TPV Seal Geometry Effects on Compression Set (CSet) and Compression Load Defglection -...

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    TPV Seal Geometry Effects On

    Compression Set (CSet) andCompression Load Deflection (CLD)

    Jere Anderson, Trexel, Inc

    Felix Zacarias, Santoprene Specialty Products

    ExxonMobil Chemical

    Above-The-Belt 2006 Novi, MI

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    Outline Background

    Study objectives

    Approach

    Sample production

    Materials

    Process Results

    Conclusions

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    Background Primary and secondary automotive weatherseals are

    complex, multifunctional profiles that:

    Control or affect:

    Water ingression

    Wind noise

    Door closing effort

    Aesthetics at vehicle entry

    Typically consist of:

    Sponge sealing section

    Mounting section

    Dense polymer

    Metal reinforcement

    Trim

    Secondary lip

    Skin coat

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    Background Performance requirements for weatherseal sponge

    Surface contact area for sealing

    Conform to sealing surface imperfections and build tolerances Low compression force

    Withstand high deformations

    Provide rapid, elastic deformation recovery

    Operate over a wide temperature range Maintain properties with cyclical deformations

    Provide consistent properties over long product life

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    Background

    Meeting weatherseal performance needs requires:

    Materials

    Process Part Design Trexel MuCell process

    Closed cellular structure

    Designed for performance Foamability

    Surface aspect

    Low CLD

    Low CSet

    Elongation

    Geometry

    Dimensions Sponge specific gravity

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    Background EPDM material properties TPV material properties

    Current weatherseal designs based on EPDM properties

    Historical material of choice Seal designer and manufacturer experiences

    Different design rules anticipated for optimal seal performance with TPV

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    Objective The objective of this investigation was to quantify the

    effects of varying TPV profile design on key weatherseal

    performance criteria to define TPV sponge designs for

    optimal weatherseal performance.

    Study variables

    Profile shape

    Profile wall thickness Sponge density

    Measured results

    CSet

    Short term

    Long term

    CLD

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    Approach Produce D shaped profiles of equal height varying:

    Shape

    Wall thickness 1.5 and 2.0 mm

    Sponge density 0.55 to 0.65 gm/cc

    Assess performance differences

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    Sample Preparation Process

    MuCell foam extrusion process

    Physical foaming technology Direct injection of supercritical N2 or CO2

    Equipment

    Trexel extrusion system 63 mm diameter, 32:1 L/D

    Throughput 45 kg/hr (100 lb/hr)

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    Sample Preparation Materials

    Santoprene X121-60F150 polymer

    typ. properties test method Specific gravity 0.97 g/cc TPE-0105/1

    Hardness 60 Shore A TPE-0104

    Ultimate tensile str. 4.5 MPa (650 psi) TPE-0153

    Elongation @ break 390% TPE-0153

    SCF

    Type N2

    Delivery pressure 172 bar (2,500 psi)

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    Results Samples Produced

    Actual optical comparator tracings

    -2O Profile 22O Profile 57O Profile

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    Results11

    Short Term Cset - 22hr @ 70OCSantoprene

    TMX121-60F150, Spong e S.g. 0.54 - 0.60 g/cc , Test Me tho d TPE 0016

    20.0

    25.0

    30.0

    35.0

    40.0

    45.0

    50.0

    1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2 2.1 2.2 2.3 2.4 2.5

    Wall Thicknes s (m m )

    CSet

    (%)

    -2O

    Profile

    22O Profile

    57O

    Profile

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    Results12

    CLD - 50% and 25% Com pressionSantoprene

    TMX121-60F150, Spon ge S.g. 0.54 - 0.60 g/cc, Tes t Met ho d A STM D 1667

    0

    2

    4

    6

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    10

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    1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2 2.1 2.2 2.3 2.4 2.5

    Wall Thickness (mm )

    CLD

    (N/1

    00mm)

