wmm%jjmm$ · insurance for the period 1980-1988. Please note that while Stanley-Vidmar believes...

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STANLEY

11 Grammes Road. Box 1151, Allentown, Pa. 18105-1151Phones: 215 • 797-6600.797-9200 • Telex * 847345

*;; wmm%jjmm$.mJuly 7, 1988 JUL081988

Mr. Michael Towle - 3HW12 EPA-RcglOn IIIHazardous Waste Management DivisionU.S. Environmental Protection AgencyRegion III841 Chestnut BuildingPhiladelphia, PA 19107

Re: EPA Request for Information Under §104(e)of CERCLA Regarding the Novak SanitaryLandfill Site, Lehigh County, Pennsylvania

Dear Mr. Towle:

This letter responds to the EPA request for information datedMay 5, 1988 . Initially I refer you to letters dated May 23 and June 17,1988 from Lawrence W. Diamond to Joseph Dpnovan of EPA Region III. The May23 letter confirms EPA's agreement to limit the information request toQuestion 1 and that part of Question 3 which addresses wastes produced byplant processes. The June 17 letter confirms that the response is due July8, 1988.

Stanley-Vidmar, Inc. has no knowledge, based on Company recordsor information known to Company employees, that any of its waste ever hasbeen disposed of at the Novak Sanitary Landfill. Accordingly, you shouldconsider that this letter supersedes the letter of November 11, 1987 fromDelia Christensen of The Stanley Vfarks to you - responding to EPA'soriginal request for information dated October 7, 1987 - to the extent thatthe November 11, 1987 letter may be construed to indicate any knowledge onthe part of the Company with respect to the disposal of Company waste atNovak Sanitary Landfill.

Stanley-Vidmar helps solve storage problems everyday...throughout \

Enclosed with this response are copies of additional recordsthat have been found, including Company remittance documents and ValleyDisposal invoices and load receipts. We note that these records dggnot addto the available information regarding either the time period duiti

i , Stanley-Vidmar used Valley Disposal, or the types of wastes that— picked up by Valley Disposal. Other enclosures are identified

Question 1. r- :Vfe have been unable to verify either through our intensive

records search or interviews of Company employees that any waste generatedby Stanley-Vidmar ever has been disposed of at the landfill. (EPA hasforwarded to Mr. Diamond copies of documents that apparently were obtainedfrom Mr. Novak's files. Those documents appear to indicate that some ofthe waste picked up at Stanley-Vidmar may have been disposed of at thelandfill. However, we are not in a position to assess the accuracy ofthose records.)

Enclosed is a fixed asset inventory list showing the year (1974- month unknown) in which the Company installed a trash compactor. Thiscompactor was associated with a removable dumpster, in which the trashactually was placed. It appears that the trash compactor may have beeninstalled at the suggestion of Mr. Novak, and that its installation isrelated to the initiation of the Company's relationship with Novak. Thedumpster was removed by Novak or Valley Disposal on a regular basis from1974 to May 1985 (the last documented date that Valley Disposal picked uptrash from Stanley-Vidmar was May 29, 1985).

Question 3.The enclosed compilation of Material Safety Data Sheet ("MSDS")

i, information describes the majority of the products (excluding steel andsome of the least frequently used paints) used at Stanley-Vidmar during thetime period 1977 to may 1985. We do not have MSDS or other documentationfor products used before 1977. Also enclosed are all available MSDSs forthose products whose constituents are believed to have been contained inprocess wastes during that period. These constituents would have been apart of one or more of the waste streams which have included cleaning ragscontaminated with solvents (Saf-T-Sol #11 and VT #3) and paint residues;peel filmite with paint (paint overspray adheres to the peel filmite);paint sludge; and waste solvent. Enclosed are two laboratory reportsshowing the constituents of the sludge and solvent waste streams. Theselab reports are dated May 27, 1981 and were prepared by ASW EnvironmentalConsultants.

- 2 -

AR2G6761*

It has been standard procedure that only ordinary trash is tobe placed in the dumpster. However, between 1974 and December 1980 peelfilmite with paint overspray may have been commingled with trash in thedumpster. Also, for much of the period between 1974 and May 1985 thecontaminated rags were mixed in with trash and presumably entered thedumpster. Further, there may nave been isolated instances between 1974 andNovember 1980 when paint sludge was placed in the dumpster. Beginning inDecember 1980 the peel filmite, paint sludge, and waste solvents weredisposed of as hazardous waste, through approved waste transporters agd ,TSDs. Prior to December of 1980, Stanley-Vidmar believes it disposed*' ';;wastes properly, but cannot document this since no manifesting or recorcf .keeping requirements existed previous to 1980. "?

As stated above, the only available information that may connectStanley-Vidmar with the landfill appears to be the records that EPAobtained from Mr. Novak. Those records indicate disposal at the landfillon 19 occasions between December 20, 1984 and May 10, 1985. During thatperiod of time, the trash consisted almost entirely of cardboard and paper.Minor quantities of cleaning rags may have been included with the normaltrash. However, the rags would have made up only a minute proportion ofthe total volume of trash placed in the dumpster.

Enclosed is a listing of pertinent information regardinginsurance for the period 1980-1988. Please note that while Stanley-Vidmarbelieves that coverage would be provided under these and, perhaps, otherpolicies, the carriers have not yet indicated their positions.

If you have any questions, please contact either Mr. Lawrence W.Diamond (201-535-5300) or Mr. Thomas M. Shaner, Plant Engineer forStanley-Vidmar (215-776-3859).

Sincerely,* X7 V

&<&**WILLIAM J. DPresident/General Manager

rrWJD/kak

ENCLOSURE 1 - Invoices & Load ReceiptsENCLOSURE 2 - Fixed Asset Inventory ListENCLOSURE 3 - MSDS SheetsENCLOSURE 4 - Laboratory ReportsENCLOSURE 5 - Insurance Information

- 3 -

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ENCLOSURE 1

Invoices & Load Receipts

REMITTANCE ADVICE <T.M. EV-V inMAE. . M r . C H E C K NO.

110

INVOICE DATE

1 01 81

* INVOICE NOS. | INVOICE AMOUNT

01-01-81 500.00

DISCOUNT

* 1 - INVOICE2 - CREWT MEMO TOTAL3 - OTHER DETACH HfSf BEFORE DEPOSITING CHECK

NET AMOUNT

500.00-»***

500.00

.i-a210

f_mm ^ ^ .. , _ 1777 GRAMMES ROADitamar INC. AUENTOWN, PA. 11103

No. 40554 OATt

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OOUARS CENTSNo. 452916/27/81

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REMITTANCE ADVICE ,11,., Ft.mni.iB. CHECK NO.

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INVOICE DATE

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Phone 395-6251 ,

VALLEY DISPOSALDiv. of Novak Landfill Corp.

MODERN SANITATION EXPERTSRD.1 BOX 246 i- - ~ • ' ' fc ' Allentown, Pa. 18104

DEC 14 1981 .ACCOUNTING ........12W.1............!!U1.......

...Stanley...Yidraar,Grammes Rd.

Altwn., Pa.

Removal Month of

Amt. $600.00

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REMITTANCE ADVICE STANLEY-VIOMAR, INC. CHECK NO. 5208e1

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MODERN SANITATION EXPERTSRD.1 BOX 246 Allentown, Pa. 18104

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AR2068I3

REMITTANCE ADVICE C-VTOMAP, TMC. ______CHECK NO.INVOICE DATE

6 01

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MODERN SANITATION EXPERTSR0.1 BOX 246 Allentown, Pa. 18104

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Phone 395-6251


MODERN SANITATION EXPERTSRD.1BOX246 - -, , Allenlown, Pa. 18104

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REMITTANCE ADVICE r,TANirY-VIC*Uw, INC. CHECK NO.

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INVOICE DATE

a 01 82

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TO THE P 0 BOX RD NO 1ORDER or ALLENTOUN PAL ' W 1

THE CHASE MANHATTAN BANK. NA1 Chase Manhattan Plaza. New YorKN.Y. 10015 NON-NEGOTIABLE


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REMITTANCE ADVICE -.TWr-VIOMR, FNC. CHECK NO.

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INC ! 1772 C«AMMES ROAD' AUENTOWN, PA. 18103

No. 54897^tw^iOOUASS ICINTSI

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VALLEY DISPOSLDiv. of Novak Landfill Corp.

MODERN SANITATION EXPERTSRD.1BOX246 Allentown, Pa. 1B104

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REMITTANCE ADVICE STaf.'irY-vinwA", T'iC. CHECK NO. -.

1010

INVOICE DATE

11 01 H?

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NET AMOUNT

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f-CO.OC

1-2210

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OOUARS CENTSNo. 56192 •S*Lll/ll/^Si

|~ VALLCY DISPOSALTO THE P 0 *0x PO NO 1ORDER OF ALLENTO'.'N PA 1L ..n*' " ) / . -

THE CHASE MANHATTAN BANK. NA.1 Chase Manhattan Pho. New York. N.Y.10015 . . ; . | NON-NEGOTIABLE

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Phone 395-8251

VALLEY DISPOSALD/v. of Novak Landfill Corp.

MODERN SANITATION EXPERTSRD.1 BOX 248 Atlentown, Pa. 18104

12-1 1982

Stanley Vidmar Inc.

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MODERN SANITATION EXPERTSRD.1 BOX 246 Allentown. Pa. 18104

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VALLEY DISPOSAL•3Allentown, Pa. 13104

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^ OUR NEW ADDRESS

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VALLEY DISPOSALDiv. of-Movak Landfill Corp.

MODERN SANITATION EXPERTSRD.1_B____t Allentown, Pa. 18104

Stanley-Vidmar. Inc.•••••••••••••••••••••••••*•«•••••••••«••••••••*••••*

Refuse Removal Month of ______April5 loads"® $160.00 ea. •*

Amt. $800.00

AR206882

REMITTANCE ADVICE STAMLCY-VIOf ARf INC. CHECK NO. 058 694*2

SO 7

INVOICE DATE

5 31 e** INVOICE NOS

05-31-84INVOICE.AMOUNT

sco. 30DISCOUNT

f 1 - ••'VOICE: -on MEMO TOTAL* '" r>cr»ru UCDB nccnpB neooeiTiuA r»uef*v «_<

NET AMOUNT

300*00

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..... 11 GRAMMES ROADINC. ALLENTOWN. PA. 18103

Nlo.058 069442 —r 7/06/84

VALLEY DISPOSAL

OOUARS (CENTS

,00

70THI OIV HOVAK LANDFILL CORP*1 BOX 268A

• AU.CN70UN PA 18104 ___________________THE CHASE MANHATTAN BANK. N.A. KI/ KI MC/»r\TIADlESYRACUSE. ME* Yowt NON-N cGOTl ABLE

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VALLEY DISPOSALDiv. of Nova* Landfill Corp.

MODERN SANITATION EXPERTSRD.1BOX248 Alien town, Pa. 13104

Stanley-Vidmar, Inc.«•••«•••••••*•••alA«*B«••••••••«•••i«»* ft ••*••••»••*•••

Refuse Removal Month of5 loads 5 $160.00

$800.00

AR206885

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REMITTANCE ADVICE sTAKLEY-VTDim. INC. CHECK NO. 058 7lGOfe

811

INVOICE DATE

7 31 84

* INVOICE NOS

07-31-S4

INVOICE AMOUNT

160.00

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TO THE DIV NCVAK LANDFILL CORP ^OROEROF RD *1 BOX 268A r^

i ALLENTOWN PA '18104 __________________^_THE CHASE MANHATTAN BANK. N.A. k.l/<\Kl MP/-/-VTI A Ol C

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Phone 395-6251

VALLEY DISPOSALDiv. of Novak Landfill Corp.MODERN SANITATION EXPERTS

RD.1 BOXCB Allentown, Pa. 181 4

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REMITTANCE ADVICE 8UHLCT-*IO!UIU INC. CHECK NO. 058 71743

939

INVOICE DATE

a 31 84

* INVOICE NOS

08-31-8J

INVOICE AMOUNT

963. 30

DISCOUNT

* 1 . INVOICE2 • CREDIT MEMO TOTAL3« OTHER ncTAi»u ueor QCCAQK neoneiTiun ~uBf*v "_•

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...— 11 GAAMMES ROADINC. ALUNTOWN. PA. 19103

No. 058 071743 OATt

10/04/34F VALLEY DISPOSAL

OIU NC\IAK LANDFILL CORPRQ Bl BOX 263A

i ALLSNTOV* PA 1310*THE CHASE MANHATTAN BANK. N.A. K< /-\MSYHACUSE. NEW YORK NvJrJ-

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Phone 39M251 • j-*jVf,V ' ADD,-;, 23 .

VAUEY D/SPOSU0/v. o/ A/ova* Landfill Corp.

VALLEY D13PCSd-OOERN SANITATION EXPERTSRe-iVBOfcftfl*! LANDFILL CORP. Allantown, Pa. 18104R.O. #1, BOX 263 AALLENTOWN. PA. 18104

Stainlay-Yidiinar, Inc.

11 Grammes Road*•*••••*•••»••••••••••••••••••••••••••»••*••••••••••••

AUentown, PA 18103

Refuse Removal Month of August6 Loads § $l60.00/ld.

Amt.

#v- S ;:JC K-v.; ::• SEP 19::''* y; . |j\\l

REMITTANCE ADVICE

1006

INVOICE DATE

9 3C £4

*CT£M FV-tTnwARt"TMr.

INVOICE NOS

09-3C-84

INVOICE AMOUNT ;

CHECK NO.DISCOUNT

* 1 -INVOICE2 -CREDIT MEMO •; ' " , TOTAL3 - OTHER DETACH HERE BEFORE BEPOSITIMR CHECK

r -m2i___NET AMOUNT

1*920. OC

1.920. OC

No. 058 072327 —10/25/8*

I VALLEY DISPOSALTO THE DIV HCIAK LANDFILL CORPORDEROF RO «1 BOX 268A

|_ ALLENTCVN PA 181C*THE CHASE MANHATTAN BANK. N.A.

SYRACUSE. NEW YORK

_Bi i i ^ ^ ______ ^ '." ' "'""'• SO-937%V". < , A*W,l3ll_U-_ ,j 213.».-, - 11 GRAMMES ROADINC. . ALLENTOWN, PA. 18103

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FORM NO. 0303 PS 10M 10/84

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MUiEV DISPOSALOUR NEW ADDRESS Div. of Novak Landfill Corp.

MODERN SANITATION EXPERTSR0.1 BOX 246 . . . . . ' . * Allentown, Pa. 18104

Se p t . 3 0 , i g 8-4

.Stanley-y idmar, Inc.

11 Grammes Road

AUentownT '

Refuse Removal Month of September6 loads i $l60.00/load

Amt.Pas -Sue August $960.00 -

T/tal Due $1920.00

AR206891f

, Pho1T395.4S80 ^ 395-6251

Phon. 395-4580——. - 395-6251 • . NOVAK'%%NOVAK'S • • SANITARY LAND FI%

SANITARY LAND FILL, INC. • RD i AUENTOWN,PAR.D. 1 • AUENTOWN/PA 18104 . . • p,, " *7* "VA *#</_

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MKO KWK tMT. MC

L. ME BURY YOUR TRASH43l_itMaMl^.| cor.

C01———'"

Phon* 395-4580 39*6251

NOVAK'S 'SANITARY LAND FILL, INC.

R.D. 1 • AlUNTOWNj. PA.. 18104

Ham*^_§

NO. OF LOADS

.WE BURY YOUR TRASH•Jrith tender loving cor*

ttKO «wm-«wT. we

REMITTANCE ADVICE STANLEY-VICEAE, U C . C H E C K NO. 058

12071208

INVOICE DATE

1110

1921

F«€4

* INVOICE NOS

11196*1021P.A

INVOICE AMOUNT

1«2?0«00320.QC

DISCOUNT

* 1 .INVOICEt -CREDIT MEMO _ TOTAL3 - OTHER nPTAr.H WFBF RPFftPP MPPCISITIMf! KHfKK ' I \J t ML

NET AMOUNT

li2?O.CC22C.OC

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No. 058 074272 JKSLCIV NOVAK LA^CFILL C09P

L

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SO-S37213

lgLf/-, : ' 11 GRAMMES ROADINC. ALLENTOWN. PA. 18103

1/03/85i— VALLEY CISFCSAl '————————Î nru mniiiiw t A t u n c T t t rnao l\ ^2.

