UOP Ortloff NGL LPG and Sulfur Recovery Technologies Tech Presentation

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Transcript of UOP Ortloff NGL LPG and Sulfur Recovery Technologies Tech Presentation

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    Ortloff NGL/LPG

    Recovery, CO2

    Separation and Sulfur

    Recovery Technologies

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    CORE BUSINESS

    NGL, LPG, ANDLNG

    TECHNOLOGY

    SULFURRECOVERY

    TECHNOLOGY

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    HISTORY OF ORTLOFF

    The Ortloff Corporation (1960 - 1985) Turnkey EPC Contractor in the gas processing industry

    Developed 5 U.S. Patents - Gas Processing Technology

    MTP - Two Stage Expander Process

    LSP - Liquid Subcooled Process

    VEP - Vapor Enrichment Process

    OHR - Overhead Recycle Process

    GSP - Gas Subcooled Process

    Withdrew from EPC contracting in 1985 and formed OrtloffEngineers, Ltd.

    Ortloff Engineers, Ltd. (1985 - Present)

    Established Reputation as Technology Supplier/Developer (21) Additional Patents

    Established Cooperative Marketing Agreement with UOP in2002

    Sold to Management Group in 2005

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    ORTLOFF TODAY

    Since 1985, Ortloff NGL/LPG Technology has been licensed to process

    over 50.0 BSCFD of natural gas in more than 120 plants ranging in

    size from 25 MSCFD to 1.4 BSCFD located in over 20 countries.

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    COOPERATIVE MARKETING AGREEMENT

    UOP MARKETS & LICENSES ORTLOFFTECHNOLOGY

    NGL / LPG / LNG / SULFUR

    Most countries outside of U.S.

    UOP / ORTLOFF SYNERGY Development of process technology

    CLIENT BENEFITS

    Single source for all major gas processing technology

    Simplifies technology contract agreements

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    NGL / LPG RECOVERY

    TECHNOLOGY

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    ETHANE RECOVERY

    NOTE: ACTUAL PERFORMANCE MAY VARY DEPENDING ON ACTUAL FEED COMPOSITON AND CONDITIONS

    MRX MULTIPLE RECTIFICATION AND REFLUX

    SRX SUPPLEMENTAL RECTIFICATION WITH REFLUX

    SRC SUPPLEMENTAL RECTIFICATION WITH COMPRESSIONRSV RECYCLE SPLIT VAPOR

    RSVE RECYCLE SPLIT VAPOR WITH ENRICHMENT

    GSP GAS SUBCOOLED PROCESS

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    PROPANE RECOVERY

    NOTE: ACTUAL PERFORMANCE MAY VARY DEPENDING ON ACTUAL FEED COMPOSITON AND CONDITIONS

    94

    95

    96

    97

    98

    99

    100

    42 46 50 54 58 62 66 70 74 78 82 86 90 94 98

    RELATIVE COMPRESSION POWER

    (HP/MMSCFD)

    %

    PROPANE

    RECOVE

    RY

    RSV

    RSVE

    GSP

    SRC

    SCORE

    MRX

    MRX MULTIPLE RECTIFICATION AND REFLUX

    SCORE SINGLE COLUMN OVERHEAD RECYCLE

    SRC SUPPLEMENTAL RECTIFICATION WITH COMPRESSION

    RSV RECYCLE SPLIT VAPORRSVE RECYCLE SPLIT VAPOR WITH ENRICHMENT

    GSP GAS SUBCOOLED PROCESS

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    CO2 TOLERANCE

    80.0

    81.0

    82.0

    83.084.0

    85.0

    86.0

    87.0

    88.0

    89.0

    90.0

    91.0

    92.0

    93.0

    94.095.0

    96.0

    97.0

    98.0

    99.0

    100.0

    0.5 0.8 1.0 1.3 1.5 1.8 2.0

    CO2in Feed Gas(mol%)

    %E

    thane

    Recovery

    GSPSRC

    RSVE

    RSV SRX

    MRX

    NOTE: ACTUAL PERFORMANCE MAY VARY DEPENDING ON ACTUAL FEED COMPOSITON AND CONDITIONS

    MRX MULTIPLE RECTIFICATION AND REFLUX

    SRX SUPPLEMENTAL RECTIFICATION WITH REFLUX

    SRC SUPPLEMENTAL RECTIFICATION WITH COMPRESSION

    RSV RECYCLE SPLIT VAPOR

    RSVE RECYCLE SPLIT VAPOR WITH ENRICHMENT

    GSP GAS SUBCOOLED PROCESS

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    NGL / LPG RECOVERY TECHNOLOGY

    Ortloff NGL / LPG recovery technology offers one ormore of the following advantages: Ethane and propane recovery levels up to 99%

    Increased recovery with no increase in horsepower

    Increased capacity with no increase in horsepower

    Lower capital cost

    High CO2 tolerance

    Improved operational stability

    Improved operating flexibility (dual mode ethane / propane recovery)

    Maintain ultra-high C3 recovery throughout all C2 operating modes Easily retrofit into existing NGL/LPG Recovery Plants

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    TECHNOLOGY OPTIONS

    SCORE S

    FRR

    IOR

    SDR

    SSP

    CRR

    SFSR

    SFR

    RSVE

    RSV

    SRP

    ????

    CDC

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    TECHNOLOGY SELECTION

    Choose a process design which.

    Meets all product specifications and recovery levels

    Avoids CO2 freeze

    Avoids unstable phase region

    Requires the least heat and compression costs Provides the required operating flexibility and upgradepotential

    Minimizes inlet/product treating costsIterations during early phase of project are critical!

