Thermodynamic Assessment of the Mn—Y—O System.

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2005 Equilibria E 4000 Thermodynamic Assessment of the Mn—Y—O System. — A complete thermody- namic description of the title system is proposed and an optimized set of parameters of Gibbs energy functions for the compounds h-YMnO3 and YMn2O5 are given. YMn2O5 is stable from room temperature up to 1461 K. Then it decomposes into h-YMnO3 and β-Mn3O4. h-YMnO3 is stable above 1062 K and decomposes into YMn2O5 and α-Y2O3 at lower temperature. — (CHEN*, M.; HALLSTEDT, B.; GAUCKLER, L. J.; J. Alloys Compd. 393 (2005) 1-2, 114-121; Nonmet. Inorg. Mater., Dep. Mater., Swiss Fed. Inst. Technol., CH-8093 Zuerich, Switz.; Eng.) — W. Pewestorf 29- 017

Transcript of Thermodynamic Assessment of the Mn—Y—O System.

2005

EquilibriaE 4000 Thermodynamic Assessment of the Mn—Y—O System. — A complete thermody-

namic description of the title system is proposed and an optimized set of parameters of Gibbs energy functions for the compounds h-YMnO3 and YMn2O5 are given. YMn2O5 is stable from room temperature up to 1461 K. Then it decomposes into h-YMnO3 and β-Mn3O4. h-YMnO3 is stable above 1062 K and decomposes into YMn2O5 and α-Y2O3 at lower temperature. — (CHEN*, M.; HALLSTEDT, B.; GAUCKLER, L. J.; J. Alloys Compd. 393 (2005) 1-2, 114-121; Nonmet. Inorg. Mater., Dep. Mater., Swiss Fed. Inst. Technol., CH-8093 Zuerich, Switz.; Eng.) — W. Pewestorf

29- 017