UNITED STATESDEPARTMENT OF THE INTERIOR

GEOLOGICAL SURVEY

WATER AND STREAMBED-MATERIAL DATA, EAGLE CREEK WATERSHED, AUGUST 1980 AND OCTOBER AND DECEMBER 1982

By David J. Wangsness

Open-File Report 83-215

Prepared in cooperation with the CITY OF INDIANAPOLIS, DEPARTMENT OF PUBLIC WORKS

Indianapolis, Indiana 1983

UNITED STATES DEPARTMENT OF THE INTERIOR

JAMES G. WATT, Secretary

GEOLOGICAL SURVEY

Dallas L. Peck, Director

For additional information write to

U.S. Geological Survey 6023 Guion Road, Suite 201 Indianapolis, Indiana

Copies of this report can be purchased from:

Open-File Services Section Western Distribution Branch U.S. Geological Survey Box 25*125, Federal Center Lakewood, Colorado 80225 (Telephone: [303] 23^-5888)

CONTENTS

PageAbstract.................................................................. 1Introduction.............................................................. 1Approach.................................................................. 3Methods................................................................... 3Data...................................................................... 5Selected references....................................................... 6Appendix 1................................................................ 35Appendix 2................................................................ 39Appendix 3................................................................ ^0

ILLUSTRATIONS

PageFigure 1. Sampling sites in the Eagle Creek watershed, Indiana, 1980..... 2

2. Sampling sites in the Eagle Creek watershed, Indiana, 1982..... *J

TABLES

Page Table 1. Total concentrations of selected metals..and.nonmetals in water,

Finley Creek and Eagle Creek, October 26-27, 1982............ 82. Total concentrations of organochlorine insecticides in water,

Finley Creek and Eagle Creek, October 26-27, 1982............ 93. Total concentrations of organophosphorus insecticides in water,

Finley Creek and Eagle Creek, October 26-27, 1982............ 104. Concentrations of volatile organic compounds in water,

Finley Creek and Eagle Creek, October 26-27, 1982............ 115. Concentrations of totally recoverable acid-extractable

compounds in water, Finley Creek and Eagle Creek, October 26-27, 1982.......................................... 13

6. Concentrations of totally recoverable base-neutral-extractable compounds in water, Finley Creek and Eagle Creek, October 26-27, 1982.......................................... 14

7. Concentrations of selected metals and nonmetals on streambed materials (<63-micron fraction), Finley Creek and Eagle Creek, October 26-27, 1982................................... 17

-iii-

TABLES Continued

Page8. Concentrations of organochlorine insecticides on streambed

materials (<63-micron fraction), Finley Creek and Eagle Creek, October 26-27, 1982................................... 18

9. Concentrations of organophosphorus insecticides on streambed materials (<63-roicron fraction), Finley Creek and Eagle Creek, October 26-27, 1982................................... 19

10. Concentrations of totally recoverable acid-extractable com­ pounds on streambed materials (<63-micron fraction), Finley Creek and Eagle Creek, October 26-27, 1982............ 20

11. Concentrations of totally recoverable base-neutral-extractable compounds on streambed materials (<63-micron fraction), Finley Creek and Eagle Creek, October 26-27, 1982............ 21

12. Total concentrations of selected metals and nonmetals in water,Finley Creek and Eagle Creek, December 14, 1982.............. 24

13. Total concentrations of organochlorine insecticides in water,Finley Creek and Eagle Creek, December 14, 1982.............. 25

14. Total concentrations of organophosphorus insecticides in water,Finley Creek and Eagle Creek, December 14, 1982.............. 26

15. Concentrations of volatile organic compounds in water,Finley Creek and Eagle Creek, December 14, 1982.............. 27

16. Concentrations of totally recoverable acid-extractable com­ pounds in water, Finley Creek and Eagle Creek, December 14, 1982......................................................... 29

17. Concentrations of totally recoverable base-neutral-extractable compounds in water, Finley Creek and Eagle Creek, December 14, 1982..................................................... 30

18. Field measurements and streambed-material-size analyses, FinleyCreek and Eagle Creek, October 26-27, 1982................... 33

19. Field measurements, Finley Creek and Eagle Creek, December 14,1982......................................................... 34

-IV-

Appendix 1. Water-quality survey of Eagle Creek and tributaries upstream from Eagle Creek Reservoir, August 25-26, 1980

A. Concentrations of selected metals and nonmetals on streambed material (<63-micron fraction)

B. Concentrations of organochlorine insecticides on streambed material (<63-raicron fraction)

C. Concentrations of organophosphorus insecticides on streambed material (<63-micron fraction)

D. Concentrations of chlorinated-phenoxy and acid herbicides on streambed material (<63-roicron fraction)

E. Concentrations of nutrients on streambed material (<63-micron fraction)

F. Field measurements and strearabed-material-size analyses

G. GC/MS base-neutral scan of streambed-material (<63-micron fraction)

2. Drinking-water standards for selected inorganic and organic chemicals

3. Select organic compounds whose concentrations exceeded background concentrations in Finley and Eagle Creek, October and December, 1982

-v-

FACTORS FOR CONVERTING INCH-POUND UNITS TO THE INTERNATIONAL SYSTEM OF UNITS (SI)

Multiply inch-pound unit By To obtain SI unit

inch (in.) 25.^0 millimeter (mm)foot (ft) 0.30U8 meter (m)square foot (ft 2 ) 0.093 square meter (m 2 )cubic foot per second (ft 3 /s) 0.0283 cubic meter per second (m 3 /s)mile (mi) 1.609 kilometer (km)

A A

square mile (mi ) 2.590 square kilometer (km )

Temperature °C = 5/9 (°F-32°)

USE OF TRADE NAMES

Any use of trade names in this report is for descriptive purpose only and does not imply endorsement by the U.S. Geological Survey.

ABBREVIATIONS AND SYMBOLS

mg/L milligram per literyg/L microgram per literUg/g microgram per grammg/kg microgram per kilogram°C degree Celsius°F degree Fahrenheitft /sec cubic foot per secondUmho/cm micromho per centimeter< less thanHwy highwaySt. streetPCB polychlorinated biphenylPCN polychlorinated naphthaleneDDD 2,2 bis(p-chlorophenyl)-l,l-dichloroethaneDDE dichlorodiphenyldichloroethyleneDDT dichlorodiphenyltrichlorethaneEPA U.S. Environmental Protection Agency

-vi-

WATER AND STREAMBED-MATERIAL DATA, EAGLE CREEK WATERSHED, INDIANA, AUGUST 1980 AND OCTOBER AND DECEMBER 1982

By David J. Wangsness

ABSTRACT

Water-quality studies within the Eagle Creek watershed, Indiana, were done by the U.S. Geological Survey in August 1980, October 1982, and December 1982 in cooperation with the city of Indianapolis, Department of Public Works. A fourth study will be done in spring 1983. Streambed-material and water samples were collected from Finley and Eagle Creeks at various flow rates and were ana­ lyzed for selected metals, nonmetals, insecticides, and acid-extractable and base-neutral-extractable compounds. Water samples also were analyzed for vola­ tile organics.

This report lists all the data collected and analyzed by the U.S. Geological Survey during the 1980 and 1982 surveys but does not interpret the data.

INTRODUCTION

In late August 1980, the city of Indianapolis, Department of Public Works, participated in a cooperative water-quality study in which the U.S. Geological Survey collected samples of streambed materials to define the general water quality of the upper Eagle Creek watershed. The samples were analyzed for a wide variety of organic and inorganic constituents (appendix 1) at 11 sampling sites (fig. 1). The purpose of the study was to collect water-quality informa­ tion that could be used by the city of Indianapolis to determine if any toxic substances were entering Eagle Creek Reservoir (where they may pollute the drinking-water supply and ultimately endanger the public safety) and to aid the city in identifying areas that may be contributing these substances to the surface-water supply.

In October 1982, a second survey was made for the city of Indianapolis. The purpose of the survey was to collect water-quality information that could be used by the city to determine if the types and concentration of substances in Eagle Creek in August 1980 had changed. Because toxic substances detected in the 1980 survey entered Finley Creek from a source between sites 3 and *J

-1-

5 MILES I EXPLANATION

2 Sampling site and > designation

Figure 1. Sampling sites in the Eagle Creek watershed, Indiana, 1980.-2-

(fig. 1), the 1982 survey was done at the same sites and at two sites on Eagle Creek downstream from Finley Creek. Four sites were sampled in October 1982, three sites in December 1982, and three sites will be sampled in spring 1983.

APPROACH

Chemical constituents and properties of surface water at four sites were measured and sampled on October 26-27, 1982. Site 1, on Finley Creek at 1100 East North Road, represents background water quality upstream from the identi­ fied change in water-quality (fig. 2). Site 2, on Finley Creek at Highway 421, represents a location where water quality is believed likely to be affected. Site 3, on Eagle Creek at West 146th Street, is downstream from the mouth of Finley Creek. Site 4, on Eagle Creek at Highway 100 (86th Street), represents the quality of water before it enters Eagle Creek Reservoir.

Dissolved-oxygen concentration, specific conductance, water temperature, pH, and discharge were measured in the field at four sampling sites, and sam­ ples of suspended sediments and streambed materials were collected and returned to the laboratory for size analysis. Water and streambed-material samples were collected and analyzed for selected metals, insecticides, and acid-extractable and base-neutral-extractable compounds. Water samples also were analyzed for volatile organics.

