WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The...
Transcript of WOODARD&CURRAN CORPORATE OFFICES: Maine, … · Woodard & Curran, Inc. completed the sampling. The...
WOODARDampCURRAN Engineering bull Science bull Operations
CORPORATE OFFICES Maine Massachusetts New Hampshire Connecticut Florida
Operational offices throughout the US
October 12 2005
Mr Terrence Connelly USEPA - New England Division 1 Congress Street Suite 1100 (HBT) Boston MA 02114-2023
RE Residential Tap Water Monitoring Program Hows Corner Superfund Site Plymouth Maine September 2005 Water Sampling Results
Dear Mr Connelly
Enclosed please find the laboratory results for the tap water sampling event conducted for the subject project in September 2(H)5 summary tables providing the data for each residence sampled and the data validation report The September 2(H)5 sampling event was completed on September 13 2005 and included the residences scheduled for quarterly sampling as follows
Quarterly Lots 2 (Skidgel) 7 (Melanson) 8-1 (Foss) ll-l(Godsoe) 11-2 (Ward) ll-3(Deraps) 11^1 (Leathers)
21-16 (Levesque) 31 (G Hopkins) 31 (Knight) 32-2 (Hames) 36 (Norris) 83-1 (Gray)
No sample was collected at Lot 2 (Skidgel) during the September 2005 sampling event because the homeowner could not be contacted by telephone to arrange a sampling appointment or in person to collect a sample Several unsuccessful attempts were made during the September sampling event to collect a sample at this residence
Quarterly Residential Sampling Results
Thirteen residences were scheduled for quarterly sampling and 12 samples were successfully collected As indicated above no sample was collected at Lot 2 (Skidgel) during this sampling event As outlined in Table 1 chloroform and tetrachloroethylene (PCE) were detected in the samples collected from the quarterly residential sampling locations Chloroform was detected in the water sample collected at Lot 7 (Melanson) at 90 figL which is below the chloroform Maximum Contaminant Level (MCL) of 100 pigL At Lot 32-2 (Hames) PCE was detected at a concentration of 028 J igL however this detection is below the PCE MCL of 50 (igL No other project-related compounds were detected in water samples collected from the quarterly residential sampling locations Therefore there were no cxceedences of the MCLs observed
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) bull 1-800-426-4262 bull wwwwoodardcurrancom 205 279069_05 summary reportdoc
WOODARD ampCURRAN Engineering bull Science bull Operations
Data Validation
The validation report indicates that chloroform was detected in one of the method blanks associated with the selected September 2005 samples indicating potential low level false positive concentrations of this compound in associated samples As a result concentrations of chloroform in associated samples below a calculated action level were qualified as non-detect Non-compliant continuing calibration results were reported for 111-trichloroethane and 11-dichloroethene resulting in qualification of positive and non-detect concentrations of these compounds in associated samples as estimated In addition non-compliant methylene chloride results were reported in one laboratory control sample therefore positive and non-detect methylene chloride results in associated samples were qualified as estimated Overall the results of the validation concluded that the data are of good quality and are suitable for their intended use
Summary
The September 2005 sampling event was completed on September 13 2005 and consisted of sampling the residences designated for quarterly sampling Woodard amp Curran Inc completed the sampling The next monitoring event is scheduled to take place in December 2005 and will consist of monitoring locations designated for quarterly sampling
If you have any questions regarding the enclosed materials or sampling program please contact me af (207)685-7333
Sincerely
WOODARD amp CURRAN INC
^-^-lffvlt^i-~ ^ ^ ^ t _ - ^ - o u _
Florence L Clauson Project Chemist
20529706 Enclosures
ex Rebecca Hewett MRDEP Mark Beliveau Pierce Atvvood
205279069_05summary reportdoc
Table 1 Summary of Quarterly Sampling Results
Residential Tap Water Program Plymouth Maine
PARAMETER (ugl)
Chloroform
11-Dichloroethene
cis-12-Dichloroethene
trans-12-Dichloroethene
12-Dichloropropane
Methylene chloride
Tetrachloroethene
124-Trichlorobenzene
111-Trichloroethane
Trichloroethene
Vinyl chloride
mp-Xylenes
o-Xylene
Xylenes (total)
WELL SAMPLE ID DATE
RESULT TYPE
LOT7 WSHC(7)MELANSON 091405 Primary
9
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
LOT8-1 WSHC8-1)FOSS 091305 Primary
lt059U
lt05
lt05
lt05
lt05
lt05
lt05
lt0S
lt05
lt05
lt05
lt1
lt05
lt15
LOT8-1 WSHC(8-1)FOSS DUP 091305 Duplicate 1
lt074U
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
LOT11-1 WSHC(11-1)GO 091305 Primary
lt05
lt 0 5
lt05
lt05
lt05
lt05
lt05 shy
lt05
lt05J
lt05
lt05
lt1
lt05
lt15
lt = Not detected at indicated reporting limit
J = Estimated U bull Result revised to non-detected due to blank contamination
qjartmonxls995037
PARAMETER (ugl)
Chloroform
11-Dichloroethene
cis-12-Dichloroethene
trans-12-Dichloroethene
12-Dtchloropropane
Methylene chloride
Tetrachtoroethene
124-Trichlorobenzene
111-Trichloroethane
Trichloroethene
Vinyl chloride
mp-Xylenes
o-Xylene
Xylenes (total)
WELL SAMPLE ID DATE RESULT TYPE
LOT11-3 WSHC(1t-3gtDERAPS 091305 Primary
lt05
lt05J
lt05
lt05
lt05
lt05J
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
Table 1 Summary of Quarterly Sampling Results
Residential Tap Water Program Plymouth Maine
LOTH-4 LOT21-16 WSHC(11-4)SAWYER WSHC(21 -16JLEVESQUE
091305 091305
Primary Primary
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05J lt05J
lt05 lt05
lt05 lt05
lt1 lt1
lt05 lt05
lt15 lt15
LOT31 WSHC(31)GHO 091305 Primary
lt05
lt05J
lt05
lt05
lt05
lt05J
bull=05
lt05
lt05
lt05
lt05
lt1
lt05
ltia
lt - Not detected at indicated reporting limit
J = Estimated U = Result revised to non-detected due to blank contamination
quartmon xlS995037
WOODARDampCURRAN Engineering gt Science bull Operations
bulli
LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05summary reportdoc
_
Llt ID laquo V lt 7 7 9 Sample Date- o s -
Dat 9
Qiydegse ^ t r a c t e d b y
f r a c t i o n Methn Ana lys i s flate 1153
W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo
Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP
7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e
0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13
0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a
05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50
0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013
degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013
Xylenes ( t o t a l ) cr 10 1 0 10 05Q
0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S
D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l
012 64
Page 01 0 f 0 1 P8B3 7
Sample natQ o_
KATAHDIH ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Project HOWS CORNER QUARTERLY
PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA
Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1
CAS Compound F l a g s Results DF PQL Adj PQL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0
75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0
71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0
79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0
75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0
156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0
15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50
78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0
127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0
m+p-Xylenes c 1 0 1 0 1 0 1 0
95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0
1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5
120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0
67-S6-3460-00-4
Chloroform P-Bromafluorobenzene
u JBT 0 7 4 56
1 0 0 5 0 0 50
2199-69-1 12-Dichlorobenzene-D4 6 4
Page 01 o f 01 F8B38D
AdjMDL 0 2 0 0 13 D13 0 1 1
0 22 0 13 0 13 0 13 0 14 0 24
0 1 0 0 34
Q2S
0 1 2
Sample Data Summary A0000004
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY
PO Na Sample Date 091305 Received Date 091505
Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA
Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1
CAS Compound Flags Results DF PQL ampdjPQL
75-01-4 Vinyl chloride U 050 10 050 050
75-35-4 11-Dichloroethene n 050 10 050 050
71-55-679-01-6
If1J1-Trichlaraethane Trichioroethene
u u 3 050
050
10
10
050
D50
050
050
75-09-2 Methylene Chloride n 050 10 050 05O
156-59-2 cis-l2-Dichloroethene D 050 10 050 050
15G-S0-5 trans-12-Dichloroethene D 050 10 050 050
7B-87-5 12-Dichloropropane a 050 10 050 050
127-10-4 Tetrachloroethene D 050 10 050 050
m+p-xylenes O 10 10 10 10
95-47-6 o-Xylena D 050 10 050 050
133D-20-7 Xylenes (total) U 15 10 15 15
120-82-1 124-Trichlorobenzene u 050 10 050 050
67-66-3 Chloroform u 050 10 050 050
460-00-4 P-Brotnofluorobenzene Bl
2199-69-1 12-Dichlorobenzene-D4 65
Page 01 Of 01 F8783D
Adj MD]
020
013
013
011
022
013
013
013
014
024
010
034
026
012
Sample Data Summary A0000005
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
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EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
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EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
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A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
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A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
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Walcr Spit 35-lTT23120_
40-110
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Walcr Soil IU-11U 21-113
15-115
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nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
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Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
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Advisory Surrogates - OLM032
Validator
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EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
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Validator ^ J IJ^J ^^JfiAjLuiati_ shy
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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
WOODARD ampCURRAN Engineering bull Science bull Operations
Data Validation
The validation report indicates that chloroform was detected in one of the method blanks associated with the selected September 2005 samples indicating potential low level false positive concentrations of this compound in associated samples As a result concentrations of chloroform in associated samples below a calculated action level were qualified as non-detect Non-compliant continuing calibration results were reported for 111-trichloroethane and 11-dichloroethene resulting in qualification of positive and non-detect concentrations of these compounds in associated samples as estimated In addition non-compliant methylene chloride results were reported in one laboratory control sample therefore positive and non-detect methylene chloride results in associated samples were qualified as estimated Overall the results of the validation concluded that the data are of good quality and are suitable for their intended use
Summary
The September 2005 sampling event was completed on September 13 2005 and consisted of sampling the residences designated for quarterly sampling Woodard amp Curran Inc completed the sampling The next monitoring event is scheduled to take place in December 2005 and will consist of monitoring locations designated for quarterly sampling
If you have any questions regarding the enclosed materials or sampling program please contact me af (207)685-7333
Sincerely
WOODARD amp CURRAN INC
^-^-lffvlt^i-~ ^ ^ ^ t _ - ^ - o u _
Florence L Clauson Project Chemist
20529706 Enclosures
ex Rebecca Hewett MRDEP Mark Beliveau Pierce Atvvood
205279069_05summary reportdoc
Table 1 Summary of Quarterly Sampling Results
Residential Tap Water Program Plymouth Maine
PARAMETER (ugl)
Chloroform
11-Dichloroethene
cis-12-Dichloroethene
trans-12-Dichloroethene
12-Dichloropropane
Methylene chloride
Tetrachloroethene
124-Trichlorobenzene
111-Trichloroethane
Trichloroethene
Vinyl chloride
mp-Xylenes
o-Xylene
Xylenes (total)
WELL SAMPLE ID DATE
RESULT TYPE
LOT7 WSHC(7)MELANSON 091405 Primary
9
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
LOT8-1 WSHC8-1)FOSS 091305 Primary
lt059U
lt05
lt05
lt05
lt05
lt05
lt05
lt0S
lt05
lt05
lt05
lt1
lt05
lt15
LOT8-1 WSHC(8-1)FOSS DUP 091305 Duplicate 1
lt074U
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
LOT11-1 WSHC(11-1)GO 091305 Primary
lt05
lt 0 5
lt05
lt05
lt05
lt05
lt05 shy
lt05
lt05J
lt05
lt05
lt1
lt05
lt15
lt = Not detected at indicated reporting limit
J = Estimated U bull Result revised to non-detected due to blank contamination
qjartmonxls995037
PARAMETER (ugl)
Chloroform
11-Dichloroethene
cis-12-Dichloroethene
trans-12-Dichloroethene
12-Dtchloropropane
Methylene chloride
Tetrachtoroethene
124-Trichlorobenzene
111-Trichloroethane
Trichloroethene
Vinyl chloride
mp-Xylenes
o-Xylene
Xylenes (total)
WELL SAMPLE ID DATE RESULT TYPE
LOT11-3 WSHC(1t-3gtDERAPS 091305 Primary
lt05
lt05J
lt05
lt05
lt05
lt05J
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
Table 1 Summary of Quarterly Sampling Results
