tr450doc

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Traabilit des mesures chimiques dans le contexte de la directive cadre sur leau

par Philippe QUEVAUVILLERCadre la Commission europenne, Direction gnrale de lEnvironnementProfesseur la Vrije Universiteit Brussel (VUB)

[1] Directive 2000/60/CE du Parlement europet du Conseil du 23 octobre 2000 tablisun cadre pour une politique communaudans le domaine de leau, Journal Ofdes Communauts europennes L 327, 22 dc. 2000.

[2] Document Guide no 7 sur la surveilldans le cadre de la Directive Cadre sur l(en anglais), Commission europeBruxelles (2003).

[3] Document Guide no 15 sur la surveilldes eaux souterraines, on Groundwaternitoring (en anglais), Commission epenne, Bruxelles (2006).

[4] Document Guide sur la surveillance des ede surface (en anglais), Commission epenne, Bruxelles, en prparation.

[5] Dcision no 2455/2001/CE du Parlementeuropen et du Conseil du 20 novembre tablissant la liste des substances dans lemaine de leau et modifiant la dire2000/60/CE, Journal officiel des commuts europennes L 331, p. 1, 15 dc. 200

[6] Directive 2006/118/CE du Parlement epen et du Conseil du 12 dcembre 2006la protection des eaux souterraines cont

616 (1999).[12] QUEVAUVILLER (Ph.). J. Environ. Monitor.,

terlaboratory Studies and Certified ReferenceMaterials for Environmental Analysis. Else-vier, Amsterdam, ISBN : 0-444-82389-1,

Produ

Tableau 1

Producteur, pays A

BAM, Allemagne http://www

CMI, Rpublique Tchque http://www

EUROFINS, Danemark http://www

GUM, Pologne http://www

IAEA, Autriche http://www

IPO, Pologne http://wwwest strictement interdite. Editions T.I. Doc. TR 450 12001 do-

ctivenau-1.

uro- surre la

vol. 2, 292 (2000).[13] QUEVAUVILLER (Ph.) et DONARD (O.F.X.).

Trends Anal. Chem., 20, 600 (2001).[14] QUEVAUVILLER (Ph.), in MESTER (Z.) et

STURGEON (B.) (Eds.). Sample Preparationfor Trace Analysis. Elsevier, Amsterdam(2004).

p. 558 (1999).

[21] Projet EAQC-WISE European AnalyticalQuality Control in support of the Water Infor-mation System for Europe , Commissioneuropenne, projet financ par le 6me Pro-gramme Cadre de Recherche et Dveloppe-ment Technologique.

cteurs de matriaux de rfrence (tableau 1)

Exemples de producteurs de matriaux de rfrence

dresse lectronique Producteur, pays Adresse lectronique

.bam.de/ IRMM, Commission europenne http://www.irmm.jrc.be

.cmi.cz/ LGC, Grande-Bretagne http://www.lgcpromochem.com/ home/home_en.aspx

.eurofins.dk/ NIST, tats-Unis http://www.nist.gov/

.gum.gov.pl/pl/site/ NRC-CNRC, Canada http://inms-ienm.nrc-cnrc.gc.ca/

.iaea.org/programmes/aqcs/ National Institute of Metrology, Chine http://www.nim.ac.cn/

.ipo.waw.pl/ SMU, Slovaquie http://www.smu.gov.sk/OIR

PLUS

Bibliographie

ensanttaireficielp. 1,

ance'eaunne,

ance Mo-uro-

auxuro-

pollution et la dtrioration, Journal officieldes communauts europennes L 372, p. 19,12 dc. 2009.

[7] Stratgie commune de mise en uvre de ladirective cadre sur leau. (Common Imple-mentation Strategy for the Water FrameworkDirective), Commission europenne,ISBN 92-894-2040-5 (2003).

[8] QUEVAUVILLER (Ph.). J. Environ. Monitor.,vol. 28, 240 (2006).

[9] ISO, International Vocabulary of Basic andGeneral Terms in Metrology, 2nd Edition, In-ternational Standardisation Organisation,Genve, Suisse (1993).

[10] VLCARCEL (M.) et ROS (A.). Anal. Chem.,vol. 65, 78A (1999).

[11] WALSH (M.C.). Trends Anal. Chem., vol. 18,

[15] QUEVAUVILLER (Ph.). Trends Anal. Chem.,vol. 23(3), p. 171-177 (2004).

