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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Expectations from a new cleaning / drying technologyExpectations from a new cleaning / drying technology
Cleaning / Drying Performance Material Compatibility Safety-in-use (toxicology, flammability, stability)
Environmental Impact Durability (regulatory issues)
Cost of Ownership (long-term strategy vs. short-term thinking)
VertrelVertrel®® is a balanced combination of properties related to performance, is a balanced combination of properties related to performance,material compatibility, operator safety, environmental issues, and costs.material compatibility, operator safety, environmental issues, and costs.
B-1
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
What is VertrelWhat is Vertrel®® HFC 43-10mee? HFC 43-10mee?
Vertrel® HFC 43-10mee is a proprietary HFC (hydrofluorocarbon) fluid suited for cleaning, rinsing and drying processes
Vertrel® HFC 43-10mee is also used as a carrier, heat transfer and dielectric fluid
Tradename: Vertrel® XF
Formula: C5H2F10
1,1,1,2,3,4,4,5,5,5 decafluoropentane
B-2
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Molecule of VertrelMolecule of Vertrel®® XF vs. Freon XF vs. Freon®® CFC-113 CFC-113
F F F F F CI F
| | | | | | |
F - C - C - C - C - C - F F - C - C - CI
| | | | | | |
F H H F F CI F
HFC-43-10 CFC-113
B-3
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Purpose of VertrelPurpose of Vertrel®® HFC 43-10mee HFC 43-10mee Vertrel® is designed to replace ozone-depleting solvents
such as: CFC-113 (Freon®) HCFC-141b HCFC-225
Vertrel® is also an ideal replacement for 1.1.1-TCA, Trichlorethylene (TCE), Perchlorethylene, and Perfluorocarbons (PFCs)
Vertrel® may also replace aqueous-, alcohol-, n-Propyl Bromide- and hydrocarbon-based cleaning systems
B-4
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Key characteristics of VertrelKey characteristics of Vertrel®® HFC 43-10mee (1) HFC 43-10mee (1)
Ozone Depletion Potential (ODP) = ZERO Very low Global Warming Potential (GWP) Non-flammable, no flashpoint, no auto-ignition Excellent toxicity profile Higher boiling point and lower surface tension than CFC-
113 Low viscosity High liquid density Very low water solubility
B-5
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Key characteristics of VertrelKey characteristics of Vertrel®® HFC 43-10mee (2) HFC 43-10mee (2)
Excellent thermal, chemical and hydrolytic stability High material compatibility Excellent dielectric properties Easily miscible with numerous common solvents Recyclability of azeotropic mixtures Low energy consuming process, thus cost efficiency Can be used in combination with low volatility solvating
agents (such as Hydrocarbons)
B-6
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Comparison of VertrelComparison of Vertrel®® with CFC-113 and HCFC-141b with CFC-113 and HCFC-141b
Physical and Chemical PropertiesPhysical and Chemical Properties
Property / Unit HFC 43-10mee CFC-113 HCFC-141b
Boiling Point (BP) °C 55 48 32Freezing Point °C -80 -35 -103Liq. density at 25°C kg/l 1.58 1.56 1.24Vapor pressure hPa 301 445 864Surface tension dyne/cm 14.1 17.3 18.4Dyn. Visc. at 25°C CP 0.67 0.68 0.44Specific heat 25°C KJ/kgK 1.13 0.912 1.16Heat of vap. at BP KJ/kg 130 147 207Kauri Butanol (KB) 9 31 51Purity (min.) % 99.9 99.5NVR max. ppm 2H2O ppm <50
B-7
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Comparison of VertrelComparison of Vertrel®® with CFC-113 and HCFC-141b with CFC-113 and HCFC-141b
Safety and Toxicity related PropertiesSafety and Toxicity related Properties
Property / Unit HFC 43-10mee CFC-113 HCFC-141b
Flash Point none none noneFlammable range % none none 5.6 – 17.7Auto-ignition temperature °C none none 532
AEL 8-hr weighted average ppm 200 1000 500Ceiling ppm 400
B-8
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Comparison of VertrelComparison of Vertrel®® with CFC-113 and HCFC-141b with CFC-113 and HCFC-141b
Environmental PropertiesEnvironmental Properties
Property / Unit HFC 43-10mee CFC-113 HCFC-141b
Atmospheric lifetime yr 17 85 9Ozone depletion potential 0.0 0.8 0.11Hal. Global warming potential
(vs. CFC-11 =1 ) 0.25 1.35 0.14Global warming potential
100 years IHT 1300 6000 700Solubility in water ppm 140 170 2700Solubility of water ppm 490 90 320
B-9
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Comparison of VertrelComparison of Vertrel®® with CFC-113 and PFC (C with CFC-113 and PFC (C66FF1414))
Dielectric Properties (at 23ºC, 1 atm)Dielectric Properties (at 23ºC, 1 atm)Property / Unit HFC 43-10mee CFC-113 C6F14
Breakdown Voltage, liquid 23.0 35.0 38.0KV-RMS (ASTM D-2477)disc electrodes, 0.1 inch gap
Dielectric constant (ASTM D-924) 1 KHz 7.00 2.41 1.76
Dissipation factor (ASTM D-924) 1 KHz 1.54 E-02 n.a. <3E-04
Conductivity (DC), (ASTM 1169) Siemens 1.19 E-11 8.33 E-11 1.0 E-15
current measured amp 2.27E-06
B-10
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Benefits of HFC 43-10 vs. CFC-113 and/or HCFC-141bBenefits of HFC 43-10 vs. CFC-113 and/or HCFC-141b
Higher BP and liquid density Reduced solvent losses due to easier containment in vapor
degreasers
Lower surface tension and viscosity Easier penetration in tight spaces (blind holes) on complex parts No solvent trapping when part is lifted into the saturated vapor
zone Easier draining from the parts
Lower heat of vaporization Reduced drying time and reduced drag out losses Reduced energy consumption to boil up the solvent
B-11
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Vertrel® Specialty FluidsVertrel® Specialty Fluids
Material Compatibility Table (non exhaustive overview)Material Compatibility Table (non exhaustive overview)
VertrelVertrel®® is highly compatible with essentially all metals, and is highly compatible with essentially all metals, and
most plastics and elastomersmost plastics and elastomersPlastics
Polyethylenes Polyacetals
Polypropylenes ABS
Polystyrenes Epoxy
Polyesters PET & PBT Ionomers
Polyphenylene Oxides Polyamides
Polyimides Polyarylates
Polycarbonates PVC, CPVC
Polyetherketones PVDF
ElastomersNatural Rubbers Nitrile Rubbers
Butyl Rubbers Neoprene®
EPDM (Nordel®) Chloro-sulfonated PE
SBR Polysulfides
Silicones Polyesters
B-12
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