US EPA - REVIEW OF DATA (ICP METALS, TCLP ICP ...tenfold dilution used to digest the extracts. / QC...

Date:

Subject:

From:

To:

255921

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION 5 CENTRAL REGIONAL LABORATORY

536 SOUTH CLARK STREET

CHICAGO, ILLINOIS 60605

November 26, 2002

Review of Region 5 Data for Hegeler Zinc

R. Dilg, Chemist, IITRI/ESATContractor to Region 5 Central Regional LaboratorySubmitted to CRL on:

Attached are the results for: Hegeler Zinc

CRL data set number: E2J2801

Samples analyzed for: 18 for ICP Metals in soils and 7 for TCLP ICP metals

Results are reported for sample designations: E2J2801-01 to -22

DEC/ 0 9 /2002Dat^/Management Coordinator and Date Received

V

Date Transmitted: iff 0 9/ 2°°2

Please have the U.S. EPA Project Manager/Officer call the CRL Sample Coordinator at 3-7444for any comments or questions.

Please sign and date this form below and return it with any comments to:

Sylvia GriffinData Management CoordinatorRegion 5 Central Regional LaboratoryML- IOC

Received by and Date

Comments:

Rev. 4/10/02

Method Number: CRL METALS 003, 004, 025, & 1 311 Site Name: Hegeler ZincDate Generated: November 25, 2002 Task Order Number: 05-0-02Author: R.Dilg, IITRI-ESAT TDF Number: 5-02-079

Job No.: 102-052 -001Batch ID No.: E2J2801Parameter: ICP - total metals in soil &

ICP - TCLP metals analysis

ICP NARRATIVE PART 1

This part of the narrative covers the analysis of 18 soil samples from the named site sampled for ICPanalysis of total metals in soil.

For a listing of sample ID's, laboratory ID's, and sampling dates refer to the initial RLIMS reportpages where such a listing can be found.

The soil samples were received in good condition. The soils were dried at 105 °C overnight. The drysoils were ground using a laboratory ball mixer / grinder. Routine CRL hot block digestion procedures

WCRL SOP Metals 004 and Metals 025) were used to prepare the soil samples for GFAA and ICP^knalysis. The digested soil samples ( RLIMS Batch EK20404 ) were analyzed using the Optima

3300 DV ICP unit using analysis run method 'Sed 11132001 ESAT for the total metals analysis. Thesame digests were used for GFAA analyses, the results of which are reported separately.

ICP RUN RESULTS

Analyte mdl's determined during late summer of 2001 and rl values calculated from that informationfor ESAT analysis work for the Optima 3300 DV were used. The calculated rl values were used inreporting sample analysis results for this data case.

Because many samples contained high levels of zinc, a second analysis run was conducted wherediluted samples were run to determine and report Zn. All Zn sample results were reported from thisrun.

^malvsis RUN E2J2801 - Optima 3300 DV

The following lists the case pertinent out-of-control QC audit check results based on default QA / QC(traditional) limits:

RUNE2J2801:

Blanks: (Blank values are truncated rather than rounded)RUN 1:

Instrblkl: AI308 24.4 ug/LCa315 10.2Fe273 31.8Mn257 - 0.76 "

Digest blank: Mn257 -1.38 "(EK20404-BLK1)

GOOOOJ

ima 3300 DV (continued)(I-

RUN 2:

Instr blk2:

Instr blk3:

Instr bM:

Digest blank:(EK20404-BLK1)

Instr blk2:

Instr blk3:

AI308Cu324Fe273Mn257

Cu324Mn257V310

Zn213

Zn213

Zn213

Zn213

12.56.5

15.0- 1.3

- 5.3- 1.8-13.7

- 4.7

- 4.2

51.1

41.9

M9/Lti

ti

n

tf

»

ti

M9/L

n

M

M

Matrix spite audits:

E2J2801-01:

(EK20404-MS1)

RUN 2

(EK20404-MS3)

RUN 2

CdCuPbZn

Ba

Zn

*f

**62.4%

f

R

Qaudit not valid ; sample concentration greater than twice the spike concentration

RL check Soln: RL1:

RL2:(See paragraph below regarding rfs)

Presently no "contror actions are being implemented with the observed RL anatyte values actuallydetermined during the analysis run. RL check solution values currently are being analyzed forpurposes of generating a benchmark set of values which can be used to monitor the appropriatenessof any given RL level of analyte concentration.

Sample anaMe qualifications:

To date, compilation of control chart information is still on-going for some of the check audits fromOptima analysis runs for soils. Too little reliable data is currently available for some QA audits. Untilsuch time when compilation and evaluation of QA data is more complete, the default limits will beused.

Sample results for As, Sb, Se, and Tl were not reported by ICP; see GFAA results for these analyte

OOOOJ.O

Analysis RUN E2J2801 - Optima 3300 DV (continued) '

For Ba, all sample results are useable. The first Ba matrix spike audit concentration was at acomparable level as the samples and met QA audit control limits. This audit then is therefore anappropriate measure of matrix effects. Since the second Ba matrix spike audit concentration was at ahigher level than that for the samples it is a less appropriate measure of matrix effects on Ba, its lowrecovery should not significantly affect the Ba values for this data set.

For Fe, the ICP analyst contends that all Fe results are usable. The originally compiled control limitsfor the SRM were used rather than the later compilation which was used by the LIMS. The Fe SRMvalue met the original limits.

