The Virginia Tech Sustainable Nanotechnology Program IGEP... · The Virginia Tech Sustainable...

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The Virginia Tech Sustainable Nanotechnology Program Peter Vikesland Amy Pruden Linsey Marr

Transcript of The Virginia Tech Sustainable Nanotechnology Program IGEP... · The Virginia Tech Sustainable...

The Virginia Tech Sustainable

Nanotechnology Program

Peter Vikesland

Amy Pruden

Linsey Marr

We live in a world beset

by complex problems

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Obesity

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We live in a world beset

by complex problems

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Water

We live in a world beset

by complex problems

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Resource

Limitationsw

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trans.worldvision.com.au

Energy

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We live in a world beset

by complex problems

Income Inequality

Favelas of Rio de Janeiro

U.S. D.R. of Congo

Hoekstra and Mekonnen ‘The

Water Footprint of Humanity’ PNAS

2012

shutterstock.com

We live in a world beset

by complex problems

Urbanization

The Philippines

Scottsdale, AZ

shutterstock.com

We live in a world beset

by complex problems

Popula

tion

(bill

ions)

Year1800 1900 20001850 1950 2050

1930

1960

1974

1987

1999

2011

2045?

1

2

3

4

5

6

7

8

9

Population

These challenges are

wicked problems…

1) Difficulty in problem formulation

2) Multiple but incompatible solutions

3) Open ended time frames

4) Novelty

5) Competing value systems or

objectives

“…the biggest problems we need to solve now require the expertise of people from different backgrounds

who bridge the gap between disciplines. Unless we learn to share

our ideas with others, we will be stuck with a word of seemingly

impossible problems”

Interdisciplinary Graduate

Education Programs (IGEPs) at Virginia Tech

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Translational

Obesity

Genetics,

Bioinformatics,

and Computational

Biology

Water INTERface

Macromolecular

Science

and Engineering

Multi-Scale

Transport in

Environmental

and Physiological

Systems

Regenerativ

e

Medicine

Remote Sensing

Interfaces ofGlobal Change

Bio-Inspired

BuildingsDisaster

Risk

Management

Translational

Plant Sciences

Human

Centered

Design

Sustainable

Nanotechnology

ComputationalTissue

Engineering

IGEPs at Virginia Tech

Sustainable

Nanotechnology

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VTSuN Interdisciplinary Graduate

Education Program (IGEP)

http://www.sun.ictas.vt.edu

Sustainable Biomaterials

BiomedicalEngineering

Geosciences

Green Engineering

Civil and Environmental Engineering

SuN IGEP

• Overriding concept is to incorporate

sustainable design concepts into the

nanotechnology field.

INPUTS OUTPUTS

IMPACTS

• Materials

• Chemicals

• Water

• Energy

Extraction

Manufacturing

Use

Disposal

• Materials

• Chemicals

• Water

• Energy

Atmosphere

Hydrosphere

Lithosphere

Health

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Sustainable Nanotechnology

DisposalApplicationsManufacturingFate

Processes

Fate

Processes

Incineration(Marr)

Wastewater

(Pruden/Vikesland)

Recycle/capture

Nanomedicine(Roman, Bickford)

Sensors(Vikesland, Pruden, Marr)

Nanocellulose applications(Renneckar)

Nanocellulose(Roman, Renneckar)

Metal NPs(Vikesland)

Fate ProcessesnC60

(Vikesland, Marr)

Metals/Metal oxides/sulfides(Bickford, Hochella, Marr, Michel, Pruden, Vikesland)

CeO2

(Hochella, Marr)

Life Cycle Assessment

AuNPs(McGinnis, Vikesland)

Nanocellulose(McGinnis, Renneckar)