COLLARS l s

THE CHASEÂNHATTAN BANK. N^. NON-NEGOTIABLE

•*o56071.2? .»• 1:0. _ .oq.?qi: &o i« eâe is

.-Phon«39M251 v. ' - ?, ........


MODERN SANITATION EXPERTSR0.1 BOX 248 * Allentown, Pa. 18104

Stanley-Vidmar, Inc.••••••••••••••••••••••••*••••••••••••••••*••••••••••••

11 Grammes Road

Allentovm, PA 18103

8 loads i $l60.00/load = $1280.00

Refuse Removal Month of October______

$1280.00

- $960.00

$320.00

to....... C)

Phone 395-4580 . ,395-6251 __---—— NQVAK'SI IVX V/\IX d ' • , • __• ^ _. _.liv _ v«4r t m _. ••*. f

N.m«

NO. OF LOADSNO. OF LOADS

00<y*co

E BURY YOUR TRASH _• 3a"-60*! Y?°.R TRAS" ^"- VE BURT TOUK 1KAM1 , ^ «T Hi* tender lovlnfl core i . ...;Jtender loving care

MC

Phone 395-4580 395-6251 - H Phon*) 395-6251 -_____• r"WI1- •"--—— v >NQVAJCS • NOVAK'S %

SANITARY LAND FILL, INC. • SANITARY LAND FIIL, C.• " a r» l . AllBklTnWKI B& \A1Q_ ^5

R.D. 1 - AtLENTOWN. PA.. 1°"" - ^ ™ *'°' * '

. ^^^^^___-Rone 395-4580 • 395-6251 ' •••••••^^ 395-6251

NOVAK'S • •". NOVAK'SSANITARY tATTD FILL, INC. _• SANITARY LAND FILL, INC.

R.D. 1 - ALLENTOWN. PA.. 18104 H R-D- ' • ALLEWOWS*. PA.. 18104/<? ' 2.

Nome

.NO. OF LOADS " NO. OF LOADS A/*_!-,

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Phone 395-6251

VALLEY DISPOSALDiv. of Novak Landfill Corp. <%>

MODERN SANITATION EXPERTSRD.1 BOX 246 . Allentown, Pa. 18104•>

Stanley-Vidmar»•*•••••••••••••••¥•*••••••*••••••••••••••

llGramBies Road

Refuse Removal Month of ____November

6 loads @ $l60.00/load =Amt. &1280.00

\

Phone 395-4580. . • - •''•'•. 395-6251NOVAK4S

SANITARY LAND FILL, INC.'R.D. 1 - AILENTOWN, PA., 13104.

Date /•/*?/W____ '/

Name

NO. OF LOADS

CC' '.V?!o HfE BURY YOUR TRASH__ frith tender loving care

KKO IWTt J«Kt. MC

Phone 395-4580 > 95-6251

NOVAK'S • ^fr-, NOVAK'S \fySANITARY LAND FILL INC • SAtfiTARtf LAflb FILLING.

R.D. 1 . AUENTOWN. PA. 18104 / " • ' R'D- ' ' AILENTOWM. PA.. 18104

"MfiU*/ Iij&njZt*.

NO. OF LOADS

BURY YOUR TRASH "; « r*E BURY YOUR TRASHith tender loving core - ^H _j -Jrith tender Icving care

MC. • ; . . ._ *nco KWK HNT. INC

Phone 395-4580 395^251_H Phone 395-4580 395-6251

NOVAK^S • NOVAK'SSANITARY LAND FILL INC. • SANITARY UfFHTFILL, INC.

R.D. 1 ALLENTOWN. PA., 18104 H R-°- 1 • AUENTOWN, PA., 18104

.. // • ts '»• g_Yf/ /ft" I//fat,* Name

NO. OF LOADS .1 _. _ _| NO.'OF LOADS

\.*A-

Q tf E BURY YOUR TRASH ^ (VE BURY YOUR TRASHQ f irh tender loving core . H Qrith tender loving care

ttico K»m*t»a. mtc. . ' • mco nm*t»a. MC.

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AR206903

Phone 395-6251

DISPOSALk Landfill Corp.ITATION EXPERTS

RD.1 BOX 246 Allentown, Pa. 18104

Div. of Novak Landfill Corp.MODERN SANITATION EXPERTS

/\

' 1C,

Refuse Removal Month of ___December6 loads i $l60.00/load =

Amt.Past Due Oct. $320.00 - Pd C* *"Past Due Nov. $1280.00- P 1*1 2*1 2>

Total Due - $2560.00

_-oO

AR206901*

Phon. 395-4580 395-6251

NOVAK'SSANITARY. LAND FILL, INC.

R.D. 1 - AUINTOWN. PA., 18104

Ham* — — — —-•— —- f •

NO. OF LOADS

.i. -»o!*i5 .-•--

&S

t

«neo xwitnMr. MC

-WE BURY YOUR TRASHfrith tender loving cart

•'?*'JES*.

NO. OF LOADS

. r¥E BURY YOUR TRASH£|. ith tender loving care

"""NOVAK* "62" OVAK'S RtCYCLINcTSANITARY L/CNlf FILL, INC.

R.D. 1 - AILENTOWN, PA., 18104

.., REcJcJjJG TO SAVE YOUR RESOURCES

1- .--'-*• A- ^

395-6251 i phone 395-4580 . 395-6251

NOVAK'S RECYCLING I NOVAK'SR 0 1 246 I SANITARYHLAND FILL, INC.

AllENTOWN, PA. 18104 J, \ R'D- ' ' AILENTOWN, PA.,

'Dote -S? ~S *•

Nome,

SERVICE

Nome.

RECYCHMG TO SAVE YOUR RESOURCESl . KKO KwiK.fniNT. IMC. "• ttico mm toa weI .-

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E BURY YOUR TRASH5th tender loving core

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MODERN SANITATION EXPERTSRD.1BOX246 ' Allentown, Pa. 16104

Stanley-Vidmar, Inc.

11 Grammes Rd.

Allentown.PA 1810JF

Refuse Removal Month of _____January6 Zoads e $315.00/load

Arnt. 1890.00

-:; ; LLEY-. ,?/OUR NEW ADDSESS R.o' «?"'-;..Ui<;

«F •• ' / -si" t3?V j - f "•' '•' ~

395-6251

NOVAK'S RECYCLING*Diu. LCfl Inc.

R.D. |1. BOX 246ALLENTOWN, PA. 13104

Dote

l*?S fcfc£«» ---..--* .* ji. tfi r-Si l--£*•

REC_CljJie TO SAVE YOUR RESOURCESKKO -*»**•»*. •*••

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NOVAK'S RECVCLING

Kome

(sOVAK'SR.D. #1. BOX 246

ALLENTOWN, PA. 18104

TO SAVE YOUR RESOURCES. me. ...

395-6251NOVAK'S RECYCLING

Diu. LCNInc.R.D. #1, BOX 246

ALLENTOWN, PA." 18104Date

Phone 395-4580 395-6251

NOVAK'SSANITARY LAND FILL, INC.

R.D. 1 - ALLENTOWN. PA.. 18104 ^

NO. OF LOADS

BURY YOUR TRASHTO SAVE YOUR RESOURCESMKO KwiK-raiNf INC. _fh tender loving careMKO «wmHiiii. me ,

REMITTANCE ADVICE ST«M,CY- VI 0MA9 » INC. CHECK NO. 058 T<i767•'

;>. 303

'•*''.

INVOICE DATE

2 28 *5

* INVOICE NOVS

022885 '. INVOICE AMOUNT

.liS^C.OC

DISCOUNT

•

'•;•' * 1 - INVOICE•;-. 2- CREDIT MEMO TOTAL>.'• ' • OTHER rteT & u LJCBC aecnce newheiTiun uc/ w

NET AMOUNT

l%%t

50-937213

_- tm* 11 GRAMMES BOAOtOiiia" INC. ALLENTOWN,PA. uioa

No. 058 076767 —v i v i w f 3/ai/asp VALLEY OISPCSAl

TOTHe ' 0!V NOVAK LANDFILL COPPOROEROf R0 B1 BOX

DOLLARS I CENTS

M; .-I'

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SANITARY LAND FILL, INC.R.D. 1 • ALLENTOWN. PA.. 18104

n-.. 3./? */<*-TCs—J- ff ' // <

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/#-*«/ 'NO. OF LOADS

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ENCLOSURE 2

Fixed Asset Inventory List

1*20692,

ENCLOSURE 3

Material Safety Data Sheets

AR206935

MATERIAL SAFET'i . . .'..-. SHEET\ ff ' /"/XL- /A

EASTMAN CHEMICAL PRODUCTS, INC.Kingsport, Tennessee 37662

For Health Hatard Information, call: (615) 229-6094• * •'•'•'. '- •'<$

For other information, call: (615) 229-2000 . Date of Preparation: 06-19-8>.o.

SECTION I. IDENTIFICATION

- Product: "EKTASOLVE" DB acetate

- Synonyms: Diethylene glycol monobutyl ether acetate, 2-(2-Butoxyethoxy)ethylacetate

- Formula: 04119(002*14)20000113- Molecular Weight: 204.27

SECTION II. PRODUCT AND COMPONENT HAZARD DATA :

•. , . . , ; Approx EastmanA. COMPONENT: Weight I CAS Reg No Kodak No

2-(2-Butoxyethoxy)ethyl acetate 100 124-17-4 902865

See Section VI-A for information on exposure limits.

B. PRECAUTIONARY LABEL STATEMENTS:

WARNING! MAT FORM EXPLOSIVE PEROXIDES

Store away from heat and light. .

Since emptied containers retain product residue, follow label warnings evenafter container is emptied.

• . * '

SECTION III. PHYSICAL DATA

- Appearance and Odor: Colorless, slightly viscous liquid; faint, pleasant odor.- Boiling Point: 246'C (475'F)- Melting Point: -32'C (-26'F)- Specific Gravity (H20 - 1): 0.98 at 20'/20*C- Vapor Pressure: 0.04 mm Hg at 20*C- Volatile Fraction by Weight: Negligible.- Vapor Density (Air ,« 1): 7.0 . , _ ; . . ;- Solubility in Water: Moderate^^" : ' fV • • v * .

rt MSDS-10,180A-1 (06-85)P fi U ^ Replaces 05-85 Edition -I

'CTION 17. FIRE AND EXPLOSION HAZARD DATA

-FlashPoint: 114*C (237'F); Method Used: Cleveland Open Cup. *- Autoignition Temperature: 201*0 (394*7); Method Used: ASTM E 659- Flammable Limits: LEL 0.76X at 135'C (275'F) UEL 10.71 at 203*C (397'F)- Extinguishing Agent: Water Spray, Dry Chemical, "Alcohol" Foam, or CC .- Special Fire-Fighting Procedures: Wear self-contained breathing apparatus andprotective clothing to prevent contact with skin and eyes. Use water spray tokeep fire-exposed containers cool.

- Unusual Fire and Explosion Hazards: 'May self ignite at the upper explosion limitconditions.

SECTION V. REACTIVITY DATA

- Stability: Unstable at elevated temperatures (may form explosive peroxides). At100*0, 2 h are required to reach a peroxide No. of .100.

- Incompatibility: Oxidizing materials can cause a vigorous reaction.- Hazardous Decomposition Products: As with any other organic material, combustionwill produce carbon dioxide and probably carbon monoxide.

- Hazardous Polymerization: Will not occur.

SECTION VI. TOXICITY AND HEALTH

A. EXPOSURE LIMITS

- OSHA Permissible Exposure Limit (PEL): Not established.- Threshold Limit Value (TLV): Not established.

B. EXPOSURE EFFECTS

Inhalation; Low hazard for usual industrial handling. .

Eyes; Low hazard for usual industrial handling. However, any material thatcontacts the eye may be irritating.

Skin; Low hazard for usual industrial handling.' * •

C. FIRST AID

Eyes: Any material that contacts the eye should be washed out immediately andmedical attention obtained if any symptoms are present after washing.

D. ANIMAL TOXICITY DATA

. Acute ToxicityTest Species Result (1) Classification (2)

Acute oral LD5Q -Rat 6.9 to 11.9 g/kg Practically nontoxicAcute oral LDjg : .Mouse * 6.6 g/kg

.;.Acute oral. LpsQi G-iriea pig V 2.3 to 2.7 g/kg;- Acute oral, U)5p < ;Rabblt 2.3 to 2.7 g/kg'V-DarJB'al LD5(j'-- v"v:-::"- Rabbit 5.4 to 14.5 g/kg Practically nontoxic« Skin irritation Rabbit SlightEye irritation Rabbit Slight

A R 206 9? 7 MSDS-10,180A-2 (06-85)' "* r Replaces 05-85 Edition

7.1. 7?a4,'£. J: .

DOT Hazard Classification: Not regulated by DOT.

SECTION XII. REFERENCES. - : ; • - . . ; > -

1. G. D. 01 ay ton and F. E. 01 ay ton, Editors. '. PATTY'S INDUSTRIAL HYGIENE ANDTOXICOLOGY, 3rd Revised Edition,'Volume 20. Wiley-Interscience, New York,1982, pp. 4027-4028. • - , . . .

2. AM IND HYG ASSOC Q 10, 93-96, (1949).i

3. Unpublished data, Health and Environment Laboratories, Eastman Kodak Co.,Rochester, New York.

The information contained herein is furnished without warranty of any!kind. Usersshould consider these data only as a supplement to other information- gathered bythem and must make independent determinations of suitability and completeness ofinformation from all sources to assure proper use and disposal of these materialsand the safety and health of employees and customers.

,..*• «•«.- v . • _ • _ > 'i .••-.- . .£• . . . _• -*;. . .- -*T-_J "».; -iy !»•!» .- •._-.r,,rL; »*.**, iiU.»" - «x .

1338S/902865/R-1/S-1/F-1/C-1MSDS-10.180A-4 (06-85)

°5'85fy 6528

/ ) ligjpgjflfrtyism and Fate Study; In an in vitro, study, diethylene glycol monobutylattSstt acetate {DB acetate) was rapidly metabolized to diethylene glycol mono-butyl ether (DB solvent). Therefore, it is reasonable to conclude that*thetoxicological properties of DB acetate would be essentially the same as those ofDB solvent. (3) For detailed toxicological data on DB solvent, SeeMSDS-10,176A. '

————————————————————————————:——————————————i————————— /SECTION VII. PERSONAL PROTECTION AND' CONTROLS

A. VENTILATION

Good general ventilation (typically 10 air changes per hour) should besufficient to control airborne levels. Ventilation rates should be matched toconditions. Supplementary local exhaust ventilation, closed systems, orrespiratory protection may be needed in.special circumstances such as poorlyventilated spaces, evaporation from large surfaces, spraying, heating, etc.

3. RESPIRATORY PROTECTION

If respiratory protection is needed, an appropriate NIOSH-approved respiratorfor organic vapor should be worn. If respirators are used, a program should beestablished to assure compliance with OSHA Standard 29 CFR 1910.134.

C. SKIN AND EYE .PROTECTION

Safety glasses are recommended for any type of industrial chemical handling.Good industrial hygiene practice should be followed which includes preventingeye contact and minimizing skin contact.

SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS

Peroxide former. Store away from heat and light. After opening, purge containerwith nitrogen before reclosing. Periodically test for peroxide formation onlong-term storage. Addition of water or appropriate reducing agents will lessenperoxide formation.

Since emptied containers retain product residue, follow label warnings even aftercontainer is emptied.

