WORLD CONGRESS IIIOF

CHEMICAL ENGINEERING

September 21(Sun)—25(Thur), 1986Keio Plaza Hotel

Tokyo, Japan

Volume I

UNIVERSITATSBIBLIOTHEKHANNOVER

TECHNISCHEINFORMATIONS8IBLIOTHEK

Sponsored by :The Asian Pacific Confederation of Chemical EngineeringThe Interamerican Confederation of Chemical Engineering

The European Federation of Chemical Engineering

Organized by :The Organizing Committee of the World Congress III of Chemical Engineering

The Society of Chemical Engineers, Japan

TIB/UB Hannover 89

111 Illllllllll

TABLE OF CONTENTS

(Chairmen listed are tentative at time of printing.)

VOLUME I

PLENARY LECTURES

1. The innovation cycle and Japan's roleS. Ishisaka 1-1

2. The outlook for liquid fuels from biomassR. G. H. Prince 1-4

3. Chemical engineering and world developmentG. H. Thomson 1-14

4. Flixborough and after—major hazard control and planning systems in theUK and Europe and the way aheadE. J. Cullen 1-15

SESSION 1 INTERNATIONAL COOPERATION

la. Marketing

Chairmen: Y. Maruta (Kao Corp.)B. B. Singh (Phillip Townsend Associates, Inc.)

la-101 Strategic options for commodity chemical producers in transition tospecialty market sectors

B. B. Singh 1-23

la-102 "C.A.S.T"—A new management tool for the marketing executiveG. Black 1-27

la-103 International business development, marketing and sales of professionalservices in a changed marketplace

M. G. Desensy 1-31

I a-104 Future trends of engineering Plastics—Reflections on product and marketdevelopment in Western Europe

K. Weirauch 1-36

lb. Manufacturing Productivity in the Chemical Industry

Chairmen: V. T. Chuang (Union Carbide Formosa Co., Ltd.)•S. Takaoka (SRI International)

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lb-101 Productivity improvement from new gradient PVB sheet ^manufacturingprocess

R. L. Bourget and R. B. Kennard 1-40

lb-102 A new process for upgrading heavy oilT. Mori, H. Matsui and Y. Ikuta 1-44

lb-103 Estimating the minimum error bounds in plant yield measurementsW. J. Anderson, I. Cox, J. Felton and W. Walker 1-47

lb-104 Automation and the choice of technologyV. L. Conzalez 1-51

lc. Management and Uncertainty Analysis

Chairmen: S. Ichihara (Mitsubishi Monsanto Chemical Co.)T. H. Lafferre (Monsanto Chemical Co.)

lc-151 Management and uncertaintyT. Watanabe 1-56

lc-152 Financial and macroeconomic impact on international petrochemicalprices, demand and trade—The development and implementation ofIMISP system

W. Huang 1-59

lc-153 Managing the effects of competitive uncertainty—A case studies approachD. F. Brestovansky and D. W. T. Rippin 1-63

lc-154 Hazardous waste disposal a taxing problem—Shrouded in uncertaintyT. H. Lafferre 1-67

SESSION 2 ECONOMIC & TECHNOLOGY OUTLOOK

2a. Internationa] Cooperation in the Field of Chemical Engineering

Chairmen: S. Chong (Bureau of Science and Technologyof Ministry of Chemical Industry)

D. Hanesian (New Jersey Institute of Technology)C. Takeuchi (Chiyoda Chemical Engineering and

Construction Co.)

2a-201 International cooperation in the chemical engineering fields—A perspective of Chinese academic circle in chemical engineering

S. Cheng 1-70

2a-202 Process development of Victorian brown coal liquefactionK. Terunuma, Y. Nakako and T. Matsumura 1-73

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2a-203 Building mutual trust is key to effective transfer of process technologyB. J. Kim 1-77

2a-204 International comparisons of chemical disasters and their implicationsfor mitigation strategies, technology transfer and internationalcooperation—A systems framework

A. V. Naimpally, S. J. K. Rao and M. Masherbash 1-81

2a-205 Commercialization of R & D results—The role of a researchcommercialization company

Y. O. Ahn 1-85

2a-206 NSF/WVU/Industrial fluidization and fluid particle cooperativeresearch center

H. O. Kono, R. C. Bailie and J. D. Henry, Jr 1-89

2a-207 Cooperative research in heat pumps between India and the U.K.L. K. Doraiswamy, R. A. Mashelkar and F. A. Holland 1-92

2a-208 Technology transfer in chemical industry—Cases of self developmentand international cooperations

V. A. Sanghani and M. H. Mehta 1-96

2b. Technology Transfer

Chairmen: M. R. Kamal (McGill University)M. Nobue (Toyo Engineering Co.)

2b-251 Activities of Japan/China and Japan/Korea technology exchange in thefield of chemical engineering

S. Nakajima and I. Kikuchi 1-100

2b-252 The role of Japan cooperation center for petroleum industry develop-ment (JCCP) in the transfer of petroleum refining technology to oil-production countries

K. Natori 1-103

2b-253 Technology transfer and coordination in developing a worldwidemolecular sieve business

K. J. Gustafson, F. Mazzali and W. Sato 1-106

2b-254 Technology transfer of chemical processes between countries by a multi-national corporation

R. L. Ahlness and W. B. Leder 1-110

2b-255 Progress in our time—The transfer of industrial competenceD. Salmona 1-114

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2b-256 A practical approach to the transfer of technologyO. R. Carmona 1-118

SESSION 3 MANAGEMENT & MARKETING

Economic and Technological Outlook for Chemical Industry in the 1990s

Chairmen: Y. Ito (Toray Co.)G. Lipphardt (Hoechst AG.)H. Shinoda (JGC Corp.)

