8/12/2019 Warehouse Fire

1/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

10643-02 RA RunRow Warehouse

Stud

Doors Closed- 20 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Fre uenc in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for stora e

Hei ht of buildin

Width of building

Length of building

Building Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Closed- 20 m2/1800 s

Scenario Inputs

20.00Fire surface area

1,800.00

492.23

1,001.92

0.41

Relative or Absolute Coordinates?

Probability or Frequency?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? No

4.00

1 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

2/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\F 2m/sWeather:

Speed: Stability: F2.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

2.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

0.28

4.57

0.06

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.21 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

2 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

3/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

3 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

4/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

2.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

0.28

4.57

0.06

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.21 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

4 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

5/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

5 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

6/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Doors Closed- 50 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50

Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Frequency in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for storage

Height of building

Width of building

Len th of buildin

Buildin Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 RA\Stud \Manual Door closin \Warehouse\Doors Closed- 50 m2/1800 s

Scenario Inputs

50.00Fire surface area

1,800.00

492.23

1,001.92

0.40

Relative or Absolute Coordinates?

Probabilit or Fre uenc ?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? No

4.00

6 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

7/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\F 2m/sWeather:

Speed: Stability: F2.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

5.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

0.28

4.57

0.06

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.53 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

7 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

8/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

8 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

9/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

5.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

0.28

4.57

0.06

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.53 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

9 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

10/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

10 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

11/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Doors Closed- 100 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50

Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Frequency in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for storage

Height of building

Width of building

Len th of buildin

Buildin Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 RA\Stud \Manual Door closin \Warehouse\Doors Closed- 100 m2/1800 s

Scenario Inputs

100.00Fire surface area

1,800.00

492.23

1,001.92

0.09

Relative or Absolute Coordinates?

Probabilit or Fre uenc ?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? No

4.00

11 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

12/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\F 2m/sWeather:

Speed: Stability: F2.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

5.93Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

0.28

4.57

0.06

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.62 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Ventilation

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

12 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

13/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

13 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

14/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

5.93Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

0.28

4.57

0.06

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.62 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Ventilation

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

14 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

15/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

15 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

16/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Doors Closed- 300 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50

Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Frequency in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for storage

Height of building

Width of building

Len th of buildin

Buildin Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 RA\Stud \Manual Door closin \Warehouse\Doors Closed- 300 m2/1800 s

Scenario Inputs

300.00Fire surface area

1,800.00

492.23

1,001.92

0.01

Relative or Absolute Coordinates?

Probabilit or Fre uenc ?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? No

4.00

16 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

17/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\F 2m/sWeather:

Speed: Stability: F2.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

5.93Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

0.28

4.57

0.06

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.62 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Ventilation

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

17 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

18/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

18 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

19/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

5.93Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

0.28

4.57

0.06

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.62 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Ventilation

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

19 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

20/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

20 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

21/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Doors O en- 20 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50

Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Frequency in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for storage

Height of building

Width of building

Len th of buildin

Buildin Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 RA\Stud \Manual Door closin \Warehouse\Doors O en- 20 m2/1800 s

Scenario Inputs

20.00Fire surface area

1,800.00

492.23

1,001.92

0.05

Relative or Absolute Coordinates?

Probabilit or Fre uenc ?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? Yes

21 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

22/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\F 2m/sWeather:

Speed: Stability: F2.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

2.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.21 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

22 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

23/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

23 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

24/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

2.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.21 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

24 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

25/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

25 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

26/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Doors O en- 50 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50

Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Frequency in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for storage

Height of building

Width of building

Len th of buildin

Buildin Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 RA\Stud \Manual Door closin \Warehouse\Doors O en- 50 m2/1800 s

Scenario Inputs

50.00Fire surface area

1,800.00

492.23

1,001.92

0.04

Relative or Absolute Coordinates?

Probabilit or Fre uenc ?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? Yes

26 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

27/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\F 2m/sWeather:

Speed: Stability: F2.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

5.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.53 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

27 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

28/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

28 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

29/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

5.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

0.53 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

29 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

30/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

30 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

31/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Doors O en- 100 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50

Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Frequency in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for storage

Height of building

Width of building

Len th of buildin

Buildin Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 RA\Stud \Manual Door closin \Warehouse\Doors O en- 100 m2/1800 s

Scenario Inputs

100.00Fire surface area

1,800.00

492.23

1,001.92

0.01

Relative or Absolute Coordinates?

Probabilit or Fre uenc ?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? Yes

31 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

32/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\F 2m/sWeather:

Speed: Stability: F2.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

10.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

1.05 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

32 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

33/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

33 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

34/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

10.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

1.05 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

34 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

35/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

35 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

36/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Doors O en- 300 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50

Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Frequency in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for storage

Height of building

Width of building

Len th of buildin

Buildin Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 RA\Stud \Manual Door closin \Warehouse\Doors O en- 300 m2/1800 s

Scenario Inputs

300.00Fire surface area

1,800.00

492.23

1,001.92

0.00

Relative or Absolute Coordinates?

