SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)
Version 6.0 Print Date 2016/04/05
Revision date / valid from 2016/04/05 MSDS code: GZD080
R45326 1/17 EN
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name : METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture
: Colouring agents, dyes
Uses advised against : At this moment we have not identified any uses advised
against
1.3. Details of the supplier of the safety data sheet
Company : Brenntag Colours Ltd. High Level Way Halifax West Yorkshire HX1 4PN - GB
Telephone : 00 44 (0) 1422 358 431 Telefax : 00 44 (0) 1422 330 867 E-mail address : [email protected]
1.4. Emergency telephone number
Emergency telephone number
: EMERGENCY ONLY TELEPHONE NUMBER:
00 32 (0) 3 575 55 55 (SGS Emergency Response Services -
24 hours)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
REGULATION (EC) No 1272/2008
Hazard class Hazard category Target Organs Hazard
statements
Acute toxicity (Oral) Category 4 --- H302
Skin corrosion Category 1B --- H314
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Acute aquatic toxicity Category 1 --- H400
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Directive 67/548/EEC or 1999/45/EC
Hazard symbol / Category of danger Risk phrases
Corrosive (C)Corrosive (C) R34
Harmful (Xn)Harmful (Xn) R22
Dangerous for the environment (N)Dangerous for the environment (N)
R50
For the full text of the R-phrases mentioned in this Section, see Section 16.
Most important adverse effects
Human Health : See section 11 for toxicological information.
Physical and chemical hazards
: See section 9 for physicochemical information.
Potential environmental effects
: See section 12 for environmental information.
2.2. Label elements
Labelling according to Regulation (EC) No 1272/2008 Hazard symbols :
Signal word : Danger
Hazard statements : H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life.
Precautionary statements
Prevention : P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response : P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do
NOT induce vomiting.
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P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Hazardous components which must be listed on the label:
• Tris[4-(diethylamino)phenyl]methylium acetate • acetic acid • hydrochloric acid
2.3. Other hazards
For Results of PBT and vPvB assessment see section 12.5.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Hazardous components Amount [%]
Classification (REGULATION (EC) No 1272/2008)
Classification
(67/548/EEC) Hazard class /
Hazard category
Hazard
statements
Tris[4-(diethylamino)phenyl]methylium acetate
CAS-No. : 63157-72-2
EC-No. : 263-974-8
>= 30 - < 50 Acute Tox.4 Skin Corr.1B
Aquatic Acute1
H302 H314
H400
Harmful; Xn; R22 Corrosive; C; R34
Dangerous for the environment; N; R50
acetic acid
Index-No. : 607-002-00-6 CAS-No. : 64-19-7
EC-No. : 200-580-7 EC Registration
: 01-2119475328-30-xxxx
>= 30 - < 50 Flam. Liq.3 Skin Corr.1A
H226 H314
R10 Corrosive; C; R35
hydrochloric acid
Index-No. : 017-002-01-X CAS-No. : 7647-01-0
EC-No. : 231-595-7 EC Registration
: 01-2119484862-27-xxxx
>= 1 - < 5 Met. Corr.1 STOT SE3
Skin Corr.1B
H290 H335
H314
Irritant; Xi; R37 Corrosive; C; R34
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For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General advice : Take off all contaminated clothing immediately.
If inhaled : If inhaled, remove to fresh air. Seek medical advice.
In case of skin contact : Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Consult a physician.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Seek medical advice.
If swallowed : Do NOT induce vomiting. Seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms : See Section 11 for more detailed information on health effects and symptoms.
Effects : See Section 11 for more detailed information on health effects and symptoms.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
: Water spray, Foam
Unsuitable extinguishing media
: No information available.
5.2. Special hazards arising from the substance or mixture
Specific hazards during firefighting
: May decompose in a fire giving off toxic fumes
5.3. Advice for firefighters
Special protective equipment for firefighters
: In the event of fire, wear self-contained breathing apparatus.Wear appropriate body protection (full protective suit)
: Wear self-contained breathing apparatus and protective suit.
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Further advice : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions : Use personal protective equipment. Keep away unprotected persons. Avoid contact with the skin and the eyes. Do not breathe vapours or spray mist. Wear respiratory protection. For personal protection see section 8.
6.2. Environmental precautions
Environmental precautions
: The product should not be allowed to enter drains, water courses or the soil. In case of large spillage contact the local authority.
6.3. Methods and materials for containment and cleaning up
Methods and materials for containment and cleaning up
: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).
Further information : Treat recovered material as described in the section "Disposal
considerations".
6.4. Reference to other sections
See Section 1 for emergency contact information. See Section 8 for information on personal protective equipment. See Section 13 for waste treatment information.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling : Ensure adequate ventilation. Avoid contact with the skin and the eyes.
Hygiene measures
: Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday. Take off all contaminated clothing immediately. Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep from freezing. Keep away from food, drink and animal feedingstuffs.
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Advice on protection against fire and explosion
: Normal measures for preventive fire protection.
