Tremco Product V.O.C. Table - arb.ca.gov · 16/06/2004 · Tremco 830 390 THC 900 Pretinted 165...

Tremco Product V.O.C. Table

Specialty Sealants Urethane Sealants Silicone Sealants/TapesProduct VOC g/L Product VOC g/L Product VOC g/L

Acoustical Sealant 180 Dymeric 240 35 440 Tape 0Butyl Sealant 240 Dymeric 240 FC 50 Polyshim Tape 0

Curtainwall Sealant 180 Dymeric 511 0 Proglaze 38JS 773 180 Dymonic 65 Proglaze II Base 30 (mixed)

Mono 555 300 Dymonic FC 50 Proglaze II Curative 30 (mixed)Spectrem EZ Seal 0 THC 900 75 (mixed) Proglaze SSG 0

Tremco 830 390 THC 900 Pretinted 165 (mixed) Spectrem 1 0Tremflex 834 0 THC 901 165 (mixed) Spectrem 2 0Ultrem 1500 23 THC 901 Pretinted 165 (mixed) Spectrem 3 0Vulkem 202 200 Universal Color Pak 0 Spectrem 4TS 0

Vulkem 45 130 Spectrem 800 46Vulkem 45 SSL 115 Spectrem 900SL 68

Vulkem 116 200 Tremsil 200 39Vulkem 227 220 Tremsil 600 0Vulkem 245 100 Universal Color Pak 0Vulkem 921 100

PrimersMembranes/Drainage Coatings Product VOC g/L

Product VOC g/L Product VOC g/L Deckline Primer 590Deckseal 0 Vulkem 345 270 ExoAir GM Primer 570

ExoAir 110 0 Vulkem 345 NF 95 ExoAir Primer 450ExoAir 120 61 Vulkem 346 420 ExoAir WB Primer 82ExoAir TWF 0 Vulkem 346NF 95 ParaPrimer 570

Paraseal (all types/grades) 0 Vulkem 350 205 Primer 1 670Tremdrain (all types/grades) 0 Vulkem 351 420 Primer 6 733

Tremproof 60 H 110 Vulkem 351 Clear 501 Primer 10 724Tremproof 60 R 215 Vulkem 351 NF 95 Primer 17 737Tremproof 60 V 110 Vulkem 360 NF - SL 120 Primer 23 114Tremproof 150 0 Vulkem 450 305 QD Low-Odor Primer 450Tremproof 260 48 Vulkem 451 420 Tremlar 120 200

Tremproof 201/222 T 190 Vulkem 640 240 TremPrime WB 82Tremproof 201/222 R 215 Vulkem 642 240 Vulkem 171 668Tremproof 201/222 SL 225 Vulkem 801 240 Vulkem 172 420

Tremproof 250 GC 150 Vulkem 950NF 16 Vulkem 181 733Tremproof 250 GC SL 320 Vulkem 951 NF 25 Vulkem 191 737

Proglaze SSG

Spectrem 1

Spectrem 2

Spectrem 3

Spectrem 4TS

Tremsil 600

mjaczola

The VOC content of the yellow highlighted products below are being questioned by another company who asserts these products are not zero VOC.

Tremflex 834

Tremco Incorporated 3735 Green Road • Beachwood, Ohio 44122 • 216-292-5000 Sealant/Weatherproofing Division Tremco® Mameco/VULKEM® ParamountTM Technical Services June 16, 2004

Re: Tremflex® 834 – LEED Product Information To Whom It May Concern: Tremco, as an organization, is committed to quality, responsive to internal and external customers, our employees, our community and environment, and we will treat all with respect and good stewardship. Tremflex 834 is manufactured in Toronto, Ontario. If Toronto falls within a 500-mile radius of the project site, the product is considered to be a locally produced material and can help contribute to earning Materials & Resources - Credit 5. The recycled content by weight is as follows: 30 ctgs (1 case) 0.07% (100% post-consumer) 60 ctg cases (1 pallet) 1.92% (all pallets are made from 100% reclaimed wood) 15 ssgs (1 case) 0.09% (100% post-consumer) 66 ssg cases (1 pallet) 2.20% (all pallets are made from 100% reclaimed wood) 1 x 2 gal pail 2.18% (.36% post-consumer and 1.82% post-industrial) 96 x 2 gal pails (1 pallet) 3.78% (all pallets are made from 100% reclaimed wood) 1 x 5 gal pail 2.10% (.35% post-consumer and 1.75% post-industrial) 36 x 5 gal pails (1 pallet) 8.62% (all pallets are made from 100% reclaimed wood) Tremflex 834 contains 0g/L volatile organic content (VOC) and therefore satisfies the LEED criteria for Indoor Environmental Quality standard as established under credit 4. Should you have any questions or require additional information, please do not hesitate to contact me. Sincerely,

Michael Schmeida Technical Service Representative LEED Accredited Professional

“LEED” is a trademark of the U.S. Green Building Council

Tremflex™ 834Tremflex™ 834Siliconized Acrylic Latex Sealant

Product Description:Tremflex 834 is a pure acrylic latexsealant formulated to provide afast-setting pliable seal with mini-mal shrinkage.

Basic Uses:Tremflex 834 can be used for gener-al purpose interior and exteriorcaulking and as a back beddingglazing compound. It is also highlyrecommended as an acoustical sealin the construction of interior walls,ceilings and floors to reduce SoundTransmission Class (STC) of partitionwalls. It is ideal for interior jointsthat will be painted such as doorand window frame perimeters andprecast concrete plank joints.Tremflex 834 is also suitable for useon vinyl, aluminum and wood sidingas well as on bathroom and kitchenfixtures.

Limitations:• Do not apply to damp or

contaminated surfaces.

Packaging:1/12 gallon (300mL) cartridges, 20 oz. (600mL) sausages, 3 gallon(11.3 L), and 5 gallon (18.9 L) pails.

Standard Color:White

Applicable Standards:Conforms to ASTM C-834 andCAN/CGSB 19-GP-17M.

INSTALLATIONJoint Design:May be used in any vertical or hori-zontal joint design in accordancewith accepted architectural/engi-neering practice. Movement should

not exceed 12.5% of the minimumjoint width.

Joint Dimensions:For joints 1/4 inch (6.4mm) to 1/2inch (12.7mm) wide, the width todepth ratio should be equal. Joints1/2 inch (12.7mm) wide or greatershould have a depth of 1/2 inch(12.7mm). Minimum joint size is1/4 inch by 1/4 inch (6.4mm by 6.4mm).

Surface Preparation:For good adhesion, the joint inter-face must be sound, clean and dry.Depending on the substrate, orpresence of form release agents,masonry waterproofings, dust, loosemortar or laitance, architecturalpaints or finishes, the joint surfacemay require a thorough wire brush-ing, grinding, sandblasting and sol-vent washing.

Tooling & CleaningTooling is recommended immediate-ly after application to insure firm,intimate contact with the jointinterface. Dry tooling is preferred.Cleaning can be accomplished withsoapy water while sealant is in anuncured state.

Joint BackingBond Breaking Tape:Closed cell polyethylene backer rodsare preferred as joint backing tocontrol depth of sealant bead.Where depth of joint will preventuse of joint backing, an adhesivebacked polyethylene tape should beinstalled to prevent three-sidedadhesion. Joint backing must bedry at time of sealant application.

Application:Tremflex 834 is easy to apply withconventional caulking equipment.Fill joint completely and tool. At75˚F (23.9˚C), 50% R.H., Tremflex834 can be painted over in 30 to 45minutes with latex or oil-basepaint.

Maintenance:Damaged sealant can be repaired.Consult your Tremco Distributor orRepresentative for repair proce-dures.

Availability:Immediately available from yourlocal Tremco Field Representative,Tremco Distributor or TremcoWarehouse.

Warranty:Tremco warrants its Sealants to befree of defects in material, butmakes no warranty as to appearanceor color. Since method of applica-tion and on-site conditions arebeyond our control and can affectperformance, Tremco makes noother warranty, expressed orimplied, including warranties ofMERCHANTABILITY and FITNESS FORA PARTICULAR PURPOSE, withrespect to Sealants. Tremco’s soleobligation shall be, at its option, toreplace or to refund the purchaseprice of the quantity of Sealantproven to be defective, and Tremcoshall not be liable for any loss ordamage.

PRINTED IN THE USA 0503/T834SD

TYPICAL PHYSICAL PROPERTIESASTM C834 Requirement Tremflex 834

Results

Extrudability 2 g/s min. 6 g/s

Artificial Weathering

Wash-out none none

Slump none none

Cracking none none

Discoloration as acceptable to purchaser none

Adhesion Loss 25% max. none

Volume Shrinkage 30% max. 25.9%

Low Temperature Flexibility No cracking through substrate or noneloss of adhesion

Recovery 75% min. 93.7%

Adhesion Loss 25% max. none

Slump 4mm max. 2mm

Stain Index 3 max. 0

Tack-free Time 1 hour max. 15 min.

Sealant/Weatherproofing Division

3735 Green Road • Beachwood, Ohio • 44122 • Phone: (216) 292-5000 • (800) 321-7906220 Wicksteed Avenue • Toronto, ON M4H 1G7 • Phone: (416) 421-3300 • (800) 363-3213

For MSDS and Spec Data Sheets,Call our 24 Hour Fax-Back Line:

1-800-551-2806or visit our website:

www.tremcosealants.com

MATERIAL SAFETY DATA SHEET3735 GREEN ROADBEACHWOOD, OHIO 44122-8068

TELEPHONE: (216)292-5000 EMERGENCIES: (216)765-6727 8:30-5:00 ESTAFTER HOURS: CHEMTREC (800)424-9300

------------------------------------------------------------------------------------------------ SECTION 1------------------------------------------------------------------------------------------------Order Code: 000000009418014323

Product Name: TREMFLEX 834 Chemical Name: Chemical Family: Sealant Product Code: 941-8XX4 Date Prepared: 12-JUL-04 MSDS Preparer: R. A. MIKOL Replaces Date: 20-JAN-97 Other Applications: THIS MATERIAL SAFETY DATA SHEET (MSDS) APPLIES TO THE FOLLOWING: 941-8014(BRONZE), 941-8024(BLACK), 941-8054(LIMESTONE), 941-8064(WHITE), 941-8074(BUFF), 941-8084(BEIGE), 941-8514(ALUMINUM STONE), 941-8544(BROWN), 941-8584(IVORY), 941-8794(CEDAR), 941-8804(CREAM), 941-800(ClEAR).--------------------------------------------------------------------------------Section 2 - Molecular Composition--------------------------------------------------------------------------------Common Name and Chemical Name Weight % CAS Number Exposure Limits

CALCIUM CARBONATE (LIMESTONE) 0.0-50.0 1317-65-3 OSHA:TWA 15 mg/M3 STEL - (total dust, 5mg/M3 respirable fraction) ACGIH:TWA 10 mg/M3 STEL - (total dust, no asbestos, <1% SiO2)

ACRYLIC POLYMER 25.0-60.0 Trade Secret OSHA:TWA - STEL - ACGIH:TWA - STEL -

WATER 15.0-25.0 7732-18-5 OSHA:TWA - STEL - ACGIH:TWA - STEL -

DIPROPYLENE GLYCOL DIBENZOATE 1.0-5.0 27138-31-4 OSHA:TWA - STEL - ACGIH:TWA - STEL -

WHITE MINERAL OIL 1.0-5.0 8042-47-5 OSHA:TWA 5 mg/M3 STEL - (mist) ACGIH:TWA 5 mg/M3 STEL 10 mg/M3 (mist)

1,2-PROPANEDIOL (PROPYLENE GLYCOL) 0.5-3.0 57-55-6 OSHA:TWA - STEL - ACGIH:TWA - STEL -

TITANIUM DIOXIDE 0.0-3.0 13463-67-7 OSHA:TWA 10 mg/M3 STEL - ACGIH:TWA 10 mg/M3 STEL - (total dust, no asbestos, <1% SiO2)

CRYSTALLINE SILICA (QUARTZ) 0.0-1.0 14808-60-7 OSHA:TWA 0.10 mg/M3 STEL - (respirable dust) ACGIH:TWA 0.10 mg/M3 STEL - (respirable dust)

CARBON BLACK 0.0-0.35 1333-86-4 OSHA:TWA 3.50 mg/M3 STEL - ACGIH:TWA 3.50 mg/M3 STEL -

------------------------------------------------------------------------------Section 3 - Hazards Identification------------------------------------------------------------------------------****************************************************************************** Emergency Overview: Various colored paste. If inhaled can cause irritation to respiratory system. Leave area to breathe fresh air.******************************************************************************

2 1 2Product 941-8XX4 Page 1 of 5

Order Code: 000000009418014323

Potential Hlth Effect/Rte of Entry: ----------------------------------- Inhalation: Can cause irritation to respiratory system. Eyes: Can cause irritation. Ingestion: Can cause gastrointestinal irritation. Skin: May cause slight irritation.

