We make CLEAN power CLEANER We make …Phase 1 Fluorine Extraction Process • The Fluorine...

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We make CLEAN power CLEANER International Isotopes Inc We make CLEAN power We make CLEAN power CLEANER Presentation on Depleted CLEAN power CLEANER Presentation on Uranium Processing Uranium Hexafluoride Processing & Presentation on Uranium Processing & Fluorine Extraction Process & Fluorine Extraction Process Prospective Investor Presentation

Transcript of We make CLEAN power CLEANER We make …Phase 1 Fluorine Extraction Process • The Fluorine...

Page 1: We make CLEAN power CLEANER We make …Phase 1 Fluorine Extraction Process • The Fluorine Extraction Process (FEP) is a si mple, one step reaction process between two granular solid

We make CLEAN power CLEANERInternational Isotopes Inc

We make CLEAN power 

We make CLEAN power CLEANER

Presentation on Depleted CLEAN power CLEANER

Presentation on Uranium Processing

ese tat o o ep etedUranium

Hexafluoride Processing&Presentation on Uranium Processing

&Fluorine Extraction Process

&Fluorine Extraction Process

uo e t act o ocess

Prospective Investor Presentation

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What We Intend to DoWhat We Intend to DoConstruct the first commercial depleted uranium de-conversion facility in the USconversion facility in the US.

– Multi-Purpose Purpose Facility

• DUF6 off-take agreements for de-conversion

• Fluorine Extraction Process – exclusive technology to INIS

• Anhydrous HF Production – Patented Process• Anhydrous HF Production – Patented Process

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Estimated Depleted Uranium Hexafluoride Production in the U.S.

Annual Production in the U S 100 ..

90

80 70

Millions of 60 Poundsof Depleted 50 Uranium

Hexafluoride 40

30

20 10

o I .,

Cumulative Production in the U S 700 . .

Millions of Pounds of

600

500

Depleted 400 Uranium

Hexafluoride Cumulative 300

200

100

o • I

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SCHEDULE GOING FORWARD• Phased Expansion Correlated to DUF6 Supply

Phase I Initial Start up BFPhase I – Initial Start-up BF3UF6 UF4 SiF4 FEP

SiF4 FEP UO2

2500

UF6 Cylinders Available Phase II – 2016 Increase De-ConversionCapability to meet anticipated demand

1500

2000

2500

Cylinders Of DUF6

UF6 UO2

HF

500

1000

1500 HF

0

500

12 13 14 15 16 17 18 19 20

20 20 20 20 20 20 20 20 20

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Site Selection - Hobbs, NM

• Public Acceptancep¯ Over 40 public meetings held¯ No negative response¯ Phase 1 Environmental completed¯ Land Transfer in Progressg

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Project Timeline

INIS Acquires FEP Patents 2004

INIS Focuses on Design of FEP Pilot Plant 2004-2007

GeF4 Pilot Plant Begins Operation 2007

Acquisition of SFC DUF6 – DUF4 De-Conversion Equipment Q2 2008

Contract with Licensing and Design Team (APTS) Q3 2008

Site Selection – completed Q1 2009

Conceptual Design Report - completed April 2009

NRC License Application Submittal Dec. 1, 2009

Land Transfer Process Dec. 30, 2009

Begin Construction Q2 2011

Begin Operation Q2 2012

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Illustrative Plant

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Phase 1 De-Conversion – DUF6to DUFto DUF4•INIS acquired assets of the only complete de-conversion plant in the U.S. in 2008

- Most key components can be re-used- Will relocate equipment Phase 1 UF6 to UF4 De-conversion Process Flowq p

HydrogenUF6

Carbon Traps

6 4

Surge Tank

Autoclave

UF4Hopper

Partial HF Condensers

AHF Storages

DrumFill

H2 Burner

To 3 stage Scrubbing System

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Phase 1 Fluorine Extraction ProcessProcess

• The Fluorine Extraction Process (FEP) is a simple, one step reaction process between two granular solid materials

D l t d i t t fl id (DUF ) d t l id h t d i ti h b t th i t– Depleted uranium tetrafluoride (DUF4) and a metal oxide are heated in a reaction chamber to the appropriate temperature

