VIACOM - SURFACE WATER, FLOW & WATER LEVEL … · 2020. 6. 13. · Viacom IIK I I Stanwix Street...

Viacom IIKI I Stanwix StreetPittsburgh, PA 15222

Dorothy M Alke(412)642-2562

VIACOMEPA Region 5 Records Ctr.

July 26, 2005259582

To: DISTRIBUTION

Re: Surface Water, Flow and Water Level MonitoringFourth Quarter 2004Neal's Landfill, Monroe County, Indiana

1.0 BACKGROUND

This report summarizes the results of surface water, flow and water level monitoring workcompleted by Viacom Inc. during the fourth quarter of 2004 at the Neal's Landfill site.

Surface water monitoring was performed at a total of two locations (springs and streams) inaccordance with the April 2002 Long Term Groundwater Monitoring Plan (LTGWMP) and theApril 2002 Groundwater Investigation Plan (GIP) for this site. Continuous monitoring of flowand water levels was also performed at five locations.

2.0 SURFACE WATER MONITORING

The monitoring work described in this report was performed on September 9, October 6 andNovember 17, 2004. The September-November time period constitutes the fourth reportingquarter for Neal's Landfill for 2004.

Scope of Work

The scope of water sampling for this monitoring period comprised monthly sampling at SouthSpring and North Spring, as stipulated in the LTGWMP and GIP and summarized in Table 1.The approximate locations of these stations are shown on Figure 1, Monitoring and SamplingLocations.

Sample Collection and Handling

Samples at the spring locations were collected by carefully filling a new disposable beaker. Thewater was transferred from the beaker into pre-cleaned amber glass 1 -liter bottles supplied by theanalytical laboratory. Routine sampling parameters including temperature and conductivity weremeasured and recorded.

July 26, 2005

Samples were analyzed by Heritage Lab of Indianapolis, Indiana. The samples were analyzed toa detection limit of 0.1 parts per billion (ppb) for all PCB parameters (except Aroclor 1221;detection limit 0.2 ppb) by EPA SW-846 method 8082. Samples were also analyzed for totalsuspended solids (TSS) by EPA method 160.2.

Quality Assurance

For quality assurance purposes a duplicate sample and a field blank were collected during eachsampling event. All environmental and blank samples were labeled and logged onto a chain-of-custody form. The samples were stored and transported on ice in insulated coolers. Custody ofthe water samples was maintained by Viacom until shipment to the analytical laboratory.

Field blank samples for these sampling events were NL4573, NL4581 and NL4809. No PCBswere detected in any of these samples.

Analytical Results for Surface Water Samples

Field parameter measurements, PCB analytical results, and QA/QC results for samples collectedfrom South Spring and North Spring during this reporting period are reported in Tables 2 and 3.Historical data for these two sampling stations are also reported in Tables 2 and 3. Historicaldata for the two Southwest Spring System sampling stations, Branam Spring and Taylor Spring,are reported in Tables 4 and 5, respectively. Each table summarizes historical groundwatermonitoring data collected since the completion of the remedy in November 1999. Copies of thechain-of-custody forms are provided in Appendix A. Copies of the certificates of analysis areprovided in Appendix B. A validation summary for these samples appears in Appendix C.Copies of the field sampling data sheets are on file at PSARA Technologies, Inc.'s BloomingtonBranch Office.

3.0 CONTINUOUS FLOW AND WATER LEVEL MONITORING

The purpose of flow and water level monitoring is to evaluate site-specific data characterizingsite hydrologic response under storm and non-storm conditions, and to evaluate correlationsbetween PCB concentrations, spring flow and groundwater elevations.

Scope of Work

The scope of groundwater level and flow monitoring during this reporting period involved theuse of dedicated instrumentation to record water level and other parameters as summarized inTable 6. Water lever transducers, water level data logging equipment, and piezometer crestgauges were operated during all or part of the period from September through November 2004.The approximate locations of these flow and water level monitoring stations are shown onFigure 1.

July 26, 2005

Flow, Water Level and Temperature Plots

The following plots for the monitored stations for this reporting period are attached:

Flow data and monthly cumulative rainfall at Conard's Branch weirWater elevation at MW EPA-5aStage at Conard's Branch at Vernal Pike, Richland Creek at Vernal Pike, and RichlandCreek at State Road 43

Quality Assurance

As a quality assurance check in documenting rain events and changes in flow, rainfall records forthis time period were obtained from the Purdue University State Climatologist's web site(shadow.agry.purdue.edu/sc.index.html) for the rain gauge station at the Monroe County Airport. Thisrecord was obtained for comparison to the downloaded transducer data at the various monitoringlocations. Raw rainfall data from the web site appears in Appendix D. Airport rain events ofapproximately 0.25 inch or more are indicated on the flow and water level plots, hi addition, theplots for the Conard's Branch weir also show cumulative rainfall data from both the airport andfrom a rain gauge at Neal's Landfill that is maintained by Viacom.

As a further data quality check, manual water level measurements were made during and aftersignificant storm events. The purpose of the manual checks was to verify instrument readings, inparticular those for installations susceptible to the accumulation of silt and/or algae growth.Manual field check data collected this reporting quarter are shown on the data plots.

A complete instrument maintenance log for all of the Neal's Landfill installations is attached.This log details the installation, re-indexing, and maintenance histories of each transducer anddata logger present at Neal's Landfill during the fourth quarter.

Two interruptions in the continuous monitoring of these stations occurred during the fourthquarter. The transducer installed in Conard's Branch at Vernal Pike was removed from thatstation from November 5 through November 23 for use at another location. Similarly, thetransducer installed in Richland Creek at Vernal Pike was removed from that station betweenNovember 12 and November 23. No data are available for those stations during those days.

The transducer installed in Richland Creek at State Road 43 began recording unusual variationsin stage in mid-October. This trend continued during the rest of the fourth quarter, as shown onthe attached stage plots. The cause of these daily fluctuations is not known, although it may bedue to progressive siltation around the transducer in the stilling well. The stilling well wascleaned out early in December 2004, which appears to temporarily eliminate the unusualvariations. The data plots attached with this report include both the raw data (showing theunusual variations) and a 24-hour moving average. The moving average gives a betterrepresentation of the stage values typically observed at this station several days after rain events,while the raw data provide a more accurate view of storm-induced peak flows.

July 26, 2005

Crest Gauges

The purpose of these gauges is to provide an indication of maximum water level in thepiezometers that do not contain transducers. Crest gauge measurements appear in Table 7. Thecrest gauges in Piezometers-02, -03, -04, and -05 showed no apparent movement during thefourth quarter of 2004. Piezometer-01 has neither transducer nor crest gage, but its water level ismeasured manually at frequent intervals, generally twice a month. Those observations appear inTable 8.

Potentiometric Data

On November 23, 2004, water levels were measured by hand at eleven monitor wells at the siteand the Conard residential well. The depth to water in the Conard residential well was 20.8 feeton this date. The other specific measurement locations are listed in the table insert on Figure 1,which also depicts the resulting potentiometric surface across the site on this date.

Scope of Non-Routine Activities

Pumping operations at the Conard's Branch Pump (CBP) station continued during the fourthreporting quarter of 2004. The system operated in full automatic mode throughout the reportingperiod. Periodic maintenance of the system during this quarter involved the cleaning ofaccumulated sediment and algae from the intake screens as needed. Operation during the firstreporting quarter for 2005 is expected to be in both continuous low flow and full automaticmodes depending on daily temperature and flow rate.

If you have questions regarding the sampling and flow/water level monitoring activities orfindings for this reporting quarter, please call Mike McCann at (812) 335-0424.

Dorothy M. AlkeProject DirectorBP:05-0048

Attachments

TABLES

Table 1. Groundwater and Surface Water Monitoring RequirementsDuring the Monitoring Period

Viacom, Inc.Neat's Landfill, Bloomington, Monroe County, Indiana

Monitoring Station

South Spring

North Spring

Conard's Branch

Spring Treatment Facility

Taylor Spring

Branam Spring

LTGWMPParameter3 Frequency

PCB, SS, C Monthly

PCB, SS, C Monthly

PCB, SS, C 2+ storms peryear in 2002

and 2003

At least 1storm in the

Spring of 2004

PCB Semimonthly

PCB, SS, C Semiannually

PCB, SS, C Semiannually

GIP Other Requirements/Frequency Comment

Qualitative or quantitativeflow estimate, if possible


4000 gpm minimum flow

4000 gpm minimum flow

NPDES sampling



"Parameters to be monitored: PCB=polychlorinated biphenyl; SS=total suspended solids; W=water level; C=conductivity;F=flow.

Table 2. Post-Remediation PCB Results

South SpringNeal's Landfill, Bloomington, Indiana

Sample ID

NL4810

NL4811*

NL4S82

NL4S83'

NL4574

NL4S75*

NL4568

NL4569*

NUS66

NL4567*

NL4524

NL4525*

NL4520

NU521"

NL4497

NL4498d

NL4353

NL4354d

NL4344

NL4345*1

NL4332

NL4333"

NL4220

NL4221d

NL4216

NL42I7"

NL42I2

NL4213*

NL4208

NL4209"

NL4204

NL4205"

NL4200

ML4201"

NLI992

NL 1993d

NLI982

NL1983d

NL19I1

NL1912"

NL1907

NL1908d

NL1903

NL1904"

Sampling

Date

11/17/04

11/17/04

10/6/04

10/6/04

9/9/04

9/9/04

8/6/04

8/6/04

7/27/04

7/27/04

6/4/04

6/4/04

5/5/04

5/5/04

4/19/04

4/19/04

3/9/04

3/9/04

2/13/04

2/13/04

1/14/04

1/14/04

12/8/03

12/8/03

1 1/5/03

1 1/5/03

10/8/03

10/8/03

9/9/03

9/9/03

8/5/03

8/5/03

7/9/03

7/9/03

6/2/03

6/2/03

5/14/03

5/14/03

4/10/03

4/10/03

3/17/03

3/17/03

2/7/03

2/7/03

PCB1,ppb

1.5

1.3

1.8

1.9

1.1

1.1

0.93

0.98

0.78

0.84

0.93

0.91

0.78

0.96

1.1

1.2

0.75

0.86

0.81

0.96

1.2

1.4

1

1.1

1.1

1.3

1.3

1.3

1.2

1.3

1.5

1.4

1.1

1.1

1.2

1.3

0.68

0.7

0.95

0.88

0.9

1.0

1.5

1.6

Data

Validated?