CeO2

16http://www.sun.ictas.vt.edu

Three “Core” courses

Environmental Nanotechnology

Interdisciplinary Sustainable Nanotechnology

Engineering Ethics

One “Elective” course

Bi-weekly meetings

Co-advising of students

GOALA cohort of

students, faculty,

and affiliates with

the collective

expertise to

address the

complexities of

sustainable

nanotechnology

THE PROGRAM

Life Cycle Assessment-Risk

Assessment

After Grieger et al. J. Nanopart. Res. 2012

Raw

Materials

Nanomaterials

Use

Disposal

Thomas Midgley

1889-1944

Hydrofluorocarbons (HFCs)100-10000x larger GWP than CO2

“The evolving and recursive

nature of wicked problems

demands a constant cycle of

anticipation and adaptation as

new information about

feedback effects and

unintended consequences is

discovered.”Seager et al.

2012

Principles of “Green”

Nanomaterial Production1. Design safer nanomaterials

2. Design for reduced environmental impact

3. Design for waste reduction

4. Design for process safety

5. Design for materials efficiency

6. Design for energy efficiency

Hutchison ACS Nano, 2008

1) Design Safer Nanomaterials

Replace toxic materials with non-toxic counterparts

Renneckar, VT

Ex. Replace CNTs with nanocellulose

Artwork byMark Harrington. Copyright University of

Canterbury, 1996

1) Design Safer Nanomaterials

Ex. Surface Enhanced Raman Spectroscopy (SERS)

Gold NPs Silver NPs

NanocomposixNanocomposix

Replace toxic materials with non-toxic counterparts

“Gate to Gate” LCA for Gold

Nanoparticle Production

Paramjeet Pati, Virginia Tech

Line thickness is indicative of the

inherent energy of a particular input or process

Simplified

“Green”

nanoparticle LCATea

Banana Peel

Extract

Grape Pomace

Cinnamon

“Green” syntheses

may not be all that

sustainable…

1) Design Safer Nanomaterials

Replace toxic materials with non-toxic counterparts

What if nanocellulose doesn’t

readily biodegrade?

Ex. Replace CNTs with nanocellulose

Renneckar, VT

1) Design Safer Nanomaterials

Silver NPs

Nanocomposix

Replace toxic materials with non-toxic counterparts

What if persistence is of greater

concern than reactivity?

Gold NPs

Nanocomposix

“The evolving and recursive

nature of wicked problems

demands a constant cycle of

anticipation and adaptation as

new information about

feedback effects and

unintended consequences is

discovered.”Seager et al.

2012

31http://www.sun.ictas.vt.edu

Three “Core” courses

Environmental Nanotechnology

Interdisciplinary Sustainable Nanotechnology

Engineering Ethics

One “Elective” course

Bi-weekly meetings

Co-advising of students

GOALA cohort of

students, faculty,

and affiliates with

the collective

expertise to

address the

complexities of

sustainable

nanotechnology

THE PROGRAM

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DisposalApplicationsManufacturingFate

Processes

Fate

Processes

Laura Reese - PosterAu/AuS (GGS) NP Production

Rebecca Lahr - Tues 3:15Intracellular SERS

Matt Chan - Mon 2:403D SERS Imaging

Jacob Metch - PosterNMs and DBP formation

Marjorie Willner - Sun 3:30Paper Based Sensors

Maria Breazeal - Sun 3:45Aptamer S. aureus sensors

Yanjun Ma - Tues 11:15Wastewater communities

Ron Kent - Tues 3:15AFM Eval. AgNP sulfidation

Fate ProcessesJames Dale - PosterCeO2 in Diesel Exhaust

Peter Vikesland - Mon 1:30Nano. Fate - Past, Present, Future Garghi Singh - Tues 3:30

Nano-cellulose in WW

Life Cycle AssessmentParamjeet Pati - Sun 2:30“Green” syntheses/LCA

Nina Quadros - Mon 11:30VTSuN and the Consumer Products Inventory

[email protected]

@petervikesland

@VTSuN

“How do we make

the world work for

100% of humanity in

the shortest possible

time through

spontaneous

cooperation without

ecological damage

or disadvantage to

anyone?”

Buckminster Fuller