 and 4005 for more details
Standard Method (ASTM D4815/D5580) Analyzer Model 4004
Published methods met: ASTM D4815, ASTM D5580 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons; (ASTM D5580): Benzene, toluene, ethylbenzene, p/m-xylene, o-xylene, C9 and heavier aromatics, total aromatics Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12%; (ASTM D5580): (all v%) Benzene – 0.1 to 5%, toluene – 1 to 15%, individual C8 aromatics – 0.5 to 10%, total C9 and heavier aromatics – 5 to 30%, total aromatics – 10 to 80% Application note reference number with technical details: D-6633, D-6635
ASTM D4815 analysis ASTM D5580 analysis 1 ASTM D5580 analysis 2
65
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Aromatic hydrocarbons are separated without interferences from other hydrocarbons in the sample
• Nonaromatic hydrocarbons having a boiling point greater than n-dodecane may cause interferences with the C9 and heavier aromatics
• For the C8 aromatics, p-xylene and m-xylene coelute, ethylbenzene and o-xylene separate
• The C9 and heavier aromatics are measured as a single group • Two separate analyses are performed. The first, the quantitation of benzene and
toluene. The second, the quantitation of ethylbenzene, p/m-xylene, o-xylene, and the C9 and heavier aromatics. The results are summed to determine total aromatic content.
• Alcohols and ethers added to gasoline do not interfere with the analysis
Standard Method (ASTM D5580) Analyzer Model 4005
Published methods met: ASTM D5580 Types of sample analyzed: Finished Gasoline Compounds separated: Benzene, toluene, ethylbenzene, p/m-xylene, o-xylene, C9 and heavier aromatics, total aromatics Guaranteed detection ranges/concentration levels: (all v%) Benzene – 0.1 to 5%, toluene – 1 to 15%, individual C8 aromatics – 0.5 to 10%, total C9 and heavier aromatics – 5 to 30%, total aromatics – 10 to 80% Application note reference number with technical details: D-6635
Analysis 1 Analysis 2
66
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Published methods met: ASTM D4420 Types of sample analyzed: Finished Gasoline Compounds separated: Benzene; toluene; C8, C9 and heavier aromatics, total aromatics Guaranteed detection ranges/concentration levels: Benzene - 0.1 to 5V%, toluene – 1 to 20V%, C8 aromatics – 3 to 25V%, C9 and heavier aromatics – 5 to 30V%, total aromatics – 10 to 80V% Application note reference number with technical details: D-6636
Standard Method (ASTM D4420) Analyzer Model 4006
• A sample is injected by syringe into a two column/valve system. Nonaromatics are vented as they elute column one. Before benzene elutes, the aromatics are backflushed from column one to column two. Aromatics elute from column two to the thermal conductivity detector (TCD) in boiling point order. After C8 aromatics have eluted, column two is backflushed to the TCD to obtain the C9 and heavier aromatics. Sample results are compared to the analysis of a blend of known aromatic content.
• A knowledge of aromatics in gasolines is needed to access sample results
• This single channel analyzer can have a second channel added, performing another
method or application. The column oven temperature requirement of the second channel cannot operate above the maximum temperature allowed by Model 4006 (200 oC).
67
Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002), as well as the benzene, toluene, ethylbenzene, C8 and other heavier aromatics, as required, (see Model 4006) in gasoline
• Two separate column systems are utilized for these methods
• See Models 4001/4002 and 4006 for more details
Standard Method (ASTM D4815/D4420) Analyzer Model 4007/4008
Published methods met: ASTM D4815, ASTM D4420 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons; (ASTM D4420): Benzene; toluene; C8, C9 and heavier aromatics, total aromatics Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12%; (ASTM D4420): Benzene - 0.1 to 5V%, toluene – 1 to 20V%, C8 aromatics – 3 to 25V%, C9 and heavier aromatics – 5 to 30V%, total aromatics – 10 to 80V% Application note reference number with technical details: D-6633, D-6636
ASTM D4815 analysis ASTM D4420 analysis
68
Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002), as well as the benzene and toluene, as required, (see Model 4013) in gasoline
• Two separate column systems are utilized for these methods
• See Models 4001/4002 and 4013 for more details
Standard Method (ASTM D4815/D3606) Analyzer Model 4009/4010
Published methods met: ASTM D4815, ASTM D3606 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons; (ASTM D3606): Benzene, toluene Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12%; (ASTM D3606): Benzene - 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6633, D-6637
ASTM D4815 analysis ASTM D3606 analysis
69
Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002), as well as the benzene and toluene, as required, (see Model 4014) in gasoline
• EPA modification of ASTM D3606 adds additional column for enhanced benzene –
ethanol (if present) separation. All other specifications and method intent remain unchanged.
