The Study of Natural Rubber - Polyethylene Polymer Mixing Method

8/18/2019 The Study of Natural Rubber - Polyethylene Polymer Mixing Method

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UNIVERSITI TEKNIKAL MALAYSIA MELAKA

THE STUDY OF NATURAL RUBBER/POLYETHYLENE

POLYMER MIXING METHOD

Thesis submitted in accordance with the requirements of theUniversity Technical Malaysia Melaka (UTeM) for the Degree of

Bachelor of Engineering (Honours) Manufacturing (Material Engineering)

By

ROHANI BINTI OSMAN

Faculty of Manufacturing Engineering

March 2008


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DECLARATION

I hereby declare that this report entitled “THE STUDY OF NR/PE POLYMER

MIXING METHOD” is the result of my own research except as cited in the references.

Signature :

Author’s Name : Rohani binti Osman

Date : 28 March 2008


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APPROVAL

This report is submitted to the Faculty of Manufacturing Engineering of UTeM as a

partial fulfillment of the requirements for the degree of Bachelor of Manufacturing

Engineering ( Material Engineering ). The members of the supervisory committee are as

follow:

Muhd.Zaimi Zainal Abidin(Main Supervisor)

28 March 2008

Dr. Mohd Warikh bin Abd Rashid(Co-Supervisor)

28 March 2008


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ABSTRACT

This research is focused on examining and characterizing the properties of combination

of elastomer which is natural rubber with thermoplastic which is polyethylene.

Improvements in strength of polyethylene (PE) can be sought by melt blending with

natural rubbers (NR). In this study, PE is blended with two types of different NR whichis indoor and outdoor storage. In this research, it is studying about the properties with

two type of polymer which is elastomer and thermoplastic when they are blending

together. The purpose of this research is to improve the thermoplastic elastomer based

on rubber-plastic blends and also to determine their mechanical properties with different

ratio mixing between of them. The ratio percentage blended between natural rubber and

polyethylene that are focused in this work which is 10%, 20% and 30% of natural

rubber. Each percentage of this, were examining their mechanical properties with two

types of testing which are flexure test and tensile test. In the end of this research, NR

indoor is identified as a good NR that can blended properly with polyethylene than NR

outdoor based on the result from mechanical testing.


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ABSTRAK

Kajian ini adalah fokus kepada penilaian dan ciri-ciri sifat yang ada pada penggabungan

elastomer iaitu getah natural dengan plastic haba iaitu polietilena. Pembaikan atau

peningkatan dalam kekuatan yang ada pada “polyethylene” boleh diperoleh melalui

campuran cair bersama dengan getah natural. Dalam kajian ini juga, polietilenadicampurkan dengan dua jenis getah natural yang berlainan keadaan iaitu getah natural

yang diletakkan didalam rumah (terlindung dari cahaya matahari) dan getah natural yang

diletakkan diluar rumah (terdedah kepada cahaya matahari, hujan dan sebagainya).

Didalam kajian ini, sifat-sifat yang terhasil diantara elastomer dan plastik haba kesan

daripada gabungan kedua-duanya telah dikaji. Tujuan kajian ini dilakukan adalah untuk

memperbaiki atau meningkatkan sifat yang ada pada “plastik haba elastomer”

berdasarkan campuran yang dilakukan dan juga untuk menentukan sifat-sifat mekanikal

mengikut nisbah campuran yang berlainan. Manakala peratus nisbah campuran diantara

getah natural dan polietilena dalam kajian ini hanya tertumpu kepada 10%, 20% dan

30% dari getah natural. Setiap peratusan ini, dinilai kekuatan mekanikalnya melalui dua

jenis ujian iaitu ujian tegangan dan ujian pelenturan. Di akhir kajian ini, keputusan yang

dicapai adalah getah yang diletakkan didalam rumah adalah lebih bagus dan elok dalam

pencampuran bersama dengan polietilena berbanding dengan getah yang diletakkan

diluar rumah.


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DEDICATION

I want to dedicate this research project to my father, Osman bin Husin; who

everlastingly stays in my heart, my mother, Fatimah binti Hj.Isa, my brothers, Arifin

Osman, Muhd Al-Amin Osman and Fauzi Osman, my sisters, Mastura Osman and other

members of my family for their continual support, prayers, understanding and mostimportantly patience during my time in graduate school.