3-301 Comparative economics for alternative fuels and power technologiesI. Leibson 1-120

3-303 Japan's chemical industry in 1990sK. Kokubo 1-130

3-304 Direction of the U.S. chemical industry and its economic environmentP. H. Spitz 1-133

3-305 Structural change and profitability of chemical industry in the 1990sT. Kato 1-136

3-306 Return on investment for fine/specialty chemicalsS. Hirata 1-139

3-307 Business needs and R & D strategyJ. N. Turnbull and W. J. Petzny 1-142

3-308 Economic environmental protection—The challenge to chemicalengineering

G. Lipphardt 1-146

3-351 Chemical engineering for development of arctic resources in the 1990sR. M. Roehner and Y. F. Okamoto 1-151

3-352 Technological prospects for large-scale production of useful compoundsby plant cell and tissue culture

Y. Fujita 1-155

3-354 Research to secure the future of a high technology businessJ. D. Rankin 1-159

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SESSION 4 ENGINEERING EDUCATION

4a. University Education, Continuing Education and In-House Training Programs

Chairmen: A. E. Cassano (Instituto de DesarrolloTechnologico para la Industria Quimica)

L. W. Shemilt (McMaster University)T. Shirotsuka (Waseda University)P. L. Silveston (University of Waterloo)N. Wakao (Yokohama National University)

4a-251 Providing role models for chemical engineering studentsE. B. Cross and E. Rhodes 1-163

4a-252 Chemical engineering education at a medium sized state university in theU.S.

L. T. Fan 1-167

4a-253 International cooperation in chemical engineering education betweencapitalistic and socialistic countries

D. Hanesian 1-171

4a-254 Past experience and future planning of biochemical engineering educationat National Taiwan University and in ROC

S. Y. Huang 1-175

4a-255 Development and implementation of CAD/CAM/CAE in chemicalengineering education

W. Huang 1-179

4a-256 Chemical engineering education in Japanese universityY. Kawamura 1-183

4a-257 The chemical engineering curriculum—A Canadian case studyL. W. Shemilt and D. R. Woods 1-186

4a-258 Engineering science vs technology—A challenge in chemical engineeringeducation in India

L. K. Doraiswamy 1-190

4a-30I Chemical engineering education in KuwaitA. H. N. Mousa 1-194

4a-302 Integration of chemical process courses, environmental engineeringcourses and safety management systems—A systems approach

A. V. Naimpally, P. A. Cowan and S. J. K. Rao 1-196

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4a-303 Trends and developments in chemical engineering educationL. Nilson 1-200

4a-304 The role of IBM's advanced control system in enhancing under-graduate education in chemical engineering

P. E. Sawyer, P. L. Yue, S. Boron, R. G. Hill and R. M. Kerr . . . .1-204

4a-305 Problems and challenges of cooperative engineering educationP. L. Silveston and J. F. Westlake 1-208

4a-306 Chemical engineering education in ThailandP. Sthapitanonda 1-213

4a-307 Chemical engineering education in SingaporeW. K. Teo and I. J. Harris 1-217

4a-308 Accelerated system of education for engineers in CzechoslovakiaV. Vacek and P. Ditl 1-221

4a-309 Creative techniques in the process of teaching chemical engineering

J. O. Valderrama 1-225

4b. The Impact of Computer Developments on Chemical Engineering Education

Chairmen: R. A. Buonopane (Northeastern University)A. Kanazawa (Tokyo Institute of Technology)

4b-351 Computer-aided teaching in chemical engineering educationN. M. Sulaiman and A. Shafii 1-230

4b-352 Impact of computer methodology on education in developing countries—A dynamic model

G. J. V. J. Raju and T. E. Ramabhadram 1-234

4b-353 The educational impact of networked engineering workstationsB. Carnahan 1-238

4b-354 A new chemical engineering curricula tool—Dynamic simulation coupledwith an expert system

V. L. Rice 1-242

4b-355 On-line data acquisition for rates and residence time distributions in abench scale reactor system

K. A. Debelak, J. A. Roth, B. K. Vaughen and K. A. Overholser. .1-246

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SESSION 5 ROLE OF CHEMICAL ENGINEERING IN NEWLYDEVELOPING HIGH TECHNOLOGY FIELD

5a. New Material Processing

Chairmen: K. S. Chou (National Tsing Hua University)J. P. Couderc (Institut du Genie Chimique)S. Hirano (Nagoya University)T. Kataoka (University of Osaka Prefecture)H. Komiyama (University of Tokyo)J. Schwank (University of Michigan)P. V. Tebo (E. I. du Pont de Nemours & Co., Inc.)H. Yanagida (University of Tokyo)

5a-101 Rapid growth of A1N films by particle-precipitation aided chemical vapordeposition

T. Osawa and H. Komiyama 1-250

5a-102 Synthesis and properties of magnetite-dispersed carbon by pressurepyrolysis of organoiron copolymer

T. Yogo, S. Naka and S. Hirano 1-254

5a-103 Amorphous TiO2 films rapidly grown by thermophoresis aided chemicalvapor deposition

Y. Shimogaki and H. Komiyama 1-258

5a-104 Control of borosilicate gel densities using colloidal phenomenaJ. R. Schlup 1-262

5a-105 Synthesis and characterization of monodispersed Y2O3-doped ZrO2 finepowders

S. Hirano, T. Hayashi and T. Kojima 1-266

5a-106 Characterization of MgO by krypton adsorption and electron microscopyA. G. Shastri, J. Schwank and M. Bretz 1-270

5a-107 On the use of ceramics dielectric for the design of high power densityozonizer