The October 1982 survey was done during an extremely low-flow period; therefore, the samples probably represented the ground-water contribution to the streams (base flow). The samples at site 4 included treated wastewater from Zionsville as another source of water. A third survey done December 14,1982. after a rainy period, represented high flow. Site 1, the upper site in Finley Creek, was not sampled in December, and only water samples were collect­ ed at sites 2, 3> and 4 at that time. A fourth survey is planned for spring1983. during high flow. Water samples from sites 2, 3, and 4 will be collect­ ed, and the water will be analyzed for selected metals and nonmetals, insecti­ cides, volatile organics, and acid-extractable and base-neutral extractable compounds.

METHODS

Dissolved-oxygen concentration, specific conductance, water temperature, and pH were measured at each site. Discharge was measured by current meters or was estimated at low flows. All water samples were collected by dipping the sample bottle from surface to bottom at several points in the stream section to assure a well-mixed sample.

-3-

5 MILES J EXPLANATION

2 Sampling site and designation

Figure 2. Sampling sites in the Eagle Creek watershed, Indiana, 1982.-4-

Streambed-material samples for determining size distribution were collected from several points in the stream section at each sampling site. These samples were slowly dried at about 60°C and were then composited and sieved through a nest of six sieves. The sieved material was weighed, and the percent of the total sample for each size fraction was calculated. Streambed-material samples for chemical analysis were collected from pooled areas where greatest amounts of fines were likely to be deposited. The fine sediments were wet sieved through a number 230 stainless-steel sieve. The smaller than 63-micron frac­ tion that passed through the sieve was composited in glass jars, refrigerated, and allowed to settle for 24 to 48 hours. Most of the water was decanted, and the fine sediments were shipped to the Geological Survey Central Laboratory in Doraville, Ga., for analysis.

DATA

The water and streambed-material data from the 1982 studies are listed in tables 1-19. The tables also include detection limits and units of measurement. Streambed-material data from the 1980 survey are listed in ap­ pendix 1. EPA water-quality standards are listed in appendix 2, and select organic compounds whose concentrations exceeded background concentrations in Finley and Eagle Creeks in October and December 1982 are listed in appendix 3.

-5-

SELECTED REFERENCES

U.S. Environmental Protection Agency, 1975, National interim primary drinking water regulations: Federal Register, v. 40, no. 248, p. 59566-59588.

____1979a, National secondary drinking water regulations: Federal Register,v. 44, no. 140, p. 52195-52202.

____1979&, National interim primary drinking water regualtions; central of trihalomethanes in drinking water: Federal Register, v. 44, no. 231, p. 68624-68707.

Windholz, Martha, ed., 1976, The Merck index: Rahway, N.J., Merck and Co., Inc., 1,900 p.

-6-

Tables 1-19

-7-

Table

1. Total conc

entr

atio

ns of

se

lect

ed metals and

nonm

etals

in water, Finley Creek

and

Eagle

Creek, Oc

tobe

r 26

-27,

1982

Finley Creek

at

Finl

ey Cr

eek

at

Eagl

e Creek

at

Eagle

Creek

at 100

1100 Ea

st Ro

ad

Highway

421

near

West 14

6 St.

near

North

Road ne

arne

ar Zionsville

Zionsville

Zionsville

Indianapolis

Constituent

1 Un

its

(site

1)

(site

2)

(sit

e 3)

(s

ite

4)

Alum

inum

2

Arse

nic

3Ba

rium

^

Cadm

ium

3Ch

romi

um 3

Copp

er 3

Cyanide

5i Iron 5

°°T

^ 3

i Le

ad 3

Mang

anes

e 5

Mercury

5Se

leni

um 3

Silver 3

Zinc

5

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Mg/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

803

200 <1 <!

9 <.01

530 6

110

.4<1 <1 10

300 6

400 <1 <! 9 <.

013,600 5

280

.4<13 10

480 4

200 <1 <! 12<.01

890 6

120

.1<1 <1 10

120 4

200 1 <1 19 <.

0128

0 6 20

.1<1 <1 10

1 All

constituents ex

cept

al

umin

um,

bari

um,

iron,

and

mang

anes

e are

EPA

prio

rity

pollutants.

2 De

tect

ion

limit:

10 Ug/L.

3 De

tect

ion

limi

t:

1 Ug/L.

^ De

tect

ion

limit:

100

Ug/L.

5 De

tect

ion

limi

t:

0.1

Ug/L.

Tabl

e 2. Total concentrations of o

rgan

ochl

orin

e in

sect

icid

es in

water,

Finl

ey Creek

and

Eagle

Cree

k, Oc

tobe

r 26-27, 19

82

Finl

ey Creek

at

Finl

ey Cr

eek

at

Eagl

e Creek

at

Eagle

Creek

at 100

1100 Ea

st Ro

ad

High

way

421

near

We

st 146

St.

near

North

Road

ne

arne

ar Zionsville

Zionsville

Zionsville

Indi

anap

olis

Constituent

* Unit

s (site

1)

(site

2)

(sit

e 3)

(sit

e 4)

Aldrin 2

Ug/L

<.01

<.01

<.

01

<.01

Chlo

rdan

e 3

Ug/L

<.l

<.l

<.l

<.l

DDD

2 Ug/L

<.01

<.

01

<.01

<.

01DD

E 2

Ug/L

<.01

<.01

<.

01

<.01

DDT

2 Ug/L

<.

01

<.01

<.

01

<.01

Diel

drin

2

Ug/L

Endo

sulf

an 2

Ug/L

i Endrin 2

ug/L

i Heptachlor epoxide

2 Ug

/LHept

achl

or 2

Ug/L

Lind

ane

2 Ug

/LMethoxychlor

2

Ug/L

Mire

x 2

Ug/L

PCB

(total)

3 Ug/L

PCN

(tot

al)

3 Ug

/L

Pert

hane

3

Ug/L

Toxaphene

^ Ug

/L

-1- Al

l co

nstitu

ents

ex

cept

me

thox

ychlor,

mire

x, PC

N, an

d pe

rtha

ne ar

e EP

A pr

iority po

llut

ants

.2 De

tect

ion

limit:

0.01

Ug/L.

3 De

tect

ion

limit:

0.1

Ug/L.

^ De

tect

ion

limit:

1 yg/L.

Tabl

e 3» Total concen

trat

ions

of

or

gano

phos

phor

us in

sect

icid

es in

wa

ter,

Fi

nley

Cr

eek

and

Eagle

Creek, October

26-27, 1982

Finley Creek

at

Finl

ey Cr

eek

at

Eagl

e Creek

at

Eagl

e Creek

at 10

01100 Ea

st Road

Highway

421

near

West

146

St.

near

North

Road

ne

arne

ar Zionsville

Zion

svil

le

Zionsville

Indianapolis

Constituent

! Unit

s (site

1)

(site

2)

(sit

e 3)

(s

ite

4)

Diazinon

Ethion

Mala

thio

nMethyl parathion

Meth

yl tr

ithi

on

Parathion

Trithion

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

<.01

.09

<.01

<.01

<.01

<.01

<.01

<.01

o 1 n

-

'

limi

t:

0.01

Ug

/L.

Table

4. Concentrations

of v

olat

ile

orga

nic

compounds

in water, Finley Cr

eek

and

Eagle

Creek, October

26-2

7, 19

82

Finl

ey Creek

at

Finl

ey Creek

at

Eagl

e Cr

eek

at

Eagl

e Creek

at 10

011

00 Ea

st Ro

ad

High

way

421

near

West

14

6 St

. near

Nort

h Ro

ad near

near Zi

onsv

ille

Zionsville

Zionsville

Indianapolis

Cons

titu

ent

l Un

its

(sit

e 1)

(s

ite

2)

(site

3)

(site

4)

Benzene

Ug/L

<1

<1

<1

<1Br

omof

orm

Ug/L

<1

<1

<1

<1Carbon te

trac

hlor

ide

Ug/L

<1

<1

<1

<1Ch

loro

benz

ene

Ug/L

<1

<1

<1

<1Chlorodibromomethane

Ug/L

<1

<1

<1

<1

Chlo

roet

hane

Ug/L

<1

<1

<1

<12-

Chlo

roet

hyl

vinyl

ether

Ug/L

<1

<1

<1

<1i Ch

loro

form

Ug/L

<1

<1

<1

<1I^

Dich

loro

bromomethane

Ug/L

<1

<1

<1

<1Dichlorodifluo

rome

than

e Ug/L

<1

<1

<1

<1

1.1-

Dich

loroethane

ug/L

<1

220

<1

<11.

2-Di

chlo

roet

hane

Ug/L

<1

<1

<1

<11.

1-Di

chlo

roet

hyle

ne

Ug/L

<1

<1

<1

<11.2-trans-Dichloroethylene

Ug/L

<1

1,000

<1

<11.