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ACKNOWLEDGEMENTS

During several steps of one’s life, the road seems uphill and full with challenges

and obstacles. While we are traveling along that road, countless times we sigh and then

ask ourselves what is the reason of going through. It is indubitably true about the part of

my life here, in Malacca. Still and all, this journey is enjoyable and memorable becauseof helps and kindness from a special group of individuals that I would like to mention as

follows. Not only I have gained much knowledgement about polymers here, but also I

have learned to work and to discipline myself in order to achieve certain important goals

in life.

I would like to express my deepest appreciation to my supervisor, Mr.

Muhd.Zaimi Zainal Abidin, for giving me the opportunity, the support and the guidance,

for his kindness and generosity. They were so enormous and I was very fortunate to be

one of his students. I would also like to thank many faculty members in the Department

of Manufacturing Engineering especially to the entire technician, for their helpful in

providing time and advice support for my research. I express gratitude all my friends in

Faculty of Manufacturing Engineering especially to student Material Engineering, for

their support and encouragement. They have shown that virtue and dignity are much

more important than other things in life and they have taught me not by words but by

examples. I am forever thankful to them. I was taught how to dream the impossible

dream and was given the courage to swim upstream in order to make even a small

difference. I hope that my work will not be the disappointment for them.


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TABLE OF CONTENTS

Declaration………………………………………………………………………….. ii

Approval…………………………………………………………………………..... iii

Abstract…………………………………………………………………………….. iv

Abstrak……………………………………………………………………………… v

Dedication…………………………………………………………………………... vi

Acknowledgements………………………………………………………………… vii

Table of Contents…………………………………………………………………… viii

List of Figures………………………………………………………………………. xiList of Tables……………………………………………………………………….. xiii

List of Abbreviations, Symbols, specialized Nomenclature………………………... xiv

1. INTRODUCTION ……………………………………………………………… 1

1.1 .Introduction………………………………………………………………….. 1

1.2 Problem Statement…………………………...…………………………….... 3

1.3 Objectives……………………………………………………………………. 31.4 Scope of Project…………………………………………………………….... 4

2. LITERATURE REVIEW ................................................................................... 5

2.1 Introduction……………………………………………….…………..…….. 5

2.2 Elastomer…...……...….…………………………………………………….. 5

2.2.1 Examples of Elastomer……………………………….……………….... 7

2.2.2 Elastomer Properties Chart………………..……….…………………… 82.2.3 Natural Rubber………………..…………….…………………………... 9

2.3 Thermoplastic……….……………………………………………………… 19

2.3.1 Polyethylene (PE)………………………….………..………………….. 19

2.4 Polymer Blends…………………………….………………………………. 21


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2.4.1 Importance and Characteristics of Polymer Blends……………………... 22

2.4.2 Why Blending………………...…….…………………………………… 22

2.4.3 Morphology of Polymer Blends…………………….……………..……. 24

2.4.4 Thermodynamics of Polymer Blends………………………….……..…. 242.4.5 Mechanical Properties………….………………..……………………… 25

2.4.6 Compatibilizers…………….……………..…………………………….. 25

2.4.7 Techniques of Blending………………….……………………...………. 26

2.4.8 Machinery used for Manufacturing Polymer Blends………………..….. 27

2.4.9 Important Blends….……………..……………………………………… 28

3. METHODOLOGY ………………………………………………………….… 29

3.1 Introduction…………………………………………………………….…... 29

3.2 Planning of Study………………………………………………….……….. 29

3.3 Process………………………………………………………………..…….. 31

3.3.1 Mixer Testing………………………………………………………..….. 31

3.3.1.1 Material/Equipment………………………………………..……….. 32

3.3.1.2 Result ……………………………………………………………….. 33

3.3.1.3 Graph result of mixer process …………………………………….... 343.3.2 Crusher Process………………………………………..………………... 37

3.3.2.1 Material/Equipment……………………………..………………….. 38

3.3.3 Drying Process……………………………………………..…………… 39

3.3.4 Hot Press Process………………………………………………..……… 39

3.3.4.1 Equipment……………………………………………..…………..... 40

3.3.4.2 Parameter…………………………………………...……………….. 40

3.3.4.3 Result after hot press………………………………………………… 41

3.3.5 Sample Cutting…………………………………………………...……… 42

3.3.5.1 Tensile specimen…………………………………………………..... 42

3.3.5.2 Flexure specimen………………………………………………...….. 44

3.3.6 Mechanical Testing…………………………………………………..…. 45


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3.3.6.1 Tensile Test………………………………………………..………... 45

