Tracing South China of Gondwana
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Tracing the position of the South China block in Gondwana: U–Pb ages and Hf isotopes of Devonian detrital zircons
Liang Duan a,⁎, Qing-Ren Meng b, Cheng-Li Zhang a, Xiao-Ming Liu a
a State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi'an 710069, Shaanxi, Chinab Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
a b s t r a c ta r t i c l e i n f o
Article history:
Received 28 December 2009Received in revised form 3 May 2010
Accepted 4 May 2010
Available online 24 May 2010
Keywords:
South China block
Gondwana
Devonian
U–Pb age
Hf isotopes
Zircon
U–Pb detrital zircon geochronology from Lower Devonian quartz arenites of the northwestern margin of
the Yangtze block yields dominant early Neoproterozoic (0.85–1.0 Ga), Pan-African (0.5–0.65 Ga) and
middle Neoproterozoic (0.68–0.8 Ga) age populations and minor Mesoproterozoic to middle Mesoarchean
(1.0–3.0 Ga) ages. Middle Mesoarchean to Mesoproterozoic rocks, however, are widespread in the South
China block. Although Hf isotopic compositions show both juvenile crustal growth and crustal reworking
for all the age groupings, the crust growth, essentially mantle-derived, occurred mainly around 3.1 Ga,
1.9 Ga and 1.0 Ga, respectively. Zircon typology and youngest grain ages indicate that this suite of
quartz arenites was the product of multiphase reworking. Abundant magmatic zircon detritus with con-
cordant U–Pb Grenvillian and Pan-African ages, together with accompanying various ε Hf(t ) values, indicate
an exotic provenance for the quartz arenite external to the South China block. Qualitative comparisons of
agespectra forthe late Neoproterozoic sedimentsof theCathaysian Block,earlyPaleozoic sedimentsof pre-
rift Tethyan Himalaya sequence in NorthIndia and lower Paleozoic sandstone from the Perth Basin in West
Australia, show that they all have two the largest age clusters representing Grenvillian and Pan-African
orogenic episodes. The resemblance of these age spectra and zircon typology suggests that the most likely
source for the Lower Devonian quartz arenites of the South China block was the East African Orogen and
Kuunga Orogen for their early Grenvillian and Pan-African populations, whereas the Hannan–Panxi arc,
Jiangn an or ogen, and t he Yangtze block basemen ts mi ght have contrib uted to th e de trital zircon grains of the Neoproterozoic and Pre-Grenvillian ages. Hf isotopic data indicate that the crustal evolution of the
drainage area matches well with the episodic crust generation of Gondwana. These results imply that the
previously suggested position of the SCB in Gondwana should be re-evaluated, and the South China block
should be linked with North India and West Australia as a part of East Gondwana during the assembly of
Gondwana, rather than a discrete continent block in the paleo-Pacific.
© 2010 International Association for Gondwana Research. Published by Elsevier B.V. All rights reserved.
1. Introduction
U–Pb geochronology is a powerful technique for extracting source
information from detrital zircon grains (e.g. DeCelles et al., 2000;
DeGraaff-Surpless et al., 2002; Gehrels et al., 2003; DeCelles et al.,
2004, 2007; Leier et al., 2007; Dickinson and Gehrels, 2009). Zircon
also contains considerable amount of HfO2, which can be used as an
indicator of crustal residence and growth via Hf isotope analysis
(Hawkesworth and Kemp, 2006; Scherer et al., 2007). Therefore, the
combination of U–Pb and Hf isotope analysis of detrital zircons can
reveal the relative contributions of juvenile (directly mantle-derived)
crust versus recycled continental crust, making zircon a ‘one-stop
shop’ for assessing crustal evolution (Scherer et al., 2007).
The link between sedimentary maturity and detrital zircon ages is
not certain yet (Fedo et al., 2005), but samples of high-maturity
sediments are suitable for researching information for large regions.
Quartz arenites are characterized by super-mature texture and
composition and thus indicative of continental derivation for all the
units sampled (Fergusson et al., 2007). Quartz arenites consist almost
entirely of sand-sized monocrystalline quartz grains and other
resistant grains like chert, metaquartzite, and heavy minerals, such
as zircon (Prothero and Schwab, 2004). These characteristics of quartz
arenites show that they must have experienced long-term transpor-
tation and sedimentation, and thus serve as a proxy for unraveling
regional geological evolution (e.g. Sircombe et al., 2001; Gehrels et al.,
2002; Avigad et al., 2005; Zimmermann and Spalletti, 2009).