Aggravated Medical Conditions: Pre-existing eye, skin, and respiratory disorders may be aggravated by exposure.Acute Health Effects: See effects described above.Chronic Health Effects: Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis may result from breathing free silica. No serious health effects have been established in man when exposed to carbon black. Inflammation, lung fibrosis, and tumors have been observed in animals at levels which overload lung clearance mechanisms. Carbon black contains varying amounts of polynuclear aromatic compounds(PNA's) which have been found to cause cancer in animals. Solvent extracts of carbon black are carcinogenic to the skin of mice. It is classified by IARC to be a known animal carcinogen and a possible human carcinogen (Group 2B). Fillers are encapsulated and not expected to be released from product under normal conditions of use.

------------------------------------------------------------------------------Section 4 - First Aid Measures------------------------------------------------------------------------------ Inhalation: Leave area to breathe fresh air. Eyes: Flush immediately with running water for 15 minutes, lifting the upper and lower lids occasionally. Get medical attention immediately. Ingestion: Get medical attention immediately. Skin: Wash with soap and water. Notes to Physician: N/A

------------------------------------------------------------------------------Section 5 - Fire Fighting Measures------------------------------------------------------------------------------ Flash Point: N/A Method: N/A Lower Flammability Limit: N/A Upper Flammability Limit: N/A Autoignition Temperature: N/A Extinguishing Media: Not applicable. Water base compound, not expected to burn. Fire and Explosion Hazards: Not Applicable Special Fire Fighting Procedures: During a fire, personnel at the scene are to prevent exposure to fumes using accepted fire fighting techniques. Fire Fighting Equipment: N/A Other Precautions: None known.


Order Code: 000000009418014323

------------------------------------------------------------------------------Section 6 - Accidental Release Measures------------------------------------------------------------------------------ Release Response Overview: Absorb spill in sand, earth or other suitable material.Transfer to appropriate container for disposal.

------------------------------------------------------------------------------Section 7 - Handling and Storage------------------------------------------------------------------------------Handling and Storage Precautions: Store under normal warehouse conditions. Handle in compliance with common hygenic practices.

------------------------------------------------------------------------------Section 8 - Exposure Controls/Personal Protection------------------------------------------------------------------------------ Respiratory: Not required. Skin: Protect hands with rubber or other suitable gloves. Eyes: Wear suitable safety eyewear. Face: Not required. Engineering: N/A

------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties------------------------------------------------------------------------------ Odor/Appearance: ACRYLIC/VARIOUS COLORED PASTE Color: VARIOUS Physical State: PASTE pH: 5.0-7.0 Vapor Pressure: N/A Vapor Density: N/A Boiling Point: N/A Melting Point: N/A Freezing Point: <32 F Solubility in Water: MISCIBLE Specific Gravity: 1.3 % Volatile Weight: 22.0

------------------------------------------------------------------------------Section 10 - Reactivity/Stability------------------------------------------------------------------------------ Stability: Stable Incompatible Products: Avoid contact with strong oxidizing agents. Conditions to Avoid Polymerization: Hazardous polymerization will not occur.

------------------------------------------------------------------------------Section 11 - Toxicological Information Eyes: SEE SECTION 3 Ingestion: " " " Inhalation: " " " Skin: " " " Subchronic: " " " Chronic: " " "

------------------------------------------------------------------------------Section 12 - Ecological Information------------------------------------------------------------------------------ Ecotoxicological Data: N/A


Order Code: 000000009418014323

Chemical Fate: N/A

------------------------------------------------------------------------------Section 13 - Disposal Considerations------------------------------------------------------------------------------ RCRA Class: N/A Disposal Method: Not regulated by RCRA. Dispose of in compliance with state and local regulations. EPA Reportable Quantities -------------------------# N/A

------------------------------------------------------------------------------Section 14 - Transportation Data------------------------------------------------------------------------------ DOT Shipping Name: NOT REGULATED DOT Hazard Class: DOT Label: UN/NA Number: Packing Group: Special Provisions: Packaging --------- Exceptions: Non-Bulk: Bulk: Quantity Limitations -------------------- Passenger Aircraft or Railcar: Cargo Aircraft: Vessel Stowage Requirements --------------------------- Vessel Stowage: Other Stowage: Transportation Notes: N/A

------------------------------------------------------------------------------Section 15 - Regulatory Information------------------------------------------------------------------------------ TSCA Status: On the TSCA Inventory OSHA Status: Considered hazardous based on the following criteria: Irritant Sensitizer

Target Organs ------------- Lung Skin Eye

OSHA Hazardous Components CAS Number ---------------------------------------------- ------------ CALCIUM CARBONATE (LIMESTONE) 1317-65-3 * CRYSTALLINE SILICA (QUARTZ) 14808-60-7 * CARBON BLACK 1333-86-4 TITANIUM DIOXIDE 13463-67-7 * WHITE MINERAL OIL 8042-47-5 * - CHEMICAL IS LISTED AS AN IARC, NTP, OSHA, or ACGIH CARCINOGEN

Compliance Quantites -------------------- N/A

SARA 311 Ratings ----------------


Order Code: 000000009418014323

Immediate Health Hazard: Y Delayed Health Hazard: Y Fire Hazard: N Reactivity Hazard: N Sudden Release of Pressure Hazard: N SARA 313 Ingredients CAS Number ---------------------------------------------- ------------ No SARA 313 Ingredients

Proposition 65 Ingredients -------------------------- Chemicals known to the State of California to cause cancer, birth defects and/or other reproductive harm. CAS Number --------------------------------------------- ------------ CRYSTALLINE SILICA (QUARTZ) 14808-60-7

------------------------------------------------------------------------------Section 16 - Other Information------------------------------------------------------------------------------ FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN. THE HAZARD INFORMATION HEREIN IS OFFERED SOLELY FOR THE CONSIDERATION OF THE USER, SUBJECT TO HIS OWN INVESTIGATION OF COMPLIANCE WITH APPLICABLE REGULATIONS, INCLUDING THE SAFE USE OF THE PRODUCT UNDER EVERY FORESEEABLE CONDITION.


Tremco Incorporated 3735 Green Road • Beachwood, Ohio 44122 • 216-292-5000 Sealant/Weatherproofing Division Tremco® Mameco/VULKEM® ParamountTM

Technical Services June 16, 2004

Re: ProGlaze® SSG – LEED™ Product Information To Whom It May Concern: Tremco, as an organization, is committed to quality, responsive to internemployees, our community and environment, and we will treat all with re ProGlaze SSG is manufactured in Toronto, Ontario. If Toronto falls withsite, the product is considered to be a locally produced material and canResources - Credit 5. The recycled content by weight is as follows: 30 ctgs (1 case) 0.08% (100% post-consumer) 60 ctg cases (1 pallet) 2.10% (all pallets are made from 100%15 ssgs (1 case) 0.09% (100% post-consumer) 66 ssg cases (1 pallet) 2.19% (all pallets are made from 100%1 x 2 gal pail 0.00% 96 x 2 gal pails (1 pallet) 1.64% (all pallets are made from 100%1 x 5 gal pail 0.00% 36 x 5 gal pails (1 pallet) 1.98% (all pallets are made from 100% ProGlaze SSG contains 0g/L volatile organic content (VOC) and therefoIndoor Environmental Quality standard as established under credit 4. Should you have any questions or require additional information, please Sincerely,



al and external customers, our spect and good stewardship.

in a 500-mile radius of the project help contribute to earning Materials &

reclaimed wood)

reclaimed wood)

reclaimed wood)

reclaimed wood)

re satisfies the LEED criteria for

do not hesitate to contact me.

Proglaze® SSGProglaze® SSG

Product Description:Proglaze SSG is a one-part, highmodulus, neutral cure siliconesealant ideal for a wide variety ofglazing applications. Proglaze SSGprovides high performance capabili-ties as well as an exceptionally fastcure.

Basic Uses:Proglaze SSG is designed to meetthe stringent performance needs forboth Structural and ProtectiveGlazing. Whether it is an unitizedcurtainwall manufactured in plantor a field glazed project, ProglazeSSG offers fast through cure andexceptional tensile strength to meetthe most stringent building codes.

• 2 or 4 sided structural glazing• Impact/Hurricane Tested,

including Miami/Dade protocol• Bomb Blast Mitigation Tested• Structural Silicone Anchor in

retrofit Blast Film applications• Cap, heel or toe bead

All Structural and ProtectiveGlazing designs must be reviewedby Tremco Technical Services.

Limitations:• Do not apply over damp or

contaminated surfaces.• Use with adequate ventilation.

Packaging:1/12 Gallon (300 ml) cartridges, 20 oz. (600 ml) sausages, 4.5 (17.1 L) gallon pails and 50 gallon(189.3 L) drums2 Gallon pails

Color:Black

Applicable Standards:Conforms to ASTM C920 Type S,Grade NS. Use NT, G, A and O andCAN/CGSB-19.13-M87 and U.S.

Federal Specification TT-S-00230C(COM-NBS) Class A, Type II, and U.S.Federal Specification TT-S-001543A(COM-NBS) Class A.

INSTALLATIONJoint Design:Complete joint design and applica-tion methods are available fromyour local Tremco Representative orTremco Technical Service.

Surface Preparation:Substrates for every structural sili-cone glazed project should be sub-mitted for adhesion and compatibil-ity testing by Tremco TechnicalServices prior to commencement ofglazing. The surface preparation(cleaning method and primer ifrequired) for each structural glazingproject will be recommended basedon production run sample substratessupplied by the customer and basedon laboratory testing performed byTremco.

Joint interfaces must be clean, dry,and free from any foreign matterprior to sealant application. Metal,glass and other non-porous surfacesshould be wiped clean with a sol-vent dampened clean towel, fol-lowed immediately by a dry wipewith a clean, lint free towel beforethe solvent evaporates (i.e. 2 ragmethod). Preferred solvent isIsopropyl Alcohol (IPA) or MethylEthyl Ketone (MEK). Follow all pre-cautions on label during handling ofsolvent. A trial application of thesolvent is recommended to ensurethere is not adverse reaction withthe substrates.