For Ag, the result for E2J2801-18 was flagged "L" and is estimated due to low bias indicated by theraw result being more negative than the negative value of the reporting limit for Ag. The Ag result forE2J2801-19 was flagged "J " since it had a result between the MDL and the rl value and is estimatedbecause of this.

Other comments

-afield QC samples included two pairs of field duplicates being designated: E2J2801-05 and -06, and%||2J2801-15 and -16. For the first pair Mn results did not exhibit good correlation. For the second

pair, results for Ba, Ca, Cu, Fe, Mg, Mn, Pb, and Zn did not exhibit good correlation.

R5CRL Files

The following pathways were used for storing analysis information to the R5CRL file server for thethis data set: Optima 3300 DV results:

(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV \Methods_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV \narrative(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV \Results_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV \SIFs_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV\SS processed data

* ICP NARRATIVE PART 2

This second part of the narrative covers the analysis of 7 soil sample TCLP extracts from the namedsite sampled for ICP analysis of selected analytes.

For a listing of sample ID's, laboratory ID's, and sampling dates refer to the initial RLIMS reportpages where such a listing can be found.

The samples were extracted using TCLP Method 1311 on 10-30-2002. An extraction blank wasincluded. Extraction fluid #1 was used for all seven samples and the blank. The extracts werepreserved for metals analysis by using nitric acid and lowering the pH to less than 2. The preservedextracts were prepared for ICP analysis on 11-4-2002 by using routine CRL hot block (water)digestion procedures. A tenfold dilution of the preserved extract solution was digested for theanalysis of each extract sample. The digested samples ( Prep batch EK20403 ) were analyzed on11-15-2002 using the Optima 3300 DV ICP unit using analysis run method water_080300_m_ESAT.Analyte holding times were met.

000011

ICP RUN RESULTS

Analyte mdl's determined during late summer of 2001 and rl values calculated from that informationfor ESAT analysis work for the Optima 3300 DV were used. The calculated rl values were used inreporting sample analysis results for this data case.

3300 DV

The digested TCLP extracts (Prep Batch EK20403) were analyzed along with other sets of TCLPextracts. Copies of the raw analysis run printouts are included with this deliverable. A number of rawprintout pages did not print out well due to the printer ink supply running out during the middle of theanalysis run. Using the "Reprocessing" feature of the WinLab software the affected data were laterreprinted and are included with TCLP run pages of this deliverable at the end of the raw run dataprintouts.

Routine ESAT ICP reporting limits for the anatytes were used for reporting the extract analyte valuesfound rather than site specific action tevefe-as-limrts The extract analyte values reported reflect thetenfold dilution used to digest the extracts.

/ QC summary reports are the traditional set based on "default" QA/ QC limits. <

The following lists the case pertinent out-of-control QC audit check results based on default QA / QC(traditional) limits:

RUN E2J2201 :

Blanks: (Blank values are truncated ralher than rounded)

Extract blank: Ba455(EK20403-BLK2) Cd226

Cr267

2.10.8 "0.35 "

AQC's: LCMVs: LCM1(1):

LCM1(2):

LCM1(3):

LCM1(4):

Ag328

Ag328

Ag328

Ag328

* upper concentration level exceeded ; LCM2 check audits used for control purposes

Matrix spike: E2J2801 -09: Se 116%R(EK20403-MS1)

Analysis RUN E2J2201 - Optima 3300 DV (continued!

RL check Soln: RL 1:(See paragraph below regarding rl's)

RL2:

Presently no "control" actions are being implemented with the observed RL analyte values actuallydetermined during the analysis run. RL check solution values currently are being analyzed forpurposes of generating a benchmark set of values which can be used to monitor the appropriatenessof any given RL level of analyte concentration.

Sample analvte qualifications:

QA / QC summary reports are the traditional set based on "default" QA/ QC limits.

For As, the sample result for E2J2801-13 is flagged "J" since it had a result between the MDL andthe rl value and is estimated because of this.

Pb, the sample result for E2J2801-11 is flagged "J" since it had a result between the MDL andrl value and is estimated because of this.

For Se, the sample result for E2J2801-04 is flagged "J" since it had a result between the MDL andthe rl value and is estimated because of this. It is also flagged "K" due to possible high bias asindicated from the matrix spike audit result.

Other comments

Copies of laboratory notebook entries for the Method 1311 extraction information are included withthis deliverable.

R5CRL Files

he following pathways were used for storing analysis information to the R5CRL file server for theis data set: Optima 3300 DV results:

(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \Methods_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \narrative(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \Results_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \SIFs_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \SS processed data

ooooia

IITRIIIT RESEARCH INSTITUTE

IIT Research Institute ESAT Region 5536 South Ctarit t, S*M* 734;T«l«phon« (312) 353-S3O2 (312) 353-S3O7

Supertax!, US EPA Region 577 West Jackson BoulevardChicago n, 60604

Pn>ject:Hegelei ZincProject Number (none)

Project Manager Howard PharaReported:

Nov-26-02 14:43

2003ZG02S01E2J2801-01(Soil)

MetabbylCr

*+*

Barf.!""BeryKaai

/^Maunai"JLmmChraaumCatoMCapperIra*LeadMacacaarafiaaiaarirNicfcdPttmfrM

Sa>crSediMVuadiMZwc

Saapted:Received:

Fl-p'Ron,, Qolrtieis MDL

I3N* 24IT* 010l-» 006032* 072MM 1.4It 07213 062

I2M 04042M4 17

22M 3433M 163N 0.1239 080

7M 38IJ 02632* 1225 19

7t«M 25

Oct-23-02 09:45Oct-28-02 12:03

Reporting

Limit Units

7 6 m£/Vg

030

0 16

072

46

072

20

IJ

38

I I

84

036

26

120

080

38

60

80

DOution Balcfc Prepared Analyzed

1 EK20404 No*-06-02 Nov- 12-02» • • •

• • m m

m m * m

^* • » •

.