SECTION IX. SPILL. LEAK. AND DISPOSAL PRACTICES

Steps to be Taken in Case Material ia Released or Spilled: Small spills may becollected with absorbent materials. For large spills, flush area with waterspray. Prevent runoff from entering drains, sewers, or streams.

Waste Disposal Method: Incineration. Observe all federal, state, and local lawsconcerning health and environment.

• • •-_•••- -Si • ' •• -'• -. . - ' • . ;SECTION X. ENVIRONMENTAL EFFECTS DATA • .--'This material has not been tested for environmental effects.

flf?9fi£-/v MSDS-lO,180A-3 (06-85)y" 4;Uf> 329 Replaces 05-85 Edition

MATERIAL L £TY DATA SHEET B, . . - . , - . . EASTMAN CffiMICAL PRODUCTS, IHC. • ?I Kingsport, Tennessee ''37(562 ^v

i •'} -For Health Hazard Information, call: (615) 229-6094, 8am-5pm (Eastern),

(615) 229-4374 at all other times

For other information, call: (615) 229-2000 Date of Preparation: 04-18-85* • . I

Form Approved by U. S. Department of Labor: Essentially Similar to OSHA-20

SECTION I . IDENTIFICATION : . . . - . -

- Product Name: EKTASOLVE* EE Acetate Solvent

- Synonym(s): Ethylene glycol monoethyl ether acetate; 2-Ethoxyethyl acetate- Formula: 02 00 2*14 OCOCH3 >- Molecular Weight: 132

SECTION II. PRODUCT AND COMPONENT HAZARD DATA

Approx.A. COMPONENT:' * Percent TLV* CAS Reg. Ko.

2-Ethoxyethyl Acetate . 100 5 ppmf

111-15-9

i i *See Section VI-A for additional information on exposure limits.

B. PRECAUTIONARY LABEL STATEMENTS:'

WARNING! MAY CAUSE'ADVERSE REPRODUCTIVE EFFECTS ; 'HARMFUL IF INHALED OR ABSORBED THROUGH THE SKIN •CC«BUSTIBLE , i

Avoid breathing vapor.Avoid contact with eyes, skin, and clothing. ' . v-IKeep container closed. . .. ",'' '• ' .'... '''•••PV.'T"' . " ' ' ;' "" . 'Use with adequate ventilation. -\; . •;Wash thoroughly after handling.Keep away from heat and flame. .

FIRST AID: If inhaled, remove to fresh air." Treat symptomatically. Call aphysician. In case of contact, immediately flush.eyes or skin with plenty ofwater for at least:15 minutes.while,removing contaminated clothing and shoes.Call a physician. '. Wash clothing"before reuse ?'- ;--r V : ::.v:'\ . ' .

• ;.:--v- •'•-? ••'•.'?.''. •••'•<.,':>-:'-f-'--~-Zt??' ' •IN CASE OF FIRE: Use dry' chemical ' "" "Water

. .exposed

MSDS-16.101A-1 (04-85)Replaces 06-82 Edition

SPILL: Eliminate all ignition sources. Flush spill area with waterrevent runoff from entering drains, sewers, and streams. a

- . t" Since emptied packages retain product residue, follow label warnings even afterpackage is emptied.

______________________________________________________-_-«__, ^SECTION III. PHYSICAL DATA

- Appearance and Odor: Colorless liquid, mild ester-like odor.- Boiling Point: 156*C (313"F)- Specific Gravity (H20 » 1): 0,975 at 20*/20*C- Vapor Pressure: 1.3 mm Hg at. 20*0- Percent Volatile by Volume: Approx 100- Vapor Density (Air '» 1): 4.7- Evaporation Rate (n-butyl acetate » 1): 0.2- Solubility in Water (X by Weight): 23.9 at 20*C

SECTION IV. FIRE AND EXPLOSION HAZARD DATA

- Flash Point: 54'C (130*F); Method Used: Tag Closed Cup.- Autoignition Temperature: 382*0 (720*7); method used: ASTM E659-78- Flammable Limits: LEL 1.24Z at 93*C UEL 12.71 at 135*0- Extinguishing Agent: Dry Chemical, 002, "Alcohol" Foam, Water Spray.- Special Fire Fighting Procedures: Wear self-contained breathing apparatus andprotective clothing to prevent contact with skin and eyes. Use water spray tokeep fire-exposed containers cool.

SECTION V. REACTIVITY DATA

- Stability: Stable.- Incompatibility: Oxidizing materials can cause a reaction.- Hazardous Decomposition Products: As with any other organic material, combustionwill produce carbon dioxide and probably carbon monoxide.

- Hazardous Polymerization: Will not occur.*

SECTION VI. TOXICITY AND 'HEALTH

A. EXPOSURE LIMITS

- Threshold Limit Value (TLV): 5 ppm-TWA, "Skin Notation", ACGIH, 1984-85.- Eastman recommends that the above TLV be used as an exposure limit.- OSHA Permissible Exposure Limit (PEL): 100 ppm-TWA,."Skin Notation".- A NIOSH industrial hygiene analytical method is available. (1)-Another industrial hygiiane analytical method is available'to health and

V safety profesaionais upon request•'•'?'••' • -'•:'-.'-• V'" -V r*-v"rt:::'-' ;r ''.-*< : "••'•.

B._EXPos ''EFFE<:T ; ; ::-r'"-;.''- •"*•'- • ' '•••-: ; •:-*'• W::* ; :;,-/•..-,"•:•;.•-•*-' General; Studies in experimental animals have produced?damagiBr>tb^the'sperm- . - :'•' producing cells of the teaticle when males were exposed and birth jdefecta when •'_'pregnant females'were exposed. r ~ -. '::*.- • • ' ^ ^ft: y ^..:--'' - '.•


--." thoi:<:,. the cdci ti .~lc (10G» : ;gr.'.><~ ) is C.25 ppni (13^. w'.c odor isr.ot sufficiently objc-cri enable at J 'Ciic in the range of the TLV of 5provide good warning properties. ;

- •••-•- •-'"' '' ''-' •InhalatioTi ;j "May be harmful-If inhaled. : . £>

Eyes; No specific hazard known to Eastman. Any material gotten into the eyemay be irritating.

Skin; May be harmful if absorbed through the skin. ,

Summary; Predicted effects listed above are baeed on experimental animaldata. No adverse effects in humans have been reported from exposure to thismaterial. (3)

C. FIRST AID

Inhalation; Remove to fresh air, treat symptomatically, and get medicalattention. i •

Eyes; Any material gotten into the eye should be washed out immediately andmedical attention obtained if symptoms are present after washing.

Skin; Immediately flush with plenty of water for at least 15 min while re-moving contaminated clothing and shoes. Get medical attention. Washcontaminated clothing before reuse.

D. ANIMAL TOXICITY DATA

Test Species ResultAcute ToxicityClassification (2)

tactically nontoxictactically.nontoxic

Acute Oral LD50 Male Rat 3.90 g/kg (4) Slightly toxicAcute Oral U>$Q • Female Rat 2.90 g/kg (4) .Slightly toxicAcute Oral LD50* Rabbit 1.95 g/kg (3)Acute Oral LD50 Guinea Pig 1.91 g/kg (3)Dermal LD50 Rabbit ' 10.3 g/kg (3)Dermal LD50 Rabbit 10.5 g/kg (4) IDermal LD50 : r * Guinea Pig >20 mL/kg (5) • IInhalation LC50 " " Rat - >2000 ppm/4 h (4)Inhalation LC50 Rabbit >2000 ppm/4 h (4)Skin Irritation Guinea Fig Slight (5)Skin Irritation Rabbit Very Slight (4)Eye Irritation Rabbit Slight (5)Eye Irritation . Rabbit Nonirritating (4)

Subchronic Studies; Three.adult male dogs were exposed to an airborne concentration of 600 ppm for 6 h/day, 5 day/wk, for 120 exposures. No adverseeffects were reported on weight gain, clinical signs,'hematology,.clinicalchemistry, gross pathology," or histopathology, (organs examined: liver, kid-ney, adrenals-thyroid, bladder, heart, intestine, lung, pancreas, spleen, andteetie). ' ' '

Groups of 10 male and 10 female rats and 2 male and 2 female rabbits .were ex-posed to an airborne concentration of 200 ppm for 4 h/day, 5 day/wk,;for ...10 mo. The only adverse effect reported was a renal tubular Nephritis in maleand female rabbits and male rats; no adverse effects were reported in femalerats. (4)


r t

i Groups of 5 male mice were given 500, 1000, 2000, or 4000 mg/kg/day by gavage,-,5 day/wk for 5 wk. No toxicologicaily significant effects were observed at• SjLoiB/k fy .At .1000. fflg/kg, minor teaticular effects weifff observed. At

-- adOo ing'/fcgrV decreased white cell count arid mfnorVeaticular effects were ob-served. At 4000 mg/kg, adverse effects included decreased white cell counts*reduced hematocrit (although hemoglobin and red cell counts were normal), andsevere testicular effects. (7)

Teratology Studies: Pregnant rats were exposed to airborne concentrations of130, 390, or 600 ppm, 7 h/day, 6n days 7-15 gestation . At 600 ppm there wastotal embryolethality. At 390 ppm, increased embryofetomortality, embryo-fetotoxicity, and several cardiac malformations were observed. At 130 ppmembryofetotoxicity and marginal teratogenicity were observed. (8)

Pregnant rabbits were exposed to airborne concentrations of 25, 100, or400 ppm, 6 h/day on days 6-18 of gestation. At 400 ppm, maternal toxicity,substantial embryofetomortality, teratogenicity, and embryofetotoxicity wereobserved. At 100 ppm, slight embryofetotoxicity was observed; 25 ppm was a noobserved effect.level. (9) " '" ---

Pregnant rats and rabbits were exposed by inhalation to airborne concen-trations of 50, 100, 200, or 300 ppm on gestation days 6-13 (rabbits) or 6-15(rats). In rabbits, maternal toxicity and embryofetotoxicity were observed atlevels MOO ppm; embryomortality and malformations were observed at 200 and300 ppm. In* rats, maternal toxicity and embryfetotoxicity were observed atlevels MOO ppm; malformations were observed at 200 and 300 ppm. A no observedeffect level of 50 ppm was observed in both studies. (10)

•

Other Studies; Studies in beagle dogs have shown that 2-etboxyethyl acetate isabsorbed through the lungs and skin. (11)

SECTION VII. PERSONAL PROTECTION AND CONTROLS ' .

A. RESPIRATORY PROTECTIONr

An appropriate NIOSH-approved respirator for organic vapor should be worn ifneeded. See Section VI-A for detailed information-on exposure limits.

B. VENTILATION;'•-•?'t\ "•>>£»;' .... •

General; Recommend at least 10 air changes per hour for good general room ven-tilation. " ' ' * . . . '

Local Exhaust: Recommended to control vapor. See Section VI-A for detailedinformation ott exposure limits.

Safety glasses shouldTbeTworn in 'any type of industrial operation. ~ Protectivegloves should be 'worn 'i?An' impermeable apron or smock should be worn to mini-_!_..._feJ_.- v_I.fc'««i!'.*i'Xi;Sv>r9' :. .*.'•'. V'.r '. •-'. r"-''T£v'> '• »'• ••..'*.-'•'•' ' - . • • • • • -iai''i '. v «'-^. •'•''•'-.a Kin-

A> safety shower, an eye bath, and washing facilities should be available. Washthoroughly after handling. Keep container closed.

MSDS-10,10lA-4 (04-85)Rejilaces 06-82 Edition

-.C'IiO.' VIII. SPECIAL STORAGE AND HA"

. Material is classified as a Combustible Liquid. Keep away.from heat and

Since emptied packages retain product residue, follow label warnings even afterpackage is emptied. . , . . . . . . .

SECTION IX. SPILL. LEAK. AND DISPOSAL PRACTICES

Steps to be Taken in Case Material is Released or Spilled: Elimin ate all ignitionsources. Small spills may be collected with absorbent materials. For largespills, flush area with water spray. Prevent runoff from entering drains, sewers,or streams. ,

Waste Disposal Method; Incineration. Observe all federal, state and local lawsconcerning health and environment.

SECTION X. ENVIRONMENTAL EFFECTS DATA

A. SUMMARY: This chemical has been tested for environmental effects. Somelaboratory test data and published data are available for this I chemical, andthese data have been used to provide the following estimate of environmentalimpact:

This chemical has a high biological oxygen demand, and it is expected to causesignificant oxygen depletion in aquatic systems. It has e low potential toaffect aquatic organisms. It is readily biodegradable and is not likely tobioconcentrate. If diluted with a large amount of water, a small quantity ofthis chemical released into the environment is not expected to have a signifi-cant impact. ' - . • • • •

B. OXYGEN DEMAND DATA: • ...

- COD: 1.63 g/g (5)- BOD5: 0.8 g/mL (5) f T

C. ACUTE AQUATIC EFFECtS:. . ;

- 24-hour LC50; goldfish: 160 mg/L C12)

SECTION XI. TRANSPORTATION

DOT Hazard Classification: Combustible LiquidFlashpoint: . See Section .IV. ;

* "• ' *•' . -• - •.«**»€• j, '*,'1 . ,1 — fj«

SECTION XII. REFERENCES-•-... ••.-;.- . ".-, ., : • -;.*•,. .-*. •

1. KIOSH Manual of Analytical Methods. (2nd Edition,) Volume 2. Issued by theNational Institute,for Occupational Safety and Health.'Washington, U. S.Ga-ffernment Printing Office, 1977, Method S41.. :V . -;.: -.U,,: _:."

2. H. C. Hodge and J. H. Sterner. Tabulation of toxicity classes. Am. ind. Hyg.Assoc. Q. 1949; 10:93-96.

MSDS-10,10lA-5 (04-85)«' • r - r. * C ' Replaces 06-82 Edition

"'" ' •> i;* .S : • "«'<

f t

3}. G. D. Clayton, F. E. Clayton, Editors. Patty's Industrial Hygiene and• Toxicology, 3rd Revised Edition, Volume 2C. New York, Wiley-Interacience,

_ ...4. R. TrufiStot, H. Dutertre-Catella, N. Phu-Lich, and V. N. Buy en. Comparative

toxicological study of ethylglycol acetate and butylglycol acetate. Toxicol .Appl. Pharmacol. 1979; 51: 117-127.

5. Unpublished data, Health and Environment Laboratories, Eastman Kodak Co.,Rochester, New York.

6. C. P. Carpenter. "Cellosolve". J. An. Med. Asaoc. 1947; 135: 880.

7. K. Nagano, E. Nakayama, H. Oobayashi, T. Nishizawa, H. Okuda, and K. Yamazaki.Experimental studies on toxicity of ethylene glycol alkyl ethers in Japan.Environ. Health Perapec. 1984; 57:75-84.

8. B. K. Nelson, J. V. Setzer, W. S. Brightwell, P. R. Mathinos, M» H. Kuczuk,T. E. Weaver and P. T. Goad. Comparative inhalation teratogenicity of fourglycol ether solvents and an'araino derivative in rats. Environ. HealthPerspec. 1984; 57:261-271.

9. J. E. Doe. Ethylene glycol monoethyl ether and ethylene glycol monoethyl etheracetate teratology studies. Environ. Health Perapec. 1984; 57:33-41.

10. R. W. Tyl. A teratologic evaluation of "Cellosolve" acetate in Fischer 344rats and New Zealand white rabbits following inhalation exposure- unpublisheddata, Bushy Run Research Center, Union Carbide Corporation, Export,Pennsylvania.

11. D. Guest, M. L. Hamilton, P. J. Deisinger, and G. D. DiVincenzo. Pulmonary andpercutaneous absorption of 2-propoxyethyl acetate and 2-ethoxyethyl acetate inbeagle dogs. Environ. Health Perspec. 1984; 57:177-183.

12. A. L. Bridie, J. C. M. Wolff , and M. Winter. The acute toxicity of some petro-chemicals to goldfish. Water Res. 1979; 16:623-626.