Tooling & Cleaning:Tooling is recommended immediate-ly after application to insure firm,intimate contact with the jointinterface. Dry tooling is preferred.Cleaning can be accomplished withsolvents such as IPA or MEK whilesealant is in uncured state.

Structural Glazing Silicone Sealant

Joint BackingBond Breaking Tape:Closed cell polyethylene backer rodsare preferred as joint backing tocontrol depth of sealant bead.Where depth of joint will preventuse of joint backing, an adhesivebacked polyethylene tape should beinstalled to prevent three-sidedadhesion. Joint backing must bedry at time of sealant application.All structural applications must usesilicone compatible spacers whichhave been approved by TremcoTechnical Service.

Application:Proglaze SSG is easy to apply withconventional caulking equipment.Fill joint completely and tool. At75°F (23.9°C), 50% R.H. recordedtooling time is 7 minutes.

Maintenance:Damaged sealant can be repaired.Consult your Tremco FieldRepresentative or Distributor forrepair procedures.


Warranty:Tremco warranties its Sealants to befree of defects in material, butmakes no warranty as to appearance

or color. Since methods of applica-tion and on-site conditions arebeyond our control and can affectperformance, Tremco makes noother warranty, expressed orimplied, including warranties ofMERCHANTABILITY and FITNESS FORA PARTICULAR PURPOSE, withrespect to Sealants. Tremco’s soleobligation shall be, at its option, toreplace, or to refund the purchaseprice of the quantity of Sealantproved to be defective and Tremcoshall not be liable for any loss ordamage.

PRINTED IN THE USA 0405/PSSGSD

Sealant/Weatherproofing Division 3735 Green Road • Beachwood, Ohio • 44122 • Phone: (216) 292-5000 • (800) 321-7906220 Wicksteed Avenue • Toronto, ON M4H 1G7 • Phone: (416) 421-3300 • (800)363-3213

For MSDS and Spec Data Sheets,visit our website:


TYPICAL PHYSICAL PROPERTIESExtrusion rate 33 seconds

Sag (ASTM C-619) None

Tooling Time 5-10 minutes

Tac free time (ASTM C-679) 10-15 minutes

Shore A hardness (ASTM C-661) 40

Tensile (ASTM D-412) 350 psi

Tear strength (ASTM D-624) 67 lbs/in

Peal Adhesion (ASTM C-749)

Aluminum and Glass 60 lbs/in

Elongation (ASTM D-412) 380%


Re: Spectrem® 1 – LEED Product Information To Whom It May Concern: Tremco, as an organization, is committed to quality, responsive to internal and external customers, our employees, our community and environment, and we will treat all with respect and good stewardship. Spectrem 1 is manufactured in Toronto, Ontario. If Toronto falls within a 500-mile radius of the project site, the product is considered to be a locally produced material and can help contribute to earning Materials & Resources - Credit 5. The recycled content by weight is as follows: 30 ctgs (1 case) 0.08% (100% post-consumer) 60 ctg cases (1 pallet) 2.10% (all pallets are made from 100% reclaimed wood)15 ssgs (1 case) 0.09% (100% post-consumer) 66 ssg cases (1 pallet) 2.19% (all pallets are made from 100% reclaimed wood)1 x 2 gal pail 0.00% 96 x 2 gal pails (1 pallet) 1.64% (all pallets are made from 100% reclaimed wood)1 x 5 gal pail 0.00% 36 x 5 gal pails (1 pallet) 1.98% (all pallets are made from 100% reclaimed wood) Spectrem 1 contains 0g/L volatile organic content (VOC) and therefore satisfies the LEED criteria for Indoor Environmental Quality standard as established under credit 4. Should you have any questions or require additional information, please do not hesitate to contact me. Sincerely,



Spectrem® 1Spectrem® 1Ultra Low Modulus SiliconeJoint Sealant

Product Description:Spectrem 1 is an ultra-low modulus,high-performance, one-part, moisture-curing silicone jointsealant.

Basic Uses:Spectrem 1 has exceptional physicalproperties, making it an idealsealant for sealing the mostdemanding dynamically movingjoints. This includes material havinga high coefficient of linear expan-sion such as aluminum curtainwalls,precast concrete panels, metal pan-els and window perimeters.Spectrem 1 is formulated for expan-sion, control, lap joints, and EIFSapplications.



Packaging:1/12 gallon (300mL) cartridges, 20oz. (600mL) sausages, 2 gallon (7.6L) and 4.5 (17 L) gallon pails and55 gallon (208 L) drums.

Standard Colors:Aluminum Stone, AnodizedAluminum, Gray, Limestone, White,Sandstone, Off White, Buff, PrecastWhite, Ivory, Blue Spruce, AdobeTan, Rustic Brick, Dusty Rose,Charcoal, Champagne, Dark Bronze,Bronze, Light Bronze, and Black.

Applicable Standards:Conforms to ASTM C920 Type S,Grade NS, Class 100/50, Use NT, M,G, A and O, ASTM C-1382 andCAN/CGSB-19.13-M87, MCG-2-40-B-Nand U.S. Federal Specification TT-S-001543A (COM-NBS) Class A,and U.S. Federal Specification TT-S-00230C (COM-NBS) Class A,Type II, EIMA Test Method 300.01ASTM C1382.

INSTALLATIONJoint Design:May be used in any joint designedin accordance with accepted archi-tectural/engineering practices.Joint width should be 4-times anticipated movement, but not lessthan 1/4 inch (6.4mm) wide.

Joint Dimensions:For joints 1/4 inch (6.4mm) to 1/2inch (12.7mm) wide, the width todepth ratio should be equal. Joints1/2 inch (12.7mm) wide or greatershould have a depth of 1/2 inch(12.7mm). Minimum joint size is1/4 inch by 1/4 inch (6.4mm by6.4mm).

Surface Preparation:For good adhesion, the joint inter-face must be sound, clean and dry.Depending on the substrates, thejoint surface may require a thor-ough wire brushing, grinding, sand

blasting, solvent washing and/orprimer.

Tooling & Cleaning:Tooling is recommended immediate-ly after application to insure firm,intimate contact with the jointinterface. Dry tooling is preferred.Cleaning can be accomplished withsolvents such as IPA or MEK whilesealant is in an uncured state.

Joint BackingBond Breaking Tape:Closed cell polyethylene backer rodsare preferred as joint backing tocontrol depth of sealant bead.Where depth of joint will preventuse of joint backing, an adhesivebacked polyethylene tape should beinstalled to prevent three-sidedadhesion. Joint backing must bedry at time of the sealant application.

Application:Spectrem 1 is easy to apply withconventional caulking equipment.Fill joint completely and tool. At75˚F (23.9˚C), 50% R.H. a durableskin will form within 10 to 30 min-utes.



Warranty:Tremco warrants its Sealants to befree of defects in material, butmakes no warranty as to appearanceor color. Since methods of applica-tion and on-site conditions arebeyond our control and can affect

performance, Tremco makes noother warranty, expressed orimplied, including warranties ofMERCHANTABILITY and FITNESS FORA PARTICULAR PURPOSE, withrespect to Sealants. Tremco’s soleobligation shall be, at its option, to

replace, or to refund the purchaseprice of the quantity of Sealantproved to be defective and Tremcoshall not be liable for any loss ordamage.

PRINTED IN THE USA 0305/SP1SD

Sealant/Weatherproofing Division 3735 Green Road • Beachwood, Ohio • 44122 • Phone: (216) 292-5000 • (800) 321-7906220 Wicksteed Avenue • Toronto, ON M4H 1G7 • Phone: (416) 421-3300 • (800) 363-3213

TYPICAL PHYSICAL PROPERTIESProperty Test Method Typical Value

As Supplied:Tack-free time ASTM C-679 30-60 min.Curing time 7-14 daysFull Adhesion 14-21 days

Flow, sag or slump ASTM C-639 NilinchesWorking time 10-20 min.

As Cured: After 14 days at 77˚F (25˚C) and 50% R.H.Hardness (Shore A) ASTM C-661 15

Tensile strength at ASTM D-412 1.38 MPa (200 psi)maximum elongation

Tensile strength at ASTM D-412 .24 MPa (35 psi)100% elongation

Tear Strength, die ("C") ASTM D-624 .7 kN/m (40 pli)

Peel Strength ASTM C-794 5.2 kN/m (30 pli)Aluminum, Glass, Concrete

Stain and Color ASTM C-510 Nonechange TT-S-001543A

Joint movement ASTM C-719capabilityExtension +100Compression -50

For MSDS and Spec Data Sheets visit our website:




------------------------------------------------------------------------------------------------ SECTION 1------------------------------------------------------------------------------------------------Order Code: 946803 802

Product Name: SPECTREM 1 Chemical Name: Chemical Family: Sealant Product Code: 946-8XX Date Prepared: 22-NOV-02 MSDS Preparer: R. A. MIKOL Replaces Date: 04-AUG-99

Other Applications: This Material Safety Data Sheet(MSDS) applies to the following: 946-801(BRONZE), 946-802(BLACK), 946-803(OFF-WHITE) 946-805(LIMESTONE), 946-811(PRECAST WHITE), 946-851(ALUMINUM STONE), AND 946-8XX & 7XX (OTHER COLORS)--------------------------------------------------------------------------------Section 2 - Molecular Compostion--------------------------------------------------------------------------------Common Name and Chemical Name Weight % CAS Number Exposure Limits


SILICONE POLYMER 30.0-40.0 Trade Secret OSHA:TWA - STEL - ACGIH:TWA - STEL -

POLYDIMETHYLSILOXANE, TRIMETHYL ENDCAP 10.0-15.0 63148-62-9 OSHA:TWA - STEL - ACGIH:TWA - STEL -

AMINOSILANE 1.0-5.0 Trade Secret OSHA:TWA - STEL - ACGIH:TWA - STEL -



STEARIC ACID 1.0-3.0 57-11-4 OSHA:TWA 15 mg/M3 STEL - (total dust) ACGIH:TWA 10 mg/M3 STEL - (total dust)



IRON OXIDE 0.0-3.0 1309-37-1 OSHA:TWA 10 mg/M3 STEL - (dust,fume as Fe) ACGIH:TWA 5 mg/M3 STEL - (fume as Fe)

------------------------------------------------------------------------------Section 3 - Hazards Identification------------------------------------------------------------------------------****************************************************************************** Emergency Overview: Various colored pastes. If inhaled, can cause headache, dizziness, irritation to respiratory system. Leave area to breathe fresh air. Avoid further overexposure. If sysptoms persist, get medical attention immediately.

112 23 2Product 946-8XX Page 1 of 5

Order Code: 946803 802

****************************************************************************** Potential Hlth Effect/Rte of Entry: ----------------------------------- Inhalation: Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system. Eyes: Can cause irritation, burns. Ingestion: Can cause burns to stomach, mouth and throat. Skin: Can cause irritation, burns.

Aggravated Medical Conditions: Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.

Acute Health Effects: See effects described above.

