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Wastewater Treatment focusing on Resource Recovery
2018.08.31
2018 Taipei International Water Environment Forum
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Wang-Kuan Chang, Ph.D.
Deputy Division DirectorDivision of Water Technology Research,Material and Chemical Research Labs
Copyright 2018 ITRI 工業技術研究院
Technology Development Programs
Government Agency/
Administration
ITRIMCL
Division of Water Technology Research
System/Service
Providers
Industries
Academics
Investigation and evaluation
Technology R&D
System design Engineering planning System start-up
Technology transfer and licensing
Technological consultation
Science/technology research collaboration
• Innovative technology research and development
• Technology verification
• Research collaboration
Technology Research and Development
• Investigation and evaluation
• System design
• Engineering planning
• System start-up
• Technology support
Technology Service
Technology Transfer
• Technology transfer and licensing
• Patent licensing
Platform for Water Technology R&D, Services, and Promotion
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Pioneer research project
Policy promotion and implementation
Copyright 2018 ITRI 工業技術研究院
•Upflow anaerobic sludge bed (UASB)•BioNET® Technology •Membrane bioreactor (MBR) and MBR system•Advanced Oxidation Processes- Fenton Family•Fluidized bed crystallization (FBC)•Electro Dialysis Reversal (EDR) -Water reclamation•Qwater
Implementation of Water Treatment Technology in Asia
China, Vietnam, Thailand, Singapore, Malaysia, Indonesia, India
Partners: • Environmental
Engineering Co.• Universities,• Research Institutes
Consultancy Service
Singapore - PUB
• Water use efficiency investigation• On-site auditing, counseling and
consultation on water saving and recycling• Training programs for government
agencies
Partners: NanyangTechnological University
•Disaster relief operation•Village water supply-Qwater
Humanitarian Operation
Philippines, Myanmar, India
Partners: Tzu Chi Foundation,Rotary International,NGOs
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Development of water technology with high efficiency, low energy consumption, and affordable cost.
Shift from Compliance with environmental legislation to water and resource reclamation
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Desalination(RO, FO, MD)Pretreatment(BioNET, UF)
Water Purification(UF, NF, Qwater, BioNET, CDI)
Sewage Treatment(MBR, BioNET)
Wastewater Treatment(UASB, Fenton, AFB, Ultrasound, BioNET, MBR, MD)
Water Treatment/Reclamation(UF, NF, EDR, CDI)
Decentralized Water Purification SystemEmergency Relief Water Supply( Qwater)
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Wastewater reuse Energy generation Valued chemical
recovery
Limited resource Sustainability
consideration Environmental
Protection
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UASB designed by ITRI in Taiwan• more than 32 factories• more than 50 reactors• more than 40,000 m3
Total UASB in Taiwan :35,000 m3
Food processing, distillery, chemical processing, pulp and paper, petrochemical industry
Overseas application :Mainland China
MalaysiaVietnam
Upflow Anaerobic Sludge Bed (UASB)
Wastewater
Biogas for power generation
Treated effluent
Remove organics
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… … …
Aeration Tank
Sedimentation Tank
Coagulation Tank
Conditioning
Dewatering
Transportation
LandfillSludge Treatment Process
Concentration
Incineration
Sludge cake
Chemical SludgeBiological SludgePrimary Sludge
Wastewater
Sludge Production and Disposal Most wastewater treatment processes consume a lot of energy and generate
large amount of sludge.
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Sludge Reduction and Biogas Production
Primary Clarifier
Aeration Secondary Clarifier
1. Sludge reduction
Ultrasound hydrolysis
Waste Sludge
Wastewater
Sludge Thickener
Sludge
2. Sludge reduction/ Biogas Production
Primary Clarifier
Aeration Secondary Clarifier
Waste Sludge
Wastewater
Digester
BiogasSludge
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Incorporation with sludge hydrolysis, Biological treatment processes produce less sludge and more biogas.
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Industrial treated effluent • Industrial process water• Cooling water
ElectrodialysisReversal(EDR)
ITRI Electrodialysis Reversal(EDR): 8 patents(Taiwan, China, Singapore), 2 pendingsTech, Transfer: Three Engineering Companies
EDR desalination of Ground water for rinsing water( 50 m3/day)
EDR desalination of RO reject for rinsing water (electronics)(300 m3/day)
Recovery of wastewater from screw manufacturing factory for rinsing water by EDR process(450 m3/day)
Recovery of wastewater from PCB manufacturing factory for cooling tower by EDR process(1200 m3/day)
Recovery of fluoride-containing wastewater from wafer factory for scrubber by EDR process (1200 m3/day)
EDR desalination of high conductivity river water for process water( 2400 m3/day)
Desalination and reuse of RO concentratestream (Food industry)(300 m3/day)
Recovery of cooling water from electronics manufacturing factory by EDR process(550 m3/day)
Desalination and reuse of wastewater from precious screw manufacturing factory by EDR process (350 m3/day)
Desalination and reuse of direct cooling water from steel rolling by EDR process (550 m3/day)
Recovery of wastewater from chemical company for cooling water by EDR process(800 m3/day)
Recovery of wastewater from zinc-plating process for rinse water by EDR process ( 700 m3/day)
Recovery of wastewater from nylon fiber manufacturing company for cooling water by EDR process ( 800 m3/day)
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EDR for Zero liquid discharge EDR can concentrate brines far in excess of RO due to a lack of osmotic pressure
barriers.
EDR can be a very effective front-end softner and back-end brine concentrator when hybridized with RO
EDR used as back-end brine concentrator to reduce energy consumption (>30%) and chemical cost
EDR
City water Pure watersystem
Wastewater Treatment RO reclamation
evaporator Crystallizer Crystals
Recovery water
IX resins regenerationWaste liquor
RO brine
Water reuse
The first case to use EDR as back-end brine concentrator in ZLD
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Valuable chemicals recovery
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Transforming ions in water into valuable chemicals
SodaWastewater
Effluent
Recycle
Distributor
Reagent
Carrier
Crystal
Carriers is in fluidized state
Applications• Fluoride-containing
wastewater treatment
• Water softening
• Heavy metal wastewater treatment
• Phosphate removal
• Ammonia/phosphate
Features• Reactor and
process control
• Influent flow distribution design
• Crystal growth control
Fluidized Bed Crystallization (FBC)
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Storagetank
FBCreactor
Solid/liquidseparation
Scrubber Wastewater Treatment
CryoliteCrystals
(Na3AlF6)
Discharge
Waste liquor: 10,000 ~100,000 mg F/L
200~1000 mg F/L
(<15 mg F/L)
Sodium solution
NaCl solution
NaOH solution
Recovery of Cryolite from Waste Fluoride liquor
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FBC recovers soluble fluoride ions in water as valuable cryolite crystals
Other advantages include reducing sludge production, saving operating cost, and reducing environmental impact
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Circular System for Water Resource
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Sewage
ValuableResourceRecovery
Industrial wastewater
Domestic users
Industries
Sewage treatment system
Wastewater treatment system
Water supply system
Rain water
River water
Groundwater Water and resource recycling system
Seawater desalination
Discharge
Sludgereuse
Water Reclamation
ZeroDischarge
• Reclamation of wastewater with acceptable water quality and low operation cost.
• Ions and Nutrient recovery from wastewater for environmental sustainability.
• Sludge generated form wastewater treatment is utilized for energy production.
Ions Recovery
Energy Recovery
Water Resource Recovery
Nutrient Recovery