Y

YYY

Y

YY

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

123

17

17

<1

5

5

4

6

6

6

7

2

4

7

7

2

4

5

6

10

I I

8

12

4

3

4

2

7

6

4

5

6

3

7

8

10

8

4

5

42

35

7

6

Conductivity,

uS/cm

575

575

628

628

645

645

580

580

603

603

465

465

521

521

541

541

501

501

542

542

525

525

530

530

624

624

613

613

576

576

587

587

587

587

579

579

483

483

511

511

490

490

626

626

Temperature,

degC

12.5

12.5

12.8

12.8

13.0

130

13.0

13.0

13.0

13.0

12.4

12.4

12.0

12.0

12.2

12.2

11.7

11.7

119

1 1.9

11.9

11.9

12.2

12.2

12.6

12.6

12.8

12.8

13.0

13.0

12.7

12.7

12.6

12.6

12.2

12.2

12.1

12.1

12.0

12.0

11.8

118

11.7

11.7

Flowb,

gal/min

5050101025

25

30

30

30

30

100

100

120

120

50

50

200

200

200

200

80

80

80

80

50

50

20

20

40

40

60

60

40

40

50

50

200

200

100

100

100

too25

25

NW Springs

Total Flow0,

gpm

1001002828

45

45

67

67

62

62

243

243

170

170

155

155

385

385

441

441

290

290

255

255

62

62

37

37

89

89

158

158

78

78

104

104

525

525

246

246

426

426

102

102

continued

Table 2. Post-Remediation PCB ResultsSouth Spring

Neal's Landfill, Bloomington, Indiana

Sample ID

NL1899

NL1900d

NL1895

NLI896d

NL1885

ML 1886'

NL187I

NLI872"

ML 1867

ML 1 868*

NL1863

ML 1864"

NLI8S8

NLI8594

NL1844

NL1845"

NL177I

NLI772"

NLI764

NL 1763d

NL1757

NLI758"

NL1699

NLI700d

ML 1693

NL1694"

NLI686

NL1692d

NLI680

NL1681*

NLI630

NL163\*

NL1620

NL1621"

NL16I4

NL1615"

NL1606

NL1607"

NL1599

NLI600"

NL1534

NLI535d

NL1526

NLI527"

SamplingDate

1/10/03

1/10/03

12/3/02

12/3/02

11/12/02

11/12/02

10/10/02

10/10/02

9/4/02

9/4/02

8/8/02

8/8/02

7/17/02

7/17/02

6/1 1/02

6/1 1/02

5/21/02

5/21/02

4/1 1/02

4/1 1/02

3/14/02

3/14/02

2/13/02

2/13/02

1/22/02

1/22/02

1/3/02

1/3/02

11/15/01

11/15/01

10/19/01

10/19/01

9/14/01

9/14/01

8/16/01

8/1 6AM

7/27/01

7/27/01

6/14/01

6/14/01

5/15/01

5/15/01

4/1 1/01

4/1 1/01

PCB1,ppb

<0.2R

1.6

1.8

1.7

2.4

2.6

1.9

1.9

1.6

2

1.3

1.4

1.4

1.5

1.1

0.91

0.89

0.81

0.77

0.65

0.96

0.96

2.3 R

1.0

0.48

0.7

1.0

0.64

1.2

1.3

1.4

1.3

16

2

1.4

1.5

1.6

1.5

1.4

0.89

1.5

1.6

1.5

1.3

DataValidated?

YYYYYY

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

2

4

6

4

18

17

4

4

8

10

9

4

7

4

5

9

9

9

5

2

5

5

4

7

8

9

7

5

7

4

5

7

13

9

11

11

22

23

8

8

23

20

17

17

Conductivity,uS/cm

530

530593

593

434

434

616

616

605

605

609

609

605

605

521

521

484

484

450

450

429

429

461

461

551

551

531

531

572

572

526

526

538

538

535

535

534

534

479

479

569

569

484

484

Temperature,degC

12.112.1

11.9

11.9

12.5

12.5

13.0

13.0

13.1

13.1

13.1

13.1

12.9

12.9

12.7

12.7

12.2

12.2

12.0

12.0

12.2

12.2

12.1

12.1

12.1

12.1

12.1

12.1

12.7

12.7

12.8

12.8

13.5

13.5

13.3

133

135

13.5

12.7

12.7

12.4

12.4

12.5

12.5

Flowb,gal/min

50

50

10

10

40

40

25

25

20

20

25

25

50

50

50

50

>100

>100

40

40

60

60

100

100

20

20

15

15

25

25

80

80

20

20

10

10

30

30

NR

NR

10

10

50

50

NW Springs

Total Flow0,gpm

182

182

30

30

150

150

29

29

36

36

42

42

74

74

290

290

359

359

554

554

461

461

249

249

too100

136

136

94

94

245

245

77

77

60

60

%

96

102

102

72

72

278

278

continued

Table 2. Post-Remediation PCB ResultsSouth Spring


Sample ID

NL15I9

ML 1520*

NL1512

NL1513*

NL1397

NL1398"

NL1387

NLI388d

NL1331

NLI332"

NL1255

NL1256*

NL1210

NLI21I"

NL1113

NLI097

ML 1083

NL1084"

SamplingDate

3/21/01

3/21/01

2/27/01

2/27/01

12/21/00

12/21/00

10/19/00

10/19/00

8/15/00

8/15/00

6/13/00

6/13/00

4/14/00

4/14/00

2/22/00

12/18/99

11/1/99

11/1/99

PCB1,ppb

0.93

0.92

0.83

0.78

0.84

0.91

1.1

1.0

2.3

2.4

1.6 )

2.21

0.81

0.73

1.8

2.4

1.0

I . I

DataValidated?

YYY

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

1067

9

9

7

10

12

7

4

9

6

4

NR

8

5

5

2

Conductivity,uS/cm

526

526

453

453

485

485

504

504

658

658

560

560

467

467

460

603

347

347

Temperature,degC

12.3

12.3

11.7

11.7

11.6

11.6

12.8

12.8

13.4

13.4

12.8

12.8

12.2

12.2

11.7

12.2

13.9

13.9

Flowb,gal/min

NRNRNR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NW Springs

Total Flow0,gpm

253

253

457

457

177+NR

177+NR

537

537

51

51

42+NR

42+NR

164+NR

164+NR

113+NR

NR

NR

NR

"Samples were analyzed to a detection limit of 0 I ppb for all PCB parameters except Aroclor 1221 (detection limit 0.2 ppb or 05 ppb).Other detection limits may occasionally result from non-normal sample volumes, dilutions, etc.

*Flow estimated visually.°NL Spring Water Treatment Facility average flow rate for the day plus Conard's Branch flow at noon on the day of sampling."Duplicate sample.NR = Not reported.J = Estimated value. The QA/QC data indicated an analytical bias.R=Unusable data. QA/QC data indicated significant deficiencies in the analytical data.

Table 3. Post-Remediation PCS ResultsNorth Spring


Sample ID

NL4808

NL4580

NL4572

NL4571

NL4556

NL4522

NL4518

NL4500

NL4356

NL4347

NL4335

NL4223

NL4219

NL4215

NL4211

NL4207

NL4203

NL1995

NL1985

NL1914

NL1910

NL1906

ML 1902

NL1898

NL1888

NL1874

NLI870

ML 1866

NL1861

ML 1847

ML 1774

NL1766

NL1760

NL1702

NL1696

NL1688

Sampling

Date

11/17/04

10/6/04

9/9/04

8/6/04

7/16/04

6/4/04

5/5/04

4/19/04

3/9/04

2/13/04

1/14/04

12/8/03

1 1/5/03

10/8/03

9/9/03

8/5/03

7/9/03

6/2/03

5/14/03

4/10/03

3/17/03

2/7/03

1/10/03

12/3/02

11/12/02

10/10/02

9/4/02

8/8/02

7/17/02

6/1 1/02

5/21/02

4/1 1/02

3/14/02

2/13/02

1/22/02

1/3/02

PCB*.

ppb

0.82

1.4

0.88

0.56

0.43

0.43

0.26

0.35

0.2

0.34

0.42

0.35

0.86

1.2

0.67

0.75

0.68

0.66

0.18J

0.36

0.24

0.63

0.58

1.3

0.82

1.6

1.1

1.2

0.71

0.54

0.3

0.2

0.22

0.42

0.39

0.56

Data

Validated?