Residential Tap Water Program Plymouth Maine
LOTH-4 LOT21-16 WSHC(11-4)SAWYER WSHC(21 -16JLEVESQUE
091305 091305
Primary Primary
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05J lt05J
lt05 lt05
lt05 lt05
lt1 lt1
lt05 lt05
lt15 lt15
LOT31 WSHC(31)GHO 091305 Primary
lt05
lt05J
lt05
lt05
lt05
lt05J
bull=05
lt05
lt05
lt05
lt05
lt1
lt05
ltia
lt - Not detected at indicated reporting limit
J = Estimated U = Result revised to non-detected due to blank contamination
quartmon xlS995037
WOODARDampCURRAN Engineering gt Science bull Operations
bulli
LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05summary reportdoc
_
Llt ID laquo V lt 7 7 9 Sample Date- o s -
Dat 9
Qiydegse ^ t r a c t e d b y
f r a c t i o n Methn Ana lys i s flate 1153
W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo
Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP
7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e
0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13
0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a
05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50
0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013
degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013
Xylenes ( t o t a l ) cr 10 1 0 10 05Q
0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S
D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l
012 64
Page 01 0 f 0 1 P8B3 7
Sample natQ o_
KATAHDIH ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Project HOWS CORNER QUARTERLY
PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA
Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1
CAS Compound F l a g s Results DF PQL Adj PQL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0
75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0
71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0
79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0
75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0
156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0
15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50
78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0
127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0
m+p-Xylenes c 1 0 1 0 1 0 1 0
95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0
1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5
120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0
67-S6-3460-00-4
Chloroform P-Bromafluorobenzene
u JBT 0 7 4 56
1 0 0 5 0 0 50
2199-69-1 12-Dichlorobenzene-D4 6 4
Page 01 o f 01 F8B38D
AdjMDL 0 2 0 0 13 D13 0 1 1
0 22 0 13 0 13 0 13 0 14 0 24
0 1 0 0 34
Q2S
0 1 2
Sample Data Summary A0000004
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY
PO Na Sample Date 091305 Received Date 091505
Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA
Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1
CAS Compound Flags Results DF PQL ampdjPQL
75-01-4 Vinyl chloride U 050 10 050 050
75-35-4 11-Dichloroethene n 050 10 050 050
71-55-679-01-6
If1J1-Trichlaraethane Trichioroethene
u u 3 050
050
10
10
050
D50
050
050
75-09-2 Methylene Chloride n 050 10 050 05O
156-59-2 cis-l2-Dichloroethene D 050 10 050 050
15G-S0-5 trans-12-Dichloroethene D 050 10 050 050
7B-87-5 12-Dichloropropane a 050 10 050 050
127-10-4 Tetrachloroethene D 050 10 050 050
m+p-xylenes O 10 10 10 10
95-47-6 o-Xylena D 050 10 050 050
133D-20-7 Xylenes (total) U 15 10 15 15
120-82-1 124-Trichlorobenzene u 050 10 050 050
67-66-3 Chloroform u 050 10 050 050
460-00-4 P-Brotnofluorobenzene Bl
2199-69-1 12-Dichlorobenzene-D4 65
Page 01 Of 01 F8783D
Adj MD]
020
013
013
011
022
013
013
013
014
024
010
034
026
012
Sample Data Summary A0000005
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
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Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
Table 1 Summary of Quarterly Sampling Results
Residential Tap Water Program Plymouth Maine
PARAMETER (ugl)
Chloroform
11-Dichloroethene
cis-12-Dichloroethene
trans-12-Dichloroethene
12-Dichloropropane
Methylene chloride
Tetrachloroethene
124-Trichlorobenzene
111-Trichloroethane
Trichloroethene
Vinyl chloride
mp-Xylenes
o-Xylene
Xylenes (total)
WELL SAMPLE ID DATE
RESULT TYPE
LOT7 WSHC(7)MELANSON 091405 Primary
9
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
LOT8-1 WSHC8-1)FOSS 091305 Primary
lt059U
lt05
lt05
lt05
lt05
lt05
lt05
lt0S
lt05
lt05
lt05
lt1
lt05
lt15
LOT8-1 WSHC(8-1)FOSS DUP 091305 Duplicate 1
lt074U
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
LOT11-1 WSHC(11-1)GO 091305 Primary
lt05
lt 0 5
lt05
lt05
lt05
lt05
lt05 shy
lt05
lt05J
lt05
lt05
lt1
lt05
lt15
lt = Not detected at indicated reporting limit
J = Estimated U bull Result revised to non-detected due to blank contamination
qjartmonxls995037
PARAMETER (ugl)
Chloroform
11-Dichloroethene
cis-12-Dichloroethene
trans-12-Dichloroethene
12-Dtchloropropane
Methylene chloride
Tetrachtoroethene
124-Trichlorobenzene
111-Trichloroethane
Trichloroethene
Vinyl chloride
mp-Xylenes
o-Xylene
Xylenes (total)
WELL SAMPLE ID DATE RESULT TYPE
LOT11-3 WSHC(1t-3gtDERAPS 091305 Primary
lt05
lt05J
lt05
lt05
lt05
lt05J
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
Table 1 Summary of Quarterly Sampling Results
Residential Tap Water Program Plymouth Maine
LOTH-4 LOT21-16 WSHC(11-4)SAWYER WSHC(21 -16JLEVESQUE
091305 091305
Primary Primary
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05J lt05J
lt05 lt05
lt05 lt05
lt1 lt1
lt05 lt05
lt15 lt15
LOT31 WSHC(31)GHO 091305 Primary
lt05
lt05J
lt05
lt05
lt05
lt05J
bull=05
lt05
lt05
lt05
lt05
lt1
lt05
ltia
lt - Not detected at indicated reporting limit
J = Estimated U = Result revised to non-detected due to blank contamination
quartmon xlS995037
WOODARDampCURRAN Engineering gt Science bull Operations
bulli
LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05summary reportdoc
_
Llt ID laquo V lt 7 7 9 Sample Date- o s -
Dat 9
Qiydegse ^ t r a c t e d b y
f r a c t i o n Methn Ana lys i s flate 1153
W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo
Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP
7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e
0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13
0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a
05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50
0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013
degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013
Xylenes ( t o t a l ) cr 10 1 0 10 05Q
0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S
D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l
012 64
Page 01 0 f 0 1 P8B3 7
Sample natQ o_
KATAHDIH ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Project HOWS CORNER QUARTERLY
PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA
Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1
CAS Compound F l a g s Results DF PQL Adj PQL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0
75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0
71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0
79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0
75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0
156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0
15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50
78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0
127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0
m+p-Xylenes c 1 0 1 0 1 0 1 0
95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0
1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5
120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0
67-S6-3460-00-4
Chloroform P-Bromafluorobenzene
u JBT 0 7 4 56
1 0 0 5 0 0 50
2199-69-1 12-Dichlorobenzene-D4 6 4
Page 01 o f 01 F8B38D
AdjMDL 0 2 0 0 13 D13 0 1 1
0 22 0 13 0 13 0 13 0 14 0 24
0 1 0 0 34
Q2S
0 1 2
Sample Data Summary A0000004
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY
PO Na Sample Date 091305 Received Date 091505
Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA
Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1
CAS Compound Flags Results DF PQL ampdjPQL
75-01-4 Vinyl chloride U 050 10 050 050
75-35-4 11-Dichloroethene n 050 10 050 050
71-55-679-01-6
If1J1-Trichlaraethane Trichioroethene
u u 3 050
050
10
10
050
D50
050
050
75-09-2 Methylene Chloride n 050 10 050 05O
156-59-2 cis-l2-Dichloroethene D 050 10 050 050
15G-S0-5 trans-12-Dichloroethene D 050 10 050 050
7B-87-5 12-Dichloropropane a 050 10 050 050
127-10-4 Tetrachloroethene D 050 10 050 050
m+p-xylenes O 10 10 10 10
95-47-6 o-Xylena D 050 10 050 050
133D-20-7 Xylenes (total) U 15 10 15 15
120-82-1 124-Trichlorobenzene u 050 10 050 050
67-66-3 Chloroform u 050 10 050 050
460-00-4 P-Brotnofluorobenzene Bl
2199-69-1 12-Dichlorobenzene-D4 65
Page 01 Of 01 F8783D
Adj MD]
020
013
013
011
022
013
013
013
014
024
010
034
026
012
Sample Data Summary A0000005
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
PARAMETER (ugl)
Chloroform
11-Dichloroethene
cis-12-Dichloroethene
trans-12-Dichloroethene
12-Dtchloropropane
Methylene chloride
Tetrachtoroethene
124-Trichlorobenzene
111-Trichloroethane
Trichloroethene
Vinyl chloride
mp-Xylenes
o-Xylene
Xylenes (total)
WELL SAMPLE ID DATE RESULT TYPE
LOT11-3 WSHC(1t-3gtDERAPS 091305 Primary
lt05
lt05J
lt05
lt05
lt05
lt05J
lt05
lt05
lt05
lt05
lt05
lt1
lt05
lt15
Table 1 Summary of Quarterly Sampling Results
Residential Tap Water Program Plymouth Maine
LOTH-4 LOT21-16 WSHC(11-4)SAWYER WSHC(21 -16JLEVESQUE
091305 091305
Primary Primary
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05 lt05
lt05J lt05J
lt05 lt05
lt05 lt05
lt1 lt1
lt05 lt05
lt15 lt15
LOT31 WSHC(31)GHO 091305 Primary
lt05
lt05J
lt05
lt05
lt05
lt05J
bull=05
lt05
lt05
lt05
lt05
lt1
lt05
ltia
lt - Not detected at indicated reporting limit
J = Estimated U = Result revised to non-detected due to blank contamination
quartmon xlS995037
WOODARDampCURRAN Engineering gt Science bull Operations
bulli
LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05summary reportdoc
_
Llt ID laquo V lt 7 7 9 Sample Date- o s -
Dat 9
Qiydegse ^ t r a c t e d b y
f r a c t i o n Methn Ana lys i s flate 1153
W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo
Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP
7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e
0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13
0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a
05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50
0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013
degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013
Xylenes ( t o t a l ) cr 10 1 0 10 05Q
0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S
D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l
012 64
Page 01 0 f 0 1 P8B3 7
Sample natQ o_
KATAHDIH ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Project HOWS CORNER QUARTERLY
PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA
Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1
CAS Compound F l a g s Results DF PQL Adj PQL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0
75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0
71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0
79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0
75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0
156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0
15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50
78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0
127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0
m+p-Xylenes c 1 0 1 0 1 0 1 0
95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0
1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5
120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0
67-S6-3460-00-4
Chloroform P-Bromafluorobenzene
u JBT 0 7 4 56
1 0 0 5 0 0 50
2199-69-1 12-Dichlorobenzene-D4 6 4
Page 01 o f 01 F8B38D
AdjMDL 0 2 0 0 13 D13 0 1 1
0 22 0 13 0 13 0 13 0 14 0 24
0 1 0 0 34
Q2S
0 1 2
Sample Data Summary A0000004
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY
PO Na Sample Date 091305 Received Date 091505
Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA
Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1
CAS Compound Flags Results DF PQL ampdjPQL
75-01-4 Vinyl chloride U 050 10 050 050
75-35-4 11-Dichloroethene n 050 10 050 050
71-55-679-01-6
If1J1-Trichlaraethane Trichioroethene
u u 3 050
050
10
10
050
D50
050
050
75-09-2 Methylene Chloride n 050 10 050 05O
156-59-2 cis-l2-Dichloroethene D 050 10 050 050
15G-S0-5 trans-12-Dichloroethene D 050 10 050 050
7B-87-5 12-Dichloropropane a 050 10 050 050
127-10-4 Tetrachloroethene D 050 10 050 050
m+p-xylenes O 10 10 10 10
95-47-6 o-Xylena D 050 10 050 050
133D-20-7 Xylenes (total) U 15 10 15 15
120-82-1 124-Trichlorobenzene u 050 10 050 050
67-66-3 Chloroform u 050 10 050 050
460-00-4 P-Brotnofluorobenzene Bl
2199-69-1 12-Dichlorobenzene-D4 65
Page 01 Of 01 F8783D
Adj MD]
020
013
013
011
022
013
013
013
014
024
010
034
026
012
Sample Data Summary A0000005
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
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Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
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The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
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Sampling variability is not assessed in data validation
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Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
