Vinyl Chloride Monomer
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GROUP MEMBERS:SHOAIB AHMED PP-005
LARAIB RAFIQUE PP-038FARKHUNDA YOUNUS PP-043
MAHA TARIQ PP-046
VINYL CHLORIDE MONOMER
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Chlorinated hydrocarbons (CHCs)
More resilient to biodegradation, unlike simple hydrocarbons
Man-made CHCs are beginning to accumulate in theenvironment.
BASIC IDEA BEHIND THE PRODUCTION OF VCM
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PRODUCTION OF VCM IS ESSENTIAL TO THE PRODUCTION OF POLYVINYL
CHLORIDE Many CHCs are created during the production of PVC this is
a growing concern.
VCM needs to be produced in a way that will minimize ortotally eliminate the release of CHCs into the environment.
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First bullet point here Second bullet point here Third bullet point here
Group A Group B
Class 1 2 85
Class 2 76 88
Class 3 84 90
Two Content Layout with Table
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Direct chlorination of ethylene to form EDC. Oxychlorination of ethylene to form from
recycled HCl and oxygen. Purification of EDC. Thermal cracking of EDC to form VCM and HCl. The purification of VCM.
Process Outline
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DIRECTCHLORINATION
OXY-CHLORINATION
HYRDRO-GENATION
CATALYTICOXIDATION
VCMSTORAGE
Ethylene
HCL
H₂
LIGHTS & HEAVIES
HCLRECYCLE
EDC
EDCPROLYSIS
HEAVY ENDS(TO CATALYTICOXIDATION)
VCM DISTILLATION
EDC
LIGHTS ENDS(TO CATALYTIC OXIDATION)
Cl₂ Vent gas
O₂ Vent gas EDC
EDC DISTILLATION VCM
VCM
O₂CO₂H₂O
PROCESS FLOW
DIAGRAM
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DIRECT CHLORINATION
Ethylene
Cl₂
Ferric chloride
(catalyst)
FeCl3 + Cl2 ↔ FeCl4-Cl+FeCl4-Cl+ + CH2CH2 → FeCl3 + ClCH2CH2Cl
feed
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REACTOR EFFLUENT
(lb-mol/hr)
EDC 2682
Trichloroethane 5
HCL 0.5
Ethylene 18
Chlorine 8
Direct Chlorination Reactor Effluent Flow Rates (lb-mol/hr)
PARAMETERS VALUES
Reactor temperature 120 ⁰C
Reactor pressure 15 psig
Reactor volume 90 ft3
Tube diameter 2 inch
Tube length 115 ft
Residence time 0.018 hr
Direct Chlorination Reactor Parameters
Trichloroethane
HCL
By-products
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Ethylene
HCL
Oxygen
Cupric chloride
(catalyst)
OXYCHLORINATION REACTION
feed
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REACTORS PARAMETER VALUESReactor temperature 305 ⁰CReactor pressure 58 psigReactor volume 461 ft3Tube diameter 2 inchTube length 1320 ftResidence time 0.05 hr
Oxychlorination Reactor Parameters
Air basedoxychlorination process have been converted to the oxygen.
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Ethylene Dichloride Purification
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(ΔH = 71 kJ/mol) Pyrolysis of EDC is an endothermic reaction
EDC Cracking and Quenching
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Vinyl Chloride Purification
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APPLICATION with
PROPERTIES
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Medical application• Packaging application• Industrial & construction
Application
APPLICATION with PROPERTIES
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WHY???
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*FLAME RETARDANT pvc fire-retardant insulating tape
DUE TO THE FOLLOWING MAJOR REASONS:
flameretardant underground pipe wrapping tap
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*CHEMICAL RESISTANT: PVC Powder chemical resistance
Disposable Medical Glove PVC Chemical-Resistant Kneeboots
*DURABLE:
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*Organoleptic:
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Fire & explosive hazards
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QUESTION & ANSWER