The history of supercontinents and their configuration have been
the focus of many investigations (e.g.: Hoffman, 1991; Condie, 1998;
Meert, 2001; Meert and Torsvik, 2003; Cawood et al., 2007; Meert and
Lieberman, 2008; Li et al., 2008a; Rino et al., 2008; Stern, 2008;
Gondwana Research 19 (2011) 141–149
⁎ Corresponding author.
E-mail address: [email protected] (L. Duan).
1342-937X/$ – see front matter © 2010 International Association for Gondwana Research. Published by Elsevier B.V. All rights reserved.
doi:10.1016/j.gr.2010.05.005
Contents lists available at ScienceDirect
Gondwana Research
j o u r n a l h o m e p a g e : w w w. e l s ev i e r. c o m / l o c a t e / g r
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Santosh et al., 2009a,b). Although some paleogeographic models were
advanced, the position of the South China block (SCB) in the
Gondwana supercontinent has been of considerable controversy
(Dalziel, 1997; Li and Powell, 2001; Cocks and Torsvik, 2002; Powell
and Pisarevsky, 2002; Yang et al., 2004; Li et al., 2008b; Yu et al.,
2008). For instance, it was inferred that the SCB was adjacent to the
western Antarctic–Australiaregion of Gondwana (Huang et al., 2000a;
Yang et al., 2004; Huang et al., 2008), most probably located close to
western Australia based on paleomagnetic analysis. Li and Powell(2001) and Li et al. (2008b), however, plotted the SCB as a discrete
plate in the paleo-Pacific, far away from the northeastern margin of
East Gondwana. In practice, the SCB was omitted in many Precam-
brian paleogeographic reconstructions of the Gondwanaland (e.g.:
Dalziel, 1997; Boger et al., 2001; Powell and Pisarevsky, 2002; Cocks
and Torsvik, 2002; Collins and Pisarevsky, 2005).
This paper presents a study of detrital zircon U–Pb geochronology
and Hf isotope geochemistry of quartz arenites of the Lower Devonian
Pingyipu Formation in the northwestern margin of the Yangtze block,
and puts some constraints on their provenance and the evolution of
the drainage area. Of importance is that the results also provide
insights into the positions of the SCB during the assembly of
Gondwana.
2. Geological background
The South China block is bordered on the north by the North China
block, with the Qinling–Dabie orogen located in between (Fig. 1A, B)
(Meng and Zhang, 2000; Li et al., 2007). It is actually a composite
continental block formed by the assembly of the Yangtze and
Cathaysian blocks amalgamated through the Jiangnan orogen
(Fig. 1B), although the timing and evolution of the orogeny are still
controversial. Some researchers suggested that the Jiangnan orogen
belongs to part of the worldwide Grenvillian orogenic belts associated
with the assembly of Rodinia (e.g., Li et al., 1995, 2002b; Greentree
et al., 2006; Ye et al., 2007; Li et al., 2008b,c), whereas others
considered that the amalgamation lasted until ca. 820 Ma or evenyounger (e.g., Li, 1999; Zhao and Cawood, 1999; Zhou et al., 2002a,b;
Wang et al., 2006; Wu et al., 2006; Zheng et al., 2007; Wang et al.,
2007, 2008). The Yangtze block comprises a crystalline basement
overlain by Neoproterozoic to Middle Triassic marine sedimentary
sequences (Yan et al., 2004). The Cathaysian block, however, is
characterized by widespread distribution of Jurassic–Cretaceous
granites and Late Triassic to Early Cretaceous continental basins ( Ji
et al., 2009).