13. K. Verschueren. Handbook of Environmental Data on Organic. Chemicals, 2ndEdition. New York Van No9,trandReinhold Company, 1983, pp.. 650.

'.--.'—•-': '•" :-ya&fr :.:. . .-'' ../" ". '--•_''_•_ . .. _ - -• • —••"-£'• •--;••-. ^ •-..:./..-- --.:•-

The information contained herein is furnished without warranty of any kind. Usersshould consider these data only as a supplement to other information gathered bythem and must make independent determinations of suitability and completeness ofinformation from all sources to assure proper use and disposal of these materialsand the safety and health of employees and customers.

MSDS-10,10lA-6 (04-85)Replaces 06-82 Edition

- v.»J • ,.-..: ••»

MATERIAL SAFETY DATA SHEET cEASTMAN CHEMICAL PRODUCTS, INC.

- . .Kingsport, Tennessee 37662.

For Health Hazard Information, call: (615) 229-6094, 8am-5pm (Eastern), Kon.-Fri.(615) 229-4374 at all other times

For other information, call: (615)'229-5305 Date of Preparation: 05-28-85

Form Approved by U. S. Department of Labor: Essentially Similar to OSHA-20

SECTION I. IDENTIFICATION

- Product Name: "EKTASOLVE" PM Acetate . .

- Synonyms: Propylene glycol nonomethyl ether acetate; l-Methoxy-2-propanol acetate- Formula: - - -- Molecular Weight: 132.16

SECTION II. PRODUCT AND COMPONENT HAZARD DATA

Approx.A. COMPONENT: Percent TLV CAS Reg. No.

l-methoxy-2-propanol acetate 100 Hone 108-65-6

B. PRECAUTIONARY LABEL STATEMENTS: ...........

WARNING! MAY FORM EXPLOSIVE PEROXIDESCOMBUSTIBLE ' : ' .

iKeep away from heat and flame. , >

^

IN CASE OF FIRE: U«.e water spray, dry chemical, "alcohol" foam', or O>2. "Usewater spray to keep fire-exposed..containers cool.. .. , , . .......

IN CASE OF SPILL: Eliminate all ignition'sources. Flush spill area with waterspray. Prevent runoff from entering drains, sewers, and streams.

Since emptied packages retain product residue; follow .label warnings even afterpackage is emptied. • •• ' ' . •.'..'•... .-;• .-,H".. •:'" T" ' . '

SECTION III

- Appearance 'and.(Molri/fiCoioir'le.ss.ll'iiquli'tfith.- Boiline Point: > 150lC 302*F)-v, »,*,;«,. ; .'1?!' ';'-«.""" -'*'."" •' '*•" V":''i ' X::Boiling . r . ,- Specific Gravity; (H,0 V i):& 0,9169 20'C " '*••* .

- Vapor Density XAir «J; \;.,,N~ot Xet i™ i"'*T ' :"'! '- Evaporation Rate (n-butyi-a eta'te i): 0.39- Solubility in Water: Approx 202, appreciable.

MSDS-10 274A-1 C05-85 )H.PI.C.. 07-.3 edUion

SECTION IV. FIRE AND EXPLOSION. HAZARD DATA~~""~ *•- ••-;. •=.* -.— . " " ~ -". •'-••->• •-- - . . . . ' . _ • . ' " . . _.r.T.... • -

- Flash Point: 45.5*C (114 *F); method used: Setaflash closed cup- Autoignition Temperature: 354.4*0 (670*F); method used: ASTM E 659-78- Flammable Limits: LEL 1.3% at 73.3*0 UEL 13. 1Z at 139.4*0- Extinguishing Agent: Water Spray, Dry Chemical, 002, "Alcohol" Foam- Special Fire-Fighting Procedures: Wear self-contained breathing apparatus andprotective clothing to prevent contact with skin and eyes. Use water spray tokeep fire-exposed containers cool.

- Unusual Fire and Explosion Hazards: None known to Eastman.

SECTION V. REACTIVITY DATA [

- Stability: Unstable at elevated temperatures (may form explosive peroxides).- Incompatibility: Oxidizing materials can cause a vigorous reaction.- Hazardous Decomposition Products: As with any other organic material, combustionwill produce carbon dioxide and probably carbon monoxide.

- Hazardous Polymerization: Will not occur.

SECTION VI. TOXICITY AND HEALTH

A. EXPOSURE LIMITS ,' * " . . . - • ~ - _ _ ~ -

- OSHA Permissible Exposure Limit (PEL): Not established.- Threshold Limit Value (TLV): Not established.

B. EXPOSURE EFFECTS

Inhalation: No specific hazard known to Eastman.

Eyes: No specific hazard known to Eastman. Any material gotten into the eyemay be irritating.

Skin; No specific hazard known to Eastman.

Ingest-on: -Classified ..a j ."praeticaj.ly nontoxic" by single oral dose testing inanimals . " '"* ""''""" ' - • "vvai--" • . -** - ....-.-—.. --,--. .*. • .. - •%.. .:••<-.- - • ••

* ' 7 - ' * ' *.- V : - ";

C. FIRST AID .

Inhalation; Remove from exposure, treat symptomatically, and get medicalattention if symptoms persist.

Eyes; Any material gotten into the eye should be washed out immediately andmedical attention obtained if symptoms are present after .washing. - .v. V ;,

Skin; Fluihc with 'plenty of water. 'Get medical attention if any symptoms are

; water, and aticking finger down throat. Get medical attention as .aoon as-pos-sible*. Never^ give, anything by mouth to an unconscious person. -'"'' '. •• . •••

MSDS-10,274A-2 (05-85)Replaces 07-8:

I ANIMAL TQXICITY DATA»

^ • : • •• • ' - v. • '-' V • Tbxicity ,,.....Test :? Species Result ^ claafif icat&>a& J)

Acute oral LDjg Male rat > 10 g/kg (2) Practically nontoxicAcute oral LD5Q Female rat 8.5 g/kg (2) Practically nontoxicInhalation LC5o Male rat >4345 ppm/6 h (3)Skin irritation- Rabbit Slight (2)Skin irritation Guinea pig Slight (2)Repeated skin application Rabbit Slight (3)Eye irritation Rabbit Slight (3)

Inhalation Study: Male and female rats and mice were exposed to airborne con-centrations of 300, 1000 or 3000 ppm, 6 hours/day, 5 days/week, .for9 exposures. (3)

- Weight gain: Normal.-Clinical signs: Normal. . . 'i- Hematology: Normal.- Clinical chemistry: Normal.- Urinalyses: Non-statistically significant lowering of specific gravity inrats only at 3000 ppm. (Mice not evaluated.) ) ..

- Body/organ weights: Minor aberrations in some liver and spleen weights notbelieved to be toxicologically significant. . . .

- Gross pathology: Reticulated appearance in kidneys of male rats at 3000 ppmand in 2 of 5 male rats at 1000 ppm. ,

- Histopathology: Slight increase in eosinophilic granularity of proximal con-voluted tubules in male rats at 3000 ppm and in 1 of 5 male-rats at1000 ppm. -Slight to moderate degeneration of olfactory epithelium in severalrats at 3000 ppm; this, effect was present in mice in-a dose-related manner atall exposure levels. . .

SECTION VII. PERSONAL. PROTECTION AND CONTROLS • • . • .

A. RESPIRATORY PROTECTION . •

An appropriate NIOSH-approved respirator for organic vapor should be worn ifneeded. .. _...._.....jr. V..... "-,- . ..... .-:.,.,.,..,,: .',„.,-• .'.,-. • .f .: ;- . . ~r'

B. VENTILATION X;/ . " ~* *

General; Recommend at least ten air changes per hour for good general roomventilation. •'• v .... -.-: . . .

Local Exhaust; If needed to control vapor. Maintain workroom air concen-trations' below irritating.levels., v . .• .'".vS,:'•;••,.. -,'-'_-,^:. -.-»•.; ,:.-; -•

CM f A + rnr _-* 1 a « •_%• _~itk_^««l_4 KA V*-ts>/-t«Mn • 4 M Antr . W**A fif 4 -n/4if« •»«•»•• D1 _>n_si"jQ^ 1 ftf% . ' * 'Safety

D. OTHER CONTROL1 •"- , ' . ' " ' • " i* •"•«'

Good industrial hygienV''j)Tac ice'eh ouid e followeeye contact, minimizing'akin'contact, and minimizing inhalation of vapor. Aneye bath and washing facilities should be available.

•• MSDS-10,27j4A-3 (05-85)Replaces 07-83 edition

SECTION VIM, , SPECIAL*STORAGE AND. HANDLING PRECAUTIONS

Material is classified as a Combustible Liquid and a peroxide former. Keep awayfrom heat and flame. After opening, purge container with nitrogen before re-closing. Periodically test for peroxide formation on long-term storage.

Since emptied packages retain product residue, follow label warnings even afterpackage is emptied. . '

SECTION IX. SPILL, LEAK. AND DISPOSAL PRACTICES

Steps to be Taken in Case Material is Released or Spilled; Eliminate all ignitionsources. Small spills may be collected with absorbent materials. For largespills, flush area with water spray. Prevent runoff from entering drains, sewers,or streams.

- » — . „ . . - .

Waste Disposal Method; Incineration. Observe all federal, state and local lawsconcerning health and environment.

SECTION X. ENVIRONMENTAL EFFECTS DATA

A. SUMMARY: This chemical has been tested for environmental effects. Some testdata are available for this chemical, and the results of these tests have beenused to provide the following estimate of environmental impact:

This chemical has a high biological oxygen demand, and it is expected to causesignificant oxygen depletion in aquatic systems. It has a low potential toaffect aquatic organisms. This chemical is readily biodegradable and is notlikely to bioconcentrate. If diluted with a large amount of water, a smallquantity of this chemical released directly or indirectly into the environmentis not expected to-have a significant impact.

B. OXYGEN DEMAND DATA

- TOD: 1.82 (ThOD-calculated) . . •- BODj: 20Z of total'organic carbon (3)- BOD2Q*. 58Z of total organic carbon (3)

C. ACUTE AQUATIC EFFECTS

- 96-hour LCso; Fathead minnow: 145-183 mg/L (3)- 48-hour LC50; Water flea: 345-499 mg/L (3)

D, BIOCONCENTRATION POTENTIAL . ; .

- Octanol/water partition coefficient: Log P » 0.556;;-. ?_?.;>. 6-(3)

SECTION XI. TRANSPORTATIOli &;'.• ? 'S* ..',;.- .. . . " ••'.'•„', ";:-.."".' •'•..; '' .."

DOT Hazard Classification: : Combustible Liquid. :Flashpoint: See Section 19.*''':,•'•.'• *'-'; '-; '-" ' ' • • • • '...--. r- :.; - .-•.-• -

MSDS-10,274A-4 (05-85)Replaces 07-83 edition

.::ic>- xn. r.r1*. H. C. Hodge and J. H. Sterner. Tabulation of toxicity classes. American,, v

Industrial Hygiene Association Quarterly 1949; 10:93-96.

2. Federal Register 46:12308-12309, February 13, 1981. '

3. Unpublished data, Dow Chemical U.S.A., Midland, HI.

The information contained herein ie furnished without warranty of any kind. Usersshould consider these data only as a supplement to other information gathered bythem and must make independent determinations of suitability and completeness ofinformation from all sources to assure proper use and disposal of these materialsand the safety and health of employees and customers.

MSDS-10,274A-5 (05-85)Replaces 07-83 edition

Mad. usi Safety. .

MSDS NUMBER E-T85 ' : ':- ' PAGE 3 ofSECTION VIII REACTIVITY

STABILITY O UNSTABLE Q STABLE I HAZARDOUS POLYMERIZATION [_J MAY OCCUR Q WILL NOT OCCUR

CONDITIONS AND MATERIALS TO AVOID* / * •

1 - . . * " *Gas and oil beaters, open flames and arc welding are capable of causing thermal decomposition. Do not mixor store vitb strong acids, bases or oxidizerc. Do not store in aluminum, zinc, or magnesium containers.Hydrolysis producing small amounts of hydrochloric acid possible with gross water contamination.

HAZARDOUS DECOMPOSITION PRODUCTS jThermal degredation produces hydrogen chloride, carbon monoxide, and very small amounts of phosgene and ,chlorine.. . : ••' . '_•_ • '';..; •AVV'r.V'"'!.''." . ' !

. «

SECTION IX EMPLOYEE PROTECTION"' ' RESPIRATORY PROTECTION

Use KIOSK approved organic vapor respirator vithin the limitation of this device. To prevent overexposure,use positive pressure self contained breathing apparatus in all other situations.

PROTECTIVE CLOTHING >. •Hear Impervious gloves (Keoprene, Viton) and protective clothing as required.to prevent skin contact. • Wearchemical goggles, safety glasses, or faceshlel.d to protect eyes.:' • '. . . - . ' ; ' ' * ' • ; .

ADDITIONAL PROTECTIVE MEASURES -'-ft* ~ - - • ' • - - « ... *. -. . ... ;,In operations where spilling and. splashing* occurs, use impervious apron and boots to protect th'e body: ,.Eyewash stations and showers oust be'readily available. Spark resistant tools suggested; -Hash hands with.soapand water after handling. . . - . . • • _ .-.. "••* • '•<•* • ' ' ' * •"

SECTION X ENVIRONMENTAL PROTECTIONSPILL OR LEAK PROCEDURESGround and/or bond all equipment ' v'f r; ^

LARGE SPILLS: Evacuate hazard area of unprotected personnel.. Wear appropriate protective equipment. Shut offsource of leak only when safe to do so. Dike, end contain liquid. Remove liquid with vacuum truck or pump tonon leaking salvage or storage containers. Soak'tip residue with absorbent materials; place into non leaking •drums to await proper disposal. Flush area to remove trace amounts, collect flushings, dispose of properly.

SHALL SPILLS: Take up* with ''i s6rb«Bt";ifi|eiriSl'limd"place" 'in "a non leaking container; seal tightly anddispose, of properly.; . £-3*$ ^ ^ -• -

WASTE DISPOSAL . - :' ViTiDispose of through KRA approved T5£D ?ffiK:fli y *rlth respect to'all state and local laws.Methods of Disposal: Ite clJLagVUiic ratiem'or)as last resort r Landfllllng. •;-..•:-. -r .- .".r .•-.- •

• " '" •' ; '. V. •.••..••'.-'•'.'""''. T';*r,?»S"'- :'•• ' '". -• ' .- • --•• : • • • • • - . * - - . - .

ENVIRONMENTAL HAZARDS .This product is to be considered a hazardous material and should not be allowed to enter surface waters orsewerage systems. Releases into environment say be reportable under state and/or federal regulations.

Material Safety Data SheetMSDS NUMBER ES-85 PAGE 4 of 4

. -j.. • ••

SECTION XI SPECIAL PRECAUTIONS

*.*• . - "•- V *--" - • - ' " • • " • ' . ' , *

'.Keep liquid or vapors away Iron open flames or sparks. . . ...-Ground all equipment. „•• •! . '' Do not weld, drill or grind on containers! •Empty containers are still considered hazardous.'Keep containers tightly closed. Store properly out of weather when possible.Hot surfaces may cause thermal decomposition and thusly,resultant noxious gases. Always have adequateventilation is work and laboratory areas.

^ECTION XII . TRANSPORTATION REQUIREMENTS

, j""l FLAMMABLE LIQUID |""1 COMBUSTIBLE LIQUID 1""1 OXIDIZING MATERIALDEPARTMENT , \

TRANSPORTATION Q FLAMMABLE SOLID Q POISON. CLASS A Q CORROSIVE MATERIALCLASSIFICATION ' _ _ - . « - - _ _. . - : I~J FLAMMABLE GAS Q POISON. CLASS B Fj IRRITATING MATERIAL

D NON-FLAMMABLEGAS

"•*-" D.O.T. REGULATIONSQ OTHER Specify below

D.O.T. PROPER SHIPPING NAME Eaken StripOTHER REQUIREMENTS ,, ,_ „, . - ._; ' • • - .&••..; •;• • .;-y. . • ;. Waste Classification: . • -^ Waste: Solvent. N.O.S. 'QRM-A ..NA 1993. •

SECTION XIII OTHER REGULATORY CONTROLSEPA. PDA. OSHA. USOA. CPSC. ETC.