Chronic Health Effects: As by-products of manufacturing and curing (due to hydrolysis), sec-butylamine (TLV=5 ppm-ceiling) and cyclohexylamine (PEL,TLV=10 ppm TWA) can be released within the product. Overexposure to amines can cause severe irritation to skin, eyes and respiratory system, conjunctivities, injury to respiratory tract, burns to mouth, throat and stomach. Cyclohexylamine is toxic by ingestion., inhalation and skin absorption. Positive results in some mutagenicity assays and reproductive studies in experimental animals have been reported in the literature. Effects of overexposure to sec-butylamine include eyes, nose and throat irritation, headache and flushing of the skin of the face and skin burns. No serious health effects have been established in man when exposed to carbon black. Inflammation,lung fibrosis, and lung tumors have been observed in animals at levels which overloaad lung clearance mechanisms. Carbon black contains varying amounts of polynuclear aromatic compounds (PNA's) which have been found to cause cancer in animals. Solvent extracts of carbon black are carcinogenic to the skin of mice. It is classified by IARC to be a known animalcarcinogen and a possible human carcinogen (Group 2B). Fillers are encapsulated and not expected to be released from product under normal conditions of use.

------------------------------------------------------------------------------Section 4 - First Aid Measures------------------------------------------------------------------------------ Inhalation: Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention immediately. Eyes: Flush immediately with running water for 15 minutes, lifting the upper and lower lids occasionally. Get medical attention immediately. Ingestion: Get medical attention immediately. Skin: Wash area of contact thoroughly with hand cleaner followed by soap and water. If irritation, rash or other disorders develop, get medical attention immediately. Notes to Physician: N/A

------------------------------------------------------------------------------Section 5 - Fire Fighting Measures------------------------------------------------------------------------------ Flash Point: N/A Method: N/A Lower Flammability Limit: N/A Upper Flammability Limit: N/A Autoignition Temperature: Not Established



Extinguishing Media: Water fog. Fire and Explosion Hazards: Not Applicable Special Fire Fighting Procedures: During a fire, personnel at the scene are to prevent exposure to fumes using accepted fire fighting techniques. Fire Fighting Equipment: N/A Other Precautions: Oxides of nitrogen and silicon can form.


------------------------------------------------------------------------------Section 7 - Handling and Storage------------------------------------------------------------------------------Handling and Storage Precautions: Store under normal warehouse conditions. Prevent inhalation of vapor, ingestion, and contact with skin and eyes. Keep container closed when not in use. Precautions also apply to emptied containers. Change soiled workclothes frequently. Clean hands thoroughly after handling.

------------------------------------------------------------------------------Section 8 - Exposure Controls/Personal Protection------------------------------------------------------------------------------ Respiratory: Wear appropriate, properly fitted NIOSH/MSHA approved respirator when the airborne contaminant level(s) exceed the exposure limits indicated on the MSDS. Follow respirator manufacturer's directions for respirator use. Skin: Protect hands with impervious rubber gloves and wear typical full cover clothing. Prevent contact with skin. Eyes: Wear suitable safety eyewear. Face: Not required.

Engineering: Use local exhaust when the general ventilation is not sufficient to keep the airborne contaminant concentration below the exposure limit in Section 2 of the MSDS.

------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties------------------------------------------------------------------------------ Odor/Appearance: AMINE/VARIOUS COLORED PASTE Color: VARIOUS Physical State: Paste pH: N/A Vapor Pressure: N/A Vapor Density: N/A Boiling Point: N/A Melting Point: N/A Freezing Point: N/A Solubility in Water: Negligible Specific Gravity: 1.35 % Volatile Weight: 0.0

------------------------------------------------------------------------------Section 10 - Reactivity/Stability------------------------------------------------------------------------------



Stability: Stable Incompatible Products: Avoid contact with strong oxidizing agents. Conditions to Avoid Polymerization: Hazardous polymerization will not occur. Decomposition Products: At temperatures over 300 F formaldehyde is a by product of oxidative thermal decomposition of dimethylsiloxane. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. This material releases cyclohexylamine and secondary-butylamine during hydrolysis (curing).

------------------------------------------------------------------------------Section 11 - Toxicological Information------------------------------------------------------------------------------ Eyes: See Section 3 Ingestion: " " " Inhalation: " " " Skin: " " " Subchronic: " " " Chronic: " " "

------------------------------------------------------------------------------Section 12 - Ecological Information------------------------------------------------------------------------------ Ecotoxicological Data: N/A Chemical Fate: N/A

------------------------------------------------------------------------------Section 13 - Disposal Considerations------------------------------------------------------------------------------ RCRA Class: N/A Disposal Method: Not regulated by RCRA. Dispose of in compliance with state and local regulations. EPA Reportable Quantities ------------------------- N/A

------------------------------------------------------------------------------Section 14 - Transportation Data------------------------------------------------------------------------------ DOT Shipping Name: NOT REGULATED DOT Hazard Class: DOT Label: UN/NA Number: Packing Group: Special Provisions: Packaging --------- Exceptions: Non-Bulk: Bulk: Quantity Limitations -------------------- Passenger Aircraft or Railcar: Cargo Aircraft: Vessel Stowage Requirements --------------------------- Vessel Stowage: Other Stowage: Transportation Notes: N/A

------------------------------------------------------------------------------Section 15 - Regulatory Information



------------------------------------------------------------------------------ TSCA Status: On the TSCA Inventory OSHA Status: Considered hazardous based on the following criteria: Corrosive Irritant

Target Organs ------------- Lung Skin Eye Mouth,Throat Central Nervous System

OSHA Hazardous Components CAS Number ---------------------------------------------- ------------ CALCIUM CARBONATE (LIMESTONE) 1317-65-3 CARBON BLACK 1333-86-4 TITANIUM DIOXIDE 13463-67-7 IRON OXIDE 1309-37-1

Compliance Quantites -------------------- N/A SARA 311 Ratings ---------------- Immediate Health Hazard: Y Delayed Health Hazard: Y Fire Hazard: Y Reactivity Hazard: N Sudden Release of Pressure Hazard: N

SARA 313 Ingredients -------------------- No SARA 313 Ingredients

Proposition 65 Ingredients -------------------------- No Proposition 65 Ingredients




Re: Spectrem® 2– LEED Product Information Tremco, as an organization, is committed to quality, responsive to internal and external customers, our employees, our community and environment, and we will treat all with respect and good stewardship. Spectrem 2 is manufactured in Toronto, Ontario. If Toronto falls within a 500-mile radius of the project site, the product is considered to be a locally produced material and can help contribute to earning Materials & Resources - Credit 5. The recycled content by weight is as follows: 30 ctgs (1 case) 0.08% (100% post-consumer) 60 ctg cases (1 pallet) 2.17% (all pallets are made from 100% reclaimed wood) 15 ssgs (1 case) 0.08% (100% post-consumer) 66 ssg cases (1 pallet) 2.05% (all pallets are made from 100% reclaimed wood) 1 x 2 gal pail 0.00% 96 x 2 gal pails (1 pallet) 1.64% (all pallets are made from 100% reclaimed wood) 1 x 5 gal pail 0.00% 36 x 5 gal pails (1 pallet) 1.98% (all pallets are made from 100% reclaimed wood) 1 x 55 gal drum 2.27% (.38% post-consumer and 1.89% post-industrial) 4 x 55 gal drum (1 pallet) 3.77% (all pallets are made from 100% reclaimed wood) Spectrem 2 contains 0g/L volatile organic content (VOC) and therefore satisfies the LEED criteria for Indoor Environmental Quality standard as established under credit 4. Should you have any questions or require additional information, please do not hesitate to contact me. Sincerely,



Spectrem 2Spectrem® 2High-Performance Silicone Sealant

Product Description:Spectrem 2 is a medium-modulus, one-part, high-performance, neutral-cure silicone sealant ideal for a variety of perimeter caulking and glazing applications. Basic Uses:• Two-sided structural glazing• Perimeter and weather seals• CAP, Heel and Toe Beads• Curtainwall or window joints

Spectrem 2 may be used on sub-strates such as aluminum, glass, steel, painted metal, plastic, stone, concrete and brick. Spectrem 2 exhibits primerless adhesion to many common building materials.

“All” Structural Glazing Appli-cations must be reviewed and approved by Tremco Technical Service prior to the application of Spectrem 2.

Limitations:• Do not apply to damp or contaminated surfaces.• Use with adequate ventilation.• Clear silicones are not recommended for structural glazing applications.

Packaging:1/12 gallon (300mL) cartridges, 20 oz. (600mL) sausages, 2 gallon (7.6 L) and 4.5 gallon (17 L) pails and 55 gallon (208.2 L) drums.

Standard Colors:White, Off-White, Clear, Gray, Bronze, Light Bronze, Limestone, Black, Aluminum Stone, Anodized Aluminum, Precast White, Adobe Tan, Blue Spruce, Buff, Charcoal, Champagne, Dark Bronze, Dusty Rose, Ivory, Rustic Brick and Sandstone.

Applicable Standards:Conforms to ASTM C920 Type S, Grade NS, Class 50, Use NT, M, G, A and O, CAN/CGSB-19.13-M87, U.S.

Federal Specification TT-S-001543A (COM-NBS) Class A, and U.S. Federal Specification TT-S-00230C (COM-NBS) Class A, Type II. Black Spectrem 2 meets all of AAMA 802.3-92 (Type I and II), 805.2-94 (Group C), and 808.3-92.INSTALLATIONJoint Design:May be used in any joint designed in accordance with accepted architec-tural/engineering practices. Joint width should be 4 times anticipated movement, but not less than 1/4 inch (6.4mm) wide.

Joint Dimensions:For joints 1/4 inch (6.4mm) to 1/2 inch (12.7mm) wide, the width to

depth ratio should be equal. Joints 1/2 inch (12.7mm) wide or greater should have a depth of 1/2 inch (12.7mm). Minimum joint size is 1/4 inch by 1/4 inch (6.4mm by 6.4mm).

Surface Preparation:For good adhesion, the joint inter-face must be sound, clean and dry. Depending on the substrates, the joint surface may require a thorough

wire brushing, grinding, sandblast-ing, solvent washing and/or primer.

Tooling & Cleaning:Tooling is recommended immedi-ately after application to insure firm, intimate contact with the joint interface. Dry tooling is preferred. Cleaning can be accomplished with solvents such as Xylene, Toluene or MEK while sealant is in an uncured state.

Joint Backing-Bond Breaking Tape:Closed cell polyethylene backer rods are preferred as joint backing to control depth of sealant bead. Where depth of joint will prevent

use of joint backing, an adhesive-backed polyethylene tape should be installed to prevent three-sided adhesion. Joint backing must be dry at time of sealant application.

Application:

Spectrem 2 is easy to apply with conventional caulking equipment. Fill joint completely and tool. At 75˚F (23.9˚C), 50% R.H. a durable skin will form typically within less than 10 minutes. Please visit trem-cosealants.com for complete appli-cation instructions.

Maintenance:Damaged sealant can be repaired. Consult your Tremco Distributor or Representative for repair proce-dures.

Availability:Immediately available from your local Tremco Field Representative, Tremco Distributor or Tremco Warehouse.

Warranty:Tremco warranties its Sealants to be free of defects in material, but makes no warranty as to appear-ance or color. Since methods of application and on-site conditions are beyond our control and can affect performance, Tremco makes no other warranty, expressed or implied, including warranties of MERCHANTABILITY and FITNESS FOR A PARTICULAR PURPOSE, with respect to Sealants. Tremco’s sole obligation shall be, at its option, to replace, or to refund the purchase price of the quantity of Sealant proved to be defective and Tremco shall not be liable for any loss or damage.