.

.

.• • • •

.

.• » ai •

• * • •

•> • <i •

« * • •

50 Nov-21-02

KidiardUilg.Lliqnist

OO0056RqmrtName: E2J2801

Page 2 of20


IIT Research Institute ESAT Region 5

536 South Clark Street, Suite 734; Chicago, IL 6O605Telephone (312) 353-8302 Facsimile (312) 353-8307

Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604

Project:Hegeler ZincProject Numberlnone] Reported:

Project ManagerHoward Pham Nov-26-02 14:43

2003ZG02S03

E2J2801-03(Soil)Sampled: Oct-23-02 10:35Received: Oct-28-02 12:03

Metals by ICP

\nalyte

AluminumBariumBeryllium

/*»-lmium%|liumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

Result

8900100

0.92

58

210009.4

8.5

98

30000720

5800800

19

780

U

120

19

11000

Flags/Qualifiers ^JTJL

2.4

0.10

0.0600.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

0.26

12

1.9

5.0

ReportingLimit

7.6

0.30

0.16

0.72

4.6

0.72

2.0

1.3

3.8

11

8.4

0.36

2.6

120

0.80

38

6.0

16

Units Dilution Batch Prepared Analyzed

mg/kg 1 EK20404 Nov-06-02 Nov- 12-02ii ii n n n

„

" "

„

„

II II H II H

-n n ii it n

n n it n n

ii n n n ii

n n n n n

i, ii ,, it .1

H n u n n

„ii ii n n n

„

10 " " Nov-21-02

Kicnaru L/iig, L,nemist

00005;Report Name: E2J2801

Page 3 of20


ESAT Region 5IIT Research

536 South Ctawfc StoMt, Sirite 734; <T«tophon« (31Z) 353-83O2 Firilali (312) 353-OO7

Soperfund. US EPA Region 577 West Jadcsoa BoulevardChicago IL, 60604

Project :Hcgelcr ZincProject Numberlnonel Reported:

Project Manager-Howard Pham Nov-26-02 14:43

2M3ZG02S05

E2J2801-05(SoiI)Sampled: Oet-23-02 11:00

Received: Oet-28-02*12:03

MetabbyKT

taatyic

Barwai

BerjUmm

3G7ChrMMM

Cobalt

C**»erITMLadMafBCMBl

Ma^aMK

Nickel

Titmnm

SivcrS^NM

Vaudaiai

ZMC

HiResult 0"»

II*•47

12

»J

IS

INN

2*

37M

22*

21

IN*

V

IM

21

2SM

V

24

0 10

0060

022

1 4

022

062

040

12

34

26

012

080

38

026

12

19

25

ReportingLimit Units Dflutxn Batch PicpMtd Analyzed

76 rng.lg 1 EK2M04 Nov-06-02 No v- 12-020.30 . . . .

0.16 . . . .0 7 2 . . . .

46 ^0 7 2 . . . .

20

13

38I I . . . .

84

OJ6

26

1200 8 0 . . . .3 8 . . . .

60

80 * 5 ' * Nov-21-02

'.)

Kjcnara tnig. L.netntsi

OOOOJdReport Name: E2J2801

Page 4 of 20

IITRINT RESEARCH INSTITUTE

I IT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 353-8302 Facsimile (312) 353-83O7


Project;Hegeler ZincProject Number: [none] Reported:Project ManagerHoward Pham Nov-26-02 14:43

2003ZG02D05

E2J2801-06(SoiI)Sampled: Oct-23-02 11:00

Received: Oct-28-02 12:03

Metals by ICP

Vnalyte


tt^tffc

ChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

Result

11000

96

0.66

1.4

5800

13

9.8

17

18000

22

3700

150

19

1200

U

99

22

2300

Flags/Qualifiers MJJL

2.4

0.10

0.060

0.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

0.26

12

1.9

2.5

Reporting

Limit Units Dilution Batch Prepared Analyzed

7.6 mg/kg 1 EK20404 Nov-06-02 Nov-12-02

0.30 " " " /

0.16 " " " " /

0.72 " " " " " ^^~

4.6

0.72

2.0 "

1.3

3.811

8.4

0.36

2.6

120

0.80

38

6.0

8.0 5 Nov-21-02

Kicnara uiig, unemist

000033Report Name: E2J2801

Page 5 of 20


IIT Research 1

536 Smith(312)353-6302

M. 60605(312)353-8307

Supofimd. US EPA Region 577 West Jackson Boulevard

Chicago IL, 60604

ProjecrHegeler Zinc

Project Number (none)Project Manager Howard Pham

Reported:

Nov-26-02 14:43

2M3ZG02S06

E2J2801-07(SoiI)

Sampled: Oct-23-02 11:12


laatyte Result

Almmmmm 2MN

Biriw l»

BcfyflMBi 1.1

•" M* MIttOtmrn IMM

QUOTUM M

€«** IS

Coffer 43

Ircai 27SM

Lad 2*MMapMpM SJ»J

RvM»fHB(9C 30VNickel 43•4^— 1— ^ ^I^ArvunMifll ZIW

Sarcr U

S^MM IJ»

VaMdiaai 35

ZMC I2M*

FiiesOoJifien MDL

2 4

010

0060

022

14

022

062

040

12

3 4

26

012

080

38

026

12

19

5 0

ReportingLimit

'6

030

( 16

072

4 6

072

20

13

3 8

II

84

(J6

26

!20

080

38

40

16

Units Dilution Batch Pieyaul Analyzed

meVg 1 EX20404 Nov-06-02 Nov-12-02. . . .

