Wade Chapter 1 Fall 2007
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Transcript of Wade Chapter 1 Fall 2007
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CHAPTER 1 -CHAPTER 1 -
Introduction and ReviewIntroduction and Review
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All Are InterconnectedAll Are Interconnected
ORGANIC
CHEMISTRY
BIOCHEMISTRY
BIOINORGANIC
CHEMISTRY
ORGANIMETALLIC
CHEMISTRY
MATERIALS
SCIENCE
POLYMER
CHEMISTRY
TEXTILES
MEDICINAL
CHEMISTRY
NATURAL
PRODUCTS
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Carbon can bond to itself and other Carbon can bond to itself and other elements to form long chains or ringselements to form long chains or rings
H
O
O H
O H
H
H
H
O H
H
O H
O H
C H3
H3
C
H3
C
HH
H O
C H3
C H3
H
C
O H
O
GlucoseCholesterol
Lauric Acid
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Anthracene
C C HH
Acetylene
C
C C
O H
OH
H
Oleic Acid
Carbon can form different types of Carbon can form different types of bonds – single, double, triplebonds – single, double, triple
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Shape is Everything!Shape is Everything!
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The Essence of an AtomThe Essence of an Atom
A Planetary ModelA Planetary Model
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Periodic TrendsPeriodic Trends1. Electronegativity1. Electronegativity
GeneralGeneralTrendsTrends
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Periodic TrendsPeriodic Trends1. Electronegativity1. Electronegativity
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Foundation of Classical ModelFoundation of Classical ModelAnd Valence Bond TheoryAnd Valence Bond Theory
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Periodic TrendsPeriodic Trends2. Atomic Radii2. Atomic Radii
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Periodic TrendsPeriodic Trends3. Ionization Energy3. Ionization Energy
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Periodic TrendsPeriodic Trends3. Ionization Energy3. Ionization Energy
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Blocks correspond to orbital types in which Blocks correspond to orbital types in which outermost Valence electrons are being filledoutermost Valence electrons are being filled
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Shapes of Different Types of Shapes of Different Types of OrbitalsOrbitals
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Spherical Boundary Surface Of Spherical Boundary Surface Of S-OrbitalsS-Orbitals
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Cross section of 1s-orbitalCross section of 1s-orbital
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Cross section of 2s-orbitalCross section of 2s-orbital
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Cross Section of s-OrbitalsCross Section of s-Orbitals
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Spherical Boundary Surface Of Spherical Boundary Surface Of p-Orbitalsp-Orbitals
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Spherical Boundary Surface Of Spherical Boundary Surface Of p-Orbitalsp-Orbitals
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Blocks correspond to orbital types in which Blocks correspond to orbital types in which outermost Valence electrons are being filledoutermost Valence electrons are being filled
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Summary of Formal ChargesSummary of Formal Charges
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Electrostatic Potential Map of Electrostatic Potential Map of the Carbonate Anionthe Carbonate Anion
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Acids & Bases - Acids & Bases -
An Introduction To An Introduction To
Chemical ReactionsChemical Reactions
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A Lewis Acid-Base Reaction A Lewis Acid-Base Reaction
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Acidity Increases Down Groups Acidity Increases Down Groups Of The Periodic TableOf The Periodic Table
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Acidity Increases Across Periods Acidity Increases Across Periods
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Acidity Increases Across Periods Acidity Increases Across Periods
Increases With Electronegativity of Increases With Electronegativity of Element Bearing Negative Charge Element Bearing Negative Charge
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Summary Of Periodic Trends Summary Of Periodic Trends In Relative AcidityIn Relative Acidity
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Potential Maps of EthanolPotential Maps of EthanolAnd TrifluoroethanolAnd Trifluoroethanol
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A Typical Acid Base ReactionA Typical Acid Base Reaction
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A Typical Acid Base ReactionA Typical Acid Base Reaction
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A Typical Acid Base ReactionA Typical Acid Base Reaction