PRINTED IN THE USA 1004/SPEC2SD



1451 Jacobson Avenue • Ashland, Ohio • 44805 • Phone: (800) 321-6357 • Fax (419) 289-6645

For MSDS and Spec Data Sheets, or visit our website:


TYPICAL PHYSICAL PROPERTIESProperty Test Method Typical ValueAs Supplied:Tack-free time ASTM C-679 20-40 minutes

Sag ASTM D-2202 0-0.1mm (0-0.03")

Tooling Time Skin formation 7-15 minutes

As Cured: After 14 days at 77˚F (25˚C) and 50% R.H.

Hardness (Shore A) ASTM C-661 37-40

Tensile strength at ASTM D-412 1.52-1.59 MPa (220-230 psi)maximum elongationElongation ASTM D-412 235-260%

Tensile Strength ASTM C-1135 0.62-0.69 MPa (90-100 psi)at 100% elongation

Tear Strength ASTM D-624 6.14-7.02 kN/m (35-40 pli)

Peel Strength ASTM C-794 2.81-3.86 kN/m (16-22 pli)Aluminum, Glass

Cyclic movement ASTM C-719 ±50%

NOTE: The foregoing information is published as general information only. The listed properties and performance characteristics are approximate values and are not part of the product specification.




Product Name: SPECTREM 2 Chemical Name: Chemical Family: Sealant Product Code: 947-8XX Date Prepared: 07-JUL-00 MSDS Preparer: R. A. MIKOL Replaces Date: 05-AUG-99

Other Applications: This Material Safety Data Sheet (MSDS) applies to the following: 947-801 (Bronze),-802 (Black),-803 (Off-White),-806 (White), -852 (Graystone),-853 (Gray),-7XX & -8XX (Other colors)

--------------------------------------------------------------------------------Section 2 - Molecular Composition--------------------------------------------------------------------------------Common Name and Chemical Name Weight % CAS Number Exposure Limits




SILICA, AMORPHOUS, FUMED 1.0-5.0 112945-52-5 OSHA:TWA 15 mg/M3 STEL - (total nuisance dust) ACGIH:TWA 10 mg/M3 STEL - (total nuisance dust)

OXIMINO SILANE 1.0-5.0 Trade Secret OSHA:TWA - STEL - ACGIH:TWA - STEL -





------------------------------------------------------------------------------Section 3 - Hazards Identification------------------------------------------------------------------------------

****************************************************************************** Emergency Overview: Various colored pastes. If inhaled can cause headache,dizziness,irritation to respiratory system. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention immediately.******************************************************************************

Potential Hlth Effect/Rte of Entry: -----------------------------------



Inhalation: Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system. Eyes: Can cause severe irritation. Ingestion: Can cause gastrointestinal irritation. Skin: Can cause irritation, possible dermal sensitization. Methyl Ethyl Ketoxime may be absorbed through the skin.

Aggravated Medical Conditions: Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.


Chronic Health Effects: During cure, up to 2% Methyl Ethyl Ketoxime (MEKO) may be released. MEKO has caused allergic skin reactions and liver tumors in animals. Overexposure to MEKO may cause blood effects (methemoglobinemia and anemia). However, due to the extremely low vapor pressure of MEKO (<8mm Hg @ 68F), release of high airborne concentration is not expected under normal conditions of use. No serious health effects have been established in man when exposed to carbon black. Inflammation, lung fibrosis, and tumors have been observed in animals at levels which overload lung clearance mechanisms. Carbon black contains varying amounts of polynuclear aromatic compounds (PNA's) which have been found to cause cancer in animals. Solvent extracts of carbon black are carcinogenic to the skin of mice. It is classified by IARC to be a known animal carcinogen and a possible human carcinogen (Group 2B). Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient evidence in humans (Group 1). Prolonged and repeated overexposure to crystalline silica dust above the TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis may result from breathing free silica. Fillers are encapsulated and not expected to be released from product under normal conditions of use.

------------------------------------------------------------------------------Section 4 - First Aid Measures------------------------------------------------------------------------------ Inhalation: Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention immediately. Eyes: Flush immediately with running water for 15 minutes, lifting the upper and lower lids occasionally. Get medical attention immediately. Ingestion: Get medical attention immediately. Skin: Wash area of contact thoroughly with hand cleaner followed by soap and water. If irritation, rash or other disorders develop, get medical attention immediately.

Notes to Physician: N/A

------------------------------------------------------------------------------Section 5 - Fire Fighting Measures------------------------------------------------------------------------------ Flash Point: N/A Method: N/A Lower Flammability Limit: N/A Upper Flammability Limit: N/A Autoignition Temperature: N/A Extinguishing Media:



Water fog. Fire and Explosion Hazards: Not Applicable Special Fire Fighting Procedures: During a fire, personnel at the scene are to prevent exposure to fumes using accepted fire fighting techniques. Fire Fighting Equipment: N/A Other Precautions: Not Applicable


------------------------------------------------------------------------------Section 7 - Handling and Storage------------------------------------------------------------------------------Handling and Storage Precautions: Store under normal warehouse conditions. Prevent inhalation of vapor, ingestion, and contact with skin and eyes. Keep container closed when not in use. Precautions also apply to emptied containers. Change soiled workclothes frequently. Clean hands thoroughly after handling. Personal protective equipment must be worn during maintenance or repair of contaminated mixer, reactor, or other equipment.

------------------------------------------------------------------------------Section 8 - Exposure Controls/Personal Protection------------------------------------------------------------------------------ Respiratory: Wear NIOSH/MSHA approved respirator as directed by the manufacturer when the ventilation is not adequate. Skin: Protect hands with impervious rubber gloves and wear typical full cover clothing. Prevent contact with skin. Eyes: Wear suitable safety eyewear. Face: Not required. Engineering: Use local exhaust when the general ventilation is not adequate.

------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties------------------------------------------------------------------------------ Odor/Appearance: OXIME/VARIOUS COLORED PASTE Color: VARIOUS Physical State: PASTE pH: N/A Vapor Pressure: N/A Vapor Density: N/A Boiling Point: N/A Melting Point: N/A Freezing Point: N/A Solubility in Water: NEGLIGIBLE Specific Gravity: 1.34 % Volatile Weight: 0.0

------------------------------------------------------------------------------Section 10 - Reactivity/Stability------------------------------------------------------------------------------ Stability: Stable Incompatible Products:



Avoid contact with strong oxidizing agents. Conditions to Avoid Polymerization: Hazardous polymerization will not occur.

------------------------------------------------------------------------------Section 11 - Toxicological Information------------------------------------------------------------------------------ Eyes: SEE SECTION 3 Ingestion: " " " Inhalation: " " " Skin: " " " Subchronic: " " " Chronic: " " "


------------------------------------------------------------------------------Section 13 - Disposal Considerations------------------------------------------------------------------------------ RCRA Class: N/A Disposal Method: Not regulated by RCRA. Dispose of in compliance with state and local regulations.

EPA Reportable Quantities ------------------------- N/A

------------------------------------------------------------------------------Section 14 - Transportation Data------------------------------------------------------------------------------ DOT Shipping Name: NOT REGULATED

DOT Hazard Class: DOT Label: UN/NA Number: Packing Group: Special Provisions: Packaging --------- Exceptions: Non-Bulk: Bulk:

Quantity Limitations -------------------- Passenger Aircraft or Railcar: Cargo Aircraft: Vessel Stowage Requirements --------------------------- Vessel Stowage: Other Stowage:

Transportation Notes: N/A

------------------------------------------------------------------------------Section 15 - Regulatory Information------------------------------------------------------------------------------ TSCA Status: On the TSCA Inventory OSHA Status: Considered hazardous based on the following criteria: Irritant



Target Organs ------------- Liver Kidney Blood Lung Skin Eye Spleen

OSHA Hazardous Components CAS Number ---------------------------------------------- ------------ CALCIUM CARBONATE (LIMESTONE) 1317-65-3 SILICA, AMORPHOUS, FUMED 112945-52-5 * CARBON BLACK 1333-86-4 TITANIUM DIOXIDE 13463-67-7 IRON OXIDE 1309-37-1 * CRYSTALLINE SILICA (QUARTZ) 14808-60-7 * - CHEMICAL IS LISTED AS AN IARC, NTP, OSHA, or ACGIH CARCINOGEN

Compliance Quantities -------------------- No Compliance Quantities

SARA 311 Ratings ---------------- Immediate Health Hazard: Y Delayed Health Hazard: Y Fire Hazard: N Reactivity Hazard: N Sudden Release of Pressure Hazard: N


Proposition 65 Ingredients -------------------------- Chemicals known to the State of California to cause cancer, birth defects and/or other reproductive harm. CAS Number ------------------------------------------- ------------ CRYSTALLINE SILICA (QUARTZ) 14808-60-7




Re: Spectrem® 3 – LEED Product Information To Whom It May Concern: Tremco, as an organization, is committed to quality, responsive to internal and external customers, our employees, our community and environment, and we will treat all with respect and good stewardship. Spectrem 3 is manufactured in Toronto, Ontario. If Toronto falls within a 500-mile radius of the project site, the product is considered to be a locally produced material and can help contribute to earning Materials & Resources - Credit 5. The recycled content by weight is as follows: 30 ctgs (1 case) 0.07% (100% post-consumer) 60 ctg cases (1 pallet) 1.92% (all pallets are made from 100% reclaimed wood) 15 ssgs (1 case) 0.08% (100% post-consumer) 66 ssg cases (1 pallet) 2.05% (all pallets are made from 100% reclaimed wood) 1 x 2 gal pail 0.00% 96 x 2 gal pails (1 pallet) 1.64% (all pallets are made from 100% reclaimed wood) 1 x 5 gal pail 0.00% 36 x 5 gal pails (1 pallet) 1.98% (all pallets are made from 100% reclaimed wood) Spectrem 3 contains 0g/L volatile organic content (VOC) and therefore satisfies the LEED criteria for Indoor Environmental Quality standard as established under credit 4. Should you have any questions or require additional information, please do not hesitate to contact me. Sincerely,



Spectrem 3Spectrem® 3Non-Staining, Long Tooling Time, Low-Modulus Silicone Sealant

Product Description:A general-purpose, low-modulus,high-performance, one-part, neutral-curing, non-staining, construction-grade silicone sealant.

Basic Uses:Spectrem 3 has been formulated tooffer exceptional physical proper-ties, making it ideal for sealingdynamically moving joints associat-ed with material having a highcoefficient of linear expansion suchas EIFS, aluminum curtain walls,metal panels and window perime-ters. This patented formula hasextended the tooling time at hightemperatures. Spectrem 3 provideshigh performance capabilities andthe unique ability to apply in bulkover a broad temperature range.

Limitations:•Do not apply to damp or

contaminated surfaces.•Use with adequate ventilation.

Packaging:1/12 gallon (300mL) cartridges, 20.3 oz. (600mL) sausages, 2 gallon(7.6 L) and 4.5 gallon (17 L) pailsand 55 gallon (208.2 L) drums.

Standard Colors:Adobe Tan, Aluminum Stone,Anodized Aluminum, Black, BlueSpruce, Bronze, Buff, Charcoal,Champagne, Dark Bronze, DustyRose, Gray, Ivory, Light Bronze,Limestone, Off White, Precast White,Rustic Brick, Sandstone and White.

Applicable Standards:Conforms to ASTM C920 Type S,Grade NS, Class 50, use NT, G, M, Aand O and CAN/CGSB-19.13-M87,U.S. Federal Specification TT-S-

00230 Class A, and U.S. FederalSpecification TT-S-001543A Class A,ASTM C1382, EIMA Test Method300.01

INSTALLATIONJoint Design:May be used in any joint designedin accordance with accepted archi-tectural/engineering practices.Joint width should be 4 times antic-ipated movement, but not less than1/4 inch (6.4mm) wide.