Y

YYY

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

24

<1

3

6

6

<1

<1

<1

< |

3

<1

<1

<1

<1

<1

8

5

<1

2

2

<1

<1

<1

2

3

3

8

<1

2

2

<1

8

3

4

2

Conductivity,

uS/cm

513591

600

530

465

441

420

450

400

393

438

449

570

580

524

515

532

496

392

396

388

473

453

564

441

592

564

570

543

466

410

379

357

387

472

465

Temperature,

degC

12.8

14.1

14.2

13.8

13.2

12.2

11.3

11.2

10.8

10.7

11.2

11.9

13.0

13.7

14.0

13.3

13.1

11.9

11.4

11.0

10.7

10.3

11.2

12.1

13.1

14.7

14.8

14.5

13.8

12.4

11.7

11.3

11.1

11.0

10.9

11.1

Flowb,

gal/min

35

15

15

15

20

40

40

30

100

100

50

30

10

10

10

20

15

15

70

50

40

15

20

10

15

15

10

15

50

40

60

40

80

40

15

20

continued

Table 3. Post-Remediation PCB ResultsNorth Spring


Sample ID

ML 1683

NL1633

NL1623

NL1617

NL1609

NL1601

NL1536

NL1528

NL1522

NL1514

NL1399

NL1393

NL1333

NL1259

NL1212

NL1112

NL1098

NL1085

SamplingDate

11/15/01

10/19/01

9/14/01

8/16/01

7/27/01

6/14/01

5/15/01

4/11/01

3/21/01

2/27/01

12/21/00

10/19/00

8/15/00

6/13/00

4/14/00

2/22/00

12/18/99

11/1/99

PCB',

ppb

0.78

0.57

1.1

0.79

0.89

<0.1R

1.1

0.63

0.31

0.23

0.33

0.36

1.5

1.6 J

0.29

0.68

2.1

1.2

DataValidated?

YY

YY

YY

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

<16

<1

4

7

9

15

2

<1

2

NR

5

3

3

<1

4

10

2

Conductivity,uS/cm

512463

521

504

531

432

517

398

435

377

419

473

623

521

409

491

599

400

Temperature,degC

12.7

13.1

14.3

14.8

13.7

12.7

12.5

11.2

10.8

10.9

11.4

13.0

14.7

13.0

11.4

10.5

12.1

14.1

Flowb,gal/min

1525

15

10

20

12

12

60

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR"Samples were analyzed to a detection limit of 0.1 ppb for all PCB parameters except Aroclor 1221 (detection limit 0.2 ppb

or 0.5 ppb). Other detection limits may occasionally result from non-normal sample volumes, dilutions, etc.bFlow estimated visually.NA = Not applicable.NR = Not reported.J = Estimated value. The QA/QC data indicated an analytical bias.R=Unusable data. QA/QC data indicated significant deficiencies in the analytical data.

Table 4. Post-Remediation PCB ResultsBranam Spring


Sample ID

NL4527

NL4225

NL1916

NL1890

NL1849

NL1777

ML 1770

NL1763

NL1705

NL1698

NL1690

NL1685

NL1636

NL1626

NL1619

NL1612

NL1605

NL1539

NL1532

NL1525

NL1517

NL1401

NL1396

NL1336

NL1262

NL1217

NLM10

NL1102

NL1089

SamplingDate

6/4/04

12/8/03

4/10/03

11/12/02

6/11/02

5/21/02

4/1 1/02

3/14/02

2/13/02

1/22/02

1/3/02

11/15/01

10/19/01

9/14/01

8/16/01

7/27/01

6/14/01

5/15/01

4/11/01

3/21/01

2/27/01

12/21/00

10/19/00

8/15/00

6/13/00

4/26/00

2/22/00

12/18/99

11/1/99

PCB',ppb

<0.1

<0.1<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.l

<0.1

0.15 J

<0.1

0.13 J

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

0.17 R

<0.1

<0.1

<0.1

<0.1

DataValidated?

YY

Y

Y

Y

Y

Y

YY

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

6

152

13

4

16

4

2

6

15

9

24

19

62

10

8

13

36

8

18

25

4

8

72

89

13

17

49

62

Conductivity,uS/cm

728

686762

650

656

548

NR

582

614

701

659

705

704

746

657

842

650

766

801

736

726

679

769

847

714

662

739

686

392

Temperature,degC

14.5

11.4

9.4

13.2

14.7

12.5

NR

8.6

8.1

8.0

9.4

13.5

15.8

18.4

19.2

17.7

14.9

13.5

9.8

7.8

10.1

8.9

15.3

18.6

15.6

10.7

7.3

10.2

14.7

Flowb,

gal/min

2

212

4

25

50

12

15

15

6

30

8

8

15

2

12

3

3

5

2

NR

NR

NR

NR

NR

NR

NR

NR

NR"Samples were analyzed to a detection limit of 0.1 ppb for all PCB parameters except Aroclor 1221 (detection limit 0.2 ppb

or 0.5 ppb). Other detection limits may occasionally result from non-normal sample volumes, dilutions, etc.""Flow estimated visually.NA = Not applicable.NR = Not reported.J = Estimated value. The QA/QC data indicated an analytical bias.R=Unusablc data. QA/QC data indicated significant deficiencies in the analytical data.

Table 5. Post-Remediation PCB ResultsTaylor Spring


Sample ID

NL4526

NL4224

NL1915

NL1889

NL1776

NL1769

ML 1762

NL1704

NL1691

NL1635

NL1625

NL1611

NL1604

NL1531

NL1524

NL1516

NL1400

NL1395

NL1335

NL1261

NL1215

NL1109

NL1101

NL1088

SamplingDate

6/4/04

12/8/03

4/10/03

11/12/02

5/21/02

4/1 1/02

3/14/02

2/13/02

1/3/02

10/19/01

9/14/01

7/27/01

6/14/01

4/11/01

3/21/01

2/27/01

12/21/00

10/19/00

8/15/00

6/13/00

4/14/00

2/22/00

12/18/99

11/1/99

PCB*,ppb

<0.1

<0.1

<0.1

0.2

<0.1

<0.1

<0.1

<0.1

0.1

<0.1

0.20 J

0.2

0.57 R

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

0.18 R

<0.5

0.11

<0.1

<0.1

DataValidated?

YY

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

3

311

5

11

6

2

<1

27

3

5

33

14

18

9

3

20

8

<1

34

5

5

6

<1

Conductivity,uS/cm

581630

554

454

543

536

500

500

527

598

506

580

495

485

546

599

588

659

706

629

567

615

635

556

Temperature,degC

22.1

7.8

16.9

10.8

19.3

19.0

14.0

3.9

0.3

14.0

16.3

26.0

25.1

25.2

17.2

9.4

3.5

17.0

27.8

28.2

16.4

8.8

5.8

13.3

Flowb,gal/min

1

5

1

10

15

20

15

1

1

15

1

1

1

1

3

50

NR

NR

NR

NR

NR

NR

NR

NR"Samples were analyzed to a detection limit of 0.1 ppb for ail PCB parameters except Aroclor 1221

or 0.5 ppb). Other detection limits may occasionally result from non-normal sample volumes,''Flow estimated visually.NA = Not applicable.NR = Not reported.R=Unusable data. QA/QC data indicated significant deficiencies in the analytical data.J = Estimated value. The QA/QC data indicated an analytical bias.

(detection limit 0.2 ppbdilutions, etc.

Table 6. Continuous Flow and Water Level MonitoringViacom, Inc.

Neal's Landfill, Monroe County, Indiana

Monitoring Station

Conard's Branch atVernal Pike

Conard's Branch Weir

NL Rain Gauge

MW EPA-5a

PZ-02, -03, -04, -05

Richland Creek atState Road 43

Richland Creek atVernal Pike

Parameter Reported Monitoring Period Instrument

Stage

Water level / flow

Rainfall

Water level

Water level

Stage

Stage

9/1-11/5

11/23-11/30

All Quarter

All Quarter

All Quarter

All Quarter

All Quarter

9/1- 11/12

1 1/23 - 1 1/30

Mini -Troll

Mini-Troll

EZ-Logger/tippingbucket rain gauge

Mini-Troll

Crest gauge

Mini-Troll

Mini-Troll

Table 7. Crest Gauge DataViacom, Inc.


Date

6/14/01

8/28/01

9/07/01

9/21/01

10/09/01

10/25/01

1/09/02

1/25/02

2/08/02

3/08/02

3/21/02

4/04/02

4/18/02

5/03/02

5/16/02

5/31/02

6/14/02

6/27/02

7/1 1/02

7/26/02

8/09/02

8/22/02

9/9/02

9/19/02

10/3/02

10/17/02

10/31/02

11/14/02

PZ-02

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Apparent

PZ-03

0.750

0

3.250

2.625

2.625

4.875

4.750

4.250

1.750

2.000

3.250

0.000

2.500

1.750

0.750

0.500

0.600

0.240

2.040

0.360

0.600

-'i

-'i

-'i

i

Movement (in)

PZ-04

0

Reinstalled

0

0

0

0

0

0

0

0

0

0

0

0

0

02

0

0

0

0

0

0

0

0

0

0

0

PZ-05

0

Reinstalled

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Continued



Date

12/2/02

12/13/02

12/30/02

1/13/03

1/28/03

2/1 1/03

2/20/03

3/6/03

3/19/03

4/7/03

4/23/03

5/8/03

5/19/03

6/6/03

6/19/03

7/3/03

7/17/03

8/1/03

8/15/03

8/29/03

9/1 1/03

9/29/03

10/9/03

10/23/03

1 1/5/03

1 1/20/03

12/8/03

12/31/03

PZ-02

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Apparent

PZ-03

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Movement (in)

PZ-04

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

PZ-05

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Continued



Date

1/15/04

1/29/04

2/12/04

2/26/04

3/11/04

3/25/04

4/13/04

4/22/04

5/10/04

5/25/04

6/15/04

6/25/04

7/13/04

8/3/04

8/1 1/04

8/31/04

9/10/04

9/23/04

10/7/04

10/26/04

1 1/22/04

PZ-02

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Apparent

PZ-03

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Movement (in)

PZ-04

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

PZ-05

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Crest gauge removed from piezometer; miniTroll instrument installed.2 No measurement possible due to jammed lock on piezometer.

