Use and Handling of Forane® FBA 1233zd HFO Blowing Agent

Nov. 7, 2018

Paul LavalleeGlobal Market Manager, Foam Arkema Inc.King of Prussia, USA

Use and Handling of Forane® FBA 1233zd

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Topics

1. Introduction to Forane® FBA 1233zd’s Capabilities

2. Packaging and Handling

3. Material Compatibility

4. Charging 1233zd

• Blending into a Polyol

5. Foam Formulation and Forane® FBA 1233zd

CAS# 102687-65-0

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FORANE® FBA 1233ZD CAPABILITIES

Forane® FBA 1233zd, an HFO

Trans-1-chloro-3,3,3-trifluoropropene

Low GWP, Zero ODP,

Non-Flammable Liquid

Better blowing efficiency

Improved foam properties

Excellent initial & long term insulation values

Low GWP

Flo

w

Lower densities

Liquid

Insulation

No

n-f

lam

mab

leFire properties

Effi

cie

nt

Forane® FBA 1233zd is commercially available in

South & Central America.

Inventory here in Brazil

As a low GWP solution, may be eligible for UN Environmental Grants

Packaging and Handling

PACKAGING OPTIONS

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• Sample Bottle

• Disposable Bottle/Cylinder

• Horizontal One-Ton Cylinder

• Iso Tank

NOTE: More package sizes may be added.

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Packaging and Handling

HANDLING: AN OVERVIEW

Forane® FBA 1233zd is

✓ Non-toxic.

✓ Non-flammable.

✓ Easily handled as a liquid.

✓ Compatible with a wide variety of materials.

✓ Little to no capital investment required to convert.

✓ Often can be used in existing blowing agent tanks. ✓ Contact your Arkema representative to evaluate storage in your existing tanks.

✓ Can be used with R141b and cyclopentane equipment with limited modifications

• Review Safety Data Sheet (SDS) to become familiar with properties.

• Protect cylinder and fittings from puncturing and denting.

• Close cylinder valves when not in use.

• Secure cylinders to prevent rolling.

• Blocks, cradles can be used.

• Especially important when moving cylinders with fork trucks.

• Forane® FBA 1233zd is a liquid with a boiling temperature of 19ºC.

• Store Forane® FBA 1233zd in a cool, well-ventilated area, away from direct sunlight.

• Store on elevated or concrete floors to avoid cylinder corrosion.

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Packaging and Handling

SAFE HANDLING OF CYLINDERS

Wood Cradle

Steel Cradle

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Packaging and Handling

UNDERSTAND TEMPERATURE, PRESSURE, & DENSITY

Plastics Elastomer, Gasketing Metal

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MATERIAL COMPATIBILITY✓ = Recommended per

Arkema Standard Test Method*

* Plastic, Elastomer Samples: Samples were introduced into a test tube filled with Forane® FBA 1233zd blowing agent. The tube was sealed and placed in a water bath kept at a temperature above the boiling point of Forane® FBA 1233zd blowing agent for 5 minutes, 24 hours, or 100 hours. At the end of each time period, the sample was removed and measured for dimensions and weight. The sample was then subjected to a tensile test.* Metal Samples were tested according to ASTM G31-72.

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Charging Forane® FBA1233zd

OVERVIEW

• Forane® FBA 1233zd boils at around 19oC (66oF), so care should be taken to limit evaporation during blending.

• Use of closed system or cooled system is recommended.

• 1233zd is soluable in polyol, typically up to 30 wt.% or more. Details on next pages

• Blending options for Forane® FBA 1233zd are similar to current blowing agents and include:

• Polyol-side or Isocyanate-side

• Metered addition

• In-line Blending

Selected examples showed on next pages

Charging Forane® FBA1233zd

BLEND INTO POLYOLS

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• Forane® FBA 1233zd has good solubility with polyols.

• Forane® FBA 1233zd can be pre-blended into polyol, typically up to 30 wt. %

or more.

▪ Data on specific polyol solubility is available in the Forane® FBA 1233zd Technical

Profile brochure.

Charging Forane® FBA 1233zd

VAPOR PRESSURE OF BLENDED POLYOL/1233zd

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Design the system to handle vapor pressure of combined Polyol/1233zd mix

Additional data available upon request.

Charging Forane® FBA 1233zd

PRE-BLEND INTO POLYOL FROM HORIZONTAL CYL.

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Charging Forane® FBA 1233zd

BLEND INTO POLYOL TANK WITH DIP TUBE

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Cradle options to hold horizontal cylinders at/close to level

Charging Forane® FBA 1233zd

BLEND INTO POLYOL TANK WITH STATIC MIXER

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Cradle options to hold horizontal cylinders at/close to level

Charging Forane® FBA 1233zd

BLEND INTO POLYOL TANK WITH METERING UNIT

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Cradle options to hold horizontal cylinders at/close to level

Charging Forane® FBA 1233zd

Factory-produced Foam: IN-LINE BLENDING AT MIX HEAD

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Foam Formulation

OVERVIEW

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With suitable selection of components, Forane® FBA 1233zd formulations can provide improved thermal performance, lower environmental impact, and long shelf-stability.