• Two separate column systems are utilized for these methods
• See Models 4001/4002 and 4014 for more details
Standard Method (ASTM D4815/D3606- EPA modified) Analyzer Model 4011/4012
Published methods met: ASTM D4815, ASTM D3606 (EPA modification) Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons; (ASTM D3606-EPA modified): Benzene, toluene Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12%; (ASTM D3606-EPA modified): Benzene - 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6633, D-6637
ASTM D4815 analysis ASTM D3606 (EPA modified) analysis
70
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Standard Method (ASTM D3606) Analyzer Model 4013
Published methods met: ASTM D3606 Types of sample analyzed: Finished Motor and Aviation Gasoline Compounds separated: Benzene, toluene Guaranteed detection ranges/concentration levels: Benzene – 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6637
• A sample, containing methyl ethyl ketone (MEK) as an internal standard, is injected by syringe into two columns in series. The first column separates components by boiling point. After octane elutes from column one into column two, carrier flow is reversed in column one. Hydrocarbons heavier than octane are vented. Column two then separates the octane and lighter components. Aromatic and nonaromatic compounds are measured with reference to the MEK by thermal conductivity detector (TCD).
• Knowledge of benzene concentration may be an aid in evaluating the toxicity of the
gasoline being analyzed. This method is not intended to evaluate that toxicity, however.
• This single-channel analyzer can have a second channel added, performing another
method or application. The column oven temperature requirement of the second channel cannot operate above the maximum temperature allowed by Model 4013 (120 oC).
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Analyzer Description
Typical Chromatogram
Major Features and Benefits
Standard Method (ASTM D3606-EPA modified) Analyzer Model 4014
Published methods met: ASTM D3606 (EPA modification) Types of sample analyzed: Finished Motor and Aviation Gasoline Compounds separated: Benzene, toluene Guaranteed detection ranges/concentration levels: Benzene – 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6637
• EPA modification of ASTM D3606 adds additional column for enhanced benzene – ethanol (if present) separation
• All other specifications and method intent remain unchanged. See Model 4013 for
details • This single channel analyzer can have a second channel added, performing another
method or application. The column oven temperature requirement of the second channel cannot operate above the maximum temperature allowed by Model 4014 (120 oC).
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Analyzer Description
Page One of Typical Report
Major Features and Benefits
• Detailed analysis of gasolines, naphthas and similar samples that boil below 250 oC • Software is mated to capillary-column output to obtain detailed hydrocarbon
characteristics • Reports include individual components, key boiling point data, oxygenates and oxygen
content and multisubstituted aromatics • Calculated values include percent carbon and hydrogen, vapor pressure, average
molecular weight and density by carbon number, octane rating and bromine number • Key separated compounds include methylcyclopentene-1/benzene; 2,3,3-
trimethylpentane/toluene and 1,4-dimethylbenzene (p-xylene)/2,3-dimethylheptane
Detailed Hydrocarbon Analyzer Model 4015
Published methods met: ASTM D5443, ASTM D6623, ASTM D6730, ASTM D6733 Types of sample analyzed: liquid Compounds separated: Paraffins, Isoparaffins, Naphthenes, Olefins, Aromatics and Oxygenates (reported by carbon number) through C13 Guaranteed detection ranges/concentration levels: All components – 10 ppm Application note reference number with technical details: D-6638
Detailed Hydrocarbon Analysis (DHAX)Neil G. Johansen, Inc.