EPA - Resource Conservation Recovery Act (aCRA) . .; • , -. . • • . . . .: If this product can no longer be usedl or is part of a waste stream, the resultant would be •-:.*.classified as a hazardous waste. ' . °' \-

SPA - Comprehensive Environmental Response, Compensation, Liability Act ICERCLA) • - :.. •• ;'-5 ;' .'Releases to air, land or water are reportable under CZRCIA (Superfund) when releues exceed- •."".>reportabla quantities. • . . ',' . . - , •' . . ;. • .. v '•*".' ..$'•.;•'

.;.:.-.. RQ .-. ioo pounds / contained: .- •. ., • ,: .' -' .'' ; " - . : • ' :.' "'\. "'£M-'' "*•'.'•

r -RESPONSE GUIDE - 27, .128 and 174.' •''_•''' ; • .-:' V .'-'. '1-"J 'v

Tha information contained herein Is based on data consideredaccurate.'However; no~ warranty is expressed or Implied "

* regarding th« accuracy of thesa data or tha results to t»obtainedfrom.thaus*thereof/ ^ v-*--;> rf--- * *- <?>Vendor assumes no responsibility for injury to vendea or third •:parsons proxlmatety caused by lha material if reasonable safetyprocedures ara not adhered to as stipulated in tha data sheet ~Additionally, vendor assumes no responsibility for Injury tovendea or third persons proximataly caused by abnormal use ofthe material even if reasonable safety procedures ara followed.Furthermore, vendee assumes tha risk in his use of the material, t

..'. v .--• : *:. . •:,.:.•*• ..i» >••-."...»_ •• - •; . .y;;.:' f\ ,--. • ••••/.-

T * ^ -•;-......•£. ... ..SIGNATURE/TITLE ;- V *,-:• ••~--i~"'. -:j":/_ .;.;-";. .,7. •- :;.i.-;..4- - 5 if*j-'.

75 7 -':.-'/ '-::ir-';!'Brx'.t••'•'•v.vt&t'•£&!&*&** * ?:U --'' •. • • ;-. .. n«w« Eaken Inc.";_.;_,:.- . .*-. •n&.fi-'? r- -f.;-, ="/••/,-• •• -:••-«:• .••••Brt -__ 4_< ,. !;••_*.•••«,» -i-««**1*P.O. Box 171 Leeiport. PJL19533. C215) 92&.2136 ..... —-....,- X

DATE PREPARED, f DOA£ OKO QCT 1985

-*• f r. m m. memmemm^ m r t *•*-:_.• ,. f f *VF FETY DATlA r» »«««

DPAGE.XOF4

SECTION I NAME . I 24 HOUR EMERGENCY ASSISTANCEPRODUCT. ""iaJcea "Strip x. /'. • -.:. /

R:Vl Eak€h IncI9 t Jj'lt T?Box;l71 Leesp6rt;PA..i9;5335 '.(2_l_5).9l f813l5> >. i ^

CHEMTHEC 800-424-8300 -

'• ' LEAST"'' SLIGHT. V-O V.-P^ft :".</ 1 ••!>>. Tit,

MODERATE,. HIGH EXTREME- -

FIRE

REA'CTIVITY

2'

o:

INGREDIENTS; . .COMPOSITION -.. ', •/ >%.-.. > . .:.:-. TOXIC»TY;DATA . . . .-.,,. C.A.S. NUMBER,

* :-

.0

n -

lr.95-5p*ri . '.;• -j-j"€7-56-i '•"'•. I'/'i- •-. . . . _ • • . ..)j-..': •j.'.""?».21;!'-ivir.'EfM' .'-.• '.v'

.19%;1'.¥

;l

^ ^ -'-•• •- :-:: '-'; 'Mi4\.-'.;'- -v^. '. i;.•:i~ {•••< '•••....'; •..•>.SECTION IU HEALTH INFORMATION

< ~-

EYE CONTACT: Vapors and liquids may.causerIrrltatlo iiJ.Has possibility of [carislng slight -transient:cornea! ••''7—."--.•*—-injury through contact.' '~r*~"*' —-*•'•- ..ji-f~> yy.»-f>i....>..'.—*.'.>.»•>;..«. i » —.~..«..--.->'-.•--.'..y..'.. iw~.v«. i;;i_ij

1KHAIATION: low level vapV>r concentrations nay cauSe~«nesthetlc or narcotic effects; High* «ntr-ttiira"i«id/oflong term exposure Bay -irritate «spiratcry _ystemr-aiz_iness;*di

SECTION IV ' OCCUPATIONAL EXPOSURE LIMITS

!. '•'•' 62 WO K.V/IHA; ACGIH

e Q £

Material Safety Data Sheet - -.MSDS NUMBER ES-85 • : PAGE 2 OF 4

SL'CTION V EMERGENCY AND FIRST AID PROCEDURES

EYE CONTACTr Irrlgata with flowing water for at least 15 minutes. If irritation persists, get medical .,-.:•""• attention. '•• .."'. "... ' Jv - • '.;..• • ' • :: • ''•"' *" ' '' •'. '

i . . .

• SKIN CONTACT: Wash off in flowing water or shower. Remove contaminated clothing and shoes. Do not reuseclothing or shoes until cleaned. If irritation persists, seeX medical attention. If rash persists,

.: t treat as contact dermatitis. ...

• INHALATION: If breathing difficulties, dizziness,, or light headedness occur, get victim to fresh air. If.,*„ .'. breathing stops, administer artificial respiration - preferably mouth to mouth. (Note: Vapors tend•;.;- • _/••.'. ..to accumulata in' low. areas;,.'areas 'of Inadequate ventilation,corners and pits.) \

SYSTEMIC: Avoid Epinephrine or similar acting .drugs if at all possible. Consult standard literature.

.• -.'DIGESTION: DO NOT INDUCE VOMITING, but if vomiting occurs spontaneously, keep head below tba hips to prevent-'' . aspiration of liquid Into the lungs.

DO NOT GIVE LIQUIDS: Contact Physician immediately.v ' ' . - ; . . . ' . - • . • • • ' : V .•••''• .; ..-'. .'• •• ' : '1 -Physician's Note: Hay cause chemical.pneumonia. If aspirated into lungs. Danger of chemical pneumonia must; . be weighed against toxicity when considering emptying the stomach. If lavage is performed, suggest

endotracheal and/or esophagoscopie control. . . .' . . •

SECTION VI PHYSICAL DATABOILING POINT ln-i

.(•F) . ' :

SPECIFICGRAVITY 1 137 Q g(jo p '"..• "•'•'

SOLUBILITY IN • -, • 'WATER Sli lt

-MELT.NG POINT .

% VOLATILE BY '. ... . .'

EVAPORATION RATE . . '(BUTYL ACETATE -.1) 9.9 <.

•i 1VAPOR . .- \PRESSURE 237.8 ' '•"•,- f(mmHg) • ; • •..;•.. V,VAPOR . •- ~ :. •DENSITY ..' ..'.' ; ••_..-1; ••' i"! ' '•.(Alfl;«1) ; . . 2>662!;. .iJv-:'

AUTO IGNITION • ^.vl r * 'TEMPERATURE N/A ': -. ;•

APPEARANCE AND ODOR . .;, .V ' j.Briber send-viscous liquidr chlorinated hydrocarbdn odor'.: ' • . ',..*. ;: -.:' "? ;••;'•' !::' '•••

SECTION VII • FIRE AND EXPLOSION HAZARDS |FLASH POINT AND METHOD USED . > ' . 1 FLAMMABLE LIMITS/% VOLUME IN AIRno flash to boiling, T.C.C. 1 estimated

LOWER UPPER r,.

5.6 36.0 *EXTINGUISHING MEDIA . . . '. , ..,- -

Water fog, "Alcohol", foaa, Dry Chemical, Carbon Dioxide. . V ' . - . /

SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS . . . .,.;•-.•.,: Use NIOSH .approved pqsitiv* pressure ,salf contained breathing apparatus in confined areas. , Us. prater to cool• exposed COTtainers. Fira, shouldba .contained, if-. possible; :wear proVectiva 'coating. ' '""'' " ' ... '. " . ~'

", '.''•: •--••'•.. > -'.:'V.::-*~\ vv-v. - Ji t --' /-?:? .' • •• ', ='•;..'-. . ;• .- •-. ~~?i .'.•'.'•• \- ,^l- .--:t -•:.,:\r r .;.•". ;.:* \ —**S •<?<.*• '- •'• fr'KS-- ;• •'•v-a :.,..,-". .-,. • - - • / •- •••'-• : • ' '" •..'••.' ;* .'.?'• ! «. .**!&~v*.

UNUSUAL FIRE AND EXPLOSION HAZARDS 9*&S&9S&i'3l*%4fifa •'C --' «i.v! •-•&•'*•-.•*£• •-•-,*JZt •'*£vv-f ^ '.-'F-'vr *'i-'' '4.J«'; >:'V;<'J-'- ' '•*'•-•• *•-.*.' '•'• ' ;r'"•*~ Vapor 'la heavier .than air and may travel great distance. Vapors have tendencies to hang

less than adequate ventilation.

• -., . ^S20fiQ/i f.

in enclosed areas o

SAFETY/ MSDS NUMBER STS11R-87 | PAGE 1 OF 4USECTION i /V , .-. NAME '-.-. : ;,-'•;:..; ; | 24 HOUR EMEprca|;r:ASsisTANCE

PRODUCT SAF-T-SOL #11

Blended By R.W. Eaken Inc.P.O. Box 171 Leesport, PA. 1953$

(215)926-2136

CHEMTREC 800-42<-9300

HAZARD RATINGLEAST SLIGHT0 1

MODERATE HIGH EXTREME2 3 4

HEALTH

FIRE

REACTIVITY -

SECTION!! :':* : : v; , INGREDIENTSCOMPOSITION TOXICITY DATA C.A.S. NUMBER

1,1,1 TRICHLOROETHANE

DIETHYLENE ETHER

1,2 BUTYLENE OXIDE

NITROMETHANE

350ppm; ACGIH

25ppm; ACGIH

40ppm; DOW

lOOppm; ACGIH

71-55-6

123-91-1

106-88-7

75-52-5

SECTION IH ; '';.'"•"•.'• '-'- "."•'"'' v: '". HEALTH INFORMATIONEYE CONTACT; May cause' pain. Hay cause slight transient corneal Injury. Excessive vapor

. . may Irritate/eyes. . " . " . " .SKIN CONTACT: Prolonged or repeated exposure may cause skin Irritation. Repeated contact

may cause defattlng ofINHALATION; Minimal anesthetic or narcotic effects may be seen In the range of 500 to

1000 ppm. As vapor concentrations approach lO.OOOppm, dizziness, drunkeness,.. unconsciousness, .and. death. may occur. .High levels may cause Irregular heart-

. beat. Confined -or poorly ventilated areas--;may allow vapors. to ..accumulatereadily; potentially, causing unconsciousness or death. . . .;\ '

INGESTION; Single dose oral toxicity 1s Vow; 1f aspirated, may cause rapid absorptionthrough the lungs which may result 1n systematic effects.

SYSTEMATIC & OTHER EFFECTS; Based on available data, repeated exposures are not antldpatto cause any significant adverse effects. Has not caused cancer; and 1s un-likely to be related to birth defects. Is not shown to Interfere with repro-duction and had negative Hutagenlty values.

••d

SECTION IV OCCUPATIONAL EXPOSURE LIMITS

350ppm TLV/THA; ACGIH - 450ppm STEL. ... •»._____ _______ «, , »,. -. '» *>•;..

Material Safety Data Sheet «MSDS NUMBER STS11R-37 PAGE 2 OF

SECTION V EMERGENCY AND FIRST AID PROCEDURES

EYE CONTACT; Irrigate Immediately with water for a minimum of 15 minutes. Consult"physician if Irritation persists.

SKIN CONTACT-; Wash of f -with shower and/or soap and water. Remove contaminated cloth1n<and wash before re-use. .

INHALATION; Remove to fresh air. If not breathing, give mouth to mouth resuscitationIf breathing.Is difficult, give oxygen.: Call physician.

IN6ESTION: DO NOT INDUCE VOMITING!! Call a physician and/or transport to emergencyfnCJl}fLJI e5l!JS3*y* Treata«nt based .on physician's judgement 1n response•t+tt/vrr- A w.pajient s reaction.**NOTE to physician; Because rapid absorption may occur through lungs If aspirated ar

cause systematic effects, the decision to whether to inducevomiting or not should be made by attending physician. If lavagis performed, suggest ends tracheal and/or esophageal control.Danger .from lung aspiration must be weighed against toxtcity wheconsidering emptying the stomach. Exposure may Increase myo-cardial Irritability. Do not administer sympathiomimstic drugs

•° unless absolutely necessary. No specific antidote. Supportive

SECTION VI PHYSICAL DATA- ; :. ; :

BOILING POINT(-F) 165

SPECIFIC ' • - . . . 'GRAVITY f 37 Qgn« p(H_0»1) •••3*,*°« r

SOLUBILITY IN :,.„,,,.< K1aWATER negligible

' MELTING POINT(•F) -34

% VOLATILE BYVOLUME 100

•EVAPORATION RATE - n(BUTYL ACETATE » 1) 6 • «

VAPORPRESSURE 100(mmHg) A }VAPORDENSITY :» ec(AIR-1) •3;J

AUTO IGNITION ....TEMPERATURE N/A

APPEARANCE AND ODORwater whits liquid; Irritating odor at .higher concentrations

| SECTION VI! FIRE AND EXFLASH POINT AND METHOD USED .

none; T.C.C."EXTINGUISHING MEDIA

water fog or spraySPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS

Use self contained, positive pressurefire zones.

PLOSION HAZARDS .(FLAMMABLE LIMITS/% VOLUME IN AIR LOWER UPPER

@25*C 7.5 15

respiratory equipment in confined areas or^

\

UNUSUAL FIRE AND EXPLpSlON HAZARDSVapors of this solvent may form flammable atmosphere'in confined areas. 'Coolcontainers with water to keep heat from attacking drum/tank.

•. i.*-

/••-•>."#.£•-• inJr.c;.V »_i *St*t« »» • IU»»01"<T VNJ*_ • *-__?"*T1 ^ r

™.._________ MSDS NUMBERSTS11R"37 PAGE 3 of 4o SECTION VIII . REACTIVITY.

STABILITY Q UNSTABLE F*l STABLE HAZARDOUS POLYMERIZATION Q MAY OCCUR EX] WILL NOT OCCUR

CONDITIONS AND MATERIALS TO AVOID

Avoid open flames, welding areas and other high temperature sources which induce thermaldecomposition. Long term contact with water can deplete the stabilizers followed byslow hydrolysis producing corrosive acid/Avoid prolonged contact with, or storage in,aluminum or its alloys. Metallic aluminum and'zinc powders should be avoided..

1

HAZARDOUS DECOMPOSITION PRODUCTSHydrogen chloride and very small amounts of phosgene may be generated.through thermaldecomposition. '

SECTION IX . EMPLOYEE PROTECTIONRESPIRATORY PROTECTION Atmospheric levels should.be maintained below the exposure guideline.

When respiratory protection Is required for certain operations, use an'approved airpurifying respirator. .For'emergencies, a positive pressure breathing apparatus or fullface respirator with approved organic.vapor carinister is recommended.

PROTECTIVE CLOTHINGUse gloves of viton, neoprene or poly vinyl alcohol. Use boots and aprons whereexposure succeptlbility 1s greater/Use safety glasses or chemical goggles asnecessary.

ADDITIONAL PROTECTIVE MEASURESIt 1s recommended that eyewash stations be made readily*available

SECTION X . ' . ENVIRONMENTAL PROTECTIONSPILL OR LEAK PROCEDURES

Small Leak; Use absorbent material and dispose of in an appropriate method. Increaseventilation In area When possible.