• * . . .

.

^• • p • •

* • p • •

• » • P •

.

• * P P •

W P P P P

• •> • p p

• p p p •

.

.

.

.

1 0 • • Nov-21-02

o

0000^0Report Name: E2J2801

Page 6 of 20


NT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL. 60605Telephone (312) 353-8302 Facsimile (312) 353-8307


Project: Hegeler ZincProject Numberfnone]

Project ManagerHoward PhamReported:

Nov-26-02 14:43

2003ZG02S07

E2J2801-08(Soil)

Metals by ICP

\nalyte


£ jiiiiumfla\ jB

VnciurnChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

Result

17000

110

2/1

28

15000

13

7.9

37

26000

70

4300

250

27

1100

V

120

23

4600

Sampled:Received:

Flags/Qualifiers MDL

2.4

0.10

0.060

0.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

0.26

12

1.9

2.5

Oct-23-02 12:55Oct-28-02 12:03

Reporting

Limit Units

7.6 mg/kg

0.30

0.16

0.72

4.6

0.72

2.0

1.3

3.8

11

8.4

0.36

2.6

120

0.80

38

6.0

8.0

Dilution Batch Prepared Analyzed

1 EK20404 Nov-06-02 Nov-12-02ii n n ii

n n n U

«

n n ii n

n it n «

n » it ii

,,

n n n n

„„„n ii n tt

n n ii n

ii it n n

„„

5 " " Nov-21-02

Kicnard uilg, cnemist

OOOOSi

Report Name: E2J2801

Page 7 of 20



(312) (312)353-8307

Svperfind. US EPA Region S77 West Jackson BonfcrardChicago IL, 60604

Project: Hegeler ZincProject Number [none]Project Manager Howard Pham

Reported:

Nov-26-02 14:43

2M3ZG02S08E2J2801-09(SoiI)

Sanpkd: Oct-23-02 13:37


MctabbylCr

Urfyte

Mmmimmm

BariMM

BeryK»^mimmdammChrwauM

CafcakCapper

ITMLead

MagattMai

Mragaawae

NiduJ

PMaaaiM

Safeer

SvJaaai

VaaadiM

Zaac

FlReadi 0"

I2*MSS

•.72

12

34M

15

ts31

22Mt

2M

2CM

lit

13

1IM

V

75

2*

IJM

2 4

010

0060

022

14

022

062

040

12

34

26

012

080

38

026

12

19

050

RepottingLimit

"6

130

016

072

46

072

20

1.3

38

11

84

OJ6

26

120

080

38

60

1 6

Units Dilubon BMcb Pleyaed Analyzed

mgV? 1 EK20404 Nov-06-02 Nov- 12-02• • * • •

r

.

• • ^g

•m m m m m

* • • • •

* • « • •

• • • ai •

* • • • •

* • m m m

• m m m m

V M M * •

m m m m m

* * at m m

-

Nov-21-02

KKtiara Lnig, L,nemtstReport Name: E2J2801

Page 8 of20


IIT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 353-8302 Facsimile (312) 353-8307


Project:Hegeler Zinc

Project Number: [none]Project ManagerHoward Pham

Reported:

Nov-26-02 14:43

2003ZG02S09


Metals by ICP

taalyte


j^Hmium%|iium

ChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

Result

6000

80

0.67

12

16000

6.4

6.1

59

27000

250

2800

520

14

600

U

120

17

2700


2.4

0.10

0.060

0.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

0.26

12

1.9

2.5

ReportingLimit

7.6

0.30

0.16

0.72

4.6

0.72

2.0

1.3

3.8

11

8.4

0.36

2.6

120

0.80

38

6.0

8.0

Units Dilution

mg/kg 1

"„

„

„

II H

II H

II II

II II

It II

n

n i,

"

M n

n n

„

„

5

Batch Prepared Analyzed

EK20404 Nov-06-02 Nov-12-02ir n H

M n n

n n . n

n n n

H n n

it n n

n n n

n n n

n it n

n » «i

" "

n n n

n n n

n » n

II N II

II II II

Nov-21-02

Kicnard Uilg, unemist

GOOOSJ


Page 9 of20

IITRIRESEARCH INS 111 If!