2-Di

chlo

ropr

opan

e Ug

/L

<1

<1

<1

<1

1.3-

Dich

loro

prop

ane

Ug/L

<1

<1

<1

<1Ethylbenzene

Ug/L

<1

<1

<1

<1Me

thylbromid

e Ug

/L

<1

<1

<1

<1Me

thyl

ene

chloride

Ug/L

<1

<1

<1

<1

1,1,2,2-Tetr

achl

oroe

than

e Ug/L

<1

<1

<1

<1

Table

4. C

once

ntrations

of volatile

orga

nic

compounds

in wa

ter,

Finley Creek

and

Eagl

e Creek, Oc

tobe

r 26

-27, 1982 (Contin

ued)

Finl

ey Creek

at

Finl

ey Creek

at

Eagl

e Creek

at

Eagl

e Cr

eek

at 10

011

00 East Road

Highway

421

near

West 1^

6 St

. near

Nort

h Road ne

arnear Zionsville

Zionsville

Zion

svil

le

Indi

anap

olis

Constituen

t l

Units

(site

1)

(site

2)

(sit

e 3)

(s

ite

4)

Tetrachloroe

thyl

ene

Tolu

ene

1,1 ,1-Trich

loro

etha

ne1 ,1,2-Trich

loro

e th

ane

Trichloroeth

ylen

e

Tric

hlor

oflu

orom

e th

ane

Viny

l chloride

Ug/L

5Ug

/L

3Ug

/L

<1Ug/L

<1Ug/L

<1

Ug/L

<1Ug

/L

<1

37

<1

<17

<1

<1510

<1

<1<1

<1

<1670

<1

<1

<1

<1

<1<1

<1

<1

ro1

Dete

ctio

n li

mit:

1

Ug/L

. All

cons

titu

ents

ar

e EPA

prio

rity

pollutants,

Tabl

e 5. Concentrations

of to

tall

y recoverable

acid

-ext

ract

able

co

mpou

nds

in wa

ter,

Finley Cr

eek

and

Eagle

Cree

k, October

26-2

7, 19

82

Finl

ey Creek

at

Finley Cr

eek

at

Eagl

e Creek

at

Eagl

e Cr

eek

at 10

01100 Ea

st Ro

ad

Highway

421

near

We

st 14

6 St.

near

North

Road

near

near Zionsville

Zionsville

Zionsville

Indianapolis

Constituent

1 Unit

s (site

1)

(sit

e 2)

(site

3)

(sit

e 4)

4-Ch

loro

-3-m

ethy

lphe

nol

Ug/L

<1

<1

<1

<12-

Chlo

roph

enol

Ug

/L

<1

<1

<1

<12,4-Dichlorophenol

Ug/L

<1

<1

<1

<12,

4-Di

meth

ylph

enol

ug/L

<1

12

<1

<1

4,6-

Dini

tro-

2-me

thyl

phen

ol

Ug/L

<1

<1

<1

<1

2,4-

Dini

trop

heno

l Ug/L

<1

<1

<1

<1

2-Ni

trop

heno

l Ug

/L

<1

<1

<1

<1i 4-

Nitr

ophe

nol

Ug/L

<1

<1

<1

<1coPentachlorophenol

Ug/L

<1

<1

<1

<1

Phenol

Ug/L

<1

2,20

0 <1

<1

2,4,6-Trichl

orophenol

Ug/L

<1

<1

<1

<1

1 De

tect

ion

limit:

1 ug/L.

All

cons

titu

ents

ex

cept

4-

chlo

ro-3

-met

hylp

heno

l an

d 4,

6-di

nitr

o-2-

meth

ylph

enol

ar

e EPA

priority pollutants.

Tabl

e 6.

Con

cent

rati

ons

of to

tall

y re

cove

rabl

e ba

se-n

eutr

al-e

xtra

ctab

le co

mpou

nds

in water,

Finl

ey Cr

eek

and

Eagle

Creek, October

26-27, 1982

Finl

ey Cr

eek

at

Finl

ey Cr

eek

at

Eagl

e Cr

eek

at

Eagle

Creek

at 100

1100 East Ro

ad

Highway

421

near

West 146

St.

near

North

Road near

near Zionsville

Zionsville

Zionsville

Indi

anap

olis

Constituent

1 Units

(sit

e 1)

(site

2)

(sit

e 3)

(sit

e 4)

Acen

apht

hene

Ug/L

<1

<1

<1

<1

Acen

apht

hyle

ne

Ug/L

<1

<1

<1

<1Anthracene

Ug/L

<1

<1

<1

<1Benzidine

Ug/L

<1

<1

<1

<1

Benzo

(a)

anthracene

Ug/L

<1

<1

<1

<1

Benzo

(b)

fluo

rant

hene

Ug/L

<1

<1

<1

<1Benzo

(k)

fluoranthene

Ug/L

<1

<1

<1

<1j^ Ben

zo (g,h,i)

perylene

Ug/L

<1

<1

<1

<1-P>

Benzo (a

) py

rene

Ug/L

<1

<1

<1

<14-

Brom

ophe

nyl

phenyl et

her

Ug/L

<1

<1

<1

<1

Butyl

benz

yl ph

thal

ate

Ug/L

<1

11

<1

<1

bis

(2-Chloroethoxy)

methane

Ug/L

<1

<1

<1

<1bis

(2-Chloroethyl)

ethe

r ug

/L

<1

43

<1

<1

bis

(2-C

hlor

oiso

prop

yl)

ether

Ug/L

<1

<1

<1

<1

2-Chloronaphthalene

Ug/L

<1

<1

<1

<1

4-Ch

loro

phen

yl phenyl et

her

Ug/L

<1

<1

<1

<1

Chrysene

Ug/L

<1

<1

<1

<1Di

benz

(a,h)

anthracene

Ug/L

<1

<1

<1

<11.2-Dichlorobenzene

Ug/L

<1

57

<1

<11.3-Dichlorobenzene

Ug/L

<1

<1

<1

<1

Tabl

e 6. Concentrations

of totally

reco

vera

ble

base

-neu

tral

-ext

ract

able

co

mpou

nds

in w

ater

, Fi

nley

Creek

and

Eagl

e Creek, Oc

tobe

r 26-27, 19

82 (

Cont

inue

d)

Cons

titu

ent

Unit

s

Finley Creek

at

1100

Ea

st Ro

ad

near

Zionsville

(sit

e 1)

Finl

ey Cr

eek

at

Highway

421

near

Zionsville

(sit

e 2)

Eagl

e Creek

at

West

14

6 St.

near

Zion

svil

le

(sit

e 3)

Eagl

e Creek

at 100

North

Road

ne

ar

Indianapolis

(sit

e 4)

1,4-Dichlorobenzene

Ug/L

3,3'-Dichlorobenzidine

Ug/L

Diet

hyl

phthalate

Ug/L

Dimethyl phth

alat

e Ug

/LDi

-n-butyl ph

thal

ate

Ug/L

2,4-

Dini

trot

olue

ne

Ug/L

2,6-Dinitrotoluene

Ug/L

i Di

-n-octyl ph

thal

ate

Ug/L

en bis

(2-Ethylhexyl)

phth

alat

e Ug/L

Fluoranthene

Ug/L

Fluorene

Ug/L

Hexa

chlo

robe

nzen

e Ug

/LHexachlorobutadiene

Ug/L

Hexachlorocyclopentadiene

Ug/L

Hexa

chlo

roet

hane

Ug/L

Inde

no (1

,2,3

) pyrene

ug/L

Isophorone

Ug/L

Napt

hale

ne

Ug/L

Nitrobenzene

Ug/L

n-Nitrosodimethylamine

Ug/L

616 27 13 360

Tabl

e 6. Concentration of

to

tall

y recoverable

base-neutral-extractable compounds

in water, Finley Cr

eek

and

Eagl

e Creek, Oc

tobe

r 26-27, 1982 (Contin

ued)

Finl

ey Cr

eek

at

Finl

ey Cr

eek

at

Eagle

Cree

k at

Eagle

Creek

at 100

1100

East Ro

ad

High

way

421

near

We

st 14

6 St.

near

North

Road

near

near

Zionsville

Zionsville

Zionsville

Indi

anap

olis

Cons

titu

ent

l Un

its

(site

1)

(site

2)

(sit

e 3)

(sit

e 4)

n-Ni

tros

odiphenylamine

Ug/L

<1

<1

<1

<1

n-Ni

tros

odi-

n-pr

opyl

amin

e Ug/L

<1

<1

<1

<1

Phen

anth

rene

Ug/L

<1

<1

<1

<1

Pyre

ne

Ug/L

<1

<1

<1

<1

2,3,7,8-Tetrachlorodibenzo-

p-di

oxin

Ug/L

<1

<1

<1

<1

1,2,

4-Tr

ichl

orob

enze

ne

Ug/L

<1

<1

<1

<1i , t

_____________ ___________________________________._________________________________________________________________

1 De

tect

ion

limit:

1 Ug

/L.

All

cons

titu

ents

ar

e EPA

prio

rity

pollutants.

Tabl

e 7. Concentrations of

se

lect

ed me

tals

and

nonm

etal

s on

streambed

mate

rial

s (<63-micron

fraction), Finley Creek

and

Eagl

e Cr

eek,

Octo

ber

26-27, 19

82

Finl

ey Cr

eek

at

Finl

ey Creek

at

Eagl

e Cr

eek

at

Eagl

e Creek

at 10

01100 Ea

st Road

High

way

421

near

West

14

6 St

. near

North

Road

ne

arne

ar Zionsville

Zionsville

Zionsville

Indi

anap

olis

Constituen

t l

Unit

s (site

1)

(site

2)

(sit

e 3)

(sit

e 4)

Aluminum 2

Arse

nic

3Ba

rium

2

Cadmium

3Chromium 3

Copp

er 3

Cyan

ide

3Ir

on 3

Lead

2

Mang

anes

e 3

Merc

ury

**Se

leni

um 3

Silver 5

Zinc

3

Ug/g

Ug/g

Ug/g

Ug/g

Ug/g

Ug/g

Mg/L

Ug/g

Ug/g

Ug/g

ug/g

ug/g

Ug/g

Ug/g

1,40

0 112

0 1 4 11 <13,000 20 330 <.