Further information on storage conditions
: Keep tightly closed in a dry and cool place. Keep in a well-ventilated place. Keep away from heat. Protect from frost.
Advice on common storage
: Keep away from food, drink and animal feedingstuffs.
Other data : Stable under normal conditions.
7.3. Specific end use(s)
Specific use(s) : No information available.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Component: acetic acid CAS-No. 64-19-7
Derived No Effect Level (DNEL)/Derived Minimal Effect Level (DMEL)
DNEL
Workers, Long-term - local effects, Inhalation
: 25 mg/m3
DNEL
Workers, Acute - local effects, Inhalation
: 25 mg/m3
DNEL
Consumers, Long-term - local effects, Inhalation
: 25 mg/m3
DNEL
Consumers, Acute - local effects, Inhalation
: 25 mg/m3
Predicted No Effect Concentration (PNEC)
Fresh water
: 3.058 mg/l
Marine water
: 0.306 mg/l
Intermittent releases
: 30.58 mg/l
Sewage treatment plant (STP)
: 85 mg/l
Fresh water sediment
: 11.36 mg/kg d.w.
Marine sediment
: 1.136 mg/kg d.w.
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Soil
: 0.47 mg/kg d.w.
Other Occupational Exposure Limit Values
EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, Time Weighted Average (TWA): 10 ppm, 25 mg/m3 Indicative ELV (IE), Short Term Exposure Limit (STEL): 15 ppm, 37 mg/m3 Indicative OELV
Component: hydrochloric acid CAS-No. 7647-01-0
Derived No Effect Level (DNEL)/Derived Minimal Effect Level (DMEL)
DNEL
Workers, Acute - local effects, Inhalation
: 15 mg/m3
DNEL
Workers, Long-term - local effects, Inhalation
: 8 mg/m3
Predicted No Effect Concentration (PNEC)
Fresh water
: 36 µg/l
Marine water
: 36 µg/l
Intermittent releases
: 45 µg/l
Sewage treatment plant (STP)
: 36 µg/l
Fresh water sediment Exposition is not expected.
:
Marine sediment Exposition is not expected.
:
Soil Exposition is not expected.
:
Other Occupational Exposure Limit Values
UK. EH40 Workplace Exposure Limits (WELs), Short Term Exposure Limit (STEL):, Gas and aerosol mists. 5 ppm, 8 mg/m3
UK. EH40 Workplace Exposure Limits (WELs), Time Weighted Average (TWA):, Gas and aerosol mists. 1 ppm, 2 mg/m3
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EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, Time Weighted Average (TWA): 5 ppm, 8 mg/m3 Indicative EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, Short Term Exposure Limit (STEL): 10 ppm, 15 mg/m3 Indicative ELV (IE), Short Term Exposure Limit (STEL): 10 ppm, 15 mg/m3 Indicative OELV ELV (IE), Time Weighted Average (TWA): 5 ppm, 8 mg/m3 Indicative OELV
8.2. Exposure controls
Appropriate engineering controls
Ensure adequate ventilation.
Personal protective equipment
Respiratory protection
Advice : In case of insufficient ventilation, wear suitable respiratory equipment.
Hand protection Advice : Protective gloves
The glove material has to be impermeable and resistant to the product / the substance / the preparation. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Protective gloves should be replaced at first signs of wear.
Material : Nitrile rubber
Eye protection
Advice : Tightly fitting safety goggles
Skin and body protection
Advice : Protective work clothing Complete suit protecting against chemicals
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Protective measures
Advice : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing
Environmental exposure controls
General advice : The product should not be allowed to enter drains, water courses or the soil. In case of large spillage contact the local authority.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Form : liquid
Colour : violet
Odour : no data available
Odour Threshold : no data available
pH : 4
Freezing point : no data available
Boiling point : no data available
Flash point : > 100 °C Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : not determined
Lower explosion limit : not determined
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : no data available
Density : no data available
Water solubility : no data available
Solubility in other solvents : not determined
Solubility/qualitative : No information available.
Partition coefficient: n-octanol/water : no data available
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Auto-ignition temperature : no data available
Thermal decomposition : Under certain fire conditions, traces of other toxic products cannot be excluded.
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Explosive properties : EU legislation: not determined
Explosivity : no data available
Oxidizing properties : Not determined.
9.2. Other information
Burning number : (20 °C) not determined
Sublimation point : no data available
Bulk density : no data available
Flow time : no data available
Impact Sensitivity : no data available
Surface tension : not determined
Oxidizing potential : no data available
SECTION 10: Stability and reactivity
10.1. Reactivity
Advice : Stable under recommended storage conditions.
10.2. Chemical stability
Advice : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Hazardous decomposition products formed under fire conditions.
10.4. Conditions to avoid
Conditions to avoid : Keep from freezing.Avoid high temperatures. Thermal decomposition : Under certain fire conditions, traces of other toxic products
cannot be excluded.