Geochronological studies show that Neoproterozoic magmatism,
ranging in ages from 830 to 740 Ma (e.g.: Zhou et al., 2002a,b; Li et al.,
2003a,b; Zheng et al., 2004; Li et al., 2005; Zheng et al., 2006a; Zhou et
al., 2006a,b; Zhu et al., 2006; Wu et al., 2006; Wu et al., 2007; Wang et
al., 2008; Li et al., 2008a,c), is widespread in the SCB, especially along
the Jiangnan orogen (e.g.: Li et al., 2003a,b, 2005; Wang et al., 2006;
Wu et al., 2006, 2007; Zhou et al., 2007; Li et al., 2008a,b; Wang et al.,
2008; Zhou et al., 2009) and at the western edge of the Yangtze block
(e.g., Li et al., 2002a,b; Zhou et al., 2002a,b, 2006a,b; Zhao and Zhou,
2007; Sun and Zhou, 2008; Munteanu et al., in press), which is often
Fig. 1. (A) Sketch map showing the main tectonic units of China; (B) Map showing the South China block consisting of the Yangtze and Cathaysia blocks, separated by a Jiangnan
orogen; (C) Simplified tectonic map of the northwestern margin of the Yangtze block and adjoining regions. NCB= North China block; SCB =South China block; HPA= Hannan–
Panxi arc; PM= Pengguan massif; HD =Hannan dome; FTB= fold-thrust belt.
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termed as the Hannan–Panxi arc (HPA) in the literature (Zhou et al.,
2002b) (Fig. 1B). The HPA was a Neoproterozoic continental arc, with
ages of igneous rocks from 860 to 740 Ma (Zhou et al., 2002a,b, 2006a,
b; Zhao and Zhou, 2007; Sun and Zhou, 2008; Sun et al., 2009 ). In
addition, the Archean (2.5–3.8 Ga) rocks and inherited zircons are
also found in the SCB (Qiu et al., 2000; Liu et al., 2006; Zhang et al.,
2006a,b,c; Zheng et al., 2006b). Abundant U–Pb ages and Hf isotopic
compositions of detrital zircons from the Neoproterozoic strata and
igneous zircons from the Archean basement suggested that thePrecambrian crustal growth of the Yangtze block is characterized by
obvious crustal additions between 3.2 and 3.8 Ga, and between 720
and 910 Ma, with a peak at 830 Ma (Liu et al., 2008). The basement
metamorphic rocks of the Cathaysian block, are dominantly of
Neoproterozoic to early Paleozoic ages (Yu et al., 2008), with the
oldest rocks in the eastern Cathaysian block being about 1.9 Ga (Gan
et al., 1995).
This study deals with Devonian rocks that arewell preservedin the
middle segment of the Longmenshan thrust belt at the northwestern
margin of the Yangtze block (Fig. 1C). The Longmenshan was a
sinistral wrench zones active in the Late Triassic (Burchfiel et al.,
1995; Worley and Wilson, 1996), and probably related to the
clockwise rotation of theSCB (Meng et al., 2005). The Lower Devonian
rests unconformably over the Middle Silurian phyllite, and can be
divided into the Pingyipu, Guixi and Yangmaba formations from
bottom upward. The Pingyipu Formation is composed primarily of
quartz arenite, greywacke, siltstone, mudstone and shale, as inter-
preted as coastal deposits (Chen 2007; Zheng et al., 1997), and its age
is assigned mainly on the basis of marine fossils, (Zheng et al., 1997).
∼5 kg quartz arenites were sampled from a succession cropping out
near Guixi village in the northern Sichuan province (N:31°58′39.3″, E:
104°38′34.1″; Fig. 1C). Given the high specific gravity of zircon (4.65),
as compared to quartz (2.65), hydraulically equivalent zircon is
expected to be approximately one sand grade finer than accompa-
nying quartz grains (Komar, 2007; Dickinson and Gehrels, 2009).
Accordingly, samples of medium-grained quartzose arenites were
chosen.
3. Analytical methods
Zircon crystals were extracted from samples by standard density
and magnetic separation techniques and then purified by hand
picking under a binocular microscope, and N1000 zircon grains
recovered. Representative zircon grains were handpicked and
mounted in epoxy resin discs, then polished and coated with gold.
All analyzed zircon grains were documented using cathodolumines-
cence (CL) images for internal morphology prior to analyses, which
were acquired with a Mono CL3+ (Gatan, USA) attached to a scanning
electron microscope (Quanta 400 FEG). Before analysis, the surface
was cleaned using dilute HNO3 (3%, v/v) and pure alcohol to remove
any lead contamination. CL imaging, U–Pb dating and Hf isotope
analysis were carried out in the State Key Laboratory of Continental
Dynamics, Northwest University, Xi'an.