[16] QUEVAUVILLER (Ph.), DONARD (O.) et THO-MAS (O.). Traabilit des analyses chimi-ques environnementales. Techniques de lIn-gnieur, [P 3 810], 16 p. (2004).

[17] DE BIVRE (P.) et in GNZLER (H.) (Ed). Ac-creditation and Quality Assurance in Analyti-cal Chemistry. Springer, Berlin (1996).

[18] QUEVAUVILLER (Ph.) et MAIER (E.). Mat-riaux de rfrence non nuclaires. Techni-ques de lIngnieur, [P 240], 16 p. (2001).

[19] QUEVAUVILLER (Ph.). Trends Anal. Chem.,vol. 13(9), p. 404-409 (1994).

[20] QUEVAUVILLER (Ph.) et MAIER (E.A.). In-


TRAABILIT DES MESURES CHIMIQUES DANS LE CONTEXTE DE LA DIRECTIVE CADRE SUR LEAU _________________________________________________

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MRC lis aux substances prioritaires de la DCE (tableaux 2 et 3)

Tableau 2 Matriaux de rfrence certifis lis aux substances prioritaires de la DCEComposs purs ou solutions

Substance prioritaire Ident. MRC Producteur Valeur certifie Rfrence

Alachlor SRM-3070 NIST 24,0 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

Anthracne DPAC-1 NRC-CNRC, Canada 13 g/g http://inms-ienm.nrc-cnrc.gc.ca/calserv/crm_e.html

SIRM 10-2-30s Q-chem Ltd.,Slovakia 48,7 g/g http://www.comar.bam.de/

SRM-1647d NIST 20,77 g/mL http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfmSRM-2260a NIST 3,231 g/mL http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

Atrazine SRM-3070 NIST 39,2 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

Benzne 7141-95M/1 GUP TSIKV 0,99 g/L http://www.comar.bam.de/

7141-95M/2 GUP TSIKV 0,495 g/L http://www.comar.bam.de/

7141-95M/3 GUP TSIKV 0,097 g/L http://www.comar.bam.de/

7141-95M GUP TSIKV 99,87 % http://www.comar.bam.de/

C03 SMU 99,9 % http://www.comar.bam.de/

GBW 06104Tian Jin Instituteof MetrologicalTechnology

99,95 % http://www.comar.bam.de/

Cadmiumet ses composs

1,2-Dichlorothane

Endosulfan

Hexachlorobenzne

Hexachloro-cyclohexanegamma-isomre

Plombet ses composs

NaphthalneToute reproduction sans autorisation du Centre franais dexploitation du droit de copie est strictement interdite. Editions T.I.

6690-93/1 GUP TSIKV 1 g/L http://www.comar.bam.de/

7325-96 GUP TSIKV 0,010 1 % http://www.comar.bam.de/

DMR-85c CENAM, Mexico 1 001,0 mg/L http://www.comar.bam.de/

DMR-8i CENAM, Mexico 1 mg/L http://www.comar.bam.de/

GBW-08602 National Instituteof Metrology, China 0,100 g/kg http://www.comar.bam.de/

GBW-08607 National Instituteof Metrology, China 0,100 g/g http://www.comar.bam.de/

GBW-08608 National Instituteof Metrology, China 10,0 g/kg http://www.comar.bam.de/

JK-0012 Cd 1000 CERI, Japan 0,1 % http://www.comar.bam.de/

7332-96 GUP TSIKV, Russia 99,76 % http://www.comar.bam.de/

SRM-3012 NIST 0,010 039 g/g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-3069 NIST 4,66 mg/kg (I) 5,29 mg/kg (II) http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-2275 NIST 2,880 mg/kg (I) 2,943 mg/kg (II) http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-1492 NIST 308 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfmSRM-2261 NIST 1,968 g/mL http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfmSRM-3069 NIST 4,39 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SLRM-10-2-08Slovak Instituteof Metrology,Slovakia

0,1 % http://www.comar.bam.de/

SRM-1492 NIST 310 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-2261 NIST 1,972 g/mL http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-3069 NIST 4,22 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-8466 NIST 99,9 weight % http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

7012-93/1 GUP TSIKV 1,01 g/L http://www.comar.bam.de/

DMR-63c CENAM, Mexico 1 002,1 mg/L http://www.comar.bam.de/

DMR-8i CENAM, Mexico 10 mg/L http://www.comar.bam.de/

DPAC-1 NRC-CNRC, Canada 116 g/g http://inms-ienm.nrc-cnrc.gc.ca/calserv/crm_e.html