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EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
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EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
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Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
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Comments
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Percent Rclntlve
QC Limits
Sniiiplcs
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Comments i
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If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
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BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
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Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
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EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
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Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
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EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
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Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
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EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
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M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
WOODARDampCURRAN Engineering gt Science bull Operations
bulli
LABORATORY ANALYTICAL RESULTS RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05summary reportdoc
_
Llt ID laquo V lt 7 7 9 Sample Date- o s -
Dat 9
Qiydegse ^ t r a c t e d b y
f r a c t i o n Methn Ana lys i s flate 1153
W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo
Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP
7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e
0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13
0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a
05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50
0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013
degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013
Xylenes ( t o t a l ) cr 10 1 0 10 05Q
0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S
D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l
012 64
Page 01 0 f 0 1 P8B3 7
Sample natQ o_
KATAHDIH ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Project HOWS CORNER QUARTERLY
PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA
Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1
CAS Compound F l a g s Results DF PQL Adj PQL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0
75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0
71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0
79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0
75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0
156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0
15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50
78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0
127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0
m+p-Xylenes c 1 0 1 0 1 0 1 0
95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0
1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5
120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0
67-S6-3460-00-4
Chloroform P-Bromafluorobenzene
u JBT 0 7 4 56
1 0 0 5 0 0 50
2199-69-1 12-Dichlorobenzene-D4 6 4
Page 01 o f 01 F8B38D
AdjMDL 0 2 0 0 13 D13 0 1 1
0 22 0 13 0 13 0 13 0 14 0 24
0 1 0 0 34
Q2S
0 1 2
Sample Data Summary A0000004
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY
PO Na Sample Date 091305 Received Date 091505
Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA
Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1
CAS Compound Flags Results DF PQL ampdjPQL
75-01-4 Vinyl chloride U 050 10 050 050
75-35-4 11-Dichloroethene n 050 10 050 050
71-55-679-01-6
If1J1-Trichlaraethane Trichioroethene
u u 3 050
050
10
10
050
D50
050
050
75-09-2 Methylene Chloride n 050 10 050 05O
156-59-2 cis-l2-Dichloroethene D 050 10 050 050
15G-S0-5 trans-12-Dichloroethene D 050 10 050 050
7B-87-5 12-Dichloropropane a 050 10 050 050
127-10-4 Tetrachloroethene D 050 10 050 050
m+p-xylenes O 10 10 10 10
95-47-6 o-Xylena D 050 10 050 050
133D-20-7 Xylenes (total) U 15 10 15 15
120-82-1 124-Trichlorobenzene u 050 10 050 050
67-66-3 Chloroform u 050 10 050 050
460-00-4 P-Brotnofluorobenzene Bl
2199-69-1 12-Dichlorobenzene-D4 65
Page 01 Of 01 F8783D
Adj MD]
020
013
013
011
022
013
013
013
014
024
010
034
026
012
Sample Data Summary A0000005
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
_
Llt ID laquo V lt 7 7 9 Sample Date- o s -
Dat 9
Qiydegse ^ t r a c t e d b y
f r a c t i o n Methn Ana lys i s flate 1153
W A r E R deg 9 2 8 2 O 0 s Analys is MethrH M ^ i L a b P r e p trade d = S P A S 2 4 3 S o l i d s WA ^ts ^ r C h bullraquobulllaquo
Compound 75 -Ol - i V i laquo y l c h l o r i d e raquo F l a g s 75-35-4 R e s u l t s l - 5 5 - S ^ - I gt i C h l o r o e t l l a i i e rr DP
7 S - 0 l - S 8 0 5 0 1-0 pound laquobullbulllaquo K M 0 5 0 T r i c h l ^ D e t i i e n e
0 5 0 0 5 0 7 5 - D g - 2 tJ 1 0 0 2 0 0 5 0 0 5 0 0 5 0 156-592 17 1 -0 0 13 O50 0 5 0 OSQ 15S-60-5 ff 1 0 O50 0 13
0 5 0 0 5 0 D 1 078-B7-5 0 5 0 0 1 1 0 5 0 0 5 0 1 01 2 7 - I H ^ O 0 2 2 0 5 0 0 50 T e t laquo c h l o t o e t h e n e 1 a
05D m + P ^ 7 i a n e 3 0 5 0 0 5 0 0-50
0 13 9 S - 4 7 - g cr 1 -0 0 5 0 013
degXylene u 0 5 0 I 0 0 5 0 3 0 - 2 0 - 7 0 5 0 013
Xylenes ( t o t a l ) cr 10 1 0 10 05Q
0 14 10 0 5 0 D 1 0 57-ES-3 O50 0 2 4 D50 1-5 I 0 4 G 0 - 0 Q - 4 O l o 1 5 15 0 5 0 i 02195-59- 0 5 0 0 34 0 50 0-5S
D 4 0 5 0 0 50 oas D l C h l o ^ e n 2 e n e - 1 0 B l l
012 64
Page 01 0 f 0 1 P8B3 7
Sample natQ o_
KATAHDIH ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Project HOWS CORNER QUARTERLY
PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA
Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1
CAS Compound F l a g s Results DF PQL Adj PQL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0
75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0
71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0
79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0
75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0
156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0
15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50
78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0
127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0
m+p-Xylenes c 1 0 1 0 1 0 1 0
95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0
1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5
120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0
67-S6-3460-00-4
Chloroform P-Bromafluorobenzene
u JBT 0 7 4 56
1 0 0 5 0 0 50
2199-69-1 12-Dichlorobenzene-D4 6 4
Page 01 o f 01 F8B38D
AdjMDL 0 2 0 0 13 D13 0 1 1
0 22 0 13 0 13 0 13 0 14 0 24
0 1 0 0 34
Q2S
0 1 2
Sample Data Summary A0000004
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY
PO Na Sample Date 091305 Received Date 091505
Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA
Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1
CAS Compound Flags Results DF PQL ampdjPQL
75-01-4 Vinyl chloride U 050 10 050 050
75-35-4 11-Dichloroethene n 050 10 050 050
71-55-679-01-6
If1J1-Trichlaraethane Trichioroethene
u u 3 050
050
10
10
050
D50
050
050
75-09-2 Methylene Chloride n 050 10 050 05O
156-59-2 cis-l2-Dichloroethene D 050 10 050 050
15G-S0-5 trans-12-Dichloroethene D 050 10 050 050
7B-87-5 12-Dichloropropane a 050 10 050 050
127-10-4 Tetrachloroethene D 050 10 050 050
m+p-xylenes O 10 10 10 10
95-47-6 o-Xylena D 050 10 050 050
133D-20-7 Xylenes (total) U 15 10 15 15
120-82-1 124-Trichlorobenzene u 050 10 050 050
67-66-3 Chloroform u 050 10 050 050
460-00-4 P-Brotnofluorobenzene Bl
2199-69-1 12-Dichlorobenzene-D4 65
Page 01 Of 01 F8783D
Adj MD]
020
013
013
011
022
013
013
013
014
024
010
034
026
012
Sample Data Summary A0000005
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
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Comments
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A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
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Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIH ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Project HOWS CORNER QUARTERLY
PO NO Sample Date 091305 Received Date 031505 Extraction Date Analysis Date 27-SEP-2005 1235 Report Date 092B2005 Matrix WATER S o l i d s NA
Lab ID WV4779-2RA3 Cl ien t TD WSHC(B-l)FOSSDUP SDG W4779 E x t r ac t ed by E x t r a c t i o n Method SW84S 5030 Analys t SKT Analysis Method EPA 5242 Lab Prep Batch WG21015 Units ug1
CAS Compound F l a g s Results DF PQL Adj PQL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 O 5 0
75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 5 0
71-55-5 111-Trichloroethane a 0 5 0 1 0 0 5 0 0 5 0
79-01-S Trichlaroethene S 0-50 1 0 0 5 0 0 5 0
75-09-2 Methylene Chloride a 0 5 0 1 0 0 5 0 0 5 0
156-59-2 cis-12-Dichloroethene B 0 5 0 1 0 0 5 0 0 5 0
15G-60-5 trans-12-Dichloroethene 0 0 5 0 1 0 0 5 0 0_50
78-87-5 12-Dichloropropane u 0 5 0 1 0 0 5 0 0 5 0
127-18-4 Tetrachloroethene U 0 5 0 l G 0 5 0 0 5 0
m+p-Xylenes c 1 0 1 0 1 0 1 0
95-47-G u-Xylene 6 0 5 0 1 0 0 5 0 0 5 0
1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5
120-B2-1 124-Trichlorobenzene U 05D 1 0 0 5 0 0 5 0
67-S6-3460-00-4
Chloroform P-Bromafluorobenzene
u JBT 0 7 4 56
1 0 0 5 0 0 50
2199-69-1 12-Dichlorobenzene-D4 6 4
Page 01 o f 01 F8B38D
AdjMDL 0 2 0 0 13 D13 0 1 1
0 22 0 13 0 13 0 13 0 14 0 24
0 1 0 0 34
Q2S
0 1 2
Sample Data Summary A0000004
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY
PO Na Sample Date 091305 Received Date 091505
Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA
Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1
CAS Compound Flags Results DF PQL ampdjPQL
75-01-4 Vinyl chloride U 050 10 050 050
75-35-4 11-Dichloroethene n 050 10 050 050
71-55-679-01-6
If1J1-Trichlaraethane Trichioroethene
u u 3 050
050
10
10
050
D50
050
050
75-09-2 Methylene Chloride n 050 10 050 05O
156-59-2 cis-l2-Dichloroethene D 050 10 050 050
15G-S0-5 trans-12-Dichloroethene D 050 10 050 050
7B-87-5 12-Dichloropropane a 050 10 050 050
127-10-4 Tetrachloroethene D 050 10 050 050
m+p-xylenes O 10 10 10 10
95-47-6 o-Xylena D 050 10 050 050
133D-20-7 Xylenes (total) U 15 10 15 15
120-82-1 124-Trichlorobenzene u 050 10 050 050
67-66-3 Chloroform u 050 10 050 050
460-00-4 P-Brotnofluorobenzene Bl
2199-69-1 12-Dichlorobenzene-D4 65
Page 01 Of 01 F8783D
Adj MD]
020
013
013
011
022
013
013
013
014
024
010
034
026
012
Sample Data Summary A0000005
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n P r o j e c t HOWS CORNER QUARTERLY
PO Na Sample Date 091305 Received Date 091505
Extraction Date Analysis Date 21-SEP-2005 1613 Report Date 09282005 Matrix WATER Solids NA
Lab ID WV4779-3RA Client ID WSHC(3G)NORRIS SDG WV4779 Extracted by Extraction Method SW346 5030 Analyst SKT Analysis Method EPA 524_2 Lab Prep Batch WG20B19 units ug1
CAS Compound Flags Results DF PQL ampdjPQL
75-01-4 Vinyl chloride U 050 10 050 050
75-35-4 11-Dichloroethene n 050 10 050 050
71-55-679-01-6
If1J1-Trichlaraethane Trichioroethene
u u 3 050
050
10
10
050
D50
050
050
75-09-2 Methylene Chloride n 050 10 050 05O
156-59-2 cis-l2-Dichloroethene D 050 10 050 050
15G-S0-5 trans-12-Dichloroethene D 050 10 050 050
7B-87-5 12-Dichloropropane a 050 10 050 050
127-10-4 Tetrachloroethene D 050 10 050 050
m+p-xylenes O 10 10 10 10
95-47-6 o-Xylena D 050 10 050 050
133D-20-7 Xylenes (total) U 15 10 15 15
120-82-1 124-Trichlorobenzene u 050 10 050 050
67-66-3 Chloroform u 050 10 050 050
460-00-4 P-Brotnofluorobenzene Bl
2199-69-1 12-Dichlorobenzene-D4 65
Page 01 Of 01 F8783D
Adj MD]
020
013
013
011
022
013
013
013
014
024
010
034
026
012
Sample Data Summary A0000005
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
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Comments
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A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
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Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
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Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard 1 Curran Lab ID WV4779-4RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-2)WAED PO NO SDG WV4 779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB46 5 03 0 Extraction Date Analyst SET Analysis Date 21-SEP-2005 1656 Analys is Method EPA 5242 Report Date 09282005 Lab Prep Ba tch WG20819 Matrix WATER U n i t s u g 1 Solids HA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjHEL
75-01-4 Vinyl chloride U 0 5 0 1 0 0 5 0 bull 50 0 2 0 75-35-4 11-Dichloroethene a 0 5 0 1 0 0 5 0 050 013 71-55-6 111-Trichloroe thane n 7 0 5 0 1 0 0 5 0 050 0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 050 0 1 1 75-09-2 Methylene Chloride n 0 5 0 1 0 0 5 0 0 50 0 22 156-59-2 cis-i2-Dichloroetlxene ti 0 5 0 1 0 0 5 0 0 50 0 13 156-60-5 trans-1 2-Dichloroethene u 05D 1 0 0 5 0 0 50 0 13 7B-87-5 12-Dichloroprcpane 5 05O 1 0 0 5 0 0 50 0 13 127-18-4 Tetrachloroethene u 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes s 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene n 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene u 0 5 0 1 0 0 5 0 0 50 0 2 6 67-66-3 Chloroform o 0 5 0 1 0 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzane 2199-69-1 12-Dichlorobenzene-D4 64