– Fluoride gas separates from uranium and combines with gaseous metal oxide• Various ultra-pure, uranium-free, fluoride gases are produced while uranium remains in solid-state• Exclusive U S Patent Technology held by INIS enhances commercial viability of de-conversionExclusive U.S. Patent Technology held by INIS enhances commercial viability of de conversion

Example Reaction - SiF4 ProductionExample Reaction SiF4 Production

UF4 (solid) + SiO2 (solid) UO2 (solid) + SiF4 (gas)Heat

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SiF4 Production4From SiO2 Hopper

Si t d

Pre-Condenser

DUF4 SiO2

To 3 stage Scrubbing

Cold Trap

SecondaryCold Trap

RotaryCalciner

Blender/Mill

Sintered metal filters

Water/HFRemoval Dust

Pre-filter

Heater

Dust Collector

g gSystems

Calciner

Cooling Conveyor Nash Pump

To Emergency ScrubberFrom Hood System

Oxide

Hopper

Collector

Vent

To Drums

EmergencyScrubber

SeparatorChillerFlashTank

Scrubber

Compressor

SiF4Storage

To Packaging

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BF3 Production3

B O DUF

To ScrubberTo ScrubberB2O3 DUF4

Cold Trap

Cold Trap

Filter Systems

BlenderPre-condenser

Filter System

Preheater

Rotary Calciner

UraniumOxide

PrimaryDC

Chiller

Separator

t

To Cylinders

Storage

SecDC

WetDrum Filling

vent

CompressionScrubberDrum FillingTo Recovery

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Phase 2 De-Conversion – DUF6to DUOxideto DUOxide

(2)

Scrubber

PrimaryDust

Collector(1)BackUp DC

DUF6ReactionVessel

DUF6

H2ODUF6ReactionVessel

H2O

VesselDistillation

UO2F2Calciner

Azeotrope

Vessel

(3)OxideHoppers

H2OSteam

To Scrubber

Air

A t A t

CDR 5/28/2009Rev 0 MS

SteamSystem

Azeotrope Azeotrope

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Environmental and Safety Concerns

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Air Emissions

• Air EmissionsAir Emissions¯ Uranium – Conservative estimate of 5.11 mrem per

year at 30 acre fence line with Phase 1 and 2year at 30 acre fence line with Phase 1 and 2 Operations

¯ Fluorine – Conservative estimate of 13.8 lb per yearFluorine Conservative estimate of 13.8 lb per year HF with Phase 1 & 2 Operations.

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Uranium Release Evaluation – 24/7 OperationsUranium Release Evaluation – 24/7 OperationsPhase 2

DUF6 to DU Oxide Stack Uranium Emissions

Phase 1 SiF4 & BF3 Production Stack

U Emissions

Phase 1 DUF6 to DUF4 Stack Uranium Emissions

Oxide Hopper to Dust Collection System

15.4 lb/hr U3O813.1 lb/hr U

BF3 Oxide Hopper to Dust Collection System

2.2 lb/hr U3O81.87 lb/hr U

SiF4 Oxide Hopper to Dust Collection System

5.5 lb/hr U3O84.66 lb/hr U

UF4 Hopper to Dust Collection System

8.8 lb/hr UF46.67 lb/hr U

H2 Burner OutputTo Dust Collection System

0.0005 lb/hr UF43.8 E- 4 lb/hr U

Dust Collector 1η = 99.5%

6.53 E-2 lb/hr U

Dust Collector 1η = 99.5%

9.33 E -3 lb/hr U

Dust Collector 1η = 99.5%

2.33 E-2 lb/hr U

Dust Collector 1η = 99.5%

3.34 E-2 lb/hr U

KOH Scrubberη = 90%

3.8 E-5 lb/hr U

Dust Collector 2η = 99.5%

3.26 E- 4 lb/hr U

3.26 E-2 lb/hr U

Dust Collector 2η= 99.5%

Dust Collector 2η = 99.5%

1.67 E-4 lb/hr U

Venturiη = 80%

1.63 E-4 lb/hr U

Venturiη = 80%Venturiη = 80%

Venturiη = 80%

2.09 mrem/yr

6.53 E- 5 lb/hr U

3.26 E- 5 lb/hr U

3.34 E- 5 lb/hr U

7.13 E-5 lb/hr U 3. 02 mrem/yr

Total Annual Dose at 30 acre fence line resulting from Phase 1 Operational U releases = 3.02 mrem/yrTotal Annual Dose at 30 acre fence line resulting from Phase 1 & 2 Operational U releases = 5 11 mrem/yrTotal Annual Dose at 30 acre fence line resulting from Phase 1 & 2 Operational U releases 5.11 mrem/yr