C. Coste, J. M. Benas, R. S. Bes and J. C. Mora 1-274

5a-108 Thermal fracture of ceramics heated and cooled under several thermalconditions

M. Takatsu and Y. Mizutani 1-277

5a-151 Effect of mass transfer on the growth of CdTe epilayer by MOCVDK. S. Chou, I. R. Liao, Y. H. Lee and M. S. Lin 1-282

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5a-152 Growth rate of gallium arsenide thin film in chemical vapor depositionM. Sato and M. Suzuki 1-286

5a-153 Low pressure chemical vapor deposition (LPCVD) of silicon dioxide athigh temperature

A. Philipossian and K. V. Wormer 1-290

5a-154 Low pressure chemical vapor deposition of polysilicon from silane in ahot-wall reactor

J. P. Denton, T. E. Wilke, G. W. Neudeck and C. G. Takoudis . 1-294

5a-201 Design of low pressure chemical vapor deposition reactorsB. Delperier, C. Vinante, G. Constant and J. P. Couderc 1-298

5a-202 Use of exothermic noncatalytic reactions for efficient synthesis ofrefractory materials

V. Hlavacek and J. Puszynski 1-301

5a-203 Convection in melt and its control for high quality of single crystalsA. Hirata, Y. Okano, A. Hatano and T. Okada 1-307

5a-204 Study of EPW etching of silicon wafersM. Matsuoka and Y. Arai 1-311

5a-205 Uniformity of etch rate in plasma etching reactorsH. G. Stenger, Jr., R. Sellamuthu, R. J. Jaccodine andJ. A. Barkanic 1-315

5a-206 Migration of two ions during electrolysis of optical glass waveguideH. Yoshidaand T. Kataoka 1-319

5a-251 Electrode materials and mechanism of electrode polarization in solidelectrolyte cells

H. Nagamoto and H. lnoue 1-323

5a-252 Metal migration in microelectronicsJ. A. Roth, J. J. Steppan, L. C. Hall, S. P. Carbone andD. A. Jeannotte 1-327

5a-253 A novel gas detection method by metal/insulator conglomerateT. Yasuda, A. Yanase, H. Komiyama and K. Tanaka 1-331

5a-254 Simulation of the temperature distribution in crystals grown byCzochralski method

P. A. Ramachandran, M. P. Dudukovic and R. K. Srivastava 1-335

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5b. Novel Processes in Chemical Industry

Chairmen: M. P. Dudkovic (Washington University)N. Kagawa (Sumitomo Chemical Industry Co.)M. Kai (Daicel Chemical Industry Co.)J. A. Mikhlin(SNC)

5b-251 Unicracking feedstock pretreatment process—A commercial route for theproduction of olefins

L. J. Scotti, A. Rhoe, J. M. F. Baujin and B. Peralta 1-339

5b-252 Achievements of chemical process development by means of chemicalengineering principles in PRC

C. J. Xiao 1-344

5b-253 Production of synthesis gas from carbon dioxideE. Kunugita, T. Hashitsume, X. W. Tao and Y. C. Wan 1-346

5b-3OI The potential of plasma technology applications in CanadaJ. A. Mikhlin 1-350

5b-302 Alusuisse Italia/Lummus crest maleic anhydride (ALMA) processR. C. Johnson and L. Verde 1-354

5b-3O3 A new process for production of butadiene (ICC PROCESS)G. L. Yang, Y. Wang, L. Z. Zhao and C. W. Yu 1-358

5b-304 Preparation of porous, amorphous and fine TiO2 particles by chemicalvapor deposition

F. Kirkbir and H. Komiyama 1-361

5b-305 Novel process for preparing porous ammonium perchlorate particlesA. L. Leu, C. C. Sun, T. F. Yeh and R. J. Wu 1-365

5b-306 A new purification process using industrial liquid chromatographH. Saito, H. Sugeno, Y. Eto, S. Ishii and S. Yamada 1-368

5b-307 Three dimensional concentration of hydrophilic organic materials bya highly water-absorbing gel

H. Unno, T. Akehata and O. Hirasa 1-371

5b-308 Production of extra high quality H, and CO, gases from the byproduct gases in iron and steel industries

K. Tachibana, M. Shino and S. Anezaki 1-375

5b-309 Oxidation of anthracene to anthraquinone with air/NO,-N2Oj systemF. Rodriguez, L. Adrados, J. Burillo and J. Tijero 1-379

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5c. Robotics in Chemical Industry

Chairman: Y. Umetani (Tokyo Institute of Technology)

5c-351 Remote control technology for plant maintenance

T. Sasaki 1-383

5c-352 Development of quadrupedal walking robot for power plantsY. Umetani, S. Hirose, T. Matsubara, T. Ohmichi, M. Nishihara,T. Ibe, H. Shuto and A. Okino 1-387

5c-353 Development of preconditioning equipment for analytical instruments

S. Yamashita, T. Shimizu, and M Onishi 1-391

SESSION 6 ENERGY AND RESOURCES

6a. Energy Conservation and Analysis

Chairmen: F. Ogino (Kyoto University)

H. Y. Sohn (University of Utah)

6a-151 Energy and the developing countries—Trends and perspectivesT. Olajuyigbe 1-394

6a-152 Energy-economic interactions in developing countries—The case of oilproducers

A. A. Ballut 1-398

6a-153 Exergoeconomic analysis of energy intensive chemical processesG. Tsatsaronis and M. Winhold 1-402

6a-l 54 Application of the concept of exergy to the optimum utilization of energyin industrial processes and equipment

A. Anaya-Durand and R. Rivero-Rodriguez 1-407

6a-155 A new process for storing electricity based on the inversion of mechanicalcompression of vapor