IIT Research tastttat* ESAT Region 5

536 South Ctarfc StrMt,Tctephon* (312) 353-83O2

734; Chicago, IL 60605(312)353-8307

SaperfuDd, US EPA Region 5 Project Hegel er Zinc77 West Jackson Boulevard Project Number 1 none]Chicago IL, 60604 Project Manager Howard Pham

Reported:Nov-26-02 14:43

2M3ZG02S10E2J2801-ll(Soil)

MetabbylCP

taalyie

AfaMBM

Bariaai

BeryBu

^^daMUX'^fffia^

ChrvaNM

Cafeaft

Capper

Ira*Lea*

riijaiiiaai

riaajiafir

Nkkrf

ruaaiiaai

Star

S^MBI

VantfMai

ZiK

o

Sampled:

Received:

Flajs'Resnh Qwlifim MDL

MM 24

27t 010

1.1 0060

15 022

21M» 14

M 022

12 062

I7f 040

74M> IJ>

12* 34

3SM 2,6

CTf 012

55 080

•!• 38

V 0.26

2M 12

2f 1 9

34M 25

Oct-23-02 14:35

Oct-28-02 12:03

Rcportiiig

Limit Units

7 6 mg/kg

030

016

072

46

072

20

1.3

38

I I

84

036

26

120

080

38

60

80

Dilutioa BaKh Prepared Analyzed

1 EK20404 Nov-06-02 Nov-12-02. . .

• Wl » •

•1 * •> •

^• • * •

.• m m m

. . .• • • •

• • • •

.

.• • • •

.* » • •

• • • •

5 ' • Nov-21-02

k^

OOOOS4

'ReportName: E2J2801

Page 10 of 20




Prqject:Hegeler ZincProject Numberfnone] Reported:Project ManagerHoward Pham Nov-26-02 14:43

2003ZG02S11E2J2801-12(Soil)

Sampled: Oct-24-02 08:15Received: Oct-28-02 12:03

Metals by ICP

taalyte

Aluminum

BariumBeryllium

^*tmiumllliumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

Result

8300

140

0.92

9.6

30000

19

9.9

110

44000

290

3900

770

21

1000

U

190

29

2300


2.4

0.10

0.060

0.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

0.26

12

1.9

2.5

ReportingLimit

7.6

0.30

0.16

0.72

4.6

0.72

2.0

1.3

3.811

8.4

0.36

2.6

120

0.80

38

6.0

8.0


mg/kg 1 EK20404 Nov-06-02 Nov-12-02i i n u n "

n n n H ii

n

"

„

"

ii n ii n n

„»ti ti it ii ti

II H It H 11

II It II tl H

I,

II II II H II

II II H It It

" 5 " " Nov-21-02

Kicnara uiig, ChemistReport Name: E2J2801

Page 11 of 20

IITRI tastitate ESAT Region 5IIT

536 South Ctawfc MrMt, Mto 734s (Tatophon* (312)353-8302 ricahali (312)353-8307

IIT

Supofuod. US EPA Regioo 577 West Jackson BoulevardChicago IL, 60604

ProjectHegeler ZincProject Number (none)

Project MnagerHoward PhamReported:

Nov-26-02 14:43

2M3ZG02S13E2J2Ml-14(SoU)


Metals by ICF

laalyle Ren** f__|___ CaMft

Bariaai 2SIBerYKM 14~\lauaai IS«_£ICMB Z/*v

ChraaMM 17Cobalt ItCapper 95Iran 4"7tMLead 4ltMHBi liaai 319Maaaaaeae 67Nkkd 3Sntanf¥TTT 7MSaVer VSaaiaai 3MVaaadim MZiac 92t

Flags/

2.4

010

00600.22

14

0.22

062

040

1.2

3.4

26

012

OK)

31

OJ6

12

19

050

Reporting

Limit

76

330

316

072

46

072

20

13

3.8

1184

OJ6

26

120

080

38

60

16

Units DfluDon Batch Prepared Analyzed

me/kg 1 EK20404 Nov-06-02 Nov-12-02m * m * •

m m m m m

m m m m m

| g.

.

.

•.

.

.

+ m m m m

* m m m m

.

.,

Nov-21-02

//-<?<£>-O>-Kicnara Lnig, coemtsi

OOOOSo


Page 12 of 20



Superfiind, US EPA Region 577 West Jackson BoulevardChicago IL, 60604

Project;Hegeler ZincProject Number: [none]


Nov-26-02 14:43

2003ZG02S14E2J2801-15(Soil)



Metals by ICP

Vnalyte

Aluminum

Barium

Beryllium^Smium^Ifcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

7900

86

1.3

25

250012

11

630

60000

4200

490

160

25

320

U

88

22

32000

Flags /Qualifiers MDL

2.4

0.10

0.060

• 0.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

0.26

12

1.92.5

Reporting

Limit

7.6

0.30

0.16

0.72

4.6

0.72

2.0

1.3

3.8

11

8.4

0.36

2.6

120

0.80

38

6.0

8.0

Units Dilution Batch Prepared

mg/kg 1 EK20404 Nov-06-02H II II II

ii n ii n

„ii n n n

n n n n

„II II H H

H ii n n

H it n n

„H II II tl

H . n n n

„„ii ii » n

ti n n ii

" 5 " "

Analyzed

Nov-12-02n

n

n

' n

it

n

n

n

n

it

•i

n

•»""

