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CH5370 Environmental Quality Monitoring and Assessment

Assignment 1- Group E

22.08.2012 CH09B049: Ramya Rathod

CH10B101: Shivani Patel

: Purvali Chaudhari

No. Chemical

Aqueous

Phase

Solubility(mg/L)

Vapour

Pressure

Henrys

Constant (H)atm-m3/mol Log Kow

Koc

(L/kg)average Exposure limit AWQC values

17

5 Benzidine 9.4 + 03mg/L 5 10-4 mm Hg 5.2 x 10-11[1.58]6 [42.9]7

6.7 10-2 (g/m3)

Through water and

contaminated

organisms- 0.000086

g/L;

Through organisms

only 0.00020 g/L

251,2-

dichlorobenzene[1.56E+02]2

.196 kPa

[1.90E-03]2 [3.43]2 [379]2

50 ppm

Through water and

contaminated

organisms- 420 g/L;

Through organisms

only 1300 g/L

44Methylene

chloride[1.30E+04]2

47.4 kPa at 20C1

[2.19E-03]2 [1.25]2 [10]2 1-day exposure to

10 mg/L or a 10-

Through water and

contaminated

organisms- 4.6 g/L;

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day exposure to 2

mg/L.]3

Through organisms

only 590 g/L

65 Phenol [8.28E+04]20.3513 mm Hg

at 25 C[3.97E-07]2 [1.48]

2 [2.88E+01]2*

Drinking Water:

4mg/L;

Surface water : 3.5mg/L

Through water and

contaminated

organisms- 10,000

g/L;Through organisms

only 860,000 g/L

84 Pyrene [1.35E-01]2

[4.50E-06 mm

Hg]14

[1.10E-05]

2[5.11]

2[6.80E+04]

2

Oral(LD50): Acute:

2700 mg/kg (rat);

800 mg/kg

(mouse)

Benzo-pyrene:

0.0002 mg/L

Through water and

contaminated

organisms- 830 g/L;

Through organisms

only 4000 g/L

103 Beta-BHC [2.40E-01]2 [3.6 E-07 mm

Hg]15

[7.43E-07]

2[3.81]

2[2.14E+03] 0.001 mg/L

Through water and

contaminated

organisms- 0.0091g/L;

Through organisms

only 0.017 g/L

121 Cyanide, Total18

Hydrogen

Cynanide :

Miscible;

Sodium

Cyanide: 48 g/

100 mL at 10C

Hydrogen

Cyanide:630 mm

Hg at 20C;

Sodium

Cyanide:0.76

mm Hg at 800C

Hydrogen

Cyanide:

5.1x10-2 atm-

m3/mol;

Sodium

Cyanide: No

data

Hydrogen

Cyanide:0.66;

Sodium

Cyanide:0.44

No data0.2 mg/L (as free

cyanide)10

Through water and

contaminated

organisms- 140 g/L;

Through organisms

only 140 g/L

*calculated value

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No. Chemical Source

5 Benzidine Dyes, pigments

25 1,2-

dichlorobenzene

Agrochemicals, fullerenes, insecticide.

44 Methylene

chloride

Medicinals, botanicals, Photographic supplies, Custom plastics, resins, Pharmaceuticals, Potato/corn chips & snacks

Air conditioning/heating, Steel pipe, tubing.3

65 Phenol Contaminated Air or Skin Exposure at workplace, use of phenol containing medical products such as mouthwashes, toothache

drops, throat lozenges, analgesic rubs, and antiseptic lotions; smoking tobacco; exposure to phenolic resins; slimicides

84 Pyrene Dyes, Plastics, Pesticides, Cigarette smoke, Tobacco, Grille and Charred Food, Smoked fish and meat, Coal Tar

Benzopyrene: Leaching from linings of water storage tanks and distribution lines9

103 Beta-BHC Discharge from Chemical Factories10

121 Cyanide, Total Discharge from steel/metal factories; discharge from plastic and fertilizer factories10

No. Chemical Chronic Health effects

5 Benzidine Bladder, Pancreatic cancer

25 1,2-

dichlorobenzene

Liver, kidney, lung and nervous system damage, Skin allergy

44 Methylene

chloride

Liver damage, cancer 3

65 Phenol Breathing phenol can cause respiratory irritation, headaches, burning eyes; Chronic effects: weakness, muscle pain, diarrhea,

anorexia, liver damage, weight loss, increase in respiratory cancer, heart disease and immunological impairment; Ingestion of or

skin contact with very high concentration of phenol has resulted in death.12

84 Pyrene Benzo-pyrene causes Reproductive difficulties; increased risk of cancer. Animal studies showed that mice exposed to pyrene

developed nephropathy, a kidney disease, along with decrease in weight of kidney, and increase in weight of liver. There were

slight changes in blood. Effects such as damage to skin, body fluids and immune system were seen i mice, but not in humans.

Toxic and Chronic Effects on humans: Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact(irritant, permeator); May affect genetic material (mutagenic). May cause cancer (tumorigenic) according to animal data.

9,14

103 Beta-BHC Kidney or stomach Problems10 , Can affect Central nervous System causing Convulsions, kidney and liver, Possibly Carcinogenic to

humans, can have toxic effects on human reproduction.16

121 Cyanide, Total Nerve damage or thyroid problems10

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Chemicals that are also present in the hazardous air pollutants list are:

Benzidine

Methylene chloride

Phenol

References:

1. http://www.inchem.org/documents/icsc/icsc/eics0058.htm

2. http://www.epa.gov/superfund/health/conmedia/soil/pdfs/part_5.pdf

3. http://www.epa.gov/ogwdw/pdfs/factsheets/voc/tech/dichloro.pdf

4. http://www.inchem.org/documents/sids/sids/95501.pdf

5. New Jersey Department of Health and Senior Services :HAZARDOUS SUBSTANCE FACT SHEET

6. http://www.epa.gov/ttn/atw/hlthef/benzidin.htm

7. http://webcache.googleusercontent.com/search?q=cache:QYrdFm4WiDEJ:www.michigan.gov/documents/deq/deq-rrd-OpMemo_1-

Attachment1Table4ChemicalPhysical_283556_7.xls+benzidine+carbon+water+partitioning+coefficient&cd=6&hl=en&ct=clnk&gl=in

8. http://www.atsdr.cdc.gov/toxprofiles/tp62-c6.pdf

9. http://www.epa.gov/osw/hazard/wastemin/minimize/factshts/pyrene.pdf

10. http://water.epa.gov/drink/contaminants/

11. http://www.sciencelab.com/msds.php?msdsId=9924760

12. http://web.epa.ohio.gov/ocapp/p2/mercury_pbt/fact99.pdf

13. http://www.epa.gov/ttn/atw/hlthef/phenol.html

14. http://www.chemicalland21.com/industrialchem/organic/PYRENE.htm

15. http://toxnet.nlm.nih.gov/cgi-bin/sis/search/r?dbs+hsdb:@term+@rn+319-85-7

16. http://www.inchem.org/documents/icsc/icsc/eics0796.htm17. http://water.epa.gov/scitech/swguidance/standards/criteria/current/index.cfm

18. Toxicological Profile for Cyanide: U.S Department of Health and Human Services, Agency for toxic substances and disease recovery.

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