Page 01 of 01 F8764D
Sample Data Summary A0000006
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
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THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
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KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lab ID WV4779-5RA P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(ll-l)GODSOE PO N o SDG WV4779 Sample Date D91305 Extracted by Received Date 091505 Extraction Method EWH46 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 173B A n a l y s i s Method EPA 5 2 4 2 Report Date 09282005 Lab P r e p B a t c h WS2DB19 Matrix WATER U n i t s uc j 1 Solids NA
CAS Compound Flags Results DF PQL AdjPQL AdjMD 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-4 1l-Dichloroethene V 050 10 050 050 013 71-55-S 111-Trichloroethane U J 05O 10 050 050 013 79-01-G Trichloroethene u OSO 10 050 O50 011 75-09-2 Methylene Chloride u 050 10 050 050 022 156-59-2 cis-l2-Dichloroethene u 050 10 050 050 013 156-60-5 trans-12-Dichloroethene tJ 050 10 D50 05D 013 7B-S7-S 12-Dichloropropane B 050 10 050 050 013 127-IB-4 Tetrachloroethene U 050 10 050 050 014
rn+p-Xylenes u 10 10 10 10 024 95-4 7-6 o-Xylene tr 050 10 OSO 050 01O 1330-20-7 Xylenes (total) V 15 10 15 15 034 120-B2-1 124-Trichlarobenzene n 050 10 050 050 026 67-6G-3 Chloroform 0 050 10 050 050 012 460-0O-4 P shy Bromofluorobenzene 73 219 9-69-1 12-Dichlorohenzene-D4 69V
Page 01 Of 01 F87B5D
Sample Data Summary A0000007
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard t Curran Lata ID W4779-6RA Project HOWS CORKER QUARTERLY Cl ien t ID WSHCOUKNIGHT PO No SDG WV4779 Sample Date 091305 E x t r ac t ed by Received Date 051505 E x t r a c t i o n Method SW846 5030 Extraction Date Analys t SKT Analysis Date 21-SEP-2005 1G21 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2D819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound Flags Results DF PQL AdjPQL AdjMDL 75-01-4 Vinyl chloride U 050 10 050 050 020 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u o J
05D
O50
10
10
05O
050
050
050
013
013 79-01-6 Trichloroethene u 050 10 050 050 011 75-05-2 Methylene Chloride a 050 10 050 050 022 156-5 9-2 cis-l2-Dichloroethene o 05O 10 050 050 013 156-G0-5 crans-l2-Dichloroethene D 050 10 050 050 013 7 B- 87 shy 5 12-Dichloroprapane 8 050 10 050 050 013 127-18-4 Tetrachloroethane D 050 10 050 050 014
m+p- Xylenes D 10 10 10 10 024 95-47-S o-Xylene D 050 10 050 050 010 133 0-20-7 Xylenes (total) U 15 10 15 15 034 12 0-H2-1 124-Trichlorobenzene II 050 1-0 05O 050 026 67-66-3 Chloroform IT 050 10 050 050 012 4S0-Q0-4 P-Bromofluorabenzene 66 2199-69-1 l2-Dichlorobenzene-D4 64
Page 01 of 01 F8786D
Sample Data Summary A0O00OOS
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
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Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-7RA2 Project SOWS CORNER QUARTERLY C l i e n t I D WSHC(31)GHOPKINS PO No SDG WV4779 Sample Date 091305 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SW846 503Q Extraction Date A n a l y s t SKT Analysis Date 22-SEP-2005 1538 Analysis Method EPA 5242 Report Date 09283005 Lab Prep Batch WH2C897 Matrix WATER Units ug1 S o l i d s KTA
CAS Compound F l a g s R e s u l t s DF PQL AdjPQL AdjMDL
75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 50 0 20 75-35-471-55-6
11-Dichloroethene 111-Trichloroethane
u c J O50
0 5 0 1 0
1 0
0 5 0
0 5 0 bull 50 D50
0 13
0 13 79-01-6 Trichloroethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2156-59-2
Methylene Chloride cis-12-Dichloroethene
u D or 0 5 0
0 5 0 1 0
1 0
0 5 0 OSO
O50 05D
0 22 0 13
156-60-5 trans-1 2-Dichloroethene O 0 5 0 1 0 0 5 0 0 50 0 13 78-87-5 12-Dichloropropane D 0 5 0 1 0 0 5 0 0 50 0 13 127-1B-4 Tetrachloroethene D 0 5 0 1 0 0 5 0 0 50 0 14
m+p-Xylenes 0 1 0 1 0 1 0 1 0 0 24 95-47-6 o-Xylene 0 0 5 0 1 0 0 5 0 0 50 0 10 1330-20-7 Xylenes (total) D 1 5 1 0 1 5 1 5 0 34 120-82-1 124-Trichlorobenzene 0 0 5 0 l Q 0 5 0 0 50 0 26 S7-SG-3 Chloroform D 0 5 0 l D 0 5 0 0 50 0 12 460-00-4 P-Bromofluorobenzene 60 2199-69-1 12-Dichlorobenzene-D4 5 7
Page 01 of 01 F8B01D
Sample Data Summary A0000009
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
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Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
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EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
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EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
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V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
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A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
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Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
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Oilier
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Advisory Surrogates - OLM032
Validator
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EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
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Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
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EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
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SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
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A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-8RA Project HOWS CORNER QUARTERLY Client ID WSHC(32-2)GHAKES PO No bull SDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SWB4G 5030 Extraction Date Analyst SKT Analysis Date 21-SEP-2005 194G Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG2G819 Matrix WATER Units ug1 Solids HA
CAS Compound F l a g s R e s u l t s D PQL AdjPQL AdjjMDL 7 5 - 0 1 - 4 V i n y l c h l o r i d e U D50 10 0 5 0 0 5 0 0 2 0 7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e U O50 10 0 5 0 CS0 0 1 3 7 1 - 5 5 - e 1 1 1 - T r i c h l o r o e t h a n e U J 0 5 0 10 0 5 0 D50 0 1 3 7 9 - 0 1 - S T r i c h l o r o e t h e n e D 0 5 0 10 0 5 0 0 5 0 0 1 1 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e U O50 1 0 0 5 0 0 5 0 0 2 2 1 5 6 - 5 9 - 2 c i s - l 2 - D i c h l D r o e t b e n e U O-50 1 0 0 5 0 0 5 0 0 1 3 1 5 6 - 6 0 - 5 t r a n s - 1 2 - D i c h l o r o e t h e n e U 0 5 0 10 0 5 0 0 5 0 0 1 3 7B-B7-5 1 2 - D i c h l o r o p r o p a n e V 0 5 0 10 0 5 0 0 5 0 0 1 3 1 2 7 - 1 8 - 4 T e t r a c h l o r o e t h e n e J 0 2 8 10 0 5 0 0 5 0 0 1 4
m+p-Xy lenes U 1 0 10 10 10 0 2 4 9 5 - 4 7 - 6 D-Xylene n o5o i o 0 5 0 0 5 0 0 1 0 133 0-20-7 X y l e n e s ( t o t a l ) D 15 10 15 15 0 3 4 1 2 0 - B 2 - 1 1 2 4 - T r i c h l o r o b e n z e n e U 0 5 0 1 0 0 5 0 0 5 0 Q2S 6 7 - 6 6 - 3 C h l o r o f o r m U 0 5 0 10 05O 0_50 0 1 2 4 6 0 - 0 0 - 4 P - B r o m o f l u o r o b e n z e n e 70 219 9 -69 -1 l 2 - D i c h l o r o b e n z e n e - D 4 62
Page 01 c f 01 F 8 7 a 8 D
Sample Data Summary A0000010
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
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Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
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Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
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EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
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II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
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Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
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BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
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List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
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V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
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A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
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EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
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15-115
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nnclgtNMHml Method QC Acceptance CrUcrln
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Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
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EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
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Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
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EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
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Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
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VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
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SDG No
Arc tnorc
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than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
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A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab ID WV4779-9RA3 P r o j e c t HOWS CORNER QUARTERLY Client ID WSHC(B3-1)GRAY PO N O EDG WV4779 Sample Date 091305 Extracted by Received Date 091505 Extraction Method SW846 5030 Extraction Date Analyst SKT Analysis Date 27-SEP-2005 1318 Analysis Method EPA 5242 Report Date 09282005 Lab Prep Batch WG21015 Matrix WATER TJnits ug1 Solids NA
CAS Compound Flags Results DP PQL AdjPQL AdjHDL 75-01-4 vinyl chloride n 050 10 050 050 0 20 75-35-4 11-Dichloroethene U OSO 10 D50 050 013 71-55-5 111-Trichloroethane 0 Q5D 10 D50 050 bull 13 7 9-01-S Trichloroethene u 050 10 050 050 bull 11 75-09-2 Methylene Chloride u 050 10 050 050 a 22 155-59-2 cis-l2-Dichloroethene -J 050 10 05O 050 013 ISS-SO-5 trans-12-Dichloroethene -J 050 10 05O 050 013 7B-B7-5 12-Dichloropropane - 050 10 Q50 050 013 127-IE-4 Tetrachloroethene D 050 10 D50 050 014
tn+p-Xylenes u 10 10 10 10 024 95-47-5 o-Xylene D 050 10 bull 50 05O 010 1330-20-7 Xylenes (total) B 15 10 15 15 034 120-82-1 124-Trichlorobenzene e 050 10 bull 50 050 026 67-66-3 Chloroform 8 050 10 050 aso 012 4S0-0O-4 P-Bromofluorobenzene 84
2199-69-1 l2-Dichlorobenzene-D4 65
Page 01 Of 01 FSB3 9D
Sample Data Summary A0000011
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
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Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
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EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
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EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
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V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
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A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
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Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
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Oilier
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Advisory Surrogates - OLM032
Validator
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EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
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Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
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EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
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SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
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A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
Client Woodard amp Curran Project HOWS CORMER QUARTERLY PO NO Sample Date 091305 Received Date 091505 E x t r a c t i o n Date A n a l y s i s Date 21-SEP-2005 11-59 Repor t Da te 09232005 M a t r i x WATER S o l i d s NA
CA3 Compound 75-01-4 Vinyl chloride 75-35-4 11-Dichloroethene 71-55-6 111-Trichloroethane 79-01-6 Trichloroethene 75-09-2 Methylene Chloride 155-59-2 cis-l2-Dichloroetheixe 1S6-60-5 trans-12-Dichloroethene 7B-87-5 12-Dichloropropane 127-1B-4 Tetrachloroethene
m+p-Xylenes 95-47-6 o-Xylene 1330-20-7 Xylenes [total 120-62-1 124-Trichlorobenzene 67-66-3 Chloroform 460-00-4 P-Bromofluorobenzene 2199-69-1 12-Dichlorcbenzene-D4
Page 0 1
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
Lab ID WV4779-10 Cl ien t ID SHC(21-16)LEVESQUE SDG W4 779 Ext rac ted by E x t r a c t i o n Method SWB46 5030
Flag
u u u 0
U
V
D
C
D
U
V
0
D
0
o f 0 1
Analys t SKT Analys is Method EPA 524a Lab Prep Batch WG20B19 Uni t s ug 1
5
cr
Resu l t s 0 5 0
0 5 0
0 5 0
0 5 0
OSO
0 5 0
OSO
0 5 0
0 5 0
1 0
aso 1 5
Q 5 0
0 5 0
7 0
7 5
F H 7 7 7 D
DF
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
1 0
PQL
0 5 0
0 5 0
0 5 0
0 5 0
0 5 D
0 5 0
0 5 0
0 5 O
0 5 0
1 0
DSO
1 5
0 5 0
0 5 O
A r i j P Q L
0 5 0
0 5 0
0 5 0
DSO
0 5 0
D 5 0
D 5 0
0 5 D
0 5 0
1 0
0 5 0
1 5
0 5 0
0 5 0
A d j M D
0 2 0
0 1 3
0 1 3
0 1 1
a 22
0 1 3
0 13 0 1 3
0 1 4
0 2 4
0 1 0
0 3 4
0 2 6
0 1 2
Sample Data Summary A0000012
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