Additive suppliers are continually developing additional products suited for HFO use, so additional options may be available.

Extending Shelf-life of 1233zd FormulationsShelf-life is typically not a concern for factory-produced foam. However, for applications where extended shelf-life is required, the Arkema Technical Service Team is happy to assist you.

Selection of key components to extend shelf-life include:1. Catalysts2. Surfactants3. Polyol Selection

➔ To summarize, with proper selection of commercially-available components, extended

shelf-life can be easily attained.

Foam Formulation

CATALYSTS SELECTION

• Catalysts can be selected to improve shelf-life while maintaining the required

reactivity.

• Catalysts manufacturers provide guidance on their solutions for HFO-based

formulations.

▪ Several new catalysts have been developed specifically for HFO’s by additive suppliers.

• Arkema has evaluated many different catalysts for several foam applications,

including spray, pour-in-place, and appliance.

▪ Achieved success achieved in extending the shelf-life across all applications.

▪ Details available from Arkema Technical Service.

▪ Publicly-available technical papers on this topic:

• Costa, J., B. Chen, L. Abbas, S. Seshadri, “Improved Shelf Stability of Rigid Polyurethane Premixes Using AFA-L1, a low GWP Blowing Agent”, Proceedings of Polyurethanes Conference 2012.

• Costa, J., B. Chen, L. Abbas, S. Seshadri, “Forane® 1233zd – Continued Improvement in Resin Shelf Stability with this Low GWP Liquid, Non-flammable Blowing Agent”, Proceedings of Polyurethanes Conference 2014.

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In some instances, formulating with Forane® FBA 1233zd

and historical catalysts led to reduced shelf life of the

polyol blend.

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Control< 1 month

Foam Formulation

POLYOL SELECTION FOR SHELF LIFE IMPROVEMENTS (1 of 3)

10

60

18 2

7

56

NO A GING GT% 7D GT% 14D

GEL

TIM

E [G

T], S

ECS

Control Comm. Cat.

Foam Formulation

POLYOL SELECTION FOR SHELF LIFE IMPROVEMENTS (2 of 3)

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*accelerated aging at 50 C

Control< 1 month

New Commercial Catalyst3 months

New Commercial Catalyst3 months

Significantly less reactivity loss

10

16

25

18 2

3 28

15 15 17

NO A GING 7 D A YS 14 D A YSGEL

TIM

E [G

T], S

ECS

Control Comm. Cat. With Arkema tool

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New Commercial Catalyst3 months

*accelerated aging at 50 C

Control< 1 month

No significant change in reactivity

Arkema Polyol Screening Tools5-6 months

Foam Formulation

POLYOL SELECTION FOR SHELF LIFE IMPROVEMENTS* (3 of 3)

Arkema’s Technical Services would be happy to setup a meeting to discuss this Polyol Screening tool with interested customers.

Foam Formulation

TYPICAL BLOWING AGENT LEVELS

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Forane® FBA1233zd

HFC-245fa HFC-365mfc Pentane

Appliance (domestic)

25 wt % of polyol side

(wt. % of resin side)

25.7 28.4 13.4

Spray Foam (wall)

11.5 wt. % 11.8 13.1 N/A

Pour-in-Place(e.g. water heaters,discontinuous panels, doors)

14.5 wt.% 14.9 16.5 7.8

Boardstock(PIR)

27 wt% N/A N/A 15

Extruded poly-styrene (XPS)

8-10% of overall foam

N/A N/A N/A

FURTHER INFORMATION & ASSISTANCE

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www.forane.com / www.arkema.cominfo.forane@arkema.com

Arkema Química LtdaAv. Ibirapuera, 2033, 4 andar, bairro MoemaCEP 04029-901 São Paulo - SP - BrasilTel.: +55 11 2148 85 70

Arkema Inc.900 First AvenueKing of Prussia, PA 19406 USATel.: (+1) 610-205-7000

Arkema France420, rue d’Estienne d’Orves92705 Colombes Cedex – FranceTel.: +33 (0)1 49 00 80 80

Hypalon® is a registered trademark of DuPont Performance Elastomers LLCZytel® & Viton® are registered trademarks of E.I. DuPont Nemours and Co.

REFERENCE SLIDES

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• Sits horizontally. Use only on wooden blocking that is shipped with the tank, or specially designed cradles.

• Approx. Gross weight: 1400-1535 kg / Net weight: 900 kg

• Volume: 760 liters

• Length: 2082.8 mm / Diameter: 762 mm

• Has two valves: one liquid & one vapor, dependent on tank orientation during use.

• Liquid valve should be on the lower end, with a slight slope to allow a complete unloading.

• Always ensure cylinder is safely braced.

Packaging and Handling

HORIZONTAL ONE-TON TANK

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Valve Outlet Connections Bracing Options

Liquid Valve (Bottom Valve)

Vapor Valve (Top Valve)

Charging Forane® FBA 1233zd

VAPOR PRESSURE OF BLENDED POLYOL/1233zd

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Design the system to handle vapor pressure of combined Polyol/1233zd mix