01<1 <1 24

940 1

100 2 4 21 <1

3,100

120

300 <.

01<1 <1 40

890 <1 70 2 3 8 <1

1,70

0 30 220 <.

01<1 <1 14

1,300 <1 160 2 4

15 <12,700 30 580 <.

01<1 <1 26

1 Al

l constituents ex

cept

al

umin

um,

bari

um,

iron

, and

mang

anes

e are

EPA

priority pollutants.

2 De

tect

ion

limi

t:

10 Ug

/L.

3 De

tect

ion

limit:

1.0

Ug/L.

^ De

tect

ion

limit:

0.01

Ug/L.

5 De

tect

ion

limit:

0.1

Ug/L.

Tabl

e 8. Concentrations

of o

rgan

ochl

orin

e in

sect

icid

es on

st

ream

bed

mate

rial

s (<

63-m

icro

n fr

acti

on),

Finley Creek

and

Eagle

Cree

k, October

26-2

7, 1982

Constituent

Units

Finl

ey Cr

eek

at

1100

East Road

near

Zi

onsv

ille

(site

1)

Finl

ey Cr

eek

at

High

way

421

near

Zionsville

(site

2)

Eagl

e Creek

at

West 146

St.

near

Zionsville

(sit

e 3)

Eagl

e Creek

at 100

North

Road

ne

ar

Indianapolis

(sit

e 4)

Aldrin 2

Chlo

rdan

e 3

DDD

2DD

E 2

DOT

2

Dieldrin 2

Endosulfan 2

i En

drin

2

oo Heptachlor

epox

ide

2Heptachlor 2

Lindane

2Methoxychlor

2

Mi rex 2

PCB

(total)

3PCN

(total)

3

Perthane 3

Toxaphene

^

Ug/k

g <0

.1

<0.1

1.

8Ug

/kg

12

13

12Ug/kg

0.7

3.3

0.5

Ug/k

g <0

.1

<0.1

<0

.1Ug

/kg

2.1

0.5

0.4

Ug/k

g 5.3

5.9

5.2

Ug/kg

<0.1

<0.1

<0

.1Ug

/kg

<0.1

<0

.1

<0.1

Ug/k

g <0

.1

<0.1

<0.1

Ug/kg

<0.1

<0.1

<0

.1

Ug/kg

<0.1

<0.1

<0.1

Ug/kg

<0.1

<0.1

<0

.1Ug/k

g <0

.1

<0.1

<0.1

Ug/kg

13

72

5Ug/kg

<1

<1

<1

Ug/kg

<1

<1

<1Ug/k

g <1

0 <10

<10

<0.1 7 0.4

<0.1 0.2

4.6

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1 4 <1 <1 <1

0

1 Al

l constituents ex

cept

methoxychlor,

mire

x, PC

N, and

perthane ar

e EPA

priority pollutants.

2 De

tect

ion

limit:

0.1

ug/kg.

3 De

tect

ion

limi

t:

1.0

ug/kg.

** De

tect

ion

limit:

10 ug/kg.

Tabl

e 9.

Con

cent

rati

ons

of o

rgan

opho

spho

rus

inse

ctic

ides

on

streambed

mate

rial

(<

6?-m

icro

n fr

acti

on),

Finley Cr

eek

and

Eagl

e Creek, October

26-27,

1982

Constituent

Units

Finl

ey Creek

at

1100

East Road

near Zi

onsv

ille

(s

ite

1)

Finley Cr

eek

at

High

way

421

near

Zionsville

(site

?)

Eagl

e Creek

at

West 14

6 St

. ne

ar

Zionsville

(sit

e 3)

Eagl

e Creek

at 10

0 North

Road

ne

ar

Indi

anap

olis

(s

ite

4)

Diaz

inon

Ethi

onMa

lath

ion

Meth

ylpa

rath

ion

Meth

yltr

ithi

on

Parathion

Trit

hion

Ug/

kg

Ug/

kg

Ug/

kg

Ug/

kg

Ug/

kg

Ug/

kg

Ug/

kg

Dete

ctio

n li

mit:

0.1

ug/kg.

Table

10.--Concentrations

of to

tall

y re

cove

rabl

e acid-extractable compounds

on streambed

materials

(<63

-mic

ron

fraction), Finley Creek

and

Eagle

Cree

k, Octo

ber

26-2

7, 19

82

Constituen

tUnits

Finl

ey Cr

eek

at

1100 Ea

st Ro

ad

near Zi

onsv

ille

(site

1)

Finl

ey Cr

eek

at

Highway

421

near

Zionsville

(sit

e 2)

Eagl

e Cr

eek

at

West

14

6 St.

near

Zionsville

(site

3)

Eagl

e Creek

at 10

0 North

Road

near

Indianapolis

(sit

e 4)

1 ro

o

4- Chl

oro-

3-me

thy

1 phenol

2-Ch

loro

phen

ol2, 4-D

ichl

orop

heno

l2

, 4-Dimethyl phenol

4 , 6-D

init

ro-2

-met

hyl phenol

2, 4-Dinitro phenol

2-Ni

trop

heno

l4-Nitro ph

enol

Pen ta

chlo

ro phe

nol

Phenol

2,4,

6-T

rich

loro

phen

ol

Ug/k

gUg/k

gUg

/kg

VJg/

kgUg

/kg

VJg/

kgUg/k

gUg/k

gUg

/kg

Ug/k

g

Ug/k

g

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

Dete

ctio

n limit:

20 ug

/kg.

All

constituents except 4-

chlo

ro-3

-met

hylp

heno

l an

d 4,

6-di

nitr

o-2-

meth

ylph

enol

ar

e EPA

priority pollutants.

Tabl

e 11.--Concentrations

of to

tall

y re

cove

rabl

e base-neutral-extract

able

co

mpou

nds

on streambed

materials

(<63

-mic

ron

fraction), Finley Creek

and

Eagl

e Creek, October

26-2

7, 19

82

Constituent

Units

Finl

ey Cr

eek

at

1100 Ea

st Ro

ad

near Zionsville

(sit

e 1)

Finl

ey Cr

eek

at

High

way

421

near

Zionsville

(site

2)

Eagl

e Creek

at

West

14

6 St.

near

Zionsville

(sit

e 3)

Eagl

e Creek

at 10

0 North

Road

ne

ar

Indi

anap

olis

(s

ite

4)

Acenaphthene

Acenaphthylene

Anthracene

Benzidine

Benzo

(a)

anth

race

ne

Benz

o (b

) fluoranthene

Benz

o (k

) fluoranthene

Benz

o (g,h,i)

perylene

Benzo

(a)

pyrene

4 -Br

omo ph

enyl

phenyl et

her

Buty

l be

nzyl

phthalate

bis

(2-Chloroethoxy

)methane

bis

(2-Chloroethyl )

ethe

rbis

(2-Chloroisopropyl )

ether

2-Chloronaphthalene

4-Ch

loro

phen

yl phenyl et

her

Chry

sene

Dibe

nz (a,h)

anth

race

ne1

, 2-D

ichl

orob

enze

ne1

, 3-D

ichl

orob

enze

ne

Ug/k

gUg/k

gUg/k

gUg/k

gUg

/kg

Ug/kg

Ug/k

gUg/kg

Ug/kg

Ug/kg

Ug/k

g

Ug/kg

Ug/k

g

Ug/kg

Ug/kg

Ug/k

gUg/k

gUg/k

gUg/kg

Ug/k

g

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<?0

<20

<20

<20

630

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

Table

11.-

-Con

cent

rati

ons

of totally

reco

vera

ble

base-neutral-extractable

co

mpou

nds

on st

ream

bed

materials

(<63

-mic

ron

fraction), Fi

nley

Cr

eek

and

Eagl

e Cr

eek,

October

26-2

7, 1982 (Continued)

Cons

titu

ent

Units

Finley Creek

at

1100

Ea

st Ro

ad

near

Zi

onsv

ille

(s

ite

1)

Finl

ey Creek

at

Highway

M21

near

Zionsville

(sit

e 2)

Eagl

e Cr

eek

at

West

146

St.

near

Zionsville

(sit

e 3)

Eagl

e Creek

at 10

0 North

Road

ne

ar

Indi

anap

olis

(s

ite

4)

1 , M-Dichlorobenzene

3, 3

! -Dichlo

robe

nzid

ine

Diethyl

phthalate

Dimethyl phthalate

Di-n-butyl phthalate

2, 4-Dinitrotoluene

2, 6-Dinitro

tol

uene

i Di-n-octylph

thal

ate

S bis

(2-E

thyl

hexy

l)phthalate

Fluoranthene

Fluo

rene

Hexa

chlo

robe

nzen

eHexachlorobutadiene

Hexachlorocy

clop

enta

dien

eHexachloroe th

ane

Inde

no (1,2,3)

pyre

neIs

opho

rone

Naphthalene

Nitrobenzene

n-Nitrosodim

ethy

lami

ne

Ug/kg

Ug/kg

Ug/k

gUg

/kg

Ug/kg

Ug/kg

Ug/kg

Ug/kg

Ug/k

gUg

/kg

Ug/k

gUg

/kg

Ug/kg

Ug/kg

Ug/k

g

Ug/kg

Ug/k

gUg

/kg

Ug/kg

Ug/kg

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

Table

11. Concentrations of

totally

recoverable

base-neutral-extractable compounds

on streambed

materials

(<63

-mic

ron

fraction), Fi

nley

Creek

and

Eagl

e Creek, October

26-2

7, 1982 (Continued)

Cons

titu

ent

Units

Finl

ey Creek

at11

00 Ea

st Road

near

Zi

onsv

ille

(sit

e 1)

Finl

ey Creek

at

High

way

421

near

Zionsville

(sit

e 2)

Eagl

e Creek

at

West 146

St.

near

Zi

onsv

ille

.

