11 Laser Physics 12
Laser Physics Laser Physics 1122..Interaction of light with matterInteraction of light with matter
MaákMaák PálPál
Atomic Physics DepartmentAtomic Physics Department
22 Laser Physics 12
Interactions in a volume V with a selected mode of frequency :spontaneous emission, absorption, stimulated emission
Probability densities of the processes ~ transition cross section [cm2]
Strength of interactions, lineshape function:
Total spontaneous emission into all modes:
Spontaneous lifetime:
Interaction with a photon beam of frequency travelling in a selected direction:
photon-flux density (photons / cm2 ·s)
S can be determined from measurement, g ( ?
Light-matter interactions (summary)
.VcnWPP,
Vcpp,
Vcp iieabieabsp
1s
.S
g,dS 1-2
0
scm1
28 sSPsp
gt
gS,t
S,t
Pspspsp
sp 881 22
.iWeffective interaction area
33 Laser Physics 12
Line-broadening mechanism
The frequency dependence of light-matter interactions is governed by the normalized lineshape function g . Materials can be classified into two basically different groups:
homogeneous
All atoms, molecules behave similarly in the light-matter interaction, they have the same individual lineshape function.
inhomogeneous
Group of atoms and molecules behave differently in the light-matter interaction, the whole system can be characterized by an average lineshape function.
The reality is always a mixture of the two properties!
Light-matter interactions
44 Laser Physics 12
Homogeneous broadening – lifetime or natural broadening
It is always present, the questions is how much dominant is?
Excited energy levels have finite lifetime. If level 2 is an excited level, its lifetime represents the inverse of the rate at which the population of that level decays to level 1 and to all other lower energy levels radiatively (tsp) or nonradiatively, therefore tsp.
The population of level 2 decays exponentially, therefore the amplitude of emitted electromagnetic field decays also exponentially
The spectral dependence can be calculated by the Fourier-transform of the exponentially decaying harmonic function.
., 01222/ 0 hEEeeE tjt
The energy decays with therefore the factor of ½!!
2
1
tsp
2
Light-matter interactions
55 Laser Physics 12
Homogeneous broadening – lifetime or natural broadening (cont)
Time dependent field amplitude:
the Fourier-transform of f(t):
is the FWHM of the Lorentz-function. We could start from the uncertainty principle of Heisenberg:
.0ha,00ha,022
ttEteetE tjt
ggnormalizin22 FdtetfFtf tj
.g,,/
/go
22
12
2022
.12, EtE
Light-matter interactions
66 Laser Physics 12
Homogeneous broadening – lifetime or natural broadening (cont)
General case: both selected energy levels are excited levels, both have lifetime broadenings:
the broadening of the transfer is:
The reciprocal of the characteristic time is the sum of the reciprocal lifetimes and the broadening can be calculated:
,2
,2 1
12
2hEhE
,12
112 21
21hhEEE
.1121111
2121
MHz.161021
2110 88 ~s~
typnattyp
Light-matter interactions
77 Laser Physics 12
Homogeneous broadening – lifetime or natural broadening (cont)
Wavepacket emissions at random time and the Lorentz-function
,g Lorentzo2
.2
12
2
spo t
In ideal case 2 = tsp and 1/ 1=0 (lower level is stationary):
10-11-10-7 cm2 in 0.1 – 10 µm wavelength range.
.2
,2
1 2
ospt
( 0) has a typical order of magnitude of 10-20-10-11cm2
(small overlap)
Light-matter interactions
88 Laser Physics 12
Homogeneous broadening – collision broadening
In gas and fluid can be important with increasing the density of particle (with increasing the pressure). All particle suffer from the same effect, therefore it is a homogeneous effect.
Collision will disturb the light emission process. Two different collisions:
inelastic – particle leaves the excited level lifetime of the excited level decreases similar to the previous case (lifetime broadening)
elastic, there is no transfer between energy levels, there is a disturbance in the mechanism of light emission random phase shift
Light-matter interactions
d ~ 10-13 s
c 10-8 s
99 Laser Physics 12
Homogeneous broadening – collision broadening (cont.)
Harmonic function with random phase shift frequency spectra by Fourier transform again Lorentz-function.
If c is the average time between collisions, the normalized lineshape function:
c depends on the pressure, estimation with drastic simplifications:
„ideal” monatomic gas of radius r, hard spheres, we fix one particle, the others are moving toward the fix particle with .
2220 41
2
c
ccg
0max 2 ccg
cc
1
relavrv
Light-matter interactions
1010 Laser Physics 12
relavrv
Homogeneous broadening – collision broadening (cont.)