Probabilit or Fre uenc ?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? Yes

36 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

37/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\F 2m/sWeather:

Speed: Stability: F2.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

30.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

3.15 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

37 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

38/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

38 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

39/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

30.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

3.15 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

39 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

40/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

40 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

41/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Doors O en- 900 m2/1800 s

Active Mass FractionStored MassWarehouse Material Name

fractionkg

HN03 15,200.00 1.00

Morpholine 15,000.00 0.99

Diethanolamine 50,000.00 1.00

HCL 16,920.00 1.00

H3P04 18,800.00 1.00

Belite (50 % Isopropanol) 4,000.00 0.50

Sulfolane 15,000.00 0.80

Hydrazine Hydrate 10,000.00 0.55

MDEA 75,000.00 0.99

Activated MDEA 25,000.00 0.80

INEOS Activated MDEA 25,000.00 0.60

SERDET (25% Sulphuric acid) 60,000.00 0.25

NALCO-8514 40,000.00 0.25

Enriched premix solution 65,000.00 0.80

Dowtherm A Heat transfer fluid 1,000.00 0.90

Defoamer 530 500.00 1.00

Warehouse Inputs

Event Frequency

m

Is Event Frequency in Use?

Event Frequency Data

Building Dimensions and Ventilation

10.00

65.00

75.00

m

m

/AvgeYear

Surface area for storage

Height of building

Width of building

Len th of buildin

Buildin Wake Effects

m2

Yes

Yes

4,875.00

8.80000E-004

Base Case

Data

\10643-02 RA\Stud \Manual Door closin \Warehouse\Doors O en- 900 m2/1800 s

Scenario Inputs

900.00Fire surface area

1,800.00

492.23

1,001.92

0.00

Relative or Absolute Coordinates?

Probabilit or Fre uenc ?

East

North

Probability

Fire duration

m

m

m2

s

fraction

Absolute

Probability

/hrVentilation Factor

Is Ventilation Factor Infinite? Yes

41 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

42/45

8/12/2019 Warehouse Fire

43/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds

43 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

44/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

Default Weathers\D 5m/sWeather:

Speed: Stability: D5.00

Average Molecular Weight

Calculated Quantities

Warehouse Results

m/s

95.40

Mass of material in warehouse 436,420.00 kg

Scenario Results

90.00Mass burnin rate kg/s

Other Results

Velocity 0.00 m/s

3,384.99

15,476.86

0.74

322,920.00

Moles of material

Moles of oxygen for complete combustion

Fraction of material that is active

Mass of active material kg

fraction

kmol

kmol

3.09 8.83 1.83

Average composition of Warehouse material (number of atoms):

C: H: O:

0.77 0.07 0.14N: S: Cl:

0.00 0.00 0.06

0.00 0.00 0.00

0.00

Br:

Mn:

I:

F:

Sn:

P:

Zn:

Composition of combustion product (moles per mole of Warehouse material):

3.09 4.34 0.08CO2: H2O: NO2:

0.07 0.14 0.00SO2: HCl: HBr:

0.00 0.03 0.00HF: P2O5: MnO2:

ZnO: SnO2: I2:

N2:

0.00 0.00 0.00

0.35

4.57

0.39

0.26

0.35

Moles O2 required / mole completely combusted

Oxygen flowrate available to fire

fraction

fraction

fraction

Molar burn rate assuming oxygen-limited fire

Pro ortion of HCl, HF, HBr in re resentative lume

Pro ortion of NO2 in re resentative lume

Pro ortion of SO2 in re esentative lume

9.46 kg/s

kg/s

kg/s

Release rate for re resentative lume

Release rate for unburned highly-toxic material

Release rate for dioxin-generating material

Surface or Ventilation limit flag

50.00 degCRelease Temperature

Ratio ox en re uired for Cate ories 10:0 & 11:0 fraction

Ratio ox en re uired for Cate or 2:0 fraction

0.11 fractionToxic products per unit mass Category 0

fractionUnburned highly toxic per unit mass Category 01.77 fractionOther burned material per unit mass Category 0

Surface

kmol/s

kmol/s

kg/kmol

n/a

sCalculated Fire duration 1,800.00

44 45ofDate: 11/7/2012 8:50:02PMTime:

8/12/2019 Warehouse Fire

45/45

WAREHOUSE FIRE

Study Folder:

Unique Audit Number: 1,174,294

10643-02 QRA (RunRow Warehouse) Phast Risk 6.7

fractionPCDD & PCDF generated per unit mass Category 0

Note:

Category 0 are materials that form toxic combustion products

Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of less than 100 degC

Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points

of more than 100 degC

Category 2 are potential PCDD and PCDF generating compounds