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Radon Levels New MexicoRadon Levels ‐ New Mexico

Zone 1 counties have a predicted average indoor radon screening level greater than 4 pCi/L (pico curies per li ) ( d )

Highest Potential

liter) (red zones)

Zone 2 counties have a predicted average indoor radon screening level between 2 and 4 pCi/L (orange zones)

Moderate Potential

Zone 3 counties have a predicted average indoor radon screening level

Low Potentialg g

less than 2 pCi/L (yellow zones)

The North Central region (Albuquerque area) exhibits an average annual absorbed dose 0.75 mGy (75 mrad); while the southeastern corner of the State (Carlsbad area), which includes the IIFP site area in Lea County, measures annual average absorbed dose of about 0.30 mGy (30 mrad), due to terrestrial radiation (NCRP, 1987a).

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Fluorine Release Evaluation – 24/7 OperationsFluorine Release Evaluation – 24/7 OperationsPhase 1 – DUF6 De-conversion & Fluorine Extraction Plants Plant

BF3 Train1.0 lb/hr BF3

DUF6 to DUF4De-conversion Plant

SiF4 Trains 1 & 20.2 lb/hr SiF4

Phase 2 – DUF6 to DU Oxide De-conversion

DUF6 to DU OxideDe-conversion Plant

Stage 1 Venturiη = 80%

Stage 1 Venturiη = 80%

Stage 1 Venturiη = 80%

35.2 lb/hr HF

5.22 lb/hr as F3.0 lb/hr HF

2.85 lb/hr as F

40.2 lb/hr HF

0.23 lb/hr as F7.0 lb/hr HF

6.65 lb/hr as F

Stage 1 Venturiη = 80%

1.66 lb/hr as F

1.04 lb/hr as F0.57 lb/hr as F 0.05 lb/hr as F 1.33 lb/hr as F

Stage 2 Packed Tower

η = 95%Stage 2

Packed Towerη = 95%

0.083 lb/hr as F

η = 95%

0.07 lb/hr as F

Stage 3 Coke Box

Stage 3 Coke Box

η = 99%

0 0008 lb/h F 7.01 lb/yr as F 6.13 lb/yr as F

Boxη = 95%

0.0007 lb/hr as F

0.0008 lb/hr as F 7.01 lb/yr as F7.38 lb/yr as HF

6.13 lb/yr as F6.45 lb/yr as HF

Phase 1 & 224/7 Operations13 1 lb/ F13.1 lb/yr as F

13.8 lb/yr as HF

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Point Source and Fugitive HF Release –New Mexico

TRI 2006 TRI 2007 (lb)Facility

TRI – 2006 (lb)

TRI – 2007 (lb)

Four Corners Steam Electric Station 90,090 86,090Giant Refining Co.(1) 58 30INTEL Corp. 3,465 2,206Navajo Refining Co 347 347Navajo Refining Co. 347 347San Juan Generating Station 58,000 67,000Tri‐State Generation & Transmission – Escalante Station 10,600 13,600

Total: 162,560 169,273 

IIFP C l l t d 14 lb/IIFP Calculated: 14 lb/year

(1) Name Change to Western Refining Southwest Inc. for 2007( ) g g

US EPA Toxic Release Inventory

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HF Emissions in New Mexico in 2007HF Emissions in New Mexico in 2007

INTERNATIONAL

SAN JUAN GENERATING

STATION

INTERNATIONAL ISOTOPES FLUORINE

PRODUCTS14 lb

INTEL CORP2,206 lb

67000 lb

WESTERN REFINING FOUR CORNERS

NAVAJO REFINING CO347 lbTRI-STATE

GENERATION & TRANSMISSION

WESTERN REFINING SOUTHWEST INC

30 lb

FOUR CORNERS STEAM ELECTRIC

STATION86,092 lb

TRANSMISSION13600 lb

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HF Emissions New Mexico 2007Four Corners Steam Electric Station – 86,090 lb

San Juan Generating Station – 67,000 lb

HF Emissions New Mexico ‐ 2007

Western Refining Southwest Inc. –Gallup Refinery – 30 lb

INTEL – 2,206 lbTri-State Generation & Transmission– Escalante Station – 13,600 lb

Navajo Refining Co. – 347 lb

IIFP – 14 lbIIFP – 14 lb

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Water Usage & Ground Water Protection

• Water UsageWater Usage¯ Minimized thru process water recycling – estimated usage

< 10,000 gallon per day.