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A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
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L _ _
bull
bull shy
bull
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Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIN ANALYTICAL SERVICES Report of Analytical Results
C l i e n t Woodard amp C u r r a n Lata I D WV4779-11 U^Gcrtvampf^ P r o j e c t HOWS CORNER QUARTERLY C l i e n t I D WSHC [11-4)SAWYER
PO No
Sample D a t e 0 9 1 3 o s R e c e i v e d D a t e 0 9 1 5 Q S
E x t r a c t i o n D a t e A n a l y s i s D a t e 2 1 - S E P - 2 0 0 5 1 2 4 2
R e p o r t D a t e 0 9 2 8 2 0 0 5 M a t r i x WATER
S o l i d s NA
CAS Compound 7 5 - 0 1 - 4 V i n y l c h l o r i d e
7 5 - 3 5 - 4 1 1 - D i c h l o r o e t h e n e
7 1 - 5 5 - G 1 1 l - T r i c h l o r o e t h a n e 7 9 - 01-G T r i c h l o r o e t h e n e 7 5 - 0 9 - 2 M e t h y l e n e C h l o r i d e
1 5 6 - 5 9 - 2 c i s - 1 2 - D i c h l o r o e t h e n e 15 6-6 0-5 t r a n s - 1 2 - D i c h l o r o e t h e n e
7 8 - H 7 - 5 1 2-Di c h l o r o p r o p a n e 1 2 7 - 1 B - 4 T e t r a c h l o r o e t h e n e
m+p-Xylenes 9 5 - 4 7 - G o -Xy lene 1 3 3 0 - 2 0 - 7 X y l e n e s ( t o t a l ) 12Q-B2-1 1 2 4 - T r i c h l o r o b e n z e n e
67-GG-3 C h l o r o f o r m 4 SO-0 0-4 P - B r o m o f l u o r o b e n z e n e 2 1 9 9 - 6 9 - 1 l 2 - D i c h l o r o b e n z e n e - D 4
P a g e
SDG WV4779
E x t r a c t e d b y
E x t r a c t i o n M e t h o d EW84G 5030 A n a l y s t SKT
A n a l y s i s M e t h o d EPA 5 2 4 2 Lab P r e p B a t c h WG20B19 U n i t s u g 1
F l a g s Results DP PQL AdjSQL AdjHD D 0 5 0 1 0 0 5 0 0 50 0 2 0 O 0 5 0 1 0 0 5 0 0 50 0 13 D J 0 5 0 1 0 0 5 0 0 50 0 1 3 0 0 5 0 1 0 05C 0 50 0 1 1 0 0 5 0 1 0 0 5 0 0 50 0 2 2 U 0 5 0 1 0 0 5 0 0 50 0 13 D 0 5 0 1 0 0 5 0 aso 0 13 O 0 5 0 1 0 05O 0 50 0 13 O 0 5 0 1 0 0 5 0 a 5 0 0 1 4 D 1 0 1 0 1 0 1 0 0 24 D 0 5 0 1 0 0 5 0 0 50 0 1 0 U 1 5 1 0 1 5 1 5 0 34
u D50 1 0 0 5 0 0 50 02G
o 0 5 0 1 0 0 5 0 a so 0 12 89 89
01 o f Dl FB77BD
Sample Data Summary A0000013
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
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FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
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(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
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(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
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REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
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I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
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F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
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COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Waodard amp Curran Lab ID WV4779-14RA Project HOWS CORNER QUARTERLY Client ID WSHC(11-3)DERAPS PO Ho SDG WV4779 Sample Date D913D5 Extracted by Received Date 091505 Extraction Method SWB46 5030 Extraction Date Analyst SKT Analysis Date 22-SEP-2005 1333 Analysis Method EPA 5242 Report Date 09282005 Lah Prep Batch WG20B97 Matrix WATER Units ug1 Solids NA
CApound Compound Flags Results DF PQL AdjPQL Adj HD 75-01-4 Vinyl chloride D 05D 10 050 050 020 75-3 5-471-55-G
11-Dichloroethene l11-Trichloroethaue
U D r 050
050 10
10
050
050
050
050
013
013 79-01-G Trichloroethene D raquo 050 10 050 050 011 75-09-2 Methylene Chloride n ) 050 10 050 050 022 156-5 9-2 cis-l2-Dichloraethene D O50 10 050 050 013 156-50-5 trans-l2-Dichlaroethene 0 050 10 O50 050 013 7 8-87-5 12-Dichloropropane D 050 10 050 050 013 127-1B-4 Tetrachloroethene tr 050 10 050 050 014
ra+p-Xylenes u 10 10 10 10 024 95-47-6 o-Xylene o 05O 10 050 050 010 1330-20-7 Xylenes total) 0 15 10 15 lS 034 120-32-1 124-Trichlorobenaene u 050 10 050 050 026 G7-6G-3 Chloroform 0 05O 10 050 050 012 460-00-4 P-Brottiofluarobenzene 63 2199-59-1 12-Dichlorobenzene-D4 64 V
Page 01 of 01 FB79SD
Sample Data Summary A0000016
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
KATAHDIK ANALYTICAL SERVICES Report of Analytical Results
Client Woodard amp Curran Lab I D WV4779-15 Project HOWS CORNER QUARTERLY C l i e n t I D WSHC(7)MKLANS0N PO NO BDG WV47 79 Sample Date 091405 E x t r a c t e d b y Received Date 091505 E x t r a c t i o n M e t h o d SWB46 5030 Extraction Date A n a l y s t SKT Analysis Date 21-SEP-20D5 1405 Analysis Method EPA 5242 Report Date DS282005 Lab Prep Batch WG20819 Matrix WATER Units ug1 S o l i d s NA
CAS Compound F l a g s R e s u l t s DP PCL AdjPQL AdjMD 75-01-4 Vinyl chloride D 0 5 0 1 0 0 5 0 0 5 0 0 2 0 75-35-4 11-Dichloroethene n 0 5 0 1 0 0 5 0 0 50 0 1 3 71-55-6 111-Trichloroethane n 0 5 0 1 0 0 5 0 0 50 0 1 3 79-01-6 Trichlorcethene u 0 5 0 1 0 0 5 0 0 50 0 1 1 75-09-2 Methylene Chloride D 0SO 1 0 0 5 0 0 50 0 2 2 156-59-2 cis-12-Dichlorcethene 0 0 5 0 1 0 05D Q50 0 1 3 15 6-60-5 trans-12-Dichloroethene u O50 1 0 Q50 0 50 0 1 3 7S-B7-5 12-Dichloropropane S 0 5 0 1 0 05O Q50 0 1 3 127-18-4 Tetrachloroethene o O50 1 0 0 5 0 0 5 0 0 1 4
m+p-Xylenes 0 1 bull 1 0 1 0 1 0 0 2 4 95-47-G o-Xylene 0 0 5 0 1 0 0 5 0 0 5 0 0 1 0 1330-20-7 Xylenes (total) u 1 5 1 0 1 5 1 5 0 3 4 120-82-1 124-Trichlorobenzene 8 0 5 0 1 0 0 5 0 0 5 0 02G 67-6G-3 chloroform 9 0 1 0 Q50 0 50 0 1 2 460-00-4 P-Eromofluorobeazene 74 2199-69-1 lr2-Dichlorobenzene-D4 7 3
Page 03 of 01 F87BDD
Sample Data Summary A0000017
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
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Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
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EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
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EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
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V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
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A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
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Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
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Oilier
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Advisory Surrogates - OLM032
Validator
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EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
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Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
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EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
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SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
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A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
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REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
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FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
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340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
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COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
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Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
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COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
WOODARDampCURRAN Engineering bull Science bull Operations
pATA VALIDATION REPORT RESIDENTIAL TAP WATER MONITORING
SEPTEMBER 2005
205279069_05sumTnary reportdoc
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
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REMARKS ^-kW^
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340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
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Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
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Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
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Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
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Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
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THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
CORPORATE OFFICES Maine Massachusetts WOODARDampCURRAN New Hampshire Connecticut Florida
Engineering bull Science bull Operations Operational offices throughout the US
October 3 2005
Mr Terrence Connelly Remedial Project Manager Office of Site Remediation and Restoration US Environmental Protection Agency- New England Region 1 Congress Street BostonMA 02114-2023 i
Subject Data Validation of Quarterly Residential Water Sample Results September 2005 Hows Corner Superfund Site Plymouth Maine
Dear Mr Connelly
Attached please find the data validation report for the quarterly residential samples collected in the vicinity of the Hows Corner Superfund Site on September 13 and 14 2005 Groundwater samples were collected in Plymouth ME to determine if residents near the site are consuming water with concentrations of compounds that exceed state and federal drinking water standards A Tier IT validation procedure was completed to assess the quality of the data associated with these samples Criteria from the Region L EPA-NR Data Validation Functional Guidelines for Evaluating Environmental Analyses (USEPA December 1996) and the Quality Assurance Project Plan West SiteHows Corner Superfund Site Plymouth Maine (Acheron 199S) were used as references in the validation process All residential water samples were submitted to Katahdm Analytical Services of Westbrook ME for analysis of a select group of volatile organic compounds (VOCs) using USEPA Method 5242 The target compounds which were reported from this analysis are included in Table 2 Samples were organized by the laboratory into the sample delivery group (SDG) WV4779 The samples associated with this SDG arc summarized in Table 1 of the attached data validation report
Data validation included an evaluation of data quality with respect to usability based on the following quality control parameters
bull Data completeness bull Preservation and Technical Holding Times bull GCMS Instrument Performance Check (Tuning) bull Initial and Continuing Calibration Results bull Blanks bull Surrogate Recoveries bull Internal Standard and Retention Time Results bull Field Duplicates bull Laboratory Control Samples bull Target Compound Identification
The results from analysis of the above quality control samples do not indicate any major data usability issues Chloroform was detected in one of the method blanks at 026 ngL indicating potential low level false positive concentrations of this compound introduced into samples from laboratory activities Detections of chloroform at concentrations below the action level reported
41 Hutchins Drive I Portland Mains 04102 bull 207-774-2112 I 207-774-6635 (Fax) bull 1-800-426-4262 I wwwwoodardcurrancom
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
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Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
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The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
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SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
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EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
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Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
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EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
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V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
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A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
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Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
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40-110
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Walcr Soil IU-11U 21-113
15-115
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nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
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NA
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Uccovery Recovery Recovery
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Advisory Surrogates - OLM032
Validator
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EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
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Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
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Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
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EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
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SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
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Sniiiplc Numdcr Cuiiipuuint MS I out run v
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A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
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Rrpoitctl Quantitation Limit