SRM-1586-1 NIST 126,5 g /g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-1586-2 NIST 126,6 g/g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-1647d NIST 20,13 g/mL http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-2270 NIST 77,0 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm04/10/2008DOCUMENTATIONDossier dlivr pour



__________________________________________________ TRAABILIT DES MESURES CHIMIQUES DANS LE CONTEXTE DE LA DIRECTIVE CADRE SUR LEAU

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Nickelet ses composs DMR-8i CENAM, Mexico 1 mg/L http://www.comar.bam.de/

Pentachlorophnol SRM-1584 NIST 15,4 g/mL http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-3066 NIST 100,7 mg/L http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

HAPs Benzo[a]pyrne

DPAC-1 NRC-CNRC, Canada 35 g/g http://inms-ienm.nrc-cnrc.gc.ca/calserv/crm_e.html

GBW-08701

Beijing Municipal Environmental Monitoring Centre, China

5,75 g/g http://www.comar.bam.de/

GBW-08702 Beijing Municipal Environmental 10,0 g/g http://www.comar.bam.de/

Monitoring Centre, China


SRM-1586-1 NIST 49,2 g/g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-1586-2

SRM-1647d

SRM-2260a

SRM-2270

Fluoranthne DPAC-1

DPAC-2

SRM-1647d

SRM-2260a

SRM-2269

Benzo[b ]fluoranthne BCR-048R

DPAC-1

SRM-1647d

SRM-2260a

SIRM 10-2-30s

Benzo[k]fluoranthne BCR-048R

SRM-1647d

SRM-2260a

SIRM 10-2-30s

Indno[1,2,3-cd ]pyrne SIRM 10-2-30s

SRM-1647d

Benzo[g,h,i]prylne BCR-052

DPAC-1

SIRM 10-2-30s

SRM-1647d

SRM-2260a

SRM-2270

Simazine SRM-3070

Trichloromthane(chloroforme) 7288-96

SRM-1639

Tableau 2 Matriaux de rfrence certifis lis aux substances prioritaires de la DCEComposs purs ou solutions (suite)

Substance prioritaire Ident. MRC Producteur Valeur certifie Rfrenceproduction sans autorisation du Centre franais dexploitation du droit de copie est strictement interdite. Editions T.I. Doc. TR 450 3

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NIST 44,1 g/g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

NIST 4,91 g/mL http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm


NIST 37,3 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

NRC-CNRC, Canada 116 g/g http://inms-ienm.nrc-cnrc.gc.ca/calserv/crm_e.htmlNRC-CNRC, Canada 117 g/g http://inms-ienm.nrc-cnrc.gc.ca/calserv/crm_e.html

NIST 7,64 g /mL http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm



EC-JRC-IRMM 0,995 g/g http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

NRC-CNRC, Canada 35 g/g http://inms-ienm.nrc-cnrc.gc.ca/calserv/crm_e.html



Q-chem Ltd.,Slovakia 49,9 g/g http://www.comar.bam.de/








NRC-CNRC, Canada 23 g/g http://inms-ienm.nrc-cnrc.gc.ca/calserv/crm_e.html






GUP TSIKV, Russia 99,88 % http://www.comar.bam.de/

NIST 6 235 ng/L http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm



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Tableau 3 Matriaux de rfrence certifis lis aux substances prioritaires de la DCEMatrices : S Sdiment ; E Eau ; B Biote (plante aquatique ou animal)

Substanceprioritaire Matrice Ident. MRC Producteur

Valeurcertifie Rfrence

Anthracne S EC-1National Water Research Institute, Canada


S EC-8National Water Research Institute, Canada

41 g/kg http://www.comar.bam.de/

S IAEA-383IAEA AnalyticalQuality ControlServices

0,03 mg/kg http://www.comar.bam.de/


0,009 8 mg/kg http://www.comar.bam.de/


630 ng/g http://www.comar.bam.de/

S HS-3B NRC-CNRC, Canada 2,76 g/g http://www.comar.bam.de/

S HS-4B NRC-CNRC, Canada 0,46 g/g http://www.comar.bam.de/

S HS-5 NRC-CNRC, Canada 0,38 g/g http://www.comar.bam.de/

S

S

S

B

B

B

Benzne S

Cadmiumet ses composs E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

EToute reproduction sans autorisation du Centre franais dexploitation du droit de copie est strictement interdite. Editions T.I.