TableS. Piezometer-01 Water ElevationsViacom, Inc.


Date

9/29/03

1 1/5/03

12/8/03

1/29/04

2/26/04

3/25/04

4/22/04

5/25/04

6/25/04

8/3/04

8/31/04

9/23/04

10/26/04

Water Elevation (ft)

772.53

772.58

772.61

772.52

772.53

772.47

772.50

772.41

772.38

772.42

772.34

772.25

772.28

Date

10/9/03

1 1/20/03

1/15/04

2/12/04

3/1 1/04

4/13/04

5/10/04

6/15/04

7/13/04

8/11/04

9/10/04

10/7/04

11/22/04

Water Elevation (ft)

772.55

772.64

772.55

772.50

772.55

772.55

772.38

772.39

772.42

772.39

772.30

772.22

772.27

FIGURES

Monitor Well Water LevelsNovember 23, 2004

Monitoring Veil

MW-5EPA-3AEPA-4AMW-10SEPA-2AMW-4EPA-5AMW-3EPA-1AAEPA-8AEPA-9A

Water LevelElevation748.87741.23733.73748.94741.99746.76739.49749.12741.82732.12730.44

Scale 1"=250'

M-23-W.d.q 9twt (Layout!)

Graphic Scale0 !360 TOO

^ •O( In FM )

TECHNOLOGIEaiNC.

LEGEND

®nw-s Monitoring Well Loeationsi

Piezometer Locations

Locations

® Residential Well Location

Contours located outside of Landfill Area arebased, on the USGS 7.5 Minute QuadrangleWhitehall, 1ND.

-745 Potentlometric surface Contour, June 21, 2004

By VIACOM. INC.

Figure 1.Monitoring and Sampling Locations

Neals LandfillBloomington, Indiana

Drawn, By:RLH

Date:S/SB/05

Scale:r-700'

FIGURES

CONTINUOUS MONITORING PLOTS

Meal's Landfill Conard's Branch Weir9/1/2004 0:00 to 9/30/2004 23:00

<:HUU -

9nnn -£.\J\J\J

ifinn -IDUU

CL

•S i9nn -~^ \f.\j\j

ou_

onnouu

4nn*tuu

0 -

1-S

-

•

•

- D

- 5

Oc

4 3H —l

ST££

0 »Rainfal

•> c

£. — —

^•11

>ep 6-Sep 11-Sep 16-Sep 21-Sep 26-Sep 1-Oct

2004

-^CBR flow A Hand Measurements Cumulative Site Rain Airport Cumulative Rain


^HUU -

!?nnn

iftnnIDUU -

Q.-~J -ionn^•^ l/UU -

Oiu.

ftnnouu

Aor\*tUU

• » *

I

P^I

: Ii

li^ 'll^ \ . ./I i

• u

. K

o4 34 cative R

ainfalC

O

0\

^- 1

n

1-Oct 6-Oct 11-Oct 16-Oct 21-Oct 26-Oct 31-Oct

2004

— — CBRflow A Hand Measurements • Airport Rain Events Cumulative Site Rain Airport Cumulative Rain


2400

2000

1-Nov 6-Nov 11-Nov 16-Nov

2004

21-Nov 26-Nov

-- 4

O

gj

0)

2 =

1-Dec

•CBR flow A Hand Measurements * Airport Rain Events ^—Cumulative Site Rain Airport Cumulative Rain

Meal's Landfill MW-EPA-5a9/1/2004 0:00 to 9/30/2004 23:00

!•*£. -

741.5 -

£ 741 -co

• mm

CO5 740.5LU

0)

g 740

739.5 -

739 -1-Sep 6-Sep 11-Sep 16-Sep 21-Sep 26-Sep 1-Oct

2004

—— Water Elevation A Hand Measurements


742

741.5

£. 741C,0'•&a5 740.5HI

£ 740

739.5

739

1-Oct 6-Oct 11-Oct 16-Oct

2004

21-Oct 26-Oct 31-Oct

Water Elevation * Airport Rain Events A Hand Measurements


742


2004

21-Nov 26-Nov 1-Dec

—Water Elevation * Airport Rain Events A Hand Measurements

Conard's Branch at Vernal Pike9/1/2004 0:00 to 9/30/2004 23:00

0.8

0.6

0.4

— 0.2

s> °«sCO .0.2

-0.4

-0.6

-0.8

-11-Sep 6-Sep 11-Sep 16-Sep

2004

21-Sep 26-Sep 1-Oct

Stage A Hand Measurements


1

0.8

0.6

0.4

0.2

&

.0.2

-0.4

-0.6

-0.8

-11-Oct 6-Oct 11-Oct 16-Oct

2004


Stage * Airport Rain Events A Hand Measurements


1 -

0 0.O

Oe.O

O A -

r\ 9 .«•-«•, \J.£.

0) o

</) n?-u.£ •

n A-U.*t

n fi-U.D

n R-u.o

•i

• « • • • • •

«^

\ IVV ^ I ~J^^-^A

A A—7

This transducer was off by 0.07' during 11/5 visit. It Transducer was installed on 1 1/23.was removed on 1 1/5 for use at another location.

-n1-Nov 6-Nov 11-Nov 16-Nov 21-Nov

2004

Stage » Airport Rain Events A Hand Measurements

26-Nov 1-Dec

Richland Creek at Vernal Pike9/1/2004 0:00 to 9/30/2004 23:00

3.8

3.6

3.4

^ 3.2

0)O)

2.8

2.6

2.4

2.2

1-Sep 6-Sep 11-Sep 16-Sep

2004

21-Sep 26-Sep 1-Oct

Stage A Hand Measurements



2004


•Stage » Airport Rain Events A Hand Measurements


4

3.8

3.6

3.4

Q> oO) 6

1CCO 2.8

Transducer was removed on 1 1/12 for useat another location.

2.6 -

2.4

2.2Transducer was reinstalled on 1 1/23.


2004

21-Nov 26-Nov 1-Dec

— Stage * Airport Rain Events A Hand Measurements

Richland Creek at State Road 439/1/2004 0:00 to 9/30/2004 23:00

3.5

0)O)

1.5

1-Sep 6-Sep 11-Sep 16-Sep

2004

21-Sep 26-Sep

•Stage A Hand Measurements ——Stage (24-hour moving average)

1-Oct



2004


•Stage • Airport Rain Events A Hand Measurements -^—Stage (24-hour moving average)



2004

21-Nov 26-Nov 1-Dec

•Stage * Airport Rain Events A Hand Measurements—"Stage (24-hour moving average)

APPENDIX A

Chain-of-Custody Records

HERITAGETO ENSURE PROPER HANDLING OF SAMPLES PLEASE COMPLETE THE SHADED AREAS OF THIS FOR,.

HERITAGE ENVIRONMENTAL SERVICES, LLC.COMMERCIAL LABORATORY OPERATIONS I - 188637901 West Morris Street Indianapolis IN 46231

www.heritage-enviro.com (800)827-4374 Fax: (317)486-5095Send Report To:Analyses Requested

(Note special detection limits or methods )

PRINT HERITAGE TSR NAME:

CUSTOMER STATUS: New / Existing

If no previous credit has been established with Heritageprepayment (check.VISA.etc) is required at the

time of sample submittal to the laboratory.

Sample ID and/or Locationwhere your sample was taken

Lab use onlySample No.

Laboratory use only

Custody seals present/intact?

Broken containers?

COC agree with sample labels?

Correct containers for testing?

Headspace issues acceptable?

Holding time(s) acceptable?

Relinquished by: (SJjJnalure )

Preservative pH's acceptable?

Distribution: White original and Yellow copies to accompany sample to the laboratory.Pink copy to be retained by the client.

Was pH left unadjusted?

HERITAGETO ENSURE PROPER HANDLING OF SA....'LES PLEASE COMPLETE THE SHADED AREAS OF THIS FORIv,

HERITAGE ENVIRONMENTAL SERVICES, LLC.COMMERCIAL LABORATORY OPERATIONS 1-188697901 West Morris Street Indianapolis IN 46231

www.heritage-enviro.com (800)827-4374 Fax: (317)486-5095Send Report To:Analyses Requested

(Note special detection limits or methods )reject Name:

PRINT HERITAGE TSR NAME:


If no previous credit has been established with Heritage,

prepayment (check.VISA.etc) is required at thetime of sample submittal to the laboratory.



Laboratory use only lYes No (CommentsCustody seals present/intact?

Broken containers?






Was pH left unadjusted?tts to accompany sample to the laboratoryPink cop/lo be retal

HERITAGETO ENSURE PROPER HANDLING OF SA>. ..ES PLEASE COMPLETE THE SHADED AREAS OF THIS FORto

HERITAGE ENVIRONMENTAL SERVICES, LLC.COMMERCIAL LABORATORY OPERATIONS7901 West Morris Street Indianapolis IN 46231

www.heritage-enviro.com (800)827-4374 Fax: (317)486-5095

1-18909

Send Report To:Analyses Requested

(Note special detection limits or methods )

Customer ria

roiect Name:

Z Quote -No: '-„• ^m

O No. or Pro

RINT HERITAGE TSR NAME:


If no previous credit has been established with Heritage,

prepayment (check,VISA,etc) is required at thetime of sample submittal to the laboratory.