(sit

e 3)

Eagl

e Creek

at 100

Nort

h Road near

Indianapolis

(sit

e 4)

n-Nitrosodip

heny

lami

nen-Nitrosodi-n-propylamine

Phen

anth

rene

Pyrene

2, 3,7,8-Tetrachlorodibenzo-

p-di

oxin

1, 2,4-Trich

loro

benz

ene

Ug/kg

Ug/kg

Ug/kg

Ug/kg

Ug/kg

Ug/kg

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

<20

CO

Detection

limi

t:

20 Ug

/kg.

Al

l constituents ar

e EPA

priority po

llut

ants

.

Tabl

e 12. Total concen

trat

ions

of se

lect

ed me

tals

and

nonm

etal

s in

water, Finley Creek

and

Eagl

e Creek, De

cemb

er 14

, 19

82

Finley Creek

at

Eagl

e Creek

at

Eagl

e Creek

at 100

Highway

421

near

We

st 14

6 St

. near

North

Road

ne

arZionsville

Zionsville

Indi

anap

olis

Cons

titu

ent

1 Units

(site

2)

(site

3)

(sit

e 4)

Alum

inum

2

Arse

nic

3Barium ^

Cadm

ium

3Ch

romi

um 3

Copper 3

Cyan

ide

2i

Iron

2

K L

ead

3Ma

ngan

ese

2

Mercury

5Selenium 3

Silv

er 3

Zinc

2

yg/L

yg/L

yg/L

yg/L

yg/L

yg/L

Mg/L

yg/L

yg/L

yg/L

yg/L

yg/L

yg/L

yg/L

100 3

100 1 1 8 <.

01420 5 80 <0.1 2

<1 30

100 2

200 <1 <1

4 <.01

340 3 70 <0.1 2 2 20

100 2

300 <1 <!

4 <.01

250 2 40 <0.1 2 1 10

1 All

cons

titu

ents

ex

cept

aluminum,

bari

um,

iron

, an

d ma

ngan

ese

are

EPA

prio

rity

po

llut

ants

.2 De

tect

ion

limi

t:

10 yg/L.

3 De

tect

ion

limi

t:

1 yg

/L.

^ De

tect

ion

limit:

100

yg/L.

5 De

tect

ion

limi

t:

0.1

yg/L.

Table 13. Total

concentrations of

org

anoc

hlor

ine

inse

ctic

ides in water, Finley Cr

eek

and

Eagl

e Creek, De

cemb

er 14

, 1982

Finl

ey Creek

at

Eagle

Cree

k at

Eagle

Creek

at 10

0Highway

421

near

We

st 14

6 St

. ne

ar

North

Road ne

arZionsville

Zionsville

Indianapolis

Cons

titu

ent

l Un

its

(sit

e 2)

(site

3)

(site

4)

Aldrin 2

Ug/L

<.01

<.01

<.01

Chlo

rdan

e 3

Ug/L

<.l

<.l

<.l

DDD

2 Ug

/L

<.01

<.01

<.01

DDE

2 Ug/L

<.01

<.01

<.01

DDT

2 Ug

/L

<.01

<.

01

<.01

Diel

drin

2

Ug/L

<.01

<.01

<.01

Endo

sulf

an 2

Ug/L

<.

01

<.01

<.01

i En

drin

2

Ug/L

<.01

<.

01

<.01

en Heptachlor epoxide

2 Ug

/L

<.01

<.01

<.01

1 He

ptac

hlor

2

Ug/L

<.

01

<.01

<.01

Lindane

2 Ug

/L

<.01

<.

01

<.01

Methoxychlor 2

Ug/L

<.01

<.01

<.01

Mirex

2 Ug/L

<.01

<.

01

<.01

PCB

(total)

3 Ug/L

<.

l <.

l <.

lPCN

(total)

3 ug

/L

<.l

<.l

<.l

Pert

hane

3

Ug/L

<.l

<.l

<.l

Toxaphene

^ Ug/L

<1

<1

<1

1 Al

l co

nsti

tuen

ts ex

cept

me

thox

ychlor,

mire

x, PC

N, an

d pe

rtha

ne ar

e EP

A priority pollutants.

2 De

tect

ion

limi

t:

0.01 Ug

/L.

3 De

tect

ion

limi

t:

0.1

Ug/L

.^ Detection

limi

t:

1 Ug

/L.

ro

cr>

Table 14

. To

tal

conc

entrations of

organophosphorus

inse

ctic

ides in wa

ter,

Finley Cr

eek

and

Eagle

Creek, December 14,

1982

Finl

ey Cr

eek

at

Eagle

Cree

k at

Ea

gle

Cree

k at 10

0Highway

421

near

West 14

6 St

. ne

ar

North

Road ne

arZi

onsv

ille

Zion

svil

le

Indianapolis

Cons

titu

ent

1 Un

its

(sit

e 2)

(sit

e 3)

(sit

e 4)

Diaz

inon

Ug/L

<.01

<.01

<.01

Ethion

Ug/L

<.01

<.01

<.

01Mala

thio

n Ug/L

<.01

<.01

<.01

Methyl pa

rathion

Ug/L

<.01

<.01

<.01

Meth

yl tr

ithi

on

Ug/L

<.

01

<.01

<.01

Para

thio

n Ug/L

<.01

<.01

<.01

Trit

hion

Ug/L

<.01

<.01

<.01

1 Detection

limit:

0.01

Ug

/L.

Tabl

e 15. Concentrations of volatile

orga

nic

comp

ound

s in

wat

er,

Finl

ey Cr

eek

and

Eagl

e Creek, December 14,

1982

Fin

ley Creek

at

Eagle

Creek

at

Eagl

e Creek

at 100

Highway 421 ne

ar

West

146

St.

near

North

Road

near

Zionsville

Zionsville

Indi

anap

olis

Constituent

l Un

its

(sit

e 2)

(sit

e 3)

(sit

e 4)

Benz

ene

Ug/L

<1

<1

<1Br

omof

orm

Ug/L

<1

<1

<1Ca

rbon

te

trac

hlor

ide

Ug/L

<1

<1

<1Ch

loro

benz

ene

Ug/L

<1

<1

<1Ch

loro

dibr

omom

etha

ne

Ug/L

<1

<1

<1

Chloroethane

Ug/L

<1

<1

<12-

Chlo

roet

hyl

viny

l et

her

ug/L

<1

<1

<1Chloroform

Ug/L

<1

<1

<1

9

Dichlorobromomethane

Ug/L

<1

<1

<1Dichlorodifl

uoromethane

Ug/L

<1

<1

<1

1.1-

Dich

loro

ethane

Ug/L

<1

<1

<11.2-Dichloroethane

Ug/L

<1

<1

<1

1.1-Dichloroethylene

Ug/L

140

<1

<11.2-trans-Dichloroethylene

Ug/L

9

<1

<11.2-Dichloropropane

Ug/L

<1

<1

<1

1.3-Dichloropropane

Ug/L

<1

<1

<1Et

hylb

enze

ne

Ug/L

<1

<1

<1Methylbromide

Ug/L

<1

<1

<1Methylene

chlo

ride

Ug

/L

<1

<1

<11,1,2,2-Tetrachloroethane

Ug/L

<1

<1

<1

i ro oo

Tabl

e 15

. Co

ncen

trat

ions

of v

olat

ile

orga

nic

compounds

in wa

ter,

Fi

nley

Cr

eek

and

Eagle

Creek, December 14,

1982 (Continued)

Finley Cr

eek

at

Eagl

e Cr

eek

at

Eagl

e Creek

at 10

0Highway

421

near

West

146

St.

near

North

Road ne

arZionsville

Zionsville

Indianapolis

Cons

titu

ent

1 Units

(sit

e 2)

(site

3)

(sit

e 4)

Tetrachloroethylene

Toluene

1 , 1

, 1-

Tric

hlor

oeth

ane

1,1,

2-T

rich

loro

etha

neTr

ichl

oroe

thyl

ene

Trichlorofluorome th

ane

Viny

l chloride

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

<1

1 <1

2 2

<1<1

<1

<1<1

<1

<123

2

<1

<1

<1

<1<1

<1

<1

1 De

tect

ion

limi

t:

1 ug/L.