Joint Dimensions:For joints 1/4 inch (6.4mm) to 1/2inch (12.7mm) wide, the width todepth ratio should be equal. Joints1/2 inch (12.7mm) wide or greatershould have a depth of 1/2 inch

(12.7mm). Minimum joint size 1/4inch by 1/4 inch (6.4mm by6.4mm).

Surface Preparation:For good adhesion, the joint inter-face must be sound, clean and dry.Depending on the substrates, thejoint surface may require a thor-ough wire brushing, grinding, sand-blasting, solvent washing and/orprimer.

Tooling & Cleaning:Tooling is recommended immediate-ly after application to ensure firm,intimate contact with the jointinterface. Dry tooling is preferred.Cleaning can be accomplished withsolvents such as IPA or MEK whilesealant is in an uncured state.

Joint BackingBond Breaking Tape:Closed cell polyethlyene backer rodsare preferred as joint backing to con-trol depth of sealant bead. Wheredepth of joint will prevent use ofjoint backing, an adhesive backedpolyethylene tape should be installedto prevent three-sided adhesion.Joint backing must be dry at time ofsealant application.

Application:Spectrem 3 is easy to apply withconventional caulking equipment.Fill joint completely and tool. At 75˚F (23.9˚C), 50% R.H. tooling timeis 1 hour.

Maintenance:Damaged sealant can be repaired.Consult your Tremco Distributor orRepresentative for repair procedures.


Warranty:Tremco warrants its Sealants to befree of defects in material. Butmakes no warranty as to appearanceor color. Since method of applica-tion and on-site conditions arebeyond our control and can affectperformance, Tremco makes no otherwarranty, expressed or implied,including warranties of MER-CHANTABILITY and FITNESS FOR APARTICULAR PURPOSE, with respectto Sealants. Tremco’s sole obligationshall be at, its option, to replace, orto refund the purchase price of thequantity of Sealant proved to bedefective and Tremco shall not beliable for any loss or damage.

PRINTED IN THE USA 0604/SP3SD

TYPICAL PHYSICAL PROPERTIESAs Supplied:ASTM C-679 Tooling Time 90 minutes

ASTM C-510 Stain and Color change None (TT-S-001543A)

ASTM C-719 Joint movement capabilityExtension Compression ±50%

As Cured: After 14 days at 25˚C (77˚F) and 50% R.H.

ASTM C-661 Hardness; Shore “A” 15After 14 days at 25˚C (77˚F).

ASTM D-412 Tensile Strength at Max Elongation 140 psi100% Modulus 16 psi

ASTM D-624 Tear Strength (die “C”) 25 pli min.

ASTM C-794 Peel Strength Aluminum, Glass, Concrete 15 pli min.Temperature Range -40˚F to +300˚F

NOTE: The foregoing information is published as general information only. The listedproperties and performance characteristics are approximate values and are not part ofthe product specification.

For MSDS and Spec Data Sheets,visit our website:

www.tremcosealants.com Sealant/Weatherproofing Division





Product Name: SPECTREM 3 Chemical Name: Chemical Family: Sealant Product Code: 968-8XX Date Prepared: 04-MAR-99 MSDS Preparer: R. A. MIKOL Replaces Date: N/A

Other applications: THIS MATERIAL SAFETY DATA SHEET APPLIES TO THE FOLLOWING: 968-801(BRONZE),-802(BLACK),-803(OFF-WHITE),-804(REDWOOD TAN),-805(LIMESTONE) -806(WHITE),-807(BUFF),-811(PRECAST WHITE),-824(HARTFORD GREEN),-831 (DARK GRAY),-858(IVORY),-878(ANODIZED ALUMINUM),-896(ALUMINUM),-897(GRAY) & -8XX AND 7XX (OTHER COLORS).--------------------------------------------------------------------------------Section 2 - Molecular Composition--------------------------------------------------------------------------------Common Name and Chemical Name Weight % CAS Number Exposure Limits

POLYMERS 60.0-80.0 Trade Secret OSHA:TWA - STEL - ACGIH:TWA - STEL -

CALCIUM CARBONATE 8.0-20.0 471-34-1 OSHA:TWA 15 mg/M3 STEL - (total dust, 5mg/M3 respirable fraction) ACGIH:TWA 10 mg/M3 STEL - (total dust, no asbestos, <1% SiO2)

PLASTICIZER 5.0-15.0 Trade Secret OSHA:TWA 5 mg/M3 STEL - ACGIH:TWA 5 mg/M3 STEL 10 mg/M3


OXIMOSILANE 1.0-5.0 22984-54-9 OSHA:TWA - STEL - ACGIH:TWA - STEL -

AMINOSILANE 0.5-2.0 1760-24-3 OSHA:TWA - STEL - ACGIH:TWA - STEL -

IRON OXIDE 0.0-5.0 1309-37-1 OSHA:TWA 10 mg/M3 STEL - (dust, fume as Fe) ACGIH:TWA 5 mg/M3 STEL - (fume as Fe)



------------------------------------------------------------------------------Section 3 - Hazards Identification------------------------------------------------------------------------------****************************************************************************** Emergency Overview: Various color pastes. If inhaled can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system. Leave area to breathe fresh air. Avoid further exposure. If symptoms persist, get medical attention.****************************************************************************** Potential Hlth Effect/Rte of Entry:



----------------------------------- Inhalation: Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system. Eyes: Can cause irritation. Ingestion: Can cause gastrointestinal irritation. Skin: Can cause irritation.

Aggravated Medical Conditions: Pre-existing eye, skin, respiratory, and liver disorders may be aggravated by exposure.


Chronic Health Effects: During cure, up to 2% Methyl Ethyl Ketoxime (MEKO) may be released. MEKO has caused allergic skin reactions and liver tumors in animals. Overexposure to MEKO may cause blood effects (methemoglobinemia and anemia). However, due to the extremely low vapor pressure of MEKO (<8mm Hg @20C), release of high airborne concentrations is not expected under normal conditions of use. Prolonged or repeated exposure (orally or by inhalation) of the plasticizer to rats produced decreased body weights, spleen and sex organ changes, increased liver and kidney weights, reduced food consumption, and effects on the liver, testes and pancreas. Birth defects have been reported in mice and rats at dose levels of the plasticizer that produce significant toxicity in the mother and offspring. However, birth defects have not been observed in rabbits. Evidence of the carcinogenicity of the plasticizer has been mixed. An initial NTP study of the effects of the plasticizer has reported an increased incidence of mononuclear cell leukemias in female rats, a commonly occuring spontaneous disease in this strain, but no increase in tumors in mice. However, a repeat study has not found an increase in leukemias, although an increase in kidney and bladder lesions in females and in pancreatic tumors in males was noted. Furthermore, a concurrent study that restricted diet also has not revealed any increase in tumors in male and female rats. Numerous studies also have indicated that the plasticizer is not genotoxic.

No serious health effects have been established in man when exposed to carbon black but inflammation, lung fibrosis, and lung tumors have been observed in animals at levels which overload lung clearance mechanisms. Carbon black contains varying amounts of of polynuclear aromatic compounds (PNA's) which have been found to cause cancer in animals. Solvent extracts of carbon black are carcinogenic to the skin of mice. Carbon black is classified by IARC to be a known animal carcinogen and a possible human carcinogen (Group 2B). Fillers are encapsulated and not expected to be released from product under normal conditions of use.

------------------------------------------------------------------------------Section 4 - First Aid Measures------------------------------------------------------------------------------ Inhalation: Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention immediately. Eyes: Flush immediately with running water for 15 minutes, lifting the upper and lower lids occasionally. Get medical attention immediately. Ingestion: Get medical attention immediately. Skin: Wash area of contact thoroughly with hand cleaner followed by soap and water. If irritation, rash or other disorders develop, get medical



attention immediately. Notes to Physician: N/A

------------------------------------------------------------------------------Section 5 - Fire Fighting Measures------------------------------------------------------------------------------ Flash Point: >200 F Method: SETA Lower Flammability Limit: N/A Upper Flammability Limit: N/A Autoignition Temperature: N/A

Extinguishing Media: Water fog.

Fire and Explosion Hazards: Not Applicable

Special Fire Fighting Procedures: During a fire, personnel at the scene are to prevent exposure to fumes using accepted fire fighting techniques.

Fire Fighting Equipment: N/A

Other Precautions: Oxides of silicon can form.




------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties------------------------------------------------------------------------------ Odor/Appearance: MILD OXIME/VARIOUS COLOR PASTES Color: VARIOUS Physical State: PASTE pH:



Vapor Pressure: NOT ESTABLISHED Vapor Density: N/A Boiling Point: >200 F Melting Point: N/A Freezing Point: N/A Solubility in Water: NEGLIGIBLE Specific Gravity: 1.1 % Volatile Weight: 0.0

------------------------------------------------------------------------------Section 10 - Reactivity/Stability------------------------------------------------------------------------------ Stability: Stable Incompatible Products: Avoid contact with oxidizing agents, strong acids and bases. Conditions to Avoid Polymerization: Hazardous polymerization will not occur.





------------------------------------------------------------------------------Section 14 - Transportation Data------------------------------------------------------------------------------ DOT Shipping Name: NOT REGULATED DOT Hazard Class: DOT Label: UN/NA Number: N/A Packing Group: Special Provisions: Packaging --------- Exceptions: Non-Bulk: Bulk: Quantity Limitations -------------------- Passenger Aircraft or Railcar: Cargo Aircraft: Vessel Stowage Requirements



--------------------------- Vessel Stowage: Other Stowage:




OSHA Hazardous Components CAS Number ---------------------------------------------- ------------ CALCIUM CARBONATE 471-34-1 PLASTICIZER Trade Secret POLYMERS Trade Secret * CARBON BLACK 1333-86-4 * - CHEMICAL IS LISTED AS AN IARC, NTP, OSHA, or ACGIH CARCINOGEN

Compliance Quantites -------------------- N/A

SARA 311 Ratings ---------------- Immediate Health Hazard: N Delayed Health Hazard: N Fire Hazard: N Reactivity Hazard: N Sudden Release of Pressure Hazard: N

SARA 313 Ingredients CAS Number ---------------------------------------------- ------------ No SARA 313 Ingredients

Proposition 65 Ingredients -------------------------- WARNING:This product contains chemicals known to the State of California to cause cancer, birth defects and/or other reproductive harm. CAS number ------------------------------------------ ------------ CRYSTALLINE SILICA (QUARTZ) (<0.05%) 14808-60-7




Re: Spectrem® 4-TS – LEED Product Information To Whom It May Concern: Tremco, as an organization, is committed to quality, responsive to internal and external customers, our employees, our community and environment, and we will treat all with respect and good stewardship. Spectrem 4TS is manufactured in Toronto, Ontario. If Toronto falls within a 500-mile radius of the project site, the product is considered to be a locally produced material and can help contribute to earning Materials & Resources - Credit 5. The recycled content by weight is as follows: 1 x 2 gal pail 0.00% 96 x 2 gal pails (1 pallet) 2.60% (all pallets are made from 100% reclaimed wood) Spectrem 4TS contains 0g/L volatile organic content (VOC) and therefore satisfies the LEED criteria for Indoor Environmental Quality standard as established under credit 4. Should you have any questions or require additional information, please do not hesitate to contact me. Sincerely,



BEST CHOICE

EIFSSpectrem 4-TS

Product Description:Spectrem 4-TS is a multi-compo-nent, neutral-curing, non-staining, low dirt pick up, low-modulus sili-cone sealant specially formulated for use in dynamically moving building joints with +/- 50% move-ment.

