CH3Br,Ion energetics
agust,heima,...CH3Br/AFSTODUMYND-190809hrh.pxpagust,www,....ch3br/PPT-210809aak.ppt
ion Lowest energy formation threshold:
Second lowestFormation threshold:
Third lowest formation threshold
fourth lowest formation threshold
fifth lowest formation threshold
sixth lowest formation threshold
C+ 152927(C++HBr+H2+e-)
156073(C++H+H2+Br-)
183237(C++H+H2+Br+e-)
189222(C++2H+HBr+e-)
192397.9(C++3H+Br-)
219532(C++3H+Br+e-)
CH+ 123115(CH++H2+Br-)
150249(CH++H2+Br)
156234(CH++H+HBr+e-)
159409.9(CH++2H+Br-)
186544(CH++2H+Br+ +e-)
CH2+ 115987
(CH2+ + HBr)
119162.9(CH2
+ + H + Br-)146297(CH2
++H+Br)
CH3+ 76818.3
(CH3++Br-)
103953(CH3
++Br+e-)
CBr+ 1511632(CBr++H2+H+e-)
187927(CBr++3H+e-)
CHBr+ 131468(CHBr++H2+e-)
167763(CHBr++2H+e-)
CH2Br+ 108078(CH2Br+ + H + e-)
CH3Br+ 85031.2(CH3Br+(3/2)+e-)
87617.2(CH3Br+(1/2)+e-)
Br+ 120137.8(CH3 + Br++e-)
- -
H+ ath
CH3Br+ formation energetichighlighted
99055
ion Lowest energy formation threshold:
Second lowestFormation threshold:
Third lowest formation threshold
fourth lowest formation threshold
fifth lowest formation threshold
sixth lowest formation threshold
C+ 5(C++HBr+H2+e-)
5(C++H+H2+Br-)
6(C++H+H2+Br+e-)
6(C++2H+HBr+e-)
6(C++3H+Br-)
7(C++3H+Br+e-)
CH+ 4(CH++H2+Br-)
5 (CH++H2+Br)
5(CH++H+HBr+e-)
5(CH++2H+Br-)
6(CH++2H+Br+ +e-)
CH2+ 4
(CH2+ + HBr)
4 (CH2
+ + H + Br-)5 (CH2
++H+Br)
CH3+ 3
(CH3++Br-)
4(CH3
++Br+e-)
CBr+ 5 (CBr++H2+H+e-)
6 (CBr++3H+e-)
CHBr+ 5 (CHBr++H2+e-)
6 (CHBr++2H+e-)
CH2Br+ 4 (CH2Br+ + H + e-)
CH3Br+ 3(CH3Br+(3/2)+e-)
3(CH3Br+(1/2)+e-)
Br+ 4(CH3 + Br++e-)
- -
H+ ath
Number of photons needed to reach thresholdsfor resonance excitation to 66037 cm-1 Rydberg / (3/2)5p;0 system:
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