All

cons

titu

ents

ar

e EPA

priority pollutants

Table

16. Concentrat

ions

of

to

tall

y re

cove

rabl

e ac

id-e

xtra

ctable

co

mpou

nds

in w

ater

,Fi

nley

Cr

eek

and

Eagl

e Creek, December 14

, 19

82

Finl

ey Creek

at

Eagl

e Creek

at

Eagl

e Cr

eek

at 10

0Highway

421

near

West 14

6 St

. near

Nort

h Ro

ad near

Zion

svil

le

Zionsville

Indi

anap

olis

Cons

titu

ent

l Units

(sit

e 2)

(site

3)

(site

4)

4-Ch

loro

-3-met

hylp

heno

l Ug

/L

<1

<1

<12-

Chlo

roph

enol

Ug/L

<1

<1

<12,

4-Di

chlo

roph

enol

Ug/L

<1

<1

<12,

4-Di

meth

ylph

enol

Ug

/L

<1

<1

<14,

6-Di

nitr

o-2-

meth

ylph

enol

ug/L

<1

<1

<1

2,4-

Dini

trophenol

Ug/L

<1

<1

<12-

Nitr

ophe

nol

Ug/L

<1

<1

<1i 4-

Nitr

ophe

nol

Ug/L

<1

<1

<1vo Pen

tach

lorophenol

Ug/L

<1

<1

<1Ph

enol

Ug/L

<1

<1

<1

2,4,

6-Tr

ichlorophenol

Ug/L

<1

<1

<1

1 De

tect

ion

limi

t:

1 ug

/L.

All

cons

titu

ents

ex

cept

4-

chloro-3-methylphenol

and

4,6-

dini

tro-

2-me

thyl

phen

ol

are

EPA

prio

rity

pollutants.

Table

17.

Conc

entr

atio

ns of totally

recoverable

base

-neu

tral

-ext

ract

able

co

mpou

nds

in wa

ter,

Finl

ey Cr

eek

and

Eagl

e Creek, December 1M

, 1982

Finl

ey Creek

at

Eagle

Creek

at

Eagl

e Creek

at 10

0Hi

ghwa

y M21

near

West 1U

6 St.

near

North

Road

ne

arZionsville

Zionsville

Indi

anap

olis

Cons

titu

ent

1 Units

(sit

e 2)

(site

3)

(sit

e M)

Acenaphthene

Ug/L

<1

<1

<1Acenaphthylene

Ug/L

<1

<1

<1Anthracene

Ug/L

<1

<1

<1

Benzidine

Ug/L

<1

<1

<1Be

nzo

(a)

anthracene

Ug/L

<1

<1

<1

Benz

o (b)

fluo

rant

hene

Ug

/L

<1

<1

<1Benzo

(k)

fluoranthene

Ug/L

<1

<1

<1i Benzo

(g,h

,i)

pery

lene

Ug

/L

<1

<1

<1o B

enzo (a)

pyre

ne

Ug/L

<1

<1

<14-

Brom

ophe

nyl

phen

yl et

her

Ug/L

<1

<1

<1

Buty

l benzyl phthalate

Ug/L

<1

<1

<1

bis

(2-C

hlor

oeth

oxy)

meth

ane

Ug/L

<1

<1

<1bi

s (2-Chloroethyl)

ether

ug/L

<1

<1

<1

bi

s (2-Chloroisopropyl)

ethe

r Ug

/L

<1

<1

<12-Chloronaphthalene

Ug/L

<1

<1

''I

iJ-C

hlor

ophe

nyl

phen

yl et

her

Ug/L

<1

<1

<1Chrysene

Ug/L

<1

<1

<1Dibenz (a,h)

anth

race

ne

Ug/L

<1

<1

<11.2-Dichloro

benzene

Ug/L

<1

<1

<1

1.3-Dichlorobenzene

Ug/L

<1

<1

<1

Tabl

e 17. Concentrations

of

to

tall

y re

cove

rabl

e base-neutral-extract

able

co

mpou

nds

in water,

Finl

ey Creek

and

Eagle

Creek, De

cemb

er 14

, 1982 (Continued)

Cons

titu

ent

Unit

s

Finl

ey Cr

eek

at

Highway

421

near

Zion

svil

le

(sit

e 2)

Eagle

Creek

at

West 14

6 St

. near

Zionsville

(sit

e 3)

Eagl

e Creek

at 10

0 No

rth

Road ne

ar

Indi

anap

olis

(site

4)

1,4-Dichloro

benzene

3,3'

-Dic

hlor

oben

zidi

ne

Diethyl

phthalate

Dimethyl ph

thal

ate

Di-n-butyl phthalate

2,4-

Dini

trotoluene

2,6-

Dini

trot

olue

ne

Di-n-octyl phthalate

bis

(2-Ethyl

hexy

l)ph

thal

ate

Fluo

rant

hene

Fluorene

Hexa

chlo

robe

nzen

e Hexachlorobu

tadiene

Hexa

chlo

rocy

clop

enta

dien

e He

xach

loro

ethane

Inde

no (1

,2,3)

pyrene

Isophorone

Naph

thal

ene

Nitr

oben

zene

n-Nitrosodim

ethy

lami

ne

Ug/L

Ug

/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug

/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug/L

Ug

/L

Ug/L

Ug/L

Ug/L

Ug

/L

Ug/L

Ug/L

Ug/L

CO ro

Table

17.

Conc

entr

atio

ns of

to

tall

y re

cove

rabl

e base-neutral-extractable co

mpou

nds

in w

ater

, Fi

nley

Creek

and

Eagle

Cree

k, December 11

, 19

82 (

Cont

inue

d)

Finl

ey Cr

eek

at

Eagl

e Creek

at

Eagl

e Creek

at 10

0Highway

121

near

West 11

6 St.

near

No

rth

Road

near

Zionsville

Zionsville

Indianapolis

Cons

titu

ent

* Un

its

(sit

e 2)

(site

3)

(site

1)

n-Nitrosodiphenylamine

Ug/L

<1

<1

<1

n-Ni

tros

odi-n-propylamine

Ug/L

<1

<1

<1

Ph

enan

thre

ne

Ug/L

<1

<1

<1

Pyrene

Ug/L

<1

<1

<1

2,3,7,8-Tetrachlorodibenzo-

p-dioxin

Ug/L

<1

<1

<1

1,2,1-Trichlorobenzene

ug/L

<1

<1

<1

Dete

ctio

n limie:

1 Ug/L.

All

cons

titu

ents

are

EPA

priority pollutants.

Table 18. Field measurements an

d st

ream

bed-

mate

rial

-siz

e analyses,

Finl

ey Creek

and

Eagle

Creek, Oc

tobe

r 26-27, 1982.

Meas

urem

ent

Unit

s

Finl

ey Cr

eek

at

1100 Ea

st Road

near Zionsville

(sit

e 1)

Finl

ey Creek

at

Highway

421

near

Zionsville

(sit

e 2)

Stre

ambe

d-ma

teri

al

size

:>2

,000

u pe

rcen

t1,000

- 2,000u

percent

500

- 1,

OOOU

pe

rcen

t250

- 500u

perc

ent

125

- 250u

perc

ent

63 -

125U

percent

<63u

perc

ent

48.7

14.2

14.4

14.5

5.3

1.4

1.5

0 0 0 0 0 0100

Eagle

Cree

k at

West 14

6 St

. near

Zion

svil

le

(site

3)

45.2

6.

0 6.

57.

77.

87.

419

.4

Eagl

e Creek

at 10

0 No

rth

Road ne

ar

Indi

anap

olis

(site

4)

Wate

r te

mper

atur

eSp

ecif

ic co

nduc

tanc

e

Dissolved

oxyg

enPH Disc

harg

eSu

spen

ded-

sediment

conc

entr

atio

ni Pe

rcen

t suspended

oo

sedi

ment

<63 micron

°C umho/cm

at25°

Cmg/L

__ ft3/

sec

mg/L

perc

ent

6.4

647 5.

47.9

<.l

86 71

6.0

1,21

5 5.2

7.9

<.l

123 71.5

8.9

607 8.

38.

10

121 51.5

6.8

887 9.

37.

59 48 91.7

51.2

12.2

16.7

15.7 3.2

0.4

0.6

Table

19. Field me

asur

emen

ts,

Finl

ey Creek

and

Eagl

e Cr

eek,

Dece

mber

14

, 1982

Finl

ey Creek

at

Eagl

e Creek

at

Eagl

e Creek

at 10

0Highway

421

near

We

st 146

St.

near

North

Road

near

Zion

svil

le

Zionsville

Indi

anap

olis

Measuremen

t Un

its

(sit

e 2)

(sit

e 3)

(sit

e 4)

CO

Water

temperature

«Specific co

nduc

tanc

eDissolved

oxygen

PH Disc

harg

eSu

spen

ded-

sedi

ment

conc

entr

atio

nPercent

suspended

sediment

<63

micron

°C umho

/cm

at 25°

Cmg

/L__ ft

3/se

c

mg/L

perc

ent

0.8

621 12.8 8.7

3.8

77 89.8

0.6

630 12.3 8.4

25.3

72 85.4

1.4

665 12.7 8.3

51 89 80.8

App

endi

x 1

.--W

ater

-qu

alit

y

surv

ey o

f E

agle

C

reek

an

d tr

ibuta

ries

upst

ream

fr

om

Eag

le

Cre

ek

Res

ervoir

, A

ugus

t 25

-26,

I9

60

A.