Nov-21-02

Kicnard Lmg, t^nemistReport Name: E2J2801

Page 13 of 20

IITRIIIT Research htstftat* ESAT Region 5

Tctophon* (312) 353O02 FacataBe (312) 353-8307

IIT RESEARCH INSTITUTE

Saperfaod. US EPA Region 5 Project:Hegeler Zinc

77 West Jadooo Boulevard Project Number [none] Reported:Chicago IL. 60604 r pject Manager Howard Pham Nov-26-02 14:43

20t3ZG62D14

E2J2Ml-16(SoiI)Sampled: Oct-24-02 08:52Received: Oct-28-02 12:03

byKT

taalytt

AtaauMmBaramBcrj«m-VtaumJLmmChraaUMiCckaJtCipatrbwLeadMlgJHBJM

InrirMichel

mania*SNtr$••!••" — -" —ZaK

Resok

S4M

II*

Ml

21

37IM12

1*

92

4IM*321

43N

rm23

1*M

V

IN

22

35M

Flap/OUUDCR (LfDI

24

010

0060

022

14

OJ22

062

040

1J

34

i6

012

080

38

026

12

19

2,5

Reporting

Limil

7.6

D30

0 16

072

46

072

20

1.3

38

I I

84

036

26

120

080

38

60

80

Units Daution Batch Prepared Analyzed

mg/kf 1 EK20404 Nov-06-02 Nov-12-02

•• • • * •

r • • • •

^* • * • • •!••

• m " • •

• • • • •

• • • * •

. . . .

* • • » •

* m • » •

* • m • *

•» » • • •

* * • • •

• • • • •

.

5 * ' Nov-21-02

Report Name: E2J2801uiig. unonui Page 14 of 20


IIT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 3534302 Facsimile (312) 353-8307

Supertund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604

Project;Hegeler ZincProject Number: [none]

Project ManagerHoward Pham

Reported:

Nov-26-02 14:43

2003ZG02S15

E2J2801-17(Soil)



Metals by ICP

\nalyte

Aluminum

Barium

Beryllium

Mrcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

7500

130

0.87

3.4

1900

12

3.6

47

89000

790

380

6511

4700

0.96

1900

30

710


2.4

0.10

0.060

0.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

0.26

12

1.9

0.50

ReportingLimit

7.6

0.30

0.16

0.72

4.6

0.72

2.0

1.3

3.8

11

8.4

0.36

2.6

120

0.80

38

6.0

1.6

Units Dilution Batch

mg/kg 1 EK20404n ii n

H n n

n n H

n H n

N n n

n n II

n n n

f. H II

H II II

It It H

.,

It II II

tl II II

„

„

„

n

Prepared

Nov-06-02"n

n

u

n

n

n

n

n

n

"

it

n

»•••"

Analyzed

Nov-12-02"it

it

it

n

n

u

»it

ti

ti

n

»-»

Nov-21-02

w

Kicnara uiig, Lnemist

0000^3


Page 15 of 20

IITRI IIT Research Institute ESAT Region 5S36 South Ctarfc ttraet, Mte 734j CWc^o, H. 6O605Tctophon* (312) 353-S3O2 FacsMte (312) 353-B3O7

Soperfnod. US EPA Region 577 West Jackson BoolevwdChioco IU 60604

Project: Hegeier ZincProject Number [none]

Project Mnager Howard Phara

Reported:

Dec-04-02 11:15

2M3ZG02S16

E2J2801-18(Soil)

Suipled: Oct-24-02 09:10


MetabbyKT

ferine

AJaaUBaai

Bariaai

ttrjmmm

•"VauaaifJUaa,

Caraatiaai

Cabatt

Caaacr

Iraa

LeadMijaiaMMaagaaeatNickelftmrimm

SaverSadiaaiVaaadiaaiZ«K

f^f^wf^**

ISM*

22*

23

19

SIM

27

7.4

12*

I4MM

MM

4tt

IM

27

24M

V

UM

7*34M

2-4

010

0060

0^2

14

0^2

062

040

1-2

3.4

2.6

012

080

38

L OJ6

12

19

2.$

Keponmf

Lima

7.6

OJO

016

072

46

072

20

U

3.8

11

84

OJ6

26

120

080

38

60

80

Units DOoboa Back Prepared Analyzed

rngAg 1 EK20404 Nov-06-02 Nov-12-02.

. . . .

. . . .

. . . . ^ |

. . .

'.

» • m m m

* m » m m

* * • • at

.

.

• * m m m

. . .

» • • • •

• •> • * •

5 Nov-21-02

Kicnara Uilg. (Joemtst


Page 16 of 20




ProjectrHegeler ZincProject Number: [none]


Nov-26-02 14:43

2003ZG02S17E2J2801-19(SoiI)

Metals by ICP

Vnalyte


/••NJmiuni%tfjumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

Result

4400

330

0.79

63

8700

10

12

480

37000

1200

2700

200

20

340

0.71

180

14

22000

Sampled:Received:


2.4

0.10

0.060

0.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

J 0.26

12

1.9

10

Oct-24-02 09:32Oct-28-02 12:03

Reporting

Limit Units

7.6 nig/kg

0.30

0.16

0.72

4.6

0.72

2.0

1.3

3.8

11

8.4

0.36

2.6

120

0.80

38

6.0

32

Dilution Batch Prepared Analyzed

1 EK20404 Nov-06-02 Nov-12-02i, „ n

H II II II

H u n i i

II n II n

n n It it

H it n it

It H It II

II H It II

It ii II n

,.

ii t, n n

1. II n „

II II tl tl

,,

H II II II

n

20 " " Nov-21-02

Kicnard Ung, cnemist

oooo;±Report Name: E2J2801

Page 17 of20

IITRI IIT Research Institute ESAT Regton 5

536 Soiith Ctefc SfaMt, Strite 734; CMcavo, ITetaphon* (312) 353-8302 FacsMte (312) 353-8307

INSTITUTE

Sopofuod, US EPA Region 5

77 West Jackson BonlewdChicago tL, 60604

Project: Hegeler Zinc

Project Numberlnone)

Project ManagerHoward Pham

Reported:

Nov-26-02 14:43

2M3ZG02S18E2J2MI-20(SoiI)

Saapled: Oct-24-02 09:50Received: Oct-28-02 12:03

MdabbyKT

lolytt

AlmmimmmBmrimmBerjflkuafif-i-lo..