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10.5. Incompatible materials
Materials to avoid : Oxidizing agents
10.6. Hazardous decomposition products
Hazardous decomposition products
: May decompose in a fire giving off toxic fumes
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Data for the product
Acute toxicity
Oral
Harmful if swallowed., Cause serious burns with severe pains,
vomiting, pains in the stomach, possibly chock and damaged kidneys. The burn may occur even if only small amounts have been swallowed.
Acute toxicity estimate
: 1064 mg/kg ) (Calculation method)
Inhalation
Inhalation may cause pain in respiratory system, sneezing,
coughing and difficulty in breathing. Risk for pulmonary edema by high concentration.
Dermal
no data available
Other routes
no data available
Irritation
Skin
Result : corrosive effects
Eyes
Result : corrosive effects
Risk of serious damage to eyes.
Splashes in the eyes may cause painful burns, which may result in
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permanent damage to the eyes.
Sensitisation
Result : No sensitizing effect known.
CMR effects
CMR Properties
Carcinogenicity
: no data available
Mutagenicity
: no data available
Teratogenicity
: no data available
Reproductive toxicity
: no data available
Specific Target Organ Toxicity
Single exposure
Remark
: no data available
Repeated exposure
Remark
: no data available
Other toxic properties
Repeated dose toxicity
no data available
Aspiration hazard
no data available,
Further information
Other relevant toxicity information
: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach.
Component: acetic acid CAS-No. 64-19-7
Acute toxicity
Oral
LD50 Oral : 3310 mg/kg (Rat)
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SECTION 12: Ecological information
12.1. Toxicity
Data for the product
Acute toxicity
Fish
no data available
Toxicity to daphnia and other aquatic invertebrates
EC50
: < 0.1 mg/l (Daphnia (water flea); 48 h)
algae
no data available
Acute aquatic toxicity
Result
: no data available
Chronic toxicity
Chronic aquatic toxicity
Result
: no data available
12.2. Persistence and degradability
Data for the product
Persistence and degradability
Biodegradability
Result
: This information is not available.
12.3. Bioaccumulative potential
Data for the product
Bioaccumulation
Result
: This information is not available.
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12.4. Mobility in soil
Data for the product
Mobility
Result
: This information is not available.
Surface tension
Result
: not determined
12.5. Results of PBT and vPvB assessment
Data for the product
Results of PBT and vPvB assessment
Result
: no data available
Result
: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6. Other adverse effects
Data for the product
Biochemical Oxygen Demand (BOD)
Result
: no data available
Chemical Oxygen Demand (COD)
Result
: no data available
Additional ecological information
Result
: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Product
: Disposal together with normal waste is not allowed. Special disposal required according to local regulations. Do not let product enter drains. Contact waste disposal services.
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Contaminated packaging
: Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning. Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
European Waste Catalogue Number
: No waste code according to the European Waste Catalogue can be assigned for this product, as the intended use dictates the assignment. The waste code is established in consultation with the regional waste disposer.
European Waste Catalogue Number
: Waste codes should be assigned by the user based on the application for which the product was used.
SECTION 14: Transport information
14.1. UN number
2801
14.2. UN proper shipping name
ADR : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid, C.I. BASIC VIOLET 4) RID : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid, C.I. BASIC VIOLET 4) IMDG : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid, C.I. BASIC VIOLET 4)
14.3. Transport hazard class(es)
ADR-Class (Labels; Classification Code; Hazard identification No; Tunnel restriction code)
: 8
8; C9; 80; (E)
RID-Class (Labels; Classification Code; Hazard identification No)
: 8
8; C9; 80
IMDG-Class (Labels; EmS)
: 8
8; F-A, S-B
14.4. Packaging group
ADR : III RID : III IMDG : III
14.5. Environmental hazards
Environmentally hazardous according to ADR : yes Environmentally hazardous according to RID : yes Marine Pollutant according to IMDG-Code : yes
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14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
IMDG : Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Data for the product
Other regulations : Occupational restrictions: Take note of Dir 92/85/EEC on the
safety and health of pregnant workers at work and of Dir 94/33/EC on the protection of young people at work.
German legislation on water endangering substances VwVwS
: WGK 3: highly water endangering; Self-classification according VwVwS of 17 May 1999, Annex 4
15.2. Chemical safety assessment
There is no data available for this product.
SECTION 16: Other information
Full text of R-phrases referred to under sections 2 and 3.
R10 Flammable. R22 Harmful if swallowed. R34 Causes burns. R35 Causes severe burns. R37 Irritating to respiratory system. R50 Very toxic to aquatic organisms.
Full text of H-Statements referred to under sections 2 and 3.
H226 Flammable liquid and vapour. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life.
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Further information
Training advice : Provide adequate information, instruction and training for operators.
Key literature references and sources for data
: Supplier information and data from the "Database of registered substances" of the European Chemicals Agency (ECHA) were used to create this safety data sheet.
Other information : The information provided in this Safety Data Sheet is correct to
our knowledge at the date of its revision. The information given only describes the products with regard to safety arrangements and is not to be considered as a warranty or quality specification and does not constitute a legal relationship. The information contained in this Safety Data Sheet relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text
|| Indicates updated section.
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