,.„* *'Sk«SBk*Sampled By://.vL&k



Custody seals present/intact?Relinquished by. (Signature } Broken containers?






Was pH left unadjusted?DislrlbjMon White original and Yellow copies lo accompany sample to \he laboratory.PlnXcopy to be retained by Ihe client

APPENDIX B

Certificates of Analysis

C E R T I F I C A T E O F A N A L Y S I S

Service Location

HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received

10-SEP-04Complete

22-SEP-04Printed

22-SEP-04

Project

4602

Lab ID

A674423PO Number

BL0177Sampled

09-SEP-04 15:00

Report To

MIKE MCCANNVIACOM, INC.2002 WEST VERNAL PIKEBLOOMINGTON, IN 47404

Bill To

BETH STEIGERWALDVIACOM, INC.11 STANWIX STREETPITTSBURGH, PA 15222

Sample DescriptionCLIENT ID: NL4572MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WSSITE: NEAL'S LANDFILLSubmitter Code :2226

*!CT SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTIpN SW846-3510C ;XiiiaiyBt: B-'DItLWORTH Analîs "O«UAV'';l3i:$8P:-.04: •"•;.'. •'." twjtrwnent » PREP . TesU P230.JUO

ParameterINITIAL WEIGHT OR VOLUMEFINAL VOLUME

Result990S •• ' • ' . ' : •'-" •.:• •' ': • •'•'

Det. Limit UnitsmLm L : • ' ' . .

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD ^846-^082 NELAC:YAnalyst t .JVHESS ' .' -^lySt^bd^sîsliBB^tViî&l . :.-' ' Iii8tnjn»ent|i GC/BCD .:.'. Teat* Q301. 7.0

^rep: K» SEPARATORS FUNNEL klQUID-ilQUIB EimikpTitJS SW84iBîsipC f230 .1.0 : . :. . . : . ; .: : "

ParameterPCB AROCLOR 1016PCB AROCLOR 1221PCB AROCLOR 1232PCB AROCLOR 1242PCB AROCLOR 1248PCB AROCLOR 1254 :PCB AROCLOR 1260PCB AROCLOR 1262

SURROGATE RECOVERY

DECACHLOROBIPHENYL (DCB) i:

SUMMATION OF AROCLORS

Result

BDL

'.:''BPL .: ' . ' : ' ' ' ' . ' : ' 'BDL0.88BDL

• B D LBDLBDL

72,0

0.88

Det. Limit

0.10

0.20

0.10

o/io0.100 .100.100.10

0.20

UnitsU9/L

ug/Lug/Lug/Lug/Lug/Lug/Lug/L

% Rec

ug/LAroclor 1242 is degraded. Aroclor 1248 characteristics present.

TOTAL SUSPENDEDAnalyst: M. GROTE

SOLIDS EPA 160.2Analysis Date: 13-SEP-04 : 15:20

NELAC:YTest: G403.7.0

1 1 1

Page 1 (continued on next page)

HERITAGE ENVIRONMENTAL SERVICES, LLC Sample ID: A674423 NL4572

ParameterSUSPENDED SOLIDS

Result

BDL

Det . Limit

1

Units

mg/L

Sample Comments

BDL Below Detection Limit

Sample was received on ice at temperature 4 C.All aqueous samples are reported on a wet weight basis unless otherwise noted.Sample chain of custody number 18863.

This Certificate shall not be reproduced, except in full,without the written approval of the lab.The sample results relate only to the analytes of interest testedor to the sample as received by the lab.Heritage Environmental Services, LLC certifies that the test resultsindicated as NELAC (National Environmental Laboratory AccreditationConference) accredited (Yes for NELAC) meet all requirements of NELAC andIllinois EPA Part 186 unless otherwise explained or justified as to thethe exact nature of the deviations.Heritage Environmental Services, LLC is accredited under Illinois NELACaccreditation number 100401.

Additional copies of this report sent to:RUSS CEPKO, VIACOM, INC11 STANWIX STREET, PITTSBURG, PA 15222-1384

Approved -. ^^>Uu^cJL &o Page 2 (last page)y-—


Service Location

HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.

INDIANAPOLIS, IN 46231

(317)243-8304

Received

10-SEP-04Complete

22-SEP-04Printed

22-SEP-04

Project

4602

Lab ID

A674424PO Number

BL0177Sampled

09-SEP-04 15:15

Report To

MIKE MCCANN

VIACOM, INC.2002 WEST VERNAL PIKEBLOOMINGTON, IN 47404

Bill TO

BETH STEIGERWALD

VIACOM, INC.11 STANWIX STREETPITTSBURGH, PA 15222

Sample Description

CLIENT ID: NL4573MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WSSITE: NEAL'S LANDFILLSubmitter Code :2226

PCT SEPARATOR* FUNNEL LIQUID -LIQUID EXTRACTION sw84€- 3 siocArwlVwt! B, OIU.WORTH An«lyaiB DateV " SJ-SJSP-flU : ::

: : .! Instrument* PREP : :: . Testi P2'30.a.p

ParameterINITIAL WEIGHT OR VOLUMEFINAL VOLUME "' . • . - . ' • ' . •'• . '.-.•'• '"•''' :-'-;-::;;/:': ::::;.:::-y'::.x

Result1000

• • x "s ' . - . - . : -Xv:V. "..•-.": ' ,•'• ' •. -V^

Det . Limit UnitsmLmL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD •&&&-$

Prep: PCB SEPARATOR? FUNNEL LIQUID-LIQUID EXlT^CTi<W;Si(84(S^3

ParameterPCB AROCLOR 1016

PCB AROCLOR 1221PCB AROCLOR 1232



PCB AROCLOR 1262

SURROGATE RECOVERY

DECACHLOROBIPHENYL (DCB)


it Si ":-. :•• ;'' jnetrumerit i ' GO/BCD .••'

S10C'.*23'b.l.'A '• ' • • ' : :'":.'"-:'-:V; - ;

ResultBDL

B D L I . - : : - . - " , . • . :BDL

• B D L /.-: ' . • • ' " .BDL

-..:.BDL ' . . . . • . • . : ; : . . . : ' •. • .BDLBDL ::.;- • • •

112,0

BDL

"•-.. •'..:'• "•'... .-.Teat

Det. Limit0.10

Q-200.10

0,100.100.100.100.10

0.20

NEIACiY« 0301*7,0

Unitsug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

% Rec

ug/L

TOTAL SUSPENDED SOLIDS EPA 160,ZAnalyst: M. GROTE Analysis Date: :13-SEP-04 :15:20





Result

BDL

Det. Limit

1

Units

mg/L

Sample Comments



This Certificate shall not be reproduced, except in full,without the written approval of the laJb.The sample results relate only to the analytes of interest testedor to the sample as received by the lab.Heritage Environmental Services, LLC certifies that the test resultsindicated as NELAC (National Environmental Laboratory AccreditationConference) accredited (Yes for NELAC) meet all requirements of NELAC andIllinois EPA Part 186 unless otherwise explained or justified as to thethe exact nature of the deviations.Heritage Environmental Services, LLC is accredited under Illinois NELACaccreditation number 100401.


Approved : \ \ , J-J>j, rj OsryO Page 2 (last page)


Service Location

HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.

INDIANAPOLIS, IN 46231(317)243-8304

Received

10-SEP-04Complete

22-SEP-04Printed

22-SEP-04

Project

4602

Lab ID

A674425PO Number

BL0177Sampled

09-SEP-04 15:30

Report To

MIKE MCCANN

VIACOM, INC.

2002 WEST VERNAL PIKE

BLOOMINGTON, IN 47404

Bill To

BETH STEIGERWALD

VIACOM, INC.

11 STANWIX STREET

PITTSBURGH, PA 15222

Sample Description

CLIENT ID: NL4574

MATRIX TYPE: NON-SPECIFIC WATER

MATRIX: WS

SITE: NEAL'S LANDFILL

Submitter Code :2226

PCB SEPARATOR? FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C :Analyst: R. DILLWORTB : : • . AnalysAe Putus 13-SBP-0.4 instrument \ PREP ^ : :

; : / !..Te8ti:.P230^l.D . ;: ;

ParameterINITIAL WEIGHT OR VOLUME

FINAL VOLUME

Result

9705

Det. Limit Units

mLmL

PCB AROCLORS i BY GAS CHROMAT<>3KAPHY/ECD SW846-8082 VT NELACsYAnalyst » J. HESS . . : ' " • ' • - . ; ' : ' • • .;Jtataiyei.i-. J»sC<!:''.i3:iSBi>-w;.12j5l . ' .' Instrument r--OC/BGD ":: . < ' . . ; . • • • :': ' :..;-TeiBt«..p391>7«0 .

?rep: PCS 8BPARATORY FUfflJEL jJWW^tioiO 6kTHACTrpM isWiiS-aSlOC P23fr.l ,0 : ; : - : - .; - . . : / . : " . : . . : - . . . : : . : . :

ParameterPCB AROCLOR 1016

PCS AROCLOR 1221PCB AROCLOR 1232

PCB AROCLOR 1242PCB AROCLOR 1248PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY

DECACHLOROBIPHENYL (DCS)


Result

BDLBDL""' ' , , : ' • • • • • ' ; , . • ' • • : •BDLT,l .. ' ' ... • " ' • ' . : : / . 'BDL

• ,BDL .. . ; • - . • " •-; ," '• ' ' ...