3.3.6.2 Flexure Test…………………………………………………..……... 46

4. RESULT ………………………………………………………………………... 484.1 Introduction……………………………………………………..………….. 48

4.2 Tensile Test for NR/PE blends and Pure PE……………………..………… 48

4.3 Flexure Test for NR/PE blends and Pure PE…………………………….… 53

5. DISCUSSION ……………………………………………...…………………… 57

5.1 Introduction………………………………………………………………...... 57

5.2 Tensile Properties……………………………………………………………. 575.3 Flexure Properties………………………...…………………………………. 61

6. CONCLUSION AND RECOMMENDATION FOR FURTHER WORK …. 64

6.1 Conclusion…………………….…………………………………………… 64

6.2 Recommendation for Further Work…………………………………………. 65

REFERENCES …………………………………………………………………….. 66

APPENDICES

A Gantt Chart 68

B Table of Tensile Test Result 70

C Table of Flexural Test Result 71


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LIST OF FIGURES

2.1 Schematic drawing of an unstressed polymer 6

2.2 Chemical structure of natural rubber 10

2.3 Structure of cyclized rubber 12

2.4 Graph of pH value 15

2.5 Graph of NH 3 content 16

2.6 Graph of MST 17

2.7 Fishbone diagram 19

2.8 Structure of polyethylene 202.9 Molecule of linear polyethylene 20

2.10 Types of polymer blends 23

2.11 Morphology of polymer blends 24

2.12 Graph of mechanical properties of polymer blends 25

3.1 The flow Chart of Study Planning 30

3.2 Mixer Machine 32

3.3 Sample of PE 33

3.4 Sample of NR after drier 33

3.5 NR mixing with PE 33

3.6 Graph of mixer NR (indoor) 10% with PE 90% 34




3.10 Graph of mixer NR (outdoor) 20% with PE 80% 36

3.11 graph of mixer NR (outdoor) 30% with PE 70% 37

3.12 Crusher machine 38

3.13 Sample from mixing NR and PE 38

3.14 Sample after crusher 38


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3.15 Flow of the basic hot press method 39