CarWMiM

CakeJtCippcr

Ira*LeadMUfitmmIttnfmntNickeltttMmimmSatorSetiM

ViaidiMZtec

3

FlRemit 0"

3SMIN•.75

3*I4M

14

II93»

71M>

MM42*2MM

3M4.1

2M1*

I9M1

IBS/lifiel» MDL

240.10

0060

02214

022

062

040

12

34

26

01208038

0261219

10

Reporting

Lhnd

76

OJO

016

072

46

072

20

IJ

381184

03626120ago386032

Uoits D3atio0 Babdi IVcpvccd Analyzed

mg^ 1 EK20404 Nov-06^2 Nov- 12-02*. . . • •

• • * • •

* m m m m

. . . ^.

»

* • m * m

n m m m m

'* m m * •

+ m m m m

+ » m m m

+ m m m •

•• m m • •

» • » * •

* • • » •

20 ' ' Nov-21-02

U

0000 ?^


Page 18 of 20


. IIT Research Institute ESAT Region 5



ProjectHegeler ZincProject Numbenfnone] Reported:

Project ManagerHoward Pham Nov-26-02 14:43

2003ZG02S19


Metals by ICP

\nalyte


fijif""1"SKiumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

Result

4300

270

0.72

78

6800

11

11

490

36000

1500

1400

270

17

360

1.6

180

14

22000

Flags /Qualifiers MDL

2.4

0.10

0.060

0.22

1.4

0.22

0.62

0.40

1.2

3.4

2.6

0.12

0.80

38

0.26

12

1.9

10

Reporting

Limit

7.6

0.30

0.16

0.72

4.6

0.72

2.0

1.3

3.8

11

8.4

0.36

2.6

120

0.80

38

6.0

32


mg/kg 1 EK20404 Nov-06-02 Nov-12-02" » »

"II II ii II n

n H n n n

H n n n II

n n H H n

n n it n it

n « it n n

n u n n n

II II II N II

n n M n n

.,II II It II H

n n ii n n

n n n n n

„ ,1 M

20 " Nov-21-02

Kicnara uilg, Chemist

000073


Page 19 of 20


IIT Research Institute ESAT Rvgfcm 5

Tctaohon* (312) 353-83O2 Fat •!••• (312) 353OO7

Soperfund. US EPA Region S Project Mcgelcr Zinc77 West Jackson Boulevard Project Number [ none) Reported:Chicago IL. 60604 Project Manager Howard Pham Nov-26-02 14:43

Notes aad DefiiitioBs

» Spice audit not valid. The ample caacemnboo exceeds twice the concentration of the spike added. No qulifiatian made for thisQCaodiL

J The identification of the aoalyte is acceptable; the reported value is an estimate.

L The identification of the analyte is acceptable; the reported value may be biased low. The actual value is expected to be greaterthan the repotted varae.

U Not Detected

tfR Not Reported

6OOO ?4


Page 20 of 20

IITRINT RESEARCH INSTITUTE




ProjecfcHegeler ZincProject Number: [none]

Project ManagenHoward PhamReported:

Nov-19-02 16:22

ANALYTICAL REPORT FOR SAMPLES

Sample ID

2003ZG02S02

2003ZG02S04

2003ZG02S08

2003ZG02S10

2003ZG02S12

2003ZG02D14

Ui03ZG02S20

Laboratory ID

E2J2801-02

E2J2801-04

E2J2801-09

E2J2801-11

E2J2801-13

E2J2801-16

E2J2801-22

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Date Sampled

Oct-23-02 10:35

Oct-23-02 10:35

Oct-23-02 13:37

Oct-23-02 14:35

Oct-24-02 08:35

Oct-24-02 08:52

Oct-24-02 09:52

Date Received |

Oct-28-02 12:03

Oct-28-02 12:03

Oct-28-02 12:03

Oct-28-02 12:03

Oct-28-02 12:03

Oct-28-02 12:03

Oct-28-02 12:03

Kicnara ung, unemistReport Name: E2J2801

Page 1 of9

IITRII IT

Tctophmw (312) 3534302

irrSvperted. US EPA Repoa 5 Project Hegekr Zinc77 WatJ*ckmBoiilcv»d Project Number [noi ] Reported:

Project KtengerHowvd Pham Nov-19-02 16:22

Saapted: Oct-234R 10:35Received: Oct-28-02 12:03

TCLTMctebbyKT

Ftap/ ReponiBgQnlifim MDL LkM (j, DOotioa Batch Pftpwed Ai^yzed

Z73 60.0 200 ug/L 10 EK20403 NwMH-02 Nov-15-02

S42 3.00 900

« . 7 3 4 0 1 0 0 . . . .

U 3 0 0 9.00 • • • • •

15» 25.0 r.O ' • • • t •

U 73.0 2 5 0 • * • • •U 5 0 0 1 7 0 . . . .