• Ground Water ProtectionGround Water Protection¯ Permit will be Issued though NMED.

¯ Storm water basins designed for 100 year rain fallStorm water basins designed for 100 year rain fall

¯ Segregated yard for DUF6 cylinder storage.

¯ Zero discharge of process waters g p

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Phase 1 Environmental Protection ProcessWaste Water Treatment Flow DiagramWaste Water Treatment  Flow Diagram

Lime Silo

KOHRecycledTo Process Scrubber

Weak HF

ThickenerPolishing Filters

Reactor

Clarifier

SolutionMix

Tank

KOHRegen

g

Rotary Vacuum

Filter

DryerSpent

Storage

Auger toDryerKOHSolution

Mix

Solids To Disposal

Auger toTruck

.5 lb/hr Ca(OH)2387 lb/hr H2O186 lb/hr CaF243 lb/hr KOH8 lb/hr KBF

Tank

Reactor Thickener

Filtrate

.8 lb/hr KBF4

.2 lb/hr B(OH)3

.4 lb/hr K2SiF6

194 lb/hr Ca(OH)2

KOH Regeneration

HF Neutralization

Common to bothFiltrate Tank

Max avg. 4 hours per day operation

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Phase 2 Environmental Protection ProcessWaste Water Treatment Flow DiagramWaste Water Treatment  Flow Diagram

Lime Silo

KOHRecycle toProcess Scrubber

Weak HF

ThickenerPolishing Filters

Reactor

Clarifier

SolutionMix

Tank

KOHRegen

St

Rotary Vacuum

Filter

DryerSpent KOH

Storage

Auger toyKOHSolution

Mix

Solids To Disposal

gTruck

.5 lb/hr Ca(OH)2112 lb/hr H2O54 lb/hr CaF212 lb/hr KOH.8 lb/hr KBF4Tank

Reactor Thickener

Filtrate

.8 lb/hr KBF4

.2 lb/hr B(OH)3

.4 lb/hr K2SiF6

56 lb/hr Ca(OH)2

KOH Regeneration

HF Neutralization

Common to both

Tank 4 hours operation per dayMaximum Avg.

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Sanitary Waste Water Treatment  Flow Diagram

PrimaryTreatment

Secondary Treatment

150 PeoplePeak HydraulicL d

Tertiary Treatment

Load3000-4500 GallonPer Day

Use for(Facility Shrubs trees & Grass)

Plant ProcessMakeup (Facility Shrubs, trees & Grass)MakeupWater

Page 25: We make CLEAN power CLEANER We make …Phase 1 Fluorine Extraction Process • The Fluorine Extraction Process (FEP) is a si mple, one step reaction process between two granular solid

Maximum InventoriesMaximum Inventories

l h hMaterial Phase 1(Kg)

Phase 2(Kg)

Uranium as “U” 750 000 2 200 000Uranium as  U 750,000 2,200,000

Anhydrous HF 15,900 17,700

SiF4 32 000 32 000SiF4 32,000 32,000

BF3 15,000 15,000

CaF2 128,500 37,200CaF2 128,500 37,200

KOH(with recycle) 8,100 2,700

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Waste Disposal

• Depleted uranium oxides are chemically stable• Depleted uranium oxides are chemically stable

• Uranium waste is shipped to licensed disposal site

Utah – Energy Solutions

Texas – WCS (after NRC Rulemaking)Texas WCS (after NRC Rulemaking)

• The by-products of chemical scrubbing are

neutralized (RCRA waste same sites as above)

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Transportation Impact ‐ Construction and Operationsand Operations

l l ff h /Average Annual Daily Traffic Highway 62/180Year Average No. Vehicles 

per DayAverage No.Com. Truckp y

Baseline  2008 5672 1645

2007 6124 1776

2006 6035 1750

During Construction IIFP Facility:17  Deliveries & site prep + 350 Construction workers(14‐18 Mos.)