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Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
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REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
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FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
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FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
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I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
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FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
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]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
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340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
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COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
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Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
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COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
f t p p P ) A D P ) XL r I R R A M CORPORATE OFFICES Maine Massachusetts V VJJLJrrLJ OtV^UrillMI | N e w H a r r ) p s h j r e Connecticut Florida Engineering bull Science bull Operations operational offices throughout the us
for the associated sample and duplicate collected at the Foss residence were qualified as nonshydetcct (U) based on the method blank detection
Initial calibration results were compliant for all target VOCs indicating that sample concentrations were accurately quantified Continuing calibration results associated with analysis of the Hows Corner residential samples were compliant for all target compounds except for 111shytrichlorocthane and 11-dichloroethene Positive and non-detcct concentrations of these target VOCs were qualified as estimated (J) for associated samples based on these results
A laboratory control sample had a non-compliant recovery of methylene chloride Positive and non-detect concentrations of this target VOC were qualified as estimated (J) for associated samples based on these results
A field duplicate sample was collected at the Foss residence to determine analytical precision The relative percent differences (RPD) between sample and duplicate concentrations were below the EPA limit of 30 for all target VOCs indicating favorable analytical precision
The following data validation report provides a detailed summary of quality control results a data summary report and an assessment of the usability of the results based on data quality Please do not hesitate to call me at 1-800-426-4262 if you have questions regarding this report
Sincerely Woodard amp Curran Inc
gtfVlt^-A^ Jpvw^gtnj-shy
David Dinsmore Data Validator AUachmcnl
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 bull wwwwoodardcurrancom
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
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REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
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COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
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COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
HOWS CORNER SUPERFUND SITE QUARTERLY RESIDENTIAL TAP WATER MONITORING PROGRAM
092005 DATA VALIDATION REPORT
SEPTEMBER 2005
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
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The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
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Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
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Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
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Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
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L _ _
bull
bull shy
bull
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Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
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F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
A summary of the quality control results is included in the following subsections
I Data Completeness
The data package was reviewed for completeness to determine if all of the supporting documentation was submitted by the analytical laboratory The data package submitted by the laboratory in conjunction with the September 2005 quarterly residential water testing for the Hows Comer Superfund Site were one hundred percent complete
II Sample Preservation and Technical Holding Times
All residential water samples were analyzed for the compound list presented in Table 2 using USEPA 5242 Samples were collected in 40 ml vials which were pre-preserved with hydrochloric acid Samples were then placed in coolers packed with ice to maintain a temperature of roughly 4degC The technical holding time for preserved water samples analyzed by USEPA 5242 is fourteen days All samples were analyzed within the fourteen day holding time No sample qualification was needed due to holding time exceedances
III GCMS Instrument Performance (heck
The ion abundance criterion for bromofluorobenzene was used to ensure proper mass calibration and resolution identification and sensitivity The results from these analyses indicate that the criteria were met and that the GCMS performance during sample analysis was satisfactory
IV Initial and Continuing Calibration Results
Initial and continuing calibration results were reviewed to ensure that sample concentrations were accurately quantified The criteria for initial calibration results was for the percent relative standard deviation (RSD) to be 30 or less and for the relative response factor to be at least 005 The initial calibration completed on the F instrument on September 16 2005 was used for quantification of sample results The relative response factors for the initial calibration used to quantitate sample concentrations were greater than 005 for all target compounds The initial calibration also had compliant RSDs of all target VOAs indicating that an acceptable calibration curve was established for sample quantification
Continuing calibration standards were analyzed as a cheek on analytical accuracy established in the initial calibration A percent difference of 25 between the true and the observed concentrations was used as a criterion to assess the results Continuing calibrations were completed on September 21 22 and 27 The continuing calibration performed on September 21 2005 had compliant percent differences for all target VOCs except 111-trichloroethane Positive and non-detect concentrations of this compound were qualified as estimated (J) for associated domestic well samples collected from the following residences Levesque Sawyer G Hames Norris Ward Godsoe and Knight The results for the continuing calibration standard analyzed on September 22 were compliant for all target VOCs For the continuing calibration standard analyzed on September 27 2005 the percent differences between the true and observed concentrations were compliant for all target VOCs except for 11-dichloroethene Concentrations of this compound were qualified as estimated (J) for associated samples collected at the DeRaps and G Hopkins residences
WOODARDampniRRAN (20529701) 1 100305
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
V Blanks
Method blanks were analyzed to determine if concentrations of target compounds were introduced during the preparation and analysis of samples at the laboratory Chloroform was detected at 026 ugL in a method blank analyzed on September 27 2005 indicating a potential introduction from the laboratory
Two trip blanks were analyzed to determine if there was cross contamination of VOAs between samples during shipment and handling There were no target VOCs detected m either of the trip blanks indicating that cross contamination between samples during the shipping process was not likely
Field blanks were collected to determine if concentrations of target compounds were present in the 40 ml vials used to contain the samples There were no target VOCs detected m the field blanks indicating that the vials did not contain concentrations of these compounds
Since there were no detections of target VOCs in other blanks the method blank detection of chloroform was used to establish an action level Trace detections of chloroform were qualified as non-dctect (U) for the associated sample collected at the Foss residence and its corresponding duplicate sample since the concentrations were below the established action limit obtained from using the 5X Rule (USFPA 1996)
VI Surrogate Recoveries
Surrogates were added to each sample to ensure instrument performance during sample analysis The surrogates which were added to samples include 4-bromofluorobenzcne (BFB) and 12shydichlorobenzene Surrogate recoveries were in compliance for all samples indicating that instrument performance during sample analyses were satisfactory
VTI Internal Standard Areas and Retention Times
Internal standard results were reviewed to determine instrument performance and stability The area counts and retention time results for the internal standard fiuorobenzene were compared to acceptance criteria for USFPA Method 5242 The criteria is for internal standard area counts of samples to be between -30 and +30 of friose obtained from the standard during the continuing calibration analysis Retention times were required to be within 05 minutes of the standard value The original analyses of several samples in the SDG had non-compliant internal standard results indicating potential instrument problems and response However the samples were all reanalyzed within holding times with compliant results Therefore no action was taken with respect to these results
VIII Laboratory Control Samples
Laboratory control samples (also referred to as laboratory fortified blanks) consist of deionized water which is spiked with known concentrations of the target compounds The recoveries of the compounds were used to determine the analytical accuracy of the system used to obtain sample concentrations Recoveries of 60 to 140 were used as control limits to determine accuracy Several laboratory control samples were analyzed in association with the Hows Comer residential samples The majority of the laboratory control samples had compliant recoveries however the laboratory control sample analyzed on September 22 2005 had one non-compliant recovery for
WOODARD amp CURRAN (20529701) 2 100305
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
methylene chloride Positive and non-detect concentrations of methylene chlonde were qualified as estimated for associated samples collected at the DeRaps and G Hopkins residences
IX Field Duplicates
Field duplicate samples were analyzed to determine the precision of sample collection and analytical techniques through comparison of reported sample concentrations Precision was determined through analysis of the relative percent difference (RPD) between reported results of the sample and the duplicate The USEPA requirement for duplicate aqueous samples is for the RPD of detections to be 30 or less A field duplicate sample was collected at the Foss residence The RPDs between sample and duplicate concentrations were compliant for all target VOCs indicating that sampling and analytical precision were acceptable
X Target Compound Identification
Target compound identification was completed through a review of retention times and mass spectra data These results were compared to those obtained through analysis of the standards of target compounds The results indicate that target compound identification was completed successfully for all samples
XI Summary and Overall Assessment of Data
Quality control results for most of the target compounds were m control and indicate that sample identification and quantification were accurately obtained No-compliant quality control parameters include a blank detection of chloroform continuing calibration results and a laboratory control sample recovery Detections of chloroform reported for the sample and duplicate collected from the Foss residence were qualified as non-detect based on the blank results Data qualifiers were also applied to associated sample concentrations associated with the non-compliant laboratory control sample recoveries and continuing calibration results
Overall the quality control results are acceptable and indicate that the data are of good quality suitable for their intended end use of monitoring concentrations of VOCs in the residential wells near the Hows Corner Supcrfund Site
WOODARD amp UJRRAN (20529701) 3 1W03QS
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
TABLE 1 RESIDENTIAL WATER SAMPLES BY SDG
PLYMOUTH ME SEPTEMBER 2005
SDG
WV4779
Analysis Completed USEPA-5242
Matrix
Water
Associated Samples
Foss Norris Ward Godsoe Knight G Hopkins G Ilames Gray Sawyer Levesque DeRaps Melanson
WOODASD amp CURRAN (20529701) 4
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
TABLE 2 SITE TARGET COMPOUNDS USING USEPA 5242
HOWS CORNER SUPEREUND SITE PLYMOUTH ME
Compound Reporting Limit (pgL) Matrix