P. L. Goff, P. Steranka and M. Jeday 1-411

6a-156 Conversion of solar energy via closed-loop thermochemical cyclesV. I. Anikeev, V. A. Kirillov and V. N. Parmon 1-415

6a-157 Thermal insulation as a potential aid for energy conservation in processindustries

V. K. Agarwal and S. C. Gupta 1-419

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6b. Coal and Oil Utilization

Chairmen: J. B. Agnew (University of Adelaide)Y. K. Ahn (Gilbert/Commonwealth International, Inc.)W. D. Deckwer (Universitat Oldenburg)S. Morooka (Kyushu University)M. Sadakata (Gunma University)K. Yoshida (University of Tokyo)

6b-251 Review of synfuels research in AustraliaP. G. Alfredson 1-424

6b-252 Effects of sulfur-form distribution and internal structure on hydro-desulfurization of coal

K. Sugawara, M. A. Sholes, T. Sugawara and H. Ohashi 1-428

6b-253 Coal cleaning by a fluidized classification columnZ. Tanaka and T. Takahashi 1-432

6b-254 Oxidation of coal slurries by Fe3+ ionsK. Kusakabe, S. Morooka, Y. Kato, K. Kawakami andK. Kusunoki 1-436

6b-255 Simultaneous hydrogen production and coal desulfurization by electrolysisS. B. Lalvani 1-440

6b-256 Chemical reaction engineering alnalysis on Morwell brown coal liquefac-tion in a donor solvent

Y. Ogo and Y. Miyamoto 1-444

6b-257 A study on the mechanism of the initial stage of coal liquefactionM. Yumura, S. Ohshima, K. Hayamizu Y. Kuriki andM. Kawamura 1-448

6b-258 A hydrodynamic study of gas-liquid-solid multiphase flowY. Hatate, T. Fujita, S. Tajiri, H. Nomura and A. Ikari 1-453

6b-259 Dewatering in brown coal liquefaction (BCL) process heat transfer andviscosity of Victorian brown coal-solvent slurry

O. Okuma, K. Mae and Y. Nakako 1-457

6b-260 Coal water slurry-fundamental characteristics and pilot plant scalepreparation

N. Hashimoto, H. Yanagimachi, Y. Suzuki, T. Hirabayashi,H. Ikushima and M. Shimamura 1-461

6b-261 Thixotropy and stability of highly loaded coal-water mixturesH. Usui and Y. Sano 1-465

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6b-262 Optimal injection strategies for the micellar/polymer enhanced oilrecovery process

W. F. Ramirez and Z. Fathi 1-469

6b-263 Evaluation of Indian crude oilsV. Krishnamoorthy and S. A. Puranik 1-472

6b-264 Kinetics of crude oil distillationS. Vossoughi and Y. E. Shoubary 1-476

6b-265 Development of a new kiln for the production of charcoal and mediumcalorific value gas

I. Gulyurtlu and J. F. P. Gomes 1-480

6b-266 Combustion of Portuguese anthracites in a fluidized bed combustorI. Gulyurtlu and J. F. P. Gomes 1-483

6b-267 Approach to newly designed coke oven—Mathematical model of cokeporosity

J. Fukai, T. Miura and S. Ohtani 1-485

6b-268 Combustion rate and particle temperature of pulverized coals and cokesM. Saito, M. Sadakata, M. Sato, T. Soutome and T. Sakai 1-489

6b-269 A proposal for new process of coal gasificationG. Chin, G. Liu, Q. Dong 1-493

6b-270 Two-stage fluidized bed coal gasifier-improvement of gasification efficiencyY. Fujioka, S. Shirakawa, S. Hozumi and J. Arai 1-497

6b-27l The behavior of minerals in the ash agglomerating-ash slagging coalgasifier

Y. Tanji, T. Mochizuki, S. Endo, A. Suzuki 1-501

6b-272 A correlation of the reactivities of gasification of coal chars withproperties of the parent coals

S. Kasaoka and Y. Sakata 1-505

6b-273 Estimation of fluidized bed gasification rate of coal-chars by CO2 and itsdynamic change with increased conversion from initially available coalcomposition alone

T. Adschiri, T. Shiraha, T. Kojima and T. Furusawa 1-509

6b-274 The behavior of ash fusion in high temperature coal gasificationM. Hirato and Y. Ninomiya 1-513

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6b-275 Effect of parent coal nature on changes in structure and intrinsic reactionrate during coal char gasification by CO2 and H2

S. Takeda, K. Kitano, J. Kawabata, J. W. Shih, T. Chiba andN. Takezawa 1-517

6b-276 Gasification rates of various coals measured by a rapid heating methodK. Hashimoto, K. Miura and T. Ueda 1-521

6b-301 Recovery and utilization of fine coal refuseC. E. Capes, R. D. Coleman and W. L. Thayer 1-525

6b-302 Coal combustion char enrichment by density separation in gas-fluidizedsystems

W. K. Lee 1-529

6b-303 The understanding and application of inorganic additives in theoxidation of Victorian brown coal

T. K. Pong, D. G. Wood, and I. J. Harris 1-533

6b-304 An incremental model for coal evaluation—(II) GasificationT. Y. Yan 1-537

6b-305 Quality improvement of coal fines by carbonizationK. Bunyakiat, S. Osuwan and A. Potjanart 1-541

6b-306 120-T/H coal-fired fluidized bed boiler and its operating results for MitsuiAluminium Co., Ltd.