// -bfe-O3- Report Name: E2J2801Page 2 of 9

IITRII IT RESEARCH INSTITUTE


536 South Clark Stravt, Suit* 734; Chicago, IL 60605T«l0phon« (312) 353-8302 Facsimile (312) 3534307


Project:Hegeler Zinc


Reported:

Nov-19-02 16:22

TCLP Metals by ICP

2003ZG02S04E2J2801-04(Soil)


\nalyte ResultFlags /

QualifiersReporting


Arsenic

Barium

Cadmium

omium

Fad

Selenium

Silver

281

782

21.1

U

5790

96.8

U

J.K

60.0

3.00

3.40

3.00

25.0

73.0

5.00

200

9.00

10.0

9.00

87.0

250

17.0

ug/L 10 EK20403 Nov-04-02 Nov-15-02

Kicnaro Dug,Report Name: E2J2801

Page 3 of9

IITRI 536 South iT»l«p*ion« (312) 353-MCtt tasMto (312) 353-8307

IIT nwin

Suptrfupd. US EPA Region 5 PnqecL-Hegder ZincrrWotJadcniBoiifevwd Project Nvober [none] Reported

Project MvueerHowvd Pham Nov-19-02

2M3ZG02S68E2J2Wl-4»(SoiI)

Suipled: Oct-23-4>2 13:37Received: Oct-2»-02 12:03

TCLTMrtahbyiCF

FUp/ ReponiagMDL Limd Units DibtiaB Bacfc Prepared Aiutyzed

U 60.0 200 ug/L 10 EK20403 Now-04-02 Nov-15-022 2 4 3.00 9.00 . . . .

I M 3.40 1 0 0 . . . .

U 3.00 900

317 25.0 »70

U 730 250

U S.OO 1 7 0 . . . .


Page 4 of9


NT Research Institute ESAT Region 5

536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 3534302 Facsimile (312) 3534307


ProjectHegeler ZincProject Number: [none]Project ManagerHoward Pham

Reported:

Nov-19-02 16:22

TCLP Metals by ICP

2003ZG02S10

E2J2801-ll(Soil)


\nalyte Result


Reporting


Arsenic

Barium

Cadmium

Lead

Selenium

Silver

394

884

121

U

30.1

V

V

60.0

3.00

3.40

3.00

25.0

73.0

5.00

200

9.00

10.0

9.00

87.0

250

17.0

ug/L 10 EK20403 Nov-04-02 Nov-15-02

OOOJ01

Kicnara uiig, unemisrReport Name: E2J2801

Page 5 of9

IITRI IITR<

irrSvpofuadLUSEPARcgioaS PrcjeccHegder Zinc77 We* Jadaoa BoafcvMd Project Nwnber|w»el Reported:

Project MMt crHowvd Pham Nov-19-02 16:22

2M3ZGt2S12E2J2Ml-13(Soil)

1: Oct-24-02 08:35

Received: Ort-2»-«2 12:03

TCLTMctabbrlCr

Q-««« MDL L-a

MJ J 600 200 ug/L 10 EK20403 Nov-04-02 Nov-15-02

2 4 t 3.00 9.00 • • • " •

14J 3.40 100 . . . .

U 3.00 9.00 . . . .

U 250 17.0

U 73.0 2 5 0 • • ' • •

U 5.00 17.0 . . . .

o


Page 6 of9



Supcrfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604

Projecf-Hegeler Zinc


Reported:

Nov-19-02 16:22

TCLP Metals by ICP

2003ZG02D14E2J2801-16(Soil)


\nalyte ResultFlags/

Qualifiers MDLReporting


Arsenic

Barium

Cadmium

ead

Selenium

Silver

353

545

3<U

U

U

U

U

60.0

3.00

3.40

3.00

25.0

73.0

5.00

200

9.00

10.0

9.00

87.0

250

17.0

ug/L 10 EK20403 Nov-04-02 Nov-15-02

-o> >-Kicnara uug, unemist

Report Name: E2J2801Page 7 of9

IITRIIfT RESEARCH

SupofiBd. US EPA Region 577 Weal Jadaon BoulevardOucagoIL, 60604

Project Hegder Zinc

Project Number[n«K]Project fcta^erHoward Pham Nov-19-02 16:22

2M3ZG02S20E2J2Ml-22(SoiI)

ipfcd: Oct-14-«2 09:52Received: Oet-2S-0112:03

TCLTMcttlibylCr

QariifirnReponmg

Units

u543

U

SBrtrU

U

60.0

300

340

300250

730500

200

9.00

10.0

900

«70

250

17.0

10 EK20403 Nor-04-02 Nov-lS-02


Page 8 of 9

IITRIIIT Research Institute ESAT Region 5

536 South Clark Straot, Suit* 734; Chicago, IL 60605Talophon* (312) 3534302 Facsimile (312) 353-8307

IIT RESEARCH INSTITUTE

Superfund, US EPA Region S Project:Hegeler Zinc77 West Jackson Boulevard Project Number: [none] Reported:Chicago IL, 60604 Project ManagcrHoward Pham Nov-19-02 16:22

Notes and Definitions

J The identification of the analyte is acceptable; the reported value is an estimate.

K The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less thanthe reported value.

U Not Detected

NR Not Reported

.--TV

-O 3_ Report Name: E2J2801Kicnara uug, cemist p 9 of 9

US EPA - REVIEW OF DATA (ICP METALS, TCLP ICP ...tenfold dilution used to digest the extracts. / QC...

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