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nn

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NNNHN

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CO2CH2CH3

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OR

R = C6H5 (1a), 4-CH3C6H4 (1b), 4-CH3OC6H4 (1c), 4-ClC6H4 (1d), 4-BrC6H4 (1e),2-CH3C6H4 (1f), 3-CH3C6H4 (1g), 3-CH3OC6H4 (1h), 2-ClC6H4 (1i), 3-ClC6H4 (1j),2,4-Cl2C6H3 (1k), 2-CH3-3-ClC6H3 (1l), 2,6-(CH3)2C6H3 (1m)

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COOK NH3SO3K NH3 S

O

O NHCOOK5

SO

O NH 5

HN

O

COOK5OAc

OAc

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