Raw File: 0928001002.raw Analyzed: 28 Sep 1999 01:33PMSample: Reported: 01 Oct 1999 02:32PM Method: DHA Initial Gasoline.mth DHA DBase File: 5987A.csv Processed 445 peaks Normalized to 100.00%
Summary Report
Group Type: Total (mass%) Total (vol%) Paraffins: 9.471 10.564 I-paraffins: 30.320 33.370 Olefins: 8.131 8.733 Naphthenes: 9.807 9.439 Aromatics: 24.981 20.917 Total C14+: 0.436 0.421 Total Unknowns: 1.384 1.171 Grand Total 100.000 100.000
Oxygenates: Total: 15.471 (mass%) 15.385 (vol%) Total Oxygen Content: 2.808 (mass%)
Multisubstituted Aromatics: 18.161 (mass%) 15.313 (vol%)
Average Molecular Weight: 80.291
Relative Density: 0.609
Vapor Pressure calc RVP (EPA method): 3.42 (psi @ 100°F)
Calculated Octane Number: 87.08
73
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Light Gas Analyzer Model 4016
Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: Ar - O2 composite; N2; CH4; CO; CO2; Ethylene; Ethane; Acetylene; H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%, all other components – 0.01 to 100%
• Typical analyses are light gases, furnace gases, stack gases, combustion gases, decoking gases, mine gases
• Packed columns/single thermal conductivity detector (TCD)
• Often used as one channel of an analyzer – very versatile
• Some common added channels are:
- Flame ionization detector (FID) for better hydrocarbon detection - Methanizer/FID and purged-valve housings for trace CO and CO2 analysis - Flame photometric detector (FPD) or a Sievers Sulfur Chemiluminescence
Detector (SCD) for trace levels of the light sulfur gases
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Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Typical analyses are light gases, furnace gases, stack gases, combustion gases, decoking gases, mine gases
• Full-range hydrogen detection using separate channel with nitrogen carrier gas added to Model 4016
• Packed columns/dual Arnel thermal conductivity detector (TCD/TCD)
• Arnel dual TCD allows analyzer to have an added third channel
• Some common added channels are:
- Flame ionization detector (FID) for better hydrocarbon detection - Methanizer/FID and purged valve housings for trace CO and CO2 analysis - Flame photometric detector (FPD) or a Sievers Sulfur Chemiluminescence
Detector (SCD) for trace levels of the light sulfur gases
Light Gas Analyzer Model 4017
Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: He; H2; Ar - O2 composite; N2; CH4; CO; CO2; Ethylene; Ethane; Acetylene; H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%, all other components – 0.01 to 100%
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Analyzer Description
Typical Chromatograms
Major Features and Benefits
• Typical analyses are light gases, furnace gases, stack gases, combustion gases, decoking gases, mine gases
• Packed columns/dual thermal conductivity detector (TCD/TCD)
• Third channel added to Model 4016 for Ar – O2 separation and measurement
Channel one – TCD Channel two - TCD
Light Gas Analyzer Model 4018
Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: Ar; O2; N2; CH4; CO; CO2; Ethylene; Ethane; Acetylene; H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%, all other components – 0.01 to 100% Application note reference number with technical details: D-6639
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Analyzer Description
Typical Chromatograms
Major Features and Benefits
Light Gas Analyzer Model 4019
Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: He; H2; Ar; O2; N2; CH4; CO; CO2; Ethylene; Ethane; Acetylene; H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%, all other components – 0.01 to 100% Application note reference number with technical details: D-6639
• Typical analyses are light gases, furnace gases, stack gases, combustion gases, decoking gases, mine gases
• Packed columns/dual Arnel thermal conductivity detector and PerkinElmer thermal
conductivity detector (TCD/TCD/TCD) • Third channel added to Model 4017 for Ar – O2 separation and measurement
• Arnel dual TCD allows analyzer to have added third channel
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Channel one and two – TCD/TCD
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Channel three - TCD
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Analyzer Description
Typical Chromatogram
Major Features and Benefits
Light Gases in Chlorine Model 4020
Published methods met: ASTM E1746 Types of sample analyzed: Gas Compounds separated: He, H2, O2, N2, CH4, CO2, CO Guaranteed detection ranges/concentration levels: He, H2 - 0.001 to 100%; all other components - .01 to 100% Application note reference number with technical details: D-6640
• All tubing and valves in contact with the samples are constructed of chlorine-resistant material
• Dual packed column channels/dual thermal conductivity detector (TCD/TCD)