3.1. U –Pb dating
U–Pb geochronology of ∼100 individual zircon grains was
conducted by laser-ablation-inductively coupled plasma-mass spec-
trometry (LA-ICP-MS). The ICP-MS used is a Varian 820-MS (Varian,
Inc., USA), and the analyses involve ablation of zircon with the GeoLas
2005 laser-ablation system (MicroLasTM Beam Delivery Systems,
Lambda Physik AG, Germany) (operating at a wavelength of
193 nm) using a spot diameter of 44 μ m. In this technique, zircons
are sampled using a focused UV laser, and the ablated microparticu-
late material is transferred in a continuous flow of helium to an ICP-
MS for isotopic quantification. The used laser frequency was 10 Hz.
Raw count rates were measured for29
Si,204
Pb,206
Pb,207
Pb,208
Pb,
232Th and 238U. U, Th and Pb concentrations were calibrated by using29Si as an internal standard and NIST 610 as the reference standard.207Pb/206Pb, 206Pb/238U, 207Pb/235U and 208Pb/232Th ratios, and then
calculated using the GLITTER 4.0 program (Macquarie University).
Finally they were corrected for both instrumental mass bias and
depth-dependent elemental and isotopic fractionation using Harvard
zircon 91500 as external standard. The detailed analytical technique
refers to Yuan et al. (2004). Age calculations and plotting of concordia
diagrams were made using ISOPLOT 3.0 (Ludwig, 2003) for resultswith 1σ errors. Our measurements of GJ-01 as an unknown yielded
weighted 206Pb/238U ages of 603.0±5.5 Ma (MSWD=0.16, n=11),
which is in good agreement with the recommended ID-TIMS 206Pb/238U ages ( Jackson et al., 2004). Because the 204Pb isotope cannot be
precisely measured with this technique, due to a combination of low
signal and interference from small amounts of 204Hg in the Ar gas
supply, common-Pb contents were calculated using the method
described by Andersen (2002). In most cases, the samples analyzed in
this study did not need correction or the common-Pb correction was
insignificant.
3.2. Lu–Hf isotope analysis
In-situ zircon Hf isotopic analyses were conducted using a Nu
Plasma HR MC-ICP-MS (Nu Instruments Ltd., UK), coupled to a GeoLas
2005 excimer ArF laser-ablation system. In this study, we use
technique of simultaneous determinations of U–Pb age, Hf isotopes
and traceelement compositions of zircon by combining excimer laser-
ablation quadruple and multiple collector ICP-MS, where age, Lu–Hf
isotopic and trace element data were collected simultaneously from
the same spot of zircon (Yuan et al., 2008). During analyses, the
energy density applied is 15–20 J/cm2 and spot sizes of 44 μ m, with a
laser repetition rate of 10 Hz, were used. The detailed analytical
technique was described by Yuan et al. (2008). Raw count rates for172Yb, 173Yb, 175Lu, 176(Hf+Yb+Lu), 177Hf, 178Hf, 179Hf, 180Hf and182 W were collected. Interference of 176Lu on 176Hf was corrected by
measuring the intensity of the interference-free 175Lu isotope and
using the recommended 176Lu/175Lu ratio of 0.02655 (Chu et al.,
2002). A 176Yb/172Yb of 0.5887 and mean β Yb obtained during Hf analysis were applied for the interference correction of 176Yb on 176Hf
(Iizuka and Hirata, 2005). During analyses, Harvard zircon 91500 was
used as the reference standard, the obtained 176Hf/177Hf ratio was
0.282304±14 (2σ , n =19), similar to the recommended 176Hf/177Hf
ratio of 0.282306±10 measured using the solution method (Wood-
head et al., 2004). The measured176Lu/177Hf ratiosand the176Lu decay
constant of 1.867× 10−11 yr−1 reported by Soderlund et al. (2004)
were adopted to calculate initial 176Hf/177Hf ratios. The chondritic
values of 176Hf/177Hf and 176Lu/177Hf reported by Bichert-Toft and
Albarède (1997) were used for the calculation of ε Hf values. Single-
stage model ages (T DM1) were calculated relative to the depleted
mantle with a present-day (176Lu/177Hf)DM=0.0384 and (176Hf/177Hf)DM=0.28325 (Grif fin et al., 2000); two-stage continental
model age (T DMC ) was also calculated by projecting the initial 176Hf/177Hf of zircon back to the depleted mantle growth curve using 176Lu/177Hf=0.015 for the average continental crust (Grif fin et al., 2000;
Yang et al., 2006). The notations of ε Hf(t ), f Lu/Hf , T DM1 and T DM
C are
defined as same as those in Yang et al. (2006).