• ;

Large Spills; Evacuate area. Contain liquids; transfer to closed metal containers.Keep out of water supplies. Dispose of through proper channels.

WASTE DISPOSAL - .Dispose of residual material in compliance with federal/state, and local

regulations. .Do not dump in sewers,' septic systems, on the ground or .into any bodyof water. . • • .

ENVIRONMENTAL HAZARDSKeep out of bodies of water and off. the ground. jReleases to environment may be reportable under environmental regulations.

r ;.

Material Safety Data Sheet " -MSDS NUMBER STS11R-37 PAGE4 of*4

SECTION XI SPECIAL PRECAUTIONS

Ground all equipment.Keep liquids and vapors away from open flames and sparks. Do not weld, drill, orgrind containers. ..:..Always have adequate ventilation in work areas.Keep containers tightly closed, store properly out of weather, if possible, In acool, dry area.Hot surfaces may cause thermal decomposition and result in noxious gases.Aluminum.is not an acceptable material to pump, mix, package, or store 1,1,1.Trichloroethane and formulated products containing this material.Avoid metallic aluminum and zinc powders.

SECTION XII . TRANSPORTATION REQUIREMENTS . •• • - - • - • • - - • • . • • • • ••

Q FLAMMABLE LIQUID Q COMBUSTIBLE LIQUID Q OXIDIZING MATERIAL Q NON-FLAMMABLEDEPARTMENT . - ' _ _ . ' G A S

TRANSPORTATION D FLAMMABLE SOLID Q POISON. CLASS A Lj CORROSIVE MATERIAL Q gOT HAZARDOUS BYCLASSIFICATION _ . „ .j. __

PJ FLAMMABLE GAS Q POISON. CLASS B f| IRRITATING MATERIAL Q OTHER Specify below

D.O.T. PROPER SHIPPING NAME SAF_T.SOL #n (not considered a hazardous material In virgin statOTHER REQUIREMENTS WASTE CLASSIFICATION:

Waste 1,1,1 TRICHLOROETHANE ORM-A UN2831Waste Code i - F001 Emergency -Response Guide - 174

0

V*

SECTION XIII OTHER REGULATORY CONTROLSEPA. FDA. OSHA. USDA. CPSC. ETC.

EPA - Resource Conservation Recovery Act (RCRA)If this product can no longer be used, or is part of a waste stream; theresultant would be^classified as a hazardous waste. . •

• " . - * • • ' i • • ' 'EPA - Comprehensive Environmental Response, Compensation, Liability Act (CERCLA)

Release to air, land, and water are reportable under CERCLA (Superfund)when releases exceed reportable quantities.

The information contained herein Is based oh data consideredaccurate; However, no warranty is expressed or implied ;regarding the accuracy of these data or the results to beobtained from.the use thereof. • -• • -• '-'.'• -Vendor assumes no responsibility for Injury to vendee or third .persons proximatelycaused by the material if reasonable safetyprocedures are not adhered to as stipulated in the data sheetAdditionally, vendor assumes no responsibility for injury tovendee or third persons proximatety caused by abnormal use ofthe material even if reasonable safety procedures are followed.Furthermore, vendee assumes the risk In his use of the material.

v» . r. *\._ A.;*

SIGNATURE/TITLE

R.W. Eaken Inc.P.O. Box 171 Leesport. PA, 19533 v JI91*\ O9A-444* ^(215) 926-2136

- .>DATE PREPARED

JULY, 1987

if ~i. sta Si .--.'.MSDS NUMBER VT3-85 PAGE 4 >*•.

ECTION XI . SPECIAL PRECAUTIONS

DANGER! FLAMMABLE! ,. ,Keep liquid and vapor away from heat, sparks and flame. :: /Use sparK resistant tools. . ;Ground all equipment. Bond and around transfer equipment.Do not weld, drill or grind on containers! ' •Empty containers nay contain explosive or flammable vapors.Keep containers tightly closed when not in use.Store containers properly. • 'Surfaces that are sufficiently hot cay ignite liquid material even in absence of spark or flame.

SECTION XII... . ... ..___... TRANSPORTATION REQUIREMENTS

FLAMMABLE LIQUID Q COMBUSTIBLE LIQUID Q OXIDIZING MATERIAL Q I'ON-FLAMMABLEDEPARTMENT —— S

TRANSPORTATION D FLAMMABLE SOLID Q POISON. CLASS A. Q CORROSIVE MATERIAL Q | jg "SfGuSSoSsCLASSIFICATION ^ -_ —, •.«.•• ncwuu«iiwiNa

Q FLAMMABLE GAS fj POISON. CLASS B |J IRRITATING MATERIAL |J OTHER Specify below

D.O.T. PROPER SHIPPING NAMEFaint Related Material Flammable Liquid HA 1263

OTHER REQUIREMENTS Kaste Classification:KASTE PAINT RELATED MATERIAL Flammable Liquid NA 1263

Lor KASTE FLAMMABLE LIQUID N.O.S. Flammable Liquid OK 1993LSECTION XIII OTHER REGULATORY CONTROLSEPA. FDA. OSHA. USDA. CPSC. ETC.

EPA - Resource Conservation Recovery Act (RCRA) . • . • • .• . ••.-.•If this product can BO longer be used, or is part of a waste stream - the resultant vould beclassified as hazardous waste.

• • '

'. '• '•• :muaoaas WASTE coDE'iroi4BER -\D001/.'F003/'JP005 - --1 .; • - ' '. •-, -.:-'-.,:-.,

EPA - Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) : 'Releases to air/ land, and/or water are reportable under CERCLA (Superfund) when release exceedsreportable quantity. •

rTIQ - 1000 FOONDS/OWTAIHER , ' . - •. -..att. . . . ' . . _ ' • • • - . . . .

•TMERGENCY RESPONSE GDIDE - 126, 12*7 ' ' • . ' " ' -' . . '• '.. " '"

-as .-.- -.

The information contained herein Is based on data consideredaccurate. However, no warranty is expressed or Impliedregarding the accuracy of these data or the results to beobtained from.the use thereof.

*4or assumes no responsibility for injury to vendee or thirdons proximately caused by the material If reasonable safety

, >edures are not adhered to as stipulated In the data sheet.\_>rtionally, vendor assumes no responsibility for injury tovendee or third persons proximately caused by abnormal use ofthe material even If reasonable safety procedures are followed.Furthermore, vendee assumes the risk in his use of the material.

SIGNATURE/TITLE

R.W. Eaken Inc.P.O. Box 171 Leespbrt, PA. 19533(JlS) 826-2136 \

DATE PREPARED

OCT 1985

Material Safety Data Sheet

SECTION VIII REACTIVITYMSDS NUMBER VT3-35 PAGE 3

n ^ - * - * - " " * ! I ""-1 •' •"•*UNSTABLE hrl STABLE HAZARDOUS POLYMERIZATION ill MAY OCCUR Q WILL NOT OCCUR

CONDITIONS AND MATERIALS TO AVOID

Keep liquid and vapor away from heat, sparks and flame.Do not mix or store with acids, bases, or other oxidising materials.Prevent vapor accumulation.

HAZARDOUS DECOMPOSITION PRODUCTSCarbon Dioxide, Carbon Monoxide and other unidentified organic compounds may be formed during combustion.

SECTION IX EMPLOYEE PROTECTIONRESPIRATORY PROTECTIONUse NIOSH approved organic vapor respirator within the limitation of this device, to prevent overexposure.Use positive pressure self contained breathing apparatus in other situations.

PROTECTIVE CLOTHING : . ; ; . . . ; ,Hear impervious gloves (Neoprene, Vlton) and protective clothing as required to prevent skin contact. Hear "chemical goggles, safety glasses, or face shield to protect eyes.

ADDITIONAL PROTECTIVE MEASURES • r : •''*..•• '..•'In operations where spilling and splashing occurs, us* impervious apron and boots to protect body. Eyewashstations and showers should ba readily available. Spark resistant tools are recommended. -Wash handsthoroughly with soap and water after handling. • •

SECTION X ENVIRONMENTAL PROTECTIONSPILL OR LEAK PROCEDURESWARNING: FLAMMABLE! Eliminate all ignition sources. . Handling equipment must b* grounded to prevent sparking.

LARGE SPILLS: Evacuate the hazard area of unprotected personnel. Rear appropriate protective equipment. Shutoff source of leak only if safe to do so. Dike and contain liquid. If vapor cloud forms, water fog may beused to suppress; contain run-off. Remove liquid with vacuum truck/pumps to storage/salvage containers.Soak up residue-with, absorbent, materials;, place -la-now-leaklng.containers -to await proper disposal. Flusharea to remove trace; collect flushings, dispose of properly.-.

SMALL SPILLS*. Take t*p with anrobsorbent.material and place-in-non leaking container; seal tightly and dispose- - •,'' O •;•: j '-X. ••«- "iS-i' \:~ .-•••.•. -of properly.-".. *". • ... . •• • •

WASTE DISPOSAL " ' ; • V**'<:'•;• \:- ••-. , ,.;,...Dispose of through RCRA approved ISO) facility. Use non-leaking 172 or tightly sealed 17B druas. Labelproperly. Check state and local laws. . "*f" . . . ;•Methods of Disposal: Incineration, Recycling, Solidification and Landfill._______ • • ' >w'ENVIRONMENTAL HAZARDSThis product is a hazardous material and should not be allowed to enter surface waters, sewer systems, anddrainage areas. Releases to environment may be reportable under environmental regulations.

• • - x •

\PA6E4 25-May-88 ^

MSDS CHEHICALS MASTER LISTING OF MATERIALS

USED AT STANLEY-VIDMAR 1981-1985

MSDS RO PERCENT1,0. CAS NUMBER

ZB 110641ZB 71238ZB e7S61ZC 766*382ZD 7664382ZEZF 1310732ZFZE 1330207ZH 64741657ZH 71556ZI 7664382ZJZK 1310732ZKZK

CHEMICAL NAME

PYRIDENEPROPANOLKETHANOL .PHOSPHORIC ACIDPHOSPHORIC ACIDPOLYKER SOLUTIONSODIUM HYDROXIDENETTING AGENT, DEFOfflERIYLENEALIPHATIC HYDROCARBON1,1,1, TR1CHLOROETHANEPHOSPHORIC ACIDCAUSTIC ALKALISODIUM HYDROXIDECHEMICAL LIKEALIPHATIC PETRO SOLVENT

1

500050005000

1000

1000

10005000

1000

PRODUCT

YELLOW H.S. ENAMELYELLOW H.S. ENAMELYELLOW H.S. ENAMELSECURE <LUH FOAM)SECURE SEALLP-1354LP-1128LP-112BXYLENESTAMP OIL f?4STAMP OIL 194TARTPH-110-LT(PAINT STRIPPAINT FLOCCULANTPAINT FLOCCULANTPAINT FLOCCULANT

VENDOR

CHEMCOATCKEMCOATCHEHCOATOUBOISDUBOISTEXOTEXOTEXOR.U. EAKENR.U. EAKENR.U. EAKENDUBOISDUBOISDUBOISDUBOISDUBOIS

BY VOL.

0.0072.310.391012

20BO100

87.512.531353511

AR20695I

25-M*y-68

USDS CHEMICALS MASTER LISTING OF MATERIALS

USED AT STANLEY-VIDHAR 1981-1985

NSDS1.0.

TUVHXYYYYYYYYYYZZZ

J \2Z22222ZAZAZAZAZAZAZAZAZAZAZAZAZAZBZB

.ZBZB

'*' 1ZBZBZB

CAS NUMBER

131058313105837664939763190568952352

1330207

108883

-

1068831330207

1330207

108883

6474295671363

7440439110430

- 5000011207021123451330207

CHEMICAL NAME

POTASSIUM HYDROXIDEPOTASSIUM HYDROXIDESULFURIC ACIDSODIUM BISULFITETRICRESYL PHOSPHATEVHIP NAPTHAEPOXY RESINAROMATIC HYDROCARBONSMETHYL ALCOHOLXYLENEPROPYLENE GLY HETH ETHER2-BUTANONETOLUENENORM BUTYL ALCHOHOLl-METHOXY-2-PROPANOLl-HETKOXY-2-PROPANOLPROPYLENE GLY HETH ETHERNORN BUTYL ALCHOHOLVHiP NAPTHAAROMATIC HYDROCARBONSEPOXY RESIN2-BUTANONEISOBUTYL ALCHOHOLTOLUENEXYLENEPETRO. HYDROCARBONMETHYL ALCOHOLMAGNESIUM SILICATEPHTHALO BLUE PIGMENTTITANIUM DIOXIDEISOBUTYL ALCHOHOLPETRO. HYDROCARBONDIETHY.6LYC.HONOBUTY ETHRXYLENEl-HETHOXY-2-PROPANOLNORM BUTYL ALCHOHOLTOLUENEVHIP NAPTHAPROPYLENE 6LV HETH ETHERFILM FORMERS AND RESINSAROMATIC 100N-BUTANOLCADMIUMHETHYL-N-AMYL KETONEFORMALDEHYDEE.6.H.6.E. ACETATED.E.6.H.B.E.XYLOL

RBLBS. '

1000100010005000

1000

1000

10001000

'

1000

1000

5000

1000

1000

' PRODUCT

IPH-5A STRIPPERPH-1IO-LT STRIPPERSULFURIC ACIDHYDRO FAX REDUCT 790PUMP LUBRICANTGRAY HIGH SOLIDSGRAY HIGH SOLIDSGRAY HIGH SOLIDSGRAY HIGH SOLIDSGRAY HIGH SOLIDSGRAY HIGH SOLIDSGRAY HIGH SOLIDSGRAY HIGH SOLIDSGRAY HIGH SOLIDSGRAY HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSGREEN HIGH SOLIDSPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELPOLY BLUE ENAMELYELLOW H.S. ENAMELYELLOW H.S. ENAMELYELLOW H.S. ENAMELYELLOW H.S. ENAMELYELLOW H.S. ENAMELYELLOW H.S. ENAMELYELLOW H.S. ENAMELYELLOW H.S. ENAMEL

VENDOR

DUBOISDUBOISTEXTILE CKEH.AHCHEN PROD.TEXTILE CHEH.PPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGCHEHCOATCHEHCOATCHEHCOATCHEHCOATCHEMCOATCKEHCOATCHEHCOATCHEHCOAT

PERCENTBY VOL.

54010045

5510555

0.50.5555555105

0.55

0.555551555120151510351.50.015.744.06

/ 0.04J 7.99< 1.6

4.24

^206952

PA6E2 25-May-88

HSDS CHEMICALS MASTER LISTING OF MATERIALSJ

USED AT STANLEY-VIDMAR 1981-1985

5DS.0.

LLLLLLLLLLMHH 'MHHHHNNNNNN000000P

CBeRRR'Sss

CAS NUMBER

1330207

71363108656107982

10888314807966

78831

78933

.1088831330207

1088831330207

1330207

1088837883171363108656

112345

•

CHEMICAL NAME

XYLENEPETRO. HYDROCARBONSBUTYL ALCHOHOLPROPYLENE. GLY HETH ETHERl-HETHOXY-2-PROPANOLHIGH FLASH VHiP NAPHTHA .TOLUENEMAGNESIUM SILICATEFILM FORMERS I RESINSISOBUTYL ALCHOHOLISOBUTANOLn-BUTOXY PROPANOLAROMATIC HYDROCARBONSn-BUTANOLMETHYL ETHYL KETONEDIETHY.6LYC.HONOBUTY ETHR2-ETHOXY ETHANOLPETRO. DISTILLATESsec-BUTANOLn-BUTOXY PROPANOLAROMATIC HYDROCARBONSPETRO. DISTILLATESTOLUOLXYLOLAROMATIC HYDROCARBONSTOLUOLXYLOLn-BUTOXY PROPANOLsec-BUTANOLPETRO. DISTILLATESXYLENEHIGH FLASK VMiP NAPHTHATOLUENEISOBUTYL ALCHOHOLBUTYL ALCHOHOLPROPYLENE GLY HETH ETHERPETRO. HYDROCARBONEPOXY RESINDIETHY.6LYC.MONOBUTY ETHRPETRO. HYDROCARBONSn-BUTYL ACETATEISOBUTYL ALCHOHOLPETRO. HYDROCARBONSISOBUTYL ALCHOHQLn-BUTYL ACETATEn-BUTYL ACETATEPETRO. HYDROCARBONSISOBUTYL ALCHOHOL

RSLBS. ,

1000

5000

1000

5000

5000

•

.