K. Kikuzawa, M. Uozumi, K. Yano, S. Shimano and S. Motono. .1-545

6b-307 Distributed kinetic parameters for the evolution of gaseous species inthe pyrolysis of Australian and U.S. coals

P. K. Agarwal, J. B. Agnew and N. Ravindran 1-549

6b-308 Pilot-flame gasification of coal by a modified fluidized bedT. C. Chou and Y. M. Uang 1-553

6b-351 Kinetics of Fischer-Tropsch synthesis in slurry phaseW. D. Deckwer, R. Kokuun, E. Sanders and S. Ledakowicz . . . . 1-557

6b-352 Simulation of ash accumulation in dissolver for direct coal liquefactionS. Morooka, Y. Kato and H. Matsuyama 1-561

6b-353 Rheological properties of coal-solvent slurries at high temperature andpressure

A. Tsutsumi and K. Yoshida 1-565

6b-354 A model for vaporization and devolatilization of a coal-water slurrydroplet under intense heating conditions

S. S. Sandhu and E. A. Hess 1-569

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6c. Renewable and Alternative Energy

Chairmen: R. Ito (Osaka University)I. Wang (Tsinghua University)

6c-201 Hydrogen production by marine green algaeK. Miyamoto, S. Ohta and Y. Miura 1-573

6c-202 Process studies for enzymatic hydrolysis using conscentrated slurriesof acid pretreated brewing bagasse

J. Juanbaro and L. Puigjaner 1-577

6c-203 Modelling of counter-current pyrolysis zone in a modified biomassgasifier

H. Susanto, K. H. Kho and A. A. C. M. Beenackers 1-581

6c-204 Fuels and chemicals from biomass by the Waterloo fast pyrolysis processD. S. Scott, J. Piskorz and D. Radlein 1-585

6c-205 The influence of air distribution methods on temperature distributionsin the partial combustion zone of an updraught rice husk pyrolysis unit

B. Dejsupa and M. A. Connor 1-589

6c-206 Solar oil recovery—Design of the unitM. Bouabdallah, J. C. Mora and R. S. Bes 1-593

6c-207 Solar energy for caprolactam productionJ. Talukdar, E. H. Wong and V. K. Mathur 1-597

6c-208 High temperature immersed reactor for thermolysis processesD. Gauthier, G. Olalde, D. Schwander and A. Vialaron 1-601

6c-251 Production of humic fertilizers from low rank coals and residual biomassJ. Coca, R. Alvarez and F. A. Riera 1-605

6c-252 Simulation of the performance of combined geothermal reservoir—Production well systems

A. Orell and A. Miller 1-609

6c-253 Direct solar distillation of ethanol-water mixtures in a PTC collectorL. Salvador, A. Garcia and P. Ollero 1-613

6c-254 Development of a biomass gasifier using a circulation system of fluidizedparticles

M. Kuramoto, T. Furusawa and D. Kunii 1-617

6c-255 Heat and mass balance around a multiple-hearth furnace for vacuumpyrolysis of biomass

C. Roy, R. Lemieux, H. Pakdel, B. de Caumia and D. Blanchette. .1-621

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6d. Thermal Energy Storage

Chairmen: C. E. Capes (National Research Council of Canada)M. Hasatani (Nagoya University)E. Kunugita (Osaka University)A. S. Mujumdar (McGill University)

6d-101 A numerical study of buoyant flow through a cubical enclosure withopenings using a scalar potential

H. Ozoe, H. Miyachi and S. W. Churchill 1-625

6d-102 Charge and discharge heat transfer rates in the latent heat thermal energystorage

T. Honda, Y. Kim, H. Kishigami and A. Kanzawa 1-629

6d-103 Heat transfer in latent thermal storage units using pentaerythritol slurryM. Kamimoto, Y. Abe, K. Kanari, S. Sawata, T. Tani andT. Ozawa 1-633

6d-I04 Pilot plant study of a heat storage system using salt hydrates and directcontact heat transfer—A summary report

A. E. Fouda, C. E. Capes and M. Nakamura 1-637

6d-IO5 Chemical storage of enthalpy, of entropy or of exergy?—An inventoryof the thermal multipole systems

P. Le. Goff, H. Le. Goff, M. Barkaoui, A. Ramadane, E. Dietrich andJ. C. Trap 1-641

6d-106 Performance of a phase change heat store designed for use with a heatpump

B. Cooke and C. Pritchard 1-645

6d-107 Study of catalyst-assisted chemical heat pump with reaction couple ofbenzene hydrogenation/cyclohexane dehydrogenation

H. Kameyama, M. Yamashita, K. Yamamoto and T. Kabe 1-649

6d-l 08 Energy policy using high temperature gas-solid reversible reactions—Study of the system MgO, SO3/MgSO4 in a fluidized bed reactor

C. Muller and G. Flamant 1-653

6d-251 Thermal performance of thermal energy storage solar water heatingsystem using air/water heat exchanger

R. S. Mishra and N. K. Bansal 1-657

6d-252 A two dimension model for liquid stratified storage tanksK. A. R. Ismail, C. Y. Liu and L. R. Carrocci 1-661

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6d-253 Heat and power co-generation system by utilizing aqueous solutionof inorganic salts

J. Kamoshida and N. Isshiki 1-664

6d-254 Transient analysis of latent heat storage system of the shell tube typeK. A. R. Ismail and C. L. F. Alves 1-668

6d-255 Thermal energy storage by means of reversible thermochemical reactionM. Hasatani, H. Matsuda and S. K. Lee 1-672

6d-256 Study of catalyst-assisted chemical heat pump with reaction coupleof acetone hydrogenation 2-propanol dehydrogenation

Y. Kato, H. Kameyama and Y. Saito 1-676

6e. Topics in Nuclear Industry

Chairmen: G. A. Pon (Atomic Energy of Canada Limited)Y. Takashima (Saitama University)