• An important feature is the use of proprietary packing materials as the first column in
both channels • Samples containing water do not interfere with the analysis or create hardware
problems • Chlorine is backflushed to vent and does not enter the detector
78
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Trace CO, CH4 and CO2 Analyzer Model 4021
Published methods met: ASTM D3416, ISO 6381 Types of sample analyzed: Gas Compounds separated: CO, CO2, CH4, ethylene – ethane composite, acetylene Guaranteed detection ranges/concentration levels: All components – 0.1 ppm Application note reference number with technical details: D-6641
• Single channel/methanizer/flame ionization detector (FID) • One valve and one column
• Can handle large methane concentrations
• Acetylene elutes after ethylene – trace acetylene can not be analyzed in large
quantities of ethylene • Purged valve housings and passivated tubing are used to enhance sensitivity
• In practical use, the sample must be free of oxygen
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Analyzer Description
Typical Chromatogram
Major Features and Benefits
Trace CO, CH4 and CO2 Analyzer Model 4022
Published methods met: ASTM D3416, ISO 6381 Types of sample analyzed: Gas Compounds separated: CO, CO2, CH4, ethylene, ethane, acetylene Guaranteed detection ranges/concentration levels: All components – 0.1 ppm Application note reference number with technical details: D-6641
• Single channel/methanizer/flame ionization detector (FID) • One valve and one column
• Can not handle large methane concentrations
• Acetylene elutes before ethylene – trace acetylene, CO, CO2, CH4 can be analyzed in
large quantities of ethylene • Purged valve housings and passivated tubing are used to enhance sensitivity
• In practical use, the sample must be free of oxygen
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Analyzer Description
Product Schematic
Major Features and Benefits
• Compliments analyzers for a fully tested complete system or sold as a stand-alone product
• If purchased with an analyzer, it will be additionally tested using an actual sample supplied by the customer or supplied by Arnel
• Designed to vaporize liquefied light hydrocarbons such as propylene • Incorporates design improvements to meet the requirements for trace hydrocarbons,
as well as trace CO and CO2 analysis in liquefied light hydrocarbon gases • The output of the Apparatus is connected directly to the analyzer to insure no air will
be added to the expanded sample • The Apparatus includes a metering valve for the sample flow, a metering valve for
calibration gases, a clear plastic graduated cylinder for use as a manometer and a burst disk located in the “liquid sample in” system, which relieves a high-pressure (above 500 psi) sample to vent, if introduced into the product
Liquid Sample Expansion Apparatus Model 4023
Published methods met: ASTM D2712 Types of sample analyzed: Pressurized liquid Compounds separated: N/A Guaranteed detection ranges/concentration levels: N/A Application note reference number with technical details: D-6642
81
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Trace CO, CH4 and CO2 Analyzer Model 4024
Car
bon
Mon
oxid
e
Met
hane Car
bon
Din
oxid
e
Published methods met: UOP 603 Types of sample analyzed: Gas Compounds separated: CO, CO2, CH4 Guaranteed detection ranges/concentration levels: All components – 0.5 ppm Application note reference number with technical details: D-6641
• Single channel/methanizer/flame ionization detector (FID) • Valving and columns meet UOP 603 methodology
• Can handle large methane concentrations
• Does not include any C2 analysis (Acetylene and ethylene coelute off of the primary
column) • Purged valve housings and passivated tubing are used to enhance sensitivity
• In practical use, the sample must be free of oxygen
82
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Full Range H2, He, O2 and N2 Analysis Model 4032/4033/4034
Published methods met: ASTM D1945, ASTM D1946 Types of sample analyzed: Gas Compounds separated: Model 4032- He, H2; Model 4033- O2, N2; Model 4034- He, H2, O2, N2 Guaranteed detection ranges/concentration levels: All components – 10 ppm to 100% Application note reference number with technical details: D-6645
• Rugged and simple packed-column technology • Models 4032 and 4033 are single channel, thermal conductivity detector analyzers.
Model 4034 is a dual-channel, dual-thermal conductivity detector analyzer. • Better detection and measurement than 10 ppm can be achieved, with modification, in
some cases. Some limitations are present, however, with certain combinations of compound levels present. Information on the complete sample matrix is required to determine true detection and measurement ranges.
