Tyndall Effect

3
Tyndall effect 1 Tyndall effect Flour suspended in water appears to be blue because only scattered light reaches the viewer and blue light is scattered by the flour particles more strongly than red. The Tyndall effect, also known as Tyndall scattering, is light scattering by particles in a colloid or particles in a fine suspension. It is named after the 19th century physicist John Tyndall. It is similar to Rayleigh scattering, in that the intensity of the scattered light depends on the fourth power of the frequency, so blue light is scattered much more strongly than red light. An example in everyday life is the blue colour sometimes seen in the smoke emitted by motorcycles, particularly two stroke machines where the burnt engine oil provides the particles. Under the Tyndall effect, the longer-wavelength light is more transmitted while the shorter-wavelength light is more reflected via scattering. An analogy to this wavelength dependency is that longwave electromagnetic waves such as radio waves are able to pass through the walls of buildings, while shortwave electromagnetic waves such as light waves are stopped and reflected by the walls. The Tyndall effect is seen when light-scattering particulate-matter is dispersed in an otherwise light-transmitting medium, when the cross-section of an individual particulate is the range of roughly between 40 and 900 nanometers, i.e., somewhat below or near the wavelength of visible light (400750 nanometers). The Tyndall effect is commercially exploited to determine the size and density of particles in aerosols and other colloidal matter; see ultramicroscope and turbidimeter. Difference from Rayleigh scattering The Tyndall effect in opalescent glass: It appears blue from the side, but orange light shines through. [1] Rayleigh scattering is defined by a mathematical formula that requires the light-scattering particles to be far smaller than the wavelength of the light. For a dispersion of particles to qualify for the Rayleigh formula, the particle sizes need to be below roughly 40 nanometers; and the particles may be individual molecules. Colloidal particles are bigger, and are in the rough vicinity of the size of a wavelength of light. It follows from scattering theory that Tyndall scattering (by colloidal particles) is much more intense than Rayleigh scattering. The importance of the size factor for intensity can be seen in the large exponent it has in the mathematical statement of the intensity of Rayleigh scattering. There is no equivalent mathematical statement for Tyndall scattering. But, if the colloid particles are spheroid, Tyndall scattering is mathematically analysable in terms of Mie theory, which admits particle sizes in the rough vicinity of the wavelength of light.

Transcript of Tyndall Effect

Page 1: Tyndall Effect

Tyndall effect 1

Tyndall effect

Flour suspended in water appears to be bluebecause only scattered light reaches the viewerand blue light is scattered by the flour particles

more strongly than red.

The Tyndall effect, also known as Tyndall scattering, is lightscattering by particles in a colloid or particles in a fine suspension. It isnamed after the 19th century physicist John Tyndall. It is similar toRayleigh scattering, in that the intensity of the scattered light dependson the fourth power of the frequency, so blue light is scattered muchmore strongly than red light. An example in everyday life is the bluecolour sometimes seen in the smoke emitted by motorcycles,particularly two stroke machines where the burnt engine oil providesthe particles.

Under the Tyndall effect, the longer-wavelength light is moretransmitted while the shorter-wavelength light is more reflected viascattering. An analogy to this wavelength dependency is that longwaveelectromagnetic waves such as radio waves are able to pass through thewalls of buildings, while shortwave electromagnetic waves such aslight waves are stopped and reflected by the walls. The Tyndall effectis seen when light-scattering particulate-matter is dispersed in anotherwise light-transmitting medium, when the cross-section of anindividual particulate is the range of roughly between 40 and 900nanometers, i.e., somewhat below or near the wavelength of visiblelight (400–750 nanometers).

The Tyndall effect is commercially exploited to determine the size anddensity of particles in aerosols and other colloidal matter; seeultramicroscope and turbidimeter.

Difference from Rayleigh scattering

The Tyndall effect in opalescent glass: It appearsblue from the side, but orange light shines

through.[1]

Rayleigh scattering is defined by a mathematical formula that requiresthe light-scattering particles to be far smaller than the wavelength ofthe light. For a dispersion of particles to qualify for the Rayleighformula, the particle sizes need to be below roughly 40 nanometers;and the particles may be individual molecules. Colloidal particles arebigger, and are in the rough vicinity of the size of a wavelength oflight. It follows from scattering theory that Tyndall scattering (bycolloidal particles) is much more intense than Rayleigh scattering. Theimportance of the size factor for intensity can be seen in the largeexponent it has in the mathematical statement of the intensity ofRayleigh scattering. There is no equivalent mathematical statement forTyndall scattering. But, if the colloid particles are spheroid, Tyndallscattering is mathematically analysable in terms of Mie theory, which admits particle sizes in the rough vicinity ofthe wavelength of light.