BDLBDL

128.0

1.1

Det. Limit

0.10

0.200.10

0.100.100.100.100.10

0.20

Units

ug/Lug/Lug/L

ug/Lug/Lug/Lug/Lug/L

% Rec

uq/L

Aroclor 1242 is degraded. Aroclor 1248 characteristics present.

TOTAL SUSPENDED SOLIDS EPA 160.2Analyst: M. GROTE Analysis Date: 13-SEP-04 15:20

NELAC.-YTest: G403.7.0




Result

BDL

Det. Limit

1

Unitsmg/L

Sample Comments





Approved : \ V A P..A,C $J\P Page 2 (last page)


Service Location


Received

10-SEP-04Complete

22-SEP-04Printed

22-SEP-04

Project

4602

Lab ID

A674426PO Number

BL0177Sampled

09-SEP-04 15:30

Report To


Bill To


Sample Description

CLIENT ID: NL4575MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WSSITE: NEAL'S LANDFILLSubmitter Code :2226

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C :Analyst! B. DlIiwoRTH x; Analysis Dates I'S-SBP-OfV. Instrument) PREP •'. • /.. \:V"..TeBt* PZapa.Q

ParameterINITIAL WEIGHT OR VOLUMEFINAL VOLUME

Result9905

Det. Limit Units

mLmL

PCT AROCLORS BY GAS CTffiOMATOGRAPHY/BO> SW846-8082 ; NElAC:YAnalyst* J. HKSS Analysis 'pa^'sTi^.fsifiPrOi^ZtiSi. ': '. instrument.! :*JC/BCp: . ; . . ; . . ..-teat* O30J, 7.0 .

l*rep: *CB :SBPARATORY FUNNEL LIQUID-LIQUID - EXTRXCTiOKf ;.8HS«^ ':'&ioc'- P230.1,0 : . / V : . , :. . I :-::;:. ' : . : ' • ., '.•':

Parameter

PCB AROCLOR 1016: PCB \AROCLOR 1221 ' :! i i iPCB AROCLOR 1232PCB AROCLOR 1242PCB AROCLOR 1248PCB AROCLOR 1254 :PCB AROCLOR 1260PCB AROCLOR 1262

SURROGATE RECOVERY



Result

BDLB E L : ' - : ' : : : ' : ; • • • •BDL

' .1,1' ' . : : . • • . • - ' . :BDLBDLBDLBDL :

112.0

':! . 1 . ': . ' :

Det. Limit

0.100.200.10o.io0.100.100.100.10

0.20

Unitsug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

% Rec

uq/L

Aroclor 1242 is degraded. Aroclor 1248 characteristics present.

TOTAL SUSPENDED SOLIDS EPA 160.2Analyst: M. GROTE Analysis Date: 13-SEP-04 1S-.20





Result

5

Det. Limit

1

Units

mg/L

Sample CommentsBDL Below Detection Limit



Additional copies of this report sent to:RUSS CEPKO, VJACOM, INC11 STANtflX STREET, PITTSBURG, PA 15222-1384

Approved : ^ -u t/-./ Gi^ Page 2 (last page)'V- . v*T-

CERTIFICATE OF ANALYSISService Location


Received

07-OCT-04

Completed

18-OCT-04

Printed

18-OCT-04

Project

4602

Lab 10

A676993

PO Number

BL0177

Sampled

06-OCT-04 16:10

Report To


Bill To

BETH STEIGERWALDVIACOM, INC.11 STANWIX STREETPITTSBURGH. PA 15222

CLIENT ID. NL4580


SUBMITTER CODE: 2226

LOCATION: NEAL'S LANDFILL

BLANKET ORDER RELEASE: BL0177

Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C• • - • • • . • • ' • - v i M '

Analyst: B. DILLWORTH ^ ;•*es&"i l l...-,

instrunient jM-i")•.-' .-••;: jJgqjjgBlSBfJf

Parameter

INITIAL WEIGHT OR VOLUME

FINAL VOLUME

Result

990

5

Det. Limit Units

mL

mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8082 ;, i£- : tij ^^^ ii-, - , • -*p3&'Xv?-fSM' •'••• -1 •-- ••**'•> -**•• i-.-;-:'?5*tBSSfe^B fe k1-

Analyst E. WERNZ , . . . l -VAnalysls Date: 12-OCT-04 jl j:37,-j|nstnimei

Prep: PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACtlON^W issiOC P230.1.0 •^•^H^^^^_ • . - . •_ •;-^* i'i -;;>^>?l 5l2:.>- • . • ^" ' - .^ '- ".^-sffParameter

PCB AROCLOR 1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY



Result

BDL

BDL

BDL

1.4

BDL

BDL

BDL

BDL

72.0

1.4

Det. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

Units

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

ug/L

Aroclor pattern is degraded, Aroclor 1242 and Aroclor 1248 characteristics

Page 1 of 2

\HDUm

HERITAGE ENVIRONMENTAL SERVICES. LLC Sample ID: A676993 NL4580

present.

''S:fciis<Tr~- •':-•.:SQUDS EPA 160.2

:K2*V>t'.-. • v-- AnalysistJate: . 12:30 v T«* G403.7.0

Parameter

SUSPENDED SOLIDS

Result Det. Limit Units

mg/L

Sample Comments


Sample was received on ice at temperature 3.2 C.Sample chain of custody number 18869.

Heritage Environmental Services, LLC certifies that the test results

indicated as NELAC (National Environmental Laboratory Accreditation

Conference) accredited (Yes for NELAC) meet all requirements of NELAC and

Illinois EPA Part 186 unless otherwise explained or justified as to the

the exact nature of the deviations.

Heritage Environmental Services. LLC is accredited under Illinois NELAC

accreditation number 100401.

Additional copies of this report sent to:

RUSS CEPKO. VIACOM, INC11 STANWIX STREET, PITTSBURG. PA 15222-1384

Approved by: PAULINE SPENCE 18-OCT-04

Page 2 of 2



Received

07-OCT-04

Completed

18-OCT-04

Printed

18-OCT-04

Project Lab ID

4602 A676994

PO Number

BL0177

Sampled

06-OCT-04 16:25

Report To Bill To

MIKE MCCANN BETH STEIGERWALDVIACOM, INC. VIACOM, INC.2002 WEST VERNAL PIKE 1 1 STANWIX STREETBLOOMINGTON. IN 47404 PITTSBURGH, PA 15222

Sample DescriptionCLIENT ID: NL4581





PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTiONlSW846-3510C

^Analyst: B. DILLWORTH V Ci ' .'/ ® ^ : 0&-OCT-04 '

Parameter


FINAL VOLUME

Result

1000

5

PCBAROCLORSBYGASCHROMATOGRAPHY/ECDSW846-8082 <- '• &^ IHB^ ELAC:Y •:. . . / • - t siits/Q * -'~ * Sii$08^SiB8i&&ifi$!s£ : «''-•"

Analyst: E. WERNZ ~|ftn^^sDate 12-OCT-0411 37 Jnstrurnen^ ^ ffliHK^SB^P30^ 7 °

Prep: PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW84J6-3510C P230 1 0 "g VJ^MH^BK^ ^K'n'""

Parameter

PCB AROCLOR 1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY



Result

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

76.0

BDL

Det. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

Units

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Rec

ug/L

Page 1 of 2

HERITAGE ENVIRONMENTAL SERVICES. IXC Sample 10: A676994 NL4S81

Parameter

SUSPENDED SOLIDS

Sample Comments








Heritage Environmental Services. LLC is accredited under Illinois NELAC



RUSS CEPKO, VIACOM, INC11 STANWIX STREET. PITTSBURG. PA 15222-1384


Page 2 of 2



Received

07-OCT-04

Completed

18-OCT-04

Printed

18-OCT-04

Project Lab ID

4602 A676995

PO Number

BL0177

Sampled

06-OCT-04 16:40

Report To Bill To

MIKE MCCANN BETH STEIGERWALDVIACOM. INC. VIACOM. INC.2002 WEST VERNAL PIKE 1 1 STANWIX STREETBLOOMINGTON, IN 47404 PITTSBURGH, PA 1(5222


MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER CODE: 2226LOCATION: NEAL'S LANDFILLBLANKET ORDER RELEASE: BL01 77

1 iPCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION

. DIU.WORTH ttnstrument: PREP..

Parameter


FINAL VOLUME

Result

990

5

Del. Limit Units

mL

mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW84&|i ^ ^p^ p :A . ? ttv i4ELAC:Y

. Analyst: E. WERNZ . - '^'-'S'--'?^

•Prep: PCB SEPARATORY FUNNEL LIQUlDiKkill ECTR^ • ' ^^^^?>^ ^ -

Parameter

PCB AROCLOR 101 6

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY



Result

BDL

BDL

BDL

1.8

BDL

BDL

BDL

BDL

72.0

1.8

Det. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

Units

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

ug/L


Page 1 of 2

\BHUW}HERITAGE ENVIRONMENTAL SERVICES. LLC Sample ID: A676995 NL4582

present.