Basic Uses:Spectrem 4-TS offers excellent per-formance in moving joints for both new construction and renovation projects. Spectrem 4-TS is the only silicone available offering color flexibility, with the opportunity to tint the material on site. Spectrem 4-TS does not require a primer on most construction materials and exhibits tenacious adhesion once fully cured. Typical applications for Spectrem 4-TS include: EIFS, expan-sion and control joints, tilt-up panel joints, precast concrete panel joints, perimeter caulking (windows, door, panels), etc.

Limitations:• Do not apply over damp or contaminated surfaces.• Not intended for continuous water immersion.

Packaging:1-1/2 gallon (5.7 L) kits that requires a separate color pack (pig-ment) to be added.

Standard Colors:Spectrem 4-TS is available in 53 standard colors and can be custom matched to virtually any color upon request.

Applicable Standards:Conforms to ASTM C920, Type M, Grade NS, Class 50, Use NT, G, M, A and O; U.S. Federal Specification TT-S-00230, Class A; U.S. Federal Specification TT-S-001543A Class A and Canadian Standard CAN/CGSB-19.13-M87, EIMA Test Method 300.01 and ASTM C1382.

INSTALLATIONJoint Design:May be used in any vertical or hori-zontal joint design in accordance with accepted architectural/engi-neering practice. Joint width should be 4-times anticipated movement, but not less than 1/4 inch (6.4mm) wide.

Dimensions:For joint 1/4 inch (6.4mm) to 1/2 inch (12.7mm) wide, the width to depth ratio should be equal. Joints 1/2 inch (12.7mm) wide or greater should have a sealant depth of 1/2 inch (12.7mm). Minimum joint size is 1/4 inch by 1/4 inch (6.4mm by 6.4mm).

Surface Preparation:For good adhesion, the joint inter-face must be sound, clean and dry. Depending on the substrate, or presence of form release agents, masonry waterproofing, dust, loose mortar or laitance, architectural paints or finishes, the joint surface may require a thorough wire brush-

ing, grinding, sandblasting, solvent washing and/or primer.

Tooling & Cleaning:Tooling is recommended immedi-ately after application to insure firm, intimate contact with the joint interface. Dry tooling is pre-ferred, although tooling agents can be utilized. Excess sealant and smears adjacent to the joint can be removed with Xylol or Toluol before sealant cures.

Joint BackingBond Breaking Tape:Closed cell polyethylene backer rods are preferred as joint backing to control depth of sealant bead. Where depth of joint will prevent use of joint backing, an adhesive backed polyethylene tape should be installed to prevent three-sided adhesion. Joint backing must be dry at time of sealant application.

Field-Tintable Silicone Sealant

Spectrem® 4-TS

Application:Mix in accordance with directions on the product container label. Mixing should continue until the desired uniform color is reached. Apply with conventional caulking equipment, filling the joint com-pletely and tool.

Maintenance:Damaged sealant can be repaired. Consult your Tremco Field Representative or Distributor for repair procedures.

Availability:Available from your local Tremco Field Representative, Tremco Distributor or Tremco Warehouse.

Warranty:Tremco warrants its Sealants to be free of defects in materials, but makes no warranty as to appear-ance or color. Since methods of application and on-site conditions are beyond our control and can affect performance, Tremco makes no other warranty, expressed or implied, including warranties of MERCHANTABILITY and FITNESS FOR A PARTICULAR PURPOSE, with respect to Tremco Sealants. Tremco’s sole obligation shall be, at its option, to replace, or refund the purchase of the quantity of Tremco Sealant proven to be defective and Tremco shall not be liable for any loss or damage.

PRINTED IN THE USA 0504/SP4TSSD

TYPICAL PHYSICAL PROPERTIESASTM C-679 Tooling Time 45-60 minutes

ASTM C-719 Joint movement capability Extension Compression ±50%

After 14 days at 25˚C (77˚F) and 50% R.H.

ASTM C-661 Hardness; Shore “A” 15 After 14 days at 25˚C (77˚F).

ASTM D-412 Tensile Strength at Max Elongation 148 psi 100% Modulus 16 psi

ASTM D-624 Tear Strength (die “C”) 23 pli min.

ASTM C-794 Peel Strength Aluminum, Glass, Concrete 17 pli min. Temperature Range -40˚F to +300˚F

NOTE: The foregoing information is published as general information only. The listed properties and performance characteristics are approximate values and are not part of the product specification.







------------------------------------------------------------------------------------------------ SECTION 1------------------------------------------------------------------------------------------------Order Code: DEV716 802

Product Name: SPECTREM 4-TS Chemical Name: Chemical Family: Sealant Product Code: DEV-716 Date Prepared: 05-MAY-03 MSDS Preparer: R. A. MIKOL Replaces Date: N/A

Other applications:


POLYMERS 60.0-80.0 Trade Secret OSHA:TWA - STEL - ACGIH:TWA - STEL -

CALCIUM CARBONATE 8.0-20.0 471-34-1 OSHA:TWA 15 mg/M3 STEL - (total dust, 5mg/M3 respirable fraction) ACGIH:TWA 10 mg/M3 STEL - (total dust, no asbestos, <1% SiO2)

PLASTICIZER 5.0-15.0 Trade Secret OSHA:TWA 5 mg/M3 STEL - ACGIH:TWA 5 mg/M3 STEL 10 mg/M3


OXIMOSILANE 1.0-5.0 22984-54-9 OSHA:TWA - STEL - ACGIH:TWA - STEL -

AMINOSILANE 0.5-2.0 1760-24-3 OSHA:TWA - STEL - ACGIH:TWA - STEL -

------------------------------------------------------------------------------Section 3 - Hazards Identification------------------------------------------------------------------------------****************************************************************************** Emergency Overview: Neutral color paste. If inhaled can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system. Leave area to breathe fresh air. Avoid further exposure. If symptoms persist, get medical attention.****************************************************************************** Potential Hlth Effect/Rte of Entry: ----------------------------------- Inhalation: Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system. Eyes: Can cause irritation. Ingestion: Can cause gastrointestinal irritation. Skin: Can cause irritation.Aggravated Medical Conditions: Pre-existing eye, skin, respiratory, and liver disorders may be aggravated by exposure.Acute Health Effects: See effects described above.Chronic Health Effects: During cure, up to 2% Methyl Ethyl Ketoxime (MEKO) may be released. MEKO

121 58 2Product DEV-716 Page 1 of 5

Order Code: DEV716 802

has caused allergic skin reactions and liver tumors in animals. Overexposure to MEKO may cause blood effects (methemoglobinemia and anemia). However, due to the extremely low vapor pressure of MEKO (<8mm Hg @20C), release of high airborne concentrations is not expected under normal conditions of use. Prolonged or repeated exposure (orally or by inhalation) of the plasticizer to rats produced decreased body weights, spleen and sex organ changes, increased liver and kidney weights, reduced food consumption, and effects on the liver, testes and pancreas. Birth defects have been reported in mice and rats at dose levels of the plasticizer that produce significant toxicity in the mother and offspring. However, birth defects have not been observed in rabbits. Evidence of the carcinogenicity of the plasticizer has been mixed. An initial NTP study of the effects of the plasticizer has reported an increased incidence of mononuclear cell leukemias in female rats, a commonly occuring spontaneous disease in this strain, but no increase in tumors in mice. However, a repeat study has not found an increase in leukemias, although an increase in kidney and bladder lesions in females and in pancreatic tumors in males was noted. Furthermore, a concurrent study that restricted diet also has not revealed any increase in tumors in male and female rats. Numerous studies also have indicated that the plasticizer is not genotoxic. Fillers are encapsulated and not expected to be released from product under normal conditions of use.


------------------------------------------------------------------------------Section 5 - Fire Fighting Measures------------------------------------------------------------------------------ Flash Point: >200 F Method: SETA Lower Flammability Limit: N/A Upper Flammability Limit: N/A Autoignition Temperature: N/A Extinguishing Media: Water fog. Fire and Explosion Hazards: Not Applicable Special Fire Fighting Procedures: During a fire, personnel at the scene are to prevent exposure to fumes using accepted fire fighting techniques. Fire Fighting Equipment: N/A Other Precautions: Oxides of silicon can form.






------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties------------------------------------------------------------------------------ Odor/Appearance: MILD OXIME/NEUTRAL COLOR PASTE Color: NEUTRAL Physical State: PASTE pH: Vapor Pressure: NOT ESTABLISHED Vapor Density: N/A Boiling Point: >200 F Melting Point: N/A Freezing Point: N/A Solubility in Water: NEGLIGIBLE Specific Gravity: 1.1 % Volatile Weight: 0.0

------------------------------------------------------------------------------Section 10 - Reactivity/Stability------------------------------------------------------------------------------ Stability: Stable Incompatible Products: Avoid contact with oxidizing agents, strong acids and bases. Conditions to Avoid Polymerization: Hazardous polymerization will not occur.







------------------------------------------------------------------------------Section 14 - Transportation Data------------------------------------------------------------------------------ DOT Shipping Name: NOT REGULATED DOT Hazard Class: DOT Label: UN/NA Number: N/A Packing Group: Special Provisions:

Packaging --------- Exceptions: Non-Bulk: Bulk: Quantity Limitations -------------------- Passenger Aircraft or Railcar: Cargo Aircraft: Vessel Stowage Requirements --------------------------- Vessel Stowage: Other Stowage:




OSHA Hazardous Components CAS Number ---------------------------------------------- ------------ CALCIUM CARBONATE 471-34-1 PLASTICIZER Trade Secret POLYMERS Trade Secret Compliance Quantites -------------------- N/A

SARA 311 Ratings ---------------- Immediate Health Hazard: N Delayed Health Hazard: N Fire Hazard: N



Reactivity Hazard: N Sudden Release of Pressure Hazard: N

SARA 313 Ingredients CAS Number ---------------------------------------------- ------------ No SARA 313 Ingredients

Proposition 65 Ingredients -------------------------- WARNING:This product contains chemicals known to the State of California to cause cancer, birth defects and/or other reproductive harm. CAS number ------------------------------------------ ------------ CRYSTALLINE SILICA (QUARTZ) (<0.05%) 14808-60-7




Re: Tremsil® 600 – LEED Product Information To Whom It May Concern: Tremco, as an organization, is committed to quality, responsive to internal and external customers, our employees, our community and environment, and we will treat all with respect and good stewardship. Tremsil 600 is manufactured in Toronto, Ontario. If Toronto falls within a 500-mile radius of the project site, the product is considered to be a locally produced material and can help contribute to earning Materials & Resources - Credit 5. The recycled content by weight is as follows: 30 ctgs (1 case) 0.08% (100% post-consumer) 60 ctg cases (1 pallet) 2.17% (all pallets are made from 100% reclaimed wood) 15 ssgs (1 case) 0.09% (100% post-consumer) 66 ssg cases (1 pallet) 2.20% (all pallets are made from 100% reclaimed wood) 1 x 2 gal pail 0.00% 96 x 2 gal pails (1 pallet) 0.66% (all pallets are made from 100% reclaimed wood) 1 x 5 gal pail 0.00% 36 x 5 gal pails (1 pallet) 3.81% (all pallets are made from 100% reclaimed wood) 1 x 55 gal drum 1.75% (.29% post-consumer and 1.46% post-industrial) 4 x 55 gal drum (1 pallet) 2.93% (all pallets are made from 100% reclaimed wood) Tremsil 600 contains 0g/L volatile organic content (VOC) and therefore satisfies the LEED criteria for Indoor Environmental Quality standard as established under credit 4. Should you have any questions or require additional information, please do not hesitate to contact me. Sincerely,



Tremsil® 600Tremsil® 600Silicone Glazing Sealant

Product Description:Tremsil 600 is a one-part, mediummodulus, neutral cure siliconesealant. The sealant cures to a flex-ible rubber when exposed to mois-ture present in the air.