4. Results
Zircons extracted from the sample are light yellow to colorless,
rounded or prismatic with rounded edges, and moderately to highly
spherical, generally rounded fragments of larger crystals, suggesting a
long-distance transport and multiphase reworking (Fig. 2). The
internal structure of these detrital zircons varies from strong
oscillatory zoning to almost homogeneous, being always faint and
weak in CL images (Fig. 2). These variable internal structures suggest
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several different origins. The majority of the zircons have Th/U N0.3,
indicating an igneous origin (Hanchar and Hoskin, 2003), and few
grainsshow typical metamorphic Th/U ratio below 0.1. Theresults are
consistent with the CL images predominated by oscillatory zoning
typical of igneous origin and irregular sector zoned domains of
metamorphic zircons. Grains with Pan-African and Grenvillian age
(Fig. 2A, B, E, F) are moderately to highly spherical. Grains with ages
from 830 to 740 Ma (Fig. 2C, D) show sub-angular or sub-rounded
edges, implying relative close provenance. Pre-Grenvillian grains
(Fig. 2G, H) are rounded to prismatic and show strong oscillatory
zoning or homogeneous internal structureindicating different origins.
4.1. Zircon U –Pb geochronology
Concordia and frequencydistribution plots of U–Pb geochronologyof the sample are presented in Figs. 3 and 4. Analyses that were N10%
discordant (by comparison of 206Pb/238Uand 206Pb/207Pb ages) are not
considered or discussed further (81 grain ages retained). We use207Pb/206Pb ages of N1.0 Ga zircons and 206Pb/238U ages of b1.0 Ga
zircons, and apply the same approach to the compilation of ages from
other studies for comparison (except for ages in Tethyan Himalaya
from Gehrels et al. (2003)). A complete list of the U–Pb ages and Hf
isotopic data is presented in the Supplementary Data table.
The majority of the grains from our sample are clustered in the
following time intervals: ca. 500–650 Ma, ca. 680–800 Ma and ca.
850–1000 Ma. The age distribution exhibits a typical Gondwana
signature (Fig. 4), with the clusters mainly at ca. 975 Ma and ca.
552 Ma. Zircons with age N1.0 Ga are widely distributed, though their
contributions are sparse. The youngest zircon yields a 206Pb/238U age
of 507±9 Ma. The interval between the youngest zircon crystalliza-
tion age and the depositional age constrained by fossils are indicative
of slow erosion of the source rocks and long-distance transport.
4.2. Hf isotope geochemistry
Zircon laser-ablated Hf isotope geochemical data are presented
graphically in Fig. 5. The ε Hf(t ) values exhibit a wide range fromnegative to positive (−49.8 to 16.1), with 176Hf/177Hf ratios varying
from 0.280658 to 0.282648. Few zircons have an Hf isotope
composition indicative of their origin from a depleted mantle
(Fig. 5), suggesting that the magmas from which most zircons formed
were derived by melting pre-existing, rather than juvenile, crustal
rocks. Of importance, several zircons with the ages of 2.8 Ga, 1.8 Ga,
and 1.0 Ga show values similar to the depleted mantle, and the two-
stage continental model ages (T DMC ) ofthetwograins withU–Pbageof
2.8 Ga and 1.8 Ga, are 3.1 Ga and 1.9 Ga, indicating the occurrence of
juvenile crustal addition at 3.1 Ga and 1.9 Ga.
5. Discussion
5.1. Sources of detrital zircons
Assemblies of the Rodinia and Gondwana supercontinents were
completed during the Grenvillian and Pan-African orogenic episodes,
and the two orogenic events were well recorded around East
Gondwana. However, the event related to Pan-African orogenesis in
the SBC was rarely reported. The existence of a Grenvillian orogenic
belt in the South China block is equivocal. Li et al. (1995, 1997, 2002b)
considered the Jiangnan orogen as a typical Grenvillian orogenic belt,
but granitoids or high-grade metamorphic rocks with Grenville ages
are absent in that region. Furthermore, metamorphic ages of the
zircon rims provided by Li et al. (2002b) cannot be regarded as
compelling geochronological evidence for the Grenvillian continental
collision (Wang et al., 2007). Although several lines of evidence
suggest that the Grenvillian high-grade metamorphism occurred
Fig. 2. CL images of representative detrital zircon grains. The results are marked using a circle with ages. Scale bar in each image is 50 µm.