TOTAL SUSPENDED SOLIDS EPA 160.2'•-r*': '.,<•'•;• ''• ' •". ' : •.••.fc'.iHr"' -;" '

Analyst. M.GROTE

• •

Analysis Date: 08JOCT-04 12:30

Parameter

SUSPENDED SOLIDS

Result

17

Sample Comments








Heritage Environmental Services, LLC is accredited under Illinois NELAC




Approved by. PAULINE SPENCE 18-OCT-04

Page 2 of 2



Received

07-OCT-04

Completed

18-OCT-04

Printed

18-OCT-04

Project Lab 10

4602 A676996

PO Number

BL0177

Sampled

06-OCT-04 16:40

Report To BUI To

MIKE MCCANN BETH STEIGERWALDVIACOM. INC. VIACOM, INC.2002 WEST VERNAL PIKE 1 1 STANWIX STREETBLOOMINGTON, IN 47404 PITTSBURGH. PA 5222



SUBMITTER CODE. 2226



PCB SEPARATORY FUNNEL 1IQUICM.IQUID EXTRACTION

Analyst: B. WOOD •*"."'' ''4^*?3&^¥&':; -:* • :':Anarysisl. • :. • •. i&*&': *~ '>-•: >" •if-? • * • _ • • •• • •• -5

•test £230.1.6

Parameter


FINAL VOLUME

Del. Limit Units

mL

mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-80JE

..Analyst: E. WERNZ '. ,' - "-^ /S^^p^K^^ . ^na^

Prep: PCB SEPARATORY FUNNEL L^Ulb^UlbEJO^CTJONSvfe^_ K . - • . . ' -t.ir., •iK'aKmlitt'Sfr.iJS.-' •..••f:-3i*'i-»3i»

Parameter

PCB AROCLOR 1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY

DECACHLOROBIPHENYL (DCS)


Q|p||£bCT7<>4 1 1 i JresfcUn^giyiEQ^ ':. ,;,

Result

BDL

BDL

BDL

1.9

BDL

BDL

BDL

BDL

58.0

1.9

Del. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

NELAC-.Y ->

^>^v'T-;;^

Units

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Rec

ug/L


Page 1 of 2


present.

TOTAL SUSPENDED SOLIDS EPA 160.2

Analyst M. GROTE Analysis Date: 0&OCT-04 12:30

Parameter

SUSPENDED SOLIDS

Result

17

Del. Limit

Sample Comments












.


Page 2 of 2


HERITAGE ENVIRONMENTAL SERVICES. LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received

17-NOV-04

Completed

01-DEC-04

Printed

03-DEC-04

Project

4602

Lab ID

A681472

PO Number

BL0177

Sampled

17-NOV-04 13:20

Report To

MIKE MCCANNVIACOM, INC.2002 WEST VERNAL PIKEBLOOMINGTON. IN 47404

Bill To


CLIENT ID: NL4808MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER CODE: 2226MATRIX: WSLOCATION: NEAL'S LANDFILLBLANKET ORDER RELEASE: BL0177

Sample Description

• -PCBSEPARATORY FUNNEL UU

- DIU.WORTH

Parameter


FINAL VOLUME

Result

1000

5.0

Units

mL

mL

Parameter

PCB AROCLOR 1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY



Result

BDL

BDL

BDL

0.82

BDL

BDL

BDL

BDL

100.0

0.82

Del. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

Units

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Rec

ug/L

Page 1 of 2

\HBUW

HERITAGE ENVIRONMENTAL SERVICES, LLC Sample ID: A6B1472 NL4808

Aroctor 1242 has characteristics of Arodor 1248.

NDED SOLIDS EPAM60.2t-.-;-.- •. **-,'•;. - - ' . i j • • ii'ttivti aratu if •• . •<

Parameter

SUSPENDED SOLIDS

ResuK Del. Limit Units

mg/L

Sample Comments












Approved by: PAULINE SPENCE 01-DEC-04

Page 2 of 2



Received

17-NOV-04

Completed

01-DEC-04

Printed

03-DEC-04

Project

4602

Lab ID

A681473

PO Number

BL0177

Sampled

17-NOV-04 13:35

Report To

MIKE MCCANNVIACOM. INC.2002 WEST VERNAL PIKEBLOOMINGTON. IN 47404

Bill To

BETH STEIGERWALDVIACOM. INC.11 STANWIX STREETPITTSBURGH. PA 15222

CLIENT ID: NL4809MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER CODE: 2226MATRIX: WSLOCATION: NEAL'S LANDFILLBLANKET ORDER RELEASE: BL0177

Sample Description

*PCB SEPARATORY FUNNJEL LIQUID-UQUIO

: B. DILLV

Parameter


FINAL VOLUME

*•' ' . . - - . - • . , • • -.-; .»-3&b-Ki-jyss&&yH:\s'.:::rs-&i,PCB AROCLORS BY GAS CHROMAT{X3RAPJWECDBW846-eOt

I— "&•igPrep: PCB SEPARATORVFUNNEL UQUlD4jlQOE^ K;™fiteWte46i

• > * * i afigijrc&wy ^y'- Xg^MaSr' Ka

Parameter

PCBAROCLOR1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY



Result

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

100.0

BDL

3HHKI

Del. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

ifeUnits

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

ug/L

Page 1 of 2

HERITAGE ENVIRONMENTAL SERVICES. LLC Sample ID: A681473 NL.4809

Parameter

SUSPENDED SOLIDS

Units

mg/L

Sample Comments











RUSS CEPKO, VIACOM, INC11 STANWIX STREET, PITTSBURG. PA 15222-1384


Page 2 of 2



Received

17-NOV-04

Completed

01-DEC-04

Printed

03-DEC-04

Project

4602

Lab 10

A681474

PO Number

BL0177

Sampled

17-NOV-04 13:45

Report To

MIKE MCCANNVIACOM. INC.2002 WEST VERNAL PIKEBLOQMINGTON. IN 47404

Bill To

BETH STEIGERWALDVIACOM. INC.11 STANWIX STREETPITTSBURGH. PA 15222

CLIENT ID: NL4810

MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER CODE: 2226

MATRIX: WS

LOCATION: MEAL'S LANDFILL


Sample Description

fiPCB ISEPARAJPBY 'Flft'NJEL L

Parameter

INITIAL WEIGHT

FINAL VOLUME

OR VOLUME

JOU I ID'll mA^TiOr W^Jf.^-.'-i ,-ryg--. . . ' _ • • . " - . ' _ .-.-07,- •'•

-•fr^~-,r:£J£--'-;'3-^ " ^t-ff^- . >•

^ES^ iS^ . i-ii ^ *

Resutt

1000

5.0

Del. Limit Units

mL

mL

; PCB AROCLORS BY GAS CHRQK

'' r .'Htes; ^J^

Parameter

PCBAROCLOR1016

PCBAROCLOR1221

PCBAROCLOR1232

PCBAROCLOR1242

PCBAROCLOR1248

PCBAROCLOR1254

PCBAROCLOR1260

PCBAROCLOR1262

SURROGATE RECOVERY



Result

BDL

BDL

BDL

1.5

BDL

BDL

BDL

BDL

126.0

1.5

Det. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

Units

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

ug/L

Page 1 of 2

\HER1WE\••i*""


Arodor 1242 has characteristics of Arodor 1248.

rofXLSUSPE^NDEDXsbubsWA 16oiH|

Parameter

SUSPENDED SOLIDS

Units

mg/L

Sample Comments











RUSS CEPKO, VIACOM, INC11 STANWIX STREET, PITTSBURG. PA 15222-1384


Page 2 of 2



Received

17-NOV-04

Completed

01-DEC-04

Printed

03-DEC-04

Project

4602

Lab ID

A681475

PO Number

BL0177

Sampled

17-NOV-04 13:45

Report To

MIKE MCCANNVIACOM, INC.2002 WEST VERNAL PIKEBLOOMINGTON. IN 47404

Bill To

BETH STEIGERWALDVIACOM, INC.11 STANWIX STREETPITTSBURGH. PA 15222

CLIENT ID: NL4811



MATRIX: WS



Sample Description

B SEPARAtORY FUNNEL LI ID4J- -

Parameter


FINAL VOLUME

Result

1000

5.0

Det. Limit Units

mL

tnL

I/PCB AROCLORS BY GAS CHRONlATpGRAPj***•<* • ' • • • - • ~ "

.-•' i^'j^v: _- \ f !

Parameter

PCB AROCLOR 1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY



Result

BDL

BDL

BDL

1.3

BDL

BDL

BDL

BDL

110.0

1.3

Det. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

Units

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Rec

ug/L

Page 1 of 2

HERITAGE ENVIRONMEKTAL SERVICES. LLC Sample ID: A68147S NL4811

Arodor 1242 has characteristics of Arodor 1248.

JJED^QLlb^EPA 160.2 :

Parameter

SUSPENDED SOLIDS

Sample Comments











RUSS CEPKO. VIACOM, INC11 STANWIX STREET. PITTSBURG. PA 15222-1384


Page 2 of 2

APPENDIX C

Data Validation

Validation Results for the September 2004 NLF Spring Water Samples

1. Validation of the following samples has been completed:

• NL 4572- NL 4575

Validation was performed per the requirements for level 4 data in the project QAPjP. This includes acheck for; Holding Time, Calibration, Blank Contamination, Precision, Accuracy, and Accuracy ofNominal Reporting Limits against method requirements. Based on this review, no data flags arerecommended as all method requirements were met.

2. The QAPjP requires an assessment of the overall data quality with respect to Precision, Accuracy,Representativeness, Completeness and Comparability (PARCC).

o Precision and accuracy: Precision and accuracy were accessed by reviewing the labperformance on lab spiked samples, lab spike duplicates and field duplicates. Allrequirements were met.

o Representativeness: The representativeness requirement involves an assessment of thefield sampling and lab analytical techniques. The fields sampling locations, and all otherfield techniques as well as lab procedures were in accordance with the approvedsampling plan and QAPjP. Overall the representativeness requirement was met.

o Completeness: The completeness goal for the project was for all project data to be 90%accepted. Completeness is calculated by dividing the total number of acceptableanalyses by the total performed. An acceptable analysis is defined as one that conformedto QC protocols and is not rejected. All of these analyses were accepted. The projectcompleteness goal has been met to date.

o Comparability: All the samples taken, analyzed and validated by Viacom were taken byViacom or it's contractors sampling crews using the same procedures as previoussamples at this location. These samples were analyzed by Heritage Labs. Care shouldbe taken when attempting to trend Heritage sample results with other labs using slightlydifferent procedures. Overall these results should be directly comparable to otherHeritage lab results from these locations.