During Operations IIFP Facility: 10 deliveries + 75‐150 Employees

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State Permitting Submittal Schedule

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Potentially Required State PermitsPotential 

RequirementAgency Comment/Status Submittal Time 

FrameAccess Permit NMDOT INIS and/or Lea County would coordinate to obtain approval, if necessary, for  2 Q, 2010

adding an entry point from U. S. Highways 62/180 or NM Highway 483.  The permit, if issued, would stipulate any safety enhancements necessary to the highway.

Air Construction Permit NMED/AQB An air construction permit may not be required because proposed INIS emissions would be below Federal and State regulatory limits depending on credits for 

If required, submit by 2 Q, 2010.

stack heights and control equipment.  Need determination with State.Air Operation Permit NMED/AQB An air operation permit may not be required because proposed INIS emissions 

would be below the Federal and State regulatory limits depending on above credits.  Need determination with State.

If required, would submit 2 Q, 2011.

NESHAP Permit NMED/AQB A NESHAP permit is likely not required because the proposed INIS emissions  If required, submit by would be below Federal and State regulatory limits.  Need to determine with State.

2 Q, 2011.

Groundwater Discharge Permit/Plan

NMED/WQB INIS will submit Groundwater Discharge Permit / Plan application to the NMED/WQB.

4 Q, 2010

NPDES Industrial Stormwater NMED/WQB INIS has the option of claiming “No Exposure” exclusion. Make determination by 3 Q, 2010.  If required, submit by 1 Q, 2011.

NPDES Construction Stormwater Permit

NMED/WQB INIS will file for coverage under the General Construction Permit for all construction activities onsite.  INIS will develop a Stormwater Pollution 

2 Q, 2010

Prevention Plan and file a Notice of Intent.Hazardous Waste Permit NMED/HWB INIS would be classified as a generator; therefore, a hazardous waste permit 

would be required.3 Q. 2011

EPA Waste Activity EPA ID Number

NMED/HWB This number is required for the storage and use of hazardous chemicals. 3 Q, 2011

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Potentially Required State PermitsPotential 

RequirementAgency Comment/Status Submittal Time 

FrameMachine‐Produced  (X‐Ray  NMED/RCB Registration is required for security nondestructive inspection (x‐ray) machines.   Decide who holds Inspection) The RCB will be notified that equipment would be registered, but the 

registration would be deferred until equipment specifications are available.  May be required by contractor with their own permit.

permit by 1Q, 2011.

Rare, Threatened, & Endangered Species Survey 

NMDFG This permit would be required for conducting surveys of the U.S. Bureau of Land Management (BLM) lands. 

4 Q, 2009

PermitRCRA Operations Permit EPA

May Involve NMED/HWB

Permit likely not required for the EPP operation, but need to confirm with the State.

If required, would submit permit application 4 Q, 2011.

Right‐of‐Entry Permit NMSLO INIS has obtained this permit for entry onto Section 26, 27, 34, or 35. Completed.

State Land Swap Arrangement NMSLO This arrangement requires that an environmental assessment and a cultural resources survey be conducted on lands offered for exchange.  .

Both surveys have been completed

Class III Cultural Survey Permit NMSHPO INIS has obtained this permit to conduct surveys on Section 26, 27, 34, or 35. Completed

NPDES – National Pollutant Discharge Elimination System; EPA – U.S. Environmental Protection Agency; 

NESHAP –National Emissions Standards for Hazardous Air Pollutants; NMDOT – New Mexico Department of Transportation; 

NMED/AQB – New Mexico Environment Department /Air Quality Bureau; NMED/HWB – New Mexico Environment Department/Hazardous Waste Bureau; 

NMED/RCB – New Mexico Environment Department/Radiological Control Bureau; 

NMED/WQB – New Mexico Environment Department/Water Quality Bureau; NMDGF – New Mexico Department of Game and Fish; 

NMSLO – New Mexico State Land Office; NMSHPO – New Mexico State Historic Preservation Office.

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Summary Page

• Fills a “Void” in the Nuclear Fuel Cycle by addressing tails

• Recycles and recovery fluorine for important products

• Plant with an emphasis upon environmental protection

• “Green” nature of this project is complimentary to New Mexico

• Robust opportunities for growth