Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche...
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Transcript of Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche...
![Page 1: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/1.jpg)
Zin
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e The art of monitoring metals: pitfalls and remedies
Frank Van Assche Director, European AffairsInternational Zinc Association168, Avenue de Tervuren B-1150 Brussels Belgium
![Page 2: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/2.jpg)
Zin
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eAll starts with measuring
metals (e.g. in water)
![Page 3: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/3.jpg)
Zin
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eAll starts with measuring
metals (in water)
measured dissolved
metal concentrations
![Page 4: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/4.jpg)
Zin
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e pitfalls
• Sampling procedure• Contamination of samples• LOD/LOQ
![Page 5: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/5.jpg)
Zin
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e1. Sampling for the dissolved
metal concentration• CIS for WFD, guidance doc 19:
– « The EQS for metals refers to the dissolved concentration …obtained by filtration on a 0.45µm filter »
– « The filtrate shall be acidified with nitric acid to ensure pH <2 »
• ISO 5667-3 (1994) - ISO 5667-3 (2012):• Focus on avoiding adsorption to the container
• Can be prevented by acidifying the sample• But solubilisation of (…metal) has to be avoided• Therefore « analyse asap »….
– no clear guidance of conditions for sampling for dissolved metals
– first stabilisation, then filtration…?
![Page 6: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/6.jpg)
Zin
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eMeasured metal depends on
sampling approach
Filter first, then stabilise
![Page 7: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/7.jpg)
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e Contamination of water samples• Metals are naturally present in soil, dust, air… • Labware may contain significant amounts of metals that
can leach into the sample, e.g.:– filter material, rubber stoppers, tubes; plastic syringes,
valves, beakers; lab gloves (talcum powder!)…• E.g.: % of cases where [Me]dissolved > [Me] total
River province Cu Zn Ni
Dommel 26 5 6
Regge & Dinkel 14 8 2
Schieland 34 21 50
(after Zwolsman & De Schamphelaere (after Zwolsman & De Schamphelaere 2007)2007)
![Page 8: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/8.jpg)
Zin
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e Attention points, e.g.:
• use of rigorously cleaned material • field rinsing of equipment used to collect samples• proper handling of equipment and samples, • routine collection of samples for quality-control• Field personnel trained in the implementation of
good field practices.
Always include distilled water blancs
![Page 9: Zinc…essential for life The art of monitoring metals: pitfalls and remedies Frank Van Assche Director, European Affairs International Zinc Association.](https://reader036.fdocuments.in/reader036/viewer/2022072014/56649e735503460f94b73ad5/html5/thumbnails/9.jpg)
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e LOQ versus EQS• LOQ vary strongly between countries/labs
– can even vary within 1 country
• LOQ/2 can be >> EQS• E.g.: country dataset 2012, 73 sampling points
– Dissolved concentrations measured– EQSZn: 10.9 µg/l (+BG)
– 35/73: PEC < EQS– 38/73: PEC > EQS
• At 23 locations LOQ = 50 or 75 µg/l LOQ/2 > EQS • 8 locations LOQ = 10 µg/l
• Relevancy of data where LOQ/2 > EQS ??