HS-6 NRC-CNRC, Canada 1,1 g/g http://www.comar.bam.de/

SRM-1941b NIST 184 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm


SRM-1974b NIST 0,527 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

IAEA-140/OCIAEA AnalyticalQuality ControlServices


IAEA-432IAEA AnalyticalQuality ControlServices

1,5 ng/g http://www.comar.bam.de/

PR 9584 RIZA QA and Inter-laboratory studies 7,62 g/kg http://www.comar.bam.de/

BCR-505 EC-JRC-IRMM 0,80 nmol/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm


BCR-609 EC-JRC-IRMM 0,164 g/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

BCR-610 EC-JRC-IRMM 2,94 g/kg http.//www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

BCR-713 EC-JRC-IRMM 5,1 g/L http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm


BCR-715 EC-JRC-IRMM 40 g/L http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

QC LL2 EUROFINS (DK) 2 g/L http://www.eurofins.dk

CASS-4 NRC-CNRC, Canada 0,026 g/L http://inms-ienm.nrc-cnrc.gc.ca

LGC-6016 LGC-Promochem 101 g/kg http://www.comar.bam.de/

LGC-6017 LGC-Promochem 0,13 g/L http://www.comar.bam.de/

LGC-6019 LGC-Promochem 0,11 g/L http://www.comar.bam.de/

NASS-5 NRC-CNRC, Canada 0,023 g/L http://inms-ienm.nrc-cnrc.gc.ca

SLEW-3 NRC-CNRC, Canada 0,048 g/L http://inms-ienm.nrc-cnrc.gc.ca

SLRM-12-3-10 Research Institute for Irrigation, Slovakia 0,005 g/g http://www.comar.bam.de/

SLRS-4 NRC-CNRC, Canada 0,012 g/L http://inms-ienm.nrc-cnrc.gc.ca

SRM-1640 NIST 22,79 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-1643e NIST 6,408 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm04/10/2008DOCUMENTATIONDossier dlivr pour




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Cadmiumet ses composs (suite)

E TM-23.2 NRC-CNRC, Canada 2,6 g/kg http://www.comar.bam.de/

E TM-24 NRC-CNRC, Canada 12,5 g/kg http://www.comar.bam.de/





E TMRAIN-51.2 NRC-CNRC, Canada 25,1 g/kg http://www.comar.bam.de/

E TMRAIN-52.2 NRC-CNRC, Canada 91,4 g/kg http://www.comar.bam.de/

E TMRAIN-53.2 NRC-CNRC, Canada 122 g/kg http://www.comar.bam.de/

E TMRAIN-54.2 NRC-CNRC, Canada 185 g/kg http://www.comar.bam.de/

E TMRAIN-95 NRC-CNRC, Canada 0,48 g/kg http://www.comar.bam.de/

S GBW-07314

S GBW-08301

S HISS-1

S IAEA-SL-1

S MESS-3

S NIES-2

S NIES-9

S PACS-2

S SRM-1646a

S SRM-1944

S SRM-2702

B DORM-2

B LUTS-1

B DOLT-3

B TORT-2

B GBW-08571

B LGC-7160

B SLRM-12-2-02

B SRM-1566b

B SRM-2976

B SRM-2977

B ERM-CE278

B BCR-279

B BCR-060

B BCR-414

B BCR-422

Tableau 3 Matriaux de rfrence certifis lis aux substances prioritaires de la DCEMatrices : S Sdiment ; E Eau ; B Biote (plante aquatique ou animal) (suite)


Valeurcertifie Rfrenceproduction sans autorisation du Centre franais dexploitation du droit de copie est strictement interdite. Editions T.I. Doc. TR 450 5

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NRCCRM, China 0,20 g/g http://www.comar.bam.de/

Institute ofEnvironmentalChemistry, China


NRC-CNRC, Canada 0,024 mg/kg http://inms-ienm.nrc-cnrc.gc.ca

IAEA, Austria 0,26 mg/kg http://www.comar.bam.de/

NRC-CNRC, Canada 0,24 mg/kg http://inms-icem.nrc-cnrc.gc.ca

NIES, Japan 0,82 g/g http://www.comar.bam.de/










Institute ofEnvironmentalChemistry, China


LGC-Promochem 1,85 mg/kg http://www.comar.bam.de/

Institute of Radio-ecology and Applied Nuclear Techniques, Slovakia

44,8 g/kg http://www.comar.bam.de/




EC-JRC-IRMM 0,348 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

EC-JRC-IRMM 0,274 mg/kg http://www.irmm.jrc. be/html/reference_materials_catalogue/index.htm