• Model 4032 and 4033 have the ability to be combined with other application channels
for cost savings
Model 4032 and Model 4034 analysis one Model 4033 and Model 4034 analysis two
83
Analyzer Description
Major Features and Benefits
Light Hydrocarbon Analyzer Model 4035
Typical Chromatogram
Published methods met: ASTM D2163, ASTM D2593, ASTM D2712, ASTM D2820, ASTM D4424, ISO 7941 Types of sample analyzed: Gas Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components - 0.1 ppm Application note reference number with technical details: D-6663
• Used to analyze a wide range of gaseous light hydrocarbon samples such as LPG • Fully automatic operation • All hydrocarbons from methane to hexane are analyzed. Complete separations of all
possible compounds are obtained in approximately 20 minutes. The analysis usually includes a column temperature program.
• This analyzer cannot be used for all samples. Two very good applications are for propylene/butylenes manufacturing and analysis of butane streams, which are free of compounds that irreversibly poison the Alumina PLOT column (NH3, H2S).
• External valve oven design allows for full range temperature programming for column reconditioning (removing CO2 and H2O)
• The valve oven assures that no sample condensation occurs in the sample loop • Possible to add second channel for another application
84
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Used to analyze a wide range of liquid light hydrocarbon samples such as LPG • Fully automatic operation • All hydrocarbons from methane to hexane are analyzed. Complete separations of all
possible compounds are obtained in approximately 20 minutes. The analysis usually includes a column temperature program.
• This analyzer cannot be used for all samples. Two very good applications are for propylene/butylenes manufacturing and analysis of butane streams, which are free of compounds that irreversibly poison the Alumina PLOT column (NH3, H2S).
• Liquid sampling valve mounted at ambient temperature allows for full range temperature programming for column reconditioning (removing CO2 and H2O)
• Includes a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection • Possible to add second channel for another application
Light Hydrocarbon Analyzer Model 4036
Published methods met: ASTM D2163, ASTM D2593, ASTM D2712, ASTM D2820, ASTM D4424, ISO 7941 Types of sample analyzed: Liquid, pressurized liquid Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components - 0.1 ppm Application note reference number with technical details: D-6663
85
Analyzer Description
Typical Chromatogram
Major Features and Benefits
• Analyzes a wide range of gaseous and liquid light hydrocarbon samples such as LPG • Fully automatic operation • All hydrocarbons from methane to hexane are analyzed. Complete separations of all
possible compounds are obtained in approximately 20 minutes. The analysis usually includes a column temperature program.
• This analyzer cannot be used for all samples. Two very good applications are for propylene/butylenes manufacturing and analysis of butane streams, which are free of compounds that irreversibly poison the Alumina PLOT column (NH3, H2S).
• Liquid sampling valve mounted at ambient temperature and external valve oven design for the gas sampling valve allows for full range temperature programming for column reconditioning (removing CO2 and H2O)
• Includes a secondary filter and back-pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection
Light Hydrocarbon Analyzer Model 4037
Published methods met: ASTM D2163, ASTM D2593, ASTM D2712, ASTM D2820, ASTM D4424, ISO 7941 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components - 0.1 ppm Application note reference number with technical details: D-6663
86
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Published methods met: EN 12177, EN 13132, IP 425/96 Types of sample analyzed: Unleaded petrol (gasoline) with a boiling point not to exceed 220 oCCompounds separated: Benzene, aromatics, MTBE, ethanol, oxygenates Guaranteed detection ranges/concentration levels: Benzene - 0.05 to 6 % (V/V), individual organic oxygenate compounds - 0.17% to 15 % (m/m), total organically bound oxygen - up to 3.7% (m/m) Application note reference number with technical details: D-6647
Benzene and Oxygenates Analyzer Model 4080
MTB
E
Benz
ene
Tolu
ene
i-But
yl-m
ethy
l-ket
one
• Pressure switched (PreVent), “heartcut” instrument configuration • The analyzer features a capillary injection port, PreVent and three capillary columns (a
liquid-sampling valve can also be used) • Total flexibility - Choosing the correct internal standard and varying the “heartcut”
times, it is possible to determine any oxygenate or aromatic found in petrol. • The same sample can be run twice with different “heartcut” times. By spreading the
components into two analyses, the interferences found with a large number of components are eliminated.