Fig. 3. U–Pb concordia plots of single zircon grains from the Early Devonian quartz
arenites in thenorthwestern marginof theYangtze block.Insetwas theenlargedplot of
the ages between 0.4 and 1.2 Ga.
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along the northern to western edges of the Yangtze block (e.g.: Qiu et
al., 2000; Xu et al., 2004; Zheng et al., 2006b), the sparse distribution
and rounded and moderately to highly spherical nature of larger
zircon crystals (Fig. 2) preclude those regions as a major source. In
addition, the age distribution of studied detrital zircons is inconsistent
with those of the Yangtze block, which are characterized by
predominant age groups between 720 Ma and 910 Ma, with a peak
at 830 Ma (Liu et al., 2008) (Fig. 4). In contrast, we propose that the
Neoproterozoic grains (680–800 Ma) were probably derived from the
Jiangnan orogen or the Hannan–Panxi arc. The reason is that the
zircon grains with ages in this range are sub-angular or sub-rounded
(Fig. 2), implying that their sources must have been nearby. Pre-
Grenvillian detrital zircons older than 1.0 Ga show various internal
structures from strong oscillatory zoning to almost homogeneous, and
different typologies from prismatic with rounded edges to moderately
or highly spherical (Fig. 2). In addition, their distribution does not
match the dispersal of Pre-Grenvillian grains in the Yangtze block.
These characters suggest that zircons in this group have different
origins. As a result, it is considered that the detrital zircons from the
Lower Devonian in the northwestern margin of the Yangtze blockwere only partially derived from the SBC, and their main sources
should be exotic to the SCB.
5.2. Position of the SBC
It is known that Early Palaeozoic shallow marine fauna of the SBC
have close af finities with those of eastern Gondwanaland, especially
Australian Gondwanaland (Burrett, 1973; Burrett and Stait, 1985;
Metcalfe, 1988; in press; Burrett et al., 1990), and belong to the Asia-
Australian and Austral realms in the Cambrian and Ordovician,
respectively (Li, 1994; Yang, 1994). However, the position of the
SCB in the Neoproterozoic–Early Palaeozoic is still under debate. A
preliminary Early Ordovician pole was obtained from the SCB, which
placesthe SCB in an intermediatepaleolatitude compared with Baltica
Fig. 4. Detrital zircon U–Pb age relative probability diagrams plotted for comparison, with the data from this study and others, including: Yu et al. (2008) for Cathaysian Block;
Cawood and Nemchin (2000) forPerthBasinin West Australia; DeCelles et al.(2000), Gehrels et al.(2003) and Myrow et al.(2003) for Tethyan Himalaya; Qiuet al.(2000), Zhang et
al. (2006a), Zheng et al. (2006a) and Li et al. (2008) for the Yangtze craton. Uniform standard (207Pb/206Pb ages for zircons of ages N1.0 Ga and 206Pb/238U ages for zircons of age
b1.0 Ga) is used in data compilation except for ages from Gehrels et al. (2003) for Tethyan Himalaya. Note that the data used for comparison are only extracted from the early
Paleozoic and late Neoproterozoic strata.
Fig. 5. Plots of ε Hf(t ) value versus U–Pb age for detrital zircons of this study. Gray fields
show evolution of typical zircons (with a 176Lu/177Hf ratio of 0.0015) with depleted