6e-301 Chemically modified coniferous barks as scavengers of uraniumin sea water

M. Fujii, A. Ito, S. Shioya and M. Tamura 1-680

6e-302 Adsorptive characteristics of uranium from seawater using chelatingresins

K. Saito, T. Hori, S. Furusaki, T. Sugo, J. Okamoto 1-683

6e-303 Conceptual process design for uranium recovery from sea waterK. Chihara and M. Suzuki 1-687

6e-304 The Canadian nuclear program—From a chemical perspectiveG. A. Pon and H. K. Rae 1-691

6e-305 The "Nymphea" concept—A new way for using ion exchange in thedecontamination of radioactive liquid wastes with low salt content

R. Pierlas, J. F. Dozol, M. Kalimbadjian, R. Nicoud andD. Schweich 1-695

6e-3O6 Application of laser photochemistry to neptunium separation processesY. Enokida, A. Suzuki and R. Kiyose 1-700

6e-307 Iodine removal by ejector scrubber for nuclear reactor safetyS. Matsumoto and Y. Takashima 1-704

6e-308 Experience in the decontamination of nuclear power reactorsT. A. Beaman, R. L. Hemmings, J. E. Le Surf and J. L. Smee . . . . 1-708

6e-351 Optimum irradiation conditions in laser isotope separation of tritiumK. Takeuchi, S. Satooka and I. Inoue 1-712

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6e-352 A process analysis on atomic vapor laser isotope separation of lithiumK. Katoh, A. Suzuki and R. Kiyose 1-715

6e-353 Separation performance of carbon isotope by counter currentpacked column with chemical exchange process

A. Kitamoto and K. Takeshita 1-719

6e-354 Electropulse column for U-Pu partitionA. F. Cermak 1-723

6f. Energy Efficient Chemical Processes

Chairmen: Z. Fonyo (Technical University of Budapest)J. H. ShiehY. Naka (Tokyo Institute of Technology)I. Yamada (Nagoya Institute of Technolohgy)

6f-301 New thermodynamic function, fugergy—Computed values of fugergyA. Naimpally, S. Thatree, L. Thanh-Van and M. Musharbash . . . .1-727

6f-302 Application of heat pump systems to chemical plantsY. Naka, K. S. Hwang and E. O'Shima 1-731

6f-303 An evaluation method for a distillation column with a heat pumpM. Nakaiwa, M. Owa, T. Akiya, S. Kawasaki, V. Lueprasitsakuland T. Takamatsu 1-735

6f-304 A shortcut method for the synthesis of energy integrated distillationflowsheets

L. Zhou, Z. He and K. Yu 1-739

6f-305 An approach to the optimal distillation sequence with energyintegration

L. Zhou, Z. He and K. Yu 1-743

6f-306 A study of the use of intermediate reboilers and condensers indistillation column used for binary systems

A. Naimpally, S. Dimoulas and T. Thanh 1-747

6f-307 Synthesis of distillation systems with energy integration and heatrecovery networks based on the pinch concept

Z. Fonyo, E. Rev and I. Meszaros 1-750

6f-308 Energy consumption in nonconventional distillation structuresZ. Fidkowski and L. Krolikowski 1-754

6f-35l Optimum operating condition of Petlyuk's distillation process forternary separation

I. Yamada, H. Mori, Y. Kato and S. Hiraoka 1-758

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6f-352 Computer-aided synthesis of thermochemical reaction systemsI. Fujiwara, M. Sato, H. Yoshitome and E. Kunugita 1-762

6f-353 Computer-aided analysis of coal gasification processesJ. H. Shieh, A. Kanai and L. T. Fan 1-766

6f-354 Energy reduction in olefin plantsR. F. Strigle, Jr 1-770

SESSION 10. BIOTECHNOLOGY

10a. Bioengineering and Bioreactor Design

Chairmen: A. E. Humphrey (Lehigh University)T. Kobayashi (Nagoya University)J. Lehmann (Gesellshaft fur Biotechnologische Forschung)R. Matsuno (Kyoto University)Y. Miura (Osaka University)K. Nakamura (University of Tokyo)D. D. Y. Ryu (University of California)H. Taguchi (Osaka University)D. I. C. Wang (Massachusetts Institute of Technology)M. M. Young (University of Waterloo)

10a-101 Multilevel approach in batch culture processingK. Ohtaguchi 1-774

10a-102 Estimation of kinetic parameters of biological reactor modelsB. Ruggeri 1-778

10a-103 Rheology of polysaccharide fermentation broths—Application tobioreactor design and control

L. Choplin and A. LeDuy 1-781

10a-104 Bioreactor design for slurry fermentation systemsM. Moo-Young and Y. Kawase 1-785

10a-105 The effect of light on baker's yeast cell growth and protein secretionL. A. Hojnicki, D. H. Park, R. D. Tanner and G. W. Malaney .. 1-789

10a-106 Estimation and control of the specific growth rate in a fed-batchculture

S. Shioya, H. Shimizu and T. Takamatsu 1-793

10a-107 Monitoring of fermentation broths with fourier transform IR spectro-scopy—A feasibility study for on-line process control

J. C. Alberti and J. A. Phillips 1-797

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10a-108 Adaptive control of the sake mashing processY. Sugimoto, N. Tanaka, A. Furukawa, K. Watanabe, T. Yoshidaand H. Taguchi 1-801

10a-151 Mechanisms of cell damage in agitated microcarrier tissue culturereactors

R. S. Cherry and E. T. Papoutsakis 1-805

10a-152 Moving membranes for aeration and perfusion in mammalian cellculture reactors

J. Lehmann, H. Buentemeyer, G. W. Piehl and S. Schulz 1-809

10a-153 Utilization of immuno-affinity chromatography for purification of bio-logical materials