EC-JRC-JRMM 0,017 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm



Doc. TR 450 6

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Hexachloro-benzne S EC-2

National Water Res. Inst., Canada 200,6 g/kg http://www.comar.bam.de/

S EC-3 National Water Res. Inst., Canada 279 g/g http://www.comar.bam.de/



S SRM-1941b NIST 5,83 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

S SRM-1944 NIST 6,03 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

B SRM-1945 NIST 32,9 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

B SRM-1946 NIST 7,25 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

B BCR-598 EC-JRC-IRMM 55,7 g/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

B IAEA-432 IAEA AnalyticalQuality Control Services 0,2 ng/g http://www.comar.bam.de/

B

Hexachloro-butadine S

S

S

B

Hexachloro-cyclohexane gamma-isomre

S

S

B

B

B

B

Plombet ses composs E

E

E

E

E

E

E

E

E

E

E

E

E

E

W

E



Valeurcertifie RfrenceToute reproduction sans autorisation du Centre franais dexploitation du droit de copie est strictement interdite. Editions T.I.


EC-2 National Water Res. Inst., Canada 21,3 g/kg http://www.comar.bam.de/

EC-3 National Water Res. Inst., Canada 61 g/g http://www.comar.bam.de/

EC-8 National Water Res. Inst., Canada 21 g/kg http://www.comar.bam.de/

SRM-1945 NIST 32,9 g /kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

IAEA-408 IAEA AnalyticalQuality Control Services 0,000 19 mg/kg http://www.comar.bam.de/

IAEA-417 IAEA AnalyticalQuality Control Services 0,54 ng/g http://www.comar.bam.de/





7272-96 GUP TSIKV 0,103 g/L http://www.comar.bam.de/




BCR-713 EC-JRC-IRMM 47 g/L htrp://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

BCR-714 EC-JRC-IRMM 145 g/L http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm


QC LL2 EUROFINS (DK) 20 g/L http://www.eurofins.dkCASS-4 NRC-CNRC, Canada 0,009 8 g/L http://inms-ienm.nrc-cnrc.gc.caNASS-5 NRC-CNRC, Canada 0,008 g/L http://inms-ienm.nrc-cnrc.gc.caSLEW-3 NRC-CNRC, Canada 0,009 0 g/L http://inms-ienm.nrc-cnrc.gc.caSLRS-4 NRC-CNRC, Canada 0,086 g/L http://inms-ienm.nrc-cnrc.gc.caGBW-08601 NRCCRM, China 1,0 g/g http://www.comar.bam.de/

GBW-08607 National Instituteof Metrology, China 1,0 g/g http://www.comar.bam.de/

GBW-08608 National Instituteof Metrology, China 50 g/kg http://www.comar.bam.de/

LGC-6016 LGC-Promochem 196 g/kg http://www.comar.bam.de/04/10/2008DOCUMENTATIONDossier dlivr pour




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Plombet ses composs (suite)

E LGC-6017 LGC-Promochem 1,0 g/L http://www.comar.bam.de/

E LGC-6019 LGC-Promochem 5,2 g/L http://www.comar.bam.de/

E ERML-CA010a LGC 95 mg/L http://www.lgcpromochem.com

E SIRM 12-3-10 Res. Inst.for Irrigation,Slovakia 0,029 g/g http://www.comar.bam.de/

E SRM-1640 NIST 22,79 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

E SRM-1643e NIST 19,45 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

E TM-23.2 NRC-CNRC, Canada 3,8 g/kg http://www.comar.bam.de/E TM-24 NRC-CNRC, Canada 7,3 g/kg http://www.comar.bam.de/E TM-26.2 NRC-CNRC, Canada 9,9 g/kg http://www.comar.bam.de/E TM-27 NRC-CNRC, Canada 4,9 g/kg http://www.comar.bam.de/E TM-27.2 NRC-CNRC, Canada 3,2 g/kg http://www.comar.bam.de/E TM-28 NRC-CNRC, Canada 3,0 g/kg http://www.comar.bam.de/E TMRAIN-51.2