Conce

ntr

atio

ns

of

sele

cted

m

etal

s an

d no

nmet

als

on

atre

arab

ed

mat

eria

l (<

63-m

icro

n fr

acti

on

^'

[ug/g

=m

loro

gra

ra

per

gra

m]

I CO on

i

Co

nst

itu

ent

Uni

ts

Alu

min

um

* U

g/g

Ars

enic

2

yg/g

B

ariu

m

3 gg

/g

Cad

miu

m

* U

g/g

Chr

omiu

m

2 U

g/g

Cop

per

2 yg

/g

Iron 2

gg

/g

Lea

d 1

Ug/

g M

anga

nese

2

Ug/

g M

ercu

ry

^ ug

/g

Sel

eniu

m

2 gg

/g

Sil

ver

2

Ug/

g Z

inc

2 U

g/g

1 D

etec

tio

n

Um

itrl

O

ug

/g.'

2 D

etec

tio

n li

rait

rl

Ug/

g.

3 D

etec

tio

n

Iim

itr2

.5

Ug/

g.

* D

etec

tio

n

linit

rO.O

l U

g/g.

Ald

rin

1 U

gAg

Chl

orda

ne

2 U

g/kg

DD

D 1

Ug/

kg

DDE

1 U

g/kg

DD

T *

Ug/

kg

Die

ldri

n

1 U

g/kg

E

ndos

ulfa

n 1

ugA

g E

ndri

n l

Ug/

kg

Hep

tach

lor-

ep

oxid

e *

Ug/

kg

Hep

tach

lor

1 U

g/kg

Lln

dane

1

UgA

g M

i rex

l

Ug/

kg

Met

hoxy

chlo

r 1

Ug/

kg

PCB

(to

tal)

2

gg/k

g PC

N (t

ota

l)

2 ug

/kg

Per

than

e 2

ug/k

g T

oxap

hene

3

ug/k

g

Eag

le

Fin

ley

Cre

ek a

t D

itch

C

reek

F

inle

y

Mou

nts

Run

300

Nor

th

to

at

1100

C

reek

at

950

Roa

d F

inle

y

Eas

t R

oad

at

Hwy

121

Eas

t H

oad

(sit

e

1)

(sit

e

2)

(sit

e

3)

(sit

e

1)

(sit

e

5)

3,90

0 7,

100

7,00

0 1,

600

1,00

0<1

3

2 1

<111

0 16

0 13

0 10

0 90

10

60

13

10

10

20

20

20

20

10

9,50

0 11

,000

11

,000

13

,000

8,

100

20

80

30

50

20

530

710

170

590

190

i»8

79

70

76

16

B.

Conce

ntr

atio

ns

of

org

anoch

lorl

ne

Inse

ctic

ides

on

7 <1

9

19

29

3.1

<0.

1 3.

7 1.

1 19

<

0.1

<0.

1 <

0.1

<0,

1 <

0.1

<0.

1 <

0.1

<0.

1 <

0.1

<0.

1

<0.

1 <

0.1

<0.

1 <

0.1

<

0il

<0.1

<

0.1

<0.

1 <

0.1

<0,

1 <

0.1

<

0.1

<

0.1

<0

.1

<0.

1

1 10

10

12

0 3

Lit

tle

Eag

le

Eag

le

Jack

son

Run

Cre

ek at

Cre

ek

at

Nor

th

121s

t S

t.

at

Will

ow

6Bth

R

oad

Wes

t >v

enue

(s

ite

6)

(sit

e

7)

(sit

e

8)

3,60

0 1,

100

1,10

0

130

110

100

10

20

10

20

10

20

10

8,20

0 8,

100

20

20

10

520

500

150

50

16

19

< 1

Eag

le

Cre

ek

belo

w

Hig

h S

choo

l A

venu

e (s

ite

9)

5,10

0 2 80 20 20

11,0

00

30

130 56

Eag

le

Fls

hbac

tc

Cre

ek a

t C

reek

L

afay

ette

at

Wil

son

Roa

d R

oad

(sit

e

10)

(si'te

11

)

8,10

0 3,

900

130

100

30

30

30

20

20,0

00

7,00

0 30

30

70

0 17

0

87

17

stre

ambe

d m

ater

ial

(<63

-mic

ron

frac

tio

n)

22

8 23

<

0.1

<0.

1 1.2

<

0.1

0.7

1.5

17

5.7

13

<0 .

1 <0

. 1

<0.

1

<0. 1

<0

. 1

<0. 1

<0. 1

<0

. 1

<0.

1 2

2 31

3 0.8

<

0.1

<0.

1

8.9

<0. 1

<0.

1 <

0. 1

<0.

1 <

0. 1

7

9 9

<0.

1 <

0.1

<0.

1 <

0.1

2.5

9.2

<0. 1

<0

. 1

<0,

1 <

0. 1

<0.

1 <

0.1

<0. 1

<

0.1

<0.

1 <

0.1

<0 .1

<0

. 1

28

3

1 D

etec

tio

n li

mit

iO.l

U

gAg

2 D

etec

tio

n ll

alt

sl

ug/k

g.3

Det

ecti

on

U

nit

ilO

U

g/W

g

Appe

ndix

1.

Wat

er-q

uali

ty su

rvey

of

Eagle

Cree

k and

trib

utar

ies

upst

ream

from Eagle

Creek

Rese

rvoi

r, August 25-26, 1980 (Continued)

C.

Conc

entr

atio

ns o

f organophosphorus insecticides on st

ream

bed

mate

rial

(<

63-n

icron

frac

tion

)

Cons

titu

ent

Dlatinon

Ethicn

Mala

thio

nMethylparathlon

Meth

yltr

ithi

on

Para

thlo

nTr

ithi

on

Units

UgAg

UgAg

UgAg

UgAg

UgAg

UgAg

UgAg

Eagle

Eagle

Finl

ey

Little Eagle

Eagle

Creek

Eagle

Flsh

bacJ

cCreek

at

Ditch

Creek

Finl

ey

Mounts Run

Jackson

Run

Cree

k at

Creek

below

High

Creek

at

Creek

300

North

to

at 1100

Cree

k at 950

at No

rth

121st

St.

at Willow

School

Lafa

yett

e at Wilson

Road

Finley

East Road

at Hw

y 121

East Road

68th

Road

West

Avenue

Avenue

Road

Ro

ad(site

1)

(site

2)

(sit

e 3)

(site

1)

(site

5)

(site

6)

(site

7)

(site

8)

(sit

e 9)

(s

ite

10)

(sit

e 11)

<0.1

2.1

2.3

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0

.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0

.1<0

.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0

.1

<0.1

<0.1

<0.1

<0

.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0

.1

<0.1

<0

.1<0

.1

<0.1

<0.1

<0.1

"

<0.1

<0.1

<0.1

<0

.1

<0.1

<0

.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0

«1

<0.1

<0

.1<0

.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0.1

<0

.1

<0.1

<0

.1

1 De

tect

ion

liml

tsO.

l UgAg.

D.

Conc

entr

atio

ns of chlorinated-phenoxy and

acid

he

rbic

ides

on st

ream

bed

mate

rial

(<63 m

icron-fraction)

00

SilvU

en

2,ID

1 2.MDP

2,1,5-T

UgA

g

Ug

Ag

U

gA

g

Ug

Ag

1 De

tect

ion

limittO.l

UgAg.

App

endi

x 1.-

-Wat

er-q

ual

ity

surv

ey of

Eag

le

Cre

ek

and

trib

uta

ries

upst

ream

fr

om

Eeg

le

Cre

ek

Res

erv

oir

, A

ugus

t 25

-26,

1980~

(Conti

nued

)E

. C

once

ntr

atio

ns

of

nutr

ients

on

st

rear

abed

m

ater

ial

(<63

-rai

cron

fr

acti

on)

I CO

Cons

titu

ent

Inorganic

carb

on(t

otal

) 1

Organic

carbon

(total

*Phosphorus

(tot

al)

2Ni

trog

en(t

otal

) 3

Oil

and

grease

(tot

al)

1Cy

anid

e "

Unit

s .

gAg

gAg

gAg

gAg

gAg

ug/g

Eagle

Creek

at300

Nort

hRoad

(site

1)

26 36 590

1,90

0 0 <.5

Ditch

toFinley

(site

2)

29 37 100

2,90

0 0 <.5

Finl

eyCr

eek

at 1100

East Road

(site

3)

15 36 690

6, MOO 0 <.

5

Little Ea

gle

Finley

Creek

at Hwy

1(21

(site

1)

18 36 560

M.100 0 <.

5

F.

Field

measurements

Water

temp

erat

ure

Spec

ific

cond

ucta

nce

AT 2

5' C

Dissolved

oryg

enPH Stre

ambe

d ma

teri

alsize:

>200

0u (gravel)

1000 -

2000

U50

0 -

1000U

250

- 500U

(sand)

125

- 250u

63 -

125u

<63u (s

ilt/

clay)

c umho

/cm2

mg/L

percent

perc

ent

perc

ent

percent

percent

perc

ent

percent

19.7

689 9.

37.

7

30.3

20.6

21.2

20.2 6.6

0.8

0.3

20.9

628 5.

17.

6

0.2

12.0

13.5

10.5

16.1)

10.1

37.3

?0.8

635 9.

17.8

12.5

18.7

19.7

11.7 3-5

0.5

O.il

22.1

621 10.

ll8.

0

0.2

5.0

1(0.14

1*5.

07.

3l.i)

0.7

Moun

ts Run

at 950

East

Road

(site

5)

23 HI

700

7,30

0 0 <.5

Jackson

Run

at North

68th Ro

ad(site

6)

16 36 530

28,000

0 <.5

and

stre

arab

ed-m

ater

ial-

size

23.0

681 11.3 8.2

1)0.5

28.1

18.8 9.5

2.D

0.5

0.2

22.2

710 10.6 8.1

56.2

1H. 6

13.5

10.5 3.8

0.8

0.6

Cree

k at

121st

St.

