Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter...

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Wednesday, April 8 Reminders: Take-home due FRIDAY Handouts: Readings: •Chang & Thoman: Appendix 11.1, 14.6 Today: Other types of spectroscopy Vibronic NMR Moving to the solid state Last Time: - Finished practice problems

Transcript of Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter...

Page 1: Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter Atkins and Julio de Paula Magnetic field on 0.0239 J 1.41 0.12 7.05 Tesla -1/2 1/2 syc

Wednesday, April 8

Reminders: •  Take-home due FRIDAY

Handouts:

Readings: • Chang & Thoman: Appendix 11.1, 14.6

Today: •  Other types of spectroscopy

•  Vibronic •  NMR

•  Moving to the solid state

Last Time: -  Finished practice problems

Page 2: Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter Atkins and Julio de Paula Magnetic field on 0.0239 J 1.41 0.12 7.05 Tesla -1/2 1/2 syc
Page 3: Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter Atkins and Julio de Paula Magnetic field on 0.0239 J 1.41 0.12 7.05 Tesla -1/2 1/2 syc
Page 4: Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter Atkins and Julio de Paula Magnetic field on 0.0239 J 1.41 0.12 7.05 Tesla -1/2 1/2 syc

Electronic-vibrational (vibronic) transitions

Page 5: Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter Atkins and Julio de Paula Magnetic field on 0.0239 J 1.41 0.12 7.05 Tesla -1/2 1/2 syc

Electronic-vibrational (vibronic) transitions

Page 6: Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter Atkins and Julio de Paula Magnetic field on 0.0239 J 1.41 0.12 7.05 Tesla -1/2 1/2 syc

Franck-Condon Principle

Page 7: Wednesday, April 8 - Stockton University...Atkins Physical Chemistry, Eighth Edition 2006 Peter Atkins and Julio de Paula Magnetic field on 0.0239 J 1.41 0.12 7.05 Tesla -1/2 1/2 syc
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Energy

UV/Vis IR Microwave

• Electronic Transitions • HOMO-LUMO gap • Sharp = Atoms • Broad = Molecules

• Vibrational transitions • Bond strength • Bond Order

• Rotational transitions • Bond length • Geometry

Molecules only

Radio X-Ray

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