3.16 Hot press machine model GT-7014-A 40

3.17 PE sample (300 mm x 300 mm x 2 mm) 41

3.18 NR/PE mixing sample (300 mm x 300 mm x 2 mm) 423.19 Specimen dimension for tensile test 42

3.20 Cutter machine 43

3.21 Example of tensile specimen 43

3.22 Example of flexure specimen 44

3.23 Universal Testing Machine 45

3.24 Specimen gripped 45

3.25 Flexure machine 473.26 Specimen is loaded between a supports span 47

4.1 Comparison strain between NR (indoor) / PE and PE pure 49

4.2 Comparison strain between NR (outdoor) /PE and PE pure 49

4.3 Comparison stress between NR (indoor) / PE and PE pure 50

4.4 Comparison stress between NR (outdoor) / PE and PE pure 50

4.5 Comparison modulus of elasticity between NR(indoor)/PE and PE pure 51

4.6 Comparison modulus of elasticity between NR(outdoor)/PE and PE pure 52

4.7 Comparison strain between NR (indoor) / PE and PE pure 53

4.8 Comparison strain between NR (outdoor) /PE and PE pure 54

4.9 Comparison stress between NR (indoor) / PE and PE pure 54

4.10 Comparison stress between NR (outdoor) / PE and PE pure 55

4.11 Comparison flexure modulus between NR(indoor)/PE and PE pure 56

4.12 Comparison flexure modulus between NR (outdoor)/PE and PE pure 56

5.1 Elongation of PE specimen 59

5.2 NR/PE specimen elongates and breaks off 59

5.3 Force that applied to the specimen 62


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LIST OF TABLES

2.1 Comparison between natural rubber latex and synthetic rubber latex 10

2.2 Specification for NR latex concentrate properties 11

2.3 Data of chemical testing 14

3.1 Parameter setting for mixer test (10% NR: 90% PE) 31



3.4 Parameter setting for hot press process 413.5 Specimen dimensions for thickness 2mm 43

3.6 Specimen dimensions for flexure testing 44

4.1 Comparison of strain and stress result for NR/PE blends and PE pure 48

4.2 Comparison modulus of elasticity result for NR/PE blends and PE pure 51

4.3 Comparison of strain and stress result for NR/PE blends and PE pure 53

4.4 Comparison of flexure modulus result for NR/PE blends and PE pure 55

5.1 Elongation for each of sample testing 60

5.2 Maximum force for flexure test 62


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LIST OF ABBREVIATIONS, SYMBOLS, SPECIALIZED

NOMENCLATURE

TPE - Thermoplastic elastomer

NR - Natural rubber

PE - Polyethylene

HA - High ammonia latex

LATZ - Low ammonia latex

IR - Polyisoprene

IIR - Copolymer of isobutylene and isoprene

CIIR - Chloro Butyl Rubber

BIIR - Brono Butyl Rubber

BR - Polybutadiene

SBR - Styrene butadiene rubber

NBR - buna N.rubber

HNBR - Hydrated Nitrile Rubbers

CR - Chloroprene RubberEPM - ethylene propylene rubber

ECO - Epichloroyhdrin rubber

ACM, ABR - Polyacrylic rubber

SI - Silicone rubber

FVMQ - Fluorosilicone rubber

FPM - Fluoroelastomers

FFRM - Perfluoroelastomers

PEBA - Polyether Block Amides

FEPM - Tetrafluoro ethylene

CSM - Chlorosulfonated polyethylene

EVA - Ethylene vinylacetate


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TPV - Thermoplastic vulcanizates

NRL - Natural rubber latex

EB - Extensibility

NH 3 - AmmoniaMST - Mechanical stability time

VFA - Volatile fatty acid number

ISO - International Standard Operation

H - Hydrogen

C - Carbon

LDPE - Low-density polyethylene

HDPE - High-density polyethylenePVC - Polyvinyl chloride

W - Width

L - Length

G - Gage length

R - Radius

D - Distance

ε - Strain

σ - Stress

E - Modulus of elasticity

EL - Elongation

σ b - Flexure strength

LNR - Liquid natural rubber


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CHAPTER 1

INTRODUCTION

1.1 Introduction

In combining together different materials to form a mixture, there are two majorconcerns. One of these is to produce a homogeneous mixture on a global level. The

achievement of compositional homogeneity in a mixing process is said to occur through

distributive mixing. The second concern is to produce as fine a dispersion of the

ingredients as possible (James L.White, 2001). For rubber-plastic blends, they have been

commercialized as thermoplastic elastomers (TPEs). The mechanical and rheological

properties of these blends depend not only on those of constituent polymers but also on

the morphologies of blends. In order to improve the properties of thermoplastic

elastomers based on rubber-plastic blends, one should understand the relationships

between morphology, processing and properties of these materials.

Natural rubber (NR) and polyethylene (PE) are very important industrial elastomer and

thermoplastic, respectively which both are widely used in different industries.

Thermoplastic properties can be imparted into natural rubber (NR) via its melt blending

with any compatible thermoplastic such as polyethylene (PE). Such blend is generally

termed thermoplastic natural rubber and by the physical characteristics exhibit, is

categorized as an elastomer lying between rubbers and plastics (Azizan Ahmad, 2005).

This project is study to obtain the mechanical properties of blends of natural rubber

(NR) with polyethylene (PE). This enables a green material to enter many markets from

which it had previously been precluded for several decades, such as automotive


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weatherstrip. Structurally, polyethylene is expected to be more readily compatible with

natural rubber when they are blended together (Azizan Ahmad, 2005).

Thermoplastic elastomers (TPEs) have become very important during last few decades.Thermoplastic elastomeric compositions based on rubber-plastic blends are becoming

increasingly significant because of their combination of elastomeric properties and ease

of thermoplastic processing to give low-cost end-use products. In order to improve the

properties of thermoplastic elastomers based on rubber-plastic blends, or to find new

rubber-thermoplastic combination to form thermoplastic elastomers, one should

understand the relationships between morphology, processing and properties of these

materials. Thermoplastic natural rubber is being based on blends of NR withthermoplastic which is polyethylene (PE). It can blend with different ratios and a wide

range of properties can be obtained.