mantle model ages between 500 and 1000 Ma, 1500 and 2000 Ma, and 2500 and
3000 Ma.
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(Fang et al., 1990). Based on the comparison of the Sinian–Cambrian
paleomagnetic records from South China with the counterparts from
Australia, Zhang and Piper (1997), however, suggested that the SCB
should be located immediately to northwestern Australia during the
early Paleozoic. Taking into account the documented late Proterozoic
and Silurian poles of the Yangtze Block (Evans et al., 2000; Huang
et al., 2000b), Yang et al. (2004) inferred that the SCB was most likely
located close to western Australia. Macouin et al. (2004) reached a
similar conclusion by measuring the paleomagnetic records of LateNeoproterozoic Nantuo tillite and overlying Doushantuo carbonates,
plotting the SCB close to the equator at the west side of Australia. By
means of paleomagnetic results from the central Yangtze block and
comparisons of Precambrian sequences between the SCB and
Australia (Li et al., 1995, 1996, 2004), Li et al. (2001, 2008b), however,
argued that the SCB was a discrete continent block in the paleo-Pacific
during the assembly of Gondwana. They proposed that the SBC was
originally located between eastern Australia and Laurentia, and linked
with them during the assembly of Rodinia. Some geochronological
and geochemical studies of Neoproterozoic arc-magmatism along the
western margin of the Yangtze block appear to support the idea that
the SCB might have been an isolated continent in Neoproterozoic
(Zhou et al., 2002b). If this paleogeographic reconstruction was
correct, the SCB must have separated from Rodinia by Early Cambrian
times, and could not be a component of Early Palaeozoic Gondwana-
land (Metcalfe, 2006). This might be the reason why the SCB was
usually omitted from paleogeographic reconstructions of Gondwana-
land (e.g.: Dalziel, 1997; Boger et al., 2001; Powell and Pisarevsky,
2002; Cocks and Torsvik, 2002; Collins and Pisarevsky, 2005).
Our discovery of abundant magmatic zircon detritus, of Grenvillian
and Pan-African ages indicating a typical Gondwana signature, is
contrary to the previous paleogeographic reconstruction of the
Gondwanaland supercontinent depicting the SCB as a discrete
continental block in the Paleo-Pacific, far away from the northeastern
margin of East Gondwana. Our result is supported by qualitative
comparisons of detrital zircon age spectra of this study with those of
late Neoproterozoic sediments from the southern Cathaysian block, of
early Paleozoic sediments in pre-rift Tethyan Himalaya sequence, and
of Ordovician sandstone from the Perth Basin in West Australia. They
all have two major age clusters representing Grenvillian and Pan-
African orogenic episodes, and show conspicuous similarity (Fig. 4).In
addition, all the peak values of Grenvillian age in these distributions
are less than 1.0 Ga, much younger than those reported in other
regions, such as the Albany–Fraser Belt in Australia and Maud
Province in West Antarctica (Fitzsimons, 2000a,b; Meert, 2003a,b).
The difference between these age spectra was the age group ranging
from 800 Ma to 680 Ma in the SCB, which might be due to a
contribution from widespread Neoproterozoic magmatic rocks bothin the Jiangnan orogen and the Hannan–Panxi arc. The close age
spectra af finities suggest a connection of the SCB with the Himalaya
region in North India and with West Australia during the assembly of
the East Gondwana (Fig. 6), and thus the SCB should be a part of East
Gondwana rather than far away from it. It is suggested that the most
likelysource of theGrenvillianand Pan-African agezircons in thewest
margin of the Yangtze block is the East African orogen, which was
uplifted during Neoproterozoic time (Dalziel, 1997) and provided the
detritus of equivalent zircons in the Tethyan Himalaya (DeCelles et al.,
2000), and Kuunga orogen (Fig. 6). The Kuunga orogen was
constituted mostly by Northern Prince Charles Mountains (NPCM)
in Antarctica, Eastern Ghats (EG) in India and some Pan-African
mobile belts (Meert, 2003a,b; Cawood and Buchan, 2007) and
behaved as a major source of the equivalent zircons in the Cathaysian
Block (Yu et al., 2008). The NPCM and EG have dominant age groups
from 990 Ma to 950 Ma (Mezger and Cosca, 1999; Fitzsimons, 2000a),
which is consistent with the peak values of the Grenvillian age groups
of our study area.