Page 2: Tyndall Effect

Tyndall effect 2

Blue irises

A blue iris

A blue iris in an eye is due to Tyndall scattering in a turbid layer in the iris.Brown and black irises have the same layer except with more melanin in it.The melanin absorbs light. In the absence of melanin, the layer is translucent(i.e., the light passing through is randomly and diffusely scattered) and anoticeable portion of the light that enters this turbid layer re-emerges via ascattered path. That is, there is backscatter, the redirection of the lightwavesback out to the open air. Scattering takes place to a greater extent at theshorter wavelengths. The longer wavelengths tend to pass straight through theturbid layer with unaltered paths, and then encounter the next layer furtherback in the iris, which is a light absorber. Thus, the longer wavelengths are

not reflected (by scattering) back to the open air as much as the shorter wavelengths are. Since the shorterwavelengths are the blue wavelengths, this gives rise to a blue hue in the light that comes out of the eye.[2] The blueiris is an example of a structural color, in contradistinction to a pigment color.

Weather

Ribbons of light due to Tyndall Scattering

On a day when the sky is overcast, the sunlight passes through theturbid layer of the clouds, resulting in scattered, diffuse light on theground. This does not exhibit Tyndall scattering because the clouddroplets are larger than the wavelength of light and scatter all colorsapproximately equally. On a day when the sky is cloud-free, the sky'scolor is blue in consequence of light scattering, but this is not termedTyndall scattering because the scattering particles are the molecules ofthe air, which are much smaller than the wavelength of the light. Onoccasion, the term Tyndall effect is incorrectly applied to lightscattering by macroscopic dust particles in the air. However, this ismore like reflection, not scattering, as the macroscopic particlesbecome clearly visible in the process.

References[1] http:/ / www. webexhibits. org/ causesofcolor/ 14B. html[2] For a short overview of how the Tyndall Effect creates the blue and green colors in animals see uni-hannover.de (http:/ / www. itp.

uni-hannover. de/ ~zawischa/ ITP/ scattering. html#tyndalleffekt) and for information in greater detail see Colourandlife.com (http:/ / www.colourandlife. com/ ).

Page 3: Tyndall Effect

Article Sources and Contributors 3

Article Sources and ContributorsTyndall effect  Source: http://en.wikipedia.org/w/index.php?oldid=505366934  Contributors: Abdull, Adambisset, Adithyak1, Afluegel, Alvis, Annielogue, Archelon, Armeria, Avathar,Belg4mit, Berland, Burn, CERminator, CPMcE, Chenzw, Conscious, D'Agosta, DanMS, Dante Alighieri, Derek1G, Drphilharmonic, Eddie Nixon, Fito, Gene s, GreatWhiteNortherner,Grogdamighty, Gruts, HappyApple, Henriquevicente, Honza Záruba, Ian Dunster, Icairns, Inourbedroomafterthewar, Inter, Jag123, Jmnbatista, Julian herrera, Karol Langner, Lamarque,Limideen, Lkjhgfdsxcvb, Lotje, M1ss1ontomars2k4, Materialscientist, Mathwhiz 29, Michael Hardy, Minna Sora no Shita, Obradovic Goran, Ozo, Palfrey, Peter Karlsen, Petergans, Pjacobi,Pradeep717, Puffin, Renata3, Renski, Rifleman 82, Rigadoun, Ruy Pugliesi, Sabri76, Seanwal111111, Shanes, Shinkolobwe, Sintaku, Slicky, Srleffler, Sundar, Taxiarchos228, Tinton5, Vonzepp,Wiki.Goodash, Wjbeaty, YanA, Yancyfry jr, 124 anonymous edits

Image Sources, Licenses and ContributorsImage:WaterAndFlourSuspensionLiquid.jpg  Source: http://en.wikipedia.org/w/index.php?title=File:WaterAndFlourSuspensionLiquid.jpg  License: GNU Free Documentation License Contributors: Chris 73, DrJunge, Ies, Lobo, Saperaud, Superm401, WstFile:Why is the sky blue.jpg  Source: http://en.wikipedia.org/w/index.php?title=File:Why_is_the_sky_blue.jpg  License: Creative Commons Attribution-Sharealike 2.0  Contributors: optickImage:Bluishgrayeye.JPG  Source: http://en.wikipedia.org/w/index.php?title=File:Bluishgrayeye.JPG  License: Copyrighted free use  Contributors: en:User:Nick4gwenImage:TyndallEffect.JPG  Source: http://en.wikipedia.org/w/index.php?title=File:TyndallEffect.JPG  License: Creative Commons Attribution-Sharealike 3.0  Contributors: Pradeep717

LicenseCreative Commons Attribution-Share Alike 3.0 Unported//creativecommons.org/licenses/by-sa/3.0/