E. Sada, S. Katoh, A. Kondo and A. Kiyokawa 1-811

10a-154 Downstream processing of fermentation broths using tubular cross-flowmembranes

M. Cheryan, K. A. Sims, M. A. Mehaia and S. Tejayadi 1-815

10a-155 Design basis for rotational reactors used in aerobic wastewatertreatment systems

C. D. de Bazua 1-819

10a-156 Production and utilization of high polyphosphate sludgeS. Tang, J. Phillips and A. Humphrey 1-823

10a-201 Separation, characterization and adsorption of cellulase enzymes fromTrichoderma reesei

K. Andreas, R. J. Neufeld and R. C. MacKenzie 1-827

10a-202 A study on enzymatic hydrolysis of cellulose in an attrition bioreactorK. D. Oh and C. Kim 1-832

10a-203 A study of cellulose hydrolysis by Clostridium thermocellum and itscellulase complex

N. B. Afeyan and D. I. C. Wang 1-839

10a-204 Separation of ethanol from culture broth by pervaporation withhydrophobic porous membrane

K. Matsumoto and H. Ohya 1-843

10a-205 The kinetics of hydrogen evolution by ChlorellaE. Kojima, Y. Yamaguchi and J. Kobayashi 1-847

10a-206 Sorption of glucose in calcium alginate gelW. K. Teo, H. C. Ti and W. H. Tan 1-851

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10a-207 Oxygen diffusion coefficients in fermentation mediaC. S. Ho, E. Livio and L. K. Ju 1-855

10a-208 Mathematical modeling of immobilized cellular electrodesX. M. Li, B. S. Liang and H. Y. Wang 1-859

10a-251 A mathematical model to analyze diffusional effects on reversibleheterogeneous Michaelis-Menten kinetics—Application to a packedbed reactor for fruit juice debittering

A. Bodalo, J. L. Gomez, E. Gomez, J. Bastida, J. L. Iborra andA. Manjdn 1-863

10a-252 Continuous production of rifamycin B in a dual hollow fiber bioreactorH. N. Chang, B. H. Chung and I. H. Kim 1-867

10a-253 Continuous glycerides syhthesis and triacylglyceride hydrolysis bylipase in microporous hydrophobic membrane bioreactor

T. Yamane, M. M. Hoq and S. Shimizu 1-871

10a-254 Plasmid stability and its effect on design strategy of recombinant fer-mentation processes

D. D. Y. Ryu and S. B. Lee 1-874

10a-255 Stability of a two-micron based plasmid in Saccharomyces cerevisiaeC. Parker and D. DiBiasio 1-879

10a-256 Cloning and expression of enterobacteriaceae hydrogenase genes inEscherichia coli

I. Karube, E. Tamiya, H. Kanayama and M. Tomiyama 1-883

10a-257 Cloning of two /5-galactosidase genes of Bacillus stearothermophilusand production of thermostable /3-galactosidase in Bacillus subtilis

H. Hirata, S. Negoro and N. Okada 1-886

10a-351 Requirements of a biotechnology process simulatorL. B. Evans and R. P. Field 1-890

10a-352 Three pool escherichia coli growth model for on-line process controlB. Palsson and A. Joshi 1-894

10a-353 Analysis of bioreactors containing immobilized recombinant cellsK. M. Bailey, W. R. Vieth and G. K. Chotani 1-898

10a-354 New equipment for enhanced mass transfer and defoamingR. Roubicek, R. Long, J. Creed and S. Holbrook 1-901

10a-355 Xanthan gum production in foam fermenterT. K. Misra and S. M. Barnett 1-905

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10a-356 Computer modeling of an extractive cycloheximide fermentationK. H. Dykstra and H. Y. Wang 1-909

10a-357 Optimal temperature control for batch beer fermentationD. A. Gee and W. F. Ramirez 1-913

10a-358 A distributive model of heterogeneous acid-catalysed hydrolysis ofcellulose biomass particles

S. X. Rong and L. T. Fan 1-917

10a-359 Development of a method for the recovery of the enzyme cellulose fromaqueous solution

J. Woodward, A. R. Baird and C. Parrish 1-921

10a-360 Process design for the extraction of nutrients from peatA. M. Martin 1-924

10a-361 Effect of formaldehyde and hydrogen peroxide on the continuousgrowth of a methanol utilizing-yeast

H. Medrano-Roldan, R. Vazquez-Juarez, J. Morales-Castro,C. Casas-Campillo, B. Servin-Massieu and I. Magafia-Plaza . . . .1-928

10a-362 Biological fluidized bed reactor for denitrificationR. Boaventura and A. Rodrigues 1-932

10a-363 Kinetic analysis of naphthalenesulfonic acid-biodegradation byimmobilized bacteria

K. Wagner and D. C. Hempel 1-935

10a-364 Metabolic models and their use to improve blood storageB. Palsson, B. Built-Kravitz and A. Joshi 1-938

10a-365 Control of environmental factors in animal cell suspension culturesystem

M. Taya, T. Mano and T. Kobayashi 1-942

10a-366 Enzymatic reactions in supercritical fluidsK. Nakamura, Y. M. Chi, Y. Yamada and T. Yano 1-945

IOa-367 The effect of product accumulation on the effectiveness factor formicroencapsulated urease

R. W. Lencki and R. J. Neufeld 1-949

10a-368 Static and dynamic behavior of the glucose sensor using theimmobilized glucose oxidase membrane

S. Gondo, M. Morishita and H. Koya 1-953

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10a-369 Response characteristics of enzyme sensor for glucose with immobilizedGOD membrane and oxygen electrode