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    LNGNGL / LPG RECOVERY

    TECHNOLOGY

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    LNG TECHNOLOGY

    INTEGRATED LNG TECHNOLOGY (SERIES)

    GAS TREATING

    AND

    DEHYDRATION

    LNG

    NGL or LPG

    FEED GAS ORTLOFF

    LIQUIDS

    RECOVERY

    NATURAL GAS

    LIQUEFACTION

    FUEL

    GAS TREATINGAND

    DEHYDRATION

    LNG

    NGL or LPG

    FEED GAS

    ORTLOFF

    LIQUIDS

    RECOVERY

    NATURAL GASLIQUEFACTION

    FUEL

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    LNG TECHNOLOGY

    INTEGRATED LNG TECHNOLOGY (ANGLE)Offers a 10% to 20% improvement in overall efficiencyof the liquefaction process

    GAS TREATING

    AND

    DEHYDRATION

    LOW-LEVEL

    REFRIGERANT

    COMPRESSION

    LNG

    HIGH-LEVEL

    REFRIGERANT

    COMPRESSION

    NGL or LPG

    FEED GAS

    LOW-LEVEL

    REFRIGERANT

    PRE-COOLING

    ORTLOFF

    LIQUIDS

    RECOVERY

    NATURAL GAS

    LIQUEFACTION

    FUEL

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    LNG TECHNOLOGY

    LNG Fractionation Process (LFP) Technology

    Ship

    Off-loading

    Ship Vapor

    Return

    BOG

    Recondenser

    Gas toPipeline

    In-Tank

    LNG Pump

    High Pres.

    LNG Pump

    Vaporizer

    LFP

    NGL / LPG

    RecoveryUnit

    NGL / LPG

    Product

    Rich

    LNG

    Lean

    LNG

    BOG

    Compressor

    LNG

    Storage

    LNG

    Storage

    LFP

    NGL / LPG

    RecoveryUnit

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    LNG FRACTIONATION TECHNOLOGY

    Ortloffs LNG fractionation technology for the recoveryof NGL / LPG at LNG receiving terminals offers the

    following advantages:

    Flexibility to handle wide range of LNG composition

    Improved plant efficiency by utilizing inherent refrigeration available

    in LNG

    No increase in heat load on vaporization

    Minimizes plant capital and operating costs over traditional straddle

    plant design Recovery of liquids easily adjusted to meet natural gas pipeline

    heating value specifications

    Requires no compression

    Easily retrofitted into an existing facility

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    CO2 / METHANE

    SEPARATION IN

    PRODUCED GAS WITHHIGH CO2 CONTENT

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    Integrated DRCF / SELEXOL Process

    Two stage process for separation of CO2 andMethane

    Stage 1: DRCF for bulk removal and purification ofCO2

    Stage 2: UOP SELEXOL for final separation and

    purification of natural gas

    DRCF - Dual Refrigerant CO2 Fractionation

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    Integrated DRCF / SELEXOL Process

    SandRidge Century Plant

    65% CO2

    1120 psigDehy DRCF DeC1

    Comp.UOP

    SELEXOL

    FlashComp.

    400

    MMSCFD 585PSIG

    1200 PSIG

    140 MMSCFD

    CO2 Product260 MMSCFD

    2,000 PSIG

    SalesGas

    38 MMSCFD90% CO2

    21%CO265% CO2

    1120 psig

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    CO2 Removed

    Process

    CO2 Removed (MMSCFD)

    SelexolSingle

    Refg CO2Frac

    Dual RefgCO2 Frac

    UOP Selexol 260 -- --Single Refg CO2 Frac + UOP

    Selexol69 191 --

    Dual Refg CO2 Frac + UOPSelexol 38 -- 222

    Based upon 400 mmscfd of 65% CO2 inlet gas

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    Power Comparison

    Process

    Power Required (MW)

    Compression Pumping Total

    UOP Selexol 71.3 10.6 81.9

    Single Refg CO2 Frac +

    UOP Selexol44.1 9.3 53.4

    Dual Refg CO2 Frac +

    UOP Selexol 37.6 7.9 45.5

    Note: UOP Selexol pumping HP is for solvent circulation

    Fractionation pumping HP is for CO2 delivery

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    Summary of Potential Savings

    CAPEX - $30 40 MM

    OPEX - $39 MM / year

    (U.S. cost basis)

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    SULFUR RECOVERY

    TECHNOLOGY

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    Early SRU Experience

    Designed / built 7 SRUs for sister company in 1960s

    Little design information available

    SRUs suffered typical reliability problems Sulfur plant reliability affects profitability

    Began analyzing reliability problems in 1969

    Developed design concepts to improve reliability

    Further improvements have been on-going

    Concepts used in all Ortloff plants since 1970

    The Ortloff Corporation (1960 1985) Designed / constructed 53 SRUs

    Ortloff Engineers, Ltd. (1986 Present)

    Designed 30 SRUs constructed by others

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    Ortloff Designed SRUs

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    LICENSING/CONSULTING

    SUPPORT SERVICES

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    CONSULTING SERVICES

    PROCESS DESIGN PACKAGES FOR LICENSEDTECHNOLOGY

    TECHNOLOGY SELECTION STUDIES

    GENERAL OPERATING MANUALS

    OPERATOR TRAINING

    PLANT STARTUP

    PLANT PERFORMANCE TESTING

    PLANT TROUBLESHOOTING &DEBOTTLENECKING

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    TECHNICAL PAPERS

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    415 W. Wall, Suite 2000Midland, Texas USA 79701

    Phone : (432) 685-0277

    Fax : (432) 685-0258

    E-mail : [email protected]

    [email protected]

    Visit our web site at www ortloff com