The localization of early Paleozoic SCB adjacent to the Himalaya
and West Australian region is consistent with the majority of
paleomagnetic data, which places the SCB in southern paleolatitudes
and close to the equator in the early Palaeozoic ( Lin et al., 1985;
Burrett et al., 1990; Zhao et al., 1996; Huang et al., 2000b), indicating a
long-term connection between the SCB and West Australia (Zhang
and Piper, 1997; Yang et al, 2004; Macouin et al., 2004). Similarly, Zhu
et al. (1998) and Huang et al. (2000a, 2008) suggested that the SCB
might be close to West Australia or as a part of Gondwana in the
Cambrian on the basis of paleomagnetic data. A study of the latest
Neoproterozoic rocks in the Lesser Himalaya of northwestern India
Fig. 6. Restored position of the South China block in Gondwana. The Gondwana reconstruction is after DeCelles et al. (2000) and Boger et al. (2001) . Arrow denotes transport
direction of detritus from East African orogen where 650–550 Ma ages dominate (Fitzsimons, 2000a,b; Kröner et al., 2000; Yibas et al., 2002; Collins et al., 2003a,b), and Kuunga
orogen where 990–950 Ma and 600–500 Ma ages dominate (Mezger and Cosca, 1999; Fitzsimons, 2000a,b). Because the geometry of past plate was modified inevitably during later
rotation, accretion, collision and plate inter-actions, the SCB in Early Paleozoic is represented using dashed line. See text for detailed discussion.
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and the SCB also reveals remarkably similar facies assemblages and
carbonate platform systems ( Jiang et al., 2003). These similarities
suggest that the SCB might have been located close to northwestern
India during late Neoproterozoic time ( Jiang et al, 2003). Based on
faunal af finities and stratigraphic comparisons, Burrett et al. (1990),
Nie (1991) and Metcalfe (1996a,b) considered that the SCB might
have had its origin on the Himalaya region of the Gondwanaland
margin. Our Hf isotopic data support this idea, which indicate that the
crust evolution in drainage area was characterized by juvenile crustaladdition at 1.9 Ga and 3.1 Ga, respectively, and was followed by long-
term melting of pre-existing crustal rocks (Fig. 5). Crustal evolution of
the drainage area might be related to episodic crustal generation of
Gondwana around 1.9 and 3.3 Gyr ago, and then reworked repeatedly
(Kemp et al., 2006). Our U–Pb geochronological and Hf geochemical
data provide a new piece of evidence that demonstrates the
connection of the South China block with the Gondwana, and
therefore clarify the previous conflicting paleomagnetic results.
6. Conclusions
U–Pb ages of detrital zircons from Early Devonian quartz arenites
of the northwestern margin of the Yangtze block reveal three major
age groups: 0.85–
1.0 Ga (early Neoproterozoic), 680–
800 Ma, and650–500 Ma (Pan-African) together with some minor but widely
distributed Pre-Grenvillian populations. It is suggested that both early
Neoproterozoic and Pan-African detrital zircons of Lower Devonian
quartz arenites most likely came from the East African Orogen and
Kuunga Orogen, whereas the Jiangnan orogen, the Hannan–Panxi arc
and the Yangtze block basements might be the sources of the
Neoproterozoic and some pre-Grenvillian detrital zircons. Although
Hf isotopic compositions show both juvenile crustal growth and
crustal reworking for all age groupings, crustal growth of the drainage
areas, essentially mantle-derived, mainly occurred around 3.1 Ga,
1.9 Ga and 1.0 Ga, and was followed by the repeated melting of pre-
existing crust rocks. Qualitative comparisons of age spectra of detrital
zircons of this study with other investigations show that they all have
the two largest age clusters, Grenvillian and Pan-African orogenic
episodes. The Hf isotopic data also indicate that the crust evolution of
drainage area is comparable with the episodic crust generation of
Gondwana. All these results suggest that the SCB should be linked
with North India and Western Australia during the assembly of East
Gondwana, challenging the previous view that envisaged the SCB as a
separate continental block.
Acknowledgments
This research was supported by grants from the China Nature
Science Foundation (grant 40830314) and the Northwest University
Graduate Innovation and Creativity Funds (grant 08YZZ51). Ian
Metcalfe and an anonymous reviewer are thanked for their construc-
tive comments and suggestions that led to considerable improvement
of the paper. We also thank Lu Sun and Hujun Gong for the
preparation of CL images of detrital zircons, and Ben Lee, Lei Kang,
Guofen He, Jing Xu, Mengning Dai and Chunrong Diwu for their lab
support.
Appendix A. Supplementary data
Supplementary data associated with this article can be found, in
the online version, at doi:10.1016/j.gr.2010.05.005.
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