E TMRAIN-52.2

E TMRAIN-53.2

E TMRAIN-54.2

E TMRAIN-95

S GBW-07314

S GBW-08301

S HISS-1

S MESS-3

S PACS-2

S IAEA-SL-1

S NIES-2

S NIES-9

S SRM-1646a

S SRM-1944

S SRM-2702

B BCR-060

B BCR-279

B BCR-414

B BCR-422

B ERM-CE278

B DOLT-3

B DORM-2

B GBW-08571

B SLRM-12-2-02

B SRM-1566b

B SRM-2976

B SRM-2977

B LUTS-1

B TORT-2




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NRC-CNRC, Canada 72,9 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 368 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 360 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 531 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 0,29 g/kg http://www.comar.bam.de/NRCCRM, China 25 g/g http://www.comar.bam.de/Inst. of EnvironmentalChemistry, China 79 g/g http://www.comar.bam.de/



NRC-CNRC, Canada 183 mg/kg http://inms-ienm.nrc-cnrc.gc.ca


NIES, Japan 105 g/g http://www.comar.bam.de/NIES, Japan 1,35 g/g http://www.comar.bam.de/


NIST 330 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm









Inst. of EnvironmentalChemistry, China 1,96 g/g http://www.comar.bam.de/

Institute of Radio-ecology and Applied Nuclear Techniques, Slovakia









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Mercureet ses composs E 8004-93/1 GUP TSIKV 1,01 g/L http://www.comar.bam.de/

E BCR-579 EC-JRC-IRMM 1,85 ng/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

E ORMS-3 NRC-CNRC, Canada 12,6 pg/g http://inms-ienm.nrc-cnrc.gc.ca

E SIRM 12-3-10 Res. Inst. for Irrigation,Slovakia 0,001 1 g/g http://www.comar.bam.de/

E SRM-1641d NIST 1,590 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

E QC LL3 EUROFINS (DK) 5 g/L http://www.eurofins.dkE QC LL3A EUROFINS (DK) 0,5 g/L http://www.eurofins.dk

S ERM-CC580 EC-JRC-IRMM 132 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

S GBW-07314 NRCCRM, China 0,20 g/g http://www.comar.bam.de/

S GBW-08301 Inst. of EnvironmentalChemistry, China 0,048 g/g http://www.comar.bam.de/

S MESS-3 NRC-CNRC, Canada 0,091 mg/kg http:/inms-ienm.nrc-cnrc.gc.ca

S PACS-2 NRC-CNRC, Canada 3,04 mg/kg http://inms-ienm.nrc-cnrc.gc.ca

S

S

S

B

B

B

B

B

B

B

B

B

B

B

B

B

B

B

Naphthalne S

S

S

S

S

S

S

S

S

B

B




SRM-2702 NIST 0,447 4 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

WQB-1 NRC-CNRC, Canada 1,09 g/g http://www.comar.bam.de/WQB-3 NRC-CNRC, Canada 2,75 g/g http://www.comar.bam.de/

BCR-060 EC-JRC-IRMM 0,34 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm




DOLT-3 NRC-CNRC, Canada 3,37 mg/kg http://inms-ienm.nrc-cnrc.gc.ca

DORM-2 NRC-CNRC, Canada 4,64 mg/kg http://inms-ienm.nrc-cnrc.gc.ca

ERM-CE278 EC-JRC-IRMM 0,196 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

ERM-CE464 EC-JRC-IRMM 5,24 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

GBW-08571 Inst. of EnvironmentalChemistry, China 0,067 g/g http://www.comar.bam.de/

LGC-7160 LGC-Promochem 0,096 mg/kg http://www.comar.bam.de/

SRM-1566b NIST 0,037 1 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm



SRM-2976 NIST 61,0 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfrn

TORT-2 NRC-CNRC, Canada 0,27 mg/kg http://inms-ienm.nrc-cnrc.gc.ca

EC-8 National Water Res. Inst., Canada 10 g/kg http://www.comar.bam.de/

IAEA-383 IAEA AnalyticalQuality Control Services 0,096 mg/kg http://www.comar.bam.de/

IAEA-408 IAEA AnalyticalQuality Control Services 0,027 mg/kg http://www.comar.bam.de/

HS-3B NRC-CNRC, Canada 2,14 g/g http://www.comar.bam.de/HS-4B NRC-CNRC, Canada 0,22 g/g http://www.comar.bam.de/HS-5 NRC-CNRC, Canada 0,25 g/g http://www.comar.bam.de/HS-6 NRC-CNRC, Canada 4,1 g/g http://www.comar.bam.de/





SRM-1974b NIST 2,43 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm04/10/2008DOCUMENTATIONDossier dlivr pour




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Nickelet ses composs E 7272-96 GUP TSIKV, Russia 0,102 g/L http://www.comar.bam.de/

