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Thermodynamics Syllabus

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Lecture hour: Tu: 10:10 to 12:00 (10:10 to 11:30)F: 11:10 to 12:00 (11:00 to 12:10)

Office hour: M: 09:10 to 10:00; 13:10 to 16:00W: 09:10 to 10:00; 13:10 to 16:00Th: 09:10 to 10:00

Consultation: Email to make appointment at office hours

Professor: Dr. Chieh-Ming J. Chang (C-M.J. Chang)Notes uploaded on http://140.120.136.121http://web.nchu.edu.tw/pweb/users/cmchang

Office: NCHU-ChE Building room 610Phone: 0928-696-267Email: cmchang@dragon.nchu.edu.tw

Grading Policy ~50% Continuous Assessment

+ MID-Term Exam+ Quizzes

~50% Final Examination

Author: Stanley I. SandlerPublisher: John Wiley, Copyright 2007 (Asia-Singapore version $50)ISBN-10: 0471-661740Title: Chemical, Biochemical, and Engineering Thermodynamics, 4th Ed..(or ISBN-13: 978-0471-661740, 3rd Ed., 2006)

Textbook

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Notes was based on textbooks of(1) S.I. Sandler's CHEMICAL, BIOCHEMICAL, and

ENGINEERING THERMODYNAMICS, 4th Eds., John Wiley, (2007). Mainly adopted from Chapter 1 (pp1) to Chapter 7 (pp187).

(2) Prausnitz, Lichtenthaler, de Azevedo, Molecular Thermodynamics of Fluid-Phase equilibria, Prentice-Hall, 3rd Ed.,(1999). ISBN-13: 978-0139-777455.

(3) Smith, Van Ness and Abbott's INTRODUCTION of CHEMICAL ENGINEERING THERMODYNAMICS, McGraw Hill, 7th Ed. (2005). ISBN-13: 978-0071-247085.

Notes

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Continuous Assessment QUIZ+MID

Multiple Choice QuestionsDerivations and Calculations

You must take both QUIZ and MID (~ 50% of final total score).

You should not bring along any list of selected formulae or table of physical constant.

Make-up test can not be possible on medical ground or officially approved leave.

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Final Examination Matters

There will only be 4~5 questions & you are required to answer All questions.

Selected formulae and table of physical constant will be given in the Appendix of the exam script.

No make-up Final can be made whatsoever.

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Final Examination Topics

Topics in the Appendices. However, you need to know the concepts in the Appendices to understand the course. For example: Unit conversion in Appendix 1. Heat capacities of gases in Appendix 2. Thermodynamic property of H2O in Appendix 3.

Mainly for the lectures and the home-works, the following topics are NOT included in the examination.

Thermodynamics in the 17th and 18th century was the study of heat and its ability to generate motions; then it merged with the larger subject of energy and its inter-conversion from one form to another. Albert Einstein once said: Thermodynamics is the only physical theory of general nature of which I am convinced that it will never be overthrown. As Einstein noted, it is remarkable that the two laws of thermodynamics are simple to state, but they relate many different phenomena and have a wider range of applicability.

What is Thermodynamics and Why Is It Useful?

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What is this course about?

Chemical Thermodynamics can be applied therein !Chemical Thermodynamics can be applied therein !

Lecture Hours

1- Introduction of Thermodynamics- Ch 1 (3U) 2- Conservation of Mass- Ch 2 (3U) 3- Conservation of Energy- Ch 3 (6U) 4- Entropy: An Additional Balance- Ch 4 (6hrs) 5- Summary of Energy Balance (3U) 6- Summary of Heat Engines- Ch 5 (3U) 7- Preface to Chapter 6 (3U) 8- Thermodynamic Properties of Real

Substances- Ch 6 (9U) 9- Partial Fugacity in Mixtures Ch 7+8+9 (12U) 10- Review and Conclusion (2U)

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ContentsCH 1 INTRODUCTION TO THERMODYNAMICS1.1. The Central Problems of Thermodynamics1.2. Equilibrium Definition1.3. The State Variables of The System1.4. The Three Laws of Thermodynamics1.5. Other Postulates for Thermodynamics1.6. A Comment on The Development of Thermodynamics

CH 2 CONSERVATION OF MASS2.1 A General Balance Equation and Conserved Quantities2.2 Conservation of Mass for a Pure Fluids

CH 3 CONSERVATION OF ENERGY3.1 Conservation of Energy3.2 Several Examples of Using the Energy Balance3.3 The Thermodynamic Properties of Matter3.4 Applications of the Mass and Energy Balances3.5 Summary for Mass and Energy Balance Equations

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CH 4 ENTROPY: AN ADDITIONAL BALANCE EQUATION4.1 Entropy: A New Concept4.2 The Entropy Balance and Reversibility4.3 Heat, Work, Engines, and Entropy4.4 Entropy Changes of Matter4.5 Applications of the Entropy Balance

CH 5 SUMMARY FOR ENTROPY BALANCES AND HEAT ENGINES5.1 Summary for Entropy Balances5.2 Summary for Heat Engines5.3 Preface to Chapter 6

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CH 6 THE THERMODYNAMIC PROPERTIES OF REAL SUBSTANCES6.1 Some Mathematical Preliminaries6.2 The Evaluation of Thermodynamic Partial Derivatives6.3 The Ideal Gas and Absolute Temperature Scales6.4 The Evaluation of Changes in the Thermodynamic Properties of Real Substances Accompanying a Change of State6.5 An Example Involving Change of State of a Real Gas6.6 The Principle of Corresponding States6.7 Generalized Equations of State

CH 7+8+9 PARTIAL FUGACITY IN MIXURES

Appendices1. Unit Conversion2. Heat Capacities of gases3. Thermodynamic properties of steam and water4. Enthalpies and Gibbs Energies of Formation5. Heat of Combustion

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Taiwan Users of Thermodynamics Textbooks

Sandler Smith

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Sandler Smith

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Survey for Chemical Engineering Thermodynamics (Accreditation) Questions used in the survey:

Q1: Student is able to describe fundamental scientific and engineering principles in chemical processes and systems.

Q2: Student is able to formulate the governing equation and to do the

performance evaluation of a given chemical industrial process.

Q3: Student is able to apply scientific and engineering principles for any specific process involving thermodynamics.

Q4: Student is able to analyze and to diagnosis power generation or

refrigeration systems using total mass, energy and entropy equations.

Q5: Student is able to evaluate validity and reliability of chemical engineering thermodynamics models by comparing either known experimental results or theoretical results.

Q6: Student is able to interpret physical significance of thermodynamic

model calculations.

Q7: Student is able to build up a thermodynamic road map and their physical data for newly developed coolants or heating media.

Q8: Student is able to select suitable phase equilibrium equations to model a

specific chemical industrial separation process or system.

Q9: Student is able to apply chemical thermodynamics functions for solving separation processes and systems involving distillation, phase splitting.

Q10: Student is able to justify limitations of thermodynamic models in

predicting the performance of chemical industrial processes and student is able to develop mathematical models in guiding engineering design work.

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- Syllabus+ScheduleAccreditation Survey questions for Ch2108-