Vinyl chloride 05 Water 11 -dichloroediene 05 Water 111 -triehloroediane 05 Water Trichloroetriene 05 Water Methylene chloride 05 Water cis-12-dichloroelhene 05 Water trans-12-diehloroethene 05 Water 12-dichloropropane 05 Water Tetrachlorethene 05 Water mp-Xylenes 10 Water o-Xytene 05 Water Total xylenes 15 Water 124-trichlorohen2ene 05 Water Chloroform 05 Water
WOODARD amp CURRAN (20529701) 5 100305
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
WOODARDampCURRAN Engineering gt Science bull Operations
( ATTACHMENT 1 DATA VALIDATION WORKSHEETS
HOWS CORNER SLTPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
205279069_05 summary reportdoc
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
Site Name n t pound Validation Worksheet Covet page - Page 1 Reference No
REGION I ORGANIC DATA VALIDATION
The following data package has been validated
^ ^ ^ T ^ T - 1 J Sarnpimg Daie^ 9f 3f V^jgshy
N o ^ S a ^ ^ a Z ^ ^ C ^ I UgtpoundKd by lab qffnff
Traffic Report Sample Nos p=rlaquo iSlotfiaU W^6oclaoe KMgfrhCV f W ^ S (^ l4a^ ltV ^ r^y Fa^ty^ 7-fa JSpoundHU TV ttrtnft y lUtMstrade
Trip Blank No Equipment Blank No Boole Blank No Field Duplicate Nos F r f l g F r f i ^ i J ^ p PES Nos^
TheReeionI F ^ - gt T ra Validation Functional Guidelines for Evaluating Environmental Analyses r c v i s l ^ Zfato was used to evaluate the data andor approved modifications to the EPA-NE Functional Guiampclpoundes were used to evaluate the data and are attached to this cover page (attach modmed criteria from EPA approved QAPjP or amendment to QAPjP)
^TieTlDor Tier m evaluation was used to validate the data (circle one) If a Tier E validation with a pbttsrfiet ffl was used then identify samples parameters etc that received puna I ter IE validation
The data were evaluated based upon the following parameters
- Overall Evaluation of Data H d d Duplini - Data Completeness (CSF Audit - Tier I) - Sensitivity Check - Preservation amp Technical Holding Times - PE SamplesAccuracy Check - GCMS amp GCECD Instrument Performance Cneck - Target Compound Iaenrmczuon - Initial ampz Continuing Calibrations - Compound Quaaticuion and Reponed - Blanks Quantitation Limits Surrogate Compounds ^ v o l a t i l e ^ P e f l c ^ p C B Cleanup - Internal Standards z n shy- Matrix SpikeMatrix Spike Duplicate _ - System Penormance
Region I Definitions and Qualifiers
A - Acceptable Data J - Numerical value associated with compound is an estimated quantity R - Th data are rejected as unusable The R replaces the numerical value or sample quantitation limit U - Comoound not detected at mat numerical sample quantitation limit UJ - The samDle quantitation limit is an estimated quantity TB BBEBCompound detected in aqueous trip blank aqueous bottle blank or aqueous q u p o t t blank associated with soilsediment samples
Validators Name A W Company N a m e A ^ Phone Number Q ^ l 2 t
amplaquo V a J i d i o n C o r r i dDat= Validation Staned J amp J O ^ - J deg M ^
1296
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
The data validator generates a Data Validation Repon applicable to Data Validation Tiers II and III that consist of the following components in the order specified below (Refer to Section 11 for a description of each of [n
Data Validation Repon components)
1 Organic Regional Data AssessmentInorganic Regional Data Assessment (ORDAIRDA) Form
2 Data Validation Memorandum a -Narrative b Table I-Qualifier Recommendation Summary Table c Table II-Overall Evaluation of Data d Table ID-Tentatively Identified Compounds e Data Summary Tables
3 Standard Data Validation Worksheets a Manual b Automated Data Review Reports ie CADRE)
4 Support Documentation a Copy of non-CLP analytical method eg DAS methods modified EPA methods
V Copies of PES Score ReportsVendor PES QC Acceptance Limits ^c Copies of Telephone LogsCommunication Forms for bull RSCC communications
bull Requests for laboratory data resubmissionsclarifications bull Communications withsamplers resolving sampling problems bull Communications with TFOLead Chemist to repon contractually-deficient da
for rejectionreduced payment shybull Communications with EPA Site Manager concerning possible data rejection bull EPA Site Manager authorization for alternate DVlier
d Copies of data supporting recommendations for reduced payment resulting from C5 Audit andor PE sample result evaluation bull
t Original data to support recommendations for data rejectionmbn-payrnent identified fro Tier II or Tier HI data validation
f Copies of field sampling notes andor field report supplied by field sampler g Copies of EPA-approved amendments to QAPjP andor SAP describing modified critei
to be used for validating site data 5 CSF Completeness Evidence Audit 6 DQO Summary Form
The data validator is responsible for implementing all corrective actions required by the contractor Lead Chem
in response to EPA-KE data validation oversight findings
12
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
EPA-Nr Data Validation Worksheet Ovcrnll i^vnluntlon of Dnln - 0ntn Validation Memornndnni - Tnbio 11
VOLATILE ORGANICS
DQO (list all DQOs) Sampling andor Analytical Mctbod
Appropriate
Measurement Error _
Analytical Error Sampling Error1
Sa Vari
Yes or No
| o twtoi-for Qonob ^fttS-of
Wgtlaquo^c^--lti
-fampk^( di^Iv^ kJbWri d i s ^
The evaluation of sampling error cannot be completely assessed in data validation
Sampling variability is not assessed in data validation
Vi^Ll^st^~M^Validator
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
EPAf X S T ^ W U - - M raquo mdash - laquotlaquo Ovcrm
SEMIV0LATILE0RGAN1CS_ Sa Measurement Error Sampling nndor V i DQO (list at DQOs) Analytical Method
Appropriate Yes or No
bull The evaluation of sampling error cannot be completely-jessed in data validation
+ Sampling variability is not assessed in data validation
Validator
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
pound bull
EPA-NE - Data Validation Worksheet VOASV - PestPCB
COMPLETE SDG FILE (CSF) AUDIT
Organic Fractions
Missing Information Date Lab Contacted Date Received
amp
Date Validator
1296
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
EPA-NE - Dntn Validation VOASV-r -1CIM
Dale Contacted Yes No Company Sample or X0K
Circle sample numbers wll needed technical bpMtag Una j i l t e d R e | PRESEUVATtON AND MOLDING TMBS - W e s a m p l e trade pound Z pound j ^ Z amp amp o m l U laquo ^ e o n t a codes
Circle nil exceeded technical holding Mutes-S S l i y U S W W after bull of DlaquojrsVltEtnlaquota Code)
Action Code bullCxlrncdon Code) rrcservntlon Cotlc J - Estimate (J) D LL - Li([uidLiltniii] 1 C o o l copy 1 C ( plusmn 2) UJ - Estimate (UJ) SON - Sonicnlion 2 Preserve wHil HCI to at least pit 2 R - Reject RJ Noi SEP - Separatory runnel 3 Protect from light SOX - Soxhlcl A Pt(ie7c
Room Temper aim e (Avoid excessive heal) SPE- Solid Phase Extraction 5
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
EPA-NE - Data Validation Wurkshccl V O A 5 i bull shy
II GCMS INSTRUMENT PERFORMANCE CHECK (TUNING)
LisL all Instrument Performance Checks that arc outside method QC tuning acceptance criteria
Volnt l lc Instrument PciTorumnce Chcctt
(Compound Nninc)
Annljsts Dnlc unit Mine
Instrument Arrccfetl
Percent Itclntlvc
Atjtmtlnii i- UilVHs-1
Sntnples
Q-2I Q 2 T 9 amp 2 Mtn shy
Comments
mdash mdash mdash i mdash [ mdash bull - bull
Srin lvolnt l lc Instrument Perform nttcc Check
Ann lysis Dnlc IITTU Time
Instrument Ioraquo(s) Arfcclctl
Percent Rclntlve
QC Limits
Sniiiplcs
(Compound Nnme) Atmuilniice
i
Comments i
1
If tuning compounds and criteria arc different from those specified in CLP SOW OLM031 then the validator sho specific tuning criteria with this worksheet
Validator M^^^d^^v
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
A-NE - Data Validation Worksheet
VOASV-III
BL INITIAL CALIBRATION - List all nnlytcs thai arc outside calibration criteria
Xi Sntiij Affec HRVDntc or CmmKraquorml USD IVfntrlx rnrninctcr Instrtiiucttl ICAL
Kloa-mdash M OK lt-bullbull bull - - - bull 9lfeo6 Vofl hi
Comments
Validator
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
EPA-N bull Data Vnlidniiun Worksheet VOASV-IV
List nit amlylcstlmt^otttsKtecatotton criteria IV CONTINUING CALIBRATION
l_9ife|opound q|2Jifll ^sgt )i-bcc _ p^^s 3JU4amp
M QiLpt(tfr
Comments
j^WdJ ^Lw^ O^^Tf^g -Validator
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
A-NE - Data Validation Worksheet vOASV-1MtICU-V-A
V BLANK ANALYSIS Co
List the blank contamination below Contacted Ye Company
Sampler _
L^onuory Mcdod Stornc mid M n m r i U N
Ftdtl Eqlaquolraquotntrtit (Rfmnte) Trip nnU Bottle BInnks2
Com poundInslnmieiitSntnolcDale rnrnmclcr iple NoNo ColumnIJnle [UlniitExlrnctctl AnnIvTctl Mnlrbc
77 IP BukraquoC
firq pom
Validator
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
I
A-NE - Dnln Validation Worksheet VOASV - Iraquocs(FCB-V-lJ
3 Blank Actions - List the maximum coneciilnlions of blank compounds
Actltm Sniniilc Sn Cuni|ii)(itiil Type uf Mlniili DIIIG Itlnnk Mnx All SmiipIetlOrlElitnlcd Cuitc Level
(units) units)
T^ f gtpQb Urvhfm lvlt4^^ qzioy JptfL lt9^y
Coiiiincnts
VnlUhlun ^ k J y j ^ ^ D
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
VI
EPA-NE - Dain VnlklaUon Worfesteset
V 0 A V I H raquo ^ n n u n d recoveries thai arc outside
VOA SUKROOATE SPIKE RECOVERIES - List all surrogate compound rccovenc
Volnttle MHlinrt PC Acceptance CrUcrln
DCE-d Oilier Mettiml Talueitc-il BPB
Water Soil Water Soil Water Soli 76-1M 70-121 OLMU37 86-115 59-113 88-110 8-1-138
Validator |^1fij V^^U
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
EPA-N - Data Valtdntiou Worksheet
T SV SURROGATE m RSCOVRRBS - Lis M lt mdash - raquo - mdash ^
OLM032
OLCU21
Oilier gmmtlc NunibcrMntrlt
Method
OLM032
OLCU2I
Otlicr Snnmlc Ni i in l tcrMnhIx
Walcr Spit 35-lTT23120_
40-110
Uccurcry
Phcnol-d
Walcr Soil IU-11U 21-113
15-115
Recovery
nnclgtNMHml Method QC Acceptance CrUcrln
TPH-dn lfrDCB-d
Water Soil -rj-lfiTsOTlS
30-110
Water Soil 33^141 18-137
20-MU
Water Soil I6-11UZU-I3U
NA
Recovery Recovery R ceo very
Acid Me Hit) J QC AcccptnnccCrKcrtn^
2-PP 24C-TBP 2-CP-d
Walcr Soil Walcr Soil Walcr SoU 33-110 2U-130 21-1IU 25-121 1(M23 ly-122 NA 15-130
Uccovery Recovery Recovery
15-110
Oilier
Re
Oilier
R
Advisory Surrogates - OLM032
Validator
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
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EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
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mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
bull
EPA-NE - Data Validation Worksheet
V O A S V - V I I
INTERNAL STANDARD PERFORMANCE VII
List the internal standards that re outside the r e count nud retention Uflfefedtod QC accepta
IS Area Count mctliod QC acceptance criteria ^ C g j 7ampjampgtmdash IS Retention Time mctliod QC acceptance criteria t O y A v n ^ i _
IS Arcn IS Ontstitc Arcn Pnrninctcr Snrtiplc Pnte unci T ime Instrument si i i r t J
Count nti i l or Number Atinlyzed [IS IVI Criteria
(TIW) bull
j f^ lnW
f A
bull I
Validator ^ J IJ^J ^^JfiAjLuiati_ shy
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
i
EPA-NE - Data Validation Worksheet VOASV - PcslPCB-VIH
VHI MATUX SPIKEMOTUX S laquo K E mm - L i MSMSD tag raquo OUUW
criteria
Use a separate worksheet for each MSMSD pair
Mnlr ix Sample _
MSD RPD Method QC Umtfa Conccttlrnllon MS Pnrntnclcr CotnpotraquoinI
Rcc Rcc TJlisplketl MS Rec RPD Sample
i
-
f gt _
Validator _
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
EPA-N Dala Validation Worksheet VOASv - PcslFCIMX
IX FIELD DUPLICATE PRECISION - List all Held duplicate analytes thai arc outside criteria
Use a separate worksheet Tor each field duplicate pair
Sample Number FoSS Duplicate Sample Number Frttamptp Matrix A- x^
Pnmniclcr Compound Snmple Snmple QL DupJIcnle Duplicate QL Cone Coitc
SQL 2xSQL SQL 2xSQL
M OK
i
Pur instances where one duplicate result is ND (or reported lefts than the sample QL)
Docs the MSMSD ttnln inilicnlc acceptable hburaiury precision r Y N
Comments _ _ _ bull bull
Sampler Name Contractor Name Date Contacted
Reason Tor Contact and resolution obtained
Q^)fLv i i M n i - I A I lti A X shy- Dure
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
bullA-NE - Data Validation Worksheet VOASV - IeslPCB-X
X SENSITIVITY CHECK (Method Detection Limit Study)
List nil compounds surrogates nnd internal standards that arc outside the MDL crKcrin
Has an appropriate MDL study been submitted with seven replicates Tor each compound and ma Dntc of Preparation Analysis Within 1 year7 -J
bull Instrument iD Same as samples _ Same ns samples bull Column ID
Com pon nil MUL gt QL MdlHMl OC Limits IS Outline Arn Counl nsu gt 10 -Sninjilti Mult IT lt B0 or gt 1207 rmlor HT OlttrJa
I
ITnn MDL study tins not been submitted use only the LFB results to evaluate data
(Lnborntury Fortified Utank) - List all LFB compounds surrogates and internal standards that arc outs
bull Has nn appropriate and complete LFB been submitted nlllie proper frequency bull 13ocs ii contain all target compounds at the method-required QLs bull Was Ihc LFB spiked with a standard from a source (vendor) independent or the calibration stand
MalT-tx CnmjirHiitil Method QC Ltmtls IS Olttttrfr Aren Snmples Affected lt fiU or gt Mt) r Count nndor RT Oflier Crltcrh
gt bullQ^-iM MCi7 ^0-t305t fdfyKtamptKft
J bull i r
bull
Validator1 hr^^^^^vLAn^^ Date fCo
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
EPA-r bull Data Validation Worksheet
VOASV - rc-fircn-xi X I ACCURACY CHECK (Perfor m M t t f t a
I - ) lt raquoltraquogtlaquo tol a r e ^ ^
SDG No
Arc tnorc
CASE
than one-half of the PESanalylcs within criteria Tor each parameter v-