In this study, natural rubber is used as one types of elastomer. It is because hevea-based

natural rubber (NR) is one of the most interesting rubbers, because of its unique

properties in numerous respects and also because of its low price in some tropical

countries, especially in Southeast Asia. Natural rubber latex is stabilized by proteins

layer and fatty acid surfactants/lipids on the surface of the rubber particles which carry a

negative charge. Actually, latex concentrate is divide to two categories which is high-

ammonia latex (HA), preserved with not < 0.61% ammonia and low ammonia latex

(LATZ), preserved with not


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1.2 Problem Statement

Natural rubber (NR) is one of the most interesting rubbers because of its unique

properties in numerous respects. Because of that, NR is blended with another type of

polymer in order to improve their properties. But, the problem is, in what condition or

type of natural rubber is a good quality before blend it with another material. So, in this

study it must to be investigating for getting the good and best quality of properties

natural rubber between indoor and outdoor storage. It is because, the properties of

natural rubber will changes and their quality will decrease time by time. Besides that,

the advantages and disadvantages relationship between natural rubbers blend with

polyethylene also must to be investigate to find a new rubber-thermoplasticcombinations in order to form a good product in future.

1.3 Objectives

i) To compared their properties between two different condition of natural rubber

which is NR in outdoor storage and NR in indoor storage.

ii) To determined the stabilization of the natural rubber with different condition.

iii) To study about the combination of natural rubber with thermoplastic (PE).


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CHAPTER 2

LITERATURE REVIEW

2.1 Introduction

This chapter is describing the topic of elastomer and thermoplastic, how natural rubber

or elastomer can blend with thermoplastic and answers the following questions:

a) What is elastomer?

b) What is thermoplastic?

c) What is polymer blends?

2.2 Elastomer

The term elastomer is often used interchangeably with the term rubber, and is preferred

when referring to vulcanisates. Elastomer comes from two terms, elastic (describing the

ability of a material to return to its original shape when a load is removed) and mer

(from polymer, in which poly means many and mer means parts ). Each link of the chain

is the "-mer" or basic unit that is usually made of carbon, hydrogen, oxygen and/or

silicon. To make the chain, many links or "-mers" are hooked or polymerized together.

They are amorphous polymers existing above their glass transition temperature, so that

considerable segmental motion is possible. At ambient temperatures rubbers are thus

relatively soft (E~3MPa) and deformable. Their primary uses are for seals, adhesives

and molded flexible parts. .(R.Chandra, S.Mishra, 1995)


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Figure 2.1: Schematic drawing of an unstressed polymer. The dots represent cross-links.

B is the same polymer under stress. When the stress is removed, it will

return to the A configuration.

Elastomers are usually thermosets (requiring vulcanization) but may also be

thermoplastic (see thermoplastic elastomer). The long polymer chains cross-link during

curing. The molecular structure of elastomer can be imagined as a 'spaghetti and

meatball' structure, with the meatballs signifying cross-links. The elasticity is derived

from the ability of the long chains to reconfigure themselves to distribute an applied

stress. The covalent cross-linkages ensure that the elastomer will return to its original

configuration when the stress is removed. As a result of this extreme flexibility,

elastomer can reversibly extend from 5-700%, depending on the specific material.

Without the cross-linkages or with short, uneasily reconfigured chains, the applied stress

would result in a permanent deformation. .(R.Chandra, S.Mishra, 1995)


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2.2.1 Examples of elastomer

2.2.1.1 Unsaturated rubbers that can be cured by sulfur vulcanization:

a) Natural Rubber (NR)

b) Polyisoprene (IR)

i. Butyl rubber (copolymer of isobutylene and isoprene, IIR)

ii. Halogenated butyl rubbers (Chloro Butyl Rubber: CIIR; Bromo

Butyl Rubber: BIIR)

c) Polybutadiene (BR)

i. Styrene-butadiene Rubber (copolymer of polystyrene and

polybutadiene, SBR)

ii. Nitrile Rubber (copolymer of polybutadiene and acrylonitrile,

NBR), also called buna N rubbers

iii. Hydrated Nitrile Rubbers (HNBR) Therban® and Zetpol

d) Chloroprene Rubber (CR), polychloroprene, Neoprene, Baypren etc.