Basic Uses:Tremsil 600 is compatible to mostcommon porous and non-porousbuilding component surfaces makingit an excellent sealant for use oncommercial construction as well as awide variety of high performancewindow systems. Tremsil 600 hasexcellent adhesion to aluminum,stainless steel, metals, glass, plas-tics, rigid P.V.C.’s, wood, brick, con-crete and painted surfaces. Tremsil600 is also designed for applicationthrough automated glazing equip-ment i.e. (x-y Tables).



Packaging:1/12 gallon (300 ml) cartridges20 oz. (600 ml) sausages, 4.5 gallon(17.0 L) pails and 50 gallon (189.3 L) drums

Standard Colors:White, Black, Clear and AnodizedAluminum.

Applicable Standards:Conforms to ASTM C920 Type S,Grade NS, use NT, G, A and O andCAN/CGSB-19.13-M87 and U.S.Federal Specification TT-S-00230C(COM-NBS) Class A, and AAMA 800-92 (802.3-92, 808.3-92) and U.S.Federal Specification TT-S-001543A (COM-NBS) Class A.

INSTALLATIONJoint Design:May be used in any joint designedin accordance with accepted archi-tectural/engineering practices.Joint width should be 4 times antic-ipated movement, but not less than1/4 inch (6.4 mm) wide.

Joint Dimensions:For joints 1/4 inch (6.4 mm) to 1/2inch ( 12.7 mm) wide, the width todepth ratio should be equal. Joints1/2 inch (12.7mm) wide or greatershould have a depth of 1/2 inch(12.7 mm). Minimum joint size 1/4inch by 1/4 inch (6.4 mm by 6.4mm).

Surface Preparation:For good adhesion, the joint inter-face must be sound, clean and dry.Depending on the substrates, thejoint surface may require a thor-ough wire brushing, grinding, sand-blasting, solvent washing and/orprimer.

Tooling & Cleaning:Tooling is recommended immediate-ly after application to ensure firm,intimate contact with the jointinterface. Dry tooling is preferred.Cleaning can be accomplished withsolvents such as IPA or MEK whilesealant is in uncured state.

Joint BackingBond Breaking Tape:Closed cell polyethylene backer rodsare preferred as joint backing tocontrol depth of sealant bead.Where depth of joint will preventuse of joint backing, an adhesivebacked polyethylene tape should beinstalled to prevent three sidedadhesion. Joint backing must bedry at time of sealant application.

Application:Tremsil 600 is easy to apply withconventional caulking equipment.Fill joint completely and tool. At75˚F (23.9˚C), 50% R.H. tooling timeis from 8 to 10 minutes.



Warranty:Tremco warrants its Sealants to befree of defects in material. Butmakes no warranty as to appearanceor color. Since method of applica-tion and on-site conditions arebeyond our control and can affect

performance, Tremco makes noother warranty, expressed orimplied, including warranties ofMERCHANTABILITY and FITNESS FORA PARTICULAR PURPOSE, withrespect to Sealants. Tremco’s soleobligation shall be at, its option, toreplace, or to refund the purchaseprice of the quantity of Sealantproved to be defective and Tremcoshall not be liable for any loss ordamage.

PRINTED IN THE USA 1104/T600SD

TYPICAL PHYSICAL PROPERTIESProperty Test Methods Typical ValueUncuredTooling Time Skin formation (Touch) 8-10 mins.

Tack free time ASTM C679 Less than 2 hrs.

Sag ASTM D2202 (full) 0-0.8mm (0-0.03")

Cure Through Cure rate for 6mm Less than 7 days(1/4") bead @ 23˚C(73˚F) and 50% R.H.

CuredHardness (Shore A) ASTM C661 20-22

Tensile Strength (max.) ASTM D412 1.4 MPa (200 psi)

Elongation ASTM D412 500%

50% Modulus ASTM D412 0.45 MPa (65 psi)

Movement ASTM C719 ±25%

NOTE: The foregoing information is published as general information only. The listedproperties and performance characteristics are approximate values and are not part ofthe product specification.

Sealant/Weatherproofing Division 3735 Green Road • Beachwood, Ohio • 44122 • Phone: (216) 292-5000 • (800) 321-7906220 Wicksteed Avenue • Toronto, ON M4H 1G7 • Phone: (416) 421-3300 • (800) 363-3213






Product Name: TREMSIL 600 Chemical Name: Chemical Family: Sealant Product Code: 944-8XX Date Prepared: 18-JAN-00 MSDS Preparer: R. A. MIKOL Replaces Date: 06-AUG-99

Other Applications: THIS MATERIAL SAFETY DATA SHEET (MSDS) ALSO APPLIES TO THE FOLLOWING: 944-802(BLACK),-806(WHITE),-807(BUFF),-854(BROWN),-855(SUPER WHITE), -858(IVORY),-971(SIMONTON TAN), -7XX & 8XX (OTHER COLORS)





SILICA, AMORPHOUS, FUMED 3.0-7.0 112945-52-5 OSHA:TWA 15 mg/M3 STEL - (total nuisance dust) ACGIH:TWA 10 mg/M3 STEL - (total nuisance dust)

OXIMINO SILANE 1.0-5.0 Trade Secret OSHA:TWA - STEL - ACGIH:TWA - STEL -





------------------------------------------------------------------------------Section 3 - Hazards Identification------------------------------------------------------------------------------****************************************************************************** Emergency Overview: Various colored paste. If inhaled can cause headache, dizziness, irritation to the respiratory system. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention immediately.******************************************************************************

Potential Hlth Effect/Rte of Entry: -----------------------------------



Inhalation: Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system. Eyes: Can cause severe irritation. Ingestion: Can cause gastrointestinal irritation. Skin: Can cause irritation, possible dermal sensitization. Methyl Ethyl Ketoxime may be absorbed through the skin.

Aggravated Mediccal Conditions: Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.


Chronic Health Effects: During cure, up to 2% Methyl Ethyl Ketoxime (MEKO) may be released. MEKO has caused allergic skin reactions and liver tumors in animals. Overexposure to MEKO may cause blood effects (methemoglobinemia and anemia). However, due to the extremely low vapor pressure of MEKO (<8mm Hg at 68F), release of high airborne concentration is not expected under normal conditions of use. Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis may result from breathing free silica. No serious health effects have been established in man when exposed to carbon black. Inflammation, lung fibrosis, and tumors have been observed in animals at levels which overload lung clearance mechanisms. Carbon black contains varying amounts of polynuclear aromatic compounds (PNA's) which have been found to cause cancer in animals. Solvent extracts of carbon black are carcinogenic to the skin of mice. It is classified by IARC to be a known animal carcinogen and a possible human carcinogen (Group 2B). Fillers are encapsulated and not expected to be released from product under normal conditions of use.


------------------------------------------------------------------------------Section 5 - Fire Fighting Measures------------------------------------------------------------------------------ Flash Point: 271 F Method: TCC Lower Flammability Limit: N/A Upper Flammability Limit: N/A Autoignition Temperature: N/A Extinguishing Media:



Water fog. Fire and Explosion Hazards: Not Applicable Special Fire Fighting Procedures: During a fire, personnel at the scene are to prevent exposure to fumes using accepted fire fighting techniques.

Fire Fighting Equipment: N/A Other Precautions: Not Applicable


------------------------------------------------------------------------------Section 7 - Handling and Storage------------------------------------------------------------------------------Handling and Storage Precautions: Store under normal warehouse conditions. Prevent inhalation of vapor, ingestion, and contact with skin and eyes. Keep container closed when not in use. Precautions also apply to emptied containers. Change soiled workclothes frequently. Clean hands thoroughly after handling. Personal protective equipment must be worn during maintenance or repair of contaminated mixer, reactor, or other equipment.------------------------------------------------------------------------------Section 8 - Exposure Controls/Personal Protection------------------------------------------------------------------------------ Respiratory: Wear NIOSH/MSHA approved respirator as directed by the manufacturer when the ventilation is not adequate. Skin: Protect hands with impervious rubber gloves and wear typical full cover clothing. Prevent contact with skin. Eyes: Wear suitable safety eyewear. Face: Not required. Engineering: Use local exhaust when the general ventilation is not adequate.

------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties------------------------------------------------------------------------------ Odor/Appearance: OXIME/VARIOUS COLORED PASTE Color: VARIOUS Physical State: PASTE pH: Vapor Pressure: N/A Vapor Density: N/A Boiling Point: N/A Melting Point: N/A Freezing Point: N/A Solubility in Water: NEGLIGIBLE Specific Gravity: 1.42 % Volatile Weight: 0.0

------------------------------------------------------------------------------Section 10 - Reactivity/Stability------------------------------------------------------------------------------ Stability: Stable Incompatible Products:



Avoid contact with strong oxidizing agents. Conditions to Avoid Polymerization: Hazardous polymerization will not occur.





------------------------------------------------------------------------------Section 14 - Transportation Data------------------------------------------------------------------------------ DOT Shipping Name: NOT REGULATED

DOT Hazard Class: DOT Label: UN/NA Number: Packing Group: Special Provisions: Packaging --------- Exceptions: Non-Bulk: Bulk:

Quantity Limitations -------------------- Passenger Aircraft or Railcar: Cargo Aircraft: Vessel Stowage Requirements --------------------------- Vessel Stowage: Other Stowage:


------------------------------------------------------------------------------Section 15 - Regulatory Information------------------------------------------------------------------------------ TSCA Status: On the TSCA Inventory OSHA Status: Considered hazardous based on the following criteria: Irritant Sensitizer



Target Organs ------------- Kidney Lung

OSHA Hazardous Components CAS Number ---------------------------------------------- ------------ CALCIUM CARBONATE (LIMESTONE) 1317-65-3 * CRYSTALLINE SILICA (QUARTZ) 14808-60-7 * CARBON BLACK 1333-86-4 TITANIUM DIOXIDE 13463-67-7 IRON OXIDE 1309-37-1 * - CHEMICAL IS LISTED AS AN IARC, NTP, OSHA, or ACGIH CARCINOGEN

Compliance Quantities -------------------- No Compliance Quantities

SARA 311 Ratings ---------------- Immediate Health Hazard: N Delayed Health Hazard: Y Fire Hazard: N Reactivity Hazard: N Sudden Release of Pressure Hazard: N


Proposition 65 Ingredients -------------------------- Chemicals known to the State of California to cause cancer, birth defects and/or other reproductive harm. CAS Number --------------------------------------------- ------------ CRYSTALLINE SILICA (QUARTZ) 14808-60-7



Tremco Product V.O.C. Table - arb.ca.gov · 16/06/2004 · Tremco 830 390 THC 900 Pretinted 165...

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Transcript of Tremco Product V.O.C. Table - arb.ca.gov · 16/06/2004 · Tremco 830 390 THC 900 Pretinted 165...