10001000

10001000

1000

1000

5000

. PRODUCT

CLEAR BASECLEAR BASECLEAR BASECLEAR BASECLEAR BASECLEAR BASECLEAR BASECLEAR BASECLEAR BASECLEAR BASEVIDMAR GREEN ENAMELVIDMAR GREEN ENAMELVIDHAR GREEN ENAMELVIDMAR GREEN ENAMELVIDNAR GREEN ENAMELVIDMAR GREEN ENAMELVIDMAR GREEN ENAMELVIDNAR GREEN ENAMELGRAY AIR DRY ENAMELGRAY AIR DRY ENAMELGRAY AIR DRY ENAMELGRAY AIR DRY ENAMELGRAY AIR DRY ENAMELGRAY AIR DRY ENAMELGREEN AIR DRY ENAMEL.GREEN AIR DRY ENAMELGREEN AIR DRY ENAMELGREEN AIR DRY ENAMELGREEN AIR DRY ENAMELGREEN AIR DRY ENAMELFED. STD. GRAYFED. STD. GRAYFED. STD. GRAYFED. STD. GRAYFED. STD. GRAYFED. STD. GRAYFED. STD. GRAYFED. STD. GRAYFED. STD. GRAYPHTHALO BLUE TINTPHTHALO BLUE TINTPHTHALO BLUE TINTPHTHALO GREEN TINTPHTHALO GREEN TINTPHTHALO GREEN TINTYELLOW OXIDE TINTYELLOW OXIDE TINTYELLOW OXIDE TINT

PPGPP6PPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPG

VENDORPERCENTBY VOL.

25105115154055

0.540

' 5< 0,5

0.50.55105525510551051020205555555

0.5255

. 520555155

T-(

PAGE! 25-Hay-B8

-/ HSDS CHEMICALS MASTER LISTING OF MATERIALS

USED AT STANLEY-VIDHAR 1981-1985

HSDSI.D.

ABCDDDDDEEEErFF66H

J«

IIII3J3J333KKKKKKKK

>» lKKKL

CAS NUMBER

1241741111591086561414357509267561955011088837155675525123911106887108BB3676306764110888375092

1333820766438277589767136350000

133020713463677647429561480796664742898688555491330207

10888371363

13463677108883

10798214807966

788311330207" 64175112345

112345

CHEMICAL NAME

2-I2-BUTOXY1ETHYL ACETATE2-ETHOXYETHYL ACETATEl-HETH-2-PROPANOL ACETATENONOETHANOLANINEHETKYLENE CHLORIDEHETKANOLORTKODICHLOROBENZENETOLUENE1,1,1 TRICHLOROETHANENITROHETHANEDIETHYLENE ETHER1,2 BUTYLENE OXIDETOLUENEISOPROPANOLACETONETOLUENEMETHYLENE CHLORIDECHROMIC ACIDPHOSPHORIC ACIDLEAD CHROMATE PIGMENTBUTANOLFORMALDEHYDEXYLENETITANIUM DIOXIDEAROMATIC 100TALCVHIP NAPHTHADIATOMACEOUS EARTHXYLENEN-BUTOXY PROPANOLDIETKY.6LVC.HONOBUTY ETHRISQBUTYL ALCHOHOLPETRO HYDROCARBONSBUTYL ALCHQHOLTOLUENEBUTYL ALCHOHOLTITANIUM DIOXIDETOLUENEFILM FORMERS I RESINSl-HETHOXY-2-PROPANQLMAGNESIUM SILICATEHIGH FLASH VMJP NAPHTHAISOBUTYL ALCHOHOLXYLENEETHYL ALCHOHOLDIETHY.GLYC.HONQBUTY ETHRPETRO. HYDROCARBONDIETHY.6LYC.HONOBUTY ETHR

RQLBS. '

10005000100

10001000

1

1000

500010001000

5000

500010001000

1000

'10005000

1000

50001000

PRODUCT

EKTASOLVE DB ACETATEEKTASQLVE EE ACETATEEKTASOLVE PH ACETATEEAKEN STRIPEAKEN STRIPEAKEN STRIPEAKEN STRIPEAKEN STRIPSAF-T-SOL 111SAF-T-SOL 111SAF-T-SOL 111SAF-T-SOL litVT 13VTI3VTI3PEEL FILHITEPEEL FILMITEDUFIXrunYELLOW ENAMELYELLOW ENAMELYELLOW ENAMELYELLOW ENAMELYELLOW ENAMELYELLOW ENAMELYELLOW ENAMELYELLOW ENAMELYELLOW ENAMELVIDMAR GRAY ENAMELVIDMAR GRAY ENAMELVIDNAR GRAY ENAMELVIDMAR GRAY ENAMELVIDMAR GRAY ENAMELVIDMAR GRAY ENAMELVIDHAR GRAY ENAMELWHITE BASEWHITE BASEWHITE BASEWHITE BASEWHITE BASEWHITE BASEWHITE BASEWHITE BASEWHITE BASEWHITE BASEWHITE BASEWHITE BASECLEAR BASE

VENDOR

R.U. EAKENR.N. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENR.U. EAKENDUBOISDUBOISDUBOISDUBOISSTRATHMORESTRATHHORESTRATHMORESTRATHHORESTRATHHORESTRATHHORESTRATHHORESTRATHHORESTRATHHOREPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPGPPG

PERCENTBY VOL.

10010010036714115960.53

0.55563925383110

12.735.1

0.2226.4

1.5

2.2

250.5555555251301155201151

/IR206S51)

DATE OF PREP. 2/20/79 I

FOR CO'-TKSS, RESIN • R'• .ATEi; : MATERIALS(Approved by U.S. D«p«rtm«m of Labor "E«»«ntl«!ly SlmHir to Form OSHA-20) M

Section IMANUFACTURER-S NAME PPG Industries,

Coatings & Resins DivisonSTREETADDRESS One Gateway Center cmr. STATE. AND ZIP CODE Pittsburgh, PA 15222

Attn: Manager, Industrial' Hygiene and Product SifetyEMERGENCYTELEPHONENO. (412> 454-51J1 or (412) 274*4508, Ext. 326

PRODUCT CLASS Alkyd-Urea MANUFACTURERS CODE IDENTIFICATION S23322I (021279S)

TRADE NAME Vidmar Green Enamel

Section 1! - HAZARDOUS INGREDIENTSINGREDIENT

Aromatic Hydrocarbonsn-Butanol . .Petroleum DistillatesIsobutanoln-Butoxy PropanolD' 'rhylene Glycol Monobutyl Ether2v--_hoxy EthanolMethyl Ethyl Ketone

Lead as % Non-Volatile <: 0.06%

PERCENTVt.

405

<-5*5<. .5<.5•c.S*.5

rutPPM mg/M*

1005020050

Not Est.Not Est.100200

LEL

1.01.71.11.76.20.92.61.8

VAPORPRESSURE

6.95.55.38.00.60.13.8

71.2

•

Section III - PHYSICAL DATABOILING RANGE

EVAPORATION RATE

78 to 280«C

} {FASTER | x|SLOWER.THAN ETHER

Section IV —

VAPOR DENSITY 'IX _

PERCENT VOLATILE ff .BY VOLUME 66.3

RRE AND EXPLOSION

] HEAVIER 1 1 LIGHTER. THAN AIR

WEIGHT PER 0 eGALLON 0.0

HAZARD DATA->3TCATEGORY Flammable FLASHPOINT 71*F P.H.C.C. LEL 1.2

EXTINGUISHING MEDIA Use National Fire Protection Association (NFPA) Class Bextinguishers (carbon dioxide, dry chemical or foam) designed to extinguishNFPA Class IB Flammable Liquid fires.

UNUSUAL FIRE AND EXPLOSION HAZARDS Keep containers tightly closed. Isolate from heat,electrical equipment, sparks, and open flame. Closed containers nay explode

exposed to extreme heat. Do not apply on hot surfaces.

SPECIAL FIRE FIGHTING PROCEDURES Water spray TR&y be ineffective. Water may be used to coolclosed containers to prevent pressure build-up and possible autoignition orexplosion when exposed to extreme heat. If water* rls-) used,rfog nozzles arepreferable. H T\ c. _ O j b 0 ?

.."<•• =fiE Ir.h&laticn: : .csthet-. _.__-_atior. 0- the rtract or acute nervoue system depression characterized by headache,dizziness, staggering gait, confusion, unconsciousness or coma.

-cin or Eye Contact: Primary irritation. <.

EMERGENCY AND FIRST AID PROCEDURES Fumes : Remove from exposure. Restore breathing. Keepwarm and quiet. Notify a physician. Splash (Eyes): Flush immediately withcopious quantities of running water for at least 15 minutes. Take to aphysician for definitive medical treatment. Splash (Skin) : Wash affectedareas with water. Remove contaminated clothing. Consult a physician.

Section VI - REACTIVITY DATASTABILITY \ | UNSTABLE f"x1 STABLE CONDITIONS TO AVOID UnJOlOWniNCOMPATABILITY(M«r«r/*/«to«rO>tf) UnknOWn

HAZARDOUS DECOMPOSITION PRODUCTS May produce hazardous fumes when heated.as in welding. Fumes may contain carbon monoxide.

IAZARDOUS POLYMERIZATION f""1 MAY OCCUR HH WILL NOT OCCUR:ONDITIONS TO AVOID Unknown

to decomposition

Section VII - SPILL OR LEAK PROCEDURESiTEPs TO BE TAKEN IN CASE MATERIAL is RELEASEOOR SPILLED Remove all sources of ignition (r lames,hot surfaces, and electrical, static, or frictional sparks). Avoid breathingvapors. Ventilate area. Remove with inert absorbent and non-sparking tools.MSTE DISPOSAL METHOD Dispose in accordance with local, state, and federal regulationsDo not incinerate closed containers,_____' __________________________

Sectlon Vl11 ~ SPECIAL PROTECTION INFORMATIONli H A T O R Y PROTECTION in outdoor or open areas use NIOSH approved mechanical filterrespirator to remove solid air borne particles of overspray during sprayapplication. In restricted ventilation areas use NIOSH approved chemical-mechanical filters designed' to remove a combination of particulate and gasand vapor. In confined areas use NIOSH approved air line type respiratorsor hoods.ENTILATION Provide general dilution or local exhaust ventilation in volume andpattern to keep TLV of most, hazardous ingredient in Section II below acceptablelimit, LEL in Section IV below stated limit, and to remove decompositionproducts during welding or flame cutting on surfaces coated with this product.•IOTECTIVEGLOVES Required for prolonged or repeated contact.'EPROTECTION Use safety eyewear designed to protect against splash of liquids.rHER PROTECTIVE EQUIPMENT Prevent prolonged skin contact to contaminated clothing.____

Section IX-SPECIAL PRECAUTIONS<ECAUTIONS TO BE TAKEN IN HANDLING AND STORING DO not store above 120°F. Store large quantitiesin buildings designed and protected for storage of NFPA Class IB Flammable^ R- nlc/SfioNS Do not take internally. Containers should be grounded when pouring.Avoid free fall of liquid in excess of a few inches. Do not flame cut, brazeor weld without NIOSH approved respirator or appropriate ventilation.Ovens must operate properly, be vented.

i<=ee text of PPG Label Warning 1857 on attached sheet.

PPG Label Warning 1857

WARNING! FLAMMABLE. VAPOR HARMFUL.

Contains: Xylol and/or Toluol and Alcohol Solvents

Keep away from heat, sparks, and open flame. USE ONLYWITH ADEQUATE VENTILATION. Avoid contact with skin andbreathing of vapor or spray mist. In case of eye contact,flush eyes immediately with plenty of water. Do not take

, internally. Close container after each use.

KEEP OUT OF THE REACH OF CHILDREN!

AR2C6957

F OR CC -"INGS. RES! -.' D RELATED MA: j-OATEOFPREP. H-l-79 (Approved by U.S. Department of Labor "Essentially Similar to Form OS HA-20)

"Mi, "•

O Section 1MANUFACTURER'S NAME PPG IndUStriCS, IttC." . !

Coatings & Resins DivisonSTREET ADDRESS One Gateway Center CITY. STATE. AND ZIP CODE Pittsburgh, PA 15222

Attn: Manager, Industrial Hygiene and Product SafetyEMERGENCE-TELEPHONE NO. (412) 434-5131 or (412) 274-4508, Ext. 326

PRODUCT CLASS Alkvd MANUFACTURERS CODE IOENTIFICATI

TRADENAME Gray Air Dry Enamel

•

°NS19687(091179S)

Section II -HAZARDOUS INGREDIENTSINGREDIENT

Petroleum Distillates -Xylol , Usec-butanoln-Butoxy PropanolToluolAromatic Hydrocarbons '

(Lead as % Non-Volatile .06%)

PERCENT

251010

TIVPPM me/M> '

200100150N.E.100100

Section III - PHYSICAL DATABOILING RANGE 78 tO 194°C * VAPOR DENSITY f3f

EVAPORATION RATE { 1 FASTER I Y 1 SLOWER. THAN ETHER PERCENT VOLATILE1 1 1 1 BY VOLUME

65.4

i

LEL

1.01.11.76.21.31.0

VAPORPRESSURE

4.76.310.00.622.47.0

HEAVIER I I LIGHTER. THAN AIR

WEIGHT PERGALLON

8.5' Section IV - FIRE AND EXPLOSION HAZARD DATA

DOTCATEGORY _.. .- FLASHPOINT c«c_i ts M f r* LEL

EXTINGUISHING MEDIA Use National Fire Protection Association (NFPA) Class Bextinguishers (carbon dioxide, dry chemical or foam) designed to extinguishNFPA Class IB Flammable Liquid fires. .

UNUSUAL FIRE AND EXPLOSION HAZARDS Keep containers tightly closed. Isolate from heat,electrical equipment, sparks, and open flame. Closed containers may explodewhen exposed to extreme heat. Do not apply on hot surfaces.• ^ " . • • • • • ' .SPECIAL FIRE FIGHTING PROCEDURES Water spray may be ineffective. Water may (be used to coo:closed containers to prevent pressure build-up and possible autoignition orexplosion when exposed to extreme heat. If water is used, fog nozzles arepreferable.

Section V- HEALTH HAZARD DATA si.9687THRESHOy> LIMIT VALUE S6S SdCtiOH II.

EFFECTS OF OVEREXPOSURE inhalation: Anesthetic. Irritation of the respiratory 'tract or acute nervous system depression characterized by headache,dizziness, staggering gait, confusion, unconsciousness or coroa.Skin or Eye Contact: Primary irritation.

EMERGENCY AND FIRST AID PROCEDURES Fumes : Remove from exposure . Restore breathing. Keepwarm and quiet. Notify a physician* Splash (Eyes): Flush immediately withcopious quantities of running water for at least 15 minutes. Take to aphysician for definitive medical treatment. Splash (Skin): Wash affectedareas with water. Remove contaminated clothing. Consult a physician.

Section VI - REACTIVITY DATASTABILITY | | UNSTABLE T"" STABLE CONDITIONS TO AVOIDINCOM PATABILITY (Materials to avoid)

HAZARDOUS DECOMPOSITION PRODUCTS May produce hazardous fumes when heated to decompositioras in welding. Fumes may contain carbon monoxide.HAZARDOUS POLYMERIZATION ! I MAY OCCUR ' y | WILL NOT OCCURCONDITIONS TO AVOID

Section Vli - SPILL OR LEAK PROCEDURESSTEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED RemOVC all SOUrCSS Of Ignition (f 1 31116 S ,hot surfaces, and electrical, static, .or frictional sparks). Avoid breathingvapors. Ventilate area. Remove with inert absorbent and non-sparking tools.WASTE DISPOSAL METHOD Dispose in- accordance with local, state, and federal regulatiorDo not incinerate closed containers.

