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Chemistry CPA Final Exam Study Guide Final Exam Date: Wednesday, June 18, 2014
Exam Time: 10:15 – 12:00 pm
Topic List
Chemical Reactions Parts of a reaction Identify the types of reactions Balance Write the formula equation if you are given a word equation
Mole Molar Mass Convert moles-grams and grams-moles Percent Composition Stoichiometry Limiting Reactant Percent Yield
Solutions Solubility Curves Molarity
Gas Laws and KMT Kinetic Molecular Theory Heating/Cooling Curves Boyle Charles’ Gay-Lussac Ideal
Acid/Base Properties Calculate pH and pOH and find [H+] and [OH-]
Exam Structure
o Part 1 = 80 points: Multiple choice questionso Part 2 = 20 points: Open-Ended/Free Response
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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moles
M L
You will be given the following formula sheet and a periodic table.
Mole Conversion
Given unit x _____________
Given unit
Percent Composition = Mass of element x 100 Molar mass
Percent yield = actual x 100 theoretical
Gas laws
Temperature in Kelvin = °C + 273
P1V1=P2V2 T1V2 = T2V1 T1P2 = T2P1
PV = nRT, where R = 0.0821L ∙atmK ∙mol
Molarity
Acids & Bases
pH + pOH = 14 pH = - log [H+] pOH = - log [OH-]
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
Desired unit
Example:
pH is 5 = [H+] = 1 x 10-5
pOH is 9 = [ OH-] = 1 x 10-9
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Unit 5: Chemical Reactions
1. What does the law of conservation of mass state?
2. Why is it necessary to balance a chemical equation?
3. What is the difference between a word equation and a chemical equation? Give an example of each.
Complete the chart
Symbol Explanation
Used to separate two reactants or two products
Yields, separates reactants and products
States of matter; Fe (s)
Aqueous solution – dissolved in water
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4. Identify the type of reaction and balance the reaction.
A) ____ NaBr + ____ Ca(OH)2 ___ CaBr2 + ____ NaOH
Type of reaction: _____________________________
B) ____ NH3+ ____ H2SO4 ____ (NH4)2SO4
Type of reaction: _____________________________
C) ____ C5H9O + ____ O2 ____ CO2 + ____ H2O
Type of reaction: _____________________________
D) ____ Pb + ____ H3PO4 ____ H2 + ____ Pb3(PO4)2
Type of reaction: _____________________________
E) ____ Li3N + ____ NH4NO3 ___ LiNO3 + ___ (NH4)3N
Type of reaction: _____________________________
F) ____ HBr ____H2 + ____Br2
Type of reaction: _____________________________
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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5. Balance the reaction: Ag + HNO3 AgNO3 + H2O + NO2
A. 1:1:1:1:1
B. 2:2:2:2:1
C. 2:1:2:2:2
D. 1:2:1:1:1
E. none
6. Given the following word equations, right a formula equation. Then identify the type of reaction:
A. Sodium metal and chlorine gas react to form sodium chloride crystals
B. propane gas and oxygen gas react to form carbon dioxide, water vapor, and energy.
C. zinc metal reacts with hydrochloric acid to form zinc chloride solution and hydrogen gas.
Lab Questions: Know/be able to do:
Know the signs of a chemical reaction
Know the five classifications of a chemical reaction
Know the activity of metals
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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Unit 6: Moles
Match each item with the correct statement below.
a. particleb. molec. Avogadro's number 6.02 x 1023
d. percent composition
7. _______ the number of particles of a substance present in 1 mole of that substance
8. _______A term to describe an atom, ion, or a molecule
9. _______the SI unit used to measure amount of substance
10._______the percent by mass of each element in a compound
Molar Mass (use your periodic table)
11.What is the molar mass of AuCl3?
12.What is the molar mass of (NH4)2CO3
13.What is the molar mass of barium?
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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Moles and Mass (use the molar mass to convert to moles or grams)
14.What is the mass in grams of 5.90 moles of C8H18
15.What is the mass in grams of 9.32 moles of He?
16.What is the number of moles in 432 g Ba(NO3)2?
17.What is the number of moles of beryllium in 36 g of Be?
Percent Composition (use the molar mass to calculate the percent of the element)
18.What is the percent composition of chromium in BaCrO ?
19.What is the percent of carbon in acetone, C H O?
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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Stoichiometry
MgCl2 + NaOH Mg(OH)2 + NaCl
20.Balance the above reaction.
21.What is the mole ratio of MgCl2 to NaOH?
22. Identify the limiting reactant if 2 mole of MgCl2 and 2 mole of NaOH are used in a reaction.
Li + H(OH) LiOH + H2
23.Balance the above reaction.
24.What is the mole ratio of Li to water?
25. Identify the limiting reactant if 2 mole Li and 2 mole of water are used in a reaction.
Lab Questions – Know/be able to do:
If you are given grams from lab data, convert to moles How to determine the mole ratio from lab data (Moles of Fe and Cu
lab) Predict the products of a single-replacement reaction:
o Mg + HCl ________ + _________ ?
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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Unit 7: Solution Chemistry
26.Given grams how do you solve for moles? Example: convert 90 grams of water to moles.
27.Molarity is equal to __.
a. Grams of solute / moles of soluteb. Volume of solution x moles of solutec. Moles of solute / liters of solution d. Volume of solution / grams of solute
28.What mass of methanol, CH3OH, must be dissolved to make 1.50 L of a 0.675M solution? SHOW YOUR WORK!!!!