Suppose that the movement of particles toward the fixed particle takes place in a unit cross section cylinder of length :
The probability of collision is proportional with the area of the fixed particle:
The number of collisions in unit time is: , N is the atomic density.
The average collision time is: . If there is m mol gas in V volume
24rrelavrvNr 24
Nvr relavr
c 241
relavrv
fixed particleunit cross section
TkPN
VmNNTkVNTkNmTRmPV
B
ABBA
kN BA
)(
Light-matter interactions
1111 Laser Physics 12
Homogeneous broadening – collision broadening (cont.)
Collision broadening is proportional to the pressure, .
Rough guide suitable for estimation:
Different homogeneous broadening together
The sum of Lorentzian distributions is again a Lorentzian function:
Crystal field interaction is a ”non conventional” collision process, interaction with phonons in solids, but similarly homogeneous effect the lineshape function is Lorentzian.
PvrTk
relavr
Bc 24 kT
Pvr relavr
cc
241
Pc ~
.105~torrMHz
Pc
)21(21
121
ccnatLLL
Light-matter interactions
1212 Laser Physics 12
,gg
Direction of observation
,000 cv
v
Temperature dependent velocity distribution in the gas
Light-matter interactionsInhomogeneous broadening –– Doppler-broadening
Different atoms have different lineshape functions or different center of frequency average lineshape function average with respect to the variable .
E.g. light emission of atoms movingwith velocity v, frequency shiftbecause of the Doppler-effect.
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Inhomogeneous broadening –– Doppler-broadening (cont.)
p(v)dv is the probability that the velocity of an atom is in the interval of [v, v+dv] , the average lineshape function is:
In equilibrium the velocity distribution of atoms with mass M at temperature T is the Maxwell - Boltzmann distribution. The probability that the velocity component of the atom is in the range of [v, v+dv] in a given direction (e.g. in the direction of the resonator axis)
Gaussian-distribution.
FWHM:
.0 dvvpcvgg
dvkT
MvkT
Mdvpv 2exp
2
22/1
maximum at v=0
.2ln2 2/1
2/1 MkTv
Light-matter interactions
1414 Laser Physics 12
Inhomogeneous broadening –– Doppler-broadening (cont.)
In case the homogeneous broadening its effect can be neglected:
where
the FWHM or Doppler broadening.
,2/10 c
vL
,2
exp2 2
22
max
2/1
dTk
MckT
Mcdgdvpo
o
B
imum
ov
o
.dcdv,cv,cv0
20
20
22
0
0
210
021
21
2002120
2021
2
2222
2222
1
/
symmetrytheofbecause
/D
/
//
MlnkT
c
,Mc
lnkT,kT
Mcexp
1
Light-matter interactions
1515 Laser Physics 12
Different inhomogeneous broadenings together
Inhomogeneous distribution of doping materials in solids causes inhomogeneous broadening Gaussian distribution. The superposition of two different Gaussian distribution:
Homogeneous and inhomogeneous distributions together
Convolution of the Lorentz and the Gauss functions Voight-integral (can be numerically calculated).
Numerical examples - He-Ne laser
D=? T = 400 K, = 633 nm,
Collision broadening? Can be neglected at 3-4 torr pressure! Typical inhomogeneously broadened laser material.
.22
21 GGG
Js10636
JK10381106
g20
34
12323
.h
.k,MNe
GHz.51Hz1051 9 ..NeD
Light-matter interactions
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Numerical examples - ruby és Nd:YAG laser
T-dependent broadening,because the lattice vibrationincreases with T!Typical systems with homogeneous broadening.Inhomogeneous effect atT ~ 0 because of impurities.
/c0 ( 1 / , cm-1) data,
e.g. at 300 K L
Nd:YAG 120 GHzRuby 330 GHz
0100 200 300
4
8
12
16
20
Hõmérséklet ( K)o
Vonalszélesség[cm ]-1
Rubinm
mNd:YagNd:YAG
Light-matter interactions
Linewidth
Temperature [K]
1717 Laser Physics 12
Typical broadenings of different laser materials
Light-matter interactions
Type Gas Liquid Solid
natural 1 kHz - 10 MHz can be neglected can be neglected
collision 5 - 10 MHz/torr 9 THz -
crystal field interaction - - 300 GHz (300K)
Doppler 50 MHz - 1 GHz can be neglected -
local field - 15 THz 30 GHz - 15 THz
Homogeneous
Inhomogeneous
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Problem
Possible decays of E2 and E1 in an atom, tsp = 5 ms, nr = 50 µs, 20 = 10 ps, 1 = 15 µs. Calculate 21 and nat of the transition! Is it an ideal choice to
use that transition for a laser transition?
Light-matter interactions
2
1
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