E 8001-93/1 GUP TSIKV, Russia 1,00 g/L http://www.comar.bam.de/

E SIRM 12-3-10 Res. Inst. for Irrigation,Slovakia 0,061 g/g http://www.comar.bam.de/

E BCR-403 EC-JRC-IRMM 4,4 nmol/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

E BCR-505 EC-JRC-IRMM 24,1 nmol/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

E BCR-713 EC-JRC-IRMM 30 g/L http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

E BCR-714 EC-JRC-IRMM 108 g/L http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

E BCR-715 EC-JRC-IRMM 1,20 g/L http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

E QC LL1 EUROFINS (DK) 15 g/L http://www.eurofins.dkE SRM-1643e NIST 60,89 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

E GBW-08607 National Instituteof Metrology, China 0,500 g/g http://www.comar.bam.de/

E GBW-08608

E LGC-6016

E LGC-6017

E LGC-6019

E ERML-CA010a

E CASS-4

E SLEW-3

E SLRS-4

E NASS-5

E TM-23.2

E TM-24

E TM-26.2

E TM-27

E TM-27.2

E TM-28

E TMRAIN-51.2

E TMRAIN-52.2

E TMRAIN-53.2

E TMRAIN-54.2

E TMRAIN-95

S SRM-1944

S SRM-2702

S GBW-07314

S HISS-1

S IAEA-SL-1

S MESS-3

S NIES-2

S PACS-2

S WQB-3

B DOLT-3

B DORM-2

B LUTS-1

B TORT-2

B GBW-08571

B BCR-414

B SRM-2977

B LGC-7160




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National Instituteof Metrology, China 60 g/kg http://www.comar.bam.de/

LGC-Promochem 186 g/kg http://www.comar.bam.de/LGC-Promochem 1,6 g/L http://www.comar.bam.de/LGC-Promochem 2,6 g/L http://www.comar.bam.de/LGC 48 mg/L http://www.lgcpromochem.com

NRC-CNRC, Canada 0,314 g/L http://inms-ienm.nrc-cnrc.gc.caNRC-CNRC, Canada 1,23 g/L http://inms-ienm.nrc-cnrc.gc.caNRC-CNRC, Canada 0,67 g/L http://inms-ienm.nrc-cnrc.gc.caNRC-CNRC, Canada 0,253 g/L http://inms-ienm.nrc-cnrc.gc.caNRC-CNRC, Canada 5,3 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 3,5 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 9,9 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 2,7 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 2,5 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 19,3 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 66,7 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 268 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 319 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 325 g/kg http://www.comar.bam.de/NRC-CNRC, Canada 0,80 g/kg http://www.comar.bam.de/



NRCCRM, China 34,3 g/g http://www.comar.bam.de/NRC-CNRC, Canada 2,16 mg/kg http://inms-ienm.nrc-cnrc.gc.ca



NIES, Japan 40 g/g http://www.comar.bam.de/NRC-CNRC, Canada 39,5 mg/kg http://inms-ienm.nrc-cnrc.gc.ca

NRC-CNRC, Canada 52,0 g/g http://www.comar.bam.de/NRC-CNRC, Canada 2,72 mg/kg http://inms-ienm.nrc-cnrc.gc.ca




Inst. of EnvironmentalChemistry, China 1,03 g/g http://www.comar.bam.de/



LGC-Promochem 0,23 mg/kg http://www.comar.bam.de/



Doc. TR 450 10

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Pentachloro-benzne S EC-2

National Water Research Institute, Canada



65 g/g http://www.comar.bam.de/



Pentachloro-phnol S BCR-530 EC-JRC-IRMM 0,47 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

HAPsBenzo[a]pyrne S BCR-535 EC-JRC-IRMM 1,16 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm



S

S

S

S

S

S

S

S

S

S

S

S

S

B

B

B

B




EC-2National Water Research Institute, Canada













2 800 ng/g http://www.comar.bam.de/

HS-3B NRC-CNRC, Canada 5,80 g/g http://www.comar.bam.de/

HS-4B NRC-CNRC, Canada 1,55 g/g http://www.comar.bam.de/









SRM-2977 NIST 8,35 g/g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

SRM-1974b NIST 2,80 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm04/10/2008DOCUMENTATIONDossier dlivr pour




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Fluoranthne S EC-1National Water Research Institute, Canada








S HS-3B NRC-CNRC, Canada 25,33 g/g http://www.comar.bam.de/S HS-4B NRC-CNRC, Canada 3,33 g/g http://www.comar.bam.de/S HS-5 NRC-CNRC, Canada 8,4 g/g http://www.comar.bam.de/S HS-6 NRC-CNRC, Canada 3,54 g/g http://www.comar.bam.de/