Section VIII - SPECIAL PROTECTION INFORMATIONRESPIRATORY PROTECTION in outdoor or open areas use NIOSH approved mechanical filterrespirator to remove solid air borne particles of.overspray during sprayapplication. In restricted ventilation areas use NIOSH approved chemical-mechanical filters designed to remove a combination of particulate and gasand vapor. In confined areas use NIOSH approved air line type respiratorsor hoods.

VENTILATION Provide general dilution or local exhaust ventilation in volume andpattern to keep TLV of most hazardous ingredient in Section II below acceptablimit, LEL in Section IV below stated limit, and to remove decompositionproducts during welding or flame cutting on surfaces coated with this product

PROTECTIVE GLOVES Required for prolonged or repeated contact.EYEPROTECTION Use safety eyewear designed to protect against splash of liquids.OTHER PROTECTIVE EQUIPMENT Prevent prolonged skin contact to contaminated clothing.

Section IX - SPECIAL PRECAUTIONSPRECAUTIONS TO BETAKEN IN HANDLING AND STORING Do not store above 120°F. Store large ouantitin buildings designed and protected for storage of NFPA Class IB FlammableOTHE^PRECAUTIONS Do not take internally. Containers should be grounded when pourAvoid free fall of liquid in excess of a few inches. Do not flame cut, brazor weld without NIOSH approved respirator or appropriate ventilation.WARNING J FLAMMABLE. VAPOR HARMFUL. CONTAINS Xylol and/or Toluol. Keep awfrom heatr sparks, and open flame. USE WITH ADEQUATE VENTILATION. Avoidprolonged or repeated contact with skin and breathing of vapor or spray nuDo not take internally. Close container after each use. KEEP OUT OF THEREACH OF CHILDREN. (L.W. S3)

FC ~; CCATlMOS. RfeSi. ' :-• r."^"- . -'-.T ED MATER^A-^OATEOFPREP 11—1-79 "i==l (Approved by U.S. Department el Labor-EssentlallySiinllar-toFonnOSHA.2O)

1 . : . • _...:. * *.•-.': 0\ Section 1 "•;-, '"•':MANUFACTURER'S NAME PPG ,

Coatings & Resins DivisonSTREET ADDRESS One Gateway Center CITY. STATE. AND ZIP CODE Pittsburgh, PA 15222

Attn: Manager, Industrial Hygiene and Product SafetyEMERGENCY TELEPHONE NO. (412) 454-J131 or (412) 274-4508, Ext. 326

PRODUCT CLASS ADcyd MANUFACTURERS CODE IDENTIFICATION S19686

'."?'•-•'• (061879S)TRADE NAME Green Air Dry Enamel

Section II - HAZARDOUS INGREDIENTSINGREDIENT '

Petroleum DistillatesToluol '•}sec-butanoln-Butoxy PropanolXylolAromatic Hydrocarbons - :i

^-J ' . - \ -

(Lead as % Non-Volatile -C. 06%)

PERCENT

2010105

£5.5

TIVPPM mg/M»

200100150N.E.100100

• •

LEL

1.11.11.76.21.11.0

VAPORPRESSURE

5.36.310.00.66.37.0

Section III - PHYSICAL DATABOILING RANGE

EVAPORATION RATE

78 to 194

j ( FASTER

°c

DL1 SLOWER. THAN ETHER

" Section IV -

VAPOR DENSITY .

PERCENT VOLATILEBYVOLUME g.

FIRE AND EXPLOSION

1 X 1 HEAVIER | __ {LIGHTER. THAN AIR

WEIGHT PER£ g GALLON g «

HAZARD DATADOT CATEGORY r>1 -«,.-=, TKl e ' FLASHPOINT e-je-p TJ M r P LEL 1 *>Flammable 01 r P.M.C.L.. i.^

EXTINGUISHING MEDIA use National Fire Protection Association (NFPA) Class Bextinguishers (carbon dioxide, dry chemical or foam) designed to extinguishNFPA Class IB Flammable Liquid fires.

UNUSUAL FIRE AND EXPLOSION HAZARDS Keep containers tightly closed. Isolate from heat,electrical equipment, sparks, and open flame. Closed containers may explodewhen exposed to extreme heat. Do not apply on hot surfaces.

, - .SPECIAL FIRE FIGHTING PROCEDURES Water spray may be ineffective. Water may be used to coolclosed containers to prevent pressure build-up and possible autoignition orexplosion when exposed to extreme heat. If water is used, fog nozzles arepreferable.

AR206S60

FOAM

Section V - HEALTH HAZARD DATA S1968.6» LIMIT VALUE SSS SdCtlOn II.

EFFECTS OF ovEREXPosuHE inhalation: Anesthetic. Irritation of the respiratorytract or acute nervous system depression characterized by headache,dizziness, staggering gait, confusion, unconsciousness or coma.Skin or Eye Contact: Primary irritation.

EMERGENCY AND FIRST AID PROCEDURES Fumes : Remove from exposure. Restore breathing. Keepwarm and quiet. Notify a physician.' Splash (Eyes): Flush immediately withcopious quantities of running water for at least 15 minutes. Take to aphysician for definitive medical treatment. Splash (Skin) : Wash affectedareas with water. Remove contaminated clothing. Consult a physician.

Section vl ~ REACTIVITY DATASTABILITY 1 ) UNSTABLE HT) STABLE CONDITIONS TO AVOIDINCOMPATABILITY (Materials toavoM)

HAZARDOUS DECOMPOSITION PRODUCTS May produce hazardous fumes when heated to decompositionas in welding. Fumes may contain carbon monoxide.

HAZARDOUS POLYMERIZATION ! 1 MAY OCCUR py"! WILL NOT OCCURCONDITIONS TO AVOID unknovm ___

________________Section VII-SPILL OR LEAK PROCEDURES _______STEPS TO BE TAKEN IN CASE MATERIAL is RELEASED OR SPILLED Remove all sources of ignition (flames,hot surfaces, and electrical, static, or frictional sparks). Avoid breathingvapors. Ventilate area. Remove with inert absorbent and non-sparking tools.WASTE DISPOSAL METHOD Dispose in' accordance with local, state, and federal regulationDo not incinerate closed containers._____________________________________

Section Vlil - SPECIAL PROTECTION INFORMATION WRESPIRATORY PROTECTION in outdoor or open areas use NIOSH approved mechanical filterrespirator to remove solid air borne particles of.overspray during sprayapplication. In restricted ventilation areas use NIOSH approved chemical-mechanical filters designed to remove a combination of particulate and gasand vapor. In confined areas use NIOSH approved air line type respiratorsor hoods.VENTILATION Provide general dilution or local exhaust ventilation in volume andpattern to keep TLV of most hazardous ingredient in Section II below acceptabllimit, LEL in Section IV balow stated limit, and to remove decompositionproducts during welding or flame cutting on surfaces coated with this product

PROTECTIVE GLOVES Required for prolonged or repeated contact.EYE PROTECTION Use safety eyewear designed to protect against splash of liquids.OTHER PROTECTIVE EQUIPMENT Prevent prolonged skin contact to contaminated clothing.

Section IX - SPECIAL PRECAUTIONSPRECAUTIONS TO BE TAKEN m HANDLING AND STORING Do not store above 120°F. Store large quant i tie

in buildings designed and protected for storage of NFPA Class IB FlammableOTHERraicAUTioNs Do not take internally. Containers should be grounded when pouriAvoid free fall of liquid in excess of a few inches. Do not flame cut, brazeor weld without NIOSH approved respirator or appropriate ventilation.WARNING: FLAMMABLE. VAPOR HARMFUL. CONTAINS xyioi and/or Toluol. Keep awefrom heat, sparks, and open flame. USE WITH ADEQUATE VENTILATION. Avoidprolonged or repeated contact with skin and breathing of vapor or spray mJvDo not take internally. Close container after each use. KEEP OUT OF THEREACH OF CHILDREN. (L. V7. S3)

flfiZC-3961

pDate of PREP: 11/05/85 (Similar to FormSECTION!

Manufacturer's Name: PPG Industries. Inc. Coatings & Resins Group\_y Address: 260 Kappa Drive Pittsburgh, Pa 15238

Attn: Manager, Industrial Hygiene and Product SafetyEmergency Telephone: (304) 843-1300Product Class: ALKYD-UREA Manufacturer Code: S26603Trade Name: FEDERAL STANDARD GRAY ' (072385S)

SECTION II - HAZARDOUS INGREDIENTSINGREDIENTS UWT. "TLVMIC4! **PPO IPEL CASNO LEL V.P.

XYLENE • 1C 1CC.C« PPMPETROLEUM HVOROCARBON-AROMATIC NAPHTHA ' S tCC.CC PPMPROPVLENE GLVCOL METHYL ETHER ACETATE • S .HEEPOXV RESIN < S .HEISO8UTVL ALCOHOL • < S SC.C« PPMNORMAL 8UTVL ALCOHOL < S 5«.«« PPMTOLUENE . < s ice.ec PPMHI4H FLASH VMIP (lAPHfHA < & 3CC.CC PPMOICTHYLENE GLVCOL MONOSUTVL ETHER <.6C .WE

133C-2C-7N.E.1CC-CS-6N.E. N A N/A78-B3-I 171-36-3 11«6-«e-3 1N.E. 111J-34-S C

I 6.36 13 3.7

r e.er 5.52 22.41 5.3» . C2

•Ore:' • threshold Limit Value csl AUsnod h»> «"«rtc»n Conference el Governmental Industrial Wrtfenbtt~"PPO'Slnten«IP«ra*stole Exposure UmU ,

SECTION IU - PHYSICAL DATABoiling Range: 108-280 DEG.C. Vapor Density - HEAVIER THAN AIREvaporation Rate = SLOWER THAN ETHER S Vplatile/Vol: 62.10 Wt/Gal: 9.65

SECTION IV - f-MRE AND EXPLOSION HAZARD DATADOT Category: FLAMMABLE Flashpoint: 60 DEG.F. PMCC LEL: 1.3

(i Extinguishing Media: .. USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS B

EXTINGUISHERS (CARBON DIOXIDE. DRY CHEMICAL OR FOAM) DESIGNED TO. EXTINGUISH NFPA CLASS IB FLAMMABLE LTQUIO FIRES.

Unusual Fire i Explosion Hazards:KEEP CONTAINERS TIGHTtV CLOSED. ISOLATE FROM HEAT. ELECTRICALEQUIPMENT. SPARKS AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODEWHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY ON HOT SURFACES.

Special Fire Fighting Procedures:• WATER SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CLOSED

CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE Al/TOIGNITIONOR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED. FOGNOZZLES ARE PREFERABLE:

SECTION V- HEALTH HAZARD DATAThreshold Limit Value: SEE SEC. II

Effects of Overexposure:INHALATION: ANESTHETIC. IRRITATION OF THE RESPIRATORY TRACTORACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY THE FOLLOWINGPROGRESSIVE STEPS: HEADACHE. DIZZINESS. STAGGERING GAIT.CONFUSION. UNCONSCIOUSNESS. OR COMA.SKIN OR EYE CONTACT: PRIMARY IRRITATION.REPEATEDOVEREXPOSURE TO SOLVENT VAPORS MAY CAUSE PERMANENTBRAIN ANDNERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BYDELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BEHARMFUL OR FATAL. EYE WATERING. HEADACHES. NAUSEA. DIZZINESS.AND LOSS OF COORDINATION ARE INDICATIONS THAT SOLVENT LEVELSARETOOHIGH.

Emergency and First Aid Procedures:FUMES: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WAI M AND

Continued on Back of Page \

n p r? n c o C 9H H c u O ./ 0 £

•** ^.v'.-!.

* " i;j QUIET. NOTIFY A PHYSICIAN. SPLASH (EYESV.FLUSH IMMEDIATELY WITHCOPIOUSQUANTII lES OF'• IUNNING WATER FOR AT LEAST 15MINUTES. TAKETO A PHYSICIAN FOR DEFINITIVE MEDICAL TREATMENT. SPLASH (SKIN):WASH AFFECTED AREAS WITH WATER. REMOVE CONTAMINATED CLOTHING.CONSULT A PHYSICIAN.

SECTION VI - REACTIVITY DATASTABILITY: STABLE Conditions to Avoid: UNKNOWNIncompatibility (Materials to Avoid): UNKNOWNHazardous Decomposition Products:May produce hazardous fumes when heated to decomposition as ir. v/elding.Fumes may contain: Cartoon Monoxide. Oxides of NitrogenHazardous Polymerization - WILL NOT OCCURCONDITIONS TO AVOID: UNKNOWN

SECTION VII - SPILL OR LEAK PROCEDURESSteps to be Taken in Case Material is Release or Spilled:

REMOVE ALL SOURCES OF IGNITION (FLAMES. HOT SURFACES. ANDELECTRICAL. STATIC. OR FRICTIONAL SPARKS). AVOID BREATHINGVAPORS. VENTILATE AREA. REMOVE WITH INERT ABSORBENT ANDNQN-SPARKING TOOLS.

Waste Disposal Method:DISPOSE IN ACCORDANCE WITH LOCAL. STATE AND FEDERAL REGULATIONS.DO NOT INCINERATE CLOSED CONTAINERS.

SECTION VIII - SPECIAL PROTECTION INFORMATIONRespiratory Protection:

OUTDOOR/OPEN AREAS: USE FILTER TYPE RESPIRATORSlNlOSH/MSHA TC21C)TO REMOVE SOLID AIRBORNE PARTICULATES FROM OVERSPRAY. RESTRICTED

• VENTILATION AREAS: USE COMBINATION ORGANIC VAPOR-FILTER TYPE RESPIRATORS (NIOSH/MSHA TC23C) DESIGNED TO PURIFY THE AIR BY REMOVINGSOLID AIRBORNE PARTICULATES AND ORGANIC VAPORS. CONFINED AREAS:

. USE SUPPLIED AIR RESPIRATORS OR HOODS (NIOSH/MSHATC19C). IN ALLCASES. PLEASE READ MANUFACTURER'S INSTRUCTIONS CAREFULLY TODETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THERESPIRATOR IS EFFECTIVE. AND HOW IT IS TO BE PROPERLY FITTED.

Ventilation:PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUMEAND PATTERN TO KEEP THE CONCENTRATION OF HAZARDOUS INGREDIENTS

• LISTED IN SECTION II BELOW THE LOWEST SUGGESTED EXPOSURE LIMITS.THE LEL IN SECTION IV BELOW THE STATED LIMIT. AND TO REMOVEDECOMPOSITION PRODUCTS DURING WELDING OR FLAME CUTTING ONSURFACES COATED WITH THIS PRODUCT.

Protective Gloves:REQUIRED FOR PROLONGED OR REPEATED CONTACT-

Eye Protection: •USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.

Other Protective Equipment:PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED CLOTHING.

SECTION IX - SPECIAL PRECAUTIONSPrecautions to be Taken in Handling and Storing:

DO NOT STORE ABOVE 120 F. STORE LARGE QUANTITIES IN BUILDINGSDESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS IB FLAMMABLELIQUIDS.

Other Precautions:DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED WHENPOURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES.DO NOT FLAME CUT.8RAZE OR WELD WITHOUT NIOSHAPPROVED RESPIRATORS OR APPROPRIATE VENTILATION.OVENS MUST OPERATE PROPERLY. BE VENTED.

AR206963

wmm%jjmm$ · insurance for the period 1980-1988. Please note that while Stanley-Vidmar believes...

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Transcript of wmm%jjmm$ · insurance for the period 1980-1988. Please note that while Stanley-Vidmar believes...