29.What is the molarity of a solution of HNO3 that contains 250 grams HNO3 in 3 L of solution? Convert grams to moles first.
30.What volume of 18.0 M H2SO4 is needed to contain 200 g H2SO4? Convert grams to moles first.
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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31.How many moles of CaCl2 are required to prepare 2.00 liters of 0.700 M CaCl2?
32.How many grams of NaI would be used to produce a 2.0 M solution with a volume of 1.0L? Solve for moles and convert your answer to grams.
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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Use this solubility curve to answer the next set of questions (#33- 37) on the following page:
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33. If there are 100 grams of KNO3 dissolved in 100 g of water at 70oC, the
solution is __.
a. saturated
b. unsaturated
c. supersaturated
34. If there are 10 grams of NaCl dissolved in 100 g of water at 30oC, the
solution is __.
a. saturated
b. unsaturated
c. supersaturated
35. If there are 70 grams of KBr dissolved in 100 g of water at 20oC, the
solution is __.
a. saturated
b. unsaturated
c. supersaturated
36. If there are 120 grams of NaClO3dissolved in 100 g of water at 60oC, the
solution is __.
a. saturated
b. unsaturated
c. supersaturated
37. If there are 190 grams of KNO3 dissolved in 100 g of water at 70oC, the
solution is __.
a. saturated
b. unsaturated
c. supersaturated
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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Lab Questions: Know/be able to do:
What “like dissolves like” means Polar dissolves polar and nonpolar dissolves nonpolar polar and nonpolar do not dissolve water is a polar molecule and makes hydrogen bonds
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Unit 8: Gas Laws and KMT
Kinetic Molecular Theory and Heating Curves
38. What is the kinetic molecular theory?
39. How are temperature and kinetic energy related?
40.When a substance is in a single state of matter and the temperature is
increasing, there will be an increase in the (kinetic energy/potential
energy) of the particles.
41.When a substance is undergoing a phase change and the temperature is
not changing, there will be an increase in the (kinetic energy/potential
energy) of the particles.
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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For questions 42 – 45, use the following graph:
42.What is the melting point of:
a. substance A?
b. substance B?
43.Which substance will melt first?
44.What is the boiling point of:
a. substance A?
b. substance B?
45.Which substance will boil first?
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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The Gas Laws
Gas Law Theory
46.Draw and label the graph for each gas law (Boyle’s, Charles’, Gay-
Lussac).
47.Why is it easier to compress a gas than it is to compress liquids or solids?
48.Why does air escape a tire valve when the cap is removed?
49. Is atmospheric pressure the highest below, at, or very high above sea level?
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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Gas Law Calculations
50.A 500.0 mL sample of gas is collected at 745.0 torr. What will the volume be at 760 torr?
Gas Law: ________________
51.A 2L sample of gas at 100 K is heated to 150 K. What is the new volume? Gas Law: ________________
52. If I initially have a gas at a pressure of 12 atm, a volume of 23 liters, and then I raise the pressure to 14 atm, what is the new volume of the gas?
Gas Law: ________________
53.A gas takes up a volume of 17 liters, and a temperature of 299 K. If I raise the temperature to 350 K what is the new volume of the gas?
Gas Law: ________________
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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54. I have a gas at a volume of 0.5 L and a temperature of 325 K. If I raise the volume to 1.2 L, what will be the new temperature?
Gas Law: ________________
55. If I have 21 liters of gas at a temperature of 900 K, what will be the volume of the gas if I decrease the temperature to 750 K?
Gas Law: ________________
56. If I have a sample of gas at 300 K and a pressure of 5 atm, what will be the temperature of the gas if I decrease the pressure to 3 atm?
Gas Law: ________________
57.A gas occupies a fixed volume at 285 K at 1 atm. If the pressure increases to 3 atm, what is the new temperature?
Gas Law: ________________
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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58.A sample of nitrogen gas (N2) occupies a volume of 0.25 L at a pressure of 2 atm and 22°C. How many moles of N2 gas are there in this sample?
Gas Law:________________
59.How many grams of N2 gas are there in question 66? (Hint: use moles to grams conversion!)
60.A 4.5 mole sample of gas occupies a volume of 1.3 L at a temperature of 293 K. What is the pressure of the gas?
Gas Law:________________
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Unit 9: Acids & Bases
61.List the properties for acids below.
62.List the properties for bases below.
63.What happens when an acid is mixed with a base? (Write the general form for the reaction that happens)
64.What is the range of the pH scale?
65.What is the pH range for acids?
66.What is the pH range for bases?
67.What is the pH for a neutral solution?
68.pH + pOH =
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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69.Complete the chart
[H+] pH [OH-] pOH Acid , Base, Neutral
11
7
1 x 10-2
1 x 10-2
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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70.Review the sample data table below from a student’s lab and answer the following questions.
Test Property
Test Solutions
A B C
Conductivity Very strong Very strong none
Litmus Paper Turns Red Turns Blue No change
Phenolphthalein colorless Pink color change
colorless
pH Test Paper
4.0 10.0 7.0
Universal Indicator
Red Purple Green
Reaction with Magnesium
Produces a gas none none
Chemistry CPA Final Exam Study Guide - 2014Callahan, Pengitore & Ricafort
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Questions to go with the #62 Data Table:
A. Is Solution A an acid, base, or neutral? Why?
B. Is Solution B an acid, base, or neutral? Why?
C. Is Solution C an acid, base, or neutral? Why?
D. What are the chemical properties that this student tested?
E. What are the physical properties that this student tested?
F. What were the qualitative observations this student made?
G. What are the quantitative observations this student made?
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