2.2.1.2 Saturated Rubbers that cannot be cured by sulfur vulcanization:

i. EPM ( ethylene propylene rubber , a copolymer faeces of

polyethylene and polypropylene) and EPDM rubber ( ethylene

propylene diene rubber , a terpolymer of polyethylene,

polypropylene and a diene-component)

ii. Epichlorohydrin rubber (ECO)

iii. Polyacrylic rubber (ACM, ABR)

iv. Silicone rubber (SI)

v. Fluorosilicone Rubber (FVMQ)

vi. Fluoroelastomers (FKM, FPM) Viton, Tecnoflon, Fluorel, Aflas and

Dai-El


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vii.Perfluoroelastomers (FFKM)Kalrez

viii. Polyether Block Amides (PEBA)

ix. Tetrafluoro ethylene/propylene rubbers (FEPM)

x. Chlorosulfonated Polyethylene (CSM), (Hypalon)xi. Ethylene-vinyl acetate (EVA)

2.2.1.3 Various other types of elastomers:

i. Thermoplastic Elastomers (TPE), for example Hytrel, etc.

ii. Thermoplastic Vulcanizates (TPV), for example Santoprene TPV

iii. Polyurethane rubber

iv.

Resilin, Elastinv. Polysulfide Rubber

2.2.2 Elastomer Properties Chart

Physical propertiesNaturalRubber

NR

StyreneButadiene

SBR

NeopreneCR Urethane

Polymer Spec.Gravity 0.93 0.93 1.23 1.05

Durometer Range 30-100 30-100 15-95 20-100Tensile Strength, PSI 4000+ 3000 3000 To 8000Elongation, % To 700 500 To 800 To 650Tear Resistance Excels Good Good ExcelsWeather Resistance Fair Fair Excels ExcelsSolvent Resistance:AliphaticHydrocarbon Poor Poor Good Excels

Solvent Resistance:Aromatic

Hydrocarbons

Poor Poor Poor Fair

Brittle Point oF -80 -80 -50 -60Stiffening Point oF(avg) -40 -35 -10 -20

Compression Set Good Good Fair ExcelsAbrasion Resistance Excels Excels Good ExcelsFlex Resistance Excels Good Good Good


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2.2.3 Natural Rubber

Natural rubber (NR) is used as a type of elastomer to blend with a thermoplastic which

is polyethylene (PE). So, the background of NR and their properties must be

investigated. Actually rubber is a group of industrial material like metals, fibers, wood,

plastics, glass etc. on which the world of modern technology depends. The world

consumption of rubber is in the order of about 16 million tons per annum and has been

increasing in recent years at the rate of about 4% per annum. Out of this about 1/3 rd is

man made synthetic rubber mainly produced from petroleum fractions.

The unique and versatile properties of rubber have made it highly indispensable for the

modern way of life. The mobility or speed of movement of the modern world mainly

dependent on rubber; in the form of bicycle tyres to highly sophisticated pneumatic tyres

for motor vehicles and aeroplanes etc. Its importance as strategic material due to its

valuable contribution in defence application is well recognized. The distinguishing of

rubber is its resilience and elasticity. In many of its modern applications rubber is not

used alone but reinforced with textiles, metals etc. Contribution of rubber in the field of

engineering, space research, medical sciences, family planning etc. is vital.(R.Chandra,

S.Mishra, 1995)

Actually, latex has divide by two types which is natural rubber latex and synthetic

rubber latex (nitrile and neoprene). But in this study, a natural rubber latex (C 5H8)n is

used for a testing. In its natural state, rubber exists as a colloidal suspension in the latex

of rubber-producing plants. Natural rubber latex (NRL) is a milky fluid that is produced

by the Hevea brazilienis rubber tree found in Africa and Southeast Asia. Often, NRL is

shortened to latex. Natural rubber is " cis 1, 4-polyisoprene " with the chemical structure

of,

The Study of Natural Rubber - Polyethylene Polymer Mixing Method

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