Petrol with heartcuts
Measured MTBE, benzene
87
Analyzer Description
Schematic of Mounted Model 4082
Major Features and Benefits
• Apparatus is designed to introduce pressurized liquid samples precisely, without sample vaporization before sample injection
• This product is normally sold as an “add on” to liquid sampling valved analyzers
• OPERATION OF THE MODEL 4082: Connect the filtered sample to the sample inlet and
start the liquid flow. There may be bubbles passing through the sight glass. Gently close the valve at the top of the sight glass until the bubbles stop. This will provide a slight backpressure in order to prevent the vaporizing of the liquid sample. Upon minimizing the vaporization (bubbles) of the sample and obtaining a desired liquid flow rate, close the toggle valve to stop the flow and make your injection. Once the run has commenced, open the toggle valve and the backpressure valve to vent the remaining liquid.
Liquid Sampling Apparatus Model 4082
Published methods met: UOP 911 Types of sample analyzed: Pressurized liquid Compounds separated: N/A Guaranteed detection ranges/concentration levels: N/A Application note reference number with technical details: None
88
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Published methods met: ASTM D2504 Types of sample analyzed: Gas Compounds separated: Hydrogen, oxygen /argon coelution, nitrogen, methane, carbon monoxide Guaranteed detection ranges/concentration levels: CO – 100 ppb, all other components – 50 ppb Application note reference number with technical details: D-6648
Trace H2, O2, Ar, N2, CH4 and CO in Light Hydrocarbons Analyzer Model 4083
• Trace level detection and measurement of components by Discharge Ionization Detector (DID)
• To maximize performance, all features of the system’s valving, fittings, tubing and columns are designed to be inert and leak tight. Key components are located in a carrier gas purged enclosure.
• If any of the target compounds are in % level concentrations in your sample, this analyzer may not be appropriate for your samples
• Extreme care must be taken in providing sample to the analyzer. Sample connections and carrier gas connections to the analyzer must be leak free.
• The analyzer includes a carrier gas purifier to ensure carrier gas quality • Can be combined with other applications or a second channel of trace level analysis
89
Analyzer Description
Typical Chromatogram
Major Features and Benefits
Trace Methanol and MTBE in Liquid Hydrocarbons Analyzer Model 4086
Published methods met: None Types of sample analyzed: Liquid Compounds separated: Acetaldehyde, MTBE, methanol, acetone, 2-propanol, others Guaranteed detection ranges/concentration levels: Acetaldehyde, MTBE, methanol – 0.5 V ppm to 1V%; all other components – 1 V ppm to 1V% Application note reference number with technical details: None
• Split/splitless injector, dual capillary column, PreVent and flame ionization detector (FID)
• An autosampler should be included for precision • Optional gas-sampling or liquid-sampling valves can be added • Capillary non-polar precolumn for separation of light non-polar compounds and
backflushing heavies. The use of a precolumn and backflushing keeps high boiling material from contaminating the main column. Backflushing of the precolumn is provided by PreVent hardware and a mid-point pressure switch time programmed from the Clarus Interface or TotalChrom.
• Capillary PLOT silica main column for separation of oxygenated compounds
90
Related Industries Also Benefit The dedicated and guaranteed PerkinElmer Arnel Analyzers and Systems in this booklet specifically address the petrochemical laboratory and process industry. Many other standard and custom Analyzers, Systems and Accessories are available for other industries such as pharmaceutical, food & beverage, and specialty gases for QC, general testing and environmental - occupational safety monitoring applications. Examples of other guaranteed products are:
• Model 4438 and 4046 Trace Impurities in Beverage CO2 Analyzers • Series 5100 Acetaldehyde in PET Bottles Analyzer • Series 5200 Workspace Air Quality Monitor
Explore both the PerkinElmer web site (www.perkinelmer.com) and the Arnel Inc. web site (www.arnelinc.com) for other products, plus contact your local PerkinElmer sales engineer or email Arnel at [email protected] for more details, literature and a quotation.
© 2003 PerkinElmer, Inc. All rights reserved. PerkinElmer is a registered trademark of PerkinElmer, Inc. Arnel is a trademark of Arnel Inc.PerkinElmer reserves the right to change this document at any time and disclaims liability for editorial, pictorial or typographical errors.
006808_02 KG060303 Printed in USA
PerkinElmer Life and Analytical Sciences710 Bridgeport Avenue Shelton, CT 06484-4794 USAPhone: 800-762-4000 or(+1) 203-925-4602www.perkinelmer.com
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