Topic 4.1.2 - Alkanes€¦ · the case of alkanes? Combustion in a limited supply of oxygen...
Transcript of Topic 4.1.2 - Alkanes€¦ · the case of alkanes? Combustion in a limited supply of oxygen...
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OCR (A) Chemistry A-levelTopic 4.1.2 - Alkanes
Flashcards
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What is an alkane?
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What is an alkane?
A saturated hydrocarbons containing C-H bonds only
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What is the general formula of an alkane?
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What is the general formula of an alkane?
CnH2n+2
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Are alkane bonds polar? Why/why not?
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Are alkane bonds polar? Why/why not?
Nonpolar because carbon and hydrogen have similar electronegativities
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What is the shape and angle of an alkane?
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What is the shape and angle of an alkane?
Tetrahedral
109.5°
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Describe the 𝜎 (sigma) bond in alkane
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Describe the 𝜎 bond in alkane
The sigma bond is a covalent bond which has a direct overlap of the electron clouds of the bonding atoms.
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What type of intermolecular forces do alkanes have? Why?
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What type of intermolecular forces do alkanes have? Why?
London force → induced dipole-dipole interaction, because the bonds are nonpolar
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What happens to the boiling point as alkane chain length
increases? Why?
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What happens to the boiling point as alkane chain length increases? Why?
The boiling point increases because there is more surface area and so more number of induced dipole- dipole interaction. Therefore more energy required to overcome the attraction
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Does a branched molecule have lower or higher boiling
point compared to equivalent straight chain? Why?
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Does a branched molecule have lower or higher boiling point compared to equivalent straight chain? Why?
The branched molecule has a lower boiling point because they have fewer surface area and hence less induced dipole -dipole interactions.
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Are alkanes soluble in water? why?
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Are alkanes soluble in water? Explain your answer.
Insoluble because hydrogen bonds in water are stronger than alkanes’ London forces of attraction
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How reactive are alkanes?
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How reactive are alkanes?
Very unreactive
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What reactions will alkanes undergo?
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What reactions will alkanes undergo?
Combustion and reaction with halogens
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What type of reaction is combustion?
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What type of reaction is combustion?
Oxidation reaction
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What is complete combustion?
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What is complete combustion?
Combustion that occurs with plentiful supply of air
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What are the products of complete combustion when
alkanes are used?
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What are the products of complete combustion when alkanes are used?
Carbon dioxide and water
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What is the colour of the bunsen burner flame during
complete combustion?
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What is the colour of the bunsen burner flame during complete combustion?
Blue flame
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What is incomplete combustion and what products
are formed in the case of alkanes?
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What is incomplete combustion and what products are formed in the case of alkanes?
Combustion in a limited supply of oxygen
Products : water, carbon dioxide and carbon monoxide
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Write an equation for the complete combustion of
propane
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Write an equation for the combustion of propane
C3H8 + 5O2 → 3CO2 + 4H2O
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What type of hydrocarbon are most likely to undergo
incomplete combustion?
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Which type of hydrocarbon are most likely to undergo incomplete combustion?
Longer chains
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What is the environmental impact of carbon monoxide?
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What is the environmental impact of carbon monoxide?
It is toxic/poisonous
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What is the environmental impact of soot (carbon)?
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What is the environmental impact of soot (carbon)?
Asthma, cancer, global dimming
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How are halogenoalkanes formed from alkanes?
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How are halogenoalkanes formed from alkanes?
Radical substitution
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In the presence of what does alkane react with halogens?
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In the presence of what does alkane react with halogens?
UV light
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What are the three stages of free radical substitution?
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What are the three stages of free radical substitution?
Initiation - breaking halogen bond to form free radicals
Propagation - chain part of the reaction where prod s
are formed but free radical remains
Termination - free radicals removed, stable products
formed
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Write equations for the reaction of CH4 with Cl2 to
form CH3Cl
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Write equations for the reaction of CH4 with Cl2 to form CH3Cl
Initiation: Cl2 → 2Cl• (in presence of UV light)Propagation: Cl• + CH4 → HCl + •CH3
•CH3 + Cl2 → CH3Cl + Cl•Termination:•CH3 + Cl• → CH3Cl2Cl• → Cl2•CH3+ •CH3→ CH3CH3
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