S. Tone and K. Yamamoto 1-957

10a-370 Transient analysis of the BR and CSTR reactors for immobilizedenzymes reacting systems with internal diffusional effects

A. Bodalo, J. L. Gomez, E. Gomez, J. Bastida, J. L. Iborra andA. Manjon 1-961

10a-371 Development of affinity chromatographic reactor for effective turnoverof dissociable cofactors

O. Miyawaki, K. Nakamura and T. Yano 1-965

10a-372 Hydrolysis of starch by simultaneous use of ^3-amylase and debranchingenzyme—Immobilized enzyme monolithic reactor

K. Kusunoki, K. Kawakami, F. Shiraishi, A. Yuasa andT. Kojima 1-969

10a-373 Sucrose hydrolysis and phenolics production by Daucus corotaentrapped in hollow fiber reactors

W. I. Jose, H. Pedersen and C. K. Chin 1-973

10a-374 Secretive fermentation of ?--linolenic acid production using cellsimmobilised in biomass support particles

H. Fukuda and H. Morikawa 1-977

10a-375 Design of proteinase-catalyzed synthesis of peptides in a water-immiscible organic solvent

K. Nakanishi, Y. Kimura and R. Matsuno 1-980

10a-376 Synthesis of aspartame precursor by solid enzyme in organic solventY. Harano, H. Mori and H. Ooshima 1-984

10a-377 Ion exchange chromatography of proteins—A simple method forpredicting optimum chromatographic conditions from linear gradientelution experiments

S. Yamamoto, M. Nomura and Y. Sano 1-988

10a-378 Adsorption characteristics of L-asparaginase in affinity chromatographyR. G. de Rebolefio, D. Cantero and M. A. Galan 1-992

10a-379 Application of a temperature-controllable experssion vector tophenylalanine production by Eschererichia coli

S. Sugimoto, T. Seki, T. Yoshida and H. Taguchi 1-996

10a-380 Production of c/s-benzeneglycol by genetically engineered benzene-oxidizing bacterium

Y. Kawakami, J. J. Yarmoff, T. Yago and H. Nishimura 1-1000

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10a-381 Genetic transfer of hydrogen-oxidizing ability of Alcaligeneshydrogenophilus to Pseudomonas oxalaticus

Y. Miura, H. Min, F. Umeda and K. Yagi 1-1004

10a-382 Computer simulation for the plasmid stability in continuous fermentationK. Shimizu, S. Hasegawa and M. Matsubara 1-1008

10a-383 Fed-batch culture of Escherichia coil harboring a runaway—Replication plasmid

S. lijima, S. Mizutani and T. Kobayashi 1-1012

10a-384 Effect of explosion operation for biochemical conversion of wood toenergy

Y. Nakamura and T. Sawada 1-1016

10a-385 The stability of a continuous stirred tank biological reactor utilizingan inhibitory substrate

W. Sokol and C. L. C. Migiro 1-1019

10a-386 Database system for the fermentation processesI. Endo and T. Nagamune 1-1022

10b. Food Processing

Chairmen: M. Le Maguer (University of Alberta)T. Yano (University of Tokyo)

10b-101 Engineering control of expansion in bakingT. Yano, Y. Shimiya and H. Sase 1-1026

10b-102 Measurement of the liquid-solid heat transfer coefficient duringcontinuous sterilization of liquids containing particles

N. J. Heppell 1-1029

10b-103 Evaluation of the solubility of fatty acids in supercritical fluidsP. Alessi, R. Cimino, M. Fermeglia, V. Gallo and I. Kikic 1-1032

10b-104 Caking degree of spray-dried avocado powdersS. C. S. Santos and J. Cal-Vidal 1-1036

10b-l05 Application of supercritical CO2 extraction to food processingM. Taniguchi, M. Kamihira, T. Tsuji and T. Kobayashi 1-1040

10b-106 Optimization of freezing conditions in freeze-drying of liquid foodsK. Nakamura and T. Yano 1-1044

10b-107 Dissolved air flotation as a means for protein recoveryC. R. Holland and M. I. A. Shahbaz 1-1048

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1 Ob-108 Fermentation of mango juice using yeast strains isolated frompalm wine

G. B. Oguntimein, M. O. Obisanya, J. O. Aina andJ. O. Akingbala 1-1052

10c. Biomedical Engineering

Chairmen: L. J. Garred (Lakehead University)K. Sakai (Waseda University)

10c-301 Carbon dioxide elimination from a hollow fiber membrane lungL. Garred, B. Burns and R. Shewchuk 1-1056

10c-302 Mass transfer and performance characteristics of a compositeartificial kidney—A hemodialysis-hemopefusion in series operation

C. J. Lee and Y. L. Chang 1-1060

10c-303 Performance of membrane filter for clinical useM. Mineshima, T. Agishi, K. Ota and K. Sakai 1-1065

10c-304 Novel application of ceramic membranes to plasma separationK. Ozawa, H. Sakurai, S. Takesawa and K. Sakai 1-1069

10c-305 Compartmental mass transfer analysis of the performance of a hybrid-type artificial liver support system utilizing isolated hepatocytes

N. Ohshima, M. Shiota, H. Kusano, G. Wada, T. Tsunetsugu andK. Ookawa 1-1073

10c-306 Drug transport through silicone elastomerY. Sun, K. Tojo, Y. W. Chien, C. L. Lee, K. L. Ulman andK. R. Larson 1-1077

10c-307 Skin permeability—Potassium chromate solutions through rat epidermisJ. Coca, R. Alvarez, M. T. Alvarez and H. Stefaniak 1-1081

10c-308 Transdermal drug delivery by prodrug bioconversionK. Tojo, K. H. Valia and Y. W. Chien 1-1085