Cone Region I EIA Non-EPA P Mnfrlx Annlyle
PE Ainpti fc Farnriieter Type oT PES Scores Scores PES Snmple Number
Number
For Rcniun I IUSs indicate the Region I PES Score RcporfRcsuIl Action fligh Action Low TCL M MIT TIC MISS TIC CONTAMINANT
+ For Non-EPA PESs indicate lhc|fon-EPA PES Score PES COMPOUND MISS PES COMPOUND CON HIT ( Recovery Limits)
Validator
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
JgtA-NIi - Dnln Validation Wuiksliccl S VOASV - rcsipcn-xti XII TARGET COMPOUND IDENTIFICATION - List ttie nnalylcs Uiat arc outside tlic acceptanc
Sniiiplc Numdcr Cuiiipuuint MS I out run v
-
bull r
~
L _ _
bull
bull shy
bull
i
gt
mdash
Validator
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
A-NE - Data Validation Worksheet V O A S V - PestPCB-XIU
XIII SAMPLE QUANTITATION
Recalculate from the raw data the concentrations Tor one positive dclccl and one reported sample quantitation limit Tor raquo non per fraction (Nole- Althoufili Section XIII CIa requires tint one calculation Tor each fraction in cadi sample be perf reproduce an example for each fraction of one positive detect and one sample quantitation limit cHcVhtion on this workshe
Do alt suitsciliincnl snni|itcs have solids greater llian 3U7 If no list sample numbcrs__
Cnleulnllon Fraction
YOA
Simple No
He ported Compound
Reported Vilue
Not Detected Compound
Rrponed Qujmiudon Limit
UNA
Simple No i
Reported Compound
Reported Vlaquotue I lt
Not Detected Compound
Rrpoitctl Quantitation Limit
TMlklde^rCn
Simple No Reported Compounit
bull
Reported Vitue
Not Delected Compound
tltpotttil Quiniititton Limit bull bull
Validator
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
gtA-NE - Data Validation Worksheet bullbull-bullgt VOASV-XIV
XIV TENTATIVELY IDENTIFIED COMPOUNDS (TICs)
List tlic 5 TICs having (lie highest concentration for each sample parameter
Snmplc Number Pnm ureter Compound jtSrr Est Co
-
bull
-
l
- m
-
1
-
1
Validator
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA) 3 r r E NAME nampJampCcrtUS RfeSijUj^f CASE
^LAB NAME SceLbrln AvXilyftic^ OF SAMPLESMATRIX t l Jfyu^
^ I n o i UJl laquoJT7Q VALIDATION CONTRACTOR I d o ^ L J i r
SOW ^CONTRACT 0 __ VALIDATORS NAME J j t V i W o
EPA-NE DV TIER LEVEL U - DATE DP RECD BY EPA-NE
TPOPO ACTION FYI DV COMPLETION DATE IQfoZif
ANALYTICAL DATA QUALITY SUMMARY
bull bull VOA SV PestPCB t Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check 3 Initial Calibration 4 Continuing Calibration 5 Blanks $ W2 6 Surrogate Compounds fe 8 Matrix SpikeMatrix Spike Duplicate MA 7 Internal Standards 9 Sensitivity Check W5 10 PE Samples-Accuracy Check
bull I I Targe Compound Identification raquo 12 Compound Quantitation and Reported QLs _ v 13 Tentatively Identified Compounds -bull bull 14 SenmrolanleaeanupPesticidcPCBaeaniip y bullbull bull bull bull
yen Data Completeness O o Overall Evaluation of Data CJ o mdash Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major conrxactual problems z = Data were rejected as unusable due major contractual problems ACTION ITEMS (z items)
AREAS OF CONCERN (m items) M l 0lt3
^ Y ^ r k g o r - i a bdquo f gt U lt J V f ^ - p g l ^ M y Mujfitamp^ shy
This form assesses the analytical data quality in terms if contractual compliance only It does not assess sampling errors andor non-contracuial analytical issues that affect data quality
Check ACTION onlv if contractual defects resulted in reduced paymentdata rejection recommendations
Jidator hhJU Q L ^ Date O0Zc6mdashmdash
INSTRUCTIONS ON REVERSE SIDE
129
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
JJI i u E i d i u UJ v_ltiic IgtiOS^
Contract Laboratory Program REGIONALLABORATORY COMMUNICATION SYSTEM
Telephone Record Log
Date of Call
Laboratory Name
Lab Contact
Region
Regional Contact
Call Initiated By Laboratory Region
In reference to datarfbr the following sample numberCs)
Summary of QuestionsIssues Discussed
Summary of Resolution
Signature Date
Distribution (I) Lab Copy (2) Region Copy (3) SMO Copy
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
WOODARDampCURRAN Engineering bull Science bull Operations
ATTACHMENT 2 FIELD SAMPLING WORKSHEETS
HOWS CORNER SUPERFUND SITE PLYMOUTH ME
SEPTEMBER 2005
20527906905 summary reportdoc
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well amp ~( F^5J
Date Weather zM cy Time Purge - Start Samplerfs) ^ - X pound j J-poundJ=^ Time Purge - Stop bullrfr
Sampled plusmn^plusmnlt^
SAMPLING POINT Kitchen Sink Outside Sillcock tt Other E ]
(Specify)
WELL SPECIFICATIONS
LAB ANALYSES C u J tVj^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) t laquo mdash J raquo F m - t d
Depth Depth Depth
A K-Uraquol i ^ t i f
ft ft ft
U- t^uA i
deg^poundc (j-i^rshBA^ 3
ff J
V J P
J^f
REMARKS
T k_ pound v
ltp-^o^ fp^JQ-j- ~ A)~ fa~lt5ltshy
WWWR I
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ D orr^r
Date_ 0lttf Weather Time Purge - Start Sampler^) rpg_A^Smdash 4 Time Purge - Stop fijj f
Sampled - lt W J ~
SAMPLING POTNT Kitchen Sink [ ] Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES ^ - k f J V L ^ t ^ A n t - l i ~ t gtf- V2_raquo tuli-^ti
u^gtC Ct2 gtflarr^J(^pyj4 A
REMARKS fjj oyovf j q^^uj^r
MftBWR
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
FIGURE 4
WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well )~T- ( J u t t f l
Date Weather plusmn4Time Purge - Start Sampler^) Time Purge - Stop amp03gt
Sampled AampSampL
SAMPLING POINT Kitchen Sink Outside Sillcock [ U Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES G^t^ Fm-cd A n u l i~i if l2-lt^ui-laquofci
bull^sfhtc ( i i i UU^^A f | n)ft _JL
REMARKS T^U^-IJLamp _ ^^^^Jtar
wsewR
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
I I
FIGURE 4
WATER SAMPLING DATA RECORD laquo RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well ll-t 6-0 ampo v
Date o 5 Weather Time Purge - Start dot Samplerfs) Time Purge - Stop 15LUshy
Sampled lt pound f V
SAMPJJNGPQINX Kitchen Sink Outside Sillcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ j Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES f u t c l M-tl^r poundAfe^iimdashlaquoampgt
0~gtsfkc ftt-$ ltpoundrtdlt13fc ( gt bull )4
REMARKS
wsewR
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
WEST SITOHOWS CORNER PLYMOUTH MAINE
Residential Well A laquo o g h J -
Date Weather 1-1 fVoi Time Purge - Start Samplerfs) f4 zL ^ ^ Time Purge - Stop lampltO
Sampled tegt3
SAMPLING POINT Kitchen Sink Outside Sillcock Other
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) LAB ANALYSES 1 lt I U - gtpound-raquo bull^va-tii HA
t^SHt ( - 3 ^ K^ L^vrTTTrnr 1
REMARKS A- vAftx ^XQfu
f
048SWR
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
I FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well ^ f G- f o p K t n
rDate Weather -nuM| Time Purge - Start Sampler^) y^XXJJLJJ Time Purge - Stop fifC
| Sampled V ^ 4 i
SAMPLING POINT Kitchen Sink [ ^ ] Outside Silicock f L Other [ ]
(Specify)
WELT SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ J Depth ft Other [ ] Depth ft
(Specify) LAB ANALYSES Pm-cJ A rvulfc~v H pound+ K u l ^ t e J
L ^ Y ^ C (~tS)^ Hajgtiampn faj)s)fo JL
REMARKS Lampj-- 4-a^~^cfL^ ~~ H Q ltx e co^or 70 rp w^o v_
MaewR
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
I FIGURE 4 WATER SAMPLING DATA RECORD - RESIDENTIAL WELLS
I WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well 3 Z - - shy H t x ^ B J
DateTime Purge - StartTime Purge - Stop
Sampled
~ y | ~ampf amp y-p 7 0 0 700
Weather Samplerfs) Y -vST
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
J J_
WELL SPECIFICATIONS
LAB ANALYSES
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) I M SL
Depth Depth Depth
A n u l
ft ft ft
TZ- bull~KJr mdashti
L ^ C (L--poundI-lta^ o (H jA A fi
REMARKS - a v^ feH- fc j Q L A ^ O ^ t ^ r
fslpoundW - R T N ^ - N T
OWBWR
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well amp~)mdash[ G^co^
Date Weather_ __^^_^M I
Time Purge - Start Samplerreg tpoS^ iltr Time Purge - Stop ngtrSampled gt Tfi
SAMPLING POINT Kitchen Sink [ ] Outside Siilcock Other [ ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depths ft Other ^ _ _ _ _ _ [ ] Depth_ ft
(Specify) LAB ANALYSES Ci^1 tS- Alaquotu bullV i y l t^raquo Lu 1 pt-lt4
b^s yt_(es-06- ltltvv Cs 1 5) A amp
REMARKS
I ^ J Q J - S 4 - poundbull-gt laquo n
bull
ltBevw
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
FIGURE 4
WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well l H t U w ^ laquo v
Date Weather M^U-Time Purge- Start ITZM Sampler^) Tj wXjT Time Purge - Stop n-o
Sampled namp
SAMPLING POINT Kitchen Sink ] Outside Sillcock U Other ]
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth ft Bedrock [ ] Depth _ft Other [ ] Depth ft
(Specify) LAB ANALYSES c ^ w P i V A t-|poundraquol ~Vl bull(bull C~ gt~y r~ t t i P^^-tL
L^S J He ( bullbull) L^TfSgtltfi^(L I ci -gtgt
(M-l)
REMARKS g^- t l t j shy
y ^ ^
tweewR
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
I
I
FIGURE 4 WATER SAMPLING DATA RECORD -- RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Well - f 9 c u v y laquo C
I
bull
Date Time Purge-Start
Time Purge - Stop Sampled
lt lt3J
raquo^_ii^ 7^J
nif
Weather Sampler^)
SAMPLING POINT
WELL SPECIFICATIONS
LAB ANALYSES lt tA 1 amp~^
Kitchen Sink [ Outside Sillcock [ J_ Other [ ]
(Specify)
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify) s kx FlTl^cd
Depth Depth Depth
ft ft ft
At-Hl^yt -r ~Ullaquo-tullt-^t3
LJJSIHCX I-H 6 laquogt ( t n U A
REMARKS j - ^ ^ f f - O v f ^ g q_ raquo^vCk j kgt ^
BWrf poundj--^ r c y poundltxLjyJiT
1 OWWVR
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
I FIGURE 4
WATER SAMPLING DATA RECORD RESIDENTIAL WELLS WEST SITEHOWS CORNER
PLYMOUTH MAINE
Residential Well p - j) altc^pT
Date ^ j ~bfof~ Weather Time Purge - Start lVCgt Samplerfs) Time Purge - Stop fSQQ
Sampled totgt
SAMPLING POINT Kitchen Sink [ ]
Outside Sillcock Other i )
(Specify)
WELL SPECIFICATIONS Overburden (Hand Dug) [ ] Depth_ ft Bedrock [ ] Depth_ ft Other [ ] Depth_ ft
(Specify) LAB ANALYSES C u l (k^ f11 V+ i^-^t^ ftd A rnl 1^4 T ^CL-^AM
HISS9HHSHHRHMHHMHH LraquoyfHc fu-iy TQlaquoPS(laquotlraquo) A
r 5
REMARKS ^bullKWt
bullbull$amp
W86WR
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
FIGURE 4 WATER SAMPLING DATA RECORD shy RESIDENTIAL WELLS
WEST SITEHOWS CORNER PLYMOUTH MAINE
Residential Wel l 7 r V Q ^ - V a v r r 5 Q ^
Date Time Purge - Start Time Purge - Stop
Sampled
li^ ^f (Soe A g c r o
Weather Samplerfs) ^ ^ g mdash
SAMPLING POINT Kitchen SinkOutside SillcockOther
(Specify)
[ [
[
] s_
]
WELL SPECIFICATIONS
LAB ANALYSES c u ^
Overburden (Hand Dug) [ ] Bedrock [ ] Other [ ]
(Specify)
Depth Depth Depth
iniV bull
ft ft ft
C-raquo- -ukAi- t i
UsftleuroL (i vsi (OOAO-N (ltfrvv (
4 _pound
REMARKS ^-kW^
-
olaquoewR
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
340Connt)gt Road No 5
PO Bon 720 CHAIN of CUSTODY Katahdin Westbmok Ml i 04092
Tel (207) R74-2400 PLEASE BEAR DOWN AND A N A L Y T I C A L S i R V l C E S Fax (207) 775-4029 PRINT LEGIBLY IN PEN Page ^- of
Client Contact Phone Fax
dOog^o^d -f C^rrcx^v Address State ^ ^ST Zip Code Ht Afo-h^ ^ ^ gt y fi^rUgt^ltl Purchase Order Proj Name No Katahdin Quote Aov^ d ^ Q
Bill (if different than above) Address 0shySampler (PrintSign) Copies To
e=Jshy^T^-^K lt H L i o r WORK OROER ANALYSIS AND CONTAINER TYPE
PRESERVATIVES LAB USE ONLY
KATAHDIN PROJECT NUMBER Fill Filt Filt Filt Filt Filt Filt Filt Filt Filt G Y H N riYDN D Y D N HY f l N OY GN bull Y D N bullYON bullYL)N bull Y nisi r iYn REMARKS
SHIPPING INFO bull FED EX n UPS bull CLIENT
AIRBILL NO
TEMPdegC D TEMP BLANK f l INTACT bull NOT INTACT
Date Time No of Sample Description Matrix colld Cntrs
^ T C y J_
gtamp C j-~lCUWltfyK 7
pound p V gt
pound
TTvptsk fl shy
_pound_ shy
fraquo sVJ ^oraquon fl
shy
OC c q ) ^ mdash
5 vi I V ^ c (7^ ^ I - fc=raquoraquo
ltsv) ^y y deg zi
F-feU Tfa^W ft j fii n i I~L plusmnL I V
COMMENTS
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
RelinquishedBy (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS
KAS-COC1 CUSTOMER COPY
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712
340 County Road No 5 PO Bos 720 CHAIN of CUSTODYKatahdin Wraquoa tirook MB (gtMW2 Tel (207) 874-2400 PLEASE BEAR DOWN ANDl S E R V I C E S Fas (207) 775-W29 PRINT LEGIBLY IN PEN Page of
Client Contact Phone Fax
lticgtrA f C^f3 p v v
Address CityHI A f o - i - ^ U ^ ygtr- P^r V tomdash--A State A poundT Zip Code
Purchase Order ProjNameNo ^ ^ n f ^ Katahdin Quote
Bill (if different than above) Address A
Sampler (PrintSign) ( Copies To -N T
WORK ORDER ftER ANALYSIS AD CONTAINER TYPELAB USE ONLY PRESERVATIVES KATAHDIN PROJECT NUMBER Filt Filt Filt Filt Filt Filt Filt Filt Filt Filt
I~IY~IN bull Y D N D Y D N r i Y D N bullYON bullYDN bullYON REMARKS rrrriN DYn
SHIPPING INFO l~l FEDEX bull UPS bull CLIENT
AIRBILL NO
TEMPC D TEMP BLANK bull INTACT O NOT INTACT
Date Time No ofSample Description Matrixcolld Cntrs
7Jltgt=gt V T laquo
rf1
v ^ O ^ ^ r t i S C J M ) ft rvf
AiiLL
t o t
B i 6raquor
3 Zi^ Oo
J3 J amprr
3
1 gtoo
COMMENTS pound LZI
Relinquished By (Signature) Date Time Received By (Signature) Relinquished By (Signature) Date Time Received By (Signature)
T pound ^ K Relinquishedd By (Signature) date Time Received By (Signature)shg B Relinquished By (Signature) Date Time Received By (Signature)
k j i f l ^nm
THE TERMS AND CONDITIONS ON THE REVERSE SIDE HEREOF SHALL GOVERN SERVICES EXCEPT WHEN A SIGNED CONTRACTUAL AGREEMENT EXISTS CUSTOMER COPY
- barcode 251712
- barcodetext SDMS DOC ID 251712