Overall, the main objective of the sampling event was to determine if PCBs are present at a concentrationof. 1 ppb or more. This data is of sufficient quality to satisfy this goal.

Validation Results for the October 2004 NLF Spring Water Samples


• NL 4580- NL 4583








Validation Results for the November 2004 NLF Spring Water Samples


• ML 4808-NL 4811








APPENDIX D

Monroe County Airport Rainfall Records

Official station hourly observations: 1 September 2004 to November 30 2004

Time Precip. Beginning EndingStation Date (EST.) (in.) Time Time QualifierBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMG

9/1/20049/1/20049/2/20049/2/20049/2/20049/3/20049/3/20049/3/20049/3/20049/4/20049/4/20049/5/20049/5/20049/10/20049/10/20049/15/20049/15/20049/16/20049/16/20049/17/20049/17/20049/17/20049/18/20049/21/20049/21/20049/21/20049/21/20049/21/20049/21/20049/22/20049/22/20049/23/20049/23/20049/23/20049/27/20049/27/20049/29/20049/30/20049/30/200410/1/200410/1/200410/2/200410/2/200410/2/200410/2/200410/9/200410/9/2004

253653185320532153

534535536533536534536534536538539539531053531532531537538539531053115312536531853453553653453653225315365319532253

53153753853353453

0.01

0.01

0000

0.01

0.01

0.01

000000

0.010

0.01

0.01

00

0.010.01

0000

18272018

453

922

10

213121

1842

2253

110741

320415

1845

21022357

1004

113230133

1848

127

757330430

$$

$$$$$$

$$$

$

$= Equipment may need calibration or replacement.

Time Precip. Beginning EndingStation Date (EST.) (in.) Time Time Qualifier

BMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMG

10/9/200410/9/200410/12/200410/12/200410/12/200410/12/200410/12/200410/12/200410/12/200410/12/200410/13/200410/13/200410/13/200410/13/200410/13/200410/13/200410/13/200410/13/200410/13/200410/13/200410/13/200410/13/200410/13/200410/14/200410/14/200410/14/200410/14/200410/14/200410/14/200410/14/200410/14/200410/14/200410/14/200410/14/200410/15/200410/15/200410/15/200410/15/200410/15/200410/15/200410/15/200410/15/200410/15/200410/15/200410/15/200410/16/200410/16/200410/16/200410/16/200410/16/200410/16/2004

55565375385395310531553165317532323

5315325335355365317531853195320532153225323226537531153135314531553165317531853225323431532533535536538539531153125320532153

531536537558531053

000

0.01000

0.050.01

00

0.060.02

00.01

00.01

00.020.01

00.010.02

0.010.020.03

00.01

000

0.010.060.08

00.01

00

0.01000

0.01

721

90710231551

2305

100

62317231754

2003

11351301143515121620

2244

149

336

648

9061149

2051

48

754754

8289201034

1709

249

6391739

1941

1136130214361535

1803

204

848907

1246

2127

104

755755

$$

$

$

$$= Equipment may need calibration or replacement.



10/16/200410/16/200410/16/200410/16/200410/16/200410/16/200410/16/200410/16/200410/16/200410/17/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/18/200410/19/200410/19/200410/19/200410/20/200410/20/200410/20/200410/20/200410/20/200410/21/200410/23/200410/23/200410/23/200410/23/200410/23/200410/23/200410/23/200410/23/200410/23/200410/24/200410/24/200410/26/200410/26/200410/26/2004

115312531353145315531653175318531953115343565375385395310531153125313531453155316531753185319532053215322536531953233035345365312531953653853953105311531253135314531553205335365385314531553

0.190.620.290.230.160.180.230.080.050.080.02

00.190.090.080.040.02

0.010.010.010.01

00.01

00.090.110.310.010.110.30

0.020.01

0.010

0.17

429608

1207

16001738

1205

825900

1311

2013

1433

623

1230

2238

1214

850

1243

1500

$$$$$$$$$$




10/26/200410/26/200410/26/200410/26/200410/26/200410/26/200410/26/200410/27/200410/27/200410/29/200410/29/200410/29/200410/29/200410/29/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200410/30/200411/1/200411/1/200411/1/200411/1/200411/1/200411/1/200411/1/200411/1/200411/1/200411/1/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/2004

16531753185319532053215322535536531053115312531353145315325345355365375385395310531153125313531453155316531753553653753853105311531253195320532153

531592533534535536537538539531053

0.120.050.05

00.030.02

00

0.010.01

0.020

0.010

0.020

0.010.010.01

00.040.220.01

00.020.070.040.050.240.060.070.040.050.080.02

0.02

530637

1151

1331

145

456

537

8131003

19171954

1002

2200544647

1207

1420

154

604

707825

12111936

2146

854

$$$$$$$$$$$$$$




11/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/2/200411/3/200411/3/200411/3/200411/3/200411/4/200411/4/200411/4/200411/4/200411/4/200411/4/200411/4/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/11/200411/12/200411/16/200411/16/200411/16/200411/16/200411/16/200411/16/200411/18/200411/18/200411/18/200411/18/200411/18/2004

11331253135314531553165317531853195365316531753185315325335355365395310534535536537538539531053115312531353145315531653175318531953205321532253653153253353553653753853953155316531753

0.010.1

0.080.010.01

00.01

00

00

0.0100

0.010.01

00000

0.120.260.060.020.040.050.030.040.040.040.05

00.010.010.01

0

00

0.010

000000

152816071741

1929

1645

1810135214300

950

413534

658

1917

120224

509

7318379001552

1747

141315491626

17551939

17071836146238305

1053423

617

1845

2202

153

324550

741848909

1631




11/18/200411/18/200411/18/200411/18/200411/18/200411/18/200411/19/200411/19/200411/19/200411/19/200411/19/200411/19/200411/19/200411/19/200411/19/200411/19/200411/20/200411/22/200411/22/200411/22/200411/22/200411/22/200411/22/200411/23/200411/23/200411/23/200411/23/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/24/200411/25/200411/25/200411/27/2004

18531953205321532253231653153253353453553653105320532253653553653753853953105365312532153225325335345355365375385395310531159125313531453165317531853195320532*5322532344

53653153

0.060.120.070.040.020.010.020.10.030.040.02

000

0.010

00.010.01

00.010.02

00.01

00.010.030.010.020.010.010.050.030.07

00.03

00.01

0

0.010.01

00.010.02

0000

100620132238

531601

813902

12042152

227

819

1352

1626

1820

2049

2322

625104

612101820212249

553

7478319111041

1213

2202

721

1235

1657

2052

232529

653117



BMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMGBMG

11/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/27/200411/28/200411/29/200411/29/200411/29/200411/29/200411/29/200411/29/200411/30/200411/30/200411/30/200411/30/200411/30/200411/30/200411/30/200411/30/200411/30/200411/30/2004

35345365375385395310531153125713531453155316531753185319532053215365317531853195320532153225335365310531153125313531453155316531753

0.01

00

0.010

0.030.070.010.020.090.080.090.090.040.040.01

0

0.010.030.030.010.01

00

00.120.020.030.010.030.060.03

338

652

1705

2241339

10191109

354

2104

348

1034


APPENDIX E

Transducer Maintenance Log

Meal's Landfill Q4 2004 Instrument Maintenance Log

Canard's Branch at Vernal Pike:Instrument

mini-Troll #5062

mini-Troll #5062

Date10/26/200411/3/200411/5/2004

11/23/2004

ActionRe-indexed by 0.02'Re-indexed by 0.08'. Changed batteries.Off by 0.07'. mT was removed for use at BD Wedge South.Installed

Conard's Branch Weir:Instrument

mini-Troll #4643Date

10/7/200410/26/2004

ActionNo water in weir pool today. Will recalibrate when flows resume.Re-indexed by 0.02'

CBR Rain Gauge:Instrument

EZLoggerDate Action

Appears to have operated fine during fourth quarter.

MW-5a:Instrument


10/26/200411/22/2004

ActionRe-indexed by 0.02'Re-indexed by 0.04'

Richland Creek at State Road 43:Instrument


9/2/2004

9/10/2004

9/23/200411/5/2004

11/22/2004

ActionRe-indexed by 0.05'. There was some fine sediment at the bottomof this stilling well, which we cleaned out today. This may havebeen the cause of the sporadic diurnal spiking we've seen sinceMay. We'll see if future downloads bear this out.Re-indexed by 0.03'. No diurnal spiking anymore, so maybe thatcleanout did the trick!Re-indexed by 0.05'Re-indexed by 0.17'. Cause of difference unknown, but water levelwas significantly higher than previous download.Re-indexed by 0.22'. Will investigate possible diurnal spiking.

Richland Creek at Vernal Pike:Instrument

mini-Troll #5079

mini-Troll #7785

Date9/23/200410/26/200411/3/2004

11/12/200411/23/2004

ActionRe-indexed by 0.02'Re-indexed by 0.07'Re-indexed by 0.08'. Changed batteries.Removed from station for use at BD MW-1Installed

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