    -2O

    Pro file - 50%

    22O

    Pro file - 50%

    57O

    Pro file - 50%

    -2O

    Pro file - 25%

    22O

    Prof ile - 25%

    57O

    Pro file - 25%

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    Results13

    50% Com pressio n CLD vs. Short Term CSetSantoprene

    TMX121-60F150, Sponge S.g. 0.54 - 0.60 g/cc, Tes t Me tho ds ASTM D 1667 & TPE 0016

    0

    5

    10

    15

    20

    25

    30

    35

    40

    1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2 2.1 2.2 2.3 2.4 2.5

    Wall Thickness (m m )

    CLD

    (N/10

    0mm)

    10

    15

    20

    25

    30

    35

    40

    45

    50

    CSet(%)

    -2O

    Profile

    22O

    Profile

    57O Profile

    -2O Profile

    22O

    Profile

    57O

    Profile CSet

    CL D

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    Results14

    Lo ng Term Cset - 1,000 ho urs @ 70OCSantoprene

    TMX121-60F150, Spong e S.g. 0.54 - 0.60 g/cc , Test Metho d TPE 0016

    0

    10

    20

    30

    40

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    0 100 200 300 400 500 600 700 800 900 1000

    Time (hours)

    CSet(%

    )

    Typical EPDM

    Typical 60F150

    -2O

    Profile

    57O

    Profile

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    Results SummarySantoprene X121-60F150 Sponge 0.54 0.60 g/cc

    Anticipated CLD and CSet range:

    Min. Max. Units

    CLD (25% compression) 2.6 10.8 N/100 mmCLD (50% compression) 7.0 34.5 N/100 mm

    CSet 32 48 %

    Shape and wall thickness changes from 1.4 to 2.2 mm.

    Sponge density changes did not affect CSet or CLD.

    Short term CSet is reduced with:

    Shape change parallel to load 5% points at fixed wall thickness.

    Wall thickness increase 1.4% points/0.1 mm increase.

    A total of 16% points with both shape and wall thickness changes.

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    Results SummarySantoprene X121-60F150 Sponge 0.54 0.60 g/cc

    CLD is reduced with :

    Shape change to more round profiles at fixed wall thickness

    11 to 12 N/100 mm (50% compression)

    1.7 to 3.8 N/100 mm (25% compression)

    Decreased wall thickness

    2 N/100 mm for a 0.1 mm wall thickness reduction

    (50% compression)

    1.7 N/100 mm for 0.1 mm wall thickness reduction

    (25% compression)

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    Conclusions Profile shape has a large effect on TPV sponge CSet

    and CLD.

    Profile shape for TPV can be optimised for CSet and

    CLD independently of sponge specific gravity.

    TPV CSet is consistent over time

    TPV sponge CSet EPDM sponge CSet after 700

    hours (29 days).

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    THANK YOU

    FOR YOUR ATTENTION!

    The authors would like to thank Curt Waddle from

    ExxonMobil Chemical for profile testing support.

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    2006 Exxon Mobil Corporation. To the extent the user is entitled to disclose anddistribute this document, the user may forward, distribute, and/or photocopy thiscopyrighted document only if unaltered and complete, including all of itsheaders, footers, disclaimers, and other information. You may not copy thisdocument to a Web site. The information in this document relates only to thenamed product or materials when not in combination with any other product ormaterials. We based the information on data believed to be reliable on the datecompiled, but we do not represent, warrant, or otherwise guarantee, expresslyor impliedly, the merchantability, fitness for a particular purpose, suitability,accuracy, reliability, or completeness of this information or the products,materials, or processes described. The user is solely responsible for alldeterminations regarding any use of material or product and any process in itsterritories of interest. We expressly disclaim liability for any loss, damage, orinjury directly or indirectly suffered or incurred as a result of or related to anyoneusing or relying on any of the information in this document. There is noendorsement of any product or process, and we expressly disclaim any contraryimplication. The terms, we, our, "ExxonMobil Chemical", or "ExxonMobil" areused for convenience, and may include any one or more of ExxonMobilChemical Company, Exxon Mobil Corporation, or any affiliates they directly orindirectly steward. The ExxonMobil Emblem, the Interlocking X Device,Santoprene and Vistalon are trademarks of ExxonMobil Corporation.

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