West

(site

7)

16 33 520

7,10

0 0 <.5

analyses

22.2

610 10.2 7.8

23.2 8.3

19.8

38.0 8.3

1.2

0.7

Eagle

Creek

at Willow

Aven

ue(s

ite

8)

18 36 670

6,HOO 0 <.

5

21.8

630 10.0 8.0

-

7.3

8.5

25.1

17.7

10.2 0.7

0.5

Eagle

Creek

below

High

School

Aven

ue(site

9)

16 39 680

6,700 0 <.

5

23-5

638 10.1)

7.9

5.6

18.8

37.1

33. «

1.7

0.2

0.2

Eagle

Creek

atLa

faye

tte

Road

(site

10)

28 12 500

6,600 0 <-

5

29.1

551 28.0 9.1

53.2

15.9 8.8

8.9

9.1

2.1

2.0

Fishback

Creek

at Wilson

Road

(sit

e 11)

15 38 5DO

7,200 0 <.

5

23.8

670 11.6 8.3

.

78 7.5

6.1

5.2

2.0

0.5

0.7

1 D

etec

tion

lim

it var

ies

wi

2 D

etec

tion

ll

rait

alO

wg/

kg.

3 D

etec

tio

n

lim

it=

l ra

g/kg

. *

Det

ecti

on ll

nit

iO.5

U

g/g.

var

ies

wit

h am

ount

of

sam

ple

anal

yze

d.

lO w

g/kg

.

Appendix 1. Water-quality survey of Eagle Creek and tributaries upstream fromEagle Creek Reservoir, August 25-26, 1980 (continued)

G. GC/MS base-neutral scan of streambed material(<63-micron fraction)

The following are results of a GC/MS base neutral scan of priority pollu­ tants on streambed materials (<63 micron) collected from Eagle Creek watershed August 25-26, 1980. Methylene chloride was used as the extraction solvent. The extract was concentrated to 1.0 ml, and approximately 4 microliters of the concentrate was analyzed. No priority pollutants were identified; however, several closely related compounds were identified and some were quantified. Minimum detection limits are approximately 2.0 ug/kg.

Site 1 One peak was identified as a phthalate; seven peaks were identified as alcohols; and thirteen peaks were identified as straight-chain, branched, and cyclic hydrocarbons.

Site 2 Concentration of strobane (related to Toxaphene) was 98.1 Ug/kg. Five peaks were identified as hydrocarbons or complex alcohols.

Site 3 One peak was identified as 1,4-dimethoxybenzene, and nine other peaks were identified as acetaldehyde derivatives or complex alcohols.

Site 4 Traces of dimethyl and trimethyl phenanthrene were identified. Concentration of strobane was 97.1 ug/kg.

Site 5 Traces of nitrobenzene, 1,4-dimethoxybenzene, and acetaldehyde derivatives were identified.

Site 6 One peak was identified as an acetaldehyde derivative, one as a fluorophenyl compound, and one as a benzenediol.

Site 7 -- Nothing was detected.

Site 8 Four peaks were identified as alcohols, and six were identified as branched or straight-chain hydrocarbons.

Site 9 Phenol was identified in trace concentrations. Seven other peaks were identified as alcohols and ketones.

Site 10 Three peaks were identified as alcohols, seven as straight-chain, branched, and cyclic hydrocarbons, and one as a complex ester.

Site 11 Trimethyloenzenes were identified in trace concentrations. Four peaks were identified as hydrocarbons or complex organic acids.

-38-

Appendix 2. Drinking-water standards for selected inorganic and organicchemicals

[Source, U.S. Environmental Protection Agency (1975, 1979a, 1979b)]

National Interim Primary Drinking Water Regulations

Inorganic:

Organic:

Constituent

ArsenicBariumCadmiumChromiumCyanideLeadMercurySeleniumSilver

BromoformChloroformEndrinLindaneMethoxychlorToxaphene

Concentration (pg/L)

501,000

1050

200502

1050

100100

0.?4

1005

National Secondary Drinking Water Regulations

Constituent or property Concentration (ug/L)

CopperIronManganesePHZinc

1,00030050

1 6.55,000

- 8.5

Not microgram per liter. pH is the negative logarithm Of the hydrogen ion concentration.

-39-

Appendix 3. Select organic

compounds

that exceeded background concentrations in Finley an

d Eagle

Cree

k,Oc

tobe

r an

d De

cemb

er,

1982

[Source, Wi

ndho

lz,

Mart

ha,

ed.,

1976]

Cons

titu

ent

Uses

Publ

ic He

alth

Co

ncer

n

bis

(2-Chloroethyl)

ether

bis

(2-Ethylhexyl) ph

thal

ate

1,2-Dichloro

benzene

O

I1.1-Dichloroethane

1.2-

tran

s-Dichloroethylene

Diet

hyl

phthalate

2,4-

Dime

thyl

phen

ol

Dime

thyl

phthalate

Di-n-butyl phthalate

Dissolves

oils,

fats,

grea

ses;

purifi­

cation of

oils; scouring te

xtil

es;

insecticidal fumigant in soils.

Used

in

vacuum pumps.

Solvent

for

waxes, gums,

resins,

tars,

rubbers, oils,

asph

alts

; insecticide

for

term

ites

an

d lo

cust

bo

rers

; degreaser.

Solvent

for

fats

, phenol,

camphor;

retards

fermentation.

Solvent

for

cell

ulos

e ac

etat

e in th

e manufacture

of v

arni

shes

and

dope

s;

fixative for

perf

umes

; denaturing

alcohol.

Prep

arat

ion

of coal ta

r di

sinf

ecta

nts;

manufacture

of artificial re

sins

.

Solvent

and

plas

tici

zer

for

cell

ulos

e ac

etat

e an

d ce

llul

ose

acetate-butyrate

comp

osit

ives

; in

sect

re

pell

ant

for

pers

onal

use.

Insect repellant

for

impregnation

on cl

othi

ng.

Irritating to

skin,

eyes

, mucous

memb

rane

.

May

cause

live

r or

ki

dney

injury;

high

concentrations cause

cent

ral

nerv

ous

syst

em (CNS)

depression.

Narcotic in

high co

ncen

trat

ion.

Irritant an

d narcotic in

hi

gh

conc

entr

atio

n.

Irritation to

mu

cous

me

mbra

nes;

narcotic in

hi

gh co

ncen

trat

ions

.

Irritating to

ey

es and

muco

us

membranes; ca

n cause

CNS

depr

es-

ion

when in

gest

ed;

not

irritating

to or

ab

sorb

ed th

roug

h sk

in.

Appe

ndix

3. Select or

gani

c compounds

that

ex

ceed

ed background co

ncen

trat

ions

in

Fi

nley

an

d Eagle

Cree

k,Oc

tobe

r an

d December,

1982 (Continued)

Cons

titu

ent

Uses

Public He

alth

Co

ncer

n

n-Nitrosodim

ethy

lami

ne

PCB

(Total)

Phen

ol

Tetrachlorethylene

Foun

d in tr

ace

amou

nts

in tobacco

smok

e condensates.

Cool

ant

in capacitors an

d transformers;

carb

onle

ss ca

rbon

paper; el

ectr

omag

nets

and

volt

age

regu

lato

rs in

fl

uore

scen

t light

fixt

ures

Disi

nfec

tant

; ma

nufa

ctur

e of

art

ific

ial

resins,

medi

cal

and

industrial or

gani

c compounds

and

dyes;

used as reagent

in

chemical analysis,

adso

rpti

on.

Degr

easi

ng m

etals; dr

y cl

eani

ng;

solvents.

Carcinogenic;

fata

l po

ison

; ca

uses

liver

injury.

Caus

es liver

inju

ry;

suspected

carc

inog

en;

acute

dose

ca

uses

chloracne, headaches, na

usea

, an

d di

arrh

ea.

May

cause

nausea,

vomi

ting

, et

c.,

aver

age

fata

l do

se is

15

g

but

as

little as

1

g ha

s ca

used

death;

pois

onin

g may

occu

r by

sk

in

Narcotic in

high concentrations;

defa

ttin

g ac

tion

on

skin can

caus

e de

rmat

itis

.

Toluene

1,1,1-Trichloroethane

Tric

hlor

oeth

ylen

e

Manufacture

of benzoic

acid,

benz

alde

hyde

, ex

plos

ives

, dy

es,

and

othe

r or

gani

c compounds; solvent

in

extraction of va

riou

s principles fr

om

plants.

Cold ty

pe me

tal

clea

ning

; cleaning

plastic

mold

s.

Solvent

for

fats,

waxe

s, re

sins

, oils,

rubb

er,

paint, va

rnis

h, ce

llul

ose

este

rs

and

ethers;

degreaser; manufacture

of

orga

nic

chem

ical

s and

phar

mace

utic

als

such as chloroacetic acid.

Narcotic in

high co

ncen

trat

ions

.

Narcotic in

high co

ncen

trat

ions

; ir

rita

ting

to

ey

es an

d mu

cous

membranes.

Mode

rate

ex

posu

re may

be similar

to al

coho

l inebriation; na

rcot

ic

in hi

gh concentration; ca

used

de

aths

by

ve

ntri

cula

r fi

bril

lati

on.