S IAEA-383IAEA AnalyticalQuality Control 0,29 mg/kg http://www.comar.bam.de/

S IAEA-408

S SRM-1941b

S SRM-1944

B IAEA-140/OC

B IAEA-432

B SRM-1974b

B SRM-2977

Benzo[b]fluoranthne S BCR-535

S IAEA-383

S IAEA-408

S IAEA-417

S SRM-1941b

S SRM-1944

S EC-8

S EC-1

S EC-2

S HS-5

S HS-6

B IAEA-432

B SRM-1974b

B SRM-2977




OIR

PLUS

Services

IAEA AnalyticalQuality ControlServices


NIST 651 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm





12 ng/g http://www.comar.bam.de/

NIST 17,1 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

















NRC-CNRC, Canada 2,0 g/g http://www.comar.bam.de/NRC-CNRC, Canada 2,8 g/g http://www.comar.bam.de/IAEA AnalyticalQuality ControlServices






Doc. TR 450 12

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Benzo[k ]fluoranthne S BCR-535 EC-JRC-IRMM 1,09 mg/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm






2 000 g/g http://www.comar.bam.de/

S SRM-1941b NIST 225 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm



S

S

S

S

S

B

B

Indno[1,2,3-cd ]pyrne S

S

S

S

S

S

S

S

S

B

B

B






























SRM-2977 NIST 4,84 g/g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm04/10/2008DOCUMENTATIONDossier dlivr pour




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Benzo[g,h,i ]prylne S EC-1











S IAEA-417

S HS-3B

S HS-4B

S HS-5

S HS-6

S SRM-1941b

S SRM-1944

B SRM-1974b

B SRM-2977

B IAEA-140/OC

Compossde tributyltain S BCR-462

S BCR-646

S HIPA-1

S PACS-1

S PACS-2

S SOPH-1

B NIES-11

Trichloro-benznes (1,2,4-trichloro-benzne)

S EC-2

S EC-8




OIR

PLUS



NRC-CNRC, Canada 3,88 g/g http://www.comar.bam.de/










EC-JRC-IRMM 54 g/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

EC-JRC-IRMM 480 g/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

NRC-CNRC, Canada 78 ng/g http://inms-ienm.nrc-cnrc.gc.ca


NRC-CNRC, Canada 0,890 mg/kg(Tri-) http://inms-ienm.nrc-cnrc.gc.ca









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Tableau 4 Matriaux de rfrence certifis lis dautres polluantsComposs purs ou solutions

Substance Matrice Ident. MRC Producteur Valeurcertifie Rfrence

DDTp, -DDT P SRM 1492 NIST 302 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

P SRM 2261 NIST 3,004 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm


P SRM 2275 NIST http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

Dieldrlne P SRM 1492 NIST 307 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm


Endrine P SRM 2275 NIST 2,908 mg/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

Carbonttra-chloride P SRM 3006 NIST 0,010 099 g/g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

Ttrachloro-thylne P SRM 3010 NIST 0,009 772 g/g http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

p

Tableau 5 Matriaux de rfrence certifis lis dautres polluantsMatrices : S Sdiment ; E Eau ; B Biote (plante aquatique ou animal)

Substanceprioritaire Matrice Ident. MRC Producteur Valeur certifie Rfrence

DDTp, -DDT S IAEA-408

IAEA Analytical Quality Control Services


S SRM-1944 NIST 199 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

B SRM-1974b NIST 3,91 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm

B

B

B

B

B

B

Dieldrine S

B

B

B

B

pToute reproduction sans autorisation du Centre franais dexploitation du droit de copie est strictement interdite. Editions T.I.

IAEA-140/OCIAEA Analytical Quality Control Services


SRM-1945 NIST 245 g/kg http://ts.nist.gov/MeasurementServices/ReferenceMaterials/232.cfm




BCR-598 EC-JRC-IRMM 179 g/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm

IAEA-408IAEA Analytical Quality Control Services


IAEA-140/OCIAEA Analytical Quality Control Services




BCR-598 EC-JRC-IRMM 59 g/kg http://www.irmm.jrc.be/html/reference_materials_catalogue/index.htm04/10/2008DOCUMENTATIONDossier dlivr pour

BibliographieProducteurs de matriaux de rfrence (tableau 1)MRC lis aux